US20170148923A1 - Perfectly shaped controlled nanowires - Google Patents
Perfectly shaped controlled nanowires Download PDFInfo
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- US20170148923A1 US20170148923A1 US15/209,509 US201615209509A US2017148923A1 US 20170148923 A1 US20170148923 A1 US 20170148923A1 US 201615209509 A US201615209509 A US 201615209509A US 2017148923 A1 US2017148923 A1 US 2017148923A1
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- nanowire
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Definitions
- the present application relates to a semiconductor structure and a method of forming the same. More particularly, the present application relates to a gate-all-around semiconductor structure including a stack of suspended semiconductor nanowires that have a uniform shape and dimension and a method of forming the same.
- MOSFETs metal oxide semiconductor field effect transistors
- CMOS complementary metal oxide semiconductor
- CMOS complementary metal oxide semiconductor
- gate-all-around semiconductor nanowire field effect transistors include at least one semiconductor nanowire including a source region, a drain region and a channel region located between the source region and the drain region, and a gate electrode that wraps around the channel region of the at least one semiconductor nanowire.
- a gate dielectric is typically disposed between the channel region of the at least one semiconductor nanowire and the gate electrode. The gate electrode regulates electron flow through the semiconductor nanowire channel between the source region and the drain region.
- Gate-all-around semiconductor nanowire field effect transistors can achieve higher drive currents with increasingly smaller dimensions as compared to conventional planar FETs.
- a fin stack structure is provided on an insulator layer.
- the fin stack structure comprises, from bottom to top, a first semiconductor fin portion, a dielectric fin portion, a second semiconductor fin portion and a hard mask fin portion.
- a sacrificial gate structure is formed on a portion of the fin stack structure.
- the hard mask fin portion and the dielectric fin portion not located beneath the sacrificial gate structure are removed.
- An epitaxial semiconductor material structure is then formed from exposed surfaces of each semiconductor fin portion.
- the sacrificial gate structure is then removed.
- remaining portions of the hard mask fin portion and the dielectric fin portion are removed.
- the insulating layer is then recessed. After recessing the insulator layer, the first and second semiconductor fin portions are suspended and are stacked one atop the other.
- a method of forming a semiconductor structure includes providing at least one fin stack structure on an insulator layer.
- the at least one fin stack structure comprises from bottom to top, a first semiconductor fin portion, a dielectric fin portion, a second semiconductor fin portion and a hard mask fin portion.
- at least one sacrificial gate structure is formed on a portion of the at least one fin stack structure.
- the hard mask fin portion and the dielectric fin portion that are not located beneath the at least one sacrificial gate structure are removed.
- an epitaxial semiconductor material structure is formed from exposed surfaces of the first semiconductor fin portion and the second semiconductor fin portion not covered by the at least one sacrificial gate structure.
- the at least one sacrificial gate structure is then removed.
- remaining portions of the hard mask fin portion and remaining portions of the dielectric fin portion of the at least one fin stack structure that were previously located beneath the at least one sacrificial gate structure are removed.
- the insulating layer is then recessed. After recessing the insulator layer, the first semiconductor fin portion and the second semiconductor fin portion are suspended and are stacked one atop the other.
- a semiconductor structure in another aspect of the present application, includes a stack of suspended semiconductor nanowires located above a surface of an insulator layer portion, wherein each semiconductor nanowire of the stack has a same shape and dimension.
- a functional gate structure wraps around each suspended semiconductor nanowire of the stack.
- FIG. 1 is a cross sectional view of an exemplary semiconductor structure of a first substrate including, from bottom to top, a first handle substrate, a first insulator layer and a first semiconductor material layer that can be employed in accordance with an embodiment of the present application.
- FIG. 2 is a cross sectional view of the exemplary semiconductor structure of FIG. 1 after forming a first dielectric layer on an exposed surface of the first semiconductor material layer.
- FIG. 3 is a cross sectional view showing a second substrate atop the exemplary semiconductor structure shown in FIG. 2 and including a second handle substrate, a second insulator layer, and a second semiconductor material layer, wherein a second dielectric layer is located on the second semiconductor material layer.
- FIG. 4 is a cross sectional view of the exemplary semiconductor structure of FIG. 3 after bonding the first dielectric layer to the second dielectric layer.
- FIG. 5 is a cross sectional view of the exemplary semiconductor structure of FIG. 4 after removing the second handle substrate and the second insulator layer.
- FIG. 6 is a cross sectional view of the exemplary semiconductor structure of FIG. 5 after forming a third dielectric layer on an exposed surface of the second semiconductor material layer.
- FIG. 7 is a cross sectional view showing an optional third substrate atop the exemplary semiconductor structure of FIG. 6 and including a third handle substrate, a third insulator layer, and a third semiconductor material layer, wherein a fourth dielectric layer is located on the third semiconductor material layer.
- FIG. 8 is a cross sectional view of the exemplary semiconductor structure of FIG. 7 after bonding the third dielectric layer to the fourth dielectric layer.
- FIG. 9 is a cross sectional view of the exemplary semiconductor structure of FIG. 8 after removing the third handle substrate and the third insulator layer.
- FIG. 10 is a cross sectional view of the exemplary semiconductor structure of FIG. 9 after forming a hard mask material layer on an exposed surface of the third semiconductor material layer.
- FIG. 11 is a cross sectional view of the exemplary semiconductor structure of FIG. 10 after patterning the hard mask material layer, the third semiconductor material layer, the fourth dielectric layer, the third dielectric layer, the second semiconductor material layer, the second dielectric layer, the first dielectric layer and the first semiconductor material layer to provide a plurality of fin stack structures extending upwards from different portions of the first insulator layer, wherein each fin stack structure includes, from bottom to top, a first semiconductor material fin portion, a combined first and second dielectric fin portion, a second semiconductor fin portion, a combined third and fourth dielectric fin portion, a third semiconductor fin portion and a hard mask fin portion.
- FIG. 12 is a top down view of the exemplary semiconductor structure of FIG. 11 after forming at least one sacrificial gate structure straddling over a portion of each fin stack structure.
- FIG. 13A is a top down view of the exemplary semiconductor structure of FIG. 12 after removing the hard mask fin portion, the combined third and fourth dielectric fin portion, and the combined first and second dielectric fin portion that are not protected by the sacrificial gate structure.
- FIG. 13B is a cross sectional view of the exemplary semiconductor structure of FIG. 13A along vertical plane B-B′.
- FIG. 14 is a top down view of the exemplary semiconductor structure of FIGS. 13A-13B after forming an epitaxial semiconductor material structure from exposed semiconductor material surfaces of each fin stack structure that are located on either side of each sacrificial gate structure.
- FIG. 15 is a top down view of the exemplary semiconductor structure of FIG. 14 after removing the at least one sacrificial gate structure.
- FIG. 16A is a cross sectional view of the exemplary semiconductor structure of FIG. 15 through vertical plane B-B′ after suspending the third semiconductor material fin portion and the second semiconductor fin portion that were located previously beneath the sacrificial gate structure.
- FIG. 16B is a cross sectional view of the exemplary semiconductor structure of FIG. 15 through vertical plane C-C′ after suspending the third semiconductor material fin portion and the second semiconductor fin portion of each fin stack structure that were located previously beneath the sacrificial gate structure.
- FIG. 17A is top down view of the exemplary semiconductor structure of FIGS. 16A-16B after recessing the first insulator layer to suspend the first semiconductor fin portion of each fin stack structure and forming a functional gate structure wrapping around each suspended first semiconductor fin portion, each second semiconductor fin portion and each third semiconductor fin portion.
- FIG. 17B is a cross sectional view of the exemplary semiconductor structure of FIG. 17A along vertical plane B-B′.
- FIG. 1 there is illustrated an exemplary semiconductor structure of a first substrate ( 10 L, 12 L, 14 L) including, from bottom to top, a first handle substrate 10 L, a first insulator layer 12 L and a first semiconductor material layer 14 L that can be employed in accordance with an embodiment of the present application.
- a first handle substrate 10 L, the first insulator layer 12 L and the first semiconductor material layer 14 L and thus the first substrate may be referred to herein as a first semiconductor-on-insulator (SOI) substrate.
- SOI semiconductor-on-insulator
- the first handle substrate 10 L may include at least one semiconductor material that has semiconductor properties.
- materials that have semiconducting properties and thus can be employed as the semiconductor material that provides the first handle substrate 10 L include silicon (Si), germanium (Ge), silicon germanium alloys (SiGe), silicon carbide (SiC), silicon germanium carbide (SiGeC), III-V compound semiconductors and/or II-VI compound semiconductors.
- III-V compound semiconductors are materials that include at least one element from Group III of the Periodic Table of Elements and at least one element from Group V of the Periodic Table of Elements.
- II-VI compound semiconductors are materials that include at least one element from Group II of the Periodic Table of Elements and at least one element from Group VI of the Periodic Table of Elements.
- the first handle substrate 10 L is composed entirely of silicon.
- the first handle substrate 10 L may be composed of a non-semiconductor material including, for example, a dielectric material and/or a conductive material.
- the at least one semiconductor material that provides the first handle substrate 10 L may be single crystalline, polycrystalline or amorphous.
- the first handle substrate 10 L is composed of single crystalline silicon.
- the at least one semiconductor material that provides the first handle substrate 10 L may have any of the well known crystal orientations.
- the crystal orientation of the first handle substrate 10 L may be ⁇ 100 ⁇ , ⁇ 110 ⁇ , or ⁇ 111 ⁇ .
- Other crystallographic orientations besides those specifically mentioned can also be used in the present application.
- the first insulator layer 12 L of the exemplary semiconductor structure shown in FIG. 1 may be a crystalline or non-crystalline dielectric material such as an oxide and/or nitride.
- the first insulator layer 12 L is a dielectric oxide such as, for example, silicon dioxide.
- the first insulator layer 12 L may be a dielectric nitride such as, for example, silicon nitride or boron nitride.
- the first insulator layer 12 L may include a stack of a dielectric oxide and a dielectric nitride.
- first insulator layer 12 L a stack of, in any order, silicon dioxide and silicon nitride or boron nitride may be employed as the first insulator layer 12 L.
- the first insulator layer 12 L may have a thickness from 10 nm to 200 nm, although other thicknesses that are lesser than, or greater than, the aforementioned thickness range may also be employed as the thickness of the first insulator layer 12 L.
- the first semiconductor material layer 14 L includes one of the semiconductor materials mentioned above for the first handle substrate 10 L.
- the semiconductor material that provides the first semiconductor material layer 14 L may be a relaxed semiconductor material or a strained semiconductor material.
- the semiconductor material that provides the first semiconductor material layer 14 L includes a same semiconductor material as the first handle substrate 10 L.
- silicon is employed as the semiconductor material for both the first handle substrate 10 L and the first semiconductor material layer 14 L.
- the first semiconductor material layer 14 L includes a semiconductor material that differs from a semiconductor material that provides the first handle substrate 10 L.
- the first handle substrate 10 L may be composed of silicon, while the first semiconductor material layer 14 L may be composed of a silicon germanium alloy.
- the first semiconductor material layer 14 L may have one of the crystal orientations mentioned above for the semiconductor material that provides the first handle substrate 10 L. In one embodiment, the crystal orientation of the first semiconductor material 14 L is the same as the crystal orientation of the first handle substrate 10 L. In another embodiment, the crystal orientation of the first semiconductor material layer 14 L differs from the crystal orientation of the first handle substrate 10 L. Typically, the first semiconductor material layer 14 L is a single crystalline semiconductor material. The first semiconductor material layer 14 L may have a thickness from 10 nm to 100 nm, although other thicknesses that are lesser than, or greater than, the aforementioned thickness range may also be employed as the thickness of the first semiconductor material layer 14 L.
- the first substrate ( 10 L, 12 L, 14 L) may be formed by wafer bonding.
- the first substrate ( 10 L, 12 L, 14 L) may be formed by an implantation process known as SIMOX (i.e., Separation by IMplanting OXygen).
- SIMOX i.e., Separation by IMplanting OXygen
- a thermal mixing process or a thermal condensation process may be employed in forming the first semiconductor material layer 14 L.
- Thermal mixing includes annealing in an inert ambient (i.e., helium and/or argon), while thermal condensation includes annealing in an oxidizing ambient (air, oxygen, ozone and/or NO 2 ).
- the anneal temperature for both thermal mixing and thermal condensation can be from 600° C.
