US20170025285A1 - High-k and p-type work function metal first fabrication process having improved annealing process flows - Google Patents
High-k and p-type work function metal first fabrication process having improved annealing process flows Download PDFInfo
- Publication number
- US20170025285A1 US20170025285A1 US14/805,527 US201514805527A US2017025285A1 US 20170025285 A1 US20170025285 A1 US 20170025285A1 US 201514805527 A US201514805527 A US 201514805527A US 2017025285 A1 US2017025285 A1 US 2017025285A1
- Authority
- US
- United States
- Prior art keywords
- dielectric layer
- forming
- gate
- fin
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 81
- 229910052751 metal Inorganic materials 0.000 title claims description 49
- 239000002184 metal Substances 0.000 title claims description 49
- 238000004519 manufacturing process Methods 0.000 title description 41
- 230000008569 process Effects 0.000 title description 41
- 238000000137 annealing Methods 0.000 title description 23
- 230000005669 field effect Effects 0.000 claims abstract description 10
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 26
- 230000015572 biosynthetic process Effects 0.000 claims description 24
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims description 7
- 229910052735 hafnium Inorganic materials 0.000 claims description 5
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 239000010937 tungsten Substances 0.000 claims description 5
- 239000004065 semiconductor Substances 0.000 description 29
- 239000000463 material Substances 0.000 description 20
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- 125000006850 spacer group Chemical group 0.000 description 12
- 239000000758 substrate Substances 0.000 description 9
- 239000000377 silicon dioxide Substances 0.000 description 7
- 230000004913 activation Effects 0.000 description 5
- 238000000151 deposition Methods 0.000 description 5
- 239000003989 dielectric material Substances 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- 230000008021 deposition Effects 0.000 description 4
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 238000002955 isolation Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(iv) oxide Chemical compound O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000000231 atomic layer deposition Methods 0.000 description 1
- 210000000746 body region Anatomy 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000007943 implant Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000005389 semiconductor device fabrication Methods 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000005641 tunneling Effects 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/51—Insulating materials associated therewith
- H01L29/511—Insulating materials associated therewith with a compositional variation, e.g. multilayer structures
- H01L29/513—Insulating materials associated therewith with a compositional variation, e.g. multilayer structures the variation being perpendicular to the channel plane
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28026—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/324—Thermal treatment for modifying the properties of semiconductor bodies, e.g. annealing, sintering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/41—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
- H01L29/417—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions carrying the current to be rectified, amplified or switched
- H01L29/41725—Source or drain electrodes for field effect devices
- H01L29/41791—Source or drain electrodes for field effect devices for transistors with a horizontal current flow in a vertical sidewall, e.g. FinFET, MuGFET
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/495—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a simple metal, e.g. W, Mo
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/4966—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a composite material, e.g. organic material, TiN, MoSi2
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/51—Insulating materials associated therewith
- H01L29/517—Insulating materials associated therewith the insulating material comprising a metallic compound, e.g. metal oxide, metal silicate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66545—Unipolar field-effect transistors with an insulated gate, i.e. MISFET using a dummy, i.e. replacement gate in a process wherein at least a part of the final gate is self aligned to the dummy gate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66787—Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel
- H01L29/66795—Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/785—Field effect transistors with field effect produced by an insulated gate having a channel with a horizontal current flow in a vertical sidewall of a semiconductor body, e.g. FinFET, MuGFET
Definitions
- the present disclosure relates in general to semiconductor device structures and their fabrication. More specifically, the present disclosure relates to the fabrication of a fin-type field effect transistor (FinFET) using a high-k and p-type work function metal first fabrication process that improves, inter alia, source/drain activation annealing and dielectric reliability annealing.
- FinFET fin-type field effect transistor
- Typical semiconductor devices are formed using active regions of a wafer.
- the active regions are defined by isolation regions used to separate and electrically isolate adjacent semiconductor devices.
- MOSFETs metal oxide semiconductor field effect transistors
- each MOSFET has a source and a drain that are formed in an active region of a semiconductor layer by implanting n-type or p-type impurities in the layer of semiconductor material.
- a channel (or body) region Disposed between the source and the drain is a channel (or body) region.
- a gate electrode Disposed above the body region is a gate electrode. The gate electrode and the body are spaced apart by a gate dielectric layer.
- FIG. 1A depicts a three-dimensional view of an exemplary FinFET 100 , which includes a shallow trench isolation (STI) region 104 for isolation of active areas from one another.
- STI shallow trench isolation
- the basic electrical layout and mode of operation of FinFET 100 do not differ significantly from a traditional field effect transistor.
- FinFET 100 includes a semiconductor substrate 102 , local STI region 104 , a fin 106 , and a gate 114 having a gate oxide layer (not shown) between the gate and the fin, configured and arranged as shown.
- Fin 106 includes a source region 108 , a drain region 110 and a channel region 112 , wherein gate 114 extends over the top and sides of channel region 112 .
- a single fin is shown in FIG. 1 .
- FinFET devices are fabricated having multiple fins formed on local STI region 104 and substrate 102 .
- Substrate 102 may be silicon
- local STI region 104 may be an oxide (e.g., SiO 2 ).
- Fin 106 may be silicon.
- Gate 114 controls the source to drain current flow (labeled ELECTRICITY FLOW in FIG. 1 ).
- source 108 , drain 110 and channel 112 are built as a three-dimensional bar on top of local STI region 104 and semiconductor substrate 102 .
- the three-dimensional bar is the aforementioned “fin 106 ,” which serves as the body of the device.
- the gate electrode is then wrapped over the top and sides of the fin, and the portion of the fin that is under the gate electrode functions as the channel.
- the source and drain regions are the portions of the fin on either side of the channel that are not under the gate electrode.
- the source and drain regions may be suitably doped to produce the desired FET polarity, as is known in the art.
- the dimensions of the fin establish the effective channel length for the transistor.
- Transistors have been made with silicon dioxide gate dielectrics and poly-silicon gate conductors for decades. However, as transistors have decreased in size, gate dielectric thickness has scaled below 2 nanometers, which increases tunneling leakage currents and power consumption and reduces device reliability. Replacing the silicon dioxide gate dielectric with a high-k material having a high dielectric constant (k) in comparison to silicon dioxide allows increases gate capacitance without the associated leakage effects. Suitable high-k materials include hafnium silicate, zirconium silicate, hafnium dioxide and zirconium dioxide, typically deposited using atomic layer deposition.
- Replacing the silicon dioxide gate dielectric with another material adds complexity to the fabrication process.
- implementing the gate dielectric based on high-k oxides of hafnium requires the poly-silicon gate material to be replaced with a metal that interfaces better with the high-k dielectric. Accordingly, the poly-silicon gate must be etched out and replaced with metal.
- the metal-gate may be formed before or after the source and drain regions. Forming the metal gate last (i.e., after formation of the source and drain regions) is known generally as a replacement metal gate (RMG) process flow.
- RMG replacement metal gate
- a typical fabrication process flow includes multiple annealing operations, including, for example, a high-k post-deposition anneal (PDA), a high temperature anneal applied to the high-k dielectric to improve reliability, and a high temperature source drain anneal applied to the doped source and drain regions to activate these regions.
