US2015864A - Processing of textiles - Google Patents
Processing of textiles Download PDFInfo
- Publication number
- US2015864A US2015864A US638345A US63834532A US2015864A US 2015864 A US2015864 A US 2015864A US 638345 A US638345 A US 638345A US 63834532 A US63834532 A US 63834532A US 2015864 A US2015864 A US 2015864A
- Authority
- US
- United States
- Prior art keywords
- textiles
- materials
- emulsion
- textile
- emulsions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004753 textile Substances 0.000 title description 28
- 239000000839 emulsion Substances 0.000 description 27
- 239000000463 material Substances 0.000 description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 238000000034 method Methods 0.000 description 10
- 230000008569 process Effects 0.000 description 9
- 238000004078 waterproofing Methods 0.000 description 9
- 239000002198 insoluble material Substances 0.000 description 8
- 238000001246 colloidal dispersion Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 239000003925 fat Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 244000299461 Theobroma cacao Species 0.000 description 3
- 235000009470 Theobroma cacao Nutrition 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical class [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- -1 aluminum compound Chemical class 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 102000009027 Albumins Human genes 0.000 description 1
- 108010088751 Albumins Proteins 0.000 description 1
- 229920002955 Art silk Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 159000000013 aluminium salts Chemical class 0.000 description 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Chemical class 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000002960 lipid emulsion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000011701 zinc Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/57—Sulfates or thiosulfates of elements of Groups 3 or 13 of the Periodic Table, e.g. alums
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/09—Sulfur-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/60—Waxes
Definitions
- the invention relates to processes of treating textiles and similar materials, and it particularly relates to a method of incorporating waxy or fatty materials and other water insoluble materialsv in textiles, yarns or fabrics.
- An object of the present invention is to provide a process whereby water insoluble materials may be incorporated in textiles and similar materials for softening, waterproofing, sizing, lustre-finishing and other finishing, with assurance that the loading material will be substantially permanently incorporated in the body of the fiber or structure of the textile.
- Another object is to provide a process whereby water insoluble materials may be incorporated in textiles and similar materials for softening, waterproofing, sizing, lustre-finishing and other finishing, with assurance that the loading material will be substantially permanently incorporated in the body of the fiber or structure of the textile by treating with emulsons or colloidal dispersions whichadmits of the possibility of utilizing very dilute emulsions or colloidal dispersions containing the water insoluble material.
- Another object is to provide improved colloidal dispersions or emulsions, which are particularly adapted for loading or filling textile materials, as for, example to waterproof them.
- Another object is to provide improved waterproofed textile materials which contain relatively small quantities of the water-proofing or fatty substances, substantially permanently absorbed inside of the fiber or inside of the structure of the textile itself.
- a textile or similar material having an electrical charge for example a negative charge
- a colloidal dispersion or emulsion the suspended particles of which have an opposite or positive charge
- the dispersed particles of the colloidal dispersion or' emulsion will incorporate themselves with and penetrate into the structure of the textile, fabric, or other similar material, even though the emulsion be very dilute. Satisfactory incorporation and consequently desirable waterproofed or finished textiles are obtained without using a highly concentrated bath.
- the textile materials it is desirable to subject the textile materials to treatment in the colloidal emulsions or dispersions for a longer period of time than has previously been the case, but this increase in exposure is over-balanced by the many other advantages artificial silk, linen and the like may be treated v by the present invention.
- Materials in non-spun 15 state, as for instance top, or woven or knitted yarn may also be treated.
- paper, leather, fur and other materials may also be similarly processed.
- the emulsion may contain colloidally dispersed fats, waxy materials, oleaginous 20 substances and other water-proofing or water insoluble materials. Other substances such as resin, caoutchouc, sulphur, asphalt and the like may also be employed in the emulsions.
- av negatively charged cocoa fat emulsion that is one having the same charge as 40 the fabric, the same effect may only be obtained with an emulsion having 4 or 5 times the above concentration.
- Accordingtothepresentinvmticnthetextiles aretreatedwithatmostanamountofemulsion tto%byweightofthematerials beingtreatcd. Thna'3kg.ofthematerialmay' beheatedwith l00litersofabathcontaining 0.3%oftheunulsinn.
- totheproceasofthepresentinventhefimeoftreatmentofthematerialsin tlon alltheamnratususemin whichthematerials m y be subjected to treatnent, as for example the reeling vat, the washing-machine, or .the vaseLispreferahlycmflnuedforasuitablyextendedperiod.