- a sacrificial silicon germanium alloy layer having a first germanium content can formed on a silicon layer that is located atop the first insulator layer.
- One of thermal mixing or thermal condensation can then be performed to convert the Si/SiGe material stack into a silicon germanium alloy layer having a second germanium content that differs from the first germanium content.
- the silicon germanium alloy having the second germanium content can be used as the first semiconductor material layer 14 L of the first substrate exemplified in FIG. 1 .
- the first dielectric layer 16 L is employed in the present application as a dielectric material bonding layer in a subsequent dielectric-to-dielectric bonding process.
- the first dielectric layer 16 L may include one of the materials mentioned above for the first insulator layer 12 L.
- the first dielectric material layer 16 L is composed of a same material as the first insulator layer 12 L.
- both the first dielectric layer 16 L and the first insulator layer 12 L are composed of silicon dioxide.
- the first dielectric layer 16 L can have a thickness from 1 nm to 10 nm, although other thicknesses that are lesser than, or greater than, the aforementioned thickness range may also be employed as the thickness of the first dielectric layer 16 L.
- the first dielectric layer 16 L can be formed utilizing a deposition process such as, for example, chemical vapor deposition (CVD) or plasma enhanced chemical vapor deposition (PECVD). In another embodiment of the present application, the first dielectric layer 16 L can be formed utilizing a thermal oxidation or thermal nitridation process.
- CVD chemical vapor deposition
- PECVD plasma enhanced chemical vapor deposition
- the second substrate ( 20 L, 22 L, 24 L) atop the exemplary semiconductor structure shown in FIG. 2 .
- the second substrate ( 20 L, 22 L, 24 L) includes a second handle substrate 20 L, a second insulator layer 22 L, and a second semiconductor material layer 24 L.
- a second dielectric layer 26 L is located on the second semiconductor material layer 24 L.
- the second handle substrate 20 L may include any of the materials mentioned above for the first handle substrate 10 L.
- the first handle substrate 10 L and the second handle substrate 20 L include a same material.
- the first handle substrate 10 L and the second handle substrate 20 L include silicon.
- the second insulator layer 22 L may include any of the materials mentioned above for the first insulator layer 12 L.
- the first insulator layer 12 L and the second insulator layer 22 L may include a same insulator material such as, for example, silicon dioxide.
- the second semiconductor material layer 24 L may include one of the semiconductor materials mentioned above for the first semiconductor material layer 14 L.
- the second semiconductor material layer 24 L and the first semiconductor material layer 14 L comprise a same semiconductor material, such as, for example, silicon or a silicon germanium alloy.
- the second semiconductor material layer 24 L comprises a different semiconductor material than the first semiconductor material layer 14 L.
- the first semiconductor material layer 14 L may be composed of silicon, while the second semiconductor material layer 24 L may be composed of a silicon germanium alloy or a III-V compound semiconductor.
- the second semiconductor material layer 24 L that is provided has a same thickness as that of the first second material layer 14 L mentioned above.
- the second substrate ( 20 L, 22 L, 24 L) may be referred to as a second SOI substrate.
- the second substrate ( 20 L, 22 L, 24 L) can be formed utilizing one of the techniques mentioned above in forming the first substrate ( 10 L, 12 L, 14 L).
- the second dielectric layer 26 L may include one of the materials mentioned above for the first dielectric layer 16 L.
- the first and second dielectric layers 16 L, 26 L are both composed of a same material such as, for example, silicon dioxide.
- the second dielectric layer 26 L is composed of a different material than the first dielectric layer 16 L.
- the second dielectric layer 26 L may have a thickness within the range mentioned above for the first dielectric layer 16 L.
- the thickness of the second dielectric layer 26 L may be the same as, lesser than, or greater than, the thickness of the first dielectric layer 16 L.
- the second dielectric layer 26 L may be formed utilizing one of the techniques mentioned above in forming the first dielectric layer 16 L.
- Bonding includes contacting an exposed surface of the first dielectric layer 16 L that is attached to the first substrate ( 10 L, 12 L, 14 L) to the second dielectric layer 26 L that is attached to the second substrate ( 20 L, 22 L, 24 L).
- a dielectric-to-dielectric bonding interface is formed. Bonding can be performed utilizing any bonding temperature including, for example, from room temperature (20° C.) up to 1200° C. Bonding can be performed in an inert ambient and an external force may or may not be applied during a part of, or the entirety of, the bonding process.
- FIG. 5 there is illustrated the exemplary semiconductor structure of FIG. 4 after removing the second handle substrate 20 L and the second insulator layer 22 L.
- the removal of the second handle substrate 20 L and the second insulator layer 22 L exposes a surface of the second semiconductor material layer 24 L which is now attached to the first substrate ( 10 L, 12 L, 14 L) through the bonded first and second dielectric layers 16 L, 26 L.
- the removal of the second handle substrate 20 L and the second insulator layer 22 L may be performed utilizing a single removal process such as, for example, a planarization process or an etching process.
- the removal of the second handle substrate 20 L and the second insulator layer 22 L are performed by utilizing a planarization such as, for example, chemical mechanical planarization or grinding.
- the removal of the second handle substrate 20 L and the second insulator layer 22 L may occur in two separate steps. For example, the second handle substrate 20 L may be removed first (via a planarization process or etching), followed by the removal of the second insulator layer 22 L (via a planarization process or etching).
- FIG. 6 there is illustrated the exemplary semiconductor structure of FIG. 5 after forming a third dielectric layer 28 L on an exposed surface of the second semiconductor material layer 24 L that is now attached to the first substrate ( 10 L, 12 L, 14 L) through bonded dielectric layers 16 L, 26 L.
- the third dielectric layer 28 L may include one of the materials mentioned above for the first dielectric layer 16 L.
- the third dielectric layer 28 L may comprise a same material as the first and second dielectric layers 16 L, 26 L.
- the first, second and third dielectric layers ( 16 L, 26 L, 28 L) may all be composed of silicon dioxide.
- the third dielectric layer 28 L may comprise a same material as the first dielectric layer 16 L, but a different material than the second dielectric layer 26 L.
- the third dielectric layer 28 L may comprise a same material as the second dielectric layer 26 L, but a different material than the first dielectric layer 16 L.
- the third dielectric layer 28 L may have a thickness within the range mentioned above for the first dielectric layer 16 L.
- the thickness of the third dielectric layer 28 L may be the same as, lesser than, or greater than, the thickness of the first and/or second dielectric layers ( 16 L, 26 L).
- the third dielectric layer 28 L may be formed utilizing one of the techniques mentioned above in forming the first dielectric layer 16 L.
- third dielectric layer 28 L is used to provide bonding to a third substrate. In yet other embodiments, the third dielectric layer 28 L may be used as topmost hard mask layer during a subsequent patterning process.
- the third substrate includes a third handle substrate 30 L, a third insulator layer 32 L, and a third semiconductor material layer 34 L.
- a fourth dielectric layer 36 L is located on the third semiconductor material layer 34 L.
- the third handle substrate 30 L may include any of the materials mentioned above for the first handle substrate 10 L.
- the first handle substrate 10 L and the third handle substrate 30 L include a same material.
- the first handle substrate 10 L and the third handle substrate 30 L include silicon.
- the third insulator layer 32 L may include any of the materials mentioned above for the first insulator layer 12 L.
- the first insulator layer 12 L and the third insulator layer 32 L may include a same insulator material such as, for example, silicon dioxide.
- the third semiconductor material layer 34 L may include one of the semiconductor materials mentioned above for the first semiconductor material layer 14 L.
- the third semiconductor material layer 34 L, the second semiconductor material layer 24 L and the first semiconductor material layer 14 L comprise a same semiconductor material, such as, for example, silicon or a silicon germanium alloy.
- the third semiconductor material layer 34 L comprises a different semiconductor material than one of the first semiconductor material layer 14 L and the second semiconductor material layer 24 L.
- the third semiconductor material layer 34 L comprises a different semiconductor material than the first and second semiconductor material layers ( 14 L, 24 L), and the first semiconductor material layer 14 L comprises a different semiconductor material than the second semiconductor material 24 L.
- the first semiconductor material layer 14 L, and the second semiconductor material layer 24 L and the third semiconductor material layer 34 L may comprise different semiconductor materials altogether.
- the third semiconductor material layer 34 L that is provided has a same thickness as that of the first and second semiconductor material layers 14 L, 24 L mentioned above.
- the third substrate ( 30 L, 32 L, 34 L) may be referred to as a third SOI substrate.
- the third substrate ( 30 L, 32 L, 34 L) can be formed utilizing one of the techniques mentioned above in forming the first substrate ( 10 L, 12 L, 14 L).
- the fourth dielectric layer 36 L may include one of the materials mentioned above for the first dielectric layer 16 L.
- the first, second, third and fourth dielectric layers 16 L, 26 L, 28 L, 36 L are all composed of a same material such as, for example, silicon dioxide.
- the fourth dielectric layer 36 L may have a thickness within the range mentioned above for the first dielectric layer 16 L.
- the thickness of the fourth dielectric layer 36 L may be the same as, lesser than, or greater than, the thickness of the first dielectric layer 16 L, the second dielectric layer 26 L and the third dielectric layer 28 L.
- the fourth dielectric layer 36 L may be formed utilizing one of the techniques mentioned above in forming the first dielectric layer 16 L.
- FIG. 8 there is illustrated the exemplary semiconductor structure of FIG. 7 after bonding the third dielectric layer 28 L to the fourth dielectric layer 36 L.
- the bonding can be performed as described above.
- the bonding forms a dielectric-to-dielectric interface between the third dielectric layer 28 L and the fourth dielectric layer 36 L.
- FIG. 9 there is illustrated the exemplary semiconductor structure of FIG. 8 after removing the third handle substrate 30 L and the third insulator layer 32 L from the bonded structure of FIG. 8 .
- the third handle substrate 30 L and the third insulator layer 32 L can be removed utilizing one of the techniques mentioned above in removing the second handle substrate 20 L and the second insulator layer 22 L from the bonded structure shown in FIG. 4 .
- additional SOI substrates and dielectric layers can be provided and bonded to each other in the manner described above and illustrated in FIGS. 1-5 .
- the number of additional SOI substrates and dielectric layers is not limited and can be selected to provide a desired numbered of semiconductor nanowires within a given stack of semiconductor nanowires.
- the hard mask material layer 38 L may include any hard mask material such as, for example, a dielectric oxide, dielectric nitride and/or a dielectric oxynitride.
- the hard mask material layer 38 L is composed of a dielectric oxide such as, for example, silicon dioxide.
- the hard mask material layer 38 L may be formed utilizing one of the techniques mentioned above in forming the first dielectric layer 16 L.
- the hard mask material layer 38 L may have a thickness from 5 nm to 25 nm, although other thicknesses that are lesser than, or greater than, the aforementioned thickness range may also be used in the present application. In some embodiments, the thickness of the hard mask material layer 38 L may be the same as the combined thickness of the first and second dielectric layers ( 16 L, 26 L) and/or the combined thickness of the third and fourth dielectric layers ( 28 L, 36 L).
- FIG. 11 there is illustrated the exemplary semiconductor structure of FIG. 10 after patterning the hard mask material layer 38 L, the third semiconductor material layer 34 L, the fourth dielectric layer 36 L, the third dielectric layer 28 L, the second semiconductor material layer 24 L, the second dielectric layer 26 L, the first dielectric layer 16 L and the first semiconductor material layer 14 L to provide a plurality of fin stack structures 50 extending upwards from different portions of the first insulator layer 12 L.
- the present application describes and illustrates a plurality of fin stack structures being formed, the present application can also be used to provide a single fin stack structure.
- Each fin stack structure 50 includes, from bottom to top, a first semiconductor material fin portion 14 P, a combined first and second dielectric fin portion 52 P, a second semiconductor fin portion 24 P, a combined third and fourth dielectric fin portion 54 P, a third semiconductor fin portion 34 P and a hard mask fin portion 38 P.
- the combined first and second dielectric fin portion 52 P may be referred to as a first dielectric fin portion
- the combined the combined third and fourth dielectric fin portion may be referred to a second dielectric fin portion.
- Each combined first and second dielectric fin portion 52 P comprises a remaining portion of the first dielectric layer 16 L and a remaining portion of the second dielectric layer 26 L (in the drawings a single layered structure is shown for clarity and can be used to illustrated an embodiment in which the first and second dielectric layers ( 16 L, 26 L) are composed of the same material).
