US20160146462A1 - PLANT, COMBUSTION APPARATUS, AND METHOD FOR REDUCTION OF NOx EMISSIONS - Google Patents
PLANT, COMBUSTION APPARATUS, AND METHOD FOR REDUCTION OF NOx EMISSIONS Download PDFInfo
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- US20160146462A1 US20160146462A1 US14/550,101 US201414550101A US2016146462A1 US 20160146462 A1 US20160146462 A1 US 20160146462A1 US 201414550101 A US201414550101 A US 201414550101A US 2016146462 A1 US2016146462 A1 US 2016146462A1
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J7/00—Arrangement of devices for supplying chemicals to fire
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C5/00—Disposition of burners with respect to the combustion chamber or to one another; Mounting of burners in combustion apparatus
- F23C5/08—Disposition of burners
- F23C5/10—Disposition of burners to obtain a flame ring
- F23C5/12—Disposition of burners to obtain a flame ring for pulverulent fuel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C5/00—Disposition of burners with respect to the combustion chamber or to one another; Mounting of burners in combustion apparatus
- F23C5/08—Disposition of burners
- F23C5/32—Disposition of burners to obtain rotating flames, i.e. flames moving helically or spirally
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C6/00—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion
- F23C6/04—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection
- F23C6/045—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection with staged combustion in a single enclosure
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C6/00—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion
- F23C6/04—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection
- F23C6/045—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection with staged combustion in a single enclosure
- F23C6/047—Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection with staged combustion in a single enclosure with fuel supply in stages
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C9/00—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber
- F23C9/06—Combustion apparatus characterised by arrangements for returning combustion products or flue gases to the combustion chamber for completing combustion
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D1/00—Burners for combustion of pulverulent fuel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D14/00—Burners for combustion of a gas, e.g. of a gas stored under pressure as a liquid
- F23D14/20—Non-premix gas burners, i.e. in which gaseous fuel is mixed with combustion air on arrival at the combustion zone
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
- F23L7/007—Supplying oxygen or oxygen-enriched air
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L9/00—Passages or apertures for delivering secondary air for completing combustion of fuel
- F23L9/04—Passages or apertures for delivering secondary air for completing combustion of fuel by discharging the air beyond the fire, i.e. nearer the smoke outlet
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2201/00—Staged combustion
- F23C2201/10—Furnace staging
- F23C2201/101—Furnace staging in vertical direction, e.g. alternating lean and rich zones
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2201/00—Staged combustion
- F23C2201/20—Burner staging
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2201/00—Staged combustion
- F23C2201/30—Staged fuel supply
- F23C2201/301—Staged fuel supply with different fuels in stages
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
- F23C2900/06041—Staged supply of oxidant
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2900/00—Special features of, or arrangements for combustion apparatus using fluid fuels or solid fuels suspended in air; Combustion processes therefor
- F23C2900/99004—Combustion process using petroleum coke or any other fuel with a very low content in volatile matters
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
Definitions
- the present innovation is related to apparatuses configured to combust a fuel and methods of making and using the same, and more specifically a combustion apparatus for burning a fuel with reduced NO x emissions.
- Combustion systems can include combustors such as a boiler, an incinerator system, or a furnace. Examples of combustion systems are disclosed in U.S. Pat. Nos. 4,719,587, 5,315,939, 5,443,805, 5,626,085, 6,258,336, 6,598,399, 8,375,723, and 8,434,311 and European Patent No. 1 530 994. Pollutants such as nitrogen oxides (e.g. NO, NO 2 , NO x ) and sulfur oxides (e.g. SO 2 , SO 3 , SO x ) can be emitted from operation of combustion systems. Operators of combustion systems may utilize pollution control equipment (e.g. desulfurization units, scrubbers, etc.) to help ensure clean and environmentally sound operation of the combustion systems.
- pollution control equipment e.g. desulfurization units, scrubbers, etc.
- a combustion apparatus includes a combustion chamber having multiple combustion zones for combustion of fuel.
- the combustion zones can include a first combustion zone, a second combustion zone, and a third combustion zone.
- the second combustion zone can be located between the first and third combustion zones.
- the combustion chamber can have at least one outlet configured to emit flue gas formed from combustion of the fuel in the combustion chamber.
- a first wind box can be in communication with the first combustion zone for feeding of fuel into the combustion chamber for initial combustion within the first combustion zone.
- a second wind box can be configured to feed a gas having oxygen into the second combustion zone.
- a third wind box can be in communication with the third combustion zone to feed a gas having oxygen into the third combustion zone.
- a conduit provides a reagent to the second combustion zone.
- a method of operating a combustion apparatus can include the step of feeding a first fuel into a combustion chamber having multiple combustion zones for combustion of the first fuel.
- the combustion zones can include a first combustion zone, a second combustion zone, and a third combustion zone.
- the second combustion zone can be located between the first and third combustion zones.
- the vessel can have at least one outlet configured to emit flue gas from the combustion chamber after the flue gas is formed from combustion of the first fuel.
- the method can also include the step of feeding a gas having oxygen and a reagent to the second combustion zone. Further, the method includes feeding a gas having oxygen to the second combustion zone.
- FIG. 1 is a schematic diagram of an exemplary embodiment of a plant in accordance with the present invention.
- FIG. 2 is a cross-sectional view of an embodiment of a reburner disposed in an upper compartment of a second wind box of a combustion apparatus in accordance with the present invention.
- FIG. 3 is a block diagram illustrating a plurality of stacked compartments of respective vertically-aligned first, second and third wind boxes to provide material to a combustion apparatus of a plant in accordance with the present invention.
- FIG. 4 is a fragmentary side view of an exemplary air nozzle disposed within a compartment of a third wind box to provide air to a third combustion zone of a combustion chamber of a plant in accordance with the present invention.
- FIG. 5 is a bar graph illustrating an amount of nitrogen oxides (NO x ) that may be emitted from a combustion apparatus 5 using different types of fuel, types A, B, C, D, and E for 3 different configurations of combustion apparatus.
- Type A is a low volatile bituminous coal
- type B is a medium volatile bituminous coal
- type C is a high volatile bituminous coal
- type D is a subbituminous coal
- type E is lignite.
- the vertical axis of the chart identifies the amount of NO x emitted as a ratio in which a pound of NO x is emitted per every million British Thermal Unit (BTU) of heat fired from the combustion of the fuel fed into the combustion apparatus 5 .
- BTU British Thermal Unit
- the horizontal axis of the chart identifies the type of fuels being compared.
- a conventional combustion apparatus is identified as bars 61 in the chart
- an embodiment of the combustion apparatus disclosed herein that only utilizes a reburner without the feeding of a reagent is identified as bars 62 in the chart
- an embodiment of the combustion apparatus that utilizes a reburner and the feeding of a reagent into the second combustion zone which is identified as bars 63 in the chart.
- FIG. 6 is a graph illustrating a percentage reduction of NO x versus the stoichiometry within the second combustion zone of a combustion apparatus in accordance with the present invention. As shown in the vertical axis of the graph, that was calculated for given stoichiometries within the second combustion zone 5 b for embodiments of the plant and combustion apparatus 5 .
- the stoichiometry ratio within the second combustion zone 5 b for the combustion apparatus is identified in the horizontal axis of the graph.
- the stoichiometry ratio expresses a ratio for an amount of the oxygen needed to fully combust the fuel within the second combustion zone 5 b as compared to the amount of fuel within the second combustion zone 5 b.
- a number over 1.0 indicates that that there is an excess of oxygen needed to fully combust the fuel and a number below 1.0 indicates that there is not enough oxygen to completely combust the fuel within the second combustion zone.
- the Line 71 of the graph refers to an embodiment of the combustion apparatus in which only a reburner 30 of the second wind box 4 is utilized.
- Line 72 of the graph identifies an embodiment of the combustion apparatus in which only the feeding of a reagent via the second wind box 4 of the combustion apparatus is utilized.
- Line 73 of the graph identifies an embodiment of the combustion apparatus that utilizes both the reburner 30 and the feeding of the reagent via the second wind box 4 .
- FIG. 7 is a graph illustrating a percentage of the reburn NO x reduction efficiency as compared to a percentage of heat input provided by the reburner fuel fed into the second combustion zone as compared to the entire amount of fuel fed into the combustion apparatus for embodiments of the combustion apparatus in accordance with the present invention.
- the vertical axis of the graph of FIG. 7 identifies the percentage of the NO x reduction efficiency and the horizontal axis of the graph identifies the percentage of heat input provided by the fuel fed into the second combustion zone 5 b via the reburner 30 as compared to the total amount of fuel fed into the combustion apparatus for combustion.
- Line 75 of the graph of FIG. 7 illustrates the calculated results from a conventional combustion apparatus utilizing a conventional reburner system.
- FIG. 8 is a graph illustrating an extent of the reburn of NO x reduction efficiency provided by an embodiment of the combustion apparatus as compared to an amount of NO x fed from the first combustion zone into the second combustion zone 5 b in parts per million volumetric dry (ppmvd) concentration based on a reference percentage oxygen.
- the vertical axis of the graph of FIG. 8 illustrates that the NO x reduction efficiency is independent of the inlet NO x concentration entering the second combustion zone 5 b.
- a calculated maximum efficiency level (MAX) is identified on the vertical axis.
- the horizontal axis of the graph of FIG. 8 is the amount of the NO x initially fed into the second combustion zone 5 b in ppmvd concentration referenced to percentage oxygen.
- FIG. 9 is a graph illustrating an extent of the reburn of NO x reduction efficiency provided by an embodiment of the combustion apparatus as compared to a fuel ratio of the fuel being fed into the combustion apparatus for combustion in accordance with the present invention.
- the fuel ratio defined as the fixed carbon to volatile ratio from a fuel's proximate analysis is identified in the horizontal axis of the graph of FIG. 9 .
- the fuel ratio is a measure of the reactivity of a fuel.
- the vertical axis of the graph of FIG. 9 illustrates calculated levels of NO x reduction efficiency and identifies a calculated maximum efficiency level (MAX).
- FIG. 10 is a plan view of a combustion chamber of a tangentially-fired system in accordance with the present invention.
- a plant 1 is shown that is configured to generate electricity.
- the plant can be an industrial plant, a power plant, or an electricity generation plant.
- the plant 1 includes a combustion apparatus 5 , such as, for example, a boiler or a furnace.
- the combustion apparatus 5 can include a vessel defining a combustion chamber 10 .
- Fuel is provided to and combusted in the combustion chamber 10 which generates a flue gas having steam and other combustion products (e.g. carbon dioxide, nitrogen, oxygen, water vapor, etc.).
