US20140102659A1 - Method for making an arrangement consisting of a cast part and a cast-in component - Google Patents

Method for making an arrangement consisting of a cast part and a cast-in component Download PDF

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Publication number
US20140102659A1
US20140102659A1 US14/134,855 US201314134855A US2014102659A1 US 20140102659 A1 US20140102659 A1 US 20140102659A1 US 201314134855 A US201314134855 A US 201314134855A US 2014102659 A1 US2014102659 A1 US 2014102659A1
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Prior art keywords
cast
component
coating
nickel layer
layer
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Abandoned
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US14/134,855
Inventor
Gerhard Bucher
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Mahle International GmbH
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Mahle International GmbH
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Priority to US14/134,855 priority Critical patent/US20140102659A1/en
Assigned to MAHLE INTERNATIONAL GMBH reassignment MAHLE INTERNATIONAL GMBH ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BUCHER, GERHARD
Publication of US20140102659A1 publication Critical patent/US20140102659A1/en
Abandoned legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00—Casting in, on, or around objects which form part of the product
    • B22D19/0081—Casting in, on, or around objects which form part of the product pretreatment of the insert, e.g. for enhancing the bonding between insert and surrounding cast metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00—Casting in, on, or around objects which form part of the product
    • B22D19/0009—Cylinders, pistons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00—Casting in, on, or around objects which form part of the product
    • B22D19/0009—Cylinders, pistons
    • B22D19/0027—Cylinders, pistons pistons
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/12—Electroplating: Baths therefor from solutions of nickel or cobalt
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00—Electroplating characterised by the article coated
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D15/00—Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/627—Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12451—Macroscopically anomalous interface between layers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12472—Microscopic interfacial wave or roughness
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771—Transition metal-base component
    • Y10T428/12861—Group VIII or IB metal-base component
    • Y10T428/12937—Co- or Ni-base component next to Fe-base component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771—Transition metal-base component
    • Y10T428/12861—Group VIII or IB metal-base component
    • Y10T428/12944—Ni-base component

