US20170178916A1 - Enhanced lateral cavity etch - Google Patents

Enhanced lateral cavity etch Download PDF

Info

Publication number
US20170178916A1
US20170178916A1 US15/429,403 US201715429403A US2017178916A1 US 20170178916 A1 US20170178916 A1 US 20170178916A1 US 201715429403 A US201715429403 A US 201715429403A US 2017178916 A1 US2017178916 A1 US 2017178916A1
Authority
US
United States
Prior art keywords
cavity
semiconductor device
substrate
under
etch
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
US15/429,403
Inventor
Brian E. Goodlin
Karen H. R. Kirmse
Iqbal R. Saraf
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Texas Instruments Inc
Original Assignee
Texas Instruments Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Texas Instruments Inc filed Critical Texas Instruments Inc
Priority to US15/429,403 priority Critical patent/US20170178916A1/en
Publication of US20170178916A1 publication Critical patent/US20170178916A1/en
Pending legal-status Critical Current

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306Chemical or electrical treatment, e.g. electrolytic etching
    • H01L21/3065Plasma etching; Reactive-ion etching
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J5/00Radiation pyrometry, e.g. infrared or optical thermometry
    • G01J5/02Constructional details
    • G01J5/0225Shape of the cavity itself or of elements contained in or suspended over the cavity
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J5/00Radiation pyrometry, e.g. infrared or optical thermometry
    • G01J5/02Constructional details
    • G01J5/0225Shape of the cavity itself or of elements contained in or suspended over the cavity
    • G01J5/024Special manufacturing steps or sacrificial layers or layer structures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306Chemical or electrical treatment, e.g. electrolytic etching
    • H01L21/308Chemical or electrical treatment, e.g. electrolytic etching using masks
    • H01L21/3081Chemical or electrical treatment, e.g. electrolytic etching using masks characterised by their composition, e.g. multilayer masks, materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306Chemical or electrical treatment, e.g. electrolytic etching
    • H01L21/308Chemical or electrical treatment, e.g. electrolytic etching using masks
    • H01L21/3083Chemical or electrical treatment, e.g. electrolytic etching using masks characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/31058After-treatment of organic layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L28/00Passive two-terminal components without a potential-jump or surface barrier for integrated circuits; Details thereof; Multistep manufacturing processes therefor
    • H01L28/10Inductors
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/04Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their crystalline structure, e.g. polycrystalline, cubic or particular orientation of crystalline planes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/06Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
    • H01L29/0657Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape of the body
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/12Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/16Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic System
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/12Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/16Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic System
    • H01L29/161Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic System including two or more of the elements provided for in group H01L29/16, e.g. alloys
    • H01L37/02
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N15/00Thermoelectric devices without a junction of dissimilar materials; Thermomagnetic devices, e.g. using the Nernst-Ettingshausen effect
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N15/00Thermoelectric devices without a junction of dissimilar materials; Thermomagnetic devices, e.g. using the Nernst-Ettingshausen effect
    • H10N15/10Thermoelectric devices using thermal change of the dielectric constant, e.g. working above and below the Curie point
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/311Etching the insulating layers by chemical or physical means
    • H01L21/31127Etching organic layers
    • H01L21/31133Etching organic layers by chemical means
    • H01L21/31138Etching organic layers by chemical means by dry-etching

