US20150101675A1 - Positive connection indicator (visual or sound) - Google Patents
Positive connection indicator (visual or sound) Download PDFInfo
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- US20150101675A1 US20150101675A1 US14/395,939 US201214395939A US2015101675A1 US 20150101675 A1 US20150101675 A1 US 20150101675A1 US 201214395939 A US201214395939 A US 201214395939A US 2015101675 A1 US2015101675 A1 US 2015101675A1
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- Prior art keywords
- ammonia
- canister
- delivery system
- coupler
- reductant
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N11/00—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2066—Selective catalytic reduction [SCR]
- F01N3/208—Control of selective catalytic reduction [SCR], e.g. dosing of reducing agent
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2896—Liquid catalyst carrier
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2450/00—Methods or apparatus for fitting, inserting or repairing different elements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2550/00—Monitoring or diagnosing the deterioration of exhaust systems
- F01N2550/05—Systems for adding substances into exhaust
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2550/00—Monitoring or diagnosing the deterioration of exhaust systems
- F01N2550/24—Determining the presence or absence of an exhaust treating device
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/10—Adding substances to exhaust gases the substance being heated, e.g. by heating tank or supply line of the added substance
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/12—Adding substances to exhaust gases the substance being in solid form, e.g. pellets or powder
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/14—Arrangements for the supply of substances, e.g. conduits
- F01N2610/1406—Storage means for substances, e.g. tanks or reservoirs
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2900/00—Details of electrical control or of the monitoring of the exhaust gas treating apparatus
- F01N2900/06—Parameters used for exhaust control or diagnosing
- F01N2900/18—Parameters used for exhaust control or diagnosing said parameters being related to the system for adding a substance into the exhaust
- F01N2900/1806—Properties of reducing agent or dosing system
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/40—Engine management systems
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/0318—Processes
- Y10T137/0402—Cleaning, repairing, or assembling
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/8158—With indicator, register, recorder, alarm or inspection means
Definitions
- the present device and methods relate to status indicators for ammonia connectors. More specifically, the device and methods relate to positive status indicators for ensuring connection between two components in an ammonia system used on internal combustion engines for exhaust gas after-treatment systems.
- Compression ignition engines provide advantages in fuel economy, but produce both NO x and particulates during normal operation. New and existing regulations continually challenge manufacturers to achieve good fuel economy and reduce the particulates and NO x emissions. Lean-burn engines achieve the fuel economy objective, but the high concentrations of oxygen in the exhaust of these engines yields significantly high concentrations of NO x as well. Accordingly, the use of NO x reducing exhaust treatment schemes is being employed in a growing number of systems.
- One such system is the direct addition of a reducing agent or reductant, such as ammonia gas to the exhaust stream. It is an advantage to deliver ammonia directly in the form of a gas, both for simplicity of the flow control system and for efficient mixing of the reducing agent, ammonia, with the exhaust gas.
- the direct use of ammonia also eliminates potential difficulties related to blocking of the dosing system, which difficulties are typically caused by, e.g., precipitation or impurities in a liquid-based urea solution.
- an aqueous urea solution cannot be dosed at a low engine load since the temperature of the exhaust line would be too low for complete conversion of urea to ammonia (and CO 2 ).
- ammonia leaves the canister, it is in gas form and presents a potential hazard if released through an improper canister connection or through a broken feed line. Even a small leak could be problematic if only for the loss of ammonia, which may deplete the source earlier than scheduled replacement.
- the present system and methods provide an on-board indication of a proper connection between the ammonia canister and the ammonia feed line.
- the system and methods facilitate proper scheduling of removal and replacement of ammonia canisters as well as provide real-time ammonia loads for canisters.
- the invention is an ammonia storage and dosing system which uses at least one canister containing a supply of ammonia in an ammonia adsorbing/desorbing material to supply, via a delivery line, an exhaust gas after-treatment system having an ammonia injector.
- a controller may be used to meter the flow of ammonia through the delivery line to the injector, while a status indicator indicates a status of the connection—i.e., connected or disconnected.