Definitions

  • the present invention relates to a method of making an arrangement consisting of a cast part and a cast-in component having a coating composed of a metallic coating material.
  • components frequently have to be provided with a coating that can fulfill various tasks, for example as a tribological coating or as a connection layer between two components.
  • An example is the production of cast parts composed of metals or metal alloys, in which other components, namely cast-in components, composed of a metallic material that differs from that of the cast part, are cast in.
  • This relates, for example, to cast parts composed of light-metal alloys, in the form of crankcases for internal combustion engines.
  • Cylinder liners are cast into these crankcases, which liners generally consist of iron casting materials, steels, or tribologically suitable light-metal alloys, for example having a high silicon content and/or intermetallic phases.
  • Another example is a hoop composed of steel or cast iron, which is cast into a brake drum composed of a light-metal alloy.
  • the cast-in component is generally provided with a coating on its surface that stands in contact with the cast part, which coating adheres well to the cast-in component, for one thing, and allows an alloy connection to be formed by the material of the cast part.
  • thermally spray-coated layers are used as coatings, not only for cast-in components, but also for other components; these layers are applied to the surface of the component by means of one of the known spray-coating methods (for example wire flame spray-coating, powder flame spray-coating, arc wire spray-coating, plasma spray-coating, HVOF spray-coating, cold gas spray-coating, and more).
  • spray-coating methods for example wire flame spray-coating, powder flame spray-coating, arc wire spray-coating, plasma spray-coating, HVOF spray-coating, cold gas spray-coating, and more.
  • thermally spray-coated layers adhere to the component solely on the basis of physical bonds.
  • Thermally spray-coated layers are furthermore generally not free of embedded oxides and porosities. All this is expressed in the adhesion tensile strength of thermally spray-coated layers, which is determined using the adhesion tensile test and generally lies in the range of 10 to 50 N/mm 2 , depending on the material and production quality (in the case of wire flame spray-coating and arc wire spray-coating, generally at 10 to 30 N/mm 2 ). There is therefore the risk that the thermally spray-coated layer tears off under great stress. Because of the great investment requirement for thermal spray-coating and process monitoring, thermally spray-coated layers represent a cost-intensive solution.
  • Coatings are also known that are obtained by means of dipping the component to be coated into a zinc or zinc-based alloy melt.
  • an immersion layer is generally formed, which adheres with sufficient strength after it hardens.
  • these coatings are not reliably suited for cast-in components, because the layer can come loose from the cast-in component during the casting-in process, on the basis of the thermal expansion of the zinc, and furthermore, it is weakened at the boundary region to the cast-in material, by means of a pore seam composed of Kirkendall pores.
  • the present invention is therefore based on the task of making available a coating for a cast-in component as well as a cast-in component that is coated on at least part of its surface, whereby a firm bond between the coating obtained and the component, particularly a good adhesion tensile strength, is supposed to be achievable in cost-advantageous manner.
  • the solution consists of a coating that consists of galvanically applied nickel, and in a cast-in component that is provided with a coating in the form of a galvanically applied nickel layer on at least part of its surface.
  • the coating according to the invention and the cast-in component according to the invention are characterized in that a firm bond between the surface of the cast-in component and the coating is produced in particularly simple and cost-advantageous manner.
  • the thermal expansion coefficient of nickel amounts to 13.3 ⁇ 10 ⁇ 6 K ⁇ 1 , and therefore lies between the values for cast iron (12.0 ⁇ 10 ⁇ 6 K ⁇ 1 ) and aluminum block alloys (21.0 ⁇ 10 ⁇ 6 K ⁇ 1 ).
  • no weakening of the bond between the galvanically applied nickel layer and the cast-in component needs to be feared on the basis of thermal expansion of the coated cast-in component, during the casting-in process.
  • the coating according to the invention therefore adheres to the cast-in component much more firmly than thermally spray-coated layers.
  • any desired metallic materials can be used for the cast-in component, because the galvanically applied nickel layer can form intermetallic bonds or alloys with the material of the cast-in component.
  • the cast-in component according to the invention can be processed further in usual manner, and is suitable for many purposes. It can be cast into another cast part, for example, in a manner known to a person skilled in the art, by means of gravity casting, low-pressure casting, die-casting, squeeze casting. If necessary, the component coated according to the invention can be preheated.
  • a layer thickness of 3 ⁇ m to 80 ⁇ m has proven to be practical. Layer thicknesses of 5 ⁇ m to 50 ⁇ m are preferred, with which a satisfactory balance between good shear strength and low material consumption is achieved. A layer thickness of 15 ⁇ m is particularly preferred.