- the combustion process can be utilized to heat water and steam which can be used to generate electricity and/or other desirable process elements that can be used downstream of the combustion apparatus 5 .
- the flue gas formed in the combustion chamber 10 of the combustion apparatus 5 may be provided to at least one outlet 7 .
- Heat from the flue gas can be transferred to water, steam and/or other fluids passing through water wall tubes (not shown) or other heat exchangers to generate heated gas or fluid for use by a generator unit 19 of the plant 1 .
- flue gas passing through the outlet 7 may pass through one or more heat exchangers (i.e., superheaters and economizers) for heating water and/or steam to be fed to a turbine of the generator unit 19 to generate electricity.
- the fuel can be a fossil fuel such as coal, oil, or natural gas or any another type of carbonaceous fuel.
- the fuel can be fed from a first fuel source 3 .
- the first fuel source 3 may include, for example, a coal mill that is configured to comminute coal and mix the comminuted coal with air for feeding the fuel to the combustion apparatus 5 .
- the source of fuel for the first fuel source 3 may be a vessel or other storage device that retain the fuel, such as pulverized coal, natural gas or oil for feeding to the combustion apparatus 5 .
- the combustion chamber 10 of the combustion apparatus 5 can include multiple combustion zones 5 a, 5 b, 5 c.
- the combustion zones 5 a, 5 b, 5 c can include a first combustion zone (or main burner zone) 5 a, a second combustion zone (or lower separated over fired air (SOFA) zone) 5 b, and a third combustion zone (or upper separated over fired air (SOFA) zone) 5 c.
- the second combustion zone 5 b is located between the first and third combustion zones 5 a, 5 c.
- the second combustion zone 5 b is an intermediate combustion zone within the combustion chamber 10 that is vertically higher than and downstream of the first combustion zone 5 a and vertically lower than and upstream of the third combustion zone 5 c.
- the second combustion zone 5 b may be disposed intermediate to the first combustion zone 5 a and the third combustion zone 5 c, both of which are disposed at opposing ends of the combustion chamber 10 .
- Each combustion zone 5 a, 5 b, 5 c includes a burnout zone disposed in the upper portion or downstream portion of each respective combustion zone which will be described in greater detail hereinafter.
- a plurality of wind boxes 2 , 4 , 6 are in fluid communication with respective combustion zones 5 a, 5 b, 5 c of the combustion chamber 10 to provide the material needed for combustion.
- Each wind box 2 , 4 , 6 includes a plurality of longitudinally stacked compartments, which will be described in greater detail hereinafter, wherein each compartment includes an associated nozzle, burner, ejector, conduit, duct or other apparatus disposed therein for providing material into the combustion chamber 10 of the combustion apparatus 5 .
- a first wind box 2 provides material to the first combustion zone 5 a.
- a second wind box 4 provides material to the second combustion zone 5 b.
- a third wind box 6 provides material to the third combustion zone 5 c.
- Fuel from the first fuel source 3 can be fed to the first wind box 2 via a fuel feed conduit connected between the first fuel source 3 and the first wind box 2 to provide the fuel to the first combustion zone 5 a.
- Air from a source of air 17 is also provided to the first wind box 2 via an air feed conduit connected between the source of air 17 and the first wind box 2 .
- At least one fan or other type of air flow driving mechanism (not shown) can be included in the source of air 17 or may be in communication with the source of air to drive the flow of air from the source of air 17 into the first combustion zone 5 a via the first wind box 2 .
- the air may be mixed with the fuel prior to the fuel and the air being provided into the first wind box 2 or into the first combustion zone 5 a.
- the fuel and air provided into the first combustion zone 5 a via the first wind box 2 may be fed to the first combustion zone for initial combustion of the fuel in the first combustion zone 5 a.
- the air source 17 provides air
- the present invention contemplates the air source 17 may provide any gas having oxygen, including a pure oxygen stream.
- the first wind box 2 can be configured as a main wind box and the second and third wind boxes 4 and 6 can be configured as multi-level separated over fire air (SOFA) wind boxes.
- SOFA multi-level separated over fire air
- the second wind box 4 can be configured as a lower separated over fire air wind box and the third wind box 6 can be configured as an upper separated over fire air wind box.
- the first wind box 2 can be configured to include multiple compartments 2 a - 2 q that are positioned in longitudinal or vertical alignment for the feeding of fuel and other material into the first combustion zone 5 a.
- the first wind box 2 may include first and second compartments 2 a and 2 b that are configured to provide close couple over fire air (CCOFA) to the first combustion zone 5 a.
- the third compartment 2 c, sixth compartment 2 f, tenth compartment 2 j, and seventeenth compartment 2 q can be configured to feed air or oxygen to the first combustion zone 5 a.
- the fourth, eighth, twelfth, and sixteenth compartments 2 d, 2 h, 2 l, and 2 p can be configured to feed fuel from the first fuel source 3 to the first combustion zone 5 a.
- the fifth compartment 2 e, seventh compartment 2 g, ninth compartment 2 i, eleventh compartment 2 k, thirteenth compartment 2 m, and fifteenth compartment 2 o can be configured to provide additional offset air to the first combustion zone 5 a.
- the fourteenth compartment 2 n can be configured to feed fuel from the second fuel source 3 a as indicated by broken line in FIG. 1 for startup and shut-down operations of the combustion apparatus 5 when the second fuel source is natural gas or oil.
- the fourteenth compartment 2 n can be configured to feed oil, natural gas, or other fuel source from a third fuel source (not shown).
- the combustion region above the close coupled over fire air (CCOFA) compartments 2 a, 2 b of the first wind box 2 and below the second wind box 4 is the burnout region of the first combustion zone 5 a where combustion continues above or downstream of the first wind box.
- COFA close coupled over fire air
- the second wind box 4 and third wind box 6 can each be configured to have fewer compartments than the first wind box 2 .
- the second wind box 4 can be configured to include an upper compartment 4 a, a lower compartment 4 c, and an intermediate compartment 4 b that is between the upper and lower compartments 4 a, 4 c.
- the upper or topmost compartment 4 a can include a reburner 30 in some embodiments.
- the reburner 30 can be the sole reburner for feeding fuel into the second combustion zone 5 b in some embodiments.
- a reagent can also be fed into the second combustion zone via the upper compartment 4 a in addition to the use of the sole reburner 30 or as an alternative to the reburner 30 .
- the intermediate and lower compartments 4 b and 4 c can be configured to feed air into the second combustion zone 5 b.
- the combustion region above the second wind box 4 and below the third wind box 6 is the burnout region of the second combustion zone 5 a where combustion and reaction of the reagent continues above or downstream of the second wind box.
- the third wind box 6 can also have upper, intermediate and lower compartments 6 a, 6 b, and 6 c. Each of these compartments of the third wind box 6 can be configured to feed air into the third combustion zone 5 c.
- the combustion region above the upper separated over fire air (SOFA) compartments 6 a, 6 b, 6 c of the third wind box 6 is the burnout region of the third combustion zone 5 a where combustion continues above or downstream of the third wind box.
- SOFA separated over fire air
- the first, second and third wind boxes 2 , 4 , and 6 can each be configured to emit a flow of fluid into the combustion chamber of the combustion apparatus 5 so that the pitch and yaw of the flow of fluid is adjustable.
- the third wind box 4 can be configured to include an air nozzle assembly 43 having a tilting mechanism 45 that can be actuated to vertically tilt the nozzles 44 through which material, for example air, is output from the compartments 6 a, 6 b, 6 c of the third wind box 6 to adjust the pitch (i.e., vertical tilt) at which the material is fed into the third combustion zone 5 c and to actuate horizontal adjustment via a horizontal adjustment mechanism 46 to adjust the yaw (i.e., horizontal angle) at which the material is fed into the third combustion zone 5 c.
- a tilt i.e., horizontal angle
- the tilting mechanism 45 may include at least one actuator (e.g. a pneumatic or electric cylinder) that is connected to the tilting mechanism 45 for actuating vertical adjustments (pitch) of the nozzles 44 .
- the second wind box 4 can also include a tilting mechanism 45 for adjusting the pitch and yaw of the nozzles 44 providing material (for example air) from the top, intermediate and bottom compartments 4 a, 4 b, 4 c of the second wind box 4 into the second combustion zone 5 b of the combustion apparatus 5 in one embodiment.
- the nozzle assembly 43 may include a tilt mechanism 45 for a pair of nozzles 44 that provide air to the intermediate and lower compartments 4 b, 4 c, wherein the upper compartment 4 a provides the reburner 30 and/or reagent.
- Fuel can also be fed to a fuel nozzle 30 (see FIG. 2 ) of the reburner 30 which provides fuel to the second combustion zone 5 b of the combustion chamber 10 for combustion therein.
- the fuel fed to the second combustion zone 5 b can be fuel from the first and/or second fuel source 3 , 3 a.
- a fuel feed conduit provides the second fuel source 3 a to the second wind box 4 for feeding the fuel to the second combustion zone 5 b via the second wind box 4 .
- the fuel of the second fuel source 3 a can be different than the fuel from the first fuel source 3 .
- the fuel of the first fuel source 3 can be coal and the fuel of the second fuel source 3 a can be natural gas or oil.
- the fuel of the first fuel source 3 may be a first type of coal and the fuel of the second fuel source 3 a may be another type of coal (e.g. micronized coal).
- the fuel fed into the second combustion zone 5 b can be from the first fuel source 3 as indicated by broken line in FIG. 1 so that the same type of fuel is fed to the first and second combustion zones 5 a, 5 b.
- the amount of fuel fed from the second fuel source 3 a to the reburner 30 of the second wind box 6 may be between 10-15% of the total amount of heat fired from the fuel fed to the combustion apparatus 5 for combusting therein. It has been determined that use of a second type of fuel at the second combustion zone 5 b can provide a reduced amount of NO x , sulfur oxides (e.g. SO 2 , SO 3 , etc.), carbon dioxide, and other pollutants (e.g. particulates such as fly ash) being formed in the flue gas formed from combustion of fuel in the combustion chamber of the combustion apparatus 5 .
- sulfur oxides e.g. SO 2 , SO 3 , etc.
- carbon dioxide e.g. particulates such as fly ash
- use of natural gas as the fuel of the second fuel source 3 a when coal is used as the fuel of the first fuel source 3 can help reduce the amount of NO x , sulfur oxides, particulates, and carbon dioxide formed from further combustion of the second fuel added at the second combustion zone 5 b as compared to the use of the same coal as fed to the first combustion zone 5 a.
- the second wind box 4 can also be configured to receive flue gas and a reagent for feeding into the second combustion zone 5 b.