- the status indicator provides a visual signal or indication, such as an LED or series of LEDs, an audible signal, such as a beep, click or buzz, or both.
- a visual signal or indication such as an LED or series of LEDs
- an audible signal such as a beep, click or buzz
- the status indicator may be an analog or digital gauge.
- FIG. 1 is a schematic overview of an ammonia storage and dosing system working in conjunction with a vehicle engine system, exhaust gas after-treatment system and the vehicle electronics;
- FIG. 2 is a schematic illustrating an embodiment of the present on-board fill-status indicator system
- FIG. 3 is a schematic illustrating a partial cross-section of an ammonia canister and an embodiment of the present canister fill-status indicator system
- FIG. 4 illustrates a particular embodiment of the indicator system used in a three cartridge array
- FIG. 5 is a schematic illustrating an embodiment of a feed line coupler/canister connection status indicator
- FIG. 6 is a schematic illustrating an embodiment of a line-break detection and indicator system
- FIGS. 7A-7D illustrate various embodiments of the placement of the line-break detection wire.
- Ammonia storage and dosing systems which are part of the exhaust gas NO x reduction (EGNR) system used in vehicles, may be comprised of several components, including a start-up canister, at least one main canister contained within a housing or storage compartment, wherein the canisters contain an ammonia adsorbing/desorbing material, an ammonia control module (AFM), a peripheral interface module (PIM), and possibly other components depending on vehicle specifications.
- the ASDS designated with the reference number 10 in the figures, typically works in conjunction with an internal combustion engine 12 , an exhaust gas after-treatment system 14 , and vehicle electronics 16 .
- At least one canister 20 containing a supply of ammonia having a solid (powder or granular) form is loaded into a carrier and secured in place.
- the canister 20 is connected to a metering system 22 via special tubing 24 and a special connector 26 to prevent leakage of the ammonia.
- a plurality of canisters will be used to provide greater travel distance between recharging.
- a heating jacket (not shown) is typically used around the canister to bring the ammonia adsorbing/desorbing material to a sublimation temperature.
- Suitable ammonia adsorbing/desorbing material useful in the treatment of NO x in an exhaust stream includes metal-ammine salts, which offer a solid storage medium for ammonia, and represent a safe, practical and compact option for storage and transportation of ammonia.
- Ammonia may be released or desorbed from the metal ammine salt by heating the salt to temperatures in the range from 10° C. to the melting point to the metal ammine salt complex, for example, to a temperature from 30° to 700° C., and preferably to a temperature of from 100° to 500° C.
- ammine salt is best having the general formula M(NH 3 ) n X z , where M is one or more metal ions selected from the group consisting of Li, Mg, Ca, Sr, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn, n is the coordination number in the range of from 2 to 12, and X is one or more anions, depending on the valence of M, selected from the group consisting of F, Cl, Br, I, SO 4 , MoO 4 , and PO 4 .
- a saturated strontium chloride has been found to be preferable for the canister storage space.
- ammonia as the preferred reductant
- the invention is not limited to such embodiments, and other reductants may be utilized instead of, or in addition to, ammonia for carrying out the inventions disclosed and claimed herein.
- examples of such other, or additional reductants include, but are not limited to, urea, ammonium carbamate, and hydrogen.
- the ammonia is metered at the ammonia flow module (AFM) 28 and is directed to an exhaust gas after-treatment system 14 having an ammonia injector 30 , as shown in FIG. 1 .
- the AFM 28 includes a controller 34 for metering flow of ammonia to an injector located within the after-treatment system 14 .
- metering it is meant that the controller 34 controls ammonia flow (rate and duration) and stores information about such details, possibly including for example: (1) the amount of ammonia required by the exhaust gas after-treatment system 14 ; (2) the amount of ammonia being delivered; (3) which of the multiple canisters provided ammonia; (4) the starting volume of deliverable ammonia in the canister; and (5) other such data which may be relevant to determining the amount of deliverable ammonia in each canister.