- Each combined third and fourth dielectric fin portion 54 P comprises a remaining portion of the third dielectric layer 28 L and a remaining portion of the fourth dielectric layer 36 L (in the drawings a single layered structure is shown for clarity and assumes one embodiment in which the third and fourth dielectric layers 28 L, 36 L are composed of the same material).
- the patterning used to provide the plurality of fin stack structures 50 may include lithography and etching.
- Lithography includes forming a photoresist material (not shown) atop a material or material stack to be patterned.
- the photoresist material may include a positive-tone photoresist composition, a negative-tone photoresist composition or a hybrid-tone photoresist composition.
- the photoresist material may be formed by a deposition process such as, for example, spin-on coating. After forming the photoresist material, the deposited photoresist material is subjected to a pattern of irradiation. Next, the exposed photoresist material is developed utilizing a conventional resist developer.
- the etch stops on the topmost surface of the first insulator layer 12 L.
- the patterning used to provide the fin stack structures 50 may include a sidewall image transfer (SIT) process.
- the SIT process includes forming a mandrel material layer (not shown) atop the material or material layers that are to be patterned.
- the mandrel material layer (not shown) can include any material (semiconductor, dielectric or conductive) that can be selectively removed from the structure during a subsequently performed etching process.
- the mandrel material layer (not shown) may be composed of amorphous silicon or polysilicon.
- the mandrel material layer (not shown) may be composed of a metal such as, for example, Al, W, or Cu.
- the mandrel material layer (not shown) can be formed, for example, by chemical vapor deposition or plasma enhanced chemical vapor deposition. Following deposition of the mandrel material layer (not shown), the mandrel material layer (not shown) can be patterned by lithography and etching to form a plurality of mandrel structures (also not shown) on the topmost surface of the structure.
- the SIT process continues by forming a spacer on each sidewall of each mandrel structure.
- the spacer can be formed by deposition of a spacer material and then etching the deposited spacer material.
- the spacer material may comprise any material having an etch selectivity that differs from the mandrel material.
- deposition processes that can be used in providing the spacer material include, for example, chemical vapor deposition (CVD), plasma enhanced chemical vapor deposition (PECVD), or atomic layer deposition (ALD).
- Examples of etching that be used in providing the spacers include any etching process such as, for example, reactive ion etching.
- the SIT process continues by removing each mandrel structure.
- Each mandrel structure can be removed by an etching process that is selective for removing the mandrel material.
- the SIT process continues by transferring the pattern provided by the spacers into the underlying material or material layers.
- the pattern transfer may be achieved by utilizing at least one etching process. Examples of etching processes that can used to transfer the pattern may include dry etching (i.e., reactive ion etching, plasma etching, and ion beam etching or laser ablation) and/or a chemical wet etch process.
- the etch process used to transfer the pattern may include one or more reactive ion etching steps. The etch stops on a topmost surface of the first insulator layer 12 L.
- the SIT process concludes by removing the spacers from the structure. Each spacer may be removed by etching or a planarization process.
- a “fin stack structure” refers to a material stack of from bottom to top, a first semiconductor material fin portion 14 P, a combined first and second dielectric fin portion 52 P, a second semiconductor fin portion 24 P, an optional combined third and fourth dielectric fin portion 54 P, an optional third semiconductor fin portion 34 P, and a hard mask fin portion 38 P, and including a pair of vertical sidewalls that are parallel to each other.
- a surface is “vertical” if there exists a vertical plane from which the surface does not deviate by more than three times the root mean square roughness of the surface.
- each fin stack structure has a width from 5 nm to 30 nm.
- Each fin stack structure 50 is spaced apart from its nearest neighboring fin stack structure 50 by a pitch of from 20 nm to 100 nm. Also, each fin stack structure 50 is oriented parallel to each other.
- each semiconductor material fin portion of the fin stack structure is located between an underlying layer of an insulator (i.e., dielectric) layer and an overlying layer of an insulator (i.e., dielectric) layer.
- each fin portion within the fin stack structure 50 has sidewall surfaces that are vertically aligned with each. As such, the width of each fin portion of the fin stack structure is the same.
- FIG. 12 there is illustrated the exemplary semiconductor structure of FIG. 11 after forming at least one sacrificial gate structure 60 straddling over a portion of each fin stack structure 50 .
- sacrificial gate structure it is meant a material or material stack that serves as a placeholder for a subsequently formed functional gate structure.
- straddling over it is meant that one material is formed atop and along sidewall surfaces of another material.
- Each sacrificial gate structure 60 may include a sacrificial gate dielectric portion, a sacrificial gate material portion and a sacrificial gate cap portion. In some embodiments, each sacrificial gate dielectric portion and/or each sacrificial gate cap portion may be omitted. For clarity, each sacrificial gate structure 60 is shown a single piece.
- the sacrificial gate dielectric portion includes a dielectric material such as for example, a dielectric oxide, dielectric nitride and/or a dielectric oxynitride.
- the sacrificial gate dielectric portion may be composed of silicon dioxide and/or silicon nitride.
- the gate dielectric that may provide the sacrificial gate dielectric portion may be formed utilizing a deposition process such as, for example, chemical vapor deposition or plasma enhanced chemical vapor deposition.
- the thickness of the sacrificial gate dielectric can be from 5 nm to 10 nm; although other thickness that are lesser than, or greater than, the aforementioned range may be used.
- the sacrificial gate conductor portion may include polysilicon or a metal or metal alloy.
- the material that provides the sacrificial gate conductor portion can be formed utilizing a deposition process such as, for example, chemical vapor deposition, plasma enhanced chemical vapor deposition, or sputtering.
- the sacrificial gate conductor portion may have a thickness from 25 nm to 150 nm, although other thickness that are lesser than, or greater than, the aforementioned thickness range can also be employed. If present, the sacrificial gate cap portion may include one of the hard mask materials mentioned above in providing the hard mask material layer 38 L.
- the hard mask material that provides the sacrificial gate cap portion can be formed by a deposition process such chemical vapor deposition or plasma enhanced chemical vapor deposition.
- the sacrificial gate cap portion can have a thickness from 5 nm to 20 nm, although other thicknesses that are lesser than, or greater than, the aforementioned thickness range may also be employed.
- Each sacrificial gate structure 60 can be formed by deposition of the various material layers and then patterning the resultant sacrificial dielectric material sack by utilizing, for example, lithography and etching.
- element 50 P denotes a fin stack structure in which portions of the hard mask fin portion 38 P, the combined third and fourth dielectric fin portion 54 P, and the combined first and second dielectric fin portion 52 P that are not protected by the sacrificial gate structure 60 and within the source region and the drain region have been removed therefrom.
- each sacrificial gate structure 60 is used as an anchoring structure during the removal of the hard mask fin portion 38 P, the combined third and fourth dielectric fin portion 54 P, and the combined first and second dielectric fin portion 52 P that are not protected by the sacrificial gate structure 60 . Also, and in accordance with the present application, the removing the hard mask fin portion 38 P, the combined third and fourth dielectric fin portion 54 P, and the combined first and second dielectric fin portion 52 P that are not protected by the sacrificial gate structure 60 releases portions of each first semiconductor material fin portion 14 P, the second semiconductor fin portion 24 P, and the third semiconductor fin portion 34 P in the source region and drain region of the structure.
- portions of each of the hard mask fin portion 38 P, the combined third and fourth dielectric fin portion 54 P, and the combined first and second dielectric fin portion 52 P remain beneath each sacrificial gate structure 60 .
- FIG. 13B one of the sacrificial gate structures 60 is shown and that sacrificial gate structure is located behind the released first semiconductor material fin portion 14 P, the second semiconductor fin portion 24 P, the third semiconductor fin portion 34 P.
- the removing the hard mask fin portion 38 P, the combined third and fourth dielectric fin portion 54 P, and the combined first and second dielectric fin portion 52 P that are not protected by the sacrificial gate structure 60 can be performed utilizing an etching process this is selective in removing the material that provides each of the hard mask fin portion 38 P, the combined third and fourth dielectric fin portion 54 P, and the combined first and second dielectric fin portion 52 P that are not protected by a sacrificial gate structure 60 .
- aqueous hydrofluoric acid or a dry etch like chemical oxide removal can be used in removing the hard mask fin portion 38 P, the combined third and fourth dielectric fin portion 54 P, and the combined first and second dielectric fin portion 52 P that are not protected by the sacrificial gate structures 60 .
- FIG. 14 there is illustrated the exemplary semiconductor structure of FIGS. 13A-13B after forming an epitaxial semiconductor material structure 70 from exposed semiconductor material surfaces (i.e., the released first semiconductor material fin portion 14 P, the second semiconductor fin portion 24 P, and the third semiconductor fin portion 34 P) of each fin stack structure that are located on either side of each sacrificial gate structure 60 .
- exposed semiconductor material surfaces i.e., the released first semiconductor material fin portion 14 P, the second semiconductor fin portion 24 P, and the third semiconductor fin portion 34 P
- the epitaxial semiconductor material structure 70 may be formed utilizing a selective epitaxial growth (or deposition) process.
- selective when used in conjugation with the phrase “selective epitaxial growth” denotes that the epitaxial material is grown only on semiconductor material surfaces not insulator or conductor surfaces.
- each epitaxial semiconductor material structure 70 is formed from exposed surfaces of the released first semiconductor material fin portion 14 P, the second semiconductor fin portion 24 P, and the third semiconductor fin portion 34 P that are not covered by the sacrificial gate structure 60 .
- Each epitaxial semiconductor material structure 70 completely surrounds the released second semiconductor fin portion 24 P and the third semiconductor fin portion 34 P of each fin stack structure.
- Each epitaxial semiconductor material structure 70 is located around the sidewall surfaces and topmost surface of the released first semiconductor fin portion 14 P of each fin stack structure.
- Each epitaxial semiconductor material structure 70 comprises an epitaxial semiconductor material that is doped.
- the epitaxial semiconductor material that provides each epitaxial semiconductor material structure 70 may include one of the semiconductor materials mentioned above for the handle substrate 10 L. In one example, silicon or a silicon germanium alloy may be used as the epitaxial semiconductor material.
- the epitaxial semiconductor material comprises a same semiconductor material as at least one of the first semiconductor material fin portion 14 P, the second semiconductor fin portion 24 P, and the third semiconductor fin portion 34 P. In another embodiment, the epitaxial semiconductor material comprises a different semiconductor material than each of the first semiconductor material fin portion 14 P, the second semiconductor fin portion 24 P, and the third semiconductor fin portion 34 P.
- epitaxial growth and/or deposition and “epitaxially formed and/or grown” mean the growth of a semiconductor material on a deposition surface of a semiconductor material, in which the semiconductor material being grown has the same crystalline characteristics as the semiconductor material of the deposition surface.
- the chemical reactants provided by the source gases are controlled and the system parameters are set so that the depositing atoms arrive at the deposition surface of the semiconductor substrate with sufficient energy to move around on the surface and orient themselves to the crystal arrangement of the atoms of the deposition surface. Therefore, an epitaxial semiconductor material has the same crystalline characteristics as the deposition surface on which it is formed.
- an epitaxial semiconductor material deposited on a ⁇ 100 ⁇ crystal surface will take on a ⁇ 100 ⁇ orientation.
- the epitaxial semiconductor material structure 70 has an epitaxial relationship with exposed surfaces of each of the released first semiconductor material fin portions 14 P, the second semiconductor fin portions 24 P, and the third semiconductor fin portions 34 P.
- Examples of various epitaxial growth process apparatuses that can be employed in the present application include, e.g., rapid thermal chemical vapor deposition (RTCVD), low-energy plasma deposition (LEPD), ultra-high vacuum chemical vapor deposition (UHVCVD), atmospheric pressure chemical vapor deposition (APCVD) and molecular beam epitaxy (MBE).
- RTCVD rapid thermal chemical vapor deposition
- LEPD low-energy plasma deposition
- UHVCVD ultra-high vacuum chemical vapor deposition
- APCVD atmospheric pressure chemical vapor deposition
- MBE molecular beam epitaxy
- the temperature for epitaxial deposition typically ranges from 550° C. to 900° C. Although higher temperature typically results in faster deposition, the faster deposition may result in crystal defects and film cracking.
- each epitaxial semiconductor material structure 70 can be performed utilizing any well known precursor gas or gas mixture including for example, a silicon containing precursor gas (such as silane) and/or a germanium containing precursor gas (such as a germane).