- Thetemperatureofthebath may bebetwcenfllandlm'llaccordingtothema- Becauseoftheoppositechargesofthetextile materialandthecmulslmitappearsthatthe agulationaswillresultimonthcmixturenf 'oppositelychargedcolloidalsolutlonsordlsper 5 colloidal waxy and fatty particles is such that the water-proofing material will be retained in the textile even though it be subjected to drastic 5 washing or other operations over long periods of time.
- the emulsions of the present invention may be conveniently prepared with soaps, sulphonated oils or fats or other proper fatty derivatives,
- Positively charged emulsions may be obtained from such negatively charged anulsiins by the additionof substancesgivingaposilivec lm to the dispersed phase.
- Such subslances are free acids as for instance hydrochloric acid.
- Salts of pol'yvalent metals, such as salts of aluminium, iron, zinc, copper and the like, as well as positively charged hydroeols for instance aluminium hydroxide may also be 61mm
- the posiiivecliargingofthedispcrsedphaseoiftheernulsion maybe done byaddingsubstances to the dilute or concentrated negatively charged emulsion.
- positive emulsions maybedirectlyproducedbyhomogenizing thewaterinsolublesubstancewithanaqueoussolution of the emulsifying agmt and of the discharging substance.
- a process of waterproofing textiles with water insoluble, oily, waxy and fatty materials from aqueous emulsions thereof which comprises providing the textile with a negative charge, preparing an emulsion of said water insoluble materials in which the emulsified or disperse phase is positively charged and then immersing the textiles in said bath to cause them to absorb the disperse phase from the bath by reason of their opposite charge.
- a process of water proofing textiles with 15 'paraflln and an aluminum compound which comprises providing the textiles with a negative charge, preparing a diluted emulsion containing the parafiln in the disperse phase and containing an aluminum compound and positively charged and then immersing the textiles in the dilute bath to absorb the parafiin therefrom by reason of the opposite charge.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Colloid Chemistry (AREA)
- Paper (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE394816X | 1931-12-17 | ||
| US659596A US2015865A (en) | 1931-12-17 | 1933-03-03 | Treatment of textiles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2015864A true US2015864A (en) | 1935-10-01 |
Family
ID=25888692
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US638345A Expired - Lifetime US2015864A (en) | 1931-12-17 | 1932-10-18 | Processing of textiles |
| US659596A Expired - Lifetime US2015865A (en) | 1931-12-17 | 1933-03-03 | Treatment of textiles |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US659596A Expired - Lifetime US2015865A (en) | 1931-12-17 | 1933-03-03 | Treatment of textiles |
Country Status (4)
| Country | Link |
|---|---|
| US (2) | US2015864A (fr) |
| BE (1) | BE389800A (fr) |
| FR (1) | FR739214A (fr) |
| GB (1) | GB394816A (fr) |
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE748226C (de) * | 1939-05-05 | 1944-10-30 | Verfahren zum Wasserabstossendmachen von Faserstoffen | |
| US2420233A (en) * | 1943-09-07 | 1947-05-06 | Boake Roberts & Company Ltd A | Production of aluminum salts of organic acids |
| US2424831A (en) * | 1942-11-24 | 1947-07-29 | Quaker Chemical Products Corp | Composition for waterproofing and fireproofing textile material, and the treated material |
| US2442972A (en) * | 1941-01-23 | 1948-06-08 | Sidney M Edelstein | Aqueous dispersions of electropositive materials |
| US2544732A (en) * | 1945-09-27 | 1951-03-13 | Isaac L Shechmeister | Method for rendering a fabric germicidal |
| US2563289A (en) * | 1947-06-12 | 1951-08-07 | Owens Corning Fiberglass Corp | Coated glass fibers and method for producing same |
| DE908052C (de) * | 1939-04-22 | 1954-04-01 | Pfersee Chem Fab | Verfahren zur Herstellung konzentrierter waesseriger Emulsionen |