  • the coating according to the invention can furthermore contain solids dispersed in it, such as, for example, reinforcement fibers composed of metal or plastic or pyrogenic silicas. In this way, the stability of the coating according to the invention can be further increased.
  • a thin copper layer can also be galvanically deposited between the surface of the cast-in component and the coating according to the invention.
  • the coating according to the invention can be applied to surfaces having a broad spectrum of properties, and therefore can be used in particularly versatile manner. For example, surfaces having a rough depth of 5 ⁇ m to 1,400 ⁇ m are suitable.
  • the surfaces can be cast in finished form or pre-machined by cutting them.
  • the surfaces can also be blasted before the coating according to the invention is applied, for example with abrasives such as glass beads, corundum sand, or steel grit.
  • the cast-in component can consist, for example, of steel or cast iron, malleable cast iron, or a light-metal alloy such as, for example, an aluminum-based or magnesium-based alloy.
  • the cast-in component can be formed originally by means of casting, forging, rolling, or by way of powder metallurgy.
  • Typical examples of materials that are suitable for the cast-in component are aluminum alloys having up to 30 wt.-% silicon and/or up to 4 wt.-% copper and/or up to 4 wt.-% magnesium and/or up to 4 wt.-% nickel; aluminum-zinc alloys or copper-aluminum-nickel alloys (aluminum bronze); copper-tin alloys having up to 14 wt.-% tin (cast tin bronze); copper-zinc alloys having up to 44 wt.-% zinc; copper-nickel alloys or copper-nickel-iron alloy; steel from the group of the highly alloyed austenitic or ferritic steels; alloys on the basis of titanium.
  • a typical example of use of the present invention is cylinder liners that are provided with the coating according to the invention and cast into a crankcase of an engine block.
  • Another example is hoops that are provided with the coating according to the invention and cast into a brake drum, or furthermore for ring carriers that are cast into a piston.
  • a component is provided with a coating on its surface.
  • the component can have any desired shape, for example flat, ring-shaped, non-uniform, etc. Examples are a cylinder liner for an internal combustion engine, or a hoop for a brake drum.
  • the surface of the component Before being coated, the surface of the component can be cleaned with corundum sand, for example.
  • the surface can be cast in finished manner and be comparatively smooth. However, the surface can also be pre-machined by cutting, or roughened, for example produced using the rough-casting method.
  • a smoothly lathed cylinder liner for the crankcase of an internal combustion engine composed of cast iron was closed off with screw-on plastic caps, in order to prevent deposition of nickel in the liner interior.
  • the current contact can also be passed out of the cylinder liner by way of the screw connection.
  • the outer mantle surface as well as the face surfaces, on the head side and foot side, of the cylinder liner were first degreased using ultrasound, and then anodically degreased. After each work step, etching took place, and rinsing took place multiple times. This method of preparation is familiar to a person skilled in the art.
  • the coating according to the invention can be applied in the form of a matte nickel plating or a shiny nickel plating, whereby the less complicated matte nickel plating is completely sufficient.
  • Nickel sulfate in aqueous solution was used as an electrolyte, as the main component, for example on the basis of the Watt nickel electrolyte.
  • solids can also be contained in it, such as reinforcement fibers or pyrogenic silicas, which disperse into the coating that forms during the production process.
  • the layer thickness of the coating according to the invention is controlled in known manner, by way of the parameters current density, bath temperature, and pH of the electrolyte. Deposition rates of 1.0 ⁇ m to 1.4 ⁇ m per minute have proven themselves. A typical deposition rate of 1.2 ⁇ m per minute for the cylinder liner coated in the exemplary embodiment is obtained, for example, at a current density of 6 A/dm 2 , a bath temperature of 60° C., and a pH of the electrolyte of 2.5 to 3.0. It is practical if the electrode is configured in such a manner that it surrounds the cylinder liner in the form of a cylinder mantle, in order to achieve a particularly uniform coating.
  • the finished, coated cylinder liner was cast into a crankcase.
  • the material of the crankcase was a block alloy of the AlSi8Cu3 type.
  • the cylinder liner according to the invention was heated to approximately 100° C., for practical reasons, particularly in order to remove traces of moisture.
  • the good adhesion of the coating according to the invention on the cast-in component is expressed, among other things, in the shear strength, whereby the cylinder liner galvanically coated with nickel on the outer mantle surface, according to the invention, already yielded values of 50 N/mm 2 when cast into the crankcase, using gravity casting.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Pistons, Piston Rings, And Cylinders (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Cylinder Crankcases Of Internal Combustion Engines (AREA)

