US2018660A - Preservative process for cellulose materials - Google Patents
Preservative process for cellulose materials Download PDFInfo
- Publication number
- US2018660A US2018660A US640351A US64035132A US2018660A US 2018660 A US2018660 A US 2018660A US 640351 A US640351 A US 640351A US 64035132 A US64035132 A US 64035132A US 2018660 A US2018660 A US 2018660A
- Authority
- US
- United States
- Prior art keywords
- approximately
- aqueous solution
- cellulose materials
- preservative
- concentration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 16
- 239000000463 material Substances 0.000 title description 14
- 239000003755 preservative agent Substances 0.000 title description 7
- 230000002335 preservative effect Effects 0.000 title description 7
- 229920002678 cellulose Polymers 0.000 title description 5
- 239000001913 cellulose Substances 0.000 title description 5
- 239000007864 aqueous solution Substances 0.000 description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 208000006558 Dental Calculus Diseases 0.000 description 7
- 239000002895 emetic Substances 0.000 description 7
- 239000002657 fibrous material Substances 0.000 description 7
- 238000011282 treatment Methods 0.000 description 6
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 5
- 239000001263 FEMA 3042 Substances 0.000 description 5
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 5
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 5
- 229940033123 tannic acid Drugs 0.000 description 5
- 235000015523 tannic acid Nutrition 0.000 description 5
- 229920002258 tannic acid Polymers 0.000 description 5
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 4
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 238000004078 waterproofing Methods 0.000 description 3
- 244000198134 Agave sisalana Species 0.000 description 2
- 240000008564 Boehmeria nivea Species 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 240000000491 Corchorus aestuans Species 0.000 description 2
- 235000011777 Corchorus aestuans Nutrition 0.000 description 2
- 235000010862 Corchorus capsularis Nutrition 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2525—Coating or impregnation functions biologically [e.g., insect repellent, antiseptic, insecticide, bactericide, etc.]
Definitions
- My invention relates to a preservative process While the art of chrome tannage oi hides and for. cellulose materials and particularly to one other animal products has been practiced for a for increasing resistance to deterioration when long time, these methods of tanning or preservaexposed in natural bodies of water or to the attion cannot be successfully and, profitably apmosphere, while damp, for relatively long periods. plied to vegetable products.
- My process provides a means for increasing the It is often desirable to apply to products of m resistance to deterioration of articles made of vegetable origin, such as cotton, linen, ramie, cellulose and fibrous materials such as, cotton, manila, sisal, or jute, a water-proofing material.
- My invention may be used for preserving fishn y -p n i pp i n Ser. No.
- a process of preserving fibrous material which comprises treating the degummed'matem rial with a mordant comprised of a heated aqueous solution of which approximately 2% is tannic acid, treating the mordanted material with a heated aqueous solution of which approximately 1% is tartar emetic, and thereafter immersing the material thus treated in an aqueous solution containing potassium bichromate of approximately 1% concentration, copper sulphate of approximately 3% concentration,-andacetic acid of approximately 2% concentration at a temperature 01 approximately 200 F. for approximately 20 minutes.
- a process of-preserving fibrous material which comprises treating the degummed material with an aqueous solution of tannlc acid,
- a process of preserving fibrous material which comprises treating the degummed material with an aqueous solution of tannic acid, treating the material thus treated with an aqueous solution of tartar emetic, and thereafter immersing the material thus treated in an aqueous solution containing potassium bichromate 0t approximately 1% concentration at a temperature of approximately 200 F. for approximately 20 minutes.
- An article of manufacture composed of fibrous material containing a tannic acid and tartar emetic mordant, and a potassium b'ichro- 1o mate oxidant.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Patented Oct. 29, 1935 PATENT OFFICE PRE SERVATIVE PROCESS FOR CELLULOSE MATERIALS Wallace T. Conn, Lawrence, Mass; assignor to the Government of the United States, representedby the Secretary of Commerce No Drawing. Application October 29, 193:.
Serial No. 640,351
Claims. (Cl. 91-08) (Granted under the act of .March 8, 1883, as
amended April The invention described herein may be manufactured and used by or for the Government of the United States for governmental purposes only without the payment of any royalty thereon.
solution of tannic' acid at one hundred and sixty degrees Fahrenheit and then in a one per cent aqueous solution of tartar emetic.
bath gives additional beneficial preservative results. However, the inclusion of the latter two chemicals in the bath are not absolutely essential to accomplish satisfactory preservative results.