- Carrier gases like hydrogen, nitrogen, helium and argon can be used.
- the dopant that can be present in each epitaxial semiconductor material structure 70 may be n-type dopant or p-type dopant.
- the dopant is typically introduced into the precursor gas during the epitaxial growth process. In other embodiments, the dopant can be introduced after the epitaxial growth process.
- p-type refers to the addition of impurities to an intrinsic semiconductor that creates deficiencies of valence electrons.
- examples of p-type dopants, i.e., impurities include, but are not limited to, boron, aluminum, gallium and indium.
- N-type refers to the addition of impurities that contributes free electrons to an intrinsic semiconductor.
- n-type dopants i.e., impurities
- examples of n-type dopants include, but are not limited to, antimony, arsenic and phosphorous.
- Each epitaxial semiconductor material structure 70 has a dopant concentration that can be within a range from 2 ⁇ 10 20 atoms/cm 3 to 1 ⁇ 10 21 atoms/cm 3 .
- each sacrificial gate structure 60 can be performed utilizing an etching process that is selective in removing the material or material stack that provides the sacrificial gate structure 60 .
- hot ammonia can be used to remove polysilicon.
- FIGS. 16A-16B there are illustrated the exemplary semiconductor structure of FIG. 15 after suspending the third semiconductor material fin portion 34 P and the second semiconductor fin portion 24 P that were located previously beneath the sacrificial gate structure 60 .
- the remaining hard mask fin portions 38 P, the combined third and fourth dielectric fin portion 54 P, and the combined first and second dielectric fin portion 52 P are completely removed from the structure.
- the suspending the third semiconductor material fin portion 34 P and the second semiconductor fin portion 24 P that were located previously beneath the sacrificial gate structure 60 includes the selective etch that was mentioned above in providing the exemplary semiconductor structure shown in FIGS. 13A-13B of the present application.
- FIGS. 17A-17B there are illustrated the exemplary semiconductor structure of FIGS. 16A-16B after recessing the first insulator layer 12 L to suspend the first semiconductor fin portion 14 P of each fin stack structure and forming a functional gate 90 structure wrapping around each suspended first semiconductor fin portion, each suspended second semiconductor fin portion and each suspended third semiconductor fin portion.
- first insulator portion 12 P The remaining portion of the first insulator layer 12 L that is formed can be referred to herein as a first insulator portion 12 P and can have a thickness that is less than the original thickness of the first insulator layer 12 L.
- Each suspended first semiconductor fin portion can be referred to herein as a first suspended semiconductor nanowire 14 S
- each suspended second semiconductor fin portion can be referred to herein as a second suspended semiconductor nanowire 24 S
- each suspended third semiconductor fin portion can be referred to herein as a third suspended semiconductor nanowire 34 S.
- each suspended first semiconductor nanowire 14 S, each suspended second semiconductor nanowire 24 S, and each suspended third semiconductor nanowire 34 S have a same shape and dimension.
- the recessing of the first insulator layer 12 L which provides first insulator portion 12 P can be performed utilizing an etching process that is selective in removing the insulator material that provides the first insulator layer 12 L.
- aqueous hydrofluoric acid can be used to recess the first insulator layer 12 L.
- the functional gate 90 includes a gate dielectric portion 92 and a gate conductor portion 94 .
- the functional gate structure 90 can be formed by first providing a gate dielectric material and a gate conductor material. A gate patterning process may follow the deposition of the gate dielectric material and the gate conductor material.
- functional gate structure it is meant a permanent gate structure used to control output current (i.e., flow of carriers in the channel) of a semiconducting device through electrical or magnetic fields. As is shown, the gate conductor portion 92 is present entirely around each semiconductor nanowire 14 S, 24 S and 34 S.
- the gate dielectric portion 92 may include a gate dielectric material.
- the gate dielectric material that provides the gate dielectric portion 92 can be an oxide, nitride, and/or oxynitride.
- the gate dielectric material that provides the gate dielectric portion 92 can be a high-k material having a dielectric constant greater than silicon dioxide.
- Exemplary high-k dielectrics include, but are not limited to, HfO 2 , ZrO 2 , La 2 O 3 , Al 2 O 3 , TiO 2 , SrTiO 3 , LaAlO 3 , Y 2 O 3 , HfO x N y , ZrO x N y , La 2 O x N y , Al 2 O x N y , TiO x N y , SrTiO x N y , LaAlO x N y , Y 2 O x N y , SiON, SiN x , a silicate thereof, and an alloy thereof.
- a multilayered gate dielectric structure comprising different gate dielectric materials, e.g., silicon dioxide, and a high-k gate dielectric, can be formed and used as the gate dielectric portion 92 .
- a first set of functional gate structures includes a first gate dielectric portion, while a second set of functional gate structures comprises a second gate dielectric portion.
- the first gate dielectric material portion may be the same as, or different from, the second gate dielectric material portion.
- the gate dielectric material used in providing the gate dielectric portion 92 can be formed by any deposition process including, for example, chemical vapor deposition (CVD), plasma enhanced chemical vapor deposition (PECVD), physical vapor deposition (PVD), sputtering, or atomic layer deposition.
- CVD chemical vapor deposition
- PECVD plasma enhanced chemical vapor deposition
- PVD physical vapor deposition
- sputtering or atomic layer deposition.
- block mask technology can be used.
- the gate dielectric material used in providing the gate dielectric portion 92 can have a thickness in a range from 1 nm to 10 nm. Other thicknesses that are lesser than, or greater than, the aforementioned thickness range can also be employed for the gate dielectric material that may provide the gate dielectric portion 92 .
- the gate conductor portion 94 can include a gate conductor material.
- the gate conductor material used in providing the gate conductor portion 94 can include any conductive material including, for example, doped polysilicon, an elemental metal (e.g., tungsten, titanium, tantalum, aluminum, nickel, ruthenium, palladium and platinum), an alloy of at least two elemental metals, an elemental metal nitride (e.g., tungsten nitride, aluminum nitride, and titanium nitride), an elemental metal silicide (e.g., tungsten silicide, nickel silicide, and titanium silicide) or multilayered combinations thereof.
- an elemental metal e.g., tungsten, titanium, tantalum, aluminum, nickel, ruthenium, palladium and platinum
- an alloy of at least two elemental metals e.g., tungsten nitride, aluminum nitride, and titanium nitride
- a first set of functional gate structures includes a first gate conductor portion, while a second set of functional gate structures comprises a second gate conductor portion.
- the first gate conductor portion may be the same as, or different from, the second gate conductor portion.
- the first gate conductor portion may comprise an nFET gate metal
- the second gate conductor portion may comprise a pFET gate metal
- the first gate conductor portion may comprise a pFET gate metal
- the second gate conductor portion may comprise an nFET gate metal.
- the gate conductor material used in providing the gate conductor portion 94 can be formed utilizing a deposition process including, for example, chemical vapor deposition (CVD), plasma enhanced chemical vapor deposition (PECVD), physical vapor deposition (PVD), sputtering, atomic layer deposition (ALD) or other like deposition processes.
- CVD chemical vapor deposition
- PECVD plasma enhanced chemical vapor deposition
- PVD physical vapor deposition
- ALD atomic layer deposition
- a metal silicide is formed
- a conventional silicidation process is employed.
- block mask technology can be used.
- the gate conductor material used in providing the gate conductor portion 94 has a thickness from 50 nm to 200 nm. Other thicknesses that are lesser than, or greater than, the aforementioned thickness range can also be employed for the gate conductor material used in providing the gate conductor portion 94 .
- the method of the present application as described in detail herein above can provide stacked semiconductor nanowires that have a uniform shape and dimension (i.e., height and width). Each stacked semiconductor nanowire can be non-rounded as is shown in the drawings of the present application.
- the method of the present application can also allow stacking of any semiconductor material independent of its lattice constant.
- the method of the present application can further allow any number of stacked semiconductor nanowires to be formed in which any type of semiconductor material can be selected from each stacked semiconductor nanowire. In some embodiments, it is possible to provide different semiconductor materials for each stacked semiconductor nanowire.
- the method of the present application also provides stacked and suspended nanowires utilizing etching processes that remove the dielectric (i.e., insulator) material that is located above and below each semiconductor fin portion that is used to provide each stacked and suspended semiconductor nanowire.
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Abstract
A fin stack structure is provided on an insulator layer. The fin stack structure comprises, from bottom to top, a first semiconductor fin portion, a dielectric fin portion, a second semiconductor fin portion and a hard mask fin portion. A sacrificial gate structure is formed on a portion of the fin stack structure. The hard mask fin portion and the dielectric fin portion not located beneath the sacrificial gate structure are removed. An epitaxial semiconductor material structure is then formed from exposed surfaces of each semiconductor fin portion. The sacrificial gate structure is then removed. Next, remaining portions of the hard mask fin portion and the dielectric fin portion are removed. The insulating layer is then recessed. After recessing the insulator layer, the first and second semiconductor fin portions are suspended and are stacked one atop the other.
Description
- The present application relates to a semiconductor structure and a method of forming the same. More particularly, the present application relates to a gate-all-around semiconductor structure including a stack of suspended semiconductor nanowires that have a uniform shape and dimension and a method of forming the same.
- For more than three decades, the continued miniaturization of metal oxide semiconductor field effect transistors (MOSFETs) has driven the worldwide semiconductor industry. Various showstoppers to continued scaling have been predicated for decades, but a history of innovation has sustained Moore's Law in spite of many challenges. However, there are growing signs today that metal oxide semiconductor transistors are beginning to reach their traditional scaling limits. Since it has become increasingly difficult to improve MOSFETs and therefore complementary metal oxide semiconductor (CMOS) performance through continued scaling, further methods for improving performance in addition to scaling have become critical.
- The use of non-planar semiconductor devices such as, for example, gate-all-around semiconductor nanowire field effect transistors is the next step in the evolution of complementary metal oxide semiconductor (CMOS) devices.
- In its basic form, gate-all-around semiconductor nanowire field effect transistors include at least one semiconductor nanowire including a source region, a drain region and a channel region located between the source region and the drain region, and a gate electrode that wraps around the channel region of the at least one semiconductor nanowire. A gate dielectric is typically disposed between the channel region of the at least one semiconductor nanowire and the gate electrode. The gate electrode regulates electron flow through the semiconductor nanowire channel between the source region and the drain region.
- Gate-all-around semiconductor nanowire field effect transistors can achieve higher drive currents with increasingly smaller dimensions as compared to conventional planar FETs. Stacked semiconductor nanowires, in which the semiconductor nanowires are formed one atop another, afford higher density than their non-stacked semiconductor nanowire counterparts.
- In the fabrication of semiconductor nanowires, it is very challenging to produce semiconductor nanowires that have a desired shape and dimension. This challenge is further compounded when stacked semiconductor nanowires are fabricated. Another issue in fabricating gate-all-around semiconductor nanowire field effect transistors having stacked semiconductor nanowires is the suspension of each stacked semiconductor nanowire.
- In view of the above, there is a need for providing gate-all-around semiconductor nanowire field effect transistors in which a stack of suspended semiconductor nanowires is provided in which each semiconductor nanowire has a same shape and a same dimension (i.e., height and width).
- A fin stack structure is provided on an insulator layer. The fin stack structure comprises, from bottom to top, a first semiconductor fin portion, a dielectric fin portion, a second semiconductor fin portion and a hard mask fin portion. A sacrificial gate structure is formed on a portion of the fin stack structure. The hard mask fin portion and the dielectric fin portion not located beneath the sacrificial gate structure are removed. An epitaxial semiconductor material structure is then formed from exposed surfaces of each semiconductor fin portion. The sacrificial gate structure is then removed. Next, remaining portions of the hard mask fin portion and the dielectric fin portion are removed. The insulating layer is then recessed. After recessing the insulator layer, the first and second semiconductor fin portions are suspended and are stacked one atop the other.
- In one aspect of the present application, a method of forming a semiconductor structure is provided. In one embodiment of the present application, the method includes providing at least one fin stack structure on an insulator layer. The at least one fin stack structure comprises from bottom to top, a first semiconductor fin portion, a dielectric fin portion, a second semiconductor fin portion and a hard mask fin portion. Next, at least one sacrificial gate structure is formed on a portion of the at least one fin stack structure. After forming the at least one sacrificial gate structure, the hard mask fin portion and the dielectric fin portion that are not located beneath the at least one sacrificial gate structure are removed. Next, an epitaxial semiconductor material structure is formed from exposed surfaces of the first semiconductor fin portion and the second semiconductor fin portion not covered by the at least one sacrificial gate structure. The at least one sacrificial gate structure is then removed. Next, remaining portions of the hard mask fin portion and remaining portions of the dielectric fin portion of the at least one fin stack structure that were previously located beneath the at least one sacrificial gate structure are removed. The insulating layer is then recessed. After recessing the insulator layer, the first semiconductor fin portion and the second semiconductor fin portion are suspended and are stacked one atop the other.