Definitions

  • This invention relates to the field of semiconductor devices and more specifically to the formation of a cavity wherein the width of the cavity exceeds the depth in a semiconductor device.
  • Cavities are frequently formed in semiconductor circuits to reduce coupling of a device such as an inductor, heater, or bolometer to the substrate.
  • a cavity is etched into a substrate material such silicon or SiGe through an opening in a dielectric layer overlying the substrate using a substantially isotropic etch.
  • the substantially isotropic etch etches the cavity vertically faster than it does laterally. Consequently a very deep cavity may need to be formed to completely remove the substrate laterally from under the device to reduce coupling.
  • the deep cavity may weaken the substrate resulting in breakage and yield loss.
  • One method to avoid etching a deep cavity is to build an etch stop layer into the substrate under the device with the coupling issue. This method may add significant complexity, cycle time, and cost to the manufacturing flow.
  • a cavity is formed in a semiconductor substrate wherein the width of the cavity is greater than the depth of the cavity and wherein the depth of the cavity is non uniform across the width of the cavity.
  • the cavity may be formed under an electronic device in the semiconductor substrate.
  • the cavity is formed in the substrate by performing a first cavity etch followed by repeated cycles of polymer deposition, cavity etch, and polymer removal.
  • FIG. 1A through FIG. 1J are cross sections illustrating the formation of a cavity in an integrated circuit in successive stages of fabrication according to principles of the invention.
  • FIG. 2 is flow diagram for the steps in a process of forming a cavity in a substrate according to principles of the invention.
  • FIG. 1F A structure with a cavity that is etched according to embodiments is illustrated in FIG. 1F .
  • the cavity is etched into the substrate 100 using an etch that is substantially isotropic.
  • the cavity is wider than it is deep.
  • the cavity depth is non uniform across the width of the cavity.
  • the cavity is deepest under the opening through which the cavity is etched.
  • FIG. 1A shows a substrate 100 that may be etched using an etchant that etches substantially isotropically, that is, etches laterally as well as vertically.
  • a hard mask (layers 102 and 104 ) overlies the substrate.
  • the etchant may be introduced through an opening 106 in the hard mask 102 / 104 to etch a cavity in the substrate 100 (step 200 in FIG. 2 ).
  • the substrate 100 is single crystal silicon and the hard mask is comprised of a layer of silicon nitride 104 which overlies a layer of silicon dioxide 102 .
  • One layer of masking material (silicon dioxide for example) may alternatively be used. Other masking materials and other substrates may also be used.
  • the opening 106 in the example embodiment may be in the range of less than a micron to many microns wide depending upon the details of the device being manufactured. In an example embodiment opening 106 is about 25 microns wide.
  • first cavity etch step 202 of FIG. 2 etchant is introduced through opening 106 and etches the substrate 100 both vertically and laterally to form a cavity with first cavity etch sidewalls 108 as shown in FIG. 1B .
  • the silicon substrate 100 is etched in a substantially isotropic manner using a SF 6 plasma etch.
  • the SF 6 etches the silicon approximately twice as fast vertically as laterally through the opening 106 .
  • Example cavity etch process conditions are 225 mT pressure, 4000 Watts source power, 0 Watts bias power, 1000 sccm SF 6 , and a temperature of 15° C.
  • polymer 110 is formed on the bottom and sidewalls 108 of the first etched cavity as shown in FIG. 1C .
  • the polymer 110 is thicker on the bottom of the cavity under the opening 106 and gets thinner on the sidewalls 108 of the cavity away from under the opening 106 .
  • the polymer deposition step is typically performed using a plasma with a fluorocarbon gas, C x H y F z , such as CH 4 , CHF 3 , CH 2 F 2 , C 2 F 6 , C 3 F 6 , and C 4 F 8 .
  • Example polymer deposition process conditions are 10 mT pressure, 3800 Watts source power, 0 Watts bias power, 200 sccm C 4 F 8 , and a temperature of 15° C.
  • an optional ashing step may be performed to remove the polymer from the sidewalls 108 of the cavity where the polymer is thin as shown in FIG. 1D .
  • a breakthrough etch step to remove minor amounts of polymer may be performed at the beginning of the subsequent SF 6 silicon etch.
  • a plasma ashing step with oxygen is used.
  • Example ashing process conditions are 30 mT pressure, 2500 Watts source power, 0 Watts bias power, 200 sccm oxygen, and a temperature of 15° C.
  • a second cavity etch is performed as shown in FIG. 1E .
  • the polymer 110 covering the bottom of the trench prevents the cavity from being etched deeper into the substrate.
  • the etchant enlarges the cavity laterally forming second cavity etch walls 112 that are spaced at a greater lateral distance from the opening than the lateral walls 108 of the first cavity etch (step 202 ).
  • step 210 of FIG. 2 the polymer may be removed from the cavity using an ashing step, as shown in FIG. 1F .
  • This step is optional if the final trench width has not been achieved.
  • a plasma ashing step containing oxygen is used. The ashing conditions are described previously.
  • step 212 of FIG. 2 a determination may be made to see if the target cavity width has been achieved. If the target cavity width is achieved the wafers may be sent on to the next process step in the manufacturing flow (step 214 in FIG. 2 ).
  • the wafers may be returned to step 204 in FIG. 2 and the process of polymer deposition followed by another cavity etch step may be repeated until the target width is achieved.
  • FIGS. 1G through FIG. 1J A second polymer deposition step followed by a third cavity etch is illustrated in FIGS. 1G through FIG. 1J . More than three cycles of polymer deposition, cavity etch, and polymer removal may be performed to achieve the desired cavity width without etching the cavity deeper.
  • step 204 of FIG. 2 polymer is deposited onto the cavity sidewalls 108 and 112 .
  • an optional ashing step is performed to remove the polymer 114 from the lateral sidewalls 112 of the cavity if it is needed.
  • a third cavity etch is performed.
  • the polymer 114 on the bottom of the cavity walls 108 and 112 prevents the cavity from being etched deeper into the silicon.
  • the exposed second cavity etch walls 112 are etched laterally away from the opening 106 to form third etch cavity walls 116 .
  • the polymer is removed from the cavity by ashing.
  • the width of the cavity is substantially wider than the depth of the cavity.
  • the width may be approximately twice the depth or more.
  • This cavity is formed without the addition of an etch stop layer in the substrate which may add significant complexity and cost to the manufacturing flow. Cavities formed when an etch stop layer is used typically have a uniform depth across the width of the cavity. The depth of the cavity formed using the embodiment process is not uniform in depth across the width of the cavity as is illustrated in FIG. 1F and FIG. 1J .