- the information may be monitored on a periodic or continuous basis.
- a status indicator 40 electronically connected to the controller 34 is activated.
- the indicator 40 may be used to generally indicate a status of the canister 20 , such as, for example, “Full” or “Empty” (see FIG. 4 , for example) or it may be a type of analog or digital gauge used to indicate a specific amount of remaining deliverable ammonia.
- the predetermined threshold level may be “empty” or it may be, for example, when only 10% of deliverable ammonia remains in a canister.
- the status indicator may use an analog or digital display of remaining ammonia, much like a fuel gauge on a vehicle operates.
- the visual indicator 40 may be mounted in proximity to the canister storage area to better advise those individuals charged with recharging and replacing empty canisters, and/or the indicator 40 may be mounted within the vehicle cab as part of the vehicle instrument cluster 42 .
- the controller 34 automatically switches to a second supply of ammonia in a second canister.
- a method for tracking the ammonia level in the ammonia canister 20 may be used on each canister, as illustrated in FIG. 3 . That is, after a canister is removed from the vehicle's ammonia storage and delivery system, the remaining ammonia in the subject canister can be readily determined Generally speaking, the method comprises attaching a memory storage device to each ammonia canister, determining the volume of ammonia in the canister, storing information relevant to the determined volume in the memory storage device and periodically updating the information on the memory storage device as the ammonia is used.
- the method further comprises metering the use of the ammonia after the step of storing the information.
- the system controller 34 previously described is suitable for such metering and information storage. However, the controller 34 remains with the vehicle when the ammonia canisters are removed and, therefore, cannot suitably operate to make such information available for a removed canister.
- the memory storage device 50 affixed to the ammonia canister comprises an RFID tag 50 which can be read by a conventional RFID reader 52 .
- an RFID reader/writer in the metering system 22 can frequently update the information stored on the RFID tag 50 as ammonia is depleted.
- the controller 34 determines information about each coupled canister 20
- the RFID reader/writer can easily write such information to the individual RFID tag 50 on each canister.
- Periodically or continuously updating the information merely comprises the steps of calculating the amount of ammonia remaining in the canister based on the flow rate and duration metered by the controller 34 and then storing a value relevant to the calculated amount on the memory storage device, i.e., the RFID tag 50 .
- each ammonia canister 20 comprises a memory storage device (e.g., RFID tag) 50 affixed to the canister 20 , wherein the memory storage device contains information relevant to the volume of ammonia-containing storage material stored in the canister at a given time.
- the vehicle components include a metering device for tracking the amount of ammonia delivered from the canister over a period of time, and an input device (e.g., RFID reader/writer) for periodically updating the memory storage device based on the amount of ammonia delivered from the canister 20 as tracked by the metering device 22 .
- the memory storage device 50 is updated with current ammonia load information. Then, a conventional handheld RFID reader 52 may be used at canister drop-off locations to determine the fill-status of each canister 20 .
- FIGS. 5-7 another aspect of the present system can be more readily understood.
- an embodiment of the system includes a positive connection indicator 60 which signals when a proper connection is achieved between the ammonia supply and the feed/delivery line 24 .
- At least one canister 20 containing a supply of ammonia in an ammonia adsorbing/desorbing material is connected, via a coupler 26 attached to an end of an ammonia delivery line 24 , to an exhaust gas after-treatment system 14 having an ammonia injector 30 .
- an AFM 28 having a controller 34 is used for metering flow of the ammonia through the delivery line 24 to the injector 30 .
- the connection status indicator 60 is used to provide a connection status of the coupler 26 to the canister 20 or a manifold (not shown) where multiple canisters are in use.
- the status indicator 60 may provide a visual signal 62 , an audible signal 66 , or both when a proper connection is made.
- a preferred indicator is an LED or a series of LEDs.
- the visual signal 62 may be provided by an analog display/gauge 63 or a digital display 64 .
- the audible signal 66 may be provided by an electronic annunciator using any variety or combination of sounds, including a click, beep, buzzer, etc.