- the reagent can be received from a source of the reagent 15 , which may be a vessel, tank or other storage device that retains the reagent.
- the reagent may be stored therein.
- the reagent may be urea, ammonia, an amine based chemical compound (e.g.
- the reagent may be in a liquid state or a gaseous state.
- the urea may be an aqueous urea mixture (e.g. urea mixed with water), the ammonia may be an aqueous ammonia (e.g.
- the reagent may be another type of aqueous state reagent that is suitable for being sprayed into the second combustion zone via a mechanical spray mechanism or an atomizer mechanism.
- the reagent may be in a gaseous state such as anhydrous ammonia, an anhydrous urea or other type of anhydrous reagent.
- a portion of the reagent material may be from other process elements of the plant that emit the reagent and send that reagent to the source of the reagent 15 for temporary storage until it is fed to the second combustion zone 5 b.
- the source of the reagent 15 can be connected to the second wind box 4 via a reagent feed conduit.
- a portion of flue gas emitted from an outlet 7 of the combustion apparatus 5 can be recycled to the nozzle or reburner 10 disposed in the second wind box 4 for feeding the flue gas, reagent and fuel into the second combustion zone 5 b.
- the recycled flue gas to be recycled to the second wind box 4 may first pass through an economizer 9 positioned in the outlet 7 .
- the economizer 9 can be configured to transfer heat from the flue gas passing therethrough to another fluid (e.g. water) that passes through the economizer 9 to heat that fluid to a pre-selected temperature for use in another process element of the plant 1 , and thereby cool the flue gas prior to being recycled.
- a flow control mechanism 11 such as a fan or other type of gas flow driving mechanism, may be used to drive the flue gas to be recycled back to the combustion apparatus 5 from the economizer 9 to the second wind box 6 .
- Another portion of the flue gas may be provided to a gas processing unit 13 via a gas processing unit feed conduit.
- the gas processing unit 13 can be configured to remove fly ash, sulfur oxides, and other elements from the flue gas prior to that flue gas being emitted from the plant 1 or used in another plant process.
- the gas processing unit 13 may include a precipitator, a bag house, a desulfurization unit, and other gas processing elements that are configured to remove elements from the flue gas prior to the flue gas being emitted from the plant 1 and/or utilized in another plant process.
- the second wind box 4 can also include a reburner or fuel nozzle 30 .
- a reburner 30 is shown in FIG. 2 .
- the reburner 30 can be positioned in an upper compartment 4 a of the second wind box 4 .
- a sole reburner 30 may be the only reburner of the second wind box 4 and may be located at the top compartment 4 a of the second wind box 4 or may be located in the compartment 4 a of the second wind box that is closest to the third combustion zone 5 c.
- the reburner 30 may be disposed in the second wind box 4 so that the second combustion zone 5 b receives a flow of flue gas 21 from the recycle conduit after that flue gas has passed through the economizer 9 , a flow of reagent 23 from the source of the reagent 15 , and a flow of fuel 25 from the first fuel source 3 or the second fuel source 3 a so that the reagent, flue gas, and fuel can be simultaneously fed to the second combustion zone 5 b.
- the reagent, fuel and flue gas can be fed in the second combustion zone 5 b via a concentric ring nozzle 39 .
- the flue gas functions as a carrier gas to improve penetration and distribution of the gaseous reagent into the second combustion zone 5 b to enable more efficient reaction between the reagent and the flue gas flowing through the combustion chamber 10 .
- the recycled flue gas further increases the mass and volume of the flue gas and reagent mixture to increase the penetration and distribution of the gaseous reagent into the second combustion zone 5 b.
- the carrier gas may be any oxygen-deficient carrier gas, for example steam, to provide the optimum stoichiometric condition within the second combustion zone 5 b.
- the carrier gas e.g., flue gas and steam
- the reagent may be injected as a liquid wherein a carrier gas may not be needed.
- a pump or other type of liquid reagent flow control device can be in communication with a liquid reagent storage vessel 15 and be configured to drive the flow of the liquid reagent into the second combustion zone 5 b.
- the liquid reagent can be fed via an atomizer that is configured to inject the reagent as an atomized liquid spray to inject the liquid reagent into the second combustion zone 5 b to help facilitate optimum penetration and mixing of the liquid reagent with the flue gas flowing through the combustion chamber 10 .
- Embodiments that utilize a liquid reagent for injection into the second combustion chamber 5 b can allow for the removal of a carrier gas (e.g. flue gas or steam) and may allow for the elimination of costly equipment, such as gas recirculation fans, ductwork, and controls for such elements.
- a carrier gas e.g. flue gas or steam
- the reagent is shown to be provided to the second combustion zone 5 b through the reburner 30 or second wind box 4 , one will appreciate that the reagent can be injected at a location above the second wind box 4 .
- the reagent may be injected at a location above the reburner 30 and/or the second wind box 4 , but below the third wind box 6 .
- Reagent injection can also be provided at this location, provided the injection location is disposed at a sufficient distance from the third wind box 6 to provide sufficient resident time for the reagent to react with the flue gas.
- the invention further contemplates that the feeding of the fuel and/or reagent to the second combustion zone 5 b may be selectively stopped by a control valve in response to the stoichiometric conditions within the combustion chamber 10 , such that fuel or reagent is provided to the second combustion zone of the combustion chamber via the upper portion of the second wind box 4 .
- the use of the reburner 30 can help provide a reduction of NO x emissions based upon the injection of the fuel into the second combustion zone so that an oxygen deficient volume within the second combustion zone exists so that the reburn fuel can help break down the formation of nitrogen containing hydrocarbon radicals that can contribute to formation of NO x when reacting with the products of the combustion of the fuel fed into the first combustion zone 5 a.
- Hydrocarbon radicals from the fuel fed into the second combustion zone 5 b can function to strip the oxygen from the NO x to form elemental nitrogen, water vapor, carbon monoxide, carbon dioxide, and other reduced species and compounds.
- One of the primary chemical NO x destruction mechanisms of the reburn process via the fuel fed to the second combustion zone 5 b is set forth below:
- High temperature reagent injection utilizing the reagent from the upper compartment of the second wind box 4 can provide a further mechanism for reducing NO x based on producing amine radicals.
- the chemical NO x destruction mechanism of the high temperature reagent injection process can be illustrated by the formula: NO+NH 2 ⁇ N 2 +H 2 O.
- the amount of fuel and/or reagent injected into the second combustion zone 5 b can be a relatively small amount as compared to the volume of flue gases generated from combustion of the fuel in the first combustion zone 5 a that subsequently passes into the second combustion zone 5 b.
- a higher reburn fuel feed velocity and/or reagent feed velocity can help provide effective penetration and rapid mixing of the reagent and fuel.
- Fuel and/or reagent feed line pressures can be set to help ensure that the fuel and/or reagent is fed into the second combustion zone 5 b at a pre-selected velocity to facilitate effective penetration and mixing.
- the mixing of the reagent can also be facilitated by use of an atomized liquid spray mechanism.
- the flue gas fed to the second wind box 4 can also help facilitate the higher velocities of the reagent and/or fuel fed to the second combustion zone 5 b.
- the recycled flue gas can be considered a carrier gas that is output with the fuel and/or reagent to provide an output of the fuel and/or reagent at a pre-selected velocity.
- the reburner 30 can include a body 33 , which can be configured as a lance, an injector, an eductor, a swirl body, or other type of body.
- the body 33 can include an inlet end 33 a and an outlet end 33 b.
- the fuel 25 may be received in the inlet end 33 a and subsequently pass out of the outlet end 33 b of the body 33 toward the second combustion zone 5 b.
- the body 33 can receive the flow of fuel 25 and be positioned within a portion of an upper compartment of the second wind box 4 so that it is structured to facilitate mixing of the flow of fuel with a flow of the reagent 23 that may pass along the body 33 .
- the body 33 can have holes along a periphery of the body so that the fuel can pass out of these holes and into a passageway 35 defined between the exterior of the body 33 and the wall of an inner conduit defining an inner passageway 35 through which the reagent and fuel can pass through toward the second combustion zone 5 b via the second wind box 4 .
- a nozzle tip 39 can be pivotally connected to the inner conduit defining the inner passageway 35 in which the body 33 is positioned by a tilting connection 31 .
- the tilting connection 31 allows the nozzle tip 39 to be tilted vertically about an axis, which can also adjust the flow direction of the flow of flue gas 21 passing through the outer passageway 37 .
- the tilting connection 31 of the nozzle tip 39 can permit the pitch angles of the flow of the flue gas, reagent, and fuel being fed into the second combustion zone 5 b via the reburner 30 to be adjusted at the same time via tilting of the nozzle tip 39 .
- the flow of the recycled flue gas 21 or other oxygen deficient carrier gas can pass through an outer passageway 37 that surrounds the inner passageway 35 and fuel passageway defined by the body 33 that is within the inner passageway 35 .
- the flow of the flue gas 21 can be a first portion of the flue gas that is recycled from the outlet 7 and economizer 9 back to the second combustion zone 5 b of the combustion apparatus 5 .
- the flow of the flue gas 21 can pass through the second feed conduit and wind box 4 and out of a concentric nozzle tip 39 .
- the direction of the flow of the flue gas passing through the outer passageway 37 to the second combustion zone 5 b can be adjusted by tilting of the nozzle tip 39 at which the flue gas passes into the second combustion zone 5 b. Tilting of the nozzle tip 39 changes the size and shape of the opening of the outer passageway 37 to adjust the flow velocity profile of the flue gas passing through the outer passageway 37 to the second combustion zone 5 b.
- the second and third wind boxes 4 , 6 can receive a flow of air from the source of air 17 for feeding into the second and third combustion zones 5 b, 5 c of the combustion chamber 10 .
- the second and third wind boxes 4 , 6 can receive a flow of other gas containing oxygen from another oxidant source (e.g. an air separation unit).
- the flow rate of oxygen containing gas fed into the first, second and third combustion zones 5 a - 5 c via the first, second and third wind boxes 2 , 4 , and 6 can be controlled to help facilitate a low creation of NO x within the flue gas.
- the stoichiometry or the amount of oxygen within the gas fed to the first combustion zone via the first wind box 2 can be between 50-70% of the oxygen needed to fully combust the fuel.
- the first wind box 2 can also include close-coupled over fired air (CCOFA) compartments for feeding an oxygen containing gas (e.g.
- the amount of oxygen within the gas fed to the second combustion zone 5 b via the second wind box 4 can be configured to increase stoichiometry or the amount of oxygen within the second combustion zone 5 b of the combustion chamber to be between 96-105% of the oxygen needed to fully combust the fuel, so that at least 96% of the fuel in the second combustion zone 5 b would be combusted therein, and at most 105% of the fuel within the second combustion zone 5 b would be combusted therein (e.g.
