US20160076130A1

US20160076130A1 - Surface modification apparatus for alloy steel component, surface modification method for alloy steel component, and method for manufacturing alloy steel component

Info

Publication number: US20160076130A1
Application number: US14/785,453
Authority: US
Inventors: Noriyuki Uematsu; Keisuke Suzuki; Satoshi Kawagashira
Original assignee: FCC Co Ltd
Current assignee: FCC Co Ltd
Priority date: 2013-04-25
Filing date: 2014-03-20
Publication date: 2016-03-17
Also published as: BR112015026667A2; CN105008575A; DE112014002156T5; TW201441422A; WO2014174949A1; JP2014214344A

Abstract

Provided are a surface modification apparatus for an alloy steel component, a surface modification method for an alloy steel component, and a method for manufacturing an alloy steel component, which can provide a deep and homogeneous hard layer for a steel component with a wide shape or a large amount of such steel components. A surface modification apparatus 100 includes a process furnace 101, and the process furnace 101 performs a surface modification process on an alloy steel component 90 including an alloy steel material to which at least one kind of nitride formation element such as chromium, molybdenum, or aluminum is added. The surface modification apparatus 100 forms a compound layer on a surface of the alloy steel component 90 by exposing the alloy steel component 90 for at least 180 minutes to an atmosphere in the process furnace 101 maintained to have an ammonia gas concentration of 80% or more and a temperature of 620° C.

Description

TECHNICAL FIELD

The present invention relates to a surface modification apparatus for an alloy steel component including an alloy steel material containing a nitride formation element, a surface modification method for an alloy steel component, and a method for manufacturing an alloy steel component.

BACKGROUND ART

Conventionally, various mechanical components made of alloy steel included in vehicles such as four-wheeled vehicles and bicycles are subjected to a surface modification process for enabling the portion of the component that mechanically slides to have higher wear and abrasion resistance. For example, Patent Literature 1 has disclosed the thermal processing method for improving the wear and abrasion resistance and the shock resistance by modifying the surface of the steel component through a so-called ion nitration process (also referred to as “plasma nitration process”).

CITATION LIST

Patent Literature

PATENT LITERATURE 1: JP-A-09-125225
In the surface modification method according to Patent Literature 1, the surface of the steel component is modified by the ion nitration process. This has led to a problem that it is difficult to form a surface modification layer (hard layer) homogeneously and the surface-modifiable component is limited due to the hollow-cathode effect or the edge effect. Here, the hollow-cathode effect refers to the phenomenon that, if the alloy steel component has a hole portion with small diameter, discharge within this hole is so difficult that the surface modification layer becomes inhomogeneous. The edge effect refers to the phenomenon that, if the alloy steel component has a corner portion with an acute, right, or obtuse angle, discharge concentrates on this corner portion to make the surface modification layer inhomogeneous. In the ion nitration process, the steel components to be processed need to be disposed apart from each other in a process furnace. This has led to another problem that the ion nitration process is not suitable for the surface modification process for a large amount of steel components.
The present invention has been made in view of the above problems. An object of the present invention is to provide a surface modification apparatus for an alloy steel component, a surface modification method for an alloy steel component, and a method for manufacturing an alloy steel component, which can provide a deep and homogeneous hard layer for a steel component with a wide shape or a large amount of such steel components.