- In another aspect of the present application, a semiconductor structure is provided. In one embodiment of the present application, the semiconductor structure includes a stack of suspended semiconductor nanowires located above a surface of an insulator layer portion, wherein each semiconductor nanowire of the stack has a same shape and dimension. A functional gate structure wraps around each suspended semiconductor nanowire of the stack.
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FIG. 1 is a cross sectional view of an exemplary semiconductor structure of a first substrate including, from bottom to top, a first handle substrate, a first insulator layer and a first semiconductor material layer that can be employed in accordance with an embodiment of the present application. -
FIG. 2 is a cross sectional view of the exemplary semiconductor structure ofFIG. 1 after forming a first dielectric layer on an exposed surface of the first semiconductor material layer. -
FIG. 3 is a cross sectional view showing a second substrate atop the exemplary semiconductor structure shown inFIG. 2 and including a second handle substrate, a second insulator layer, and a second semiconductor material layer, wherein a second dielectric layer is located on the second semiconductor material layer. -
FIG. 4 is a cross sectional view of the exemplary semiconductor structure ofFIG. 3 after bonding the first dielectric layer to the second dielectric layer. -
FIG. 5 is a cross sectional view of the exemplary semiconductor structure ofFIG. 4 after removing the second handle substrate and the second insulator layer. -
FIG. 6 is a cross sectional view of the exemplary semiconductor structure ofFIG. 5 after forming a third dielectric layer on an exposed surface of the second semiconductor material layer. -
FIG. 7 is a cross sectional view showing an optional third substrate atop the exemplary semiconductor structure ofFIG. 6 and including a third handle substrate, a third insulator layer, and a third semiconductor material layer, wherein a fourth dielectric layer is located on the third semiconductor material layer. -
FIG. 8 is a cross sectional view of the exemplary semiconductor structure ofFIG. 7 after bonding the third dielectric layer to the fourth dielectric layer. -
FIG. 9 is a cross sectional view of the exemplary semiconductor structure ofFIG. 8 after removing the third handle substrate and the third insulator layer. -
FIG. 10 is a cross sectional view of the exemplary semiconductor structure ofFIG. 9 after forming a hard mask material layer on an exposed surface of the third semiconductor material layer. -
FIG. 11 is a cross sectional view of the exemplary semiconductor structure ofFIG. 10 after patterning the hard mask material layer, the third semiconductor material layer, the fourth dielectric layer, the third dielectric layer, the second semiconductor material layer, the second dielectric layer, the first dielectric layer and the first semiconductor material layer to provide a plurality of fin stack structures extending upwards from different portions of the first insulator layer, wherein each fin stack structure includes, from bottom to top, a first semiconductor material fin portion, a combined first and second dielectric fin portion, a second semiconductor fin portion, a combined third and fourth dielectric fin portion, a third semiconductor fin portion and a hard mask fin portion. -
FIG. 12 is a top down view of the exemplary semiconductor structure ofFIG. 11 after forming at least one sacrificial gate structure straddling over a portion of each fin stack structure. -
FIG. 13A is a top down view of the exemplary semiconductor structure ofFIG. 12 after removing the hard mask fin portion, the combined third and fourth dielectric fin portion, and the combined first and second dielectric fin portion that are not protected by the sacrificial gate structure. -
FIG. 13B is a cross sectional view of the exemplary semiconductor structure ofFIG. 13A along vertical plane B-B′. -
FIG. 14 is a top down view of the exemplary semiconductor structure ofFIGS. 13A-13B after forming an epitaxial semiconductor material structure from exposed semiconductor material surfaces of each fin stack structure that are located on either side of each sacrificial gate structure. -
FIG. 15 is a top down view of the exemplary semiconductor structure ofFIG. 14 after removing the at least one sacrificial gate structure. -
FIG. 16A is a cross sectional view of the exemplary semiconductor structure ofFIG. 15 through vertical plane B-B′ after suspending the third semiconductor material fin portion and the second semiconductor fin portion that were located previously beneath the sacrificial gate structure. -
FIG. 16B is a cross sectional view of the exemplary semiconductor structure ofFIG. 15 through vertical plane C-C′ after suspending the third semiconductor material fin portion and the second semiconductor fin portion of each fin stack structure that were located previously beneath the sacrificial gate structure. -
FIG. 17A is top down view of the exemplary semiconductor structure ofFIGS. 16A-16B after recessing the first insulator layer to suspend the first semiconductor fin portion of each fin stack structure and forming a functional gate structure wrapping around each suspended first semiconductor fin portion, each second semiconductor fin portion and each third semiconductor fin portion. -
FIG. 17B is a cross sectional view of the exemplary semiconductor structure ofFIG. 17A along vertical plane B-B′. - The present application will now be described in greater detail by referring to the following discussion and drawings that accompany the present application. It is noted that the drawings of the present application are provided for illustrative purposes only and, as such, the drawings are not drawn to scale. It is also noted that like and corresponding elements are referred to by like reference numerals.
- In the following description, numerous specific details are set forth, such as particular structures, components, materials, dimensions, processing steps and techniques, in order to provide an understanding of the various embodiments of the present application. However, it will be appreciated by one of ordinary skill in the art that the various embodiments of the present application may be practiced without these specific details. In other instances, well-known structures or processing steps have not been described in detail in order to avoid obscuring the present application.
- It will be understood that when an element as a layer, region or substrate is referred to as being “on” or “over” another element, it can be directly on the other element or intervening elements may also be present. In contrast, when an element is referred to as being “directly on” or “directly over” another element, there are no intervening elements present. It will also be understood that when an element is referred to as being “beneath” or “under” another element, it can be directly beneath or under the other element, or intervening elements may be present. In contrast, when an element is referred to as being “directly beneath” or “directly under” another element, there are no intervening elements present.
- Referring first to
FIG. 1 , there is illustrated an exemplary semiconductor structure of a first substrate (10L, 12L, 14L) including, from bottom to top, afirst handle substrate 10L, afirst insulator layer 12L and a firstsemiconductor material layer 14L that can be employed in accordance with an embodiment of the present application. Collectively, thefirst handle substrate 10L, thefirst insulator layer 12L and the firstsemiconductor material layer 14L and thus the first substrate may be referred to herein as a first semiconductor-on-insulator (SOI) substrate. - In one embodiment of the present application, the
first handle substrate 10L may include at least one semiconductor material that has semiconductor properties. Examples of materials that have semiconducting properties and thus can be employed as the semiconductor material that provides thefirst handle substrate 10L include silicon (Si), germanium (Ge), silicon germanium alloys (SiGe), silicon carbide (SiC), silicon germanium carbide (SiGeC), III-V compound semiconductors and/or II-VI compound semiconductors. III-V compound semiconductors are materials that include at least one element from Group III of the Periodic Table of Elements and at least one element from Group V of the Periodic Table of Elements. II-VI compound semiconductors are materials that include at least one element from Group II of the Periodic Table of Elements and at least one element from Group VI of the Periodic Table of Elements. In one embodiment, thefirst handle substrate 10L is composed entirely of silicon. - In another embodiment of the present application, the
first handle substrate 10L may be composed of a non-semiconductor material including, for example, a dielectric material and/or a conductive material. - When the
first handle substrate 10L is composed of at least one semiconductor material, the at least one semiconductor material that provides thefirst handle substrate 10L may be single crystalline, polycrystalline or amorphous. In one example, thefirst handle substrate 10L is composed of single crystalline silicon. - When the
first handle substrate 10L is composed of at least one semiconductor material, the at least one semiconductor material that provides thefirst handle substrate 10L may have any of the well known crystal orientations. For example, the crystal orientation of thefirst handle substrate 10L may be {100}, {110}, or {111}. Other crystallographic orientations besides those specifically mentioned can also be used in the present application. - The
first insulator layer 12L of the exemplary semiconductor structure shown inFIG. 1 may be a crystalline or non-crystalline dielectric material such as an oxide and/or nitride. In one embodiment, thefirst insulator layer 12L is a dielectric oxide such as, for example, silicon dioxide. In another embodiment of the present application, thefirst insulator layer 12L may be a dielectric nitride such as, for example, silicon nitride or boron nitride. In yet another embodiment of the present application, thefirst insulator layer 12L may include a stack of a dielectric oxide and a dielectric nitride. In one example, a stack of, in any order, silicon dioxide and silicon nitride or boron nitride may be employed as thefirst insulator layer 12L. Thefirst insulator layer 12L may have a thickness from 10 nm to 200 nm, although other thicknesses that are lesser than, or greater than, the aforementioned thickness range may also be employed as the thickness of thefirst insulator layer 12L. - The first
semiconductor material layer 14L includes one of the semiconductor materials mentioned above for thefirst handle substrate 10L. The semiconductor material that provides the firstsemiconductor material layer 14L may be a relaxed semiconductor material or a strained semiconductor material. In one embodiment, the semiconductor material that provides the firstsemiconductor material layer 14L includes a same semiconductor material as thefirst handle substrate 10L. In one example, silicon is employed as the semiconductor material for both thefirst handle substrate 10L and the firstsemiconductor material layer 14L. In another embodiment, the firstsemiconductor material layer 14L includes a semiconductor material that differs from a semiconductor material that provides thefirst handle substrate 10L. In one example, thefirst handle substrate 10L may be composed of silicon, while the firstsemiconductor material layer 14L may be composed of a silicon germanium alloy. - The first
semiconductor material layer 14L may have one of the crystal orientations mentioned above for the semiconductor material that provides thefirst handle substrate 10L. In one embodiment, the crystal orientation of thefirst semiconductor material 14L is the same as the crystal orientation of thefirst handle substrate 10L. In another embodiment, the crystal orientation of the firstsemiconductor material layer 14L differs from the crystal orientation of thefirst handle substrate 10L. Typically, the firstsemiconductor material layer 14L is a single crystalline semiconductor material. The firstsemiconductor material layer 14L may have a thickness from 10 nm to 100 nm, although other thicknesses that are lesser than, or greater than, the aforementioned thickness range may also be employed as the thickness of the firstsemiconductor material layer 14L. - In one embodiment, the first substrate (10L, 12L, 14L) may be formed by wafer bonding. In yet another embodiment, the first substrate (10L, 12L, 14L) may be formed by an implantation process known as SIMOX (i.e., Separation by IMplanting OXygen). In some embodiments of the present application, a thermal mixing process or a thermal condensation process may be employed in forming the first
semiconductor material layer 14L. Thermal mixing includes annealing in an inert ambient (i.e., helium and/or argon), while thermal condensation includes annealing in an oxidizing ambient (air, oxygen, ozone and/or NO2). The anneal temperature for both thermal mixing and thermal condensation can be from 600° C. to 1200° C. In such a process a sacrificial silicon germanium alloy layer having a first germanium content can formed on a silicon layer that is located atop the first insulator layer. One of thermal mixing or thermal condensation can then be performed to convert the Si/SiGe material stack into a silicon germanium alloy layer having a second germanium content that differs from the first germanium content. The silicon germanium alloy having the second germanium content can be used as the firstsemiconductor material layer 14L of the first substrate exemplified inFIG. 1 . - Referring now to
FIG. 2 , there is illustrated the exemplary semiconductor structure ofFIG. 1 after forming a firstdielectric layer 16L on an exposed surface of the firstsemiconductor material layer 14L. The firstdielectric layer 16L is employed in the present application as a dielectric material bonding layer in a subsequent dielectric-to-dielectric bonding process. The firstdielectric layer 16L may include one of the materials mentioned above for thefirst insulator layer 12L. In one embodiment, the firstdielectric material layer 16L is composed of a same material as thefirst insulator layer 12L. In one example, both the firstdielectric layer 16L and thefirst insulator layer 12L are composed of silicon dioxide. The firstdielectric layer 16L can have a thickness from 1 nm to 10 nm, although other thicknesses that are lesser than, or greater than, the aforementioned thickness range may also be employed as the thickness of the firstdielectric layer 16L. - In one embodiment of the present application, the first
dielectric layer 16L can be formed utilizing a deposition process such as, for example, chemical vapor deposition (CVD) or plasma enhanced chemical vapor deposition (PECVD). In another embodiment of the present application, the firstdielectric layer 16L can be formed utilizing a thermal oxidation or thermal nitridation process. - Referring now to
FIG. 3 , there is illustrated a second substrate (20L, 22L, 24L) atop the exemplary semiconductor structure shown inFIG. 2 . The second substrate (20L, 22L, 24L) includes asecond handle substrate 20L, asecond insulator layer 22L, and a secondsemiconductor material layer 24L. As is further shown, asecond dielectric layer 26L is located on the secondsemiconductor material layer 24L. - The
second handle substrate 20L may include any of the materials mentioned above for thefirst handle substrate 10L. In one embodiment, thefirst handle substrate 10L and thesecond handle substrate 20L include a same material. In one example, thefirst handle substrate 10L and thesecond handle substrate 20L include silicon. - The
second insulator layer 22L may include any of the materials mentioned above for thefirst insulator layer 12L. In one embodiment, thefirst insulator layer 12L and thesecond insulator layer 22L may include a same insulator material such as, for example, silicon dioxide. - The second
semiconductor material layer 24L may include one of the semiconductor materials mentioned above for the firstsemiconductor material layer 14L. In one embodiment, the secondsemiconductor material layer 24L and the firstsemiconductor material layer 14L comprise a same semiconductor material, such as, for example, silicon or a silicon germanium alloy. In another embodiment, the secondsemiconductor material layer 24L comprises a different semiconductor material than the firstsemiconductor material layer 14L. In one example, the firstsemiconductor material layer 14L may be composed of silicon, while the secondsemiconductor material layer 24L may be composed of a silicon germanium alloy or a III-V compound semiconductor. The secondsemiconductor material layer 24L that is provided has a same thickness as that of the firstsecond material layer 14L mentioned above. - The second substrate (20L, 22L, 24L) may be referred to as a second SOI substrate. The second substrate (20L, 22L, 24L) can be formed utilizing one of the techniques mentioned above in forming the first substrate (10L, 12L, 14L).