Abstract

A cavity is formed in a semiconductor substrate wherein the width of the cavity is greater than the depth of the cavity and wherein the depth of the cavity is non uniform across the width of the cavity. The cavity may be formed under an electronic device in the semiconductor substrate. The cavity is formed in the substrate by performing a first cavity etch followed by repeated cycles of polymer deposition, cavity etch, and polymer removal.

Description

    CROSS REFERENCE TO RELATED APPLICATIONS
  • This application is a divisional of U.S. Nonprovisional Patent Application Ser. No. 14/973,904, filed Dec 18, 2015, the contents of which are herein incorporated by reference in its entirety.
  • FIELD OF THE INVENTION
  • This invention relates to the field of semiconductor devices and more specifically to the formation of a cavity wherein the width of the cavity exceeds the depth in a semiconductor device.
  • BACKGROUND
  • Cavities are frequently formed in semiconductor circuits to reduce coupling of a device such as an inductor, heater, or bolometer to the substrate. Typically a cavity is etched into a substrate material such silicon or SiGe through an opening in a dielectric layer overlying the substrate using a substantially isotropic etch. Typically the substantially isotropic etch, etches the cavity vertically faster than it does laterally. Consequently a very deep cavity may need to be formed to completely remove the substrate laterally from under the device to reduce coupling. The deep cavity may weaken the substrate resulting in breakage and yield loss.
  • One method to avoid etching a deep cavity is to build an etch stop layer into the substrate under the device with the coupling issue. This method may add significant complexity, cycle time, and cost to the manufacturing flow.
  • SUMMARY
  • The following presents a simplified summary in order to provide a basic understanding of one or more aspects of the invention. This summary is not an extensive overview of the invention, and is neither intended to identify key or critical elements of the invention, nor to delineate the scope thereof. Rather, the primary purpose of the summary is to present some concepts of the invention in a simplified form as a prelude to a more detailed description that is presented later.
  • A cavity is formed in a semiconductor substrate wherein the width of the cavity is greater than the depth of the cavity and wherein the depth of the cavity is non uniform across the width of the cavity. The cavity may be formed under an electronic device in the semiconductor substrate. The cavity is formed in the substrate by performing a first cavity etch followed by repeated cycles of polymer deposition, cavity etch, and polymer removal.
  • DESCRIPTION OF THE VIEWS OF THE DRAWINGS
  • FIG. 1A through FIG. 1J are cross sections illustrating the formation of a cavity in an integrated circuit in successive stages of fabrication according to principles of the invention.
  • FIG. 2 is flow diagram for the steps in a process of forming a cavity in a substrate according to principles of the invention.
  • DETAILED DESCRIPTION OF EXAMPLE EMBODIMENTS
  • The present invention is described with reference to the attached figures. The figures are not drawn to scale and they are provided merely to illustrate the invention. Several aspects of the invention are described below with reference to example applications for illustration. It should be understood that numerous specific details, relationships, and methods are set forth to provide an understanding of the invention. One skilled in the relevant art, however, will readily recognize that the invention can be practiced without one or more of the specific details or with other methods. In other instances, well-known structures or operations are not shown in detail to avoid obscuring the invention. The present invention is not limited by the illustrated ordering of acts or events, as some acts may occur in different orders and/or concurrently with other acts or events. Furthermore, not all illustrated acts or events are required to implement a methodology in accordance with the present invention.
  • A structure with a cavity that is etched according to embodiments is illustrated in FIG. 1F. The cavity is etched into the substrate 100 using an etch that is substantially isotropic. The cavity is wider than it is deep. The cavity depth is non uniform across the width of the cavity. The cavity is deepest under the opening through which the cavity is etched.
  • The method for forming a cavity wherein the width of the cavity is substantially wider than the depth of the cavity is described in the process flow in FIG. 2 and in the cross sections in FIGS. 1A through 1J.
  • FIG. 1A shows a substrate 100 that may be etched using an etchant that etches substantially isotropically, that is, etches laterally as well as vertically. A hard mask (layers 102 and 104) overlies the substrate. The etchant may be introduced through an opening 106 in the hard mask 102/104 to etch a cavity in the substrate 100 (step 200 in FIG. 2). In an example embodiment, the substrate 100 is single crystal silicon and the hard mask is comprised of a layer of silicon nitride 104 which overlies a layer of silicon dioxide 102. One layer of masking material (silicon dioxide for example) may alternatively be used. Other masking materials and other substrates may also be used. The opening 106 in the example embodiment may be in the range of less than a micron to many microns wide depending upon the details of the device being manufactured. In an example embodiment opening 106 is about 25 microns wide.