SUMMARY OF INVENTION

An aspect of the present invention for achieving the above object is a surface modification apparatus for an alloy steel component, which performs the surface modification on an alloy steel component including an alloy steel material containing a nitride formation element. The apparatus includes a surface modification processing unit for modifying a surface of the alloy steel component by exposing the alloy steel component for at least 180 minutes to the atmosphere with an ammonia gas concentration of 80% or more and a temperature of 610° C. or more and 630° C. or less. In this case, the nitride formation element refers to an element which forms a hard nitride due to the permeation and diffusion of nitrogen, and specifically corresponds to at least one of chromium, molybdenum, and aluminum. The alloy steel material containing a nitride formation element is obtained by adding at least the minimum amount, which is defined by JIS (Japanese Industrial Standard), of the nitride formation element to the carbon steel, and specifically 0.3 wt % or more of chromium, 0.08 wt % of molybdenum, and 0.1 wt % of aluminum.
According to the aspect of the present invention described above, the surface modification apparatus for an alloy steel component is structured to include the surface modification processing unit for exposing the alloy steel component for at least 180 minutes to the atmosphere with an ammonia gas concentration of 80% or more and a temperature of 610° C. or more and 630° C. or less. According to the experiments by the present inventors, it has been confirmed that the compound layer with a thickness of 25 μm or more can be formed stably on the surface of the alloy steel component. In other words, by a surface modification method for an alloy steel component according to the present invention, the surface modification process is performed in an atmosphere where nitrogen generated by the thermal decomposition of ammonia gas floats. This can form a deep and homogenous hard layer for the alloy steel component with a wide shape. In the surface modification apparatus for an alloy steel component according to the present invention, the alloy steel components to be processed are disposed in the process furnace with a space therebetween large enough for the ammonia gas to spread. This enables the efficient surface modification process to be performed on a large amount of alloy steel components as compared to the ion nitration process. According to the experiments by the present inventors, the ammonia gas concentration is preferably constant during the surface modification process for the alloy steel component.
Another aspect of the present invention is the surface modification apparatus for an alloy steel component wherein the temperature is set to 620° C. by the surface modification processing unit.
In the other aspect of the surface modification apparatus for an alloy steel component according to the present invention as described above, the temperature of the atmosphere to which the alloy steel component is exposed is set to 620° C. Therefore, according to the experiments by the present inventors, the hard layer can be formed more stably. According to the experiments by the present inventors, the temperature of the atmosphere to which the alloy steel component is exposed is preferably 610° C. or more and 630° C. or less, more preferably 615° C. or more and 625° C. or less, and the most preferably 620° C. In any of these cases, the temperature of the atmosphere to which the alloy steel component is exposed is desirably maintained constant during the process.
In another aspect of the surface modification apparatus for an alloy steel component according to the present invention, the alloy steel component includes at least one of a corner portion with an acute shape and a hole portion with a diameter of 8 mm or less. In this case, the corner portion may include, for example, a portion with an acute angle, a right angle, or an obtuse angle or an acute shape like a spindle.
According to the other aspect of the surface modification method for an alloy steel component according to the present invention as described above, the homogeneous hard layer can be formed even though the alloy steel component is formed to have a corner portion with an acute shape or a hole portion with a diameter of 8 mm or less.
The present invention can be implemented not just as the invention of the surface modification apparatus for an alloy steel component but also as the invention of the surface modification method for an alloy steel component and the invention of a method for manufacturing an alloy steel component.
Specifically, the surface modification method for an alloy steel component may be a surface modification apparatus for an alloy steel component for performing the surface modification on an alloy steel component including an alloy steel material containing a nitride formation element, and the method may include a surface modification processing step of modifying a surface of the alloy steel component by exposing the alloy steel component for at least 180 minutes to the atmosphere with an ammonia gas concentration of 80% or more and a temperature of 610° C. or more and 630° C. or less.
In this case, in the surface modification processing step, the temperature is more preferably 615° C. or more and 625° C. or less, and the most preferably 620° C.
In this case, the alloy steel component preferably includes at least one of the corner portion with an acute shape and the hole portion with a diameter of 8 mm or less.
The method for manufacturing an alloy steel component may be a method for manufacturing an alloy steel component including an alloy steel material containing a nitride formation element, and the method may include a surface modification processing step of modifying a surface of the alloy steel component by exposing the alloy steel component for at least 180 minutes to the atmosphere with an ammonia gas concentration of 80% or more and a temperature of 610*C or more and 630° C. or less.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic view illustrating the outline of an apparatus structure of a surface modification apparatus for an alloy steel component used in a surface modification method for an alloy steel component according to the present invention.

FIG. 2 is a sectional view illustrating the outline of a structure of an alloy steel component to which a surface modification method for an alloy steel component according to the present invention is applied.

FIG. 3 is a flowchart illustrating a manufacturing process for an alloy steel component by a surface modification method for an alloy steel component according to an embodiment of the present invention.

