US20170194443A1 - Loading effect reduction through multiple coat-etch processes - Google Patents

Loading effect reduction through multiple coat-etch processes Download PDF

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Publication number
US20170194443A1
US20170194443A1 US15/079,436 US201615079436A US2017194443A1 US 20170194443 A1 US20170194443 A1 US 20170194443A1 US 201615079436 A US201615079436 A US 201615079436A US 2017194443 A1 US2017194443 A1 US 2017194443A1
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Prior art keywords
reflective material
trench
trenches
height
work function
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US15/079,436
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US9711604B1 (en
Inventor
Jin-Dah Chen
Ming-Feng Shieh
Han-Wei Wu
Yu-Hsien Lin
Po-Chun Liu
Stan Chen
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Taiwan Semiconductor Manufacturing Co TSMC Ltd
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Taiwan Semiconductor Manufacturing Co TSMC Ltd
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Assigned to TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD. reassignment TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: Chen, Jin-Dah, CHEN, STAN, LIN, YU-HSIEN, LIU, PO-CHUN, SHIEH, MING-FENG, WU, HAN-WEI
Priority to US15/079,436 priority Critical patent/US9711604B1/en
Priority to TW105126796A priority patent/TWI590464B/en
Priority to DE102016116586.7A priority patent/DE102016116586B4/en
Priority to CN201610819304.XA priority patent/CN106935488B/en
Priority to KR1020160133507A priority patent/KR101901018B1/en
Priority to US15/642,559 priority patent/US10276392B2/en
Publication of US20170194443A1 publication Critical patent/US20170194443A1/en
Publication of US9711604B1 publication Critical patent/US9711604B1/en
Application granted granted Critical
Priority to US16/396,429 priority patent/US10755936B2/en
Priority to US17/001,382 priority patent/US11387105B2/en
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    • H01L21/78Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
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    • H01L21/8232Field-effect technology
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    • H01L21/823456MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type with a particular manufacturing method of the gate conductors, e.g. particular materials, shapes gate conductors with different shapes, lengths or dimensions
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Definitions

  • the ever-shrinking geometry size brings challenges to semiconductor fabrication. For example, as the device sizes become smaller, variations in device density or size across different parts of the semiconductor device may cause loading problems. The loading problems may lead to undesirably high resistance, for example.
  • FIGS. 1-14 are diagrammatic fragmentary cross-sectional side views of a semiconductor device at various stages of fabrication in accordance with embodiments of the present disclosure.
  • FIG. 15 is a flowchart illustrating a method of fabricating a semiconductor device in accordance with embodiments of the present disclosure.
  • first and second features are formed in direct contact
  • additional features may be formed interposing the first and second features, such that the first and second features may not be in direct contact.
  • Various features may be arbitrarily drawn in different scales for the sake of simplicity and clarity.
  • FIGS. 1-14 are diagrammatic fragmentary cross-sectional side views of a semiconductor device 35 undergoing various stages of fabrication according to embodiments of the present disclosure.
  • the semiconductor device 35 has a substrate 40 .
  • the substrate 40 is a silicon substrate doped with a P-type dopant such as boron (for example a P-type substrate).
  • the substrate 40 could be another suitable semiconductor material.
  • the substrate 40 may be a silicon substrate that is doped with an N-type dopant such as phosphorous or arsenic (an N-type substrate).
  • the substrate 40 may alternatively be made of some other suitable elementary semiconductor, such as diamond or germanium; a suitable compound semiconductor, such as silicon carbide, indium arsenide, or indium phosphide; or a suitable alloy semiconductor, such as silicon germanium carbide, gallium arsenic phosphide, or gallium indium phosphide. Further, the substrate 40 could include an epitaxial layer (epi-layer), may be strained for performance enhancement, and may include a silicon-on-insulator (SOI) structure.
  • epi-layer epitaxial layer
  • SOI silicon-on-insulator
  • shallow trench isolation (STI) features 45 are formed in the substrate 40 .
  • the STI features 45 are formed by etching recesses (or trenches) in the substrate 45 and filling the recesses with a dielectric material.
  • the dielectric material of the STI features 45 includes silicon oxide.
  • the dielectric material of the STI features 45 may include silicon nitride, silicon oxy-nitride, fluoride-doped silicate (FSG), and/or a low-k dielectric material known in the art.
  • DTI deep trench isolation
  • a dummy gate dielectric layer 80 is formed over the substrate 40 .
  • the dummy gate dielectric layer 80 may contain a dielectric material such as silicon oxide or silicon nitride.
  • the dummy gate dielectric layer 80 will be removed as a part of a gate replacement process discussed below.
  • gate structures 120 A, 120 B, and 120 C are formed over the substrate 40 .
  • the gate structure 120 A includes dummy gate dielectric film 80 A, dummy gate electrode 130 A, and spacers 150 A.
  • the gate structure 120 B includes dummy gate dielectric film 80 B, dummy gate electrode 130 B, and spacers 150 B.
  • the gate structure 120 C includes dummy gate dielectric film 80 C, dummy gate electrode 130 C, and spacers 150 C.
  • the formation of the gate structures 120 A- 120 B may include depositing a gate electrode layer 130 and thereafter patterning the gate electrode layer 130 and the layers therebelow (e.g., the dummy gate dielectric layer 80 ) with patterned hard masks 140 A, 140 B, and 140 C, respectively.
  • the gate electrodes 130 A, 130 B, and 130 C are dummy gate electrodes for the gate structure 120 B.
  • the gate electrodes 130 A, 130 B, and 130 C each include a polysilicon material. These dummy gate electrodes 130 A, 130 B, and 130 C will be removed and replaced by functional (e.g., metal) gate electrodes in a gate replacement process discussed below.
  • the hard masks 140 A, 140 B, and 140 C include a dielectric material, such as silicon oxide or silicon nitride.
  • the gate spacers 150 A, 150 B, and 150 C also include a dielectric material.
  • the gate spacers 150 A, 150 B, and 150 C include silicon nitride.
  • the gate spacers 150 A, 150 B, and 150 C may include silicon oxide, silicon carbide, silicon oxy-nitride, or combinations thereof.
  • the gate structure 120 A is formed to have a lateral dimension 160 A
  • the gate structure 120 B is formed to have a lateral dimension 160 B
  • the gate structure 120 C is formed to have a lateral dimension 160 C.
  • the lateral dimension 160 C is substantially greater than the lateral dimensions 160 A and 160 B.
  • the lateral dimension 160 C exceeds the lateral dimensions 160 A or 160 B by a factor of 3 or more.
  • the gate structure 120 C is at least 3 times as wide (or wider) than either the gate structure 120 A or the gate structure 120 B.
  • the lateral dimensions 160 A and 160 B may not be too different from one another.
  • the lateral dimensions 160 A and 160 B are equal to one another.
  • the lateral dimension 160 A is within about 50% to about 200% of the lateral dimension 160 B, or vice versa.
  • the substantially greater lateral dimension 160 C (compared to the lateral dimensions 160 A or 160 B) may cause loading problems, which will be discussed below in more detail.
  • Heavily doped source and drain regions 200 A, 200 B and 200 C are formed in the substrate 40 after the formation of the gate structures 120 A, 120 B, and 120 C.
  • the heavily doped source/drain regions 200 A are formed on opposite sides of the gate structure 120 A
  • the heavily doped source/drain regions 200 B are formed on opposite sides of the gate structure 120 B
  • the heavily doped source/drain regions 200 C are formed on opposite sides of the gate structure 120 C.
  • the S/D regions 200 A- 200 B may be formed by an ion implantation process or a diffusion process known in the art.
  • the source/drain regions 200 A, 200 B and 200 C are aligned with the outer boundaries of the gate spacers 150 A, 150 B, and 150 C, respectively. Since no photolithography process is required to define the area or the boundaries of the source/drain regions 200 A, 200 B, and 200 C, it may be said that the source/drain regions 200 A, 200 B and 200 C are formed in a “self-aligning” manner.
  • One or more annealing processes are performed on the semiconductor device 35 to activate the source/drain regions 200 A, 200 B and 200 C.
  • lightly-doped source/drain (LDD) regions may be formed in the substrate before the gate spacers are formed, but for reasons of simplicity, the LDD regions are not specifically illustrated herein.