- The
second dielectric layer 26L may include one of the materials mentioned above for the firstdielectric layer 16L. In one embodiment of the present application, the first and seconddielectric layers second dielectric layer 26L is composed of a different material than the firstdielectric layer 16L. Thesecond dielectric layer 26L may have a thickness within the range mentioned above for the firstdielectric layer 16L. The thickness of thesecond dielectric layer 26L may be the same as, lesser than, or greater than, the thickness of the firstdielectric layer 16L. Thesecond dielectric layer 26L may be formed utilizing one of the techniques mentioned above in forming the firstdielectric layer 16L. - Referring now to
FIG. 4 , there is illustrated the exemplary semiconductor structure ofFIG. 3 after bonding the firstdielectric layer 16L to thesecond dielectric layer 26L. Bonding includes contacting an exposed surface of the firstdielectric layer 16L that is attached to the first substrate (10L, 12L, 14L) to thesecond dielectric layer 26L that is attached to the second substrate (20L, 22L, 24L). A dielectric-to-dielectric bonding interface is formed. Bonding can be performed utilizing any bonding temperature including, for example, from room temperature (20° C.) up to 1200° C. Bonding can be performed in an inert ambient and an external force may or may not be applied during a part of, or the entirety of, the bonding process. - Referring now to
FIG. 5 , there is illustrated the exemplary semiconductor structure ofFIG. 4 after removing thesecond handle substrate 20L and thesecond insulator layer 22L. The removal of thesecond handle substrate 20L and thesecond insulator layer 22L exposes a surface of the secondsemiconductor material layer 24L which is now attached to the first substrate (10L, 12L, 14L) through the bonded first and seconddielectric layers - In one embodiment, the removal of the
second handle substrate 20L and thesecond insulator layer 22L may be performed utilizing a single removal process such as, for example, a planarization process or an etching process. In one example, the removal of thesecond handle substrate 20L and thesecond insulator layer 22L are performed by utilizing a planarization such as, for example, chemical mechanical planarization or grinding. In another embodiment, the removal of thesecond handle substrate 20L and thesecond insulator layer 22L may occur in two separate steps. For example, thesecond handle substrate 20L may be removed first (via a planarization process or etching), followed by the removal of thesecond insulator layer 22L (via a planarization process or etching). - Referring now to
FIG. 6 , there is illustrated the exemplary semiconductor structure ofFIG. 5 after forming a thirddielectric layer 28L on an exposed surface of the secondsemiconductor material layer 24L that is now attached to the first substrate (10L, 12L, 14L) through bondeddielectric layers - The third
dielectric layer 28L may include one of the materials mentioned above for the firstdielectric layer 16L. In one embodiment, the thirddielectric layer 28L may comprise a same material as the first and seconddielectric layers dielectric layer 28L may comprise a same material as the firstdielectric layer 16L, but a different material than thesecond dielectric layer 26L. In yet another embodiment, the thirddielectric layer 28L may comprise a same material as thesecond dielectric layer 26L, but a different material than the firstdielectric layer 16L. - The third
dielectric layer 28L may have a thickness within the range mentioned above for the firstdielectric layer 16L. The thickness of the thirddielectric layer 28L may be the same as, lesser than, or greater than, the thickness of the first and/or second dielectric layers (16L, 26L). The thirddielectric layer 28L may be formed utilizing one of the techniques mentioned above in forming the firstdielectric layer 16L. - In some embodiments, third
dielectric layer 28L is used to provide bonding to a third substrate. In yet other embodiments, the thirddielectric layer 28L may be used as topmost hard mask layer during a subsequent patterning process. - Referring now to
FIG. 7 , there is illustrated an optional third substrate (30L, 32L, 34L) atop the exemplary semiconductor structure ofFIG. 6 . The third substrate includes athird handle substrate 30L, athird insulator layer 32L, and a thirdsemiconductor material layer 34L. Afourth dielectric layer 36L is located on the thirdsemiconductor material layer 34L. - The
third handle substrate 30L may include any of the materials mentioned above for thefirst handle substrate 10L. In one embodiment, thefirst handle substrate 10L and thethird handle substrate 30L include a same material. In one example, thefirst handle substrate 10L and thethird handle substrate 30L include silicon. - The
third insulator layer 32L may include any of the materials mentioned above for thefirst insulator layer 12L. In one embodiment, thefirst insulator layer 12L and thethird insulator layer 32L may include a same insulator material such as, for example, silicon dioxide. - The third
semiconductor material layer 34L may include one of the semiconductor materials mentioned above for the firstsemiconductor material layer 14L. In one embodiment, the thirdsemiconductor material layer 34L, the secondsemiconductor material layer 24L and the firstsemiconductor material layer 14L comprise a same semiconductor material, such as, for example, silicon or a silicon germanium alloy. In another embodiment, the thirdsemiconductor material layer 34L comprises a different semiconductor material than one of the firstsemiconductor material layer 14L and the secondsemiconductor material layer 24L. In yet another embodiment, the thirdsemiconductor material layer 34L comprises a different semiconductor material than the first and second semiconductor material layers (14L, 24L), and the firstsemiconductor material layer 14L comprises a different semiconductor material than thesecond semiconductor material 24L. Stated in different terms, the firstsemiconductor material layer 14L, and the secondsemiconductor material layer 24L and the thirdsemiconductor material layer 34L may comprise different semiconductor materials altogether. The thirdsemiconductor material layer 34L that is provided has a same thickness as that of the first and second semiconductor material layers 14L, 24L mentioned above. - The third substrate (30L, 32L, 34L) may be referred to as a third SOI substrate. The third substrate (30L, 32L, 34L) can be formed utilizing one of the techniques mentioned above in forming the first substrate (10L, 12L, 14L).
- The fourth
dielectric layer 36L may include one of the materials mentioned above for the firstdielectric layer 16L. In one embodiment of the present application, the first, second, third and fourthdielectric layers dielectric layer 36L may have a thickness within the range mentioned above for the firstdielectric layer 16L. The thickness of the fourthdielectric layer 36L may be the same as, lesser than, or greater than, the thickness of the firstdielectric layer 16L, thesecond dielectric layer 26L and the thirddielectric layer 28L. The fourthdielectric layer 36L may be formed utilizing one of the techniques mentioned above in forming the firstdielectric layer 16L. - Referring now to
FIG. 8 , there is illustrated the exemplary semiconductor structure ofFIG. 7 after bonding the thirddielectric layer 28L to the fourthdielectric layer 36L. The bonding can be performed as described above. The bonding forms a dielectric-to-dielectric interface between the thirddielectric layer 28L and the fourthdielectric layer 36L. - Referring now to
FIG. 9 , there is illustrated the exemplary semiconductor structure ofFIG. 8 after removing thethird handle substrate 30L and thethird insulator layer 32L from the bonded structure ofFIG. 8 . Thethird handle substrate 30L and thethird insulator layer 32L can be removed utilizing one of the techniques mentioned above in removing thesecond handle substrate 20L and thesecond insulator layer 22L from the bonded structure shown inFIG. 4 . - Although not shown, additional SOI substrates and dielectric layers can be provided and bonded to each other in the manner described above and illustrated in
FIGS. 1-5 . The number of additional SOI substrates and dielectric layers is not limited and can be selected to provide a desired numbered of semiconductor nanowires within a given stack of semiconductor nanowires. - Referring now to
FIG. 10 , there is illustrated the exemplary semiconductor structure ofFIG. 9 after forming a hardmask material layer 38L on an exposed surface of the thirdsemiconductor material layer 34L. The hardmask material layer 38L may include any hard mask material such as, for example, a dielectric oxide, dielectric nitride and/or a dielectric oxynitride. In one example, the hardmask material layer 38L is composed of a dielectric oxide such as, for example, silicon dioxide. The hardmask material layer 38L may be formed utilizing one of the techniques mentioned above in forming the firstdielectric layer 16L. The hardmask material layer 38L may have a thickness from 5 nm to 25 nm, although other thicknesses that are lesser than, or greater than, the aforementioned thickness range may also be used in the present application. In some embodiments, the thickness of the hardmask material layer 38L may be the same as the combined thickness of the first and second dielectric layers (16L, 26L) and/or the combined thickness of the third and fourth dielectric layers (28L, 36L). - Referring now to
FIG. 11 , there is illustrated the exemplary semiconductor structure ofFIG. 10 after patterning the hardmask material layer 38L, the thirdsemiconductor material layer 34L, the fourthdielectric layer 36L, the thirddielectric layer 28L, the secondsemiconductor material layer 24L, thesecond dielectric layer 26L, the firstdielectric layer 16L and the firstsemiconductor material layer 14L to provide a plurality offin stack structures 50 extending upwards from different portions of thefirst insulator layer 12L. Although the present application describes and illustrates a plurality of fin stack structures being formed, the present application can also be used to provide a single fin stack structure. - Each
fin stack structure 50 includes, from bottom to top, a first semiconductormaterial fin portion 14P, a combined first and seconddielectric fin portion 52P, a secondsemiconductor fin portion 24P, a combined third and fourth dielectric fin portion 54P, a thirdsemiconductor fin portion 34P and a hardmask fin portion 38P. The combined first and seconddielectric fin portion 52P may be referred to as a first dielectric fin portion, and the combined the combined third and fourth dielectric fin portion may be referred to a second dielectric fin portion. - Each combined first and second
dielectric fin portion 52P comprises a remaining portion of the firstdielectric layer 16L and a remaining portion of thesecond dielectric layer 26L (in the drawings a single layered structure is shown for clarity and can be used to illustrated an embodiment in which the first and second dielectric layers (16L, 26L) are composed of the same material). Each combined third and fourth dielectric fin portion 54P comprises a remaining portion of the thirddielectric layer 28L and a remaining portion of the fourthdielectric layer 36L (in the drawings a single layered structure is shown for clarity and assumes one embodiment in which the third and fourthdielectric layers - In one embodiment of the present application, the patterning used to provide the plurality of
fin stack structures 50 may include lithography and etching. Lithography includes forming a photoresist material (not shown) atop a material or material stack to be patterned. The photoresist material may include a positive-tone photoresist composition, a negative-tone photoresist composition or a hybrid-tone photoresist composition. The photoresist material may be formed by a deposition process such as, for example, spin-on coating. After forming the photoresist material, the deposited photoresist material is subjected to a pattern of irradiation. Next, the exposed photoresist material is developed utilizing a conventional resist developer. This provides a patterned photoresist atop a portion of the material or material stack to be patterned. The pattern provided by the patterned photoresist material is thereafter transferred into the underlying material layer or material layers utilizing at least one pattern transfer etching process. Typically, the at least one pattern transfer etching process is an anisotropic etch. In one embodiment, a dry etching process such as, for example, reactive ion etching can be used. In another embodiment, a chemical etchant can be used. In still a further embodiment, a combination of dry etching and wet etching can be used. In the illustrated embodiment, the etch stops on the topmost surface of thefirst insulator layer 12L. - In another embodiment of the present application, the patterning used to provide the
fin stack structures 50 may include a sidewall image transfer (SIT) process. The SIT process includes forming a mandrel material layer (not shown) atop the material or material layers that are to be patterned. The mandrel material layer (not shown) can include any material (semiconductor, dielectric or conductive) that can be selectively removed from the structure during a subsequently performed etching process. In one embodiment, the mandrel material layer (not shown) may be composed of amorphous silicon or polysilicon. In another embodiment, the mandrel material layer (not shown) may be composed of a metal such as, for example, Al, W, or Cu. The mandrel material layer (not shown) can be formed, for example, by chemical vapor deposition or plasma enhanced chemical vapor deposition. Following deposition of the mandrel material layer (not shown), the mandrel material layer (not shown) can be patterned by lithography and etching to form a plurality of mandrel structures (also not shown) on the topmost surface of the structure. - The SIT process continues by forming a spacer on each sidewall of each mandrel structure. The spacer can be formed by deposition of a spacer material and then etching the deposited spacer material. The spacer material may comprise any material having an etch selectivity that differs from the mandrel material. Examples of deposition processes that can be used in providing the spacer material include, for example, chemical vapor deposition (CVD), plasma enhanced chemical vapor deposition (PECVD), or atomic layer deposition (ALD). Examples of etching that be used in providing the spacers include any etching process such as, for example, reactive ion etching.