FIG. 4 is a graph expressing the relation between the hardness and the depth of a hard layer formed on a surface layer of an alloy steel component by the surface modification method for an alloy steel component according to the present invention.

FIG. 5 is a table showing the chemical composition values of Samples A to E which have been subjected to the surface modification process by the surface modification method for an alloy steel component according to the present invention.

FIG. 6 is a graph expressing the hardness of a compound layer formed on a surface layer of each of Samples A to E by the surface modification method for an alloy steel component according to the present invention.

FIG. 7 is a graph relatively expressing the thickness of the compound layer formed on the surface layer of Sample B for each of different process conditions including the surface modification method for an alloy steel component according to the present invention.

FIG. 8 is a graph relatively expressing the thickness of the compound layer formed on the surface layer of Sample C for each of different process conditions including the surface modification method for an alloy steel component according to the present invention.

FIG. 9 is a graph relatively expressing the thickness of the compound layer formed on the surface layer of Sample D for each of different process conditions including the surface modification method for an alloy steel component according to the present invention.

FIG. 10 is a graph relatively expressing the thickness of the compound layer formed on the surface layer of Sample E for each of different process conditions including the surface modification method for an alloy steel component according to the present invention.

DESCRIPTION OF EMBODIMENTS

An embodiment of a surface modification apparatus for an alloy steel component, a surface modification method for an alloy steel component, and a method for manufacturing an alloy steel component according to the present invention will be described below with reference to drawings. FIG. 1 is a schematic view illustrating the outline of an apparatus structure of a surface modification apparatus 100 for an alloy steel component, which is used in a surface modification method for an alloy steel component according to the present invention. In each drawing in the present specification, some elements are illustrated schematically, for example, drawn exaggerated in order to help the understanding of the present invention. Therefore, the size, ratio, etc. among the elements may be different. This surface modification apparatus 100 corresponds to a thermal processing apparatus for performing a surface modification process to improve the wear and abrasion resistance by forming a hard layer on a surface layer of an alloy steel component 90 such as a cylindrical boss component included in an alloy steel mechanical component, for example, a power transmission device such as a clutch in a vehicle like a four-wheeled vehicle or a bicycle.
First, description is made of the alloy steel component 90 molded by the surface modification apparatus 100 according to the present invention. This alloy steel component 90 is a component included in a power transmission device such as a clutch in a vehicle, and is formed of an alloy steel material corresponding to carbon steel to which a nitride formation element has been added. In this case, the nitride formation element added to the carbon steel is at least one kind of element that combines with nitrogen to form a nitride, and corresponds to, for example, chromium, molybdenum, or aluminum. The amount of the nitride formation element to be added is more than or equal to the minimum amount defined by JIS (Japanese Industrial Standard), and specifically, if the element is chromium, the amount is 0.3 wt % or more, if the element is molybdenum, the amount is 0.08 wt % or more, and if the element is aluminum, the amount is 0.1 wt % or more.
As specifically illustrated in FIG. 2, the alloy steel component 90 includes a main body portion 91 formed to have an approximately cylindrical shape. The main body portion 91 includes a cylindrical sliding portion 92 on which another member of the power transmission device slides, and a flange portion 93 that extends in a circular-plate shape outward in the radial direction from one end (right side in the figure) of the sliding portion 92. The sliding portion 92 of the main body portion 91 is provided with a penetration hole 94 in a state of penetrating in the radial direction of the main body portion 91. The penetration hole 94 is formed to have a diameter of 8 mm.