  • an inter-layer (or inter-level) dielectric (ILD) layer 220 is formed over the substrate 40 and over the gate structures 120 A, 120 B, and 120 C.
  • the ILD layer 220 may be formed by chemical vapor deposition (CVD), high density plasma CVD, spin-on, sputtering, or other suitable methods.
  • the ILD layer 220 includes silicon oxide.
  • the ILD layer 220 may include silicon oxy-nitride, silicon nitride, or a low-k material.
  • a polishing process 230 (for example a chemical-mechanical-polishing (CMP) process) is performed on the ILD layer 220 to remove portions of the ILD layer 220 .
  • the polishing is performed until a top surface of the dummy gate electrodes of gate structures 120 A, 120 B and 120 C is exposed.
  • the hard masks 140 A, 140 B and 140 C are also removed by the polishing process 230 .
  • one or more etching processes may be performed to remove the dummy gate electrodes 130 A, 130 B, and 130 C, thereby forming openings or trenches 270 A, 270 B, and 270 C.
  • a gate dielectric layer 300 is formed over the substrate 40 and over the ILD layer 220 , partially filling the openings/trenches 270 A, 270 B, and 270 C.
  • the gate dielectric layer 300 is formed by an atomic layer deposition (ALD) process.
  • the gate dielectric layer 300 includes a high-k dielectric material.
  • a high-k dielectric material is a material having a dielectric constant that is greater than a dielectric constant of SiO2, which is approximately 4.
  • the gate dielectric layer 300 includes hafnium oxide (HfO2), which has a dielectric constant that is in a range from approximately 18 to approximately 40.
  • the gate dielectric layer 300 may include one of ZrO2, Y2O3, La2O5, Gd2O5, TiO2, Ta2O5, HfErO, HfLaO, HfYO, HfGdO, HfAlO, HfZrO, HfTiO, HfTaO, and SrTiO.
  • an interfacial layer may be optionally formed before the formation of the gate dielectric layer 300 in some embodiments.
  • the interfacial layer may be formed by an atomic layer deposition (ALD) process and may contain silicon oxide (SiO2).
  • ALD atomic layer deposition
  • SiO2 silicon oxide
  • the gate dielectric layer 300 would then be formed on the interfacial layer.
  • a work function layer 310 is formed over the gate dielectric layer 300 .
  • the work function layer 310 contains a conductive material such as a metal or metal compound.
  • the work function layer 310 may contain materials such as titanium nitride (TiN) material, tungsten (W), tungsten nitride (WN), or tungsten aluminum (WAl).
  • TiN titanium nitride
  • W tungsten
  • WN tungsten nitride
  • WAl tungsten aluminum
  • the work function layer 310 is configured to tune the work function of gates (to be formed in subsequent processes) of transistors, such that a desired threshold voltage may be achieved for the transistor.
  • the work function layer has a thickness in a range from about 10 angstroms to about 50 angstroms.
  • a capping layer may also be formed between the gate dielectric layer 300 and the work function layer 310 .
  • the capping layer contains a lanthanum oxide material (LaOx, where x is an integer).
  • the capping layer can contain rare earth oxides such as LaOx, GdOx, DyOx, or ErOx.
  • the capping layer may work in conjunction with the work function layer 310 to help tune the work function of the gates.
  • an anti-reflective material 330 is formed over the work function layer 310 .
  • the anti-reflective material 330 may be formed by a coating process.
  • the anti-reflective material 330 completely fills the openings/trenches 270 A, 270 B, and 270 C.
  • the anti-reflective material 330 includes a bottom anti-reflective coating (BARC), which may contain an organic material.
  • BARC material is configured to suppress problems associated with reflection by the layers below during a photolithography process to be performed subsequently.
  • a portion 330 A of the anti-reflective material disposed above the opening/trench 270 A has a greater height (i.e., taller) than a portion 330 B of the anti-reflective material disposed above the opening/trench 270 B, and the portion 330 B of the anti-reflective material has a greater height (i.e., taller) than a portion 330 C of the anti-reflective material disposed above the opening/trench 270 C.
  • a height difference 340 A exists between the portion 330 A and the portion 330 B of the anti-reflective material.
  • This height discrepancy or unevenness is caused by loading effects, for example due to the fact that the trench 270 C is closed adjacent to, but is also substantially wider than, the trenches 270 A and 270 B.
  • the loading effect may become exacerbated, which may manifest itself as an even greater unevenness among the upper surfaces of the different portions of the anti-reflective material 330 .
  • This issue if left unaddressed, may lead to problems such as poor trench filling (especially in the trench 270 A) during a metal gate electrode formation process discussed below. This could cause problems such as excessive resistance gate, among other drawbacks.
  • an etch-back process 350 is performed to the anti-reflective material 330 .
  • the etch-back process 350 is configured to etch away the anti-reflective material 330 without substantially etching the materials other than the anti-reflective material 330 .
  • the work function layer 310 is substantially unaffected by the etch-back process 350 .
  • the portion 330 A of the anti-reflective material may be barely coming out of the opening/trench 270 A
  • the portion 330 B of the anti-reflective material may be partially filling the opening/trench 270 B (i.e., a top portion of the opening/trench 270 B is unfilled)
  • the portion 330 C of the anti-reflective material may also be filling the opening/trench 270 C.
  • the portion 330 A of the anti-reflective material may also be sufficiently etched-back such that it no longer fills the opening/trench 270 A completely.
  • the end result of the etch-back process 350 is that the trenches 270 A, 270 B, and 270 C are either filled or partially filled such that the aspect ratio (e.g., depth VS width) of the remaining “trench” is reduced, which will make any subsequent deposition in the trench easier.
  • the aspect ratio e.g., depth VS width
  • an additional coating process is performed to form additional anti-reflective material 330 over the existing anti-reflective material and over the work function metal layer 310 .
  • the additional anti-reflective material 330 has the same material composition as the anti-reflective material 330 formed in the previous coating process discussed above with reference to FIG. 7 . Consequently, the heights of the portions 330 A, 330 B, and 330 C of the anti-reflective material are increased. However, the anti-reflective material 330 has a different surface topography than what is shown in FIG. 7 (i.e., before the etch-back process 350 was performed). In FIG.
  • the surface topography of the anti-reflective material 330 is such that the different portions 330 A, 330 B, 330 C have relatively large differences in height, which as discussed above is caused by loading effects.
  • the surface topography of the anti-reflective material 330 in FIG. 9 is such that the height differences between the portions 330 A, 330 B, and 330 C are reduced.
  • the portion 330 A may still be taller than the portion 330 B, which may still be taller than 330 C, but the height difference between the portion 330 A and 330 B (or 330 B and 330 C) is substantially smaller than compared to the case in FIG. 7 .
  • a height difference 340 B exists between the portion 330 A and the portion 330 B of the anti-reflective material.
  • the height difference 340 B is reduced by at least 50% (or more) compared to the height difference 340 A shown in FIG. 7 .
  • the height difference 340 B between the portions 330 A and 330 B in FIG. 9 may even reach 0.
  • the reduction in the height difference 340 A to 340 B is attributed to the fact that the additional anti-reflective material 330 is coated on existing anti-reflective material 330 (shown in FIG. 8 ) and without having to fill deep trenches.
  • the etch-back process 350 performed in FIG. 8 reduces the effective aspect ratio of the trenches 270 B and 270 C.
  • a photoresist material 370 is formed over the portion 330 C of the anti-reflective material but not over the portions 330 A and 330 B of the anti-reflective material.
  • the formation of the photoresist material 370 may involve one or more spin coating, exposing, developing, baking, and rinsing processes (not necessarily performed in that order).
  • the photoresist material 370 may serve as a protective mask in a subsequent process.
  • an additional etch-back process 390 is performed to partially remove portions 330 A and 330 B of the anti-reflective material in the openings/trenches 270 A and 270 B. Meanwhile, the portion 330 C of the anti-reflective material is protected by the photoresist material 370 and remains unaffected by the etch-back process 390 .
  • the height of the portion 330 A of the anti-reflective material in the trench 270 A is substantially reduced, as is the case for the portion 330 B of the anti-reflective material in the trench 270 B. In other words, a significant portion of the trench 270 A (and the trench 270 B) is now unoccupied by the anti-reflective material 330 , which will allow another conductive material to be deposited therein in a subsequent process.