- PDA high-k post-deposition anneal
- a high temperature anneal applied to the high-k dielectric to improve reliability to improve reliability
- a high temperature source drain anneal applied to the doped source and drain regions to activate these regions.
- Embodiments are directed to a method of forming portions of a fin-type field effect transistor (FinFET).
- the method includes forming at least one fin, and forming a dielectric layer over at least a portion of the at least one fin.
- the method further includes forming a work-function layer over at least a portion of the dielectric layer.
- the method further includes forming a source region or a drain region adjacent the at least one fin, and performing an anneal operation, wherein the anneal operation anneals the dielectric layer and either the source region or the drain region, and wherein the work function layer provides a protection function to the at least a portion of the dielectric layer during the anneal operation.
- Embodiments are further directed to a FinFET device having at least one fin, a dielectric layer over at least a portion of the at least one fin, and a source region or a drain region adjacent the at least one fin, wherein, during a fabrication of the device, one anneal operation annealed the dielectric layer and the source region or the drain region.
- FIG. 1A depicts a three-dimensional view of an exemplary configuration of a known FinFET device
- FIG. 1B depicts a cross sectional view of a known final gate structure
- FIG. 1C depicts a cross sectional view of another known final gate structure
- FIG. 2 depicts a semiconductor substrate, a bulk semiconductor material and a hard mask layer after an initial fabrication stage according to one or more embodiments
- FIG. 3 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments
- FIG. 4 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments
- FIG. 5 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments
- FIG. 6 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments
- FIG. 7 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments
- FIG. 8 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments
- FIG. 9 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments.
- FIG. 10 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments
- FIG. 11 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments
- FIG. 12 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments
- FIG. 13A depicts a cross sectional view of a final gate structure according to one or more embodiments
- FIG. 13B depicts a cross sectional view of a final gate structure according to one or more embodiments.
- FIG. 14 is a flow diagram illustrating a methodology according to one or more embodiments.
- replacing the silicon dioxide gate dielectric with another material adds complexity to the manufacturing process.
- implementing the gate dielectric based on high-k oxides of hafnium requires the poly-silicon gate material to be replaced with a metal that interfaces better with the high-k dielectric. Accordingly, the poly-silicon gate must be etched out and replaced with metal.
- the metal-gate may be formed before or after the source and drain regions. Forming the metal gate last (i.e., after formation of the source and drain regions) is known generally as a replacement metal gate (RMG) process flow.
- RMG replacement metal gate
- FIGS. 1B and 1C depict cross sectional views of known final (i.e., post fabrication) configurations for gate 114 shown in FIG. 1A .
- FIG. 1B depicts an n-type FET gate 114 A configuration
- FIG. 1B depicts a p-type FET gate 114 B configuration.
- the final gate includes independently optimized complex stacks of thin work-function metals of tungsten (W), titanium nitride (TiN) and titanium carbide (TiC), along with high-k dielectric layers 122 , 122 A.
- CMOS gate configurations 114 A, 114 B form high-k dielectric layers 122 , 122 A later in the fabrication process, typically after the POC (poly-silicon open CMP) process and before the gate last, RMG process.
- the RMG process applied to the gate configurations 114 A, 114 B shown in FIGS. 1B and 1C includes the formation of a dummy gate structure (not shown in FIGS. 1B and 1C ) used to self-align the source and drain implant and anneals. The dummy gate materials are then stripped out and replaced with the high-k dielectric and metal gate materials.
- a typical fabrication process flow used to form gate configurations 114 A, 114 B includes multiple anneal operations, including a high-k PDA, a high temperature source drain “activation” anneal applied to the doped source and drain regions to activate these regions, and a subsequent high temperature “reliability” anneal operation applied to high-k dielectric layers 122 , 122 A to improve the reliability of these layers.
- high-k dielectric layers 122 , 122 A extend horizontally substantially along elongated surfaces of sidewalls 130 , 130 A of gates 114 A, 114 B, which reduces the total volume of the metal gate materials (e.g., W, TiN, TiC, etc.) that can be formed in the gate region between sidewalls 130 , 130 A.
- the metal gate materials e.g., W, TiN, TiC, etc.
- one or more embodiments provide a fabrication process flow and resulting device structure of a fin-type field effect transistor (FinFET) that uses a novel “high-k p-type work function metal first” fabrication process that improves the efficiency of source/drain activation annealing and reliability annealing, and also improves the total width (e.g., width 1324 shown in FIGS. 13A and 13B ) available for formation of the metal gate materials (e.g., W, TiN, etc.) in the gate region.
- the metal gate materials e.g., W, TiN, etc.
- one or more disclosed embodiments form the high-k dielectric layer “first,” which for a FinFET device means that the high-k dielectric layer is formed before formation of the source drain regions.
- a work-function metal layer e.g., a cap TiN layer of from about 10 to about 50 Angstroms ( ⁇ ) in thickness
- ⁇ Angstroms
- the high temperature annealing of both the high-k dielectric layer and the source drain regions can performed as a single annealing operation. Additionally, because a work-function metal layer is in place over the high-k dielectric layer when the source drain regions are formed, the work-function metal protects the high-k dielectric layer during the high temperature annealing of both the high-k dielectric layer and the source drain regions. Further, forming the high-k dielectric layer “first” allows the area occupied by the high-k dielectric layer to be controlled such that the high-k dielectric material does not extend along the sidewalls of the gate structure, which leave more volume between the sidewalls for the formation of the final metal gate structure. Increasing the available volume between the sidewalls for forming the gate structure results in a lower resistance of the resulting gate structure.
- FIG. 2 an initial structure is formed having semiconductor substrate 202 , a bulk semiconductor material 204 and a hard mask layer 206 , configured and arranged as shown. It is noted that bulk semiconductor material 204 and semiconductor substrate 202 may be substantially the same material. Hard mask layer 206 may be a silicon nitride material (e.g., Si 3 N 4 ). In FIG. 3 , a patterned resist 302 is added over hard mask layer 206 to pattern and form fins 402 (shown in FIG. 4 ) from bulk semiconductor 204 .
- a patterned resist 302 is added over hard mask layer 206 to pattern and form fins 402 (shown in FIG. 4 ) from bulk semiconductor 204 .
- Fins 402 may be formed by applying an anisotropic etch process, which results in the structure shown in FIG. 4 . Because there is no stop layer on semiconductor substrate 202 , the etch process is time based. Bulk semiconductor 204 may also be implemented as a silicon-on-insulator (SOI) structure, wherein a buried oxide (BOX) layer of the SOI would act as an etch stop.
- SOI silicon-on-insulator
- BOX buried oxide
- FIG. 5 a local oxide (e.g., SiO 2 ) is deposited between fins 402 and over substrate 202 . For ease of illustration, only one fin is labeled with a reference number. As shown in FIGS. 6 and 7 , the local oxide is polished and recessed back to form local STI regions 606 , and to expose upper portions of fins 402 . Again, for ease of illustration, only one local STI region is labeled with a reference number.
- an interfacial/high-k dielectric layer 804 and a TiN layer 802 are deposited over fins 402 and STI 606 .
- TiN layer 802 will form part of the work-function layers of the ultimate metal gate structure.