Abstract

A method for making an arrangement consisting of a cast part and a cast-in component composed of a metallic material. The cast-in component is composed of a metallic material that has a galvanically applied nickel layer. The layer is applied by positioning the cast-in component in an electrolyte bath and applying the coating on at least part of the surface of the component. The cast-in component is then positioned in a casting mold and a cast part is casted around the cast-in part.

Description

    CROSS REFERENCE TO RELATED APPLICATIONS
  • This is a divisional of U.S. patent application Ser. No. 13/325,521, filed on Dec. 14, 2011, which claims priority under 35 U.S.C. §119 of German Application No. 10 2010 055 162.7 filed on Dec. 18, 2010, the disclosures of which are incorporated by reference.
    • BACKGROUND OF THE INVENTION
  • The present invention relates to a method of making an arrangement consisting of a cast part and a cast-in component having a coating composed of a metallic coating material.
  • In machine construction, in particular, components frequently have to be provided with a coating that can fulfill various tasks, for example as a tribological coating or as a connection layer between two components. An example is the production of cast parts composed of metals or metal alloys, in which other components, namely cast-in components, composed of a metallic material that differs from that of the cast part, are cast in. This relates, for example, to cast parts composed of light-metal alloys, in the form of crankcases for internal combustion engines. Cylinder liners are cast into these crankcases, which liners generally consist of iron casting materials, steels, or tribologically suitable light-metal alloys, for example having a high silicon content and/or intermetallic phases. Another example is a hoop composed of steel or cast iron, which is cast into a brake drum composed of a light-metal alloy.
  • In this connection, a firm bond between the material of the cast-in component and the material of the cast part is required, in order to ensure sufficient mechanical anchoring of the cast-in component in the cast part and good heat transfer between the cast-in component and the cast part. However, the materials used for the cast-in component and the cast part, respectively, are generally incompatible and do not form a firm bond with one another. For this reason, the cast-in component is generally provided with a coating on its surface that stands in contact with the cast part, which coating adheres well to the cast-in component, for one thing, and allows an alloy connection to be formed by the material of the cast part.
  • Frequently, thermally spray-coated layers are used as coatings, not only for cast-in components, but also for other components; these layers are applied to the surface of the component by means of one of the known spray-coating methods (for example wire flame spray-coating, powder flame spray-coating, arc wire spray-coating, plasma spray-coating, HVOF spray-coating, cold gas spray-coating, and more). Such a coating is described in DE 10 2005 027 828 A1, for example.
  • However, all the thermal spray-coating processes have in common that the thermally spray-coated layers adhere to the component solely on the basis of physical bonds. Thermally spray-coated layers are furthermore generally not free of embedded oxides and porosities. All this is expressed in the adhesion tensile strength of thermally spray-coated layers, which is determined using the adhesion tensile test and generally lies in the range of 10 to 50 N/mm2, depending on the material and production quality (in the case of wire flame spray-coating and arc wire spray-coating, generally at 10 to 30 N/mm2). There is therefore the risk that the thermally spray-coated layer tears off under great stress. Because of the great investment requirement for thermal spray-coating and process monitoring, thermally spray-coated layers represent a cost-intensive solution.
  • Coatings are also known that are obtained by means of dipping the component to be coated into a zinc or zinc-based alloy melt. In this connection, an immersion layer is generally formed, which adheres with sufficient strength after it hardens.
  • However, these coatings are not reliably suited for cast-in components, because the layer can come loose from the cast-in component during the casting-in process, on the basis of the thermal expansion of the zinc, and furthermore, it is weakened at the boundary region to the cast-in material, by means of a pore seam composed of Kirkendall pores.
    • SUMMARY OF THE INVENTION
  • The present invention is therefore based on the task of making available a coating for a cast-in component as well as a cast-in component that is coated on at least part of its surface, whereby a firm bond between the coating obtained and the component, particularly a good adhesion tensile strength, is supposed to be achievable in cost-advantageous manner.
  • The solution consists of a coating that consists of galvanically applied nickel, and in a cast-in component that is provided with a coating in the form of a galvanically applied nickel layer on at least part of its surface.
  • The coating according to the invention and the cast-in component according to the invention are characterized in that a firm bond between the surface of the cast-in component and the coating is produced in particularly simple and cost-advantageous manner. Nickel bonds easily to other metallic materials. It alloys with cast iron, for example, and forms a connection system with aluminum and its alloys. The thermal expansion coefficient of nickel amounts to 13.3×10−6 K−1, and therefore lies between the values for cast iron (12.0×10−6 K−1) and aluminum block alloys (21.0×10−6 K−1). Despite these differences, which still exist, no weakening of the bond between the galvanically applied nickel layer and the cast-in component needs to be feared on the basis of thermal expansion of the coated cast-in component, during the casting-in process.