  • In first cavity etch step 202 of FIG. 2, etchant is introduced through opening 106 and etches the substrate 100 both vertically and laterally to form a cavity with first cavity etch sidewalls 108 as shown in FIG. 1B. In an example embodiment the silicon substrate 100 is etched in a substantially isotropic manner using a SF6 plasma etch. In the example embodiment, the SF6 etches the silicon approximately twice as fast vertically as laterally through the opening 106.
  • Example cavity etch process conditions are 225 mT pressure, 4000 Watts source power, 0 Watts bias power, 1000 sccm SF6, and a temperature of 15° C.
  • In step 204 of FIG. 2 polymer 110 is formed on the bottom and sidewalls 108 of the first etched cavity as shown in FIG. 1C. Typically the polymer 110 is thicker on the bottom of the cavity under the opening 106 and gets thinner on the sidewalls 108 of the cavity away from under the opening 106. The polymer deposition step is typically performed using a plasma with a fluorocarbon gas, CxHyFz, such as CH4, CHF3, CH2F2, C2F6, C3F6, and C4F8.
  • Example polymer deposition process conditions are 10 mT pressure, 3800 Watts source power, 0 Watts bias power, 200 sccm C4F8, and a temperature of 15° C.
  • In step 206 of FIG. 2 an optional ashing step may be performed to remove the polymer from the sidewalls 108 of the cavity where the polymer is thin as shown in FIG. 1D. In some cases so little polymer may be formed in the sidewalls that a separate ashing step is unnecessary. Instead a breakthrough etch step to remove minor amounts of polymer may be performed at the beginning of the subsequent SF6 silicon etch. In the example embodiment a plasma ashing step with oxygen is used.
  • Example ashing process conditions are 30 mT pressure, 2500 Watts source power, 0 Watts bias power, 200 sccm oxygen, and a temperature of 15° C.
  • In step 208 of FIG. 2, a second cavity etch is performed as shown in FIG. 1E. The polymer 110 covering the bottom of the trench prevents the cavity from being etched deeper into the substrate. The etchant enlarges the cavity laterally forming second cavity etch walls 112 that are spaced at a greater lateral distance from the opening than the lateral walls 108 of the first cavity etch (step 202).
  • In step 210 of FIG. 2 the polymer may be removed from the cavity using an ashing step, as shown in FIG. 1F. This step is optional if the final trench width has not been achieved. In the example embodiment a plasma ashing step containing oxygen is used. The ashing conditions are described previously.
  • In step 212 of FIG. 2, a determination may be made to see if the target cavity width has been achieved. If the target cavity width is achieved the wafers may be sent on to the next process step in the manufacturing flow (step 214 in FIG. 2).
  • If, however, the target cavity width is not achieved, the wafers may be returned to step 204 in FIG. 2 and the process of polymer deposition followed by another cavity etch step may be repeated until the target width is achieved.
  • A second polymer deposition step followed by a third cavity etch is illustrated in FIGS. 1G through FIG. 1J. More than three cycles of polymer deposition, cavity etch, and polymer removal may be performed to achieve the desired cavity width without etching the cavity deeper.
  • In FIG. 1G (step 204 of FIG. 2), polymer is deposited onto the cavity sidewalls 108 and 112.
  • In FIG. 1H (step 206 of FIG. 2), an optional ashing step is performed to remove the polymer 114 from the lateral sidewalls 112 of the cavity if it is needed.
  • In FIG. 1I (step 208 of FIG. 2), a third cavity etch is performed. The polymer 114 on the bottom of the cavity walls 108 and 112 prevents the cavity from being etched deeper into the silicon. The exposed second cavity etch walls 112 are etched laterally away from the opening 106 to form third etch cavity walls 116.
  • In FIG. 1J, (step 210 of FIG. 2) the polymer is removed from the cavity by ashing. As shown in FIG. 1J, the width of the cavity is substantially wider than the depth of the cavity. As an example, the width may be approximately twice the depth or more. This cavity is formed without the addition of an etch stop layer in the substrate which may add significant complexity and cost to the manufacturing flow. Cavities formed when an etch stop layer is used typically have a uniform depth across the width of the cavity. The depth of the cavity formed using the embodiment process is not uniform in depth across the width of the cavity as is illustrated in FIG. 1F and FIG. 1J.
  • While various embodiments of the present invention have been described above, it should be understood that they have been presented by way of example only and not limitation. Numerous changes to the disclosed embodiments can be made in accordance with the disclosure herein without departing from the spirit or scope of the invention. Thus, the breadth and scope of the present invention should not be limited by any of the above described embodiments. Rather, the scope of the invention should be defined in accordance with the following claims and their equivalents.