- TiN layer 802 and a poly-silicon gate/PC layer 902 (shown in FIG. 9A ) provide protection for interfacial/high-k dielectric layer 804 and prevent re-growth of interfacial/high-k dielectric layer 804 during subsequent high temperature anneal operations.
- Interfacial/high-k layer 804 is deposited, followed by a nitridation and a PDA at approximately 700 degrees Celsius for approximately 30 seconds, followed by deposition of a cap TiN layer 802 of from about 10 to about 50 Angstroms ( ⁇ ) in thickness.
- interfacial/high-k layer 804 and TiN layer 802 are formed after fin formation and before the PC module (i.e., gate module) formation, the spacer and epitaxial source/drain formation, and the POC process.
- interfacial/high-k layer is formed after the PC module formation, the spacer and epitaxial source/drain formation, and the POC process, and wherein the work-function layers are all formed as part of the RMG process.
- FIG. 10 depicts a cross sectional view of the FinFET device after a subsequent fabrication stage, wherein the device has been rotated by 90 degrees such that fins 402 extend through and between poly-silicon gate/PC layers 902 .
- FIG. 10 depicts a cross sectional view of the FinFET device after a subsequent fabrication stage, wherein the device has been rotated by 90 degrees such that fins 402 extend through and between poly-silicon gate/PC layers 902 .
- FIG. 10 depicts the FinFET device after a fabrication stage wherein fins 402 , interfacial/high-k layers 804 and TiN layers 802 have been recessed in the areas not covered by poly-silicon gate/PC layers 902 , and the only remaining portions of fins 402 , interfacial/high-k layers 804 and TiN layers 802 are the portions of fins 402 that form the channel regions, along with the portions of interfacial/high-k layers 804 and TiN layers 802 that cover the fin channel regions.
- the fin channel regions, interfacial/high-k layers 804 and TiN layers 802 are surrounded by poly-silicon gate/PC layers 902 and are not visible in FIG. 10 .
- Offset spacers 1002 are formed along the sidewalls of poly-silicon gate/PC layers 902 , as shown. Offset spacers 1002 may be formed using a spacer pull down formation process. Offset spacers 1002 may also be formed using a sidewall image transfer (SIT) spacer formation process, which includes spacer material deposition followed by directional RIE of the deposited spacer material.
- SIT sidewall image transfer
- raised source drain (RSD) regions 1102 are deposited using an epitaxial layer deposition process. RSD regions 1102 may be suitably doped to produce the desired FET polarity.
- a high temperature anneal e.g., from about 1000 to about 1025 degrees Celsius
- the high temperature anneal may be a spike anneal lasting less than about 1 second.
- the interfacial/high-k dielectric layers 804 shown in FIGS.
- the high temperature annealing of both the interfacial/high-k dielectric layers 804 and RSD regions 1102 can performed as a single annealing operation. Additionally, because TiN layers 802 , which will subsequently function as work-function metal layer, are in place over interfacial/high-k layers 804 when RSD regions 1102 are formed, TiN layers 802 protect interfacial/high-k layers 804 during the high temperature annealing of both interfacial/high-k dielectric layers 804 and RSD regions 1102 .
- interfacial/high-k dielectric layers 804 and TiN layers 802 “first” allows the area occupied by interfacial/high-k dielectric layer 804 to be controlled such that interfacial/high-k dielectric layers 804 do not extend along the offset spacers 1002 of the gate structure, which leaves more volume for the formation of the final metal gate structure. Increasing the available volume for forming the metal gate structure results in a lower resistance of the resulting gate structure.
- FIG. 12 depicts a stage of the fabrication process flow after the poly open CMP (POC) process but before the metal gate deposition.
- poly-silicon gate/PC layers 902 comprise a dummy gate structure that may be removed and replaced with a metal gate (e.g., shown in FIGS. 13A and 13B ).
- Poly-silicon gate/PC layers 902 can be removed by an etching process, e.g., RIE or chemical oxide removal (COR), to form a trench.
- a gate metal (not shown in FIG. 12 ) can subsequently be deposited within the trench.
- a metal liner e.g., a work-function metal, and a gate metal can then be deposited on the high-k dielectric material to complete the gate formation.
- the metal liner can be, for example, TiN or TaN, and the gate metal can be aluminum or tungsten.
- a silicon dielectric 1204 is deposited over RSD regions 1102 .
- FIGS. 13A and 13B depict cross sectional views of final (i.e., post fabrication) configurations of gates 1320 , 1320 A that would result from implementation of one or more embodiments of the high-k p-type work-function metal first fabrication process flow of the present disclosure.
- FIG. 13A depicts an n-type FET gate 1320 configuration
- FIG. 13B depicts a p-type FET gate 1320 A configuration.
- the final gate includes independently optimized complex stacks of thin work-function metals of tungsten (W), titanium nitride (TiN) and titanium carbide (TiC), along with high-k dielectric layers 1322 , 1322 A.
- one or more disclosed embodiments form the high-k dielectric layer and a TiN work-function layer “first,” which for a FinFET device means that the high-k dielectric layers 1322 , 1322 A and TiN work-function layer (shown for the pFET gate configuration 1320 A in FIG. 13B ) are formed before formation of the source drain regions.
- the TiN layer has been etched away in the final gate configuration.
- the high temperature annealing operation of both the high-k dielectric layers 1322 , 1322 A and the source drain regions can be performed as a single annealing operation.
- TiN layer which in the final gate configuration functions as part of the work-function metal layers, is in place over high-k layers 1322 , 1322 A when RSD regions 1102 (shown in FIGS. 11 and 12 ) are formed, TiN layer protects high-k layers 1322 , 1322 A during the high temperature annealing of both high-k dielectric layer 1322 , 1322 A and RSD regions 1102 .
- forming the high-k dielectric layer and TiN work-function layer “first” allows the area or volume occupied by the high-k dielectric layers 1322 , 1322 A to be controlled such that the high-k dielectric material does not extend substantially along elongated surfaces of sidewalls 1330 , 1330 A of the gate structure, which leaves more volume for the formation of the final metal gate structure. Increasing the available volume for forming the gate structure results in a lower resistance of the resulting gate structure.
- the elongated surfaces of sidewalls 1330 , 1330 A extend for a dimension that is significantly more than a width dimension of sidewalls 1330 , 1330 A.
- FIG. 13B includes an additional legend showing an x-y axis of the cross-sectional view of gate configurations 1320 , 1320 A shown in FIGS. 13A and 13B , which may be used to further illustrate that high-k dielectric layers 1322 , 1322 A do not extend substantially along an elongated surface of sidewalls 1330 , 1330 A.
- This legend also applies to gate configurations 114 A, 114 B shown in FIGS. 1B and 1C .
- high-k dielectric layers 1322 , 1322 A extend substantially along an x direction of gate configurations 1320 , 1320 A but do not extend substantially along a y direction of gate configurations 1320 , 1320 A.
- the prior art gate configurations 114 A, 114 B include high-k dielectric layers 122 , 122 A that extend substantially along an x direction of gate configurations 114 A, 114 B and substantially along a y direction of gate configurations 114 A, 114 B.
- FIG. 14 is a flow diagram illustrating a methodology 1400 according to one or more embodiments.