  • the etch-back process 390 may either not remove enough of the portion 330 A of the anti-reflective material in the trench 270 A (which will adversely affect the subsequent metal filling process), or it may lead to an over-etching of the portion 330 B of the anti-reflective material, which may not leave enough work function metal 310 in the trench 270 B after a metal pullback process is performed subsequently.
  • the present disclosure avoids either of these problems by repeating the coating and etch-back processes, which as discussed above reduces the height difference between the portions 330 A and 330 B of the anti-reflective material filling their respective trenches 270 A and 270 B.
  • a metal pull-back process 400 is performed to remove portions of the work function layer 310 unprotected by the photoresist material 370 .
  • the metal pull-back process 400 includes an etching process where the etchant is configured to remove the material of the work function layer 310 without substantially affecting other materials.
  • the metal pull-back process 400 being performed, portions of the work function layer 310 disposed above the ILD layer 220 are removed, as well as portions of the work function layer 310 disposed on the sidewalls of the trenches 270 A and 270 B.
  • the metal pull-back process 400 forms a work function metal 310 A in the trench 270 A and a work function metal 310 B in the trench 270 B (as well as a work function metal 310 C below the photoresist 370 ).
  • work function metals 270 A, 270 B, and 270 C will serve as elements of their respective gate electrodes and help tune a work function of the respective gate, so that a desired threshold voltage Vt can be achieved.
  • the photoresist material 370 is removed, for example using a photoresist stripping or ashing process.
  • the anti-reflective material 330 is also removed.
  • the work function metals 310 A, 310 B, and 310 C are exposed.
  • the work function metals 310 A and 310 B inherit the improved height uniformity from the previous fabrication stage shown in FIG. 12 .
  • the work function metal 310 A has a height 410 A
  • the work function metal 310 B has a height 410 B. Due to the multiple coating and etch-back processes performed according to the present disclosure, the difference between the height 410 A and the height 410 B is within (or no greater) than the height difference 340 B ( FIG. 9 ) between the portions 330 A and 300 B of the anti-reflective material. In other words, the height difference 340 B may be largely inherited by the work function metals 310 A and 310 B.
  • the height 410 A and the height 410 B can be controlled to be within a certain percentage from each other.
  • the height 410 A differs from the height 410 B by no more than 60%, or vice versa.
  • the height 410 B is 100 angstroms
  • the height 410 A is less than 160 angstroms (i.e., +60% of 100 angstroms) and greater than 40 angstroms (i.e., ⁇ 60% of 100 angstroms).
  • the height 410 A differs from the height 410 B no more than 30%, or vice versa.
  • the height 410 B is 100 angstroms
  • the height 410 A is less than 130 angstroms (i.e., +30% of 100 angstroms) and greater than 70 angstroms (i.e., ⁇ 30% of 100 angstroms).
  • the height 410 A and the height 410 B are controlled to be substantially equal to one another. It can also be seen from FIG. 13 that a height 410 C of the portion of the work function metal 310 C disposed within the trench 270 C is substantially taller than the heights 410 A and 410 B.
  • a conductive material is formed over the work function metals 310 A, 310 B, and 310 C, thereby filling the openings/trenches 270 A, 270 B, 270 C.
  • a planarization process e.g., a CMP process
  • this process forms fill metals 420 A, 420 B, and 420 C, in the trenches 270 A, 270 B, and 270 C, respectively.
  • the fill metals 420 A, 420 B, and 420 C serve as the main conductive portion of their respective gates 450 A, 450 B, and 450 C.
  • the fill metals 420 A, 420 B, and 420 C may contain materials such as tungsten (W), aluminum (Al), titanium (Ti), copper (Cu), or combinations thereof.
  • a blocking layer may also be formed between the work function metals 310 A, 310 B, 310 C and the fill metals 420 A, 420 B, 420 C, respectively.
  • the blocking layer is configured to block or reduce diffusion between the work function metal and the fill metal.
  • the blocking layer contains titanium nitride (TiN) or tantalum nitride (TaN).
  • the fill metals 420 A and 420 B can easily fill the trenches 270 A and 270 B, and as such the resulting gate electrodes will have a desired amount of resistance (i.e., not too high or too low). If the processes of the present disclosure had not been performed, then it is likely that the work function metal in trench 270 A would be substantially taller than the work function metal in trench 270 B, and there may not be a sufficient amount of fill metal formed in trench 270 A, which can lead to degraded resistance of the corresponding gate electrode.
  • the gate resistance is improved, for example both the gate electrodes in trenches 270 A and 270 B will have similar and well-controlled gate resistances).
  • the coating and etch-back processes of the present disclosure may be performed more than twice.
  • an additional etch-back may be performed, followed by a third coating process.
  • the anti-reflective material may have a surface topography that is even more uniform.
  • the final etch-back process and the subsequent metal pull-back process discussed above with reference to FIGS. 11-12 may then be performed. In this manner, the coating and etch-back processes discussed above may be repeated more than once.
  • Additional fabrication processes may be performed to complete the fabrication of the semiconductor device 35 .
  • these additional processes may include formation of conductive contacts for the gates and source/drain regions, deposition of passivation layers, formation of interconnect structures (e.g., metal lines and vias, metal layers, and interlayer dielectric that provide electrical interconnection to the device including the formed metal gate), packaging, and testing.
  • these additional processes are not described herein. It is also understood that some of the fabrication processes for the various embodiments discussed above may be combined depending on design needs and manufacturing requirements.
  • the fabrication process discussed above with reference to FIGS. 1-14 pertain to a “high-k”-last gate replacement process.
  • the gate dielectric layer 300 containing the high-k dielectric material is formed after the removal of the dummy gate electrodes 120 A, 120 B, and 120 C.
  • the concepts of the present disclosure may also apply to a gate-last gate replacement process, where a gate dielectric layer containing the high-k gate dielectric material is formed first, and the dummy gate electrodes are formed on the high-k gate dielectric material. In that case, the removal of the dummy gate electrodes does not remove the high-k gate dielectric material, and the work function metal layer would then be formed over the high-k gate dielectric material.
  • the repeated coating and etch-back processes as discussed above help reduce the surface topography unevenness that is caused by loading effects. As a result, the formation of the fill metal of the gate electrode can still be improved.
  • the multiple coating and etch-back processes discussed above may apply not just in the gate replacement context. Rather, the approach of repeating the cycle of a coating process followed by an etch-back process may be implemented in other semiconductor fabrication contexts, for example in the formation of vias or contacts.
  • Other suitable candidates for the application of the present disclosure include situations where loading effect is a concern, for example when multiple small (e.g., narrow) openings are formed adjacent to a significantly larger (e.g., wider) opening.
  • FIG. 15 is a flowchart illustrating a method 600 of fabricating a semiconductor device according to embodiments of the present disclosure.
  • the method 600 includes a step 610 of forming a first trench, a second trench, and a third trench in a layer over a substrate.
  • the third trench has a greater lateral dimension than the first trench and the second trench.
  • the forming of the first, second, and third trenches is performed such that the lateral dimension of the third trench is at least three times greater than a lateral dimension of the first or a lateral dimension of the second trench.
  • the forming of the first, second, and third trenches is performed such that the lateral dimension of the first trench is substantially equal to the lateral dimension of the second trench.
  • the method 600 includes a step 620 of partially filling the first, second, and third trenches with a first conductive material.
  • the method 600 includes a step 630 of coating a first anti-reflective material over the first, second, and third trenches that are partially filled with the first conductive material.
  • the first anti-reflective material has a first surface topography variation.
  • the coating of the first anti-reflective material is performed such that the first surface topography variation is caused by a loading effect.
  • a first portion of the first anti-reflective material disposed over the first trench is taller than a second portion of the first anti-reflective material disposed over the second trench
  • the second portion of the first anti-reflective material is taller than a third portion of the first anti-reflective material disposed over the third trench.
  • the method 600 includes a step 640 of performing a first etch-back process to partially remove the first anti-reflective material.
  • the method 600 includes a step 650 of coating a second anti-reflective material over the first anti-reflective material.
  • the second anti-reflective material has a second surface topography variation that is smaller than the first surface topography variation.
  • the coating of the second anti-reflective material is performed such that the second anti-reflective material has a same material composition as the first anti-reflective material.
  • the method 600 includes a step 660 of performing a second etch-back process to at least partially remove the second anti-reflective material in the first and second trenches.