- the amount of oxygen fed into the third combustion zone 5 c via the third wind box 6 can be configured to increase the stoichiometry or the amount of oxygen needed to fully combust the fuel passing through the third combustion zone 5 c so that more than 105% of the fuel within the third combustion zone would be combustible in the third combustion zone (e.g. there is an excess of oxygen so that there is between 15%-25% more oxygen than theoretically needed to fully combust the fuel within the third combustion zone 5 c ).
- the combustion apparatus 5 is similar to the combustion apparatus described herein having a reburner 30 however, this embodiment does not include the reburner 30 for providing fuel to the second combustion zone 5 b.
- the reagent is provided to the second combustion zone as described hereinbefore.
- the reagent injection system can be positioned for injection of the reagent so that there is a sufficient residence time within the combustion chamber prior to the flow of fluid entering the third combustion zone 5 c to allow for the reagent to react with elements of the fluid passing through the combustion chamber to facilitate removal of elements that can contribute to formation of NO x .
- the reagent may be injected or provided to the upper chamber 4 a of the second wind box 4 as a liquid or gas, which may be mixed with over fire air and/or an oxygen deficient carrier gas, such as recycled flue gas, steam or other oxygen-deficient gas.
- an oxygen deficient carrier gas such as recycled flue gas, steam or other oxygen-deficient gas.
- the reagent and flue gas can be fed separately, but at the same time, into the second combustion zone 5 b via the second wind box 4 such that the flue gas acts as a carrier gas to help penetrate and disperse the reagent into the second combustion zone 5 b.
- the reagent may be injected into the second combustion zone 5 b as a liquid such that no carrier gas is utilized to facilitate injection of the reagent into the second combustion zone 5 b.
- the stoichiometry for low NO x formation can be changed within each of the combustion zones 5 a, 5 b, 5 c of the combustion apparatus 5 to provide low NO x formation within the flue gas formed via combustion of the fuel.
- the stoichiometry within each of the combustion zones of the combustion apparatus can be configured for such embodiments having no reburner 30 or fuel provided to the second combustion zone 5 b, wherein the first combustion zone 5 a has a stoichiometry between 50% and 70% of the oxygen needed to fully combust the fuel within the first combustion zone 5 a and 70-85% of the oxygen needed to fully combust the fuel within the upper portion (the reburn zone) of the first combustion zone 5 a.
- the stoichiometry or the amount of oxygen within the second combustion zone 5 b can be between 85-95% of the oxygen needed for full combustion of the fuel within the second combustion zone 5 b.
- the third wind box 6 can be configured to provide oxygen within the gas fed into the third combustion zone 5 c so that the stoichiometry or the amount of oxygen therein is more than 95% of the oxygen (e.g. 95% to more than 105% of the oxygen needed to fully combust the fuel within the third combustion zone 5 c ) is present in the third combustion zone.
- the combustion apparatus 5 can be configured for tangential firing and includes a tangential firing system, similar to that described in U.S. Pat. No. 5,315,939, which is incorporated herein by reference.
- the wind boxes 2 , 4 , 6 of FIGS. 1 and 2 may be located at the four corners of the combustion chamber 10 .
- FIG. 1 schematically shows the complementary wind boxes 2 , 4 , 6 (shown in dotted line) disposed at or near the other corners of the combustion chamber 10 .
- the air and fuel nozzles disposed in the compartments of the wind boxes 2 , 4 , 6 are angled to create a fireball 80 flowing in a circular pattern.
- the fuel via a reburner 30 and/or the reagent may be provided by or above the second wind boxes 2 , 4 , 6 at one, two, three or four of the corners of the combustion chamber 10 in any combination of locations or corners.
- the one or more stacked wind boxes 2 , 4 , 6 may be disposed in one or more walls defining the combustion chamber 10 to provide a wall firing combustion system or apparatus.
- Embodiments of the combustion apparatus 5 and plant 1 can be configured so that a furnace or combustion chamber 10 having a shorter height or length as compared to conventional furnaces may be utilized, which can reduce the costs associated with material, fabrication, maintenance and operation of embodiments of the plant or embodiments of the combustion apparatus. For instance, it has been determined that the incorporation of a reburner 30 and/or the feeding of a reagent into the top compartment of the second wind box 4 can permit adequate residence time within the second and third combustion zones 5 b and 5 c to complete combustion of the fuel passing therethrough and can eliminate a need for additional furnace height that may be required in a conventional furnace that utilizes a reburner on top of an unstaged combustion system or after a final over fire air wind box.
- embodiments of the combustion apparatus and plant that utilize the feeding of a reagent in the second combustion zone 5 b can help facilitate a reduction in NO x formation.
- the reduction in NO formation can be further improved by integration of the feeding of the reagent into the second combustion zone 5 b with the feeding of fuel into the second combustion zone 5 b via the reburner 30 .
- FIGS. 5-9 it has been determined that a reduction of between 65-70% in the formation of NO x from the combustion of coal fed to the first combustion zone 5 a of a combustion apparatus 5 can be facilitated by utilization of the reburner 30 in combination with reagent injection via the second wind box 4 for embodiments of the plant 1 and combustion apparatus 5 disclosed herein.
- NO x emissions can be reduced to below 0.10 pound/10 6 BTU (e.g. between 0.03 to 0.10 pound/10 6 BTU).
- Such low NO x emissions can be achieved while maintaining acceptable levels of unburned carbon, carbon monoxide emissions, and unreacted ammonia.
- the reduction in NO x emissions can be obtained more efficiently with less heat input provided by the reburner as compared to conventional systems as can be seen from FIG. 7 .
- This can allow for embodiments to be configured so that the quantity of reburn fuel used is lower as compared to conventional designs while also providing for a substantial reduction in NO x emissions.
- FIG. 7 can allow for embodiments to be configured so that the quantity of reburn fuel used is lower as compared to conventional designs while also providing for a substantial reduction in NO x emissions.
- the reduction in NO x formation that can be facilitated by embodiments, can allow coal to be used as a fuel that has a fuel ratio under 3.0, so that a larger array of fuel options can be utilized in the combustion apparatus 5 while still complying with emission requirements, which can allow embodiments of the plant to be utilized that operate at a lower fuel operating cost.
- embodiments of the plant and combustion apparatus may utilize a control system to control operation of the combustion apparatus and plant.
- the control system can include hardware such as a processor, memory, and a transceiver and be configured to communication with sensors and valves and other plant elements to monitor operation of the plant 1 and combustion apparatus 5 and communicate with those plant elements to adjust operational parameters of the plant 1 and combustion apparatus 5 .
- the source of air 17 may provide a flow of oxygen containing gas via an air separation unit for some embodiments of the plant and combustion apparatus.
- the temperature and pressures at which the combustion apparatus is to operate may vary to accommodate different design objectives or performance objectives.
- the type of reagent and/or type of fuel fed into the second combustion zone 5 b may be any type of suitable reagent and/or fuel that accommodates a particular set of design criteria.
- the number of fans or pumps and positioning of such fans or pumps utilized to control flow rates of fluid or fuel to the combustion apparatus can be any configuration that is able to meet a particular set of design criteria.
- the reburner 30 can be configured to inject fuel, the reagent and/or flue gas into the second combustion zone 5 b via only one outlet or in multiple feed outlets positioned in the second combustion zone 5 b (e.g. at outlets that are each located in a respective corner of the combustion chamber in the second combustion zone 5 b ).
- some embodiments of the plant can include a gas processing unit 13 that has one or more elements to facilitate carbon capture from the flue gas.
Abstract
A combustion apparatus includes a combustion chamber having multiple combustion zones. A first wind box is in communication with the first combustion zone to feed the fuel to be fed into the combustion chamber for initial combustion of the fuel within the first combustion zone. A second wind box has a reburner in communication with the second combustion zone. The reburner is configured to feed fuel, a reagent and a first portion of the flue gas to be recycled to the second combustion zone into the second combustion zone to reduce nitrogen oxide emissions of the apparatus. A third wind box is in communication with the third combustion zone to feed air to the third combustion zone to complete the combustion process.
Description
- The present innovation is related to apparatuses configured to combust a fuel and methods of making and using the same, and more specifically a combustion apparatus for burning a fuel with reduced NOx emissions.
- Combustion systems can include combustors such as a boiler, an incinerator system, or a furnace. Examples of combustion systems are disclosed in U.S. Pat. Nos. 4,719,587, 5,315,939, 5,443,805, 5,626,085, 6,258,336, 6,598,399, 8,375,723, and 8,434,311 and European Patent No. 1 530 994. Pollutants such as nitrogen oxides (e.g. NO, NO2, NOx) and sulfur oxides (e.g. SO2, SO3, SOx) can be emitted from operation of combustion systems. Operators of combustion systems may utilize pollution control equipment (e.g. desulfurization units, scrubbers, etc.) to help ensure clean and environmentally sound operation of the combustion systems.
- According to aspects illustrated herein, a combustion apparatus includes a combustion chamber having multiple combustion zones for combustion of fuel. The combustion zones can include a first combustion zone, a second combustion zone, and a third combustion zone. The second combustion zone can be located between the first and third combustion zones. The combustion chamber can have at least one outlet configured to emit flue gas formed from combustion of the fuel in the combustion chamber. A first wind box can be in communication with the first combustion zone for feeding of fuel into the combustion chamber for initial combustion within the first combustion zone. A second wind box can be configured to feed a gas having oxygen into the second combustion zone. A third wind box can be in communication with the third combustion zone to feed a gas having oxygen into the third combustion zone. A conduit provides a reagent to the second combustion zone.
- According to other aspects illustrated herein, a method of operating a combustion apparatus can include the step of feeding a first fuel into a combustion chamber having multiple combustion zones for combustion of the first fuel. The combustion zones can include a first combustion zone, a second combustion zone, and a third combustion zone. The second combustion zone can be located between the first and third combustion zones. The vessel can have at least one outlet configured to emit flue gas from the combustion chamber after the flue gas is formed from combustion of the first fuel. The method can also include the step of feeding a gas having oxygen and a reagent to the second combustion zone. Further, the method includes feeding a gas having oxygen to the second combustion zone.
- The above described and other features are exemplified by the following figures and Detailed Description.