- methodology 1400 is illustrated in a particular order, it will be understood by persons of ordinary skill in the relevant art that the order of the illustrated operations may be changed without departing from the teachings of the present disclosure.
- one or more of the illustrated operations may be omitted, and/or operations not shown (e.g., routine intermediary operations) may be incorporated, without departing from the teachings of the present disclosure.
- methodology 1400 begins at block 1402 by forming at least one fin.
- Block 1404 forms a dielectric layer (e.g., a high-k dielectric) over at least a portion of the at least one fin.
- the dielectric layer may include an interfacial layer.
- Block 1404 may include a post deposition anneal operation, which may be performed at approximately 700 degrees Celsius for approximately 30 seconds.
- Block 1405 deposits a work-function metal layer (e.g., a cap TiN layer of from about 10 to about 50 Angstroms ( ⁇ ) in thickness) over the high-k dielectric layer.
- Block 1406 forms a dummy gate/PC over the dielectric layer, and block 1408 forms spacer sidewalls along the dummy gate/PC.
- Block 1410 forms the source/drain regions and performs an anneal operation.
- the anneal operation is a high temperature anneal, which includes a temperature above about 1000 Celsius.
- the anneal operation may be a spike anneal operation that lasts less than approximately 1 second.
- the high temperature anneal operation anneals both the high-k dielectric layer and the source/drain regions in a single, spike annealing operation.
- the work-function metal layer protects the dielectric layer during the high temperature annealing of both the dielectric layer and the source/drain regions. Further, forming high-k dielectric layer and at least one of the work-function layers “first” allows the area occupied by high-k dielectric layer 804 to be controlled such that the high-k dielectric layer does not extend substantially along an elongated surface of the spacers that define the gate structure, wherein more volume is available for the formation of the final metal gate structure. Increasing the available volume for forming the gate structure results in a lower resistance of the resulting gate structure.
- Block 1412 performs a POC process to remove the poly-silicon dummy gate/PC, and block 1414 performs a known RMG process that replaces the poly-silicon dummy gate/PC with a metal gate.
- the high temperature anneals are combined into a single anneal and performed at some point in the process after the high-k dielectric layer has been deposited and the source drain regions have been formed, and the other fabrication steps shown in FIG. 14 may be performed in any order.
- embodiments of the present disclosure provide structures and methodologies for forming a high-k dielectric region of a FinFET device having improved reliability annealing and source drain activation annealing.
- one or more embodiments provide a fabrication process flow and resulting device structure of a fin-type field effect transistor (FinFET) that uses a novel “high-k p-type work-function first” fabrication process that improves the efficiency of source/drain activation annealing and reliability annealing, and also increases the total volume available for formation of the replacement metal gate in the gate region.
- FinFET fin-type field effect transistor
- one or more disclosed embodiments form the high-k dielectric layer and at least one of the work-function layers “first,” which for a FinFET device means that the high-k dielectric layer and at least one of the work-function layers are formed before formation of the source drain regions. Because the high-k dielectric layer and at least one of the work-function layers are already in place when the source drain regions are formed, the high temperature annealing of both the high-k dielectric layer and the source drain regions can performed as a single annealing operation.
- forming the high-k dielectric layer “first” allows the area occupied by the high-k dielectric layer to be controlled such that the high-k dielectric material does not extend along the sidewalls of the gate structure, which leave more volume for the formation of the final metal gate structure. Increasing the available volume for forming the gate structure results in a lower resistance of the resulting gate structure.
- the method as described above is used in the fabrication of integrated circuit chips.
- the resulting integrated circuit chips can be distributed by the fabricator in raw wafer form (that is, as a single wafer that has multiple unpackaged chips), as a bare die, or in a packaged form.
- the chip is mounted in a single chip package (such as a plastic carrier, with leads that are affixed to a motherboard or other higher level carrier) or in a multichip package (such as a ceramic carrier that has either or both surface interconnections or buried interconnections).
- the chip is then integrated with other chips, discrete circuit elements, and/or other signal processing devices as part of either (a) an intermediate product, such as a motherboard, or (b) an end product.
- the end product can be any product that includes integrated circuit chips, ranging from toys and other low-end applications to advanced computer products having a display, a keyboard or other input device, and a central processor.
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Computer Hardware Design (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
- Thin Film Transistor (AREA)
Abstract
Description
- The present disclosure relates in general to semiconductor device structures and their fabrication. More specifically, the present disclosure relates to the fabrication of a fin-type field effect transistor (FinFET) using a high-k and p-type work function metal first fabrication process that improves, inter alia, source/drain activation annealing and dielectric reliability annealing.
- Typical semiconductor devices are formed using active regions of a wafer. The active regions are defined by isolation regions used to separate and electrically isolate adjacent semiconductor devices. For example, in an integrated circuit having a plurality of metal oxide semiconductor field effect transistors (MOSFETs), each MOSFET has a source and a drain that are formed in an active region of a semiconductor layer by implanting n-type or p-type impurities in the layer of semiconductor material. Disposed between the source and the drain is a channel (or body) region. Disposed above the body region is a gate electrode. The gate electrode and the body are spaced apart by a gate dielectric layer.
- One particularly advantageous type of MOSFET is known generally as a fin-type field effect transistor (FinFET).
FIG. 1A depicts a three-dimensional view of an exemplary FinFET 100, which includes a shallow trench isolation (STI)region 104 for isolation of active areas from one another. The basic electrical layout and mode of operation of FinFET 100 do not differ significantly from a traditional field effect transistor. FinFET 100 includes asemiconductor substrate 102,local STI region 104, afin 106, and agate 114 having a gate oxide layer (not shown) between the gate and the fin, configured and arranged as shown. Fin 106 includes asource region 108, adrain region 110 and a channel region 112, whereingate 114 extends over the top and sides of channel region 112. For ease of illustration, a single fin is shown inFIG. 1 . In practice, FinFET devices are fabricated having multiple fins formed onlocal STI region 104 andsubstrate 102.Substrate 102 may be silicon, andlocal STI region 104 may be an oxide (e.g., SiO2). Fin 106 may be silicon.Gate 114 controls the source to drain current flow (labeled ELECTRICITY FLOW inFIG. 1 ). In contrast to a planar MOSFET, however,source 108,drain 110 and channel 112 are built as a three-dimensional bar on top oflocal STI region 104 andsemiconductor substrate 102. The three-dimensional bar is the aforementioned “fin 106,” which serves as the body of the device. The gate electrode is then wrapped over the top and sides of the fin, and the portion of the fin that is under the gate electrode functions as the channel. The source and drain regions are the portions of the fin on either side of the channel that are not under the gate electrode. The source and drain regions may be suitably doped to produce the desired FET polarity, as is known in the art. The dimensions of the fin establish the effective channel length for the transistor. - Transistors have been made with silicon dioxide gate dielectrics and poly-silicon gate conductors for decades. However, as transistors have decreased in size, gate dielectric thickness has scaled below 2 nanometers, which increases tunneling leakage currents and power consumption and reduces device reliability. Replacing the silicon dioxide gate dielectric with a high-k material having a high dielectric constant (k) in comparison to silicon dioxide allows increases gate capacitance without the associated leakage effects. Suitable high-k materials include hafnium silicate, zirconium silicate, hafnium dioxide and zirconium dioxide, typically deposited using atomic layer deposition.