  • the method 600 includes a step 670 of partially removing the first conductive material in the first and second trenches. After the step 670 is performed, a first portion of the first conductive material disposed in the first trench has a first height, a second portion of the first conductive material disposed in the second trench has second first height. A difference between the first height and the second height is within a certain percentage of the first height or the second height.
  • a photoresist is formed to cover a portion of the second anti-reflective material disposed over the third trench.
  • the second etch-back process removes portions of the second anti-reflective material not covered by the photoresist.
  • the method 600 may include a step of completely removing the second anti-reflective material and a step of completely filling the first, second, and third trenches with a second conductive material.
  • the first conductive material is a work function metal configured to tune a work function for a gate of a transistor
  • the second conductive material is a fill metal serving as a main conductive portion of the gate of the transistor.
  • the method 600 may include a step of, before the forming the first, second, and third trenches: forming a first dummy gate, a second dummy gate, and a third dummy gate, wherein the first, second, and third trenches are formed by removing the first, second, and third dummy gates, respectively.
  • One advantage is that the processes of the present disclosure can reduce the coating loading between different patterns. As discussed above, by repeating the coating of the anti-reflective material and then repeating the etch-back process, the surface topography variation of the anti-reflective material is substantially reduced. This allows the anti-reflective materials in the trenches to have relatively even heights after the last etching-back process is performed, which in turn allows the work function metals in the trenches to have relatively even heights. As a result, the subsequent fill metal deposition for the metal gate electrode is improved, which allows the metal gates to have improved resistance. Another advantage is that the processes of the present disclosure are compatible with existing fabrication process flow, etc.
  • One aspect of the present disclosure involves a method of fabricating a semiconductor device.
  • a first trench, a second trench, and a third trench are formed in a layer over a substrate.
  • the third trench has a greater lateral dimension than the first trench and the second trench.
  • the first, second, and third trenches are partially filled with a first conductive material.
  • a first anti-reflective material is coated over the first, second, and third trenches that are partially filled with the first conductive material.
  • the first anti-reflective material has a first surface topography variation.
  • a first etch-back process is performed to partially remove the first anti-reflective material. After the first etch-back process is performed, a second anti-reflective material is coated over the first anti-reflective material.
  • the second anti-reflective material has a second surface topography variation that is smaller than the first surface topography variation.
  • a second etch-back process is performed to at least partially remove the second anti-reflective material in the first and second trenches. After the second etch-back process is performed, the first conductive material is partially removed in the first and second trenches.
  • a first opening, a second opening, and a third opening are formed in a dielectric layer over a substrate.
  • the first, second, and third openings have first, second, and third widths, respectively.
  • the third width is at least three times wider than the first width or the second width.
  • the first, second, and third openings are partially filled with a work function metal.
  • the work function metal is configured to tune a work function of a gate of a transistor.
  • a bottom anti-reflecting coating (BARC) material is formed over the work function metal in the first, second, and third openings.
  • a first height difference exists between a first portion of the BARC material disposed over the first opening and a second portion of the BARC material disposed over the second opening.
  • a first etch-back process is performed to partially remove the BARC material.
  • Additional BARC material is formed on the etched-back BARC material.
  • a second height difference exists between a first portion of the additional BARC material disposed over the first opening and a second portion of the additional BARC material disposed over the second opening. The second height difference is smaller than the first height difference.
  • a photoresist material is formed over a third portion of the additional BARC material over the third opening.
  • a second etch-back process is performed to the first and second portions of the additional BARC material. The photoresist material serves as a mask during the second etch-back process.
  • the work function metal is partially removed in the first and second openings. After the work function metal is partially removed, the work function metal disposed in the first opening and the work function metal disposed in the second opening have a height difference that is no
  • the semiconductor device includes a substrate.
  • the semiconductor device also includes a first gate, a second gate, and a third gate disposed over the substrate.
  • the third gate has a greater lateral dimension than the first gate and the second gate.
  • the first, second, and third gates include first, second, and third work function metal components, respectively.
  • the first, second, and third work function metal components are configured to tune a respective work function of the first, second, and third gates, respectively.
  • a height of the first work function metal component is within a certain percentage of a height of the second work function metal component.

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Abstract

First, second, and third trenches are formed in a layer over a substrate. The third trench is substantially wider than the first and second trenches. The first, second, and third trenches are partially filled with a first conductive material. A first anti-reflective material is coated over the first, second, and third trenches. The first anti-reflective material has a first surface topography variation. A first etch-back process is performed to partially remove the first anti-reflective material. Thereafter, a second anti-reflective material is coated over the first anti-reflective material. The second anti-reflective material has a second surface topography variation that is smaller than the first surface topography variation. A second etch-back process is performed to at least partially remove the second anti-reflective material in the first and second trenches. Thereafter, the first conductive material is partially removed in the first and second trenches.

Description

    PRIORITY DATA
  • This application claims priority to Provisional Patent Application No. 62/273,522, filed Dec. 31, 2015, and entitled “Loading Effect Reduction Through Multiple Coat-Etch Processes,” the disclosure of which is hereby incorporated by reference in its entirety.
  • BACKGROUND
  • The semiconductor integrated circuit (IC) industry has experienced rapid growth. Technological advances in IC materials and design have produced generations of ICs where each generation has smaller and more complex circuits than the previous generation. In the course of integrated circuit evolution, functional density (i.e., the number of interconnected devices per chip area) has generally increased while geometry size (i.e., the smallest component (or line) that can be created using a fabrication process) has decreased.
  • The ever-shrinking geometry size brings challenges to semiconductor fabrication. For example, as the device sizes become smaller, variations in device density or size across different parts of the semiconductor device may cause loading problems. The loading problems may lead to undesirably high resistance, for example.
  • Therefore, while existing semiconductor fabrication technologies have been generally adequate for their intended purposes, they have not been entirely satisfactory in every aspect.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • Aspects of the present disclosure are understood from the following detailed description when read with the accompanying figures. It is emphasized that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
  • FIGS. 1-14 are diagrammatic fragmentary cross-sectional side views of a semiconductor device at various stages of fabrication in accordance with embodiments of the present disclosure.
  • FIG. 15 is a flowchart illustrating a method of fabricating a semiconductor device in accordance with embodiments of the present disclosure.
  • DETAILED DESCRIPTION
  • It is to be understood that the following disclosure provides many different embodiments, or examples, for implementing different features of the invention. Specific examples of components and arrangements are described below to simplify the present disclosure. These are, of course, merely examples and are not intended to be limiting. Moreover, the formation of a first feature over or on a second feature in the description that follows may include embodiments in which the first and second features are formed in direct contact, and may also include embodiments in which additional features may be formed interposing the first and second features, such that the first and second features may not be in direct contact. Various features may be arbitrarily drawn in different scales for the sake of simplicity and clarity.
  • FIGS. 1-14 are diagrammatic fragmentary cross-sectional side views of a semiconductor device 35 undergoing various stages of fabrication according to embodiments of the present disclosure. The semiconductor device 35 has a substrate 40. In some embodiments, the substrate 40 is a silicon substrate doped with a P-type dopant such as boron (for example a P-type substrate). Alternatively, the substrate 40 could be another suitable semiconductor material. For example, the substrate 40 may be a silicon substrate that is doped with an N-type dopant such as phosphorous or arsenic (an N-type substrate). The substrate 40 may alternatively be made of some other suitable elementary semiconductor, such as diamond or germanium; a suitable compound semiconductor, such as silicon carbide, indium arsenide, or indium phosphide; or a suitable alloy semiconductor, such as silicon germanium carbide, gallium arsenic phosphide, or gallium indium phosphide. Further, the substrate 40 could include an epitaxial layer (epi-layer), may be strained for performance enhancement, and may include a silicon-on-insulator (SOI) structure.
  • Referring back to FIG. 1, shallow trench isolation (STI) features 45 are formed in the substrate 40. The STI features 45 are formed by etching recesses (or trenches) in the substrate 45 and filling the recesses with a dielectric material. In the present embodiment, the dielectric material of the STI features 45 includes silicon oxide. In alternative embodiments, the dielectric material of the STI features 45 may include silicon nitride, silicon oxy-nitride, fluoride-doped silicate (FSG), and/or a low-k dielectric material known in the art. In other embodiments, deep trench isolation (DTI) features may be formed in place of, or in combination with, the STI features 45.