| US2746836A (en) * | 1951-08-31 | 1956-05-22 | Monsanto Chemicals | Process of dyeing acrylonitrile fibers |
| US3022885A (en) * | 1957-03-11 | 1962-02-27 | Inland Container Corp | Antimar coated articles |
| US3619258A (en) * | 1968-04-10 | 1971-11-09 | Phillips Petroleum Co | Plasticized sulfur, coated asphalt impregnated fabric |
| US3657003A (en) * | 1970-02-02 | 1972-04-18 | Western Electric Co | Method of rendering a non-wettable surface wettable |
| US3945792A (en) * | 1969-07-09 | 1976-03-23 | Ciba-Geigy Corporation | Process for the filling of leather and compositions therefor |
| US7141518B2 (en) | 2003-10-16 | 2006-11-28 | Kimberly-Clark Worldwide, Inc. | Durable charged particle coatings and materials |
| US7413550B2 (en) | 2003-10-16 | 2008-08-19 | Kimberly-Clark Worldwide, Inc. | Visual indicating device for bad breath |
| US7438875B2 (en) | 2003-10-16 | 2008-10-21 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using metal-modified silica particles |
| US7488520B2 (en) | 2003-10-16 | 2009-02-10 | Kimberly-Clark Worldwide, Inc. | High surface area material blends for odor reduction, articles utilizing such blends and methods of using same |
| US7582485B2 (en) | 2003-10-16 | 2009-09-01 | Kimberly-Clark Worldride, Inc. | Method and device for detecting ammonia odors and helicobacter pylori urease infection |
| US7582308B2 (en) | 2002-12-23 | 2009-09-01 | Kimberly-Clark Worldwide, Inc. | Odor control composition |
| US7666410B2 (en) | 2002-12-20 | 2010-02-23 | Kimberly-Clark Worldwide, Inc. | Delivery system for functional compounds |
| US7678367B2 (en) | 2003-10-16 | 2010-03-16 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using metal-modified particles |
| US7754197B2 (en) | 2003-10-16 | 2010-07-13 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using coordinated polydentate compounds |
| US7794737B2 (en) | 2003-10-16 | 2010-09-14 | Kimberly-Clark Worldwide, Inc. | Odor absorbing extrudates |
| US7837663B2 (en) | 2003-10-16 | 2010-11-23 | Kimberly-Clark Worldwide, Inc. | Odor controlling article including a visual indicating device for monitoring odor absorption |
| US7879350B2 (en) | 2003-10-16 | 2011-02-01 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using colloidal nanoparticles |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2524017A (en) * | 1950-09-26 | Metalworking lubricant | ||
| DE975801C (de) * | 1937-09-29 | 1962-09-27 | Bayer Ag | Verfahren zum Impraegnieren von Textilien mit Metallsalze enthaltenden waessrigen Dispersionen von Paraffin oder Wachsen im Einbad-Verfahren |
| DE905967C (de) * | 1939-08-19 | 1954-03-08 | Ciba Geigy | Verfahren zum Mattieren von Textilien |
| DE870990C (de) * | 1941-05-08 | 1953-03-19 | Basf Ag | Verfahren zum Veredeln von Textilien |
| US2416134A (en) * | 1943-07-23 | 1947-02-18 | West Bank Oil Terminal Inc | Road paving composition |
| US2480352A (en) * | 1944-11-04 | 1949-08-30 | Warren S D Co | Separable liner for tacky elastomers |
| US2456595A (en) * | 1946-12-26 | 1948-12-14 | Johnson & Son Inc S C | Solid water-repellency composition |
| US2482917A (en) * | 1947-05-16 | 1949-09-27 | Onyx Oil & Chemical Company | Scrooping composition |
| US2635055A (en) * | 1948-07-08 | 1953-04-14 | Hans G Figdor | Water repellent composition |
| US2711378A (en) * | 1952-07-24 | 1955-06-21 | Socony Mobil Oil Co Inc | Emulsion, method of preparing same, and method of applying same |
| BE533966A (fr) * | 1954-05-10 | |||
| US3308826A (en) * | 1961-03-09 | 1967-03-14 | Celanese Corp | Sanitary napkins |
| US3285775A (en) * | 1965-06-14 | 1966-11-15 | United Shoe Machinery Corp | Penetration of collagen fibers through inclusion of protective colloid |
| CA1001994A (en) * | 1973-12-14 | 1976-12-21 | Michael A. Dudley | Electroimpregnation of paper and non-woven fabrics |
| JPH09207467A (ja) | 1996-02-02 | 1997-08-12 | Fuji Photo Film Co Ltd | 平版印刷版支持体の製造方法 |
-
1932
- 1932-06-28 FR FR739214D patent/FR739214A/fr not_active Expired
- 1932-06-29 GB GB18357/32A patent/GB394816A/en not_active Expired
- 1932-07-12 BE BE389800D patent/BE389800A/xx unknown