- Replacing the silicon dioxide gate dielectric with another material adds complexity to the fabrication process. For example, implementing the gate dielectric based on high-k oxides of hafnium requires the poly-silicon gate material to be replaced with a metal that interfaces better with the high-k dielectric. Accordingly, the poly-silicon gate must be etched out and replaced with metal. The metal-gate may be formed before or after the source and drain regions. Forming the metal gate last (i.e., after formation of the source and drain regions) is known generally as a replacement metal gate (RMG) process flow.
- Known process flows for the metal gate formation involves independently optimized complex stacks of thin work-function metals topped by a bulk conductor layer. Additionally, a typical fabrication process flow includes multiple annealing operations, including, for example, a high-k post-deposition anneal (PDA), a high temperature anneal applied to the high-k dielectric to improve reliability, and a high temperature source drain anneal applied to the doped source and drain regions to activate these regions.
- Embodiments are directed to a method of forming portions of a fin-type field effect transistor (FinFET). The method includes forming at least one fin, and forming a dielectric layer over at least a portion of the at least one fin. The method further includes forming a work-function layer over at least a portion of the dielectric layer. The method further includes forming a source region or a drain region adjacent the at least one fin, and performing an anneal operation, wherein the anneal operation anneals the dielectric layer and either the source region or the drain region, and wherein the work function layer provides a protection function to the at least a portion of the dielectric layer during the anneal operation.
- Embodiments are further directed to a FinFET device having at least one fin, a dielectric layer over at least a portion of the at least one fin, and a source region or a drain region adjacent the at least one fin, wherein, during a fabrication of the device, one anneal operation annealed the dielectric layer and the source region or the drain region.
- Additional features and advantages are realized through techniques described herein. Other embodiments and aspects are described in detail herein. For a better understanding, refer to the description and to the drawings.
- The subject matter which is regarded as embodiments is particularly pointed out and distinctly claimed in the claims at the conclusion of the specification. The foregoing and other features and advantages of the embodiments are apparent from the following detailed description taken in conjunction with the accompanying drawings in which:
-
FIG. 1A depicts a three-dimensional view of an exemplary configuration of a known FinFET device; -
FIG. 1B depicts a cross sectional view of a known final gate structure; -
FIG. 1C depicts a cross sectional view of another known final gate structure; -
FIG. 2 depicts a semiconductor substrate, a bulk semiconductor material and a hard mask layer after an initial fabrication stage according to one or more embodiments; -
FIG. 3 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments; -
FIG. 4 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments; -
FIG. 5 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments; -
FIG. 6 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments; -
FIG. 7 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments; -
FIG. 8 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments; -
FIG. 9 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments; -
FIG. 10 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments; -
FIG. 11 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments; -
FIG. 12 depicts a cross sectional view of a semiconductor device after an intermediate fabrication stage according to one or more embodiments; -
FIG. 13A depicts a cross sectional view of a final gate structure according to one or more embodiments; -
FIG. 13B depicts a cross sectional view of a final gate structure according to one or more embodiments; and -
FIG. 14 is a flow diagram illustrating a methodology according to one or more embodiments. - It is understood in advance that although this disclosure includes a detailed description of an exemplary FinFET configuration, implementation of the teachings recited herein are not limited to the particular FinFET structure disclosed herein. Rather, embodiments of the present disclosure are capable of being implemented in conjunction with any other type of fin-based transistor device now known or later developed.
- For the sake of brevity, conventional techniques related to FinFET semiconductor device fabrication may not be described in detail herein. Moreover, the various tasks and process steps described herein may be incorporated into a more comprehensive procedure or process having additional steps or functionality not descried in detail herein. In particular, various steps in the manufacture of semiconductor based transistors are well known and so, in the interest of brevity, many conventional steps will only be mentioned briefly herein or will be omitted entirely without providing the well-known process details.
- As previously noted herein, replacing the silicon dioxide gate dielectric with another material adds complexity to the manufacturing process. For example, implementing the gate dielectric based on high-k oxides of hafnium requires the poly-silicon gate material to be replaced with a metal that interfaces better with the high-k dielectric. Accordingly, the poly-silicon gate must be etched out and replaced with metal. The metal-gate may be formed before or after the source and drain regions. Forming the metal gate last (i.e., after formation of the source and drain regions) is known generally as a replacement metal gate (RMG) process flow.
-
FIGS. 1B and 1C depict cross sectional views of known final (i.e., post fabrication) configurations forgate 114 shown inFIG. 1A .FIG. 1B depicts an n-type FET gate 114A configuration, andFIG. 1B depicts a p-type FET gate 114B configuration. In either configuration, the final gate includes independently optimized complex stacks of thin work-function metals of tungsten (W), titanium nitride (TiN) and titanium carbide (TiC), along with high-k dielectric layers 122, 122A. Known process flows for fabricatinggate configurations gate configurations FIGS. 1B and 1C includes the formation of a dummy gate structure (not shown inFIGS. 1B and 1C ) used to self-align the source and drain implant and anneals. The dummy gate materials are then stripped out and replaced with the high-k dielectric and metal gate materials. - A typical fabrication process flow used to form
gate configurations sidewalls gates sidewalls - Turning now to an overview of the present disclosure, one or more embodiments provide a fabrication process flow and resulting device structure of a fin-type field effect transistor (FinFET) that uses a novel “high-k p-type work function metal first” fabrication process that improves the efficiency of source/drain activation annealing and reliability annealing, and also improves the total width (e.g.,
width 1324 shown inFIGS. 13A and 13B ) available for formation of the metal gate materials (e.g., W, TiN, etc.) in the gate region. More specifically, instead of forming a high-k dielectric layer later in the fabrication process flow, one or more disclosed embodiments form the high-k dielectric layer “first,” which for a FinFET device means that the high-k dielectric layer is formed before formation of the source drain regions. Additionally, instead of forming all work-function metal gate layers later in the process flow (e.g., during the RMG process) a work-function metal layer (e.g., a cap TiN layer of from about 10 to about 50 Angstroms (Å) in thickness) is deposited over the high-k dielectric layer. Because the high-k dielectric layer is already in place when the source drain regions are formed, the high temperature annealing of both the high-k dielectric layer and the source drain regions can performed as a single annealing operation. Additionally, because a work-function metal layer is in place over the high-k dielectric layer when the source drain regions are formed, the work-function metal protects the high-k dielectric layer during the high temperature annealing of both the high-k dielectric layer and the source drain regions. Further, forming the high-k dielectric layer “first” allows the area occupied by the high-k dielectric layer to be controlled such that the high-k dielectric material does not extend along the sidewalls of the gate structure, which leave more volume between the sidewalls for the formation of the final metal gate structure. Increasing the available volume between the sidewalls for forming the gate structure results in a lower resistance of the resulting gate structure. - A fabrication methodology for forming various stages of a FinFET semiconductor device in accordance with one or more embodiments of the present disclosure will now be described with reference to