  • A dummy gate dielectric layer 80 is formed over the substrate 40. The dummy gate dielectric layer 80 may contain a dielectric material such as silicon oxide or silicon nitride. The dummy gate dielectric layer 80 will be removed as a part of a gate replacement process discussed below.
  • Referring now to FIG. 2, gate structures 120A, 120B, and 120C are formed over the substrate 40. The gate structure 120A includes dummy gate dielectric film 80A, dummy gate electrode 130A, and spacers 150A. The gate structure 120B includes dummy gate dielectric film 80B, dummy gate electrode 130B, and spacers 150B. The gate structure 120C includes dummy gate dielectric film 80C, dummy gate electrode 130C, and spacers 150C.
  • The formation of the gate structures 120A-120B may include depositing a gate electrode layer 130 and thereafter patterning the gate electrode layer 130 and the layers therebelow (e.g., the dummy gate dielectric layer 80) with patterned hard masks 140A, 140B, and 140C, respectively. The gate electrodes 130A, 130B, and 130C are dummy gate electrodes for the gate structure 120B. In some embodiments, the gate electrodes 130A, 130B, and 130C each include a polysilicon material. These dummy gate electrodes 130A, 130B, and 130C will be removed and replaced by functional (e.g., metal) gate electrodes in a gate replacement process discussed below.
  • The hard masks 140A, 140B, and 140C include a dielectric material, such as silicon oxide or silicon nitride. The gate spacers 150A, 150B, and 150C also include a dielectric material. In some embodiments, the gate spacers 150A, 150B, and 150C include silicon nitride. In alternative embodiments, the gate spacers 150A, 150B, and 150C may include silicon oxide, silicon carbide, silicon oxy-nitride, or combinations thereof.
  • The gate structure 120A is formed to have a lateral dimension 160A, the gate structure 120B is formed to have a lateral dimension 160B, and the gate structure 120C is formed to have a lateral dimension 160C. As is shown in FIG. 2, the lateral dimension 160C is substantially greater than the lateral dimensions 160A and 160B. In some embodiments, the lateral dimension 160C exceeds the lateral dimensions 160A or 160B by a factor of 3 or more. In other words, the gate structure 120C is at least 3 times as wide (or wider) than either the gate structure 120A or the gate structure 120B. Meanwhile, the lateral dimensions 160A and 160B may not be too different from one another. In some embodiments, the lateral dimensions 160A and 160B are equal to one another. In other embodiments, the lateral dimension 160A is within about 50% to about 200% of the lateral dimension 160B, or vice versa. The substantially greater lateral dimension 160C (compared to the lateral dimensions 160A or 160B) may cause loading problems, which will be discussed below in more detail.
  • Heavily doped source and drain regions 200A, 200B and 200C (also referred to as S/D regions) are formed in the substrate 40 after the formation of the gate structures 120A, 120B, and 120C. The heavily doped source/drain regions 200A are formed on opposite sides of the gate structure 120A, the heavily doped source/drain regions 200B are formed on opposite sides of the gate structure 120B, and the heavily doped source/drain regions 200C are formed on opposite sides of the gate structure 120C. The S/D regions 200A-200B may be formed by an ion implantation process or a diffusion process known in the art.
  • As is illustrated in FIG. 2, the source/ drain regions 200A, 200B and 200C are aligned with the outer boundaries of the gate spacers 150A, 150B, and 150C, respectively. Since no photolithography process is required to define the area or the boundaries of the source/ drain regions 200A, 200B, and 200C, it may be said that the source/ drain regions 200A, 200B and 200C are formed in a “self-aligning” manner. One or more annealing processes are performed on the semiconductor device 35 to activate the source/ drain regions 200A, 200B and 200C. It is also understood that in some embodiments, lightly-doped source/drain (LDD) regions may be formed in the substrate before the gate spacers are formed, but for reasons of simplicity, the LDD regions are not specifically illustrated herein.
  • Referring now to FIG. 3, an inter-layer (or inter-level) dielectric (ILD) layer 220 is formed over the substrate 40 and over the gate structures 120A, 120B, and 120C. The ILD layer 220 may be formed by chemical vapor deposition (CVD), high density plasma CVD, spin-on, sputtering, or other suitable methods. In an embodiment, the ILD layer 220 includes silicon oxide. In other embodiments, the ILD layer 220 may include silicon oxy-nitride, silicon nitride, or a low-k material.
  • Referring to FIG. 4, a polishing process 230 (for example a chemical-mechanical-polishing (CMP) process) is performed on the ILD layer 220 to remove portions of the ILD layer 220. The polishing is performed until a top surface of the dummy gate electrodes of gate structures 120A, 120B and 120C is exposed. The hard masks 140A, 140B and 140C are also removed by the polishing process 230.
  • Referring now to FIG. 5, one or more etching processes may be performed to remove the dummy gate electrodes 130A, 130B, and 130C, thereby forming openings or trenches 270A, 270B, and 270C.
  • Referring to FIG. 6, a gate dielectric layer 300 is formed over the substrate 40 and over the ILD layer 220, partially filling the openings/ trenches 270A, 270B, and 270C. In some embodiments, the gate dielectric layer 300 is formed by an atomic layer deposition (ALD) process. The gate dielectric layer 300 includes a high-k dielectric material. A high-k dielectric material is a material having a dielectric constant that is greater than a dielectric constant of SiO2, which is approximately 4. In an embodiment, the gate dielectric layer 300 includes hafnium oxide (HfO2), which has a dielectric constant that is in a range from approximately 18 to approximately 40. In alternative embodiments, the gate dielectric layer 300 may include one of ZrO2, Y2O3, La2O5, Gd2O5, TiO2, Ta2O5, HfErO, HfLaO, HfYO, HfGdO, HfAlO, HfZrO, HfTiO, HfTaO, and SrTiO.
  • It is understood that an interfacial layer may be optionally formed before the formation of the gate dielectric layer 300 in some embodiments. The interfacial layer may be formed by an atomic layer deposition (ALD) process and may contain silicon oxide (SiO2). The gate dielectric layer 300 would then be formed on the interfacial layer.
  • A work function layer 310 is formed over the gate dielectric layer 300. The work function layer 310 contains a conductive material such as a metal or metal compound. In various embodiments, the work function layer 310 may contain materials such as titanium nitride (TiN) material, tungsten (W), tungsten nitride (WN), or tungsten aluminum (WAl). The work function layer 310 is configured to tune the work function of gates (to be formed in subsequent processes) of transistors, such that a desired threshold voltage may be achieved for the transistor. In some embodiments, the work function layer has a thickness in a range from about 10 angstroms to about 50 angstroms.
  • It is understood that a capping layer may also be formed between the gate dielectric layer 300 and the work function layer 310. In some embodiments, the capping layer contains a lanthanum oxide material (LaOx, where x is an integer). In other embodiments, the capping layer can contain rare earth oxides such as LaOx, GdOx, DyOx, or ErOx. The capping layer may work in conjunction with the work function layer 310 to help tune the work function of the gates.
  • Referring now to FIG. 7, an anti-reflective material 330 is formed over the work function layer 310. The anti-reflective material 330 may be formed by a coating process. The anti-reflective material 330 completely fills the openings/ trenches 270A, 270B, and 270C. In some embodiments, the anti-reflective material 330 includes a bottom anti-reflective coating (BARC), which may contain an organic material. The BARC material is configured to suppress problems associated with reflection by the layers below during a photolithography process to be performed subsequently.
  • As is shown in FIG. 7, a portion 330A of the anti-reflective material disposed above the opening/trench 270A has a greater height (i.e., taller) than a portion 330B of the anti-reflective material disposed above the opening/trench 270B, and the portion 330B of the anti-reflective material has a greater height (i.e., taller) than a portion 330C of the anti-reflective material disposed above the opening/trench 270C. For example, a height difference 340A exists between the portion 330A and the portion 330B of the anti-reflective material.
  • This height discrepancy or unevenness is caused by loading effects, for example due to the fact that the trench 270C is closed adjacent to, but is also substantially wider than, the trenches 270A and 270B. As advanced semiconductor fabrication technology nodes continue to shrink device sizes (including the respective sizes of the trenches 270A, 270B, and 270C), the loading effect may become exacerbated, which may manifest itself as an even greater unevenness among the upper surfaces of the different portions of the anti-reflective material 330. This issue, if left unaddressed, may lead to problems such as poor trench filling (especially in the trench 270A) during a metal gate electrode formation process discussed below. This could cause problems such as excessive resistance gate, among other drawbacks.