The surface modification apparatus 100 includes a process furnace 101. The process furnace 101 is a vessel with an approximately cylindrical shape formed to be airtight so that the surface modification process is performed on the alloy steel component 90. The process furnace 101 is formed of a material that can resist 620° C. corresponding to the process temperature of the alloy steel component 90, for example, a ceramic material. This process furnace 101 is mainly formed of a main chamber 101 a and a stand-by chamber 101 b.
The main chamber 101 a is a space where the surface modification process is performed on the alloy steel component 90. The stand-by chamber 101 b is a space where the alloy steel component 90 is set before or after the alloy steel component 90 is taken in or out of the main chamber 101 a, and is formed to have a release door 101 c that is opened and closed toward the outside. Between the main chamber 101 a and the stand-by chamber 101 b is provided a partition wall 101 d that partitions between both chambers in a manner that the partition wall 101 d can freely connect or disconnect the chambers. Moreover, a conveyance mechanism 101 e is provided between the main chamber 101 a and the stand-by chamber 101 b. The conveyance mechanism 101 e conveys the alloy steel component 90 between the stand-by chamber 101 b and the main chamber 101 a under the operation control by a control device 111 to be described below. In FIG. 1, the partition wall 101 c is illustrated by a dashed line, and the conveyance mechanism 101 e and the alloy steel component 90 in the stand-by chamber 101 b are each illustrated by a two-dot chain line.
A heater 102 is provided outside the outer peripheral surface of the process furnace 101. The heater 102 is an electric heater used for heating the main chamber 101 a in the process furnace 101 up to 620° C. corresponding to the process temperature and moreover for maintaining this temperature. The operation of the hater 102 is controlled by the control device 111.
The process furnace 101 is connected to a main gas supply pipe 103, a sub-gas supply pipe 106, and an exhaust pipe 109. The main gas supply pipe 103 is a pipe for guiding ammonia gas (not shown) into the process furnace 101. On the upstream side of the main gas supply pipe 103, a main gas cylinder 105 is connected through a flow rate adjuster 104. The flow rate adjuster 104 is a device for adjusting the flow rate of the ammonia gas to be introduced into the process furnace 101. The flow rate adjuster 104 includes, for example, a gasifier (not shown) for gasifying liquid ammonia and a flow rate adjustment valve (not shown) for adjusting the flow rate of the gasified ammonia gas. The operation of the flow rate adjuster 104 is controlled by the control device 111. The main gas cylinder 105 is a vessel for storing the liquid ammonia.
The sub-gas supply pipe 106 is a pipe for guiding the nitrogen gas (not shown) into the process furnace 101. On the upstream side of the sub-gas supply pipe 106, a sub-gas cylinder 108 is connected through a flow rate adjuster 107. The flow rate adjuster 107 is similar to the flow rate adjuster 104 and is a device for adjusting the flow rate of the nitrogen gas to be introduced into the process furnace 101. The flow rate adjuster 107 includes, for example, a gasifier (not shown) for gasifying liquid nitrogen and a flow rate adjustment valve (not shown) for adjusting the flow rate of the gasified nitrogen gas. The operation of the flow rate adjuster 107 is controlled by the control device 111. The sub-gas cylinder 108 is a vessel for storing the liquid nitrogen.
The exhaust pipe 109 is a pipe for guiding the gas in the process furnace 101 to the outside of the process chamber 101. On the downstream side of the exhaust pipe 109, an exhaust gas process device 110 for deodorizing and burning the exhaust gas led out of the process furnace 101 is connected.
The control device 111 is configured by a microcomputer including a CPU, a ROM, a RAM, and the like. The control device 111 further includes an input device (not shown) for an operator to input an instruction, and a display device (not shown) to show the operator the operation status of the surface modification apparatus 100. The control device 111 executes the programs stored in advance in the storage device such as the ROM in accordance with the operator's instruction, thereby controlling the operation of the surface modification apparatus 100. Specifically, the control device 100 controls the operation of each of the heater 102, the flow rate adjusting devices 104 and 107, and the exhaust gas process device 110 in accordance with the operator's instruction. The surface modification apparatus 100 is further provided with a temperature sensor 112 a and a concentration sensor 112 b. These sensors 112 a and 112 b measure the temperature of the furnace 101 and the ammonia gas concentration, respectively and output the results to the control device 111.