- 1932-10-18 US US638345A patent/US2015864A/en not_active Expired - Lifetime
-
1933
- 1933-03-03 US US659596A patent/US2015865A/en not_active Expired - Lifetime
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE908052C (de) * | 1939-04-22 | 1954-04-01 | Pfersee Chem Fab | Verfahren zur Herstellung konzentrierter waesseriger Emulsionen |
| DE748226C (de) * | 1939-05-05 | 1944-10-30 | Verfahren zum Wasserabstossendmachen von Faserstoffen | |
| US2442972A (en) * | 1941-01-23 | 1948-06-08 | Sidney M Edelstein | Aqueous dispersions of electropositive materials |
| US2424831A (en) * | 1942-11-24 | 1947-07-29 | Quaker Chemical Products Corp | Composition for waterproofing and fireproofing textile material, and the treated material |
| US2420233A (en) * | 1943-09-07 | 1947-05-06 | Boake Roberts & Company Ltd A | Production of aluminum salts of organic acids |
| US2544732A (en) * | 1945-09-27 | 1951-03-13 | Isaac L Shechmeister | Method for rendering a fabric germicidal |
| US2563289A (en) * | 1947-06-12 | 1951-08-07 | Owens Corning Fiberglass Corp | Coated glass fibers and method for producing same |
| US2746836A (en) * | 1951-08-31 | 1956-05-22 | Monsanto Chemicals | Process of dyeing acrylonitrile fibers |
| US3022885A (en) * | 1957-03-11 | 1962-02-27 | Inland Container Corp | Antimar coated articles |
| US3619258A (en) * | 1968-04-10 | 1971-11-09 | Phillips Petroleum Co | Plasticized sulfur, coated asphalt impregnated fabric |
| US3945792A (en) * | 1969-07-09 | 1976-03-23 | Ciba-Geigy Corporation | Process for the filling of leather and compositions therefor |
| US3657003A (en) * | 1970-02-02 | 1972-04-18 | Western Electric Co | Method of rendering a non-wettable surface wettable |
| US7666410B2 (en) | 2002-12-20 | 2010-02-23 | Kimberly-Clark Worldwide, Inc. | Delivery system for functional compounds |
| US7582308B2 (en) | 2002-12-23 | 2009-09-01 | Kimberly-Clark Worldwide, Inc. | Odor control composition |
| US7678367B2 (en) | 2003-10-16 | 2010-03-16 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using metal-modified particles |
| US7488520B2 (en) | 2003-10-16 | 2009-02-10 | Kimberly-Clark Worldwide, Inc. | High surface area material blends for odor reduction, articles utilizing such blends and methods of using same |
| US7582485B2 (en) | 2003-10-16 | 2009-09-01 | Kimberly-Clark Worldride, Inc. | Method and device for detecting ammonia odors and helicobacter pylori urease infection |
| US7438875B2 (en) | 2003-10-16 | 2008-10-21 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using metal-modified silica particles |
| US7141518B2 (en) | 2003-10-16 | 2006-11-28 | Kimberly-Clark Worldwide, Inc. | Durable charged particle coatings and materials |
| US7413550B2 (en) | 2003-10-16 | 2008-08-19 | Kimberly-Clark Worldwide, Inc. | Visual indicating device for bad breath |
| US7754197B2 (en) | 2003-10-16 | 2010-07-13 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using coordinated polydentate compounds |
| US7794737B2 (en) | 2003-10-16 | 2010-09-14 | Kimberly-Clark Worldwide, Inc. | Odor absorbing extrudates |
| US7837663B2 (en) | 2003-10-16 | 2010-11-23 | Kimberly-Clark Worldwide, Inc. | Odor controlling article including a visual indicating device for monitoring odor absorption |
| US7879350B2 (en) | 2003-10-16 | 2011-02-01 | Kimberly-Clark Worldwide, Inc. | Method for reducing odor using colloidal nanoparticles |
| US8211369B2 (en) | 2003-10-16 | 2012-07-03 | Kimberly-Clark Worldwide, Inc. | High surface area material blends for odor reduction, articles utilizing such blends and methods of using same |
| US8221328B2 (en) | 2003-10-16 | 2012-07-17 | Kimberly-Clark Worldwide, Inc. | Visual indicating device for bad breath |
| US8702618B2 (en) | 2003-10-16 | 2014-04-22 | Kimberly-Clark Worldwide, Inc. | Visual indicating device for bad breath |
Also Published As
| Publication number | Publication date |
|---|---|
| US2015865A (en) | 1935-10-01 |
| BE389800A (fr) | 1932-08-31 |
| FR739214A (fr) | 1933-01-06 |
| GB394816A (en) | 1933-07-06 |
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