  • The present disclosure addresses this issue by performing multiple anti-reflective coating and etch-back processes. Referring now to FIG. 8, an etch-back process 350 is performed to the anti-reflective material 330. The etch-back process 350 is configured to etch away the anti-reflective material 330 without substantially etching the materials other than the anti-reflective material 330. For example, the work function layer 310 is substantially unaffected by the etch-back process 350.
  • In the embodiment shown in FIG. 8, after the performance of the etch-back process 350, the portion 330A of the anti-reflective material may be barely coming out of the opening/trench 270A, the portion 330B of the anti-reflective material may be partially filling the opening/trench 270B (i.e., a top portion of the opening/trench 270B is unfilled), and the portion 330C of the anti-reflective material may also be filling the opening/trench 270C. In other embodiments, the portion 330A of the anti-reflective material may also be sufficiently etched-back such that it no longer fills the opening/trench 270A completely. In any case, the end result of the etch-back process 350 is that the trenches 270A, 270B, and 270C are either filled or partially filled such that the aspect ratio (e.g., depth VS width) of the remaining “trench” is reduced, which will make any subsequent deposition in the trench easier.
  • Referring now to FIG. 9, an additional coating process is performed to form additional anti-reflective material 330 over the existing anti-reflective material and over the work function metal layer 310. In some embodiments, the additional anti-reflective material 330 has the same material composition as the anti-reflective material 330 formed in the previous coating process discussed above with reference to FIG. 7. Consequently, the heights of the portions 330A, 330B, and 330C of the anti-reflective material are increased. However, the anti-reflective material 330 has a different surface topography than what is shown in FIG. 7 (i.e., before the etch-back process 350 was performed). In FIG. 7, the surface topography of the anti-reflective material 330 is such that the different portions 330A, 330B, 330C have relatively large differences in height, which as discussed above is caused by loading effects. In comparison, the surface topography of the anti-reflective material 330 in FIG. 9 is such that the height differences between the portions 330A, 330B, and 330C are reduced. Stated differently, the portion 330A may still be taller than the portion 330B, which may still be taller than 330C, but the height difference between the portion 330A and 330B (or 330B and 330C) is substantially smaller than compared to the case in FIG. 7.
  • For example, a height difference 340B exists between the portion 330A and the portion 330B of the anti-reflective material. In some embodiments, the height difference 340B is reduced by at least 50% (or more) compared to the height difference 340A shown in FIG. 7. In some embodiments, the height difference 340B between the portions 330A and 330B in FIG. 9 may even reach 0. The reduction in the height difference 340A to 340B is attributed to the fact that the additional anti-reflective material 330 is coated on existing anti-reflective material 330 (shown in FIG. 8) and without having to fill deep trenches. Again, the etch-back process 350 performed in FIG. 8 reduces the effective aspect ratio of the trenches 270B and 270C. Shallower trenches are easier to fill, and this effectively reduces the loading effect discussed above. Consequently, the surface topography of the resulting anti-reflective material 330 is “flatter” after the second coating process, as shown in FIG. 9. This will lead to other improvements in later fabrication steps, as discussed in more detail below.
  • Referring now to FIG. 10, a photoresist material 370 is formed over the portion 330C of the anti-reflective material but not over the portions 330A and 330B of the anti-reflective material. The formation of the photoresist material 370 may involve one or more spin coating, exposing, developing, baking, and rinsing processes (not necessarily performed in that order). The photoresist material 370 may serve as a protective mask in a subsequent process.
  • Referring to FIG. 11, an additional etch-back process 390 is performed to partially remove portions 330A and 330B of the anti-reflective material in the openings/ trenches 270A and 270B. Meanwhile, the portion 330C of the anti-reflective material is protected by the photoresist material 370 and remains unaffected by the etch-back process 390. After the etch-back process 390 is performed, the height of the portion 330A of the anti-reflective material in the trench 270A is substantially reduced, as is the case for the portion 330B of the anti-reflective material in the trench 270B. In other words, a significant portion of the trench 270A (and the trench 270B) is now unoccupied by the anti-reflective material 330, which will allow another conductive material to be deposited therein in a subsequent process.
  • Also, since the height difference between the portions 330A and 330B of the anti-reflective material was already minimized as shown in FIG. 10, the height difference between them is still small after the etch-back process 390, as shown in FIG. 11. Had the height difference between the portions 330A and 330B not been minimized, the etch-back process 390 may either not remove enough of the portion 330A of the anti-reflective material in the trench 270A (which will adversely affect the subsequent metal filling process), or it may lead to an over-etching of the portion 330B of the anti-reflective material, which may not leave enough work function metal 310 in the trench 270B after a metal pullback process is performed subsequently. The present disclosure avoids either of these problems by repeating the coating and etch-back processes, which as discussed above reduces the height difference between the portions 330A and 330B of the anti-reflective material filling their respective trenches 270A and 270B.
  • Referring now to FIG. 12, a metal pull-back process 400 is performed to remove portions of the work function layer 310 unprotected by the photoresist material 370. In some embodiments, the metal pull-back process 400 includes an etching process where the etchant is configured to remove the material of the work function layer 310 without substantially affecting other materials. As a result of the metal pull-back process 400 being performed, portions of the work function layer 310 disposed above the ILD layer 220 are removed, as well as portions of the work function layer 310 disposed on the sidewalls of the trenches 270A and 270B. The portions of the work function layer 310 in physical contact with the portions 330A and 330B of the anti-reflective material (in trenches 270A and 270B) are not removed, however. Thus, the metal pull-back process 400 forms a work function metal 310A in the trench 270A and a work function metal 310B in the trench 270B (as well as a work function metal 310C below the photoresist 370). These work function metals 270A, 270B, and 270C will serve as elements of their respective gate electrodes and help tune a work function of the respective gate, so that a desired threshold voltage Vt can be achieved.
  • Referring now to FIG. 13, the photoresist material 370 is removed, for example using a photoresist stripping or ashing process. The anti-reflective material 330 is also removed. As such, the work function metals 310A, 310B, and 310C are exposed. Again, the work function metals 310A and 310B inherit the improved height uniformity from the previous fabrication stage shown in FIG. 12. In some embodiments, the work function metal 310A has a height 410A, and the work function metal 310B has a height 410B. Due to the multiple coating and etch-back processes performed according to the present disclosure, the difference between the height 410A and the height 410B is within (or no greater) than the height difference 340B (FIG. 9) between the portions 330A and 300B of the anti-reflective material. In other words, the height difference 340B may be largely inherited by the work function metals 310A and 310B.
  • In some embodiments, the height 410A and the height 410B can be controlled to be within a certain percentage from each other. For example, in some embodiments, the height 410A differs from the height 410B by no more than 60%, or vice versa. For example, if the height 410B is 100 angstroms, then the height 410A is less than 160 angstroms (i.e., +60% of 100 angstroms) and greater than 40 angstroms (i.e., −60% of 100 angstroms). In some other embodiments, the height 410A differs from the height 410B no more than 30%, or vice versa. For example, if the height 410B is 100 angstroms, then the height 410A is less than 130 angstroms (i.e., +30% of 100 angstroms) and greater than 70 angstroms (i.e., −30% of 100 angstroms). In some embodiments, the height 410A and the height 410B are controlled to be substantially equal to one another. It can also be seen from FIG. 13 that a height 410C of the portion of the work function metal 310C disposed within the trench 270C is substantially taller than the heights 410A and 410B.
  • Referring now to FIG. 14, a conductive material is formed over the work function metals 310A, 310B, and 310C, thereby filling the openings/ trenches 270A, 270B, 270C. A planarization process (e.g., a CMP process) is then performed to remove excessive portions of the conductive material (as well as portions of the gate dielectric layer 300) outside the trenches 270A, 270B, and 270C. As a result, this process forms fill metals 420A, 420B, and 420C, in the trenches 270A, 270B, and 270C, respectively. The fill metals 420A, 420B, and 420C serve as the main conductive portion of their respective gates 450A, 450B, and 450C. In various embodiments, the fill metals 420A, 420B, and 420C may contain materials such as tungsten (W), aluminum (Al), titanium (Ti), copper (Cu), or combinations thereof. In some embodiments, a blocking layer may also be formed between the work function metals 310A, 310B, 310C and the fill metals 420A, 420B, 420C, respectively. The blocking layer is configured to block or reduce diffusion between the work function metal and the fill metal. In some embodiments, the blocking layer contains titanium nitride (TiN) or tantalum nitride (TaN).