- the status indicator 60 can be used to indicate either proper or improper connection or disconnection of the coupler 26 to the canister 20 .
- the user is able to verify a proper connection between an ammonia canister 20 and a coupler attached to a feed line 24 for a delivery system 10 .
- at least one ammonia canister 20 must be positioned for connection to a coupler 26 fixed to an ammonia feed line 24 .
- a mechanism such as the status indicator 60 must be set to activate upon a proper connection between the ammonia canister 20 and the coupler 26 .
- the user connects the coupler 26 to the ammonia canister 20 , the user is able to determine whether the mechanism has been activated and, therefore, whether a proper connection has been made.
- the user may disconnect the coupler 26 from the ammonia canister 20 and then reconnect the coupler 26 to the ammonia canister 20 . This disconnect/reconnect pattern can be followed until the user has determined that that the status indicator 60 has been activated.
- a feature of another embodiment of the ammonia delivery system 10 is the use of a line-break detector 70 and indicator 72 .
- the line-break indicator 72 is connected and responsive to the detector 70 and is useful for visually and/or audibly indicating a disconnection or break at any point in the ammonia delivery line 24 .
- a preferred mechanism for use with the line-break indicator 72 is an electronic annunciator connected to the line break detector 70 .
- the annunciator may be a LED, a series of LEDs, or some other electronic visual signal, such as an analog or digital gauge.
- the annunciator may also emit an audible signal such as a beep, buzz, click, chime or the like.
- the preferred line-break detector 70 for the ammonia delivery system 10 comprises at least one wire 74 extending a length of the feed line 24 , from the coupler 26 to the flow controller 28 .
- the wire(s) 74 would have an electric signal constantly running there through such that a break in any part of the wire 74 would prevent transmission of the signal.
- a break in the wire(s) 74 would coincide with a break in the physical ammonia feed line 24 .
- the termination of the electric signal would trigger the activation of the line-break indicator 72 .
- the wire(s) 74 may be positioned on an external surface of the feed line 24 ( 7 A), integrated into a sidewall of the feed line 24 ( 7 B), located within an interior of the feed line 24 ( 7 C), or a combination of these locations ( 7 D).
- the ammonia flow controller 28 may be signaled to automatically stop the ammonia flow from the canister 20 through the feed line 24 upon an event related to a line break, such as termination of the electric signal or activation of the line-break indicator 72 .
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
Description
- The present device and methods relate to status indicators for ammonia connectors. More specifically, the device and methods relate to positive status indicators for ensuring connection between two components in an ammonia system used on internal combustion engines for exhaust gas after-treatment systems.
- Compression ignition engines provide advantages in fuel economy, but produce both NOx and particulates during normal operation. New and existing regulations continually challenge manufacturers to achieve good fuel economy and reduce the particulates and NOx emissions. Lean-burn engines achieve the fuel economy objective, but the high concentrations of oxygen in the exhaust of these engines yields significantly high concentrations of NOx as well. Accordingly, the use of NOx reducing exhaust treatment schemes is being employed in a growing number of systems.
- One such system is the direct addition of a reducing agent or reductant, such as ammonia gas to the exhaust stream. It is an advantage to deliver ammonia directly in the form of a gas, both for simplicity of the flow control system and for efficient mixing of the reducing agent, ammonia, with the exhaust gas. The direct use of ammonia also eliminates potential difficulties related to blocking of the dosing system, which difficulties are typically caused by, e.g., precipitation or impurities in a liquid-based urea solution. In addition, an aqueous urea solution cannot be dosed at a low engine load since the temperature of the exhaust line would be too low for complete conversion of urea to ammonia (and CO2).
- Due to its caustic nature, transporting ammonia as a pressurized liquid can be hazardous if the container bursts as the result of an accident or if a valve or tube breaks. In the case of using a solid storage medium, the safety issues are much less critical since a small amount of heat is required to release the ammonia and the equilibrium pressure at room temperature can be—if a proper solid material is chosen—well below 1 bar. Solid ammonia-containing material, as a powder or granular form, can be provided in the form of disks or balls loaded into a cartridge or canister. The canisters are then loaded into a mantle or other storage device and secured to the vehicle for use. Appropriate heat is applied to the canisters, which then causes the ammonia-containing storage material to release ammonia gas from the canister into a feed line where it is metered into the exhaust system of a vehicle, for example.