FIGS. 2-12 . Referring now toFIG. 2 , an initial structure is formed havingsemiconductor substrate 202, abulk semiconductor material 204 and ahard mask layer 206, configured and arranged as shown. It is noted thatbulk semiconductor material 204 andsemiconductor substrate 202 may be substantially the same material.Hard mask layer 206 may be a silicon nitride material (e.g., Si3N4). InFIG. 3 , a patterned resist 302 is added overhard mask layer 206 to pattern and form fins 402 (shown inFIG. 4 ) frombulk semiconductor 204.Fins 402 may be formed by applying an anisotropic etch process, which results in the structure shown inFIG. 4 . Because there is no stop layer onsemiconductor substrate 202, the etch process is time based.Bulk semiconductor 204 may also be implemented as a silicon-on-insulator (SOI) structure, wherein a buried oxide (BOX) layer of the SOI would act as an etch stop. InFIG. 5 , a local oxide (e.g., SiO2) is deposited betweenfins 402 and oversubstrate 202. For ease of illustration, only one fin is labeled with a reference number. As shown inFIGS. 6 and 7 , the local oxide is polished and recessed back to formlocal STI regions 606, and to expose upper portions offins 402. Again, for ease of illustration, only one local STI region is labeled with a reference number. - In
FIG. 8 , an interfacial/high-k dielectric layer 804 and aTiN layer 802 are deposited overfins 402 andSTI 606. For p-type configurations of the present disclosure (e.g., as shown inFIG. 13B and described in greater detail herein below)TiN layer 802 will form part of the work-function layers of the ultimate metal gate structure.TiN layer 802 and a poly-silicon gate/PC layer 902 (shown inFIG. 9A ) provide protection for interfacial/high-k dielectric layer 804 and prevent re-growth of interfacial/high-k dielectric layer 804 during subsequent high temperature anneal operations. Interfacial/high-k layer 804 is deposited, followed by a nitridation and a PDA at approximately 700 degrees Celsius for approximately 30 seconds, followed by deposition of acap TiN layer 802 of from about 10 to about 50 Angstroms (Å) in thickness. In accordance with one or more embodiments, interfacial/high-k layer 804 andTiN layer 802 are formed after fin formation and before the PC module (i.e., gate module) formation, the spacer and epitaxial source/drain formation, and the POC process. This is in contrast to known fabrication methodologies, wherein the interfacial/high-k layer is formed after the PC module formation, the spacer and epitaxial source/drain formation, and the POC process, and wherein the work-function layers are all formed as part of the RMG process. - As shown in
FIG. 9 , poly-silicon gate/PC layers 902 and nitridedhard masks 904 are deposited over TiN layers 802.FIG. 10 depicts a cross sectional view of the FinFET device after a subsequent fabrication stage, wherein the device has been rotated by 90 degrees such thatfins 402 extend through and between poly-silicon gate/PC layers 902.FIG. 10 depicts the FinFET device after a fabrication stage whereinfins 402, interfacial/high-k layers 804 and TiN layers 802 have been recessed in the areas not covered by poly-silicon gate/PC layers 902, and the only remaining portions offins 402, interfacial/high-k layers 804 and TiN layers 802 are the portions offins 402 that form the channel regions, along with the portions of interfacial/high-k layers 804 and TiN layers 802 that cover the fin channel regions. The fin channel regions, interfacial/high-k layers 804 and TiN layers 802 are surrounded by poly-silicon gate/PC layers 902 and are not visible inFIG. 10 . Offsetspacers 1002 are formed along the sidewalls of poly-silicon gate/PC layers 902, as shown. Offsetspacers 1002 may be formed using a spacer pull down formation process. Offsetspacers 1002 may also be formed using a sidewall image transfer (SIT) spacer formation process, which includes spacer material deposition followed by directional RIE of the deposited spacer material. - As shown in
FIG. 11 , raised source drain (RSD)regions 1102 are deposited using an epitaxial layer deposition process.RSD regions 1102 may be suitably doped to produce the desired FET polarity. A high temperature anneal (e.g., from about 1000 to about 1025 degrees Celsius) is now applied. The high temperature anneal may be a spike anneal lasting less than about 1 second. In accordance with one or more embodiments of the present disclosure, because the interfacial/high-k dielectric layers 804 (shown inFIGS. 8 and 9 ) are already in place whenRSD regions 1102 are formed, the high temperature annealing of both the interfacial/high-k dielectric layers 804 andRSD regions 1102 can performed as a single annealing operation. Additionally, because TiN layers 802, which will subsequently function as work-function metal layer, are in place over interfacial/high-k layers 804 whenRSD regions 1102 are formed, TiN layers 802 protect interfacial/high-k layers 804 during the high temperature annealing of both interfacial/high-k dielectric layers 804 andRSD regions 1102. Further, forming interfacial/high-k dielectric layers 804 and TiN layers 802 “first” allows the area occupied by interfacial/high-k dielectric layer 804 to be controlled such that interfacial/high-k dielectric layers 804 do not extend along the offsetspacers 1002 of the gate structure, which leaves more volume for the formation of the final metal gate structure. Increasing the available volume for forming the metal gate structure results in a lower resistance of the resulting gate structure. -
FIG. 12 depicts a stage of the fabrication process flow after the poly open CMP (POC) process but before the metal gate deposition. In a gate-last fabrication process, poly-silicon gate/PC layers 902 comprise a dummy gate structure that may be removed and replaced with a metal gate (e.g., shown inFIGS. 13A and 13B ). Poly-silicon gate/PC layers 902 can be removed by an etching process, e.g., RIE or chemical oxide removal (COR), to form a trench. A gate metal (not shown inFIG. 12 ) can subsequently be deposited within the trench. More specifically, a metal liner, e.g., a work-function metal, and a gate metal can then be deposited on the high-k dielectric material to complete the gate formation. In one or more embodiments, the metal liner can be, for example, TiN or TaN, and the gate metal can be aluminum or tungsten. Asilicon dielectric 1204 is deposited overRSD regions 1102. -
FIGS. 13A and 13B depict cross sectional views of final (i.e., post fabrication) configurations ofgates FIG. 13A depicts an n-type FET gate 1320 configuration, andFIG. 13B depicts a p-type FET gate 1320A configuration. In either configuration, the final gate includes independently optimized complex stacks of thin work-function metals of tungsten (W), titanium nitride (TiN) and titanium carbide (TiC), along with high-k dielectric layers gates k dielectric layers pFET gate configuration 1320A inFIG. 13B ) are formed before formation of the source drain regions. For thenFET gate configuration 1324 shown inFIG. 13A , the TiN layer has been etched away in the final gate configuration. Because the high-k dielectric layers k dielectric layers k layers FIGS. 11 and 12 ) are formed, TiN layer protects high-k layers k dielectric layer RSD regions 1102. Additionally, forming the high-k dielectric layer and TiN work-function layer “first” allows the area or volume occupied by the high-k dielectric layers sidewalls sidewalls -