(Operation of Surface Modification Apparatus 100)

Next, the surface modification process performed on the alloy steel component 90 by the surface modification apparatus 100 with the above structure is described with reference to the flowchart of FIG. 3. FIG. 3 is the flowchart illustrating a process for manufacturing the alloy steel component 90.
The operator who manufactures the alloy steel component 90 molds the alloy steel component 90 in a first step. Specifically, the operator molds the main body portion 91, the sliding portion 92, the flange portion 93, and the penetration hole 94 through cutting, welding, and grinding of the alloy steel material using the machining equipment including a machine tool, which is not shown. In this case, in this embodiment, the alloy steel component 90 is not subjected to a heat treatment including a quenching process. However, the heat treatment including quenching may be performed before or after the surface modification process according to the present invention.
Next, the operator performs the surface modification process on the alloy steel component 90 in a second step. In this case, the surface modification process corresponds to a process of forming a hard layer made of a nitride on a surface layer of the alloy steel component 90. Specifically, the operator manipulates the control device 111 to close the partition wall 101 d in the process furnace 101 so as to make the main chamber 101 a airtight. After that, the operator disposes the alloy steel component 90 molded by the machining in the stand-by chamber 101 b through the opening and closing door 101 c. If the operator disposes a plurality of alloy steel components 90, the operator disposes the alloy steel components 90 with a space therebetween so that the ammonia gas can spread in the space.
Next, the operator manipulates the control device 111 to introduce the ammonia gas and the nitrogen gas into the main chamber 101 a in the process furnace 101 and heats the process furnace 101. In this case, the operator introduces the ammonia gas and the nitrogen gas into the main chamber 101 a so that 80% or more of the gas in the main chamber 101 a of the process furnace 101 is constituted by ammonia gas while the remainder is constituted by the nitrogen gas. In addition, the operator heats the main chamber 101 a of the process furnace 101 so that the chamber has a temperature of 620° C.
Next, if the main chamber 101 a of the process furnace 101 has an atmosphere with an ammonia gas concentration of 80% and with a temperature of 620° C. or more, the operator manipulates the control device 111 to move the alloy steel component 90 from the stand-by chamber 101 b to the main chamber 101 a. After that, the operator manipulates the control device 111 to expose the alloy steel component 90 for at least 180 minutes to the maintained atmosphere of the main chamber 101 a of the process furnace 101, specifically the atmosphere of the main chamber 101 a maintained to have an ammonia gas concentration of 80% and a temperature of 620° C. In other words, this process furnace 101 corresponds to the surface modification processing unit according to the present invention.
This causes the nitrogen, which is generated by the thermal decomposition of the ammonia gas, to permeate into the surface layer of the alloy steel component 90 in the main chamber 101 a of the process chamber 101, thereby forming the hard layer. Specifically, on the surface layer of the alloy steel component 90, the hard layer formed of a compound layer and a diffusion layer in the order from the outermost surface is generated. In this case, the surface modification process for the alloy steel component 90 is performed by having the nitrogen floating in the main chamber 101 a in contact with the alloy steel component 90. Thus, the hard layer is generated homogeneously without unevenness for the inside of the penetration hole 94 and the corner portion of the flange portion 92.
After the alloy steel component 90 is exposed to the atmosphere in the main chamber 101 a of the process furnace 101 for at least 180 minutes, the operator manipulates the control device 111 to stop the supply of the ammonia gas and the nitrogen gas to the process furnace 101 and stop the heating of the process furnace 101. The operator extracts the alloy steel component 90 out of the process furnace 101 after the temperature in the process furnace 101 has decreased to be less than a predetermined temperature (for example, 150° C.).
Here, description is made of the hardness of the surface layer of the alloy steel component 90 extracted from the process furnace 101. FIG. 4 is a graph expressing an example of how the hardness changes relative to the distance from the surface layer of the alloy steel component 90 containing the so-called nitride formation element. According to FIG. 4, it has been confirmed that the compound layer with a hardness of 780 HmV through 660 HmV to 880 HmV is formed in the range of thicknesses from the surface up to approximately 25 μm in the alloy steel component 90 and the diffusion layer is formed to a depth of 0.2 mm from this compound layer toward the lower layer. This means that the compound layer with a hardness (750 HmV or more) more than or equal to the hardness of chromium plating defined in JIS (Japanese Industrial Standard) is formed on the surface of the alloy steel component 90.
Next, the operator performs a finishing process in a third step. Specifically, the operator performs a grinding process on the outer surface of the alloy steel component 90 extracted from the process furnace 101 so that the alloy steel component 90 has a predetermined size or a predetermined surface roughness. In this case, since the compound layer with a thickness of 25 μm or more is formed on the surface of the alloy steel component 90, the operator can easily achieve the predetermined size or the predetermined surface roughness by a sufficient process margin.