- However, as the ammonia leaves the canister, it is in gas form and presents a potential hazard if released through an improper canister connection or through a broken feed line. Even a small leak could be problematic if only for the loss of ammonia, which may deplete the source earlier than scheduled replacement.
- Further, as alluded to above, eventually the ammonia in a canister is depleted and must be recharged or replaced. Unfortunately, there are no systems in place which are capable of indicating the fill-status of a canister. This shortcoming requires a plurality of canisters to be used in a vehicle system in order to provide a level of redundancy. Further, the canisters are typically changed on a regular basis, regardless of the fill-level, to avoid the possibility of ammonia depletion during engine operation. The result is sometimes the carrying of too much ammonia to provide the desired redundancy, and sometimes the removal and replacement of partially-filled ammonia canisters with full canisters to avoid depletion. Such conditions and procedures may increase the possibility of an accidental ammonia release.
- Thus, the present system and methods provide an on-board indication of a proper connection between the ammonia canister and the ammonia feed line. The system and methods facilitate proper scheduling of removal and replacement of ammonia canisters as well as provide real-time ammonia loads for canisters. These and other problems are addressed and resolved by the disclosed systems and method of the present application.
- Generally speaking, the invention is an ammonia storage and dosing system which uses at least one canister containing a supply of ammonia in an ammonia adsorbing/desorbing material to supply, via a delivery line, an exhaust gas after-treatment system having an ammonia injector. A controller may be used to meter the flow of ammonia through the delivery line to the injector, while a status indicator indicates a status of the connection—i.e., connected or disconnected.
- In an embodiment, the status indicator provides a visual signal or indication, such as an LED or series of LEDs, an audible signal, such as a beep, click or buzz, or both. Alternatively, the status indicator may be an analog or digital gauge.
- Additional features and aspects of the invention can be more readily discerned from a reading of the following “Detailed Description” with reference to the appended drawing figures.
-
FIG. 1 is a schematic overview of an ammonia storage and dosing system working in conjunction with a vehicle engine system, exhaust gas after-treatment system and the vehicle electronics; -
FIG. 2 is a schematic illustrating an embodiment of the present on-board fill-status indicator system; -
FIG. 3 is a schematic illustrating a partial cross-section of an ammonia canister and an embodiment of the present canister fill-status indicator system; -
FIG. 4 illustrates a particular embodiment of the indicator system used in a three cartridge array; -
FIG. 5 is a schematic illustrating an embodiment of a feed line coupler/canister connection status indicator; -
FIG. 6 is a schematic illustrating an embodiment of a line-break detection and indicator system; and -
FIGS. 7A-7D illustrate various embodiments of the placement of the line-break detection wire. - With reference to
FIGS. 1-7 , the embodiments of the system and methods are described to one of skill in the relevant art. Ammonia storage and dosing systems (ASDS), which are part of the exhaust gas NOx reduction (EGNR) system used in vehicles, may be comprised of several components, including a start-up canister, at least one main canister contained within a housing or storage compartment, wherein the canisters contain an ammonia adsorbing/desorbing material, an ammonia control module (AFM), a peripheral interface module (PIM), and possibly other components depending on vehicle specifications. Generally speaking, the ASDS, designated with thereference number 10 in the figures, typically works in conjunction with aninternal combustion engine 12, an exhaust gas after-treatment system 14, andvehicle electronics 16. - In an embodiment of the ammonia storage and dosing or