- Exemplary embodiments of an apparatus, a plant, and associated exemplary methods are shown in the accompanying drawings. It should be understood that like reference numbers used in the drawings may identify like components, wherein:
-
FIG. 1 is a schematic diagram of an exemplary embodiment of a plant in accordance with the present invention. -
FIG. 2 is a cross-sectional view of an embodiment of a reburner disposed in an upper compartment of a second wind box of a combustion apparatus in accordance with the present invention. -
FIG. 3 is a block diagram illustrating a plurality of stacked compartments of respective vertically-aligned first, second and third wind boxes to provide material to a combustion apparatus of a plant in accordance with the present invention. -
FIG. 4 is a fragmentary side view of an exemplary air nozzle disposed within a compartment of a third wind box to provide air to a third combustion zone of a combustion chamber of a plant in accordance with the present invention. -
FIG. 5 is a bar graph illustrating an amount of nitrogen oxides (NOx) that may be emitted from acombustion apparatus 5 using different types of fuel, types A, B, C, D, and E for 3 different configurations of combustion apparatus. Type A is a low volatile bituminous coal, type B is a medium volatile bituminous coal, type C is a high volatile bituminous coal, type D is a subbituminous coal, and type E is lignite. The vertical axis of the chart identifies the amount of NOx emitted as a ratio in which a pound of NOx is emitted per every million British Thermal Unit (BTU) of heat fired from the combustion of the fuel fed into thecombustion apparatus 5. The horizontal axis of the chart identifies the type of fuels being compared. A conventional combustion apparatus is identified asbars 61 in the chart, an embodiment of the combustion apparatus disclosed herein that only utilizes a reburner without the feeding of a reagent is identified asbars 62 in the chart and an embodiment of the combustion apparatus that utilizes a reburner and the feeding of a reagent into the second combustion zone, which is identified asbars 63 in the chart. -
FIG. 6 is a graph illustrating a percentage reduction of NOx versus the stoichiometry within the second combustion zone of a combustion apparatus in accordance with the present invention. As shown in the vertical axis of the graph, that was calculated for given stoichiometries within thesecond combustion zone 5 b for embodiments of the plant andcombustion apparatus 5. The stoichiometry ratio within thesecond combustion zone 5 b for the combustion apparatus is identified in the horizontal axis of the graph. The stoichiometry ratio expresses a ratio for an amount of the oxygen needed to fully combust the fuel within thesecond combustion zone 5 b as compared to the amount of fuel within thesecond combustion zone 5 b. A number over 1.0 indicates that that there is an excess of oxygen needed to fully combust the fuel and a number below 1.0 indicates that there is not enough oxygen to completely combust the fuel within the second combustion zone. TheLine 71 of the graph refers to an embodiment of the combustion apparatus in which only areburner 30 of thesecond wind box 4 is utilized.Line 72 of the graph identifies an embodiment of the combustion apparatus in which only the feeding of a reagent via thesecond wind box 4 of the combustion apparatus is utilized.Line 73 of the graph identifies an embodiment of the combustion apparatus that utilizes both thereburner 30 and the feeding of the reagent via thesecond wind box 4. -
FIG. 7 is a graph illustrating a percentage of the reburn NOx reduction efficiency as compared to a percentage of heat input provided by the reburner fuel fed into the second combustion zone as compared to the entire amount of fuel fed into the combustion apparatus for embodiments of the combustion apparatus in accordance with the present invention. The vertical axis of the graph ofFIG. 7 identifies the percentage of the NOx reduction efficiency and the horizontal axis of the graph identifies the percentage of heat input provided by the fuel fed into thesecond combustion zone 5 b via thereburner 30 as compared to the total amount of fuel fed into the combustion apparatus for combustion.Line 74 of the graph ofFIG. 7 illustrates the calculated results for an embodiment of the combustion apparatus utilizing thereburner 30 of thesecond wind box 4 as well as the feeding of a reagent into thesecond combustion zone 5 b.Line 75 of the graph ofFIG. 7 illustrates the calculated results from a conventional combustion apparatus utilizing a conventional reburner system. -
FIG. 8 is a graph illustrating an extent of the reburn of NOx reduction efficiency provided by an embodiment of the combustion apparatus as compared to an amount of NOx fed from the first combustion zone into thesecond combustion zone 5 b in parts per million volumetric dry (ppmvd) concentration based on a reference percentage oxygen. The vertical axis of the graph ofFIG. 8 illustrates that the NOx reduction efficiency is independent of the inlet NOx concentration entering thesecond combustion zone 5 b. A calculated maximum efficiency level (MAX) is identified on the vertical axis. The horizontal axis of the graph ofFIG. 8 is the amount of the NOx initially fed into thesecond combustion zone 5 b in ppmvd concentration referenced to percentage oxygen. -
FIG. 9 is a graph illustrating an extent of the reburn of NOx reduction efficiency provided by an embodiment of the combustion apparatus as compared to a fuel ratio of the fuel being fed into the combustion apparatus for combustion in accordance with the present invention. The fuel ratio defined as the fixed carbon to volatile ratio from a fuel's proximate analysis is identified in the horizontal axis of the graph ofFIG. 9 . The fuel ratio is a measure of the reactivity of a fuel. The vertical axis of the graph ofFIG. 9 illustrates calculated levels of NOx reduction efficiency and identifies a calculated maximum efficiency level (MAX). -
FIG. 10 is a plan view of a combustion chamber of a tangentially-fired system in accordance with the present invention. - Other details, objects, and advantages of embodiments of the innovations disclosed herein will become apparent from the following description of exemplary embodiments and associated exemplary methods.
- Referring to
FIGS. 1-4 , aplant 1 is shown that is configured to generate electricity. In some embodiments, the plant can be an industrial plant, a power plant, or an electricity generation plant. Theplant 1 includes acombustion apparatus 5, such as, for example, a boiler or a furnace. Thecombustion apparatus 5 can include a vessel defining acombustion chamber 10. Fuel is provided to and combusted in thecombustion chamber 10 which generates a flue gas having steam and other combustion products (e.g. carbon dioxide, nitrogen, oxygen, water vapor, etc.). The combustion process can be utilized to heat water and steam which can be used to generate electricity and/or other desirable process elements that can be used downstream of thecombustion apparatus 5. The flue gas formed in thecombustion chamber 10 of thecombustion apparatus 5 may be provided to at least oneoutlet 7. - Heat from the flue gas can be transferred to water, steam and/or other fluids passing through water wall tubes (not shown) or other heat exchangers to generate heated gas or fluid for use by a
generator unit 19 of theplant 1. For instance, flue gas passing through theoutlet 7 may pass through one or more heat exchangers (i.e., superheaters and economizers) for heating water and/or steam to be fed to a turbine of thegenerator unit 19 to generate electricity. - The fuel can be a fossil fuel such as coal, oil, or natural gas or any another type of carbonaceous fuel. The fuel can be fed from a
first fuel source 3. Thefirst fuel source 3 may include, for example, a coal mill that is configured to comminute coal and mix the comminuted coal with air for feeding the fuel to thecombustion apparatus 5. In other embodiments, the source of fuel for thefirst fuel source 3 may be a vessel or other storage device that retain the fuel, such as pulverized coal, natural gas or oil for feeding to thecombustion apparatus 5. - As best shown in
FIG. 1 , thecombustion chamber 10 of thecombustion apparatus 5 can includemultiple combustion zones combustion zones second combustion zone 5 b is located between the first andthird combustion zones combustion chamber 10 along its longitudinal axis, thesecond combustion zone 5 b is an intermediate combustion zone within thecombustion chamber 10 that is vertically higher than and downstream of thefirst combustion zone 5 a and vertically lower than and upstream of thethird combustion zone 5 c. Similarly for embodiments in which the longitudinal axis of thecombustion chamber 10 is horizontal, thesecond combustion zone 5 b may be disposed intermediate to thefirst combustion zone 5 a and thethird combustion zone 5 c, both of which are disposed at opposing ends of thecombustion chamber 10. Eachcombustion zone - As best shown in
FIGS. 1 and 3 , a plurality ofwind boxes respective combustion zones combustion chamber 10 to provide the material needed for combustion. Eachwind box combustion chamber 10 of thecombustion apparatus 5. For instance, afirst wind box 2 provides material to thefirst combustion zone 5 a. Asecond wind box 4 provides material to thesecond combustion zone 5 b. Athird wind box 6 provides material to thethird combustion zone 5 c. Fuel from thefirst fuel source 3 can be fed to thefirst wind box 2 via a fuel feed conduit connected between thefirst fuel source 3 and thefirst wind box 2 to provide the fuel to thefirst combustion zone 5 a. Air from a source ofair 17 is also provided to thefirst wind box 2 via an air feed conduit connected between the source ofair 17 and thefirst wind box 2. At least one fan or other type of air flow driving mechanism (not shown) can be included in the source ofair 17 or may be in communication with the source of air to drive the flow of air from the source ofair 17 into thefirst combustion zone 5 a via thefirst wind box 2. The air may be mixed with the fuel prior to the fuel and the air being provided into thefirst wind box 2 or into thefirst combustion zone 5 a. The fuel and air provided into thefirst combustion zone 5 a via thefirst wind box 2 may be fed to the first combustion zone for initial combustion of the fuel in thefirst combustion zone 5 a. While theair source 17 provides air, the present invention contemplates theair source 17 may provide any gas having oxygen, including a pure oxygen stream. - An exemplary structure of the first, second, and
third wind boxes FIG. 3 . Thefirst wind box 2 can be configured as a main wind box and the second andthird wind boxes second wind box 4 can be configured as a lower separated over fire air wind box and thethird wind box 6 can be configured as an upper separated over fire air wind box. - The
first wind box 2 can be configured to includemultiple compartments 2 a-2 q that are positioned in longitudinal or vertical alignment for the feeding of fuel and other material into thefirst combustion zone 5 a. For example, thefirst wind box 2 may include first andsecond compartments first combustion zone 5 a. Thethird compartment 2 c,sixth compartment 2 f, tenth compartment 2 j, andseventeenth compartment 2 q can be configured to feed air or oxygen to thefirst combustion zone 5 a. The fourth, eighth, twelfth, and sixteenthcompartments first fuel source 3 to thefirst combustion zone 5 a. Thefifth compartment 2 e,seventh compartment 2 g,ninth compartment 2 i,eleventh compartment 2 k,thirteenth compartment 2 m, and fifteenth compartment 2 o can be configured to provide additional offset air to thefirst combustion zone 5 a. Thefourteenth compartment 2 n can be configured to feed fuel from thesecond fuel source 3 a as indicated by broken line inFIG. 1 for startup and shut-down operations of thecombustion apparatus 5 when the second fuel source is natural gas or oil. In some embodiments, thefourteenth compartment 2 n can be configured to feed oil, natural gas, or other fuel source from a third fuel source (not shown). The combustion region above the close coupled over fire air (CCOFA) compartments 2 a, 2 b of thefirst wind box 2 and below thesecond wind box 4 is the burnout region of thefirst combustion zone 5 a where combustion continues above or downstream of the first wind box. - The