FIG. 13B includes an additional legend showing an x-y axis of the cross-sectional view ofgate configurations FIGS. 13A and 13B , which may be used to further illustrate that high-k dielectric layers sidewalls gate configurations FIGS. 1B and 1C . As illustrated, high-k dielectric layers gate configurations gate configurations art gate configurations gate configurations gate configurations -
FIG. 14 is a flow diagram illustrating amethodology 1400 according to one or more embodiments. Although the operations ofmethodology 1400 are illustrated in a particular order, it will be understood by persons of ordinary skill in the relevant art that the order of the illustrated operations may be changed without departing from the teachings of the present disclosure. In addition, it will be understood by persons of ordinary skill in the relevant art that one or more of the illustrated operations may be omitted, and/or operations not shown (e.g., routine intermediary operations) may be incorporated, without departing from the teachings of the present disclosure. - As shown in
FIG. 14 ,methodology 1400 begins atblock 1402 by forming at least one fin.Block 1404 forms a dielectric layer (e.g., a high-k dielectric) over at least a portion of the at least one fin. The dielectric layer may include an interfacial layer.Block 1404 may include a post deposition anneal operation, which may be performed at approximately 700 degrees Celsius for approximately 30 seconds.Block 1405 deposits a work-function metal layer (e.g., a cap TiN layer of from about 10 to about 50 Angstroms (Å) in thickness) over the high-k dielectric layer.Block 1406 forms a dummy gate/PC over the dielectric layer, and block 1408 forms spacer sidewalls along the dummy gate/PC.Block 1410 forms the source/drain regions and performs an anneal operation. The anneal operation is a high temperature anneal, which includes a temperature above about 1000 Celsius. The anneal operation may be a spike anneal operation that lasts less than approximately 1 second. In accordance with one or more embodiments of the present disclosure, because the high-k dielectric layer is already in place when the source/drain regions are formed, the high temperature anneal operation anneals both the high-k dielectric layer and the source/drain regions in a single, spike annealing operation. Additionally, because the work-function metal layers are is in place over the dielectric layer when the source/drain regions are formed, the work-function metal layer protects the dielectric layer during the high temperature annealing of both the dielectric layer and the source/drain regions. Further, forming high-k dielectric layer and at least one of the work-function layers “first” allows the area occupied by high-k dielectric layer 804 to be controlled such that the high-k dielectric layer does not extend substantially along an elongated surface of the spacers that define the gate structure, wherein more volume is available for the formation of the final metal gate structure. Increasing the available volume for forming the gate structure results in a lower resistance of the resulting gate structure.Block 1412 performs a POC process to remove the poly-silicon dummy gate/PC, andblock 1414 performs a known RMG process that replaces the poly-silicon dummy gate/PC with a metal gate. - In an alternative embodiment, the high temperature anneals are combined into a single anneal and performed at some point in the process after the high-k dielectric layer has been deposited and the source drain regions have been formed, and the other fabrication steps shown in
FIG. 14 may be performed in any order. - Thus, it can be seen from the forgoing detailed description and accompanying illustrations that embodiments of the present disclosure provide structures and methodologies for forming a high-k dielectric region of a FinFET device having improved reliability annealing and source drain activation annealing. As described above, one or more embodiments provide a fabrication process flow and resulting device structure of a fin-type field effect transistor (FinFET) that uses a novel “high-k p-type work-function first” fabrication process that improves the efficiency of source/drain activation annealing and reliability annealing, and also increases the total volume available for formation of the replacement metal gate in the gate region. More specifically, instead of forming a high-k dielectric layer and at least one of the work-function layers later in the fabrication process flow, one or more disclosed embodiments form the high-k dielectric layer and at least one of the work-function layers “first,” which for a FinFET device means that the high-k dielectric layer and at least one of the work-function layers are formed before formation of the source drain regions. Because the high-k dielectric layer and at least one of the work-function layers are already in place when the source drain regions are formed, the high temperature annealing of both the high-k dielectric layer and the source drain regions can performed as a single annealing operation. Additionally, forming the high-k dielectric layer “first” allows the area occupied by the high-k dielectric layer to be controlled such that the high-k dielectric material does not extend along the sidewalls of the gate structure, which leave more volume for the formation of the final metal gate structure. Increasing the available volume for forming the gate structure results in a lower resistance of the resulting gate structure.
- The method as described above is used in the fabrication of integrated circuit chips. The resulting integrated circuit chips can be distributed by the fabricator in raw wafer form (that is, as a single wafer that has multiple unpackaged chips), as a bare die, or in a packaged form. In the latter case the chip is mounted in a single chip package (such as a plastic carrier, with leads that are affixed to a motherboard or other higher level carrier) or in a multichip package (such as a ceramic carrier that has either or both surface interconnections or buried interconnections). In any case the chip is then integrated with other chips, discrete circuit elements, and/or other signal processing devices as part of either (a) an intermediate product, such as a motherboard, or (b) an end product. The end product can be any product that includes integrated circuit chips, ranging from toys and other low-end applications to advanced computer products having a display, a keyboard or other input device, and a central processor.
- The descriptions of the various embodiments of the present disclosure have been presented for purposes of illustration, but are not intended to be exhaustive or limited to the embodiments disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the described embodiments. The terminology used herein was chosen to best explain the principles of the embodiments, the practical application or technical improvement over technologies found in the marketplace, or to enable others of ordinary skill in the art to understand the embodiments disclosed herein. As used herein, the singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, element components, and/or groups thereof.
- The corresponding structures, materials, acts, and equivalents of all means or step plus function elements in the claims below are intended to include any structure, material, or act for performing the function in combination with other claimed elements as specifically claimed. The description of the present disclosure has been presented for purposes of illustration and description, but is not intended to be exhaustive or limited to the disclosure in the form disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the disclosure. The embodiment was chosen and described in order to best explain the principles of the disclosure and the practical application, and to enable others of ordinary skill in the art to understand the disclosure for various embodiments with various modifications as are suited to the particular use contemplated.