  • As a result of the processes performed according to the various aspects of the present discussed above, there is sufficient (i.e., not too much or too little) amount of room in the trenches 270A and 270B. The fill metals 420A and 420B can easily fill the trenches 270A and 270B, and as such the resulting gate electrodes will have a desired amount of resistance (i.e., not too high or too low). If the processes of the present disclosure had not been performed, then it is likely that the work function metal in trench 270A would be substantially taller than the work function metal in trench 270B, and there may not be a sufficient amount of fill metal formed in trench 270A, which can lead to degraded resistance of the corresponding gate electrode. Here, the gate resistance is improved, for example both the gate electrodes in trenches 270A and 270B will have similar and well-controlled gate resistances).
  • It is understood that the coating and etch-back processes of the present disclosure may be performed more than twice. For example, in some embodiments, after the second coating process is performed (as shown in FIG. 9, following the first etch-back process 350 performed in FIG. 8) to form additional anti-reflective material 330, an additional etch-back may be performed, followed by a third coating process. At that point, the anti-reflective material may have a surface topography that is even more uniform. The final etch-back process and the subsequent metal pull-back process discussed above with reference to FIGS. 11-12 may then be performed. In this manner, the coating and etch-back processes discussed above may be repeated more than once.
  • Additional fabrication processes may be performed to complete the fabrication of the semiconductor device 35. For example, these additional processes may include formation of conductive contacts for the gates and source/drain regions, deposition of passivation layers, formation of interconnect structures (e.g., metal lines and vias, metal layers, and interlayer dielectric that provide electrical interconnection to the device including the formed metal gate), packaging, and testing. For the sake of simplicity, these additional processes are not described herein. It is also understood that some of the fabrication processes for the various embodiments discussed above may be combined depending on design needs and manufacturing requirements.
  • It is understood that the fabrication process discussed above with reference to FIGS. 1-14 pertain to a “high-k”-last gate replacement process. In other words, the gate dielectric layer 300 containing the high-k dielectric material is formed after the removal of the dummy gate electrodes 120A, 120B, and 120C. Alternatively, the concepts of the present disclosure may also apply to a gate-last gate replacement process, where a gate dielectric layer containing the high-k gate dielectric material is formed first, and the dummy gate electrodes are formed on the high-k gate dielectric material. In that case, the removal of the dummy gate electrodes does not remove the high-k gate dielectric material, and the work function metal layer would then be formed over the high-k gate dielectric material. Regardless of whether the “gate-last” approach is used or the “high-k last” approach is used, the repeated coating and etch-back processes as discussed above help reduce the surface topography unevenness that is caused by loading effects. As a result, the formation of the fill metal of the gate electrode can still be improved.
  • It is also understood that the multiple coating and etch-back processes discussed above may apply not just in the gate replacement context. Rather, the approach of repeating the cycle of a coating process followed by an etch-back process may be implemented in other semiconductor fabrication contexts, for example in the formation of vias or contacts. Other suitable candidates for the application of the present disclosure include situations where loading effect is a concern, for example when multiple small (e.g., narrow) openings are formed adjacent to a significantly larger (e.g., wider) opening.
  • FIG. 15 is a flowchart illustrating a method 600 of fabricating a semiconductor device according to embodiments of the present disclosure. The method 600 includes a step 610 of forming a first trench, a second trench, and a third trench in a layer over a substrate. The third trench has a greater lateral dimension than the first trench and the second trench. In some embodiments, the forming of the first, second, and third trenches is performed such that the lateral dimension of the third trench is at least three times greater than a lateral dimension of the first or a lateral dimension of the second trench. In some embodiments, the forming of the first, second, and third trenches is performed such that the lateral dimension of the first trench is substantially equal to the lateral dimension of the second trench.
  • The method 600 includes a step 620 of partially filling the first, second, and third trenches with a first conductive material.
  • The method 600 includes a step 630 of coating a first anti-reflective material over the first, second, and third trenches that are partially filled with the first conductive material. The first anti-reflective material has a first surface topography variation. In some embodiments, the coating of the first anti-reflective material is performed such that the first surface topography variation is caused by a loading effect. According to the first topography variation: a first portion of the first anti-reflective material disposed over the first trench is taller than a second portion of the first anti-reflective material disposed over the second trench, and the second portion of the first anti-reflective material is taller than a third portion of the first anti-reflective material disposed over the third trench.
  • The method 600 includes a step 640 of performing a first etch-back process to partially remove the first anti-reflective material.
  • The method 600 includes a step 650 of coating a second anti-reflective material over the first anti-reflective material. The second anti-reflective material has a second surface topography variation that is smaller than the first surface topography variation. In some embodiments, the coating of the second anti-reflective material is performed such that the second anti-reflective material has a same material composition as the first anti-reflective material.
  • The method 600 includes a step 660 of performing a second etch-back process to at least partially remove the second anti-reflective material in the first and second trenches.
  • The method 600 includes a step 670 of partially removing the first conductive material in the first and second trenches. After the step 670 is performed, a first portion of the first conductive material disposed in the first trench has a first height, a second portion of the first conductive material disposed in the second trench has second first height. A difference between the first height and the second height is within a certain percentage of the first height or the second height.
  • It is understood that additional steps may be performed before, during, and after the steps 610-670 of the method 600. For example, in some embodiments, before the performing of the second etch-back process, a photoresist is formed to cover a portion of the second anti-reflective material disposed over the third trench. The second etch-back process removes portions of the second anti-reflective material not covered by the photoresist. As another example, after the first conductive material is partially removed, the method 600 may include a step of completely removing the second anti-reflective material and a step of completely filling the first, second, and third trenches with a second conductive material. The first conductive material is a work function metal configured to tune a work function for a gate of a transistor, and the second conductive material is a fill metal serving as a main conductive portion of the gate of the transistor. As yet another example, the method 600 may include a step of, before the forming the first, second, and third trenches: forming a first dummy gate, a second dummy gate, and a third dummy gate, wherein the first, second, and third trenches are formed by removing the first, second, and third dummy gates, respectively.
  • Based on the above discussions, it can be seen that the present disclosure offers advantages over conventional methods. It is understood, however, that other embodiments may offer additional advantages, and not all advantages are necessarily disclosed herein, and that no particular advantage is required for all embodiment.
  • One advantage is that the processes of the present disclosure can reduce the coating loading between different patterns. As discussed above, by repeating the coating of the anti-reflective material and then repeating the etch-back process, the surface topography variation of the anti-reflective material is substantially reduced. This allows the anti-reflective materials in the trenches to have relatively even heights after the last etching-back process is performed, which in turn allows the work function metals in the trenches to have relatively even heights. As a result, the subsequent fill metal deposition for the metal gate electrode is improved, which allows the metal gates to have improved resistance. Another advantage is that the processes of the present disclosure are compatible with existing fabrication process flow, etc.
  • One aspect of the present disclosure involves a method of fabricating a semiconductor device. A first trench, a second trench, and a third trench are formed in a layer over a substrate. The third trench has a greater lateral dimension than the first trench and the second trench. The first, second, and third trenches are partially filled with a first conductive material. A first anti-reflective material is coated over the first, second, and third trenches that are partially filled with the first conductive material. The first anti-reflective material has a first surface topography variation. A first etch-back process is performed to partially remove the first anti-reflective material. After the first etch-back process is performed, a second anti-reflective material is coated over the first anti-reflective material. The second anti-reflective material has a second surface topography variation that is smaller than the first surface topography variation. A second etch-back process is performed to at least partially remove the second anti-reflective material in the first and second trenches. After the second etch-back process is performed, the first conductive material is partially removed in the first and second trenches.