Claims (18)

What is claimed is:
1. A semiconductor device comprising a cavity in a substrate wherein the cavity is wider than it is deep and wherein a depth of the cavity is non-uniform across a width of the cavity.
2. The semiconductor device of claim 1, wherein the substrate is single crystal silicon.
3. The semiconductor device of claim 1, wherein the substrate is single crystal silicon germanium.
4. The semiconductor device of claim 1, wherein the cavity underlies an opening in an overlying masking layer.
5. The semiconductor device of claim 4, wherein the masking layer comprises a layer of silicon nitride overlying a layer of silicon dioxide.
6. The semiconductor device of claim 1, wherein the cavity is under an inductor.
7. The semiconductor device of claim 1, wherein the cavity is under a bolometer.
8. The semiconductor device of claim 1, wherein the cavity is under an electronic device that is sensitive to capacitive coupling to the substrate.
9. A semiconductor device comprising:
a silicon substrate without an etch stop layer within the silicon substrate;
a cavity in the silicon substrate wherein the cavity is at least twice as wide as it is deep.
10. The semiconductor device of claim 9, wherein the silicon substrate is single crystal silicon.
11. The semiconductor device of claim 9, wherein the silicon substrate is single crystal silicon germanium.
12. The semiconductor device of claim 9, wherein the cavity is under an inductor.
13. The semiconductor device of claim 9, wherein the cavity is under a bolometer.
14. The semiconductor device of claim 9, wherein the cavity is under an electronic device that is sensitive to capacitive coupling to the substrate.
15. A semiconductor device comprising:
a substrate of single crystal silicon;
a cavity in the substrate wherein the cavity is at least twice as wide as it is deep, wherein single crystal silicon forms a bottom surface and side surfaces of the cavity and wherein a depth of the cavity is non-uniform across a width of the cavity.
16. The semiconductor device of claim 15, wherein the cavity is under an inductor.
17. The semiconductor device of claim 15, wherein the cavity is under a bolometer.
18. The semiconductor device of claim 15, wherein the cavity is under an electronic device that is sensitive to capacitive coupling to the substrate.
US15/429,403 2015-12-18 2017-02-10 Enhanced lateral cavity etch Pending US20170178916A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US15/429,403 US20170178916A1 (en) 2015-12-18 2017-02-10 Enhanced lateral cavity etch