  • The coating according to the invention therefore adheres to the cast-in component much more firmly than thermally spray-coated layers. Furthermore, any desired metallic materials can be used for the cast-in component, because the galvanically applied nickel layer can form intermetallic bonds or alloys with the material of the cast-in component.
  • The cast-in component according to the invention can be processed further in usual manner, and is suitable for many purposes. It can be cast into another cast part, for example, in a manner known to a person skilled in the art, by means of gravity casting, low-pressure casting, die-casting, squeeze casting. If necessary, the component coated according to the invention can be preheated.
  • A layer thickness of 3 μm to 80 μm has proven to be practical. Layer thicknesses of 5 μm to 50 μm are preferred, with which a satisfactory balance between good shear strength and low material consumption is achieved. A layer thickness of 15 μm is particularly preferred.
  • Depending on the area of application, the coating according to the invention can furthermore contain solids dispersed in it, such as, for example, reinforcement fibers composed of metal or plastic or pyrogenic silicas. In this way, the stability of the coating according to the invention can be further increased. Finally, a thin copper layer can also be galvanically deposited between the surface of the cast-in component and the coating according to the invention.
  • The coating according to the invention can be applied to surfaces having a broad spectrum of properties, and therefore can be used in particularly versatile manner. For example, surfaces having a rough depth of 5 μm to 1,400 μm are suitable. The surfaces can be cast in finished form or pre-machined by cutting them. The surfaces can also be blasted before the coating according to the invention is applied, for example with abrasives such as glass beads, corundum sand, or steel grit.
  • The cast-in component can consist, for example, of steel or cast iron, malleable cast iron, or a light-metal alloy such as, for example, an aluminum-based or magnesium-based alloy. The cast-in component can be formed originally by means of casting, forging, rolling, or by way of powder metallurgy. Typical examples of materials that are suitable for the cast-in component are aluminum alloys having up to 30 wt.-% silicon and/or up to 4 wt.-% copper and/or up to 4 wt.-% magnesium and/or up to 4 wt.-% nickel; aluminum-zinc alloys or copper-aluminum-nickel alloys (aluminum bronze); copper-tin alloys having up to 14 wt.-% tin (cast tin bronze); copper-zinc alloys having up to 44 wt.-% zinc; copper-nickel alloys or copper-nickel-iron alloy; steel from the group of the highly alloyed austenitic or ferritic steels; alloys on the basis of titanium.
  • A typical example of use of the present invention is cylinder liners that are provided with the coating according to the invention and cast into a crankcase of an engine block. Another example is hoops that are provided with the coating according to the invention and cast into a brake drum, or furthermore for ring carriers that are cast into a piston.
    • DETAILED DESCRIPTION OF THE EMBODIMENTS
  • Exemplary embodiments of the present invention will be explained in greater detail below.
  • A component is provided with a coating on its surface. The component can have any desired shape, for example flat, ring-shaped, non-uniform, etc. Examples are a cylinder liner for an internal combustion engine, or a hoop for a brake drum. Before being coated, the surface of the component can be cleaned with corundum sand, for example. The surface can be cast in finished manner and be comparatively smooth. However, the surface can also be pre-machined by cutting, or roughened, for example produced using the rough-casting method.
  • To prepare the coating, a smoothly lathed cylinder liner for the crankcase of an internal combustion engine composed of cast iron was closed off with screw-on plastic caps, in order to prevent deposition of nickel in the liner interior. The current contact can also be passed out of the cylinder liner by way of the screw connection. The outer mantle surface as well as the face surfaces, on the head side and foot side, of the cylinder liner were first degreased using ultrasound, and then anodically degreased. After each work step, etching took place, and rinsing took place multiple times. This method of preparation is familiar to a person skilled in the art.
  • The coating according to the invention can be applied in the form of a matte nickel plating or a shiny nickel plating, whereby the less complicated matte nickel plating is completely sufficient. Nickel sulfate in aqueous solution was used as an electrolyte, as the main component, for example on the basis of the Watt nickel electrolyte. If necessary, solids can also be contained in it, such as reinforcement fibers or pyrogenic silicas, which disperse into the coating that forms during the production process.
  • The layer thickness of the coating according to the invention is controlled in known manner, by way of the parameters current density, bath temperature, and pH of the electrolyte. Deposition rates of 1.0 μm to 1.4 μm per minute have proven themselves. A typical deposition rate of 1.2 μm per minute for the cylinder liner coated in the exemplary embodiment is obtained, for example, at a current density of 6 A/dm2, a bath temperature of 60° C., and a pH of the electrolyte of 2.5 to 3.0. It is practical if the electrode is configured in such a manner that it surrounds the cylinder liner in the form of a cylinder mantle, in order to achieve a particularly uniform coating.
  • The finished, coated cylinder liner was cast into a crankcase. The material of the crankcase was a block alloy of the AlSi8Cu3 type. Before being cast in, the cylinder liner according to the invention was heated to approximately 100° C., for practical reasons, particularly in order to remove traces of moisture.
  • The good adhesion of the coating according to the invention on the cast-in component is expressed, among other things, in the shear strength, whereby the cylinder liner galvanically coated with nickel on the outer mantle surface, according to the invention, already yielded values of 50 N/mm2 when cast into the crankcase, using gravity casting.