5 My invention relates to a preservative process While the art of chrome tannage oi hides and for. cellulose materials and particularly to one other animal products has been practiced for a for increasing resistance to deterioration when long time, these methods of tanning or preservaexposed in natural bodies of water or to the attion cannot be successfully and, profitably apmosphere, while damp, for relatively long periods. plied to vegetable products. My process provides a means for increasing the It is often desirable to apply to products of m resistance to deterioration of articles made of vegetable origin, such as cotton, linen, ramie, cellulose and fibrous materials such as, cotton, manila, sisal, or jute, a water-proofing material. linen, ramie, manila, sisal, jute and other vegesuch as a wax or a fat which is insoluble in I table fibers, when exposed under unfavorable water. Such water-proofing treatments do not conditions and thereby materially increasing the usually conflict with the application of my meth- 15 useful life of such articles. It is a decided im- 0d and treatments may be applied to articles provement over preservative processes considered after receiving my chrome tanning treatment by my predecessor, Mr. Harden F. Taylor, in a and drying, usually with better results than publication entitled Department of Commerce, when applied to similar articles which have 3 Bureau of Fisheries, Document No. 898. not been tanned by my method which leaves the It is a chemical treatment which will increase articles in a condition which permits a more the present standard tensile strengths and/ or rethorough waxing or water-proofing. sistance to deterioration. My invention may be used for preserving fishn y -p n i pp i n Ser. No. 624,139 lines; fish nets; canvas life boat covers; life I have disclosed a process for removing oily or belts; awnings; sailsi tents; wagon covers; toresinous constituents which I have described as bacco cloth and other textiles used for ground a "degumming process, one of which comprises coverings; sewing thread and generally to all boiling the article for about five minutes in an cellulose products which are normally exposed in aqueous solution of soap and sodium carbonate natural bodies of water or are exposed to the i followed by a cold water rinse. A solution of weather or todampness.
One f Of 0118 p cent P White Soap and The foregoing description comprehends only a p nt f s dium ar nat was f und t iv general and preferred embodiment of my invensatisfactory results- In the a e application I tion and detail changes in the process, method d c os d a me o of m rd n n mw a and compositions may be made within the scope st k was xp s d i a tw p efit a s of my claims which are therefore intended as not restricted to the specific details of my invention as disclosed herein.
What I claim is:
1. A process of preserving fibrous material which comprises treating the degummed'matem rial with a mordant comprised of a heated aqueous solution of which approximately 2% is tannic acid, treating the mordanted material with a heated aqueous solution of which approximately 1% is tartar emetic, and thereafter immersing the material thus treated in an aqueous solution containing potassium bichromate of approximately 1% concentration, copper sulphate of approximately 3% concentration,-andacetic acid of approximately 2% concentration at a temperature 01 approximately 200 F. for approximately 20 minutes.
2. A process of-preserving fibrous material which comprises treating the degummed material with an aqueous solution of tannlc acid,
, In the present process of treating fibrous material, I employ the same mordanting process and fixative treatment therefor, i. e., the aqueous solution of tannic acid followed by the aqueous solution oi. tartar emetic, as disclosed and claimed in my copending application ,Serial No. 624,139, and set forth-in the preceding paragraph, but in combination with a following treatment for the material, which comprises immersing the material, treated as above, in an aqueous solution containing potassium bichromate of approximately 1% concentration at a temperature of approximately 200 F. for approximately 20 minutes. I have also found that the addition of 'copper sulphate of approximately 3% concentration and acetic acid (thirty degrees) of approximately 2% concentration to the oxidizing treating the material thus treated with an aqueous solution of tartar emetic, and thereafter immersing the material thus treated in an aqueous solution containing potassium. bichromate, copper sulphate, and'acetic acid.
3. A process of preserving fibrous material which comprises treating the degummed material with an aqueous solution of tannic acid, treating the material thus treated with an aqueous solution of tartar emetic, and thereafter immersing the material thus treated in an aqueous solution containing potassium bichromate 0t approximately 1% concentration at a temperature of approximately 200 F. for approximately 20 minutes.
4. An article composed of fibrous material containing a mordant comprised of tannic acid and tartar emetic, and an oxidant preservative comprised of potassium bichromate, copper sulphate, and acetic acid.
5. An article of manufacture composed of fibrous material containing a tannic acid and tartar emetic mordant, and a potassium b'ichro- 1o mate oxidant.
WALLACE T. CONN.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US640351A US2018660A (en) | 1932-10-29 | 1932-10-29 | Preservative process for cellulose materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US640351A US2018660A (en) | 1932-10-29 | 1932-10-29 | Preservative process for cellulose materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2018660A true US2018660A (en) | 1935-10-29 |
Family
ID=24567892
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US640351A Expired - Lifetime US2018660A (en) | 1932-10-29 | 1932-10-29 | Preservative process for cellulose materials |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2018660A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE917446C (en) * | 1937-09-28 | 1954-09-02 | Chemieprodukte K G | Protective bandage for cables, gas and water pipes or the like |
-
1932
- 1932-10-29 US US640351A patent/US2018660A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE917446C (en) * | 1937-09-28 | 1954-09-02 | Chemieprodukte K G | Protective bandage for cables, gas and water pipes or the like |
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