- After formation of the spacers, the SIT process continues by removing each mandrel structure. Each mandrel structure can be removed by an etching process that is selective for removing the mandrel material. Following the mandrel structure removal, the SIT process continues by transferring the pattern provided by the spacers into the underlying material or material layers. The pattern transfer may be achieved by utilizing at least one etching process. Examples of etching processes that can used to transfer the pattern may include dry etching (i.e., reactive ion etching, plasma etching, and ion beam etching or laser ablation) and/or a chemical wet etch process. In one example, the etch process used to transfer the pattern may include one or more reactive ion etching steps. The etch stops on a topmost surface of the
first insulator layer 12L. Upon completion of the pattern transfer, the SIT process concludes by removing the spacers from the structure. Each spacer may be removed by etching or a planarization process. - As used herein, a “fin stack structure” refers to a material stack of from bottom to top, a first semiconductor
material fin portion 14P, a combined first and seconddielectric fin portion 52P, a secondsemiconductor fin portion 24P, an optional combined third and fourth dielectric fin portion 54P, an optional thirdsemiconductor fin portion 34P, and a hardmask fin portion 38P, and including a pair of vertical sidewalls that are parallel to each other. As used herein, a surface is “vertical” if there exists a vertical plane from which the surface does not deviate by more than three times the root mean square roughness of the surface. In one embodiment of the present application, each fin stack structure has a width from 5 nm to 30 nm. Other widths that is lesser than, or greater than the range mentioned herein can also be used in the present application. Eachfin stack structure 50 is spaced apart from its nearest neighboringfin stack structure 50 by a pitch of from 20 nm to 100 nm. Also, eachfin stack structure 50 is oriented parallel to each other. - As is shown, each semiconductor material fin portion of the fin stack structure is located between an underlying layer of an insulator (i.e., dielectric) layer and an overlying layer of an insulator (i.e., dielectric) layer. As is further shown, each fin portion within the
fin stack structure 50 has sidewall surfaces that are vertically aligned with each. As such, the width of each fin portion of the fin stack structure is the same. - Referring now to
FIG. 12 , there is illustrated the exemplary semiconductor structure ofFIG. 11 after forming at least onesacrificial gate structure 60 straddling over a portion of eachfin stack structure 50. By “sacrificial gate structure” it is meant a material or material stack that serves as a placeholder for a subsequently formed functional gate structure. By “straddling over” it is meant that one material is formed atop and along sidewall surfaces of another material. Although a plurality ofsacrificial gate structures 60 is described and illustrated, the present application can also be used when a single sacrificial gate structure is formed. - Each
sacrificial gate structure 60 may include a sacrificial gate dielectric portion, a sacrificial gate material portion and a sacrificial gate cap portion. In some embodiments, each sacrificial gate dielectric portion and/or each sacrificial gate cap portion may be omitted. For clarity, eachsacrificial gate structure 60 is shown a single piece. - When present, the sacrificial gate dielectric portion includes a dielectric material such as for example, a dielectric oxide, dielectric nitride and/or a dielectric oxynitride. In one example, the sacrificial gate dielectric portion may be composed of silicon dioxide and/or silicon nitride. The gate dielectric that may provide the sacrificial gate dielectric portion may be formed utilizing a deposition process such as, for example, chemical vapor deposition or plasma enhanced chemical vapor deposition. The thickness of the sacrificial gate dielectric can be from 5 nm to 10 nm; although other thickness that are lesser than, or greater than, the aforementioned range may be used. The sacrificial gate conductor portion may include polysilicon or a metal or metal alloy. The material that provides the sacrificial gate conductor portion can be formed utilizing a deposition process such as, for example, chemical vapor deposition, plasma enhanced chemical vapor deposition, or sputtering. The sacrificial gate conductor portion may have a thickness from 25 nm to 150 nm, although other thickness that are lesser than, or greater than, the aforementioned thickness range can also be employed. If present, the sacrificial gate cap portion may include one of the hard mask materials mentioned above in providing the hard
mask material layer 38L. The hard mask material that provides the sacrificial gate cap portion can be formed by a deposition process such chemical vapor deposition or plasma enhanced chemical vapor deposition. The sacrificial gate cap portion can have a thickness from 5 nm to 20 nm, although other thicknesses that are lesser than, or greater than, the aforementioned thickness range may also be employed. Eachsacrificial gate structure 60 can be formed by deposition of the various material layers and then patterning the resultant sacrificial dielectric material sack by utilizing, for example, lithography and etching. - Referring now to
FIGS. 13A-13B , there are illustrated various views the exemplary semiconductor structure ofFIG. 12 after removing the hardmask fin portion 38P, the combined third and fourth dielectric fin portion 54P, and the combined first and seconddielectric fin portion 52P that are not protected by thesacrificial gate structure 60. In the drawings,element 50P denotes a fin stack structure in which portions of the hardmask fin portion 38P, the combined third and fourth dielectric fin portion 54P, and the combined first and seconddielectric fin portion 52P that are not protected by thesacrificial gate structure 60 and within the source region and the drain region have been removed therefrom. - In accordance with the present application, each
sacrificial gate structure 60 is used as an anchoring structure during the removal of the hardmask fin portion 38P, the combined third and fourth dielectric fin portion 54P, and the combined first and seconddielectric fin portion 52P that are not protected by thesacrificial gate structure 60. Also, and in accordance with the present application, the removing the hardmask fin portion 38P, the combined third and fourth dielectric fin portion 54P, and the combined first and seconddielectric fin portion 52P that are not protected by thesacrificial gate structure 60 releases portions of each first semiconductormaterial fin portion 14P, the secondsemiconductor fin portion 24P, and the thirdsemiconductor fin portion 34P in the source region and drain region of the structure. Although not shown in the drawings, portions of each of the hardmask fin portion 38P, the combined third and fourth dielectric fin portion 54P, and the combined first and seconddielectric fin portion 52P remain beneath eachsacrificial gate structure 60. InFIG. 13B , one of thesacrificial gate structures 60 is shown and that sacrificial gate structure is located behind the released first semiconductormaterial fin portion 14P, the secondsemiconductor fin portion 24P, the thirdsemiconductor fin portion 34P. - The removing the hard
mask fin portion 38P, the combined third and fourth dielectric fin portion 54P, and the combined first and seconddielectric fin portion 52P that are not protected by thesacrificial gate structure 60 can be performed utilizing an etching process this is selective in removing the material that provides each of the hardmask fin portion 38P, the combined third and fourth dielectric fin portion 54P, and the combined first and seconddielectric fin portion 52P that are not protected by asacrificial gate structure 60. In one example, aqueous hydrofluoric acid or a dry etch like chemical oxide removal (COR) can be used in removing the hardmask fin portion 38P, the combined third and fourth dielectric fin portion 54P, and the combined first and seconddielectric fin portion 52P that are not protected by thesacrificial gate structures 60. - Referring now to
FIG. 14 , there is illustrated the exemplary semiconductor structure ofFIGS. 13A-13B after forming an epitaxialsemiconductor material structure 70 from exposed semiconductor material surfaces (i.e., the released first semiconductormaterial fin portion 14P, the secondsemiconductor fin portion 24P, and the thirdsemiconductor fin portion 34P) of each fin stack structure that are located on either side of eachsacrificial gate structure 60. - The epitaxial
semiconductor material structure 70 may be formed utilizing a selective epitaxial growth (or deposition) process. The term “selective” when used in conjugation with the phrase “selective epitaxial growth” denotes that the epitaxial material is grown only on semiconductor material surfaces not insulator or conductor surfaces. Thus, in the present application, each epitaxialsemiconductor material structure 70 is formed from exposed surfaces of the released first semiconductormaterial fin portion 14P, the secondsemiconductor fin portion 24P, and the thirdsemiconductor fin portion 34P that are not covered by thesacrificial gate structure 60. Each epitaxialsemiconductor material structure 70 completely surrounds the released secondsemiconductor fin portion 24P and the thirdsemiconductor fin portion 34P of each fin stack structure. Each epitaxialsemiconductor material structure 70 is located around the sidewall surfaces and topmost surface of the released firstsemiconductor fin portion 14P of each fin stack structure. - Each epitaxial
semiconductor material structure 70 comprises an epitaxial semiconductor material that is doped. The epitaxial semiconductor material that provides each epitaxialsemiconductor material structure 70 may include one of the semiconductor materials mentioned above for thehandle substrate 10L. In one example, silicon or a silicon germanium alloy may be used as the epitaxial semiconductor material. In one embodiment, the epitaxial semiconductor material comprises a same semiconductor material as at least one of the first semiconductormaterial fin portion 14P, the secondsemiconductor fin portion 24P, and the thirdsemiconductor fin portion 34P. In another embodiment, the epitaxial semiconductor material comprises a different semiconductor material than each of the first semiconductormaterial fin portion 14P, the secondsemiconductor fin portion 24P, and the thirdsemiconductor fin portion 34P. - The terms “epitaxial growth and/or deposition” and “epitaxially formed and/or grown” mean the growth of a semiconductor material on a deposition surface of a semiconductor material, in which the semiconductor material being grown has the same crystalline characteristics as the semiconductor material of the deposition surface. In an epitaxial deposition process, the chemical reactants provided by the source gases are controlled and the system parameters are set so that the depositing atoms arrive at the deposition surface of the semiconductor substrate with sufficient energy to move around on the surface and orient themselves to the crystal arrangement of the atoms of the deposition surface. Therefore, an epitaxial semiconductor material has the same crystalline characteristics as the deposition surface on which it is formed. For example, an epitaxial semiconductor material deposited on a {100} crystal surface will take on a {100} orientation. In the present application, the epitaxial
semiconductor material structure 70 has an epitaxial relationship with exposed surfaces of each of the released first semiconductormaterial fin portions 14P, the secondsemiconductor fin portions 24P, and the thirdsemiconductor fin portions 34P. - Examples of various epitaxial growth process apparatuses that can be employed in the present application include, e.g., rapid thermal chemical vapor deposition (RTCVD), low-energy plasma deposition (LEPD), ultra-high vacuum chemical vapor deposition (UHVCVD), atmospheric pressure chemical vapor deposition (APCVD) and molecular beam epitaxy (MBE). The temperature for epitaxial deposition typically ranges from 550° C. to 900° C. Although higher temperature typically results in faster deposition, the faster deposition may result in crystal defects and film cracking. The epitaxial growth of each epitaxial
semiconductor material structure 70 can be performed utilizing any well known precursor gas or gas mixture including for example, a silicon containing precursor gas (such as silane) and/or a germanium containing precursor gas (such as a germane). Carrier gases like hydrogen, nitrogen, helium and argon can be used. - The dopant that can be present in each epitaxial
semiconductor material structure 70 may be n-type dopant or p-type dopant. The dopant is typically introduced into the precursor gas during the epitaxial growth process. In other embodiments, the dopant can be introduced after the epitaxial growth process. The term “p-type” refers to the addition of impurities to an intrinsic semiconductor that creates deficiencies of valence electrons. In a silicon-containing semiconductor material, examples of p-type dopants, i.e., impurities, include, but are not limited to, boron, aluminum, gallium and indium. “N-type” refers to the addition of impurities that contributes free electrons to an intrinsic semiconductor. In a silicon containing semiconductor material, examples of n-type dopants, i.e., impurities, include, but are not limited to, antimony, arsenic and phosphorous. Each epitaxialsemiconductor material structure 70 has a dopant concentration that can be within a range from 2×1020 atoms/cm3 to 1×1021 atoms/cm3. - Referring now to