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14/973,904 US9607847B1 (en) 2015-12-18 2015-12-18 Enhanced lateral cavity etch
US15/429,403 US20170178916A1 (en) 2015-12-18 2017-02-10 Enhanced lateral cavity etch

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US14/973,904 Division US9607847B1 (en) 2015-12-18 2015-12-18 Enhanced lateral cavity etch

Publications (1)

Publication Number Publication Date
US20170178916A1 true US20170178916A1 (en) 2017-06-22

Family

ID=58360124

Family Applications (2)

Application Number Title Priority Date Filing Date
US14/973,904 Active US9607847B1 (en) 2015-12-18 2015-12-18 Enhanced lateral cavity etch
US15/429,403 Pending US20170178916A1 (en) 2015-12-18 2017-02-10 Enhanced lateral cavity etch

Family Applications Before (1)

Application Number Title Priority Date Filing Date
US14/973,904 Active US9607847B1 (en) 2015-12-18 2015-12-18 Enhanced lateral cavity etch

Country Status (1)

Country Link
US (2) US9607847B1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11955504B2 (en) 2019-03-11 2024-04-09 Teledyne Flir Commercial Systems, Inc. Microbolometer systems and methods

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5971825A (en) * 1996-04-03 1999-10-26 Yamaha Corporation Fabrication of field emission element with sharp emitter tip
US6034409A (en) * 1997-08-28 2000-03-07 Mitsubishi Denki Kabushiki Kaisha Isolation trench having plural profile angles
US6383938B2 (en) * 1999-04-21 2002-05-07 Alcatel Method of anisotropic etching of substrates
US20020057176A1 (en) * 2000-11-09 2002-05-16 Hans Norstrom Integrated circuit inductor structure and non-destructive etch depth measurement
US20030067014A1 (en) * 2001-10-04 2003-04-10 Kazuhiro Tsuruta Semiconductor substrate for a one-chip electronic device and related manufacturing method
US20080290445A1 (en) * 2007-04-17 2008-11-27 Austriamicrosystems Ag Schloss Premstatten Method for manufacturing a semiconductor body with a trench and semiconductor body with a trench
US20090274418A1 (en) * 2008-05-01 2009-11-05 Massachusetts Institute Of Technology Reduction of substrate optical leakage in integrated photonic circuits through localized substrate removal
US20100087044A1 (en) * 2008-10-03 2010-04-08 Semiconductor Energy Laboratory Co., Ltd. Method for manufacturing soi substrate
US20110049651A1 (en) * 2009-08-25 2011-03-03 Electronics And Telecommunications Research Institute Three-dimensional mems structure and method of manufacturing the same
US20110214719A1 (en) * 2010-03-04 2011-09-08 Bo Li Method of fabricating a back-contact solar cell and device thereof
US20130180944A1 (en) * 2012-01-13 2013-07-18 Canon Kabushiki Kaisha Process for producing a liquid ejection head
US9076868B1 (en) * 2014-07-18 2015-07-07 Globalfoundries Inc. Shallow trench isolation structure with sigma cavity
US20160146672A1 (en) * 2014-11-25 2016-05-26 International Business Machines Corporation MICROBOLOMETER DEVICES IN CMOS AND BiCMOS TECHNOLOGIES