Claims (20)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/805,527 US9570318B1 (en) | 2015-07-22 | 2015-07-22 | High-k and p-type work function metal first fabrication process having improved annealing process flows |
US15/183,390 US9876089B2 (en) | 2015-07-22 | 2016-06-15 | High-k and p-type work function metal first fabrication process having improved annealing process flows |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14/805,527 US9570318B1 (en) | 2015-07-22 | 2015-07-22 | High-k and p-type work function metal first fabrication process having improved annealing process flows |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US15/183,390 Division US9876089B2 (en) | 2015-07-22 | 2016-06-15 | High-k and p-type work function metal first fabrication process having improved annealing process flows |
Publications (2)
Publication Number | Publication Date |
---|---|
US20170025285A1 true US20170025285A1 (en) | 2017-01-26 |
US9570318B1 US9570318B1 (en) | 2017-02-14 |
Family
ID=57837304
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US14/805,527 Expired - Fee Related US9570318B1 (en) | 2015-07-22 | 2015-07-22 | High-k and p-type work function metal first fabrication process having improved annealing process flows |
US15/183,390 Active US9876089B2 (en) | 2015-07-22 | 2016-06-15 | High-k and p-type work function metal first fabrication process having improved annealing process flows |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US15/183,390 Active US9876089B2 (en) | 2015-07-22 | 2016-06-15 | High-k and p-type work function metal first fabrication process having improved annealing process flows |
Country Status (1)
Country | Link |
---|---|
US (2) | US9570318B1 (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10177041B2 (en) * | 2017-03-10 | 2019-01-08 | Globalfoundries Inc. | Fin-type field effect transistors (FINFETS) with replacement metal gates and methods |
US10164056B2 (en) * | 2017-05-17 | 2018-12-25 | International Business Machines Corporation | Vertical field effect transistors with uniform threshold voltage |
CN109326595B (en) | 2017-07-31 | 2021-03-09 | 联华电子股份有限公司 | Semiconductor element and manufacturing method thereof |
EP3813124A1 (en) | 2019-10-22 | 2021-04-28 | Imec VZW | Split replacement metal gate integration |
US11588033B2 (en) | 2021-05-20 | 2023-02-21 | Omnivision Technologies, Inc. | Uniform threshold voltage non-planar transistors |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6575997B1 (en) * | 1999-12-23 | 2003-06-10 | Endovascular Technologies, Inc. | Embolic basket |
US7611943B2 (en) * | 2004-10-20 | 2009-11-03 | Texas Instruments Incorporated | Transistors, integrated circuits, systems, and processes of manufacture with improved work function modulation |
US7629212B2 (en) * | 2007-03-19 | 2009-12-08 | Texas Instruments Incorporated | Doped WGe to form dual metal gates |
US7993999B2 (en) | 2009-11-09 | 2011-08-09 | International Business Machines Corporation | High-K/metal gate CMOS finFET with improved pFET threshold voltage |
US8357603B2 (en) * | 2009-12-18 | 2013-01-22 | Taiwan Semiconductor Manufacturing Company, Ltd. | Metal gate fill and method of making |
US20110147831A1 (en) | 2009-12-23 | 2011-06-23 | Steigerwald Joseph M | Method for replacement metal gate fill |
US8653610B2 (en) * | 2010-04-21 | 2014-02-18 | International Business Machines Corporation | High performance non-planar semiconductor devices with metal filled inter-fin gaps |
CN102891178A (en) | 2011-07-19 | 2013-01-23 | 中芯国际集成电路制造(北京)有限公司 | Semiconductor device and manufacturing method thereof |
US8557666B2 (en) * | 2011-09-13 | 2013-10-15 | GlobalFoundries, Inc. | Methods for fabricating integrated circuits |
US8420459B1 (en) | 2011-10-20 | 2013-04-16 | International Business Machines Corporation | Bulk fin-field effect transistors with well defined isolation |
US9006094B2 (en) | 2012-04-18 | 2015-04-14 | International Business Machines Corporation | Stratified gate dielectric stack for gate dielectric leakage reduction |
KR20130127257A (en) | 2012-05-14 | 2013-11-22 | 삼성전자주식회사 | Semiconductor device and method for manufacturing the device |
US20130309856A1 (en) | 2012-05-15 | 2013-11-21 | International Business Machines Corporation | Etch resistant barrier for replacement gate integration |
US8546209B1 (en) | 2012-06-15 | 2013-10-01 | International Business Machines Corporation | Replacement metal gate processing with reduced interlevel dielectric layer etch rate |
-
2015
- 2015-07-22 US US14/805,527 patent/US9570318B1/en not_active Expired - Fee Related
-
2016
- 2016-06-15 US US15/183,390 patent/US9876089B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
US9876089B2 (en) | 2018-01-23 |
US9570318B1 (en) | 2017-02-14 |
US20170025526A1 (en) | 2017-01-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20210391420A1 (en) | Fin recess last process for finfet fabrication | |
USRE45944E1 (en) | Structure for a multiple-gate FET device and a method for its fabrication | |
US7538351B2 (en) | Method for forming an SOI structure with improved carrier mobility and ESD protection | |
US11302691B2 (en) | High voltage integration for HKMG technology | |
TWI462234B (en) | Structure and method for forming programmable high-k/metal gate memory device | |
US9876089B2 (en) | High-k and p-type work function metal first fabrication process having improved annealing process flows | |
US9018739B2 (en) | Semiconductor device and method of fabricating the same | |
KR20150060578A (en) | Structure and method for finfet device with buried sige oxide | |
US10985075B2 (en) | Gate formation scheme for n-type and p-type transistors having separately tuned threshold voltages | |
TWI469262B (en) | Manufacturing method of semiconductor device and semiconductor device | |
US9147679B2 (en) | Method of semiconductor integrated circuit fabrication | |
US20140217505A1 (en) | Double patterning method for semiconductor devices | |
US11038059B2 (en) | Semiconductor device and method of forming the same | |
TW201724215A (en) | Semiconductor devices | |
US11282705B2 (en) | Semiconductor device and method of forming the same | |
US10847634B2 (en) | Field effect transistor and method of forming the same | |
US20180090488A1 (en) | Integrated ldmos and vfet transistors | |
US20200312977A1 (en) | Positioning air-gap spacers in a transistor for improved control of parasitic capacitance | |
TWI538060B (en) | Gate encapsulation achieved by single-step deposition | |
CN109860114A (en) | Fin diode structure and its method | |
US20220223693A1 (en) | Effective work function tuning via silicide induced interface dipole modulation for metal gates | |
US10388570B2 (en) | Substrate with a fin region comprising a stepped height structure | |
US20230411219A1 (en) | Semiconductor structure and method for manufacturing the same | |
KR20230091798A (en) | Method and multi-channel devices with anti-punch-through features | |
TW202320335A (en) | Semiconductor structure and forming method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: GLOBALFOUNDRIES INC., CAYMAN ISLANDS Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:CHO, JIN;ZANG, HUI;SIGNING DATES FROM 20150702 TO 20150713;REEL/FRAME:036150/0084 Owner name: INTERNATIONAL BUSINESS MACHINES CORPORATION, NEW Y Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:WANG, MIAOMIAO;REEL/FRAME:036150/0511 Effective date: 20150702 |
|
STCF | Information on status: patent grant |
Free format text: PATENTED CASE |
|
AS | Assignment |
Owner name: WILMINGTON TRUST, NATIONAL ASSOCIATION, DELAWARE Free format text: SECURITY AGREEMENT;ASSIGNOR:GLOBALFOUNDRIES INC.;REEL/FRAME:049490/0001 Effective date: 20181127 |
|
FEPP | Fee payment procedure |
Free format text: MAINTENANCE FEE REMINDER MAILED (ORIGINAL EVENT CODE: REM.); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
AS | Assignment |
Owner name: GLOBALFOUNDRIES U.S. INC., CALIFORNIA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:GLOBALFOUNDRIES INC.;REEL/FRAME:054633/0001 Effective date: 20201022 |
|
AS | Assignment |
Owner name: GLOBALFOUNDRIES INC., CAYMAN ISLANDS Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:WILMINGTON TRUST, NATIONAL ASSOCIATION;REEL/FRAME:054636/0001 Effective date: 20201117 |
|
LAPS | Lapse for failure to pay maintenance fees |
Free format text: PATENT EXPIRED FOR FAILURE TO PAY MAINTENANCE FEES (ORIGINAL EVENT CODE: EXP.); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
STCH | Information on status: patent discontinuation |
Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362 |
|
FP | Lapsed due to failure to pay maintenance fee |
Effective date: 20210214 |
|
AS | Assignment |
Owner name: GLOBALFOUNDRIES U.S. INC., NEW YORK Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:WILMINGTON TRUST, NATIONAL ASSOCIATION;REEL/FRAME:056987/0001 Effective date: 20201117 |