Here, the results of experiments by the present inventors are described. FIG. 5 shows the values of the chemical compositions of Samples A to E used in the present experiments. FIG. 6 shows the results of measuring the surface hardness of Samples A to E in FIG. 5 that have been subjected to the surface modification process similar to the process in the above embodiment. In FIG. 6, the hardness of Sample B satisfying the hardness required in the specification of the alloy steel component 90 is regarded as 100%, based on which the hardness of the other Samples A and C to E are shown. According to the experiment results in FIG. 6, it has been confirmed that the alloy steel component 09 needs to be formed of the alloy steel material containing a nitride formation element in order for the compound layer to have the required hardness.
Next, FIG. 7 to FIG. 10 show the results of measuring the thickness of the compound layer of each of Samples B to E, among Samples A to E in FIG. 5, which have been subjected to the surface modification process according to the conventional condition, the temperature changed condition, the time changed condition, the concentration changed condition, and the condition of the present invention. In FIG. 7 to FIG. 10, the thicknesses of the compound layers of Samples C to E are expressed assuming the thickness of the compound layer that has been increased by 60% of the thickness of the compound layer of Sample B subjected to the conventional surface modification process is the target value (achievement rate 100%).
In this experiment, the conventional technique corresponds to the conventional nitration process, specifically the gas soft-nitriding process performed on the alloy steel component 90 in the atmosphere with a temperature of 530 to 580° C., a process time of 60 to 180 minutes, and an ammonia gas concentration of 30 to 50% in the furnace. The conventional technique provides the compound layer with a hardness of 350 HmV or more in general and with a thickness of approximately 8 μm to 15 μm.
In regard to the temperature changed condition, the conventional condition is changed into a process condition where just the temperature condition is changed to 620° C. corresponding to the temperature condition according to the present invention; under this process condition, the alloy steel component 90 is processed. In regard to the time changed condition, the conventional condition is changed into a process condition where just the time condition is changed to 180 minutes or more corresponding to the time condition according to the present invention; under this condition, the alloy steel component 90 is processed. In regard to the concentration changed condition, the conventional condition is changed into a process condition where just the concentration condition of the gas confined in the main chamber 101 a is changed to 80% or more of ammonia gas corresponding to the gas concentration condition according to the present invention; under this condition, the alloy steel component 90 is processed. In regard to the condition according to the present invention, the alloy steel component 90 is processed under the process condition in the above embodiment, i.e., the temperature is set to 620° C., the process time is 180 minutes or more, and the ammonia concentration is 80% or more.
According to the results of the experiments shown in FIG. 7 to FIG. 10, it has been confirmed that the thickness of the compound layer formed based on the process condition of the present invention is clearly larger than that of the compound layer formed by any process condition that has employed part of the temperature condition, the time condition, and the ammonia concentration condition in the process condition in the present invention. In other words, the thickness of the compound layer formed based on the present invention cannot be achieved by the process condition that has employed part of the process condition in the present invention, and can be achieved only by executing the process condition including all the temperature condition, the time condition, and the ammonia concentration condition in the present invention.
In regard to how much the thickness of the hard layer formed by the surface modification process according to the present invention has increased relative to the conventional thickness, the experiment results from Samples B to E indicate that the thickness of the compound layer has increased 1.9 times to 2.5 times and the thickness of the diffusion layer has increased 1.2 times to 1.6 times. In this case, along with the increase of the compound layer, the diffusion layer is increased but in regard to the increase rate, the increase rate of the diffusion layer is smaller than that of the compound layer. In other words, through the surface modification process according to the present invention, the thickness of the compound layer formed on the surface of the alloy steel component 90 can be increased while the modification of the mother material inside the alloy steel component 90, more specifically the tough part thereof is suppressed. Therefore, the surface modification process according to the present invention is particularly effective in mechanical parts required to have the toughness on the inside and have the wear and abrasion resistance on the surface.
The thickness of the compound layer formed on the surface of each of Samples B to E through the surface modification process according to the present invention is 25 μm to 33 μm. This thickness is as large as the depth of each hard layer in the thermally processed product obtained by carburizing and quenching a conventional chromium molybdenum steel material and plating the material with chromium and the thermally processed product obtained by hardening a medium carbon steel material with high frequency and plating the material with chromium as compared to the thickness of the compound layer obtained from the conventional gas nitration process.