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5971825A (en) * 1996-04-03 1999-10-26 Yamaha Corporation Fabrication of field emission element with sharp emitter tip
US6034409A (en) * 1997-08-28 2000-03-07 Mitsubishi Denki Kabushiki Kaisha Isolation trench having plural profile angles
US6383938B2 (en) * 1999-04-21 2002-05-07 Alcatel Method of anisotropic etching of substrates
US20020057176A1 (en) * 2000-11-09 2002-05-16 Hans Norstrom Integrated circuit inductor structure and non-destructive etch depth measurement
US20030067014A1 (en) * 2001-10-04 2003-04-10 Kazuhiro Tsuruta Semiconductor substrate for a one-chip electronic device and related manufacturing method
US20080290445A1 (en) * 2007-04-17 2008-11-27 Austriamicrosystems Ag Schloss Premstatten Method for manufacturing a semiconductor body with a trench and semiconductor body with a trench
US20090274418A1 (en) * 2008-05-01 2009-11-05 Massachusetts Institute Of Technology Reduction of substrate optical leakage in integrated photonic circuits through localized substrate removal
US20100087044A1 (en) * 2008-10-03 2010-04-08 Semiconductor Energy Laboratory Co., Ltd. Method for manufacturing soi substrate
US20110049651A1 (en) * 2009-08-25 2011-03-03 Electronics And Telecommunications Research Institute Three-dimensional mems structure and method of manufacturing the same
US20110214719A1 (en) * 2010-03-04 2011-09-08 Bo Li Method of fabricating a back-contact solar cell and device thereof
US20130180944A1 (en) * 2012-01-13 2013-07-18 Canon Kabushiki Kaisha Process for producing a liquid ejection head
US9076868B1 (en) * 2014-07-18 2015-07-07 Globalfoundries Inc. Shallow trench isolation structure with sigma cavity
US20160146672A1 (en) * 2014-11-25 2016-05-26 International Business Machines Corporation MICROBOLOMETER DEVICES IN CMOS AND BiCMOS TECHNOLOGIES

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11955504B2 (en) 2019-03-11 2024-04-09 Teledyne Flir Commercial Systems, Inc. Microbolometer systems and methods

Also Published As

Publication number Publication date
US9607847B1 (en) 2017-03-28

Similar Documents

Publication Publication Date Title
US6372655B2 (en) Two etchant etch method
KR100518606B1 (en) Method for fabricating a recess channel array transistor using a mask layer having high etch selectivity for silicon substrate
US7696045B2 (en) Method of manufacturing semiconductor device
CN105589131B (en) A kind of silicon chip groove etching method for optical waveguide
US8901004B2 (en) Plasma etch method to reduce micro-loading
US20150087150A1 (en) Semiconductor structures and fabrication method thereof
JP2008547238A (en) Method for forming a semiconductor structure
US20040077178A1 (en) Method for laterally etching a semiconductor structure
CN104658962A (en) Through hole forming method
KR20200102952A (en) Plasma etch processes
CN103050434A (en) Through silicon via etching method
US20170178916A1 (en) Enhanced lateral cavity etch
CN108573867B (en) Silicon deep hole etching method
US11011601B2 (en) Narrow gap device with parallel releasing structure
JPH07235590A (en) Manufacture of semiconductor device
TW201604993A (en) Etching method of high aspect-ratio structure and manufacturing method of MEMS devices
US11232954B2 (en) Sidewall protection layer formation for substrate processing
US7005385B2 (en) Method for removing a resist mask with high selectivity to a carbon hard mask used for semiconductor structuring
CN105439081A (en) Method for forming MEMS (Micro-Electro-Mechanical-Systems) device
US10312163B2 (en) Method of improving surface smoothness of dummy gate
CN113363149B (en) Method for forming semiconductor device
CN101752292A (en) Method for making shallow groove insolation structure
TWI630655B (en) Dry etching method
KR100838399B1 (en) Method for forming trench in semiconductor device
KR100481557B1 (en) Method for making narrow sti by using double nitride etch

Legal Events

Date Code Title Description
STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER

STPP Information on status: patent application and granting procedure in general

Free format text: FINAL REJECTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: ADVISORY ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: FINAL REJECTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER

STPP Information on status: patent application and granting procedure in general

Free format text: FINAL REJECTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: RESPONSE TO NON-FINAL OFFICE ACTION ENTERED AND FORWARDED TO EXAMINER

STPP Information on status: patent application and granting procedure in general

Free format text: FINAL REJECTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: RESPONSE AFTER FINAL ACTION FORWARDED TO EXAMINER

STPP Information on status: patent application and granting procedure in general

Free format text: ADVISORY ACTION MAILED

STPP Information on status: patent application and granting procedure in general

Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION

STPP Information on status: patent application and granting procedure in general

Free format text: NON FINAL ACTION MAILED