delivery system 10, at least onecanister 20 containing a supply of ammonia having a solid (powder or granular) form is loaded into a carrier and secured in place. Thecanister 20 is connected to ametering system 22 viaspecial tubing 24 and aspecial connector 26 to prevent leakage of the ammonia. In most systems, a plurality of canisters will be used to provide greater travel distance between recharging. However, the current system works sufficiently with a single canister for some applications and as desired or necessary. A heating jacket (not shown) is typically used around the canister to bring the ammonia adsorbing/desorbing material to a sublimation temperature. - Suitable ammonia adsorbing/desorbing material useful in the treatment of NOx in an exhaust stream includes metal-ammine salts, which offer a solid storage medium for ammonia, and represent a safe, practical and compact option for storage and transportation of ammonia. Ammonia may be released or desorbed from the metal ammine salt by heating the salt to temperatures in the range from 10° C. to the melting point to the metal ammine salt complex, for example, to a temperature from 30° to 700° C., and preferably to a temperature of from 100° to 500° C. It has been found that the ammine salt is best having the general formula M(NH3)nXz, where M is one or more metal ions selected from the group consisting of Li, Mg, Ca, Sr, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn, n is the coordination number in the range of from 2 to 12, and X is one or more anions, depending on the valence of M, selected from the group consisting of F, Cl, Br, I, SO4, MoO4, and PO4. A saturated strontium chloride has been found to be preferable for the canister storage space. While embodiments using ammonia as the preferred reductant are disclosed, the invention is not limited to such embodiments, and other reductants may be utilized instead of, or in addition to, ammonia for carrying out the inventions disclosed and claimed herein. Examples of such other, or additional reductants include, but are not limited to, urea, ammonium carbamate, and hydrogen.
- Once converted to a gas, the ammonia is metered at the ammonia flow module (AFM) 28 and is directed to an exhaust gas after-
treatment system 14 having anammonia injector 30, as shown inFIG. 1 . The AFM 28 includes acontroller 34 for metering flow of ammonia to an injector located within the after-treatment system 14. By “metering” it is meant that thecontroller 34 controls ammonia flow (rate and duration) and stores information about such details, possibly including for example: (1) the amount of ammonia required by the exhaust gas after-treatment system 14; (2) the amount of ammonia being delivered; (3) which of the multiple canisters provided ammonia; (4) the starting volume of deliverable ammonia in the canister; and (5) other such data which may be relevant to determining the amount of deliverable ammonia in each canister. The information may be monitored on a periodic or continuous basis. When thecontroller 34 determines that the amount of deliverable ammonia (i.e., approximately the amount of ammonia remaining in a particular canister) is below a predetermined level, astatus indicator 40 electronically connected to thecontroller 34 is activated. Theindicator 40 may be used to generally indicate a status of thecanister 20, such as, for example, “Full” or “Empty” (seeFIG. 4 , for example) or it may be a type of analog or digital gauge used to indicate a specific amount of remaining deliverable ammonia. - In an embodiment for indicating a general threshold level of ammonia, the status indicator is preferably a single LED or other such simple visual indicator capable of signifying two separate conditions (e.g., LED “on”=empty and “off”=not empty). The predetermined threshold level may be “empty” or it may be, for example, when only 10% of deliverable ammonia remains in a canister. In a similar embodiment, the status indicator may include a series of LEDs (or other such visual indicators) to indicate ranges or a decreasing series of different threshold levels of deliverable ammonia remaining—e.g., one light=80%, two lights=50%, three lights=20%, etc. For more acute concerns, the status indicator may use an analog or digital display of remaining ammonia, much like a fuel gauge on a vehicle operates.