Claims (16)

What is claimed is:
1. A method for making an arrangement consisting of a cast part, and a cast-in component, around which the cast part is cast, comprising the following steps:
preparing a cast-in component composed of steel or cast iron or a light-metal alloy,
positioning the cast-in component in an electrolyte bath and applying a coating composed of a galvanically applied nickel layer on at least part of the surface of said cast-in component which is intended to be casted in a casting process,
positioning the coated cast-in part in a casting mould for said cast part, and
casting the cast part around the cast-in part.
2. The method according to claim 1, wherein the nickel layer is applied with a deposition rate of 1.0 μm to 1.4 μm per minute.
3. The method according to claim 1, where the nickel layer is applied at a current-density of 6 A/dm2.
4. The method according to claim 1, where the nickel layer is applied at a bath temperature of 60° C.
5. The method according to claim 1, where the nickel layer is applied at a pH value of the electrolyte bath of 2.5 to 3.0.
6. The method according to claim 1, where the nickel layer is applied using an electrolyte comprising an aqueous solution of nickel sulfate.
7. The method according to claim 1, wherein the electrolyte bath contains at least one solid component.
8. The method according to claim 1, wherein the coating after deposition of the nickel layer has a layer thickness of 3 μm to 80 μm.
9. The method according to claim 1, wherein the coating furthermore contains at least one of solids dispersed in the layer
10. The method according to claim 1, wherein the coating furthermore comprises a galvanically deposited carrier layer composed of copper.
11. The method according to claim 1, wherein the coating is applied to a surface region of the cast-in component having a rough depth of 5 μm to 1,400 μm.
12. The method according to claim 11, wherein the coating is applied to a surface region of the cast-in component that has been cast in finished manner or pre-machined by cutting.
13. The method according to claim 11, wherein the coating is applied to a blasted surface region.
14. The method according to claim 1, wherein the cast-in component is a cylinder liner and the cast part is a crankcase of an engine block.
15. The method according to claim 1, wherein the cast-in component is a hoop and the cast part is a break drum.
16. The method according to claim 1, wherein the cast-in component is a ring carrier and the cast part is a piston for an internal combustion engine.
US14/134,855 2010-12-18 2013-12-19 Method for making an arrangement consisting of a cast part and a cast-in component Abandoned US20140102659A1 (en)

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US13/325,521 US20120189864A1 (en) 2010-12-18 2011-12-14 Coating and cast-in component
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CN102534698B (en) 2016-06-29

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