  • Another aspect of the present disclosure involves a method of fabricating a semiconductor device. A first opening, a second opening, and a third opening are formed in a dielectric layer over a substrate. The first, second, and third openings have first, second, and third widths, respectively. The third width is at least three times wider than the first width or the second width. The first, second, and third openings are partially filled with a work function metal. The work function metal is configured to tune a work function of a gate of a transistor. A bottom anti-reflecting coating (BARC) material is formed over the work function metal in the first, second, and third openings. A first height difference exists between a first portion of the BARC material disposed over the first opening and a second portion of the BARC material disposed over the second opening. A first etch-back process is performed to partially remove the BARC material. Additional BARC material is formed on the etched-back BARC material. A second height difference exists between a first portion of the additional BARC material disposed over the first opening and a second portion of the additional BARC material disposed over the second opening. The second height difference is smaller than the first height difference. A photoresist material is formed over a third portion of the additional BARC material over the third opening. A second etch-back process is performed to the first and second portions of the additional BARC material. The photoresist material serves as a mask during the second etch-back process. Thereafter, the work function metal is partially removed in the first and second openings. After the work function metal is partially removed, the work function metal disposed in the first opening and the work function metal disposed in the second opening have a height difference that is no greater than the second height difference.
  • Yet another aspect of the present disclosure involves a semiconductor device. The semiconductor device includes a substrate. The semiconductor device also includes a first gate, a second gate, and a third gate disposed over the substrate. The third gate has a greater lateral dimension than the first gate and the second gate. The first, second, and third gates include first, second, and third work function metal components, respectively. The first, second, and third work function metal components are configured to tune a respective work function of the first, second, and third gates, respectively. A height of the first work function metal component is within a certain percentage of a height of the second work function metal component.
  • The foregoing has outlined features of several embodiments so that those skilled in the art may better understand the detailed description that follows. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they may make various changes, substitutions and alterations herein without departing from the spirit and scope of the present disclosure.

Claims (21)

1. A method of fabricating a semiconductor device, comprising:
forming a first trench, a second trench, and a third trench in a layer over a substrate, the third trench having a greater lateral dimension than the first trench and the second trench;
partially filling the first, second, and third trenches with a first conductive material;
coating a first anti-reflective material over the first, second, and third trenches that are partially filled with the first conductive material, the first anti-reflective material having a first surface topography variation;
performing a first etch-back process to partially remove the first anti-reflective material;
coating a second anti-reflective material over the first anti-reflective material, the second anti-reflective material having a second surface topography variation that is smaller than the first surface topography variation;
performing a second etch-back process to at least partially remove the second anti-reflective material in the first and second trenches; and
partially removing the first conductive material in the first and second trenches.
2. The method of claim 1, wherein the forming of the first, second, and third trenches is performed such that the lateral dimension of the third trench is at least three times greater than a lateral dimension of the first or a lateral dimension of the second trench.
3. The method of claim 2, wherein the forming of the first, second, and third trenches is performed such that the lateral dimension of the first trench is substantially equal to the lateral dimension of the second trench.
4. The method of claim 1, wherein the coating of the first anti-reflective material is performed such that the first surface topography variation is caused by a loading effect, and wherein according to the first topography variation:
a first portion of the first anti-reflective material disposed over the first trench is taller than a second portion of the first anti-reflective material disposed over the second trench; and
the second portion of the first anti-reflective material is taller than a third portion of the first anti-reflective material disposed over the third trench.
5. The method of claim 1, wherein the coating of the second anti-reflective material is performed such that the second anti-reflective material has a same material composition as the first anti-reflective material.
6. The method of claim 1, further comprising, before the performing of the second etch-back process, forming a photoresist to cover a portion of the second anti-reflective material disposed over the third trench, and wherein the performing of the second etch-back process comprises removing portions of the second anti-reflective material not covered by the photoresist.
7. The method of claim 1, wherein the partially removing the first conductive material is performed such that, after the partially removing:
a first portion of the first conductive material disposed in the first trench has a first height;
a second portion of the first conductive material disposed in the second trench has second first height; and
a difference between the first height and the second height is within a certain percentage of the first height or the second height.
8. The method of claim 1, further comprising, after the first conductive material is partially removed:
completely removing the second anti-reflective material; and
completely filling the first, second, and third trenches with a second conductive material.
9. The method of claim 8, wherein:
the partially filling the first, second, and third trenches comprises filling the first, second, and third trenches with a work function metal as the first conductive material, the work function metal being configured to tune a work function for a gate of a transistor; and
the completely filling the first, second, and third trenches comprises filling the first, second, and third trenches with a fill metal as the second conductive material, the fill metal serving as a main conductive portion of the gate of the transistor.
10. The method of claim 1, further comprising, before the forming the first, second, and third trenches: forming a first dummy gate, a second dummy gate, and a third dummy gate, wherein the first, second, and third trenches are formed by removing the first, second, and third dummy gates, respectively.
11. A method of fabricating a semiconductor device, comprising:
forming a first opening, a second opening, and a third opening in a dielectric layer over a substrate, the first, second, and third openings having first, second, and third widths, respectively, the third width being at least three times wider than the first width or the second width;
partially filling the first, second, and third openings with a work function metal, the work function metal being configured to tune a work function of a gate of a transistor;
forming a bottom anti-reflecting coating (BARC) material over the work function metal in the first, second, and third openings, wherein a first height difference exists between a first portion of the BARC material disposed over the first opening and a second portion of the BARC material disposed over the second opening;
performing a first etch-back process to partially remove the BARC material;
forming additional BARC material on the etched-back BARC material, wherein a second height difference exists between a first portion of the additional BARC material disposed over the first opening and a second portion of the additional BARC material disposed over the second opening, wherein the second height difference is smaller than the first height difference;
forming a photoresist material over a third portion of the additional BARC material over the third opening;
performing a second etch-back process to the first and second portions of the additional BARC material, the photoresist material serving as a mask during the second etch-back process; and
thereafter partially removing the work function metal in the first and second openings, wherein after the partially removing, the work function metal disposed in the first opening and the work function metal disposed in the second opening have a height difference that is no greater than the second height difference.
12. The method of claim 11, wherein the forming of the first, second, and third openings is performed such that the first width is equal to the second width.
13. The method of claim 11, wherein additional BARC material and the BARC material have identical material compositions.
14. The method of claim 11, further comprising:
completely removing the BARC material; and
completely filling the first, second, and third openings with a metal material different from the work function metal.
15. The method of claim 11, further comprising, before the forming the first, second, and third openings: forming a first dummy gate, a second dummy gate, and a third dummy gate, wherein the first, second, and third openings are formed by removing the first, second, and third dummy gates, respectively.
16-25. (canceled)
26. A method of fabricating a semiconductor device, comprising:
forming a first recess, a second recess, and a third recess in a layer over a substrate, the third recess having a lateral dimension that is at least multiple times greater than respective lateral dimensions of the first recess and the second recess;
partially filling the first, second, and third recesses with a first conductive material;
coating a first anti-reflective material over the first, second, and third recesses that are partially filled with the first conductive material, the first anti-reflective material having a first surface topography;
performing a first etch-back process to partially remove the first anti-reflective material;
coating a second anti-reflective material over the first anti-reflective material, the second anti-reflective material having a second surface topography that is different from the first surface topography;
forming a photoresist to cover a portion of the second anti-reflective material disposed over the third recess;
performing a second etch-back process to remove portions of the second anti-reflective material not covered by the photoresist, the second etch-back process at least partially removing the second anti-reflective material in the first and second recesses; and
at least partially removing the first conductive material in the first and second recesses.
27. The method of claim 26, wherein the forming of the first, second, and third recesses is performed such that the lateral dimension of the third recess is at least three times greater than the respective lateral dimensions of the first recess and the second recess.
28. The method of claim 26, wherein the coating of the first anti-reflective material is performed such that the first surface topography is caused by a loading effect, and wherein according to the first topography:
a first portion of the first anti-reflective material disposed over the first recess is taller than a second portion of the first anti-reflective material disposed over the second recess; and
the second portion of the first anti-reflective material is taller than a third portion of the first anti-reflective material disposed over the third recess.
29. The method of claim 26, wherein the partially removing the first conductive material is performed such that, after the partially removing:
a first portion of the first conductive material disposed in the first recess has a first height;
a second portion of the first conductive material disposed in the second recess has second first height; and
a difference between the first height and the second height is within a certain percentage of the first height or the second height.
30. The method of claim 26, further comprising, after the first conductive material is partially removed:
completely removing the second anti-reflective material; and
completely filling the first, second, and third recesses with a second conductive material.
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