second wind box 4 andthird wind box 6 can each be configured to have fewer compartments than thefirst wind box 2. For instance, thesecond wind box 4 can be configured to include anupper compartment 4 a, alower compartment 4 c, and anintermediate compartment 4 b that is between the upper andlower compartments topmost compartment 4 a can include areburner 30 in some embodiments. Thereburner 30 can be the sole reburner for feeding fuel into thesecond combustion zone 5 b in some embodiments. In addition, a reagent can also be fed into the second combustion zone via theupper compartment 4 a in addition to the use of thesole reburner 30 or as an alternative to thereburner 30. The intermediate andlower compartments second combustion zone 5 b. The combustion region above thesecond wind box 4 and below thethird wind box 6 is the burnout region of thesecond combustion zone 5 a where combustion and reaction of the reagent continues above or downstream of the second wind box. - The
third wind box 6 can also have upper, intermediate andlower compartments third wind box 6 can be configured to feed air into thethird combustion zone 5 c. The combustion region above the upper separated over fire air (SOFA) compartments 6 a, 6 b, 6 c of thethird wind box 6 is the burnout region of thethird combustion zone 5 a where combustion continues above or downstream of the third wind box. - The first, second and
third wind boxes combustion apparatus 5 so that the pitch and yaw of the flow of fluid is adjustable. For instance, as may be appreciated fromFIG. 4 , thethird wind box 4 can be configured to include anair nozzle assembly 43 having atilting mechanism 45 that can be actuated to vertically tilt thenozzles 44 through which material, for example air, is output from thecompartments third wind box 6 to adjust the pitch (i.e., vertical tilt) at which the material is fed into thethird combustion zone 5 c and to actuate horizontal adjustment via ahorizontal adjustment mechanism 46 to adjust the yaw (i.e., horizontal angle) at which the material is fed into thethird combustion zone 5 c. Thetilting mechanism 45 may include at least one actuator (e.g. a pneumatic or electric cylinder) that is connected to thetilting mechanism 45 for actuating vertical adjustments (pitch) of thenozzles 44. Thesecond wind box 4 can also include atilting mechanism 45 for adjusting the pitch and yaw of thenozzles 44 providing material (for example air) from the top, intermediate andbottom compartments second wind box 4 into thesecond combustion zone 5 b of thecombustion apparatus 5 in one embodiment. Alternatively, thenozzle assembly 43 may include atilt mechanism 45 for a pair ofnozzles 44 that provide air to the intermediate andlower compartments upper compartment 4 a provides thereburner 30 and/or reagent. - Fuel can also be fed to a fuel nozzle 30 (see
FIG. 2 ) of thereburner 30 which provides fuel to thesecond combustion zone 5 b of thecombustion chamber 10 for combustion therein. The fuel fed to thesecond combustion zone 5 b can be fuel from the first and/orsecond fuel source second fuel source 3 a to thesecond wind box 4 for feeding the fuel to thesecond combustion zone 5 b via thesecond wind box 4. The fuel of thesecond fuel source 3 a can be different than the fuel from thefirst fuel source 3. For example, the fuel of thefirst fuel source 3 can be coal and the fuel of thesecond fuel source 3 a can be natural gas or oil. As another example, the fuel of thefirst fuel source 3 may be a first type of coal and the fuel of thesecond fuel source 3 a may be another type of coal (e.g. micronized coal). In other embodiments, the fuel fed into thesecond combustion zone 5 b can be from thefirst fuel source 3 as indicated by broken line inFIG. 1 so that the same type of fuel is fed to the first andsecond combustion zones - In some embodiments, the amount of fuel fed from the
second fuel source 3 a to thereburner 30 of thesecond wind box 6 may be between 10-15% of the total amount of heat fired from the fuel fed to thecombustion apparatus 5 for combusting therein. It has been determined that use of a second type of fuel at thesecond combustion zone 5 b can provide a reduced amount of NOx, sulfur oxides (e.g. SO2, SO3, etc.), carbon dioxide, and other pollutants (e.g. particulates such as fly ash) being formed in the flue gas formed from combustion of fuel in the combustion chamber of thecombustion apparatus 5. For example, use of natural gas as the fuel of thesecond fuel source 3 a when coal is used as the fuel of thefirst fuel source 3 can help reduce the amount of NOx, sulfur oxides, particulates, and carbon dioxide formed from further combustion of the second fuel added at thesecond combustion zone 5 b as compared to the use of the same coal as fed to thefirst combustion zone 5 a. - The
second wind box 4 can also be configured to receive flue gas and a reagent for feeding into thesecond combustion zone 5 b. The reagent can be received from a source of thereagent 15, which may be a vessel, tank or other storage device that retains the reagent. The reagent may be stored therein. The reagent may be urea, ammonia, an amine based chemical compound (e.g. methylamine, a primary amine, a secondary amine, a tertiary amine, or a cyclic amine, etc.) or another type of reagent that can be fed into the combustion chamber to remove nitrogen oxides (NOx) or elements that contribute to the formation of NOx from the flue gas formed when the fuel is combusted. The reagent may be in a liquid state or a gaseous state. For example, in some embodiments the urea may be an aqueous urea mixture (e.g. urea mixed with water), the ammonia may be an aqueous ammonia (e.g. ammonia mixed with water), or the reagent may be another type of aqueous state reagent that is suitable for being sprayed into the second combustion zone via a mechanical spray mechanism or an atomizer mechanism. As another example, the reagent may be in a gaseous state such as anhydrous ammonia, an anhydrous urea or other type of anhydrous reagent. In some embodiments, a portion of the reagent material may be from other process elements of the plant that emit the reagent and send that reagent to the source of thereagent 15 for temporary storage until it is fed to thesecond combustion zone 5 b. The source of thereagent 15 can be connected to thesecond wind box 4 via a reagent feed conduit. - A portion of flue gas emitted from an
outlet 7 of thecombustion apparatus 5 can be recycled to the nozzle orreburner 10 disposed in thesecond wind box 4 for feeding the flue gas, reagent and fuel into thesecond combustion zone 5 b. The recycled flue gas to be recycled to thesecond wind box 4 may first pass through aneconomizer 9 positioned in theoutlet 7. Theeconomizer 9 can be configured to transfer heat from the flue gas passing therethrough to another fluid (e.g. water) that passes through theeconomizer 9 to heat that fluid to a pre-selected temperature for use in another process element of theplant 1, and thereby cool the flue gas prior to being recycled. Aflow control mechanism 11, such as a fan or other type of gas flow driving mechanism, may be used to drive the flue gas to be recycled back to thecombustion apparatus 5 from theeconomizer 9 to thesecond wind box 6. Another portion of the flue gas may be provided to agas processing unit 13 via a gas processing unit feed conduit. - The
gas processing unit 13 can be configured to remove fly ash, sulfur oxides, and other elements from the flue gas prior to that flue gas being emitted from theplant 1 or used in another plant process. For instance, thegas processing unit 13 may include a precipitator, a bag house, a desulfurization unit, and other gas processing elements that are configured to remove elements from the flue gas prior to the flue gas being emitted from theplant 1 and/or utilized in another plant process. - In one embodiment as describe hereinbefore, the
second wind box 4 can also include a reburner orfuel nozzle 30. An example of areburner 30 is shown inFIG. 2 . Thereburner 30 can be positioned in anupper compartment 4 a of thesecond wind box 4. For instance, in some embodiments asole reburner 30 may be the only reburner of thesecond wind box 4 and may be located at thetop compartment 4 a of thesecond wind box 4 or may be located in thecompartment 4 a of the second wind box that is closest to thethird combustion zone 5 c. Thereburner 30 may be disposed in thesecond wind box 4 so that thesecond combustion zone 5 b receives a flow offlue gas 21 from the recycle conduit after that flue gas has passed through theeconomizer 9, a flow ofreagent 23 from the source of thereagent 15, and a flow offuel 25 from thefirst fuel source 3 or thesecond fuel source 3 a so that the reagent, flue gas, and fuel can be simultaneously fed to thesecond combustion zone 5 b. In some embodiments, the reagent, fuel and flue gas can be fed in thesecond combustion zone 5 b via aconcentric ring nozzle 39. One will appreciate that the flue gas functions as a carrier gas to improve penetration and distribution of the gaseous reagent into thesecond combustion zone 5 b to enable more efficient reaction between the reagent and the flue gas flowing through thecombustion chamber 10. The recycled flue gas further increases the mass and volume of the flue gas and reagent mixture to increase the penetration and distribution of the gaseous reagent into thesecond combustion zone 5 b. - While recycled flue gas is provided to the
reburner 30 to function as a carrier gas to optimize penetration of the reagent into thesecond combustion zone 5 b, one will appreciate that the carrier gas may be any oxygen-deficient carrier gas, for example steam, to provide the optimum stoichiometric condition within thesecond combustion zone 5 b. Depending upon the amount of reagent being provided to thecombustion chamber 10 and the condition within the combustion chamber, the carrier gas (e.g., flue gas and steam) may not be needed. In another embodiment, the reagent may be injected as a liquid wherein a carrier gas may not be needed. For example, a pump or other type of liquid reagent flow control device (not shown) can be in communication with a liquidreagent storage vessel 15 and be configured to drive the flow of the liquid reagent into thesecond combustion zone 5 b. In this embodiment, the liquid reagent can be fed via an atomizer that is configured to inject the reagent as an atomized liquid spray to inject the liquid reagent into thesecond combustion zone 5 b to help facilitate optimum penetration and mixing of the liquid reagent with the flue gas flowing through thecombustion chamber 10. Embodiments that utilize a liquid reagent for injection into thesecond combustion chamber 5 b can allow for the removal of a carrier gas (e.g. flue gas or steam) and may allow for the elimination of costly equipment, such as gas recirculation fans, ductwork, and controls for such elements. - While the reagent is shown to be provided to the
second combustion zone 5 b through thereburner 30 orsecond wind box 4, one will appreciate that the reagent can be injected at a location above thesecond wind box 4. For instance, the reagent may be injected at a location above thereburner 30 and/or thesecond wind box 4, but below thethird wind box 6. Reagent injection can also be provided at this location, provided the injection location is disposed at a sufficient distance from thethird wind box 6 to provide sufficient resident time for the reagent to react with the flue gas. - The invention further contemplates that the feeding of the fuel and/or reagent to the