- The
visual indicator 40 may be mounted in proximity to the canister storage area to better advise those individuals charged with recharging and replacing empty canisters, and/or theindicator 40 may be mounted within the vehicle cab as part of thevehicle instrument cluster 42. When a first canister registers as “empty” or when it is removed from the canister mounting, thecontroller 34 automatically switches to a second supply of ammonia in a second canister. - In another feature of an embodiment of the present system, a method for tracking the ammonia level in the
ammonia canister 20 may be used on each canister, as illustrated inFIG. 3 . That is, after a canister is removed from the vehicle's ammonia storage and delivery system, the remaining ammonia in the subject canister can be readily determined Generally speaking, the method comprises attaching a memory storage device to each ammonia canister, determining the volume of ammonia in the canister, storing information relevant to the determined volume in the memory storage device and periodically updating the information on the memory storage device as the ammonia is used. - As with the
system 10 previously described, the method further comprises metering the use of the ammonia after the step of storing the information. Thesystem controller 34 previously described is suitable for such metering and information storage. However, thecontroller 34 remains with the vehicle when the ammonia canisters are removed and, therefore, cannot suitably operate to make such information available for a removed canister. Instead, thememory storage device 50 affixed to the ammonia canister comprises anRFID tag 50 which can be read by aconventional RFID reader 52. - When a
canister 20 is connected to the vehicle's ammonia storage anddosing system 10, an RFID reader/writer in themetering system 22 can frequently update the information stored on theRFID tag 50 as ammonia is depleted. As thecontroller 34 determines information about each coupledcanister 20, the RFID reader/writer can easily write such information to theindividual RFID tag 50 on each canister. Periodically or continuously updating the information merely comprises the steps of calculating the amount of ammonia remaining in the canister based on the flow rate and duration metered by thecontroller 34 and then storing a value relevant to the calculated amount on the memory storage device, i.e., theRFID tag 50. - In an embodiment of the canister ammonia volume tracking method, each
ammonia canister 20 comprises a memory storage device (e.g., RFID tag) 50 affixed to thecanister 20, wherein the memory storage device contains information relevant to the volume of ammonia-containing storage material stored in the canister at a given time. The vehicle components include a metering device for tracking the amount of ammonia delivered from the canister over a period of time, and an input device (e.g., RFID reader/writer) for periodically updating the memory storage device based on the amount of ammonia delivered from thecanister 20 as tracked by themetering device 22. - Before the
canister 20 is removed from the vehicle, thememory storage device 50 is updated with current ammonia load information. Then, a conventionalhandheld RFID reader 52 may be used at canister drop-off locations to determine the fill-status of eachcanister 20. - Referring to
FIGS. 5-7 , another aspect of the present system can be more readily understood. There are two additional points for potential ammonia leaks in the present system. The first is as a result of an improper coupling at any point in the ammonia flow, while the second is as a result of a break in the feed line. - As to leaks due to improper couplings, an embodiment of the system includes a
positive connection indicator 60 which signals when a proper connection is achieved between the ammonia supply and the feed/delivery line 24. At least onecanister 20 containing a supply of ammonia in an ammonia adsorbing/desorbing material is connected, via acoupler 26 attached to an end of anammonia delivery line 24, to an exhaust gas after-treatment system 14 having anammonia injector 30. As previously described, anAFM 28 having acontroller 34 is used for metering flow of the ammonia through thedelivery line 24 to theinjector 30. Theconnection status indicator 60 is used to provide a connection status of thecoupler 26 to thecanister 20 or a manifold (not shown) where multiple canisters are in use. - In an embodiment of the ammonia storage and
dosing system 10, thestatus indicator 60 may provide avisual signal 62, anaudible signal 66, or both when a proper connection is made. A preferred indicator is an LED or a series of LEDs. Alternatively, thevisual signal 62 may be provided by an analog display/gauge 63 or adigital display 64. Theaudible signal 66 may be provided by an electronic annunciator using any variety or combination of sounds, including a click, beep, buzzer, etc. Thestatus indicator 60 can be used to indicate either proper or improper connection or disconnection of thecoupler 26 to thecanister 20. - In use, the user is able to verify a proper connection between an