As can be understood from the above description about the operation, the surface modification apparatus 100 for the alloy steel component in the above embodiment is structured to have the process furnace 101 where the alloy steel component 90 is exposed for at least 180 minutes to the atmosphere with an ammonia gas concentration of 80% or more and a temperature of 620° C. According to the experiments by the present inventors, it has been confirmed that the compound layer with a thickness of 25 μm or more can be formed stably on the surface of the alloy steel component 90. In other words, the surface modification apparatus 100 for the alloy steel component 90 according to the present invention performs the surface modification process in the atmosphere containing nitrogen generated by the thermal decomposition of the ammonia gas. This can form the hard layer that is deep and homogeneous in the alloy steel component 90 with a wide shape. In the surface modification apparatus 90 for an alloy steel component according to the present invention, the alloy steel components 90 to be processed are disposed in the process furnace 101 with a space between the components 90 so that the ammonia gas spreads in the space. This enables the efficient surface modification process on a large amount of alloy steel components 90 as compared to the ion nitration process.
In the implementation of the present invention, various changes can be made without departing from the purpose of the present invention and without being limited to the above embodiment.
For example, in regard to the concentration of the gas in the main chamber 101 a of the process furnace 101 in the above embodiment, the ammonia gas constitutes 80% or more with the remainder constituted by the nitrogen gas. However, the concentration of the gas in the main chamber 101 a is not limited to that in the above embodiment as long as the ammonia gas constitutes at least 80%. Therefore, the main chamber 101 a may be formed to contain the ammonia gas only. Alternatively, 80% or more of the gas concentration in the main chamber 101 a may be constituted by the ammonia gas with the remainder constituted by other gas than the nitrogen gas, such as carbon gas or hydrogen gas. In these cases, according to the experiments by the present inventors, the ammonia gas concentration is preferably maintained constant during the surface modification process on the alloy steel component 90.
In the above embodiment, the alloy steel component 90 may be subjected to the surface modification process while the inside of the main chamber 101 a of the process furnace 101 is maintained to be heated at 620° C. According to the experiments by the present inventors, however, it has been confirmed that the effect of the present invention is achieved if the temperature condition in the surface modification process in the present invention is in the range of ±10° C. from 620° C., i.e., from 610° C. to 630° C. and that the effect of the present invention cannot be fully achieved if the temperature is out of that range. Moreover, according to the experiments by the present inventors, it has been confirmed that the temperature of the atmosphere to which the alloy steel component is exposed is more appropriate to be 615° C. or more and 625° C. or less, and the most appropriate to be 620° C. It has also been confirmed that in those cases, the temperature of the atmosphere to which the alloy steel component is exposed is desirably maintained to be constant during the process.
In the above embodiment, the alloy steel component 90 is one of parts constituting the power transmission device such as a clutch in a self-propelled vehicle. However, the surface modification apparatus 100 for the alloy steel component 90 according to the present invention is widely applicable to the mechanical parts formed of alloy steel. In this case, the surface modification apparatus 100 for the alloy steel component 90 according to the present invention is appropriate because the thick and homogeneous compound layer can be formed even for the alloy steel component 90 including at least one of a corner portion with the shape having a narrowing end, such as a conical shape or an acute angle, a right angle, or an obtuse angle and a hole portion with a diameter of 8 mm or less, preferably 5 mm or less, and more preferably 4 mm or less. In regard to the alloy steel component 90 including a mechanically slidable portion partly or entirely in the alloy steel component 90, the hard layer (compound layer) formed by the surface modification apparatus 100 for the alloy steel component 90 according to the present invention is effective because the hard layer can be formed more easily and in a shorter time than the hard layer formed by the conventional process for forming the hard layer, specifically the hard layer formed by the hard chromium plating process after the high-frequency hardening or the carburizing and quenching.
In the above embodiment, the surface modification apparatus 100 exposes the alloy steel component 90 for at least 180 minutes to the atmosphere maintained to have an ammonia gas concentration of 80% and a temperature of 620° C. in the main chamber 101 a. This is based on the experiments by the present inventors, which have confirmed that the effect of the present invention cannot fully be achieved if the surface modification process on the alloy steel component 90 is less than 180 minutes. Thus, the surface modification apparatus 100 needs to expose the alloy steel component 90 for at least 180 minutes to the atmosphere maintained to have an ammonia gas concentration of 80% and a temperature of 610° C. or more and 630° C. or less.
The surface modification method for an alloy steel component according to the present invention is widely applicable to the alloy steel material containing the nitride formation element. In this case, examples of the alloy steel material containing the nitride formation element include steel materials containing more than or equal to the minimum amount, which is defined by JIS (Japanese Industrial Standard), of at least one element of chromium, molybdenum, and aluminum, such as chromium alloy steel, chromium molybdenum steel, nitride steel, and carbon steel, chromium alloy steel, or chromium molybdenum steel containing 0.1 to 0.3 wt % of aluminum.