second combustion zone 5 b may be selectively stopped by a control valve in response to the stoichiometric conditions within thecombustion chamber 10, such that fuel or reagent is provided to the second combustion zone of the combustion chamber via the upper portion of thesecond wind box 4. - The use of the reburner 30 can help provide a reduction of NOx emissions based upon the injection of the fuel into the second combustion zone so that an oxygen deficient volume within the second combustion zone exists so that the reburn fuel can help break down the formation of nitrogen containing hydrocarbon radicals that can contribute to formation of NOx when reacting with the products of the combustion of the fuel fed into the first combustion zone 5 a. Hydrocarbon radicals from the fuel fed into the second combustion zone 5 b can function to strip the oxygen from the NOx to form elemental nitrogen, water vapor, carbon monoxide, carbon dioxide, and other reduced species and compounds. One of the primary chemical NOx destruction mechanisms of the reburn process via the fuel fed to the second combustion zone 5 b is set forth below:
- High temperature reagent injection utilizing the reagent from the upper compartment of the
second wind box 4 can provide a further mechanism for reducing NOx based on producing amine radicals. The chemical NOx destruction mechanism of the high temperature reagent injection process can be illustrated by the formula: NO+NH2→N2+H2O. - The amount of fuel and/or reagent injected into the
second combustion zone 5 b can be a relatively small amount as compared to the volume of flue gases generated from combustion of the fuel in thefirst combustion zone 5 a that subsequently passes into thesecond combustion zone 5 b. A higher reburn fuel feed velocity and/or reagent feed velocity can help provide effective penetration and rapid mixing of the reagent and fuel. Fuel and/or reagent feed line pressures can be set to help ensure that the fuel and/or reagent is fed into thesecond combustion zone 5 b at a pre-selected velocity to facilitate effective penetration and mixing. The mixing of the reagent can also be facilitated by use of an atomized liquid spray mechanism. The flue gas fed to thesecond wind box 4 can also help facilitate the higher velocities of the reagent and/or fuel fed to thesecond combustion zone 5 b. The recycled flue gas can be considered a carrier gas that is output with the fuel and/or reagent to provide an output of the fuel and/or reagent at a pre-selected velocity. - Referring to
FIG. 2 , thereburner 30 can include abody 33, which can be configured as a lance, an injector, an eductor, a swirl body, or other type of body. Thebody 33 can include aninlet end 33 a and anoutlet end 33 b. Thefuel 25 may be received in the inlet end 33 a and subsequently pass out of theoutlet end 33 b of thebody 33 toward thesecond combustion zone 5 b. Thebody 33 can receive the flow offuel 25 and be positioned within a portion of an upper compartment of thesecond wind box 4 so that it is structured to facilitate mixing of the flow of fuel with a flow of thereagent 23 that may pass along thebody 33. Thebody 33 can have holes along a periphery of the body so that the fuel can pass out of these holes and into apassageway 35 defined between the exterior of thebody 33 and the wall of an inner conduit defining aninner passageway 35 through which the reagent and fuel can pass through toward thesecond combustion zone 5 b via thesecond wind box 4. - A
nozzle tip 39 can be pivotally connected to the inner conduit defining theinner passageway 35 in which thebody 33 is positioned by atilting connection 31. Thetilting connection 31 allows thenozzle tip 39 to be tilted vertically about an axis, which can also adjust the flow direction of the flow offlue gas 21 passing through theouter passageway 37. For instance, thetilting connection 31 of thenozzle tip 39 can permit the pitch angles of the flow of the flue gas, reagent, and fuel being fed into thesecond combustion zone 5 b via thereburner 30 to be adjusted at the same time via tilting of thenozzle tip 39. - The flow of the
recycled flue gas 21 or other oxygen deficient carrier gas can pass through anouter passageway 37 that surrounds theinner passageway 35 and fuel passageway defined by thebody 33 that is within theinner passageway 35. The flow of theflue gas 21 can be a first portion of the flue gas that is recycled from theoutlet 7 andeconomizer 9 back to thesecond combustion zone 5 b of thecombustion apparatus 5. - The flow of the
flue gas 21 can pass through the second feed conduit andwind box 4 and out of aconcentric nozzle tip 39. The direction of the flow of the flue gas passing through theouter passageway 37 to thesecond combustion zone 5 b can be adjusted by tilting of thenozzle tip 39 at which the flue gas passes into thesecond combustion zone 5 b. Tilting of thenozzle tip 39 changes the size and shape of the opening of theouter passageway 37 to adjust the flow velocity profile of the flue gas passing through theouter passageway 37 to thesecond combustion zone 5 b. - The second and
third wind boxes air 17 for feeding into the second andthird combustion zones combustion chamber 10. In other embodiments, the second andthird wind boxes third combustion zones third wind boxes - The flow rate of oxygen containing gas fed into the first, second and
third combustion zones 5 a-5 c via the first, second andthird wind boxes combustion apparatus 5 having fuel (via a reburner 30) and a reagent being provided into thesecond combustion zone 5 b of the combustion chamber of the present invention, the stoichiometry or the amount of oxygen within the gas fed to the first combustion zone via thefirst wind box 2 can be between 50-70% of the oxygen needed to fully combust the fuel. Thefirst wind box 2 can also include close-coupled over fired air (CCOFA) compartments for feeding an oxygen containing gas (e.g. air or other type of oxidant flow) into the first combustion zone to increase stoichiometry or the amount of oxygen within the upper portion (a reburn zone) of the first zone to be between 70-96% of the oxygen needed to fully combust the fuel. The amount of oxygen within the gas fed to thesecond combustion zone 5 b via thesecond wind box 4 can be configured to increase stoichiometry or the amount of oxygen within thesecond combustion zone 5 b of the combustion chamber to be between 96-105% of the oxygen needed to fully combust the fuel, so that at least 96% of the fuel in thesecond combustion zone 5 b would be combusted therein, and at most 105% of the fuel within thesecond combustion zone 5 b would be combusted therein (e.g. there is a 5% excess of oxygen needed to fully combust the fuel passing through thesecond combustion zone 5 b) via the oxygen within the gas fed into thesecond combustion zone 5 b via thesecond wind box 4. The amount of oxygen fed into thethird combustion zone 5 c via thethird wind box 6 can be configured to increase the stoichiometry or the amount of oxygen needed to fully combust the fuel passing through thethird combustion zone 5 c so that more than 105% of the fuel within the third combustion zone would be combustible in the third combustion zone (e.g. there is an excess of oxygen so that there is between 15%-25% more oxygen than theoretically needed to fully combust the fuel within thethird combustion zone 5 c). - In another embodiment of the present invention, the
combustion apparatus 5 is similar to the combustion apparatus described herein having areburner 30 however, this embodiment does not include thereburner 30 for providing fuel to thesecond combustion zone 5 b. In this other embodiment, the reagent is provided to the second combustion zone as described hereinbefore. For example, only the reagent may be fed into thesecond combustion zone 5 b at such a location above thesecond wind box 4 and below thethird wind box 6 without the use of any reburner or the feeding of reburn fuel into thesecond combustion zone 5 b For such embodiments, the reagent injection system can be positioned for injection of the reagent so that there is a sufficient residence time within the combustion chamber prior to the flow of fluid entering thethird combustion zone 5 c to allow for the reagent to react with elements of the fluid passing through the combustion chamber to facilitate removal of elements that can contribute to formation of NOx. Alternatively, the reagent may be injected or provided to theupper chamber 4 a of thesecond wind box 4 as a liquid or gas, which may be mixed with over fire air and/or an oxygen deficient carrier gas, such as recycled flue gas, steam or other oxygen-deficient gas. Alternatively, the reagent and flue gas can be fed separately, but at the same time, into thesecond combustion zone 5 b via thesecond wind box 4 such that the flue gas acts as a carrier gas to help penetrate and disperse the reagent into thesecond combustion zone 5 b. In yet other embodiments, the reagent may be injected into thesecond combustion zone 5 b as a liquid such that no carrier gas is utilized to facilitate injection of the reagent into thesecond combustion zone 5 b. - For embodiments which do not include a
reburner 30 and where fuel is not fed into thecombustion chamber 10 at thesecond combustion zone 5 b, the stoichiometry for low NOx formation can be changed within each of thecombustion zones combustion apparatus 5 to provide low NOx formation within the flue gas formed via combustion of the fuel. The stoichiometry within each of the combustion zones of the combustion apparatus can be configured for such embodiments having noreburner 30 or fuel provided to thesecond combustion zone 5 b, wherein thefirst combustion zone 5 a has a stoichiometry between 50% and 70% of the oxygen needed to fully combust the fuel within thefirst combustion zone 5 a and 70-85% of the oxygen needed to fully combust the fuel within the upper portion (the reburn zone) of thefirst combustion zone 5 a. The stoichiometry or the amount of oxygen within thesecond combustion zone 5 b can be between 85-95% of the oxygen needed for full combustion of the fuel within thesecond combustion zone 5 b. Thethird wind box 6 can be configured to provide oxygen within the gas fed into thethird combustion zone 5 c so that the stoichiometry or the amount of oxygen therein is more than 95% of the oxygen (e.g. 95% to more than 105% of the oxygen needed to fully combust the fuel within thethird combustion zone 5 c) is present in the third combustion zone. - The present invention further contemplates that the
combustion apparatus 5 can be configured for tangential firing and includes a tangential firing system, similar to that described in U.S. Pat. No. 5,315,939, which is incorporated herein by reference. As shown inFIG. 10 , thewind boxes FIGS. 1 and 2 may be located at the four corners of thecombustion chamber 10.FIG. 1 schematically shows thecomplementary wind boxes combustion chamber 10. As shown inFIG. 10 , the air and fuel nozzles disposed in the compartments of thewind boxes fireball 80 flowing in a circular pattern. In the tangentially fired system ofFIG. 10 , the fuel via areburner 30 and/or the reagent may be provided by or above thesecond wind boxes combustion chamber 10 in any combination of locations or corners. Alternatively, the one or morestacked wind boxes combustion chamber 10 to provide a wall firing combustion system or apparatus. - Embodiments of the