FIG. 15 , there is illustrated the exemplary semiconductor structure ofFIG. 14 after removing the at least onesacrificial gate structure 60. As is shown, the hardmask fin portion 38P of each fin stack structure that was previously located beneath eachsacrificial gate structure 60 is now exposed. The removal of eachsacrificial gate structure 60 can be performed utilizing an etching process that is selective in removing the material or material stack that provides thesacrificial gate structure 60. In one example, and when polysilicon is used as thesacrificial gate structures 60, hot ammonia can be used to remove polysilicon. - Referring now to
FIGS. 16A-16B , there are illustrated the exemplary semiconductor structure ofFIG. 15 after suspending the third semiconductormaterial fin portion 34P and the secondsemiconductor fin portion 24P that were located previously beneath thesacrificial gate structure 60. In this step of the present application, the remaining hardmask fin portions 38P, the combined third and fourth dielectric fin portion 54P, and the combined first and seconddielectric fin portion 52P are completely removed from the structure. The suspending the third semiconductormaterial fin portion 34P and the secondsemiconductor fin portion 24P that were located previously beneath thesacrificial gate structure 60 includes the selective etch that was mentioned above in providing the exemplary semiconductor structure shown inFIGS. 13A-13B of the present application. - Referring now to
FIGS. 17A-17B , there are illustrated the exemplary semiconductor structure ofFIGS. 16A-16B after recessing thefirst insulator layer 12L to suspend the firstsemiconductor fin portion 14P of each fin stack structure and forming afunctional gate 90 structure wrapping around each suspended first semiconductor fin portion, each suspended second semiconductor fin portion and each suspended third semiconductor fin portion. - The remaining portion of the
first insulator layer 12L that is formed can be referred to herein as afirst insulator portion 12P and can have a thickness that is less than the original thickness of thefirst insulator layer 12L. Each suspended first semiconductor fin portion can be referred to herein as a first suspendedsemiconductor nanowire 14S, each suspended second semiconductor fin portion can be referred to herein as a second suspendedsemiconductor nanowire 24S, and each suspended third semiconductor fin portion can be referred to herein as a third suspendedsemiconductor nanowire 34S. In accordance with the present application, each suspendedfirst semiconductor nanowire 14S, each suspendedsecond semiconductor nanowire 24S, and each suspendedthird semiconductor nanowire 34S have a same shape and dimension. - The recessing of the
first insulator layer 12L which providesfirst insulator portion 12P can be performed utilizing an etching process that is selective in removing the insulator material that provides thefirst insulator layer 12L. In one example, and when thefirst insulator layer 12L comprises silicon dioxide, aqueous hydrofluoric acid can be used to recess thefirst insulator layer 12L. - The
functional gate 90 includes a gatedielectric portion 92 and agate conductor portion 94. Thefunctional gate structure 90 can be formed by first providing a gate dielectric material and a gate conductor material. A gate patterning process may follow the deposition of the gate dielectric material and the gate conductor material. By “functional gate structure” it is meant a permanent gate structure used to control output current (i.e., flow of carriers in the channel) of a semiconducting device through electrical or magnetic fields. As is shown, thegate conductor portion 92 is present entirely around eachsemiconductor nanowire - The gate
dielectric portion 92 may include a gate dielectric material. The gate dielectric material that provides the gatedielectric portion 92 can be an oxide, nitride, and/or oxynitride. In one example, the gate dielectric material that provides the gatedielectric portion 92 can be a high-k material having a dielectric constant greater than silicon dioxide. Exemplary high-k dielectrics include, but are not limited to, HfO2, ZrO2, La2O3, Al2O3, TiO2, SrTiO3, LaAlO3, Y2O3, HfOxNy, ZrOxNy, La2OxNy, Al2OxNy, TiOxNy, SrTiOxNy, LaAlOxNy, Y2OxNy, SiON, SiNx, a silicate thereof, and an alloy thereof. Each value of x is independently from 0.5 to 3 and each value of y is independently from 0 to 2. In some embodiments, a multilayered gate dielectric structure comprising different gate dielectric materials, e.g., silicon dioxide, and a high-k gate dielectric, can be formed and used as the gatedielectric portion 92. In some embodiments, a first set of functional gate structures includes a first gate dielectric portion, while a second set of functional gate structures comprises a second gate dielectric portion. In such an embodiment, the first gate dielectric material portion may be the same as, or different from, the second gate dielectric material portion. - The gate dielectric material used in providing the gate
dielectric portion 92 can be formed by any deposition process including, for example, chemical vapor deposition (CVD), plasma enhanced chemical vapor deposition (PECVD), physical vapor deposition (PVD), sputtering, or atomic layer deposition. In some embodiments and when different gate dielectric materials are used in providing the gate dielectric portions of different functional gate structures, block mask technology can be used. In one embodiment of the present application, the gate dielectric material used in providing the gatedielectric portion 92 can have a thickness in a range from 1 nm to 10 nm. Other thicknesses that are lesser than, or greater than, the aforementioned thickness range can also be employed for the gate dielectric material that may provide the gatedielectric portion 92. - The
gate conductor portion 94 can include a gate conductor material. The gate conductor material used in providing thegate conductor portion 94 can include any conductive material including, for example, doped polysilicon, an elemental metal (e.g., tungsten, titanium, tantalum, aluminum, nickel, ruthenium, palladium and platinum), an alloy of at least two elemental metals, an elemental metal nitride (e.g., tungsten nitride, aluminum nitride, and titanium nitride), an elemental metal silicide (e.g., tungsten silicide, nickel silicide, and titanium silicide) or multilayered combinations thereof. In some embodiments, a first set of functional gate structures includes a first gate conductor portion, while a second set of functional gate structures comprises a second gate conductor portion. In such an embodiment, the first gate conductor portion may be the same as, or different from, the second gate conductor portion. For example, the first gate conductor portion may comprise an nFET gate metal, while the second gate conductor portion may comprise a pFET gate metal. In another example, the first gate conductor portion may comprise a pFET gate metal, while the second gate conductor portion may comprise an nFET gate metal. - The gate conductor material used in providing the
gate conductor portion 94 can be formed utilizing a deposition process including, for example, chemical vapor deposition (CVD), plasma enhanced chemical vapor deposition (PECVD), physical vapor deposition (PVD), sputtering, atomic layer deposition (ALD) or other like deposition processes. When a metal silicide is formed, a conventional silicidation process is employed. When a different gate conductor material is used for gate conductor portions of different functional gate structures, block mask technology can be used. In one embodiment, the gate conductor material used in providing thegate conductor portion 94 has a thickness from 50 nm to 200 nm. Other thicknesses that are lesser than, or greater than, the aforementioned thickness range can also be employed for the gate conductor material used in providing thegate conductor portion 94. - The method of the present application as described in detail herein above can provide stacked semiconductor nanowires that have a uniform shape and dimension (i.e., height and width). Each stacked semiconductor nanowire can be non-rounded as is shown in the drawings of the present application. The method of the present application can also allow stacking of any semiconductor material independent of its lattice constant. The method of the present application can further allow any number of stacked semiconductor nanowires to be formed in which any type of semiconductor material can be selected from each stacked semiconductor nanowire. In some embodiments, it is possible to provide different semiconductor materials for each stacked semiconductor nanowire. The method of the present application also provides stacked and suspended nanowires utilizing etching processes that remove the dielectric (i.e., insulator) material that is located above and below each semiconductor fin portion that is used to provide each stacked and suspended semiconductor nanowire.
- While the present application has been particularly shown and described with respect to preferred embodiments thereof, it will be understood by those skilled in the art that the foregoing and other changes in forms and details may be made without departing from the spirit and scope of the present application. It is therefore intended that the present application not be limited to the exact forms and details described and illustrated, but fall within the scope of the appended claims.
Claims (18)
1. A semiconductor structure comprising:
a stack of suspended semiconductor nanowires located above a surface of an insulator layer, wherein each semiconductor nanowire of said stack has a same shape and dimension; and
a functional gate structure wrapping around each suspended semiconductor nanowire of said stack, wherein an entirety of a bottommost surface of said functional gate structure is in direct physically contact with said surface of said insulator layer.
2. The semiconductor structure of claim 1 , wherein each semiconductor nanowire comprises a same semiconductor material.
3. The semiconductor structure of claim 1 , wherein at least one semiconductor nanowire of said stack comprises a semiconductor material that differs from remaining semiconductor nanowires of said stack.
4. The semiconductor structure of claim 1 , wherein said functional gate structure comprises a gate dielectric portion and a gate conductor portion, wherein said gate dielectric portion is present entirely around each semiconductor nanowire of said stack.
5. The semiconductor structure of claim 4 , wherein said insulator layer has a topmost surface contacting a portion of said gate conductor portion of said functional gate structure and a bottommost surface contacting a topmost surface of a handle substrate.
6. The semiconductor structure of claim 1 , further comprising an epitaxial semiconductor structure located on opposites sides of said functional gate structure.
7. The semiconductor structure of claim 1 , wherein a first suspended semiconductor nanowire of said stack of suspended semiconductor nanowires comprises a first semiconductor material, a second suspended semiconductor nanowire of said stack of suspended semiconductor nanowires comprises a second semiconductor material, and a third suspended semiconductor nanowire of said stack of suspended semiconductor nanowires comprises a third semiconductor material, wherein said third semiconductor material is different from at least one of said first semiconductor material and said second semiconductor material.
8. The semiconductor structure of claim 1 , wherein at least one of said suspended semiconductor nanowires of said stack of suspended semiconductor nanowires comprises a III-V compound semiconductor or a silicon germanium alloy.
9. The semiconductor structure of claim 1 , wherein each suspended semiconductor nanowire of said stack of suspended semiconductor nanowires has sidewall surfaces that are vertically aligned to each other.
10. The semiconductor structure of claim 1 , wherein each suspended semiconductor nanowire has non-rounded surfaces.
11. A semiconductor structure comprising:
a plurality of vertically stacked and suspended semiconductor nanowires present above an insulator layer, wherein each semiconductor nanowire of said plurality of vertically stacked and suspended semiconductor nanowires has a same shape and dimension; and
a functional gate structure wrapping around each suspended semiconductor nanowire of said plurality of vertically stacked and suspended semiconductor nanowires, wherein an entirety of a bottommost surface of said functional gate structure is in direct physically contact with a surface of said insulator layer.
12. The semiconductor structure of claim 11 , wherein each vertically stacked and suspended semiconductor nanowire is separated from its nearest neighboring vertically stacked and suspended semiconductor nanowire by a pitch from 20 nm to 50 nm.
13. The semiconductor structure of claim 12 , wherein each suspended semiconductor nanowire of said plurality of vertically stacked and suspended semiconductor nanowires has sidewall surfaces that are vertically aligned to each other.
14. The semiconductor structure of claim 13 , wherein each suspended semiconductor nanowire has non-rounded surfaces.
15. The semiconductor structure of claim 11 , wherein each suspended semiconductor nanowire within one of said plurality of vertically stacked and suspended semiconductor nanowires comprises a different semiconductor material.
16. The semiconductor structure of claim 11 , wherein each suspended semiconductor nanowire of said plurality of vertically stacked and suspended semiconductor nanowires comprises a same semiconductor material.
17. The semiconductor structure of claim 1 , further comprising a handle substrate located entirely beneath a bottommost surface of said insulator layer.
18. The semiconductor structure of claim 17 , wherein said handle substrate comprises a semiconductor material.
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