DESCRIPTION OF REFERENCE SIGNS

90 Alloy steel component
91 Main body portion
92 Sliding portion
93 Flange portion
94 Penetration hole
100 Surface modification apparatus
101 Process furnace
101 a Main chamber
101 b Stand-by chamber
101 c Opening and closing door
101 d Partition wall
101 e Conveyance mechanism
102 Heater
103 Main gas supply pipe
104 Flow rate adjuster
105 Main gas cylinder
106 Sub-gas supply pipe
107 Flow rate adjuster
108 Sub-gas cylinder
109 Exhaust pipe
110 Exhaust gas process device
111 Control device
112 a Temperature sensor
112 b Concentration sensor

Claims

1. A surface modification apparatus for an alloy steel component, which performs surface modification on an alloy steel component including an alloy steel material containing a nitride formation element, the apparatus comprising

a surface modification processing unit for modifying a surface of the alloy steel component by exposing the alloy steel component for at least 180 minutes to an atmosphere with an ammonia gas concentration of 80% or more and a temperature of 610° C. or more and 630° C. or less.

2. The surface modification apparatus for an alloy steel component according to claim 1, wherein the temperature is set to 620° C. by the surface modification processing unit.

3. The surface modification apparatus for an alloy steel component according to claim 1, wherein the alloy steel component includes at least one of a corner portion with an acute shape and a hole portion with a diameter of 8 mm or less.

4. A surface modification method for an alloy steel component including an alloy steel material containing a nitride formation element, the method comprising

a surface modification processing step of modifying a surface of an alloy steel component by exposing the alloy steel component for at least 180 minutes to an atmosphere with an ammonia gas concentration of 80% or more and a temperature of 610° C. or more and 630° C. or less.

5. The surface modification method for an alloy steel component according to claim 4, wherein the temperature is set to 620° C. in the surface modification processing step.

6. The surface modification method for an alloy steel component according to claim 4, wherein the alloy steel component includes at least one of a corner portion with an acute shape and a hole portion with a diameter of 8 mm or less.

7. A method for manufacturing an alloy steel component including an alloy steel material containing a nitride formation element, the method comprising

a surface modification processing step of modifying a surface of an alloy steel component by exposing the alloy steel component for at least 180 minutes to the atmosphere with an ammonia gas concentration of 80% or more and a temperature of 610° C. or more and 630° C. or less.

8. The surface modification apparatus for an alloy steel component according to claim 2, wherein the alloy steel component includes at least one of a corner portion with an acute shape and a hole portion with a diameter of 8 mm or less.

9. The surface modification method for an alloy steel component according to claim 5, wherein the alloy steel component includes at least one of a corner portion with an acute shape and a hole portion with a diameter of 8 mm or less.