combustion apparatus 5 andplant 1 can be configured so that a furnace orcombustion chamber 10 having a shorter height or length as compared to conventional furnaces may be utilized, which can reduce the costs associated with material, fabrication, maintenance and operation of embodiments of the plant or embodiments of the combustion apparatus. For instance, it has been determined that the incorporation of areburner 30 and/or the feeding of a reagent into the top compartment of thesecond wind box 4 can permit adequate residence time within the second andthird combustion zones second combustion zone 5 b can help facilitate a reduction in NOx formation. The reduction in NO formation can be further improved by integration of the feeding of the reagent into thesecond combustion zone 5 b with the feeding of fuel into thesecond combustion zone 5 b via thereburner 30. For example, as can be appreciated fromFIGS. 5-9 , it has been determined that a reduction of between 65-70% in the formation of NOx from the combustion of coal fed to thefirst combustion zone 5 a of acombustion apparatus 5 can be facilitated by utilization of thereburner 30 in combination with reagent injection via thesecond wind box 4 for embodiments of theplant 1 andcombustion apparatus 5 disclosed herein. For some embodiments, NOx emissions can be reduced to below 0.10 pound/106 BTU (e.g. between 0.03 to 0.10 pound/106 BTU). Such low NOx emissions can be achieved while maintaining acceptable levels of unburned carbon, carbon monoxide emissions, and unreacted ammonia. Further, the reduction in NOx emissions can be obtained more efficiently with less heat input provided by the reburner as compared to conventional systems as can be seen fromFIG. 7 . This can allow for embodiments to be configured so that the quantity of reburn fuel used is lower as compared to conventional designs while also providing for a substantial reduction in NOx emissions. Moreover, as can be appreciated fromFIG. 9 , the reduction in NOx formation that can be facilitated by embodiments, can allow coal to be used as a fuel that has a fuel ratio under 3.0, so that a larger array of fuel options can be utilized in thecombustion apparatus 5 while still complying with emission requirements, which can allow embodiments of the plant to be utilized that operate at a lower fuel operating cost. - It should be appreciated the different modifications can be made to embodiments of the plant, combustion apparatus, and method of utilizing the same to meet different sets of design criteria. For instance, embodiments of the plant and combustion apparatus may utilize a control system to control operation of the combustion apparatus and plant. The control system can include hardware such as a processor, memory, and a transceiver and be configured to communication with sensors and valves and other plant elements to monitor operation of the
plant 1 andcombustion apparatus 5 and communicate with those plant elements to adjust operational parameters of theplant 1 andcombustion apparatus 5. As another example, the source ofair 17 may provide a flow of oxygen containing gas via an air separation unit for some embodiments of the plant and combustion apparatus. As yet another example, the temperature and pressures at which the combustion apparatus is to operate may vary to accommodate different design objectives or performance objectives. As yet another example, the type of reagent and/or type of fuel fed into thesecond combustion zone 5 b may be any type of suitable reagent and/or fuel that accommodates a particular set of design criteria. As yet another example, the number of fans or pumps and positioning of such fans or pumps utilized to control flow rates of fluid or fuel to the combustion apparatus can be any configuration that is able to meet a particular set of design criteria. As yet another example, thereburner 30 can be configured to inject fuel, the reagent and/or flue gas into thesecond combustion zone 5 b via only one outlet or in multiple feed outlets positioned in thesecond combustion zone 5 b (e.g. at outlets that are each located in a respective corner of the combustion chamber in thesecond combustion zone 5 b). As yet another example, some embodiments of the plant can include agas processing unit 13 that has one or more elements to facilitate carbon capture from the flue gas. - While the invention has been described with reference to various exemplary embodiments, it will be understood by those skilled in the art that various changes can be made and equivalents can be substituted for elements thereof without departing from the scope of the invention. In addition, many modifications can be made to adapt a particular situation or material to the teachings of the invention without departing from the essential scope thereof. Therefore, it is intended that the invention not be limited to the particular embodiment disclosed as the best mode contemplated for carrying out this invention, but that the invention will include all embodiments falling within the scope of the appended claims.
Claims (20)
1. A combustion apparatus, comprising:
a combustion chamber having multiple combustion zones for combustion of fuel, the combustion zones including a first combustion zone, a second combustion zone, and a third combustion zone wherein the second combustion zone is located between the first and third combustion zones, the combustion chamber having at least one outlet configured to emit flue gas formed from combustion of the fuel in the combustion chamber;
a first wind box in communication with the first combustion zone for feeding of fuel into the combustion chamber for initial combustion within the first combustion zone;
a second wind box in communication with second combustion zone to feed a first gas having oxygen into the second combustion zone;
a third wind box in communication with the third combustion zone to feed a second gas having oxygen into the third combustion zone; and
a conduit in communication with the second combustion zone to feed a reagent into the second combustion zone.
2. The combustion apparatus of claim 1 , wherein the second wind box has a reburner in communication with the second combustion zone, the reburner configured to feed fuel into the second combustion zone and also feed the reagent into the second combustion zone.
3. The combustion apparatus of claim 2 , wherein the reburner comprises a nozzle that is configured to spray the reagent into the second combustion zone with the fuel fed to the second combustion zone via the second feed conduit.
4. The combustion apparatus of claim 1 , wherein the first and second gases are air.
5. The combustion apparatus of claim 2 , wherein each of the first, second and third feed conduits comprise at least one wind box.
6. The combustion apparatus of claim 5 , wherein the reburner is positioned at an upper compartment of the second wind box or is positioned above the second wind box between the second wind box and the third wind box.
7. The combustion apparatus of claim 1 , wherein at least one of the first, second, and third wind boxes are configured to facilitate tangential firing of fuel.
8. The combustion apparatus of claim 2 , wherein the reburner is also configured to feed a first portion of the flue gas to be recycled into the second combustion zone.
9. The combustion apparatus of claim 1 , wherein the reagent is provided to the second combustion zone at an upper compartment of the second wind box or is positioned above the second wind box between the second wind box and the third wind box.
10. The combustion apparatus of claim 1 , wherein the second wind box is configured to feed a first portion of the flue gas to be recycled into the second combustion zone with the reagent to facilitate mixing of the reagent within the second combustion zone.
11. A method of operating a combustion apparatus having a combustion chamber including a first combustion zone, a second combustion zone, and a third combustion zone wherein the second combustion zone is located between the first and third combustion zones; the method comprising:
providing a first fuel into the first combustion zone of the combustion chamber;
providing a reagent and a first gas having oxygen to the second combustion zone of the combustion chamber; and
providing a second gas having oxygen to the third combustion zone of the combustion chamber.
12. The method of claim 11 further comprising:
feeding a second fuel to the second combustion zone, wherein the reagent and the second fuel are simultaneously fed to the second combustion zone.
13. The method of claim 12 further comprising:
recycling a first portion of flue gas exiting the combustion chamber to the second combustion zone such that the reagent, the second fuel and the first portion of the flue gas are simultaneously fed to the second combustion zone.
14. The method of claim 13 wherein the first and second gases are air.
15. The method of claim 12 , wherein:
the first fuel is coal and the first fuel is fed into the first combustion zone;
the second fuel is natural gas or oil; and
the reagent is one of aqueous ammonia, aqueous urea, and anhydrous ammonia.
16. The method of claim 12 , wherein:
the first, second, and third combustion zones are each positioned adjacent to a respective wind box; and
the second fuel being fed into the second combustion zone via a sole reburner of the wind box of the second combustion zone, the reburner being positioned at one of:
an upper compartment of the wind box of the second combustion zone, and
above the wind box of the second combustion zone between the wind box of the second combustion zone and the wind box of the third combustion zone.
17. The method of claim 11 , wherein the feeding of the first fuel into the combustion chamber comprises feeding the first fuel into the first combustion zone, the method also comprising:
feeding a second fuel to the second combustion zone, the second fuel differing from the first fuel such that the reagent and the second fuel are simultaneously fed to the second combustion zone; and
combusting the first fuel in the combustion chamber via a tangential firing system.
18. The method of claim 11 , wherein the reagent is a liquid and is sprayed into the second combustion zone.
19. The method of claim 18 , wherein the reagent is fed into the second combustion zone while no fuel is fed into the second combustion zone via a reburner.
20. The method of claim 12 , wherein the reagent is provided to the second combustion zone above the location where the gas having oxygen is provided to the second combustion zone.
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US14/550,101 US20160146462A1 (en) | 2014-11-21 | 2014-11-21 | PLANT, COMBUSTION APPARATUS, AND METHOD FOR REDUCTION OF NOx EMISSIONS |
PCT/US2015/060080 WO2016081233A1 (en) | 2014-11-21 | 2015-11-11 | Combustion apparatus and method for reduction of nox emissions using nitrogenous reagents with re-burning |
TW104138601A TW201632787A (en) | 2014-11-21 | 2015-11-20 | Plant, combustion apparatus, and method for reduction of nox emissions |
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US14/550,101 US20160146462A1 (en) | 2014-11-21 | 2014-11-21 | PLANT, COMBUSTION APPARATUS, AND METHOD FOR REDUCTION OF NOx EMISSIONS |
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DE69729371T2 (en) * | 1996-01-11 | 2005-06-02 | Energy And Environmental Research Corp., Irvine | IMPROVED ADVANCED RECYCLING METHOD WITH A HIGH PERFORMANCE FOR REDUCING NOx EMISSIONS |
DE10001997A1 (en) | 2000-01-19 | 2001-07-26 | Alstom Power Schweiz Ag Baden | Composite power plant and method for operating such a composite power plant |
US7374736B2 (en) | 2003-11-13 | 2008-05-20 | General Electric Company | Method to reduce flue gas NOx |
EP1930569A1 (en) | 2006-11-01 | 2008-06-11 | ALSTOM Technology Ltd | System for controlling a combustion process for a gas turbine |
JP5415276B2 (en) | 2006-12-01 | 2014-02-12 | アルストム テクノロジー リミテッド | How to operate a gas turbine |
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2014
- 2014-11-21 US US14/550,101 patent/US20160146462A1/en not_active Abandoned
-
2015
- 2015-11-11 WO PCT/US2015/060080 patent/WO2016081233A1/en active Application Filing
- 2015-11-20 TW TW104138601A patent/TW201632787A/en unknown
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20180058687A1 (en) * | 2016-08-23 | 2018-03-01 | General Electric Technology Gmbh | Overfire Air System For Low Nitrogen Oxide Tangentially Fired Boiler |
CN109563987A (en) * | 2016-08-23 | 2019-04-02 | 通用电器技术有限公司 | Overfire air system for low NOx tangentially fired boiler |
US10634341B2 (en) * | 2016-08-23 | 2020-04-28 | General Electric Technology Gmbh | Overfire air system for low nitrogen oxide tangentially fired boiler |
TWI789359B (en) * | 2016-08-23 | 2023-01-11 | 瑞士商通用電氣技術公司 | Tangentially fired boiler and method of operating a tangentially fired boiler |
US20230129890A1 (en) * | 2021-10-22 | 2023-04-27 | Tyler KC Kimberlin | Variable Vane Overfire Air Nozzles, System, and Strategy |
Also Published As
Publication number | Publication date |
---|---|
TW201632787A (en) | 2016-09-16 |
WO2016081233A1 (en) | 2016-05-26 |
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