ammonia canister 20 and a coupler attached to afeed line 24 for adelivery system 10. First, at least oneammonia canister 20 must be positioned for connection to acoupler 26 fixed to anammonia feed line 24. Then, a mechanism such as thestatus indicator 60 must be set to activate upon a proper connection between theammonia canister 20 and thecoupler 26. When the user connects thecoupler 26 to theammonia canister 20, the user is able to determine whether the mechanism has been activated and, therefore, whether a proper connection has been made. - Where an activation of the
status indicator 60 is not made—i.e., the connection is not proper—then the user may disconnect thecoupler 26 from theammonia canister 20 and then reconnect thecoupler 26 to theammonia canister 20. This disconnect/reconnect pattern can be followed until the user has determined that that thestatus indicator 60 has been activated. - The other potential for an ammonia gas leak is as a result of a break or disconnection of some kind in the
ammonia delivery line 24. Accordingly, a feature of another embodiment of theammonia delivery system 10 is the use of a line-break detector 70 andindicator 72. The line-break indicator 72 is connected and responsive to thedetector 70 and is useful for visually and/or audibly indicating a disconnection or break at any point in theammonia delivery line 24. - As with the
connection indicator 60 described above, a preferred mechanism for use with the line-break indicator 72 is an electronic annunciator connected to theline break detector 70. The annunciator may be a LED, a series of LEDs, or some other electronic visual signal, such as an analog or digital gauge. The annunciator may also emit an audible signal such as a beep, buzz, click, chime or the like. - The preferred line-
break detector 70 for theammonia delivery system 10 comprises at least onewire 74 extending a length of thefeed line 24, from thecoupler 26 to theflow controller 28. The wire(s) 74 would have an electric signal constantly running there through such that a break in any part of thewire 74 would prevent transmission of the signal. A break in the wire(s) 74 would coincide with a break in the physicalammonia feed line 24. The termination of the electric signal would trigger the activation of the line-break indicator 72. - The positioning of the line-
break detector 70 is variable. As illustrated inFIGS. 7A-7D , the wire(s) 74 may be positioned on an external surface of the feed line 24 (7A), integrated into a sidewall of the feed line 24 (7B), located within an interior of the feed line 24 (7C), or a combination of these locations (7D). - As still a further safety feature of the present
ammonia delivery system 10, theammonia flow controller 28 may be signaled to automatically stop the ammonia flow from thecanister 20 through thefeed line 24 upon an event related to a line break, such as termination of the electric signal or activation of the line-break indicator 72.
Claims (17)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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PCT/US2012/035145 WO2013162565A1 (en) | 2012-04-26 | 2012-04-26 | Positive connection indicator (visual or sound) |
Publications (1)
Publication Number | Publication Date |
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US20150101675A1 true US20150101675A1 (en) | 2015-04-16 |
Family
ID=49483667
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US14/395,939 Abandoned US20150101675A1 (en) | 2012-04-26 | 2012-04-26 | Positive connection indicator (visual or sound) |
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US (1) | US20150101675A1 (en) |
WO (1) | WO2013162565A1 (en) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4115733A (en) * | 1976-09-17 | 1978-09-19 | The United States Of America As Represented By Of The Department Of Health, Education And Welfare | Digital display plug-in |
US5543782A (en) * | 1993-11-16 | 1996-08-06 | Protex International Corp. | Security device for merchandise and the like |
US5626129A (en) * | 1993-04-02 | 1997-05-06 | Josef Klimm | Device for monitoring at least one connection in a medical tubing system |
US20090019835A1 (en) * | 2007-07-16 | 2009-01-22 | Dingle Philip J G | Fluid delivery system |
-
2012
- 2012-04-26 US US14/395,939 patent/US20150101675A1/en not_active Abandoned
- 2012-04-26 WO PCT/US2012/035145 patent/WO2013162565A1/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4115733A (en) * | 1976-09-17 | 1978-09-19 | The United States Of America As Represented By Of The Department Of Health, Education And Welfare | Digital display plug-in |
US5626129A (en) * | 1993-04-02 | 1997-05-06 | Josef Klimm | Device for monitoring at least one connection in a medical tubing system |
US5543782A (en) * | 1993-11-16 | 1996-08-06 | Protex International Corp. | Security device for merchandise and the like |
US20090019835A1 (en) * | 2007-07-16 | 2009-01-22 | Dingle Philip J G | Fluid delivery system |
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