US20140065346A1 - Processes to make water and oil repellent bcf yarn - Google Patents

Processes to make water and oil repellent bcf yarn Download PDF

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Publication number
US20140065346A1
US20140065346A1 US14/005,142 US201214005142A US2014065346A1 US 20140065346 A1 US20140065346 A1 US 20140065346A1 US 201214005142 A US201214005142 A US 201214005142A US 2014065346 A1 US2014065346 A1 US 2014065346A1
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Prior art keywords
yarn
bcf yarn
soil
nylon
fluorochemical
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US14/005,142
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Wae-Hai Tung
Ronnie Rittenhouse
Daniel Reynolds
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Invista North America LLC
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Individual
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Priority to US14/005,142 priority Critical patent/US20140065346A1/en
Assigned to INVISTA NORTH AMERICA S.A R.L. reassignment INVISTA NORTH AMERICA S.A R.L. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: TUNG, WAE-HAI, REYNOLDS, DANIEL, RITTENHOUSE, RONNIE
Publication of US20140065346A1 publication Critical patent/US20140065346A1/en
Abandoned legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47G—HOUSEHOLD OR TABLE EQUIPMENT
    • A47G27/00—Floor fabrics; Fastenings therefor
    • A47G27/02—Carpets; Stair runners; Bedside rugs; Foot mats
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/04—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments
    • D06B3/06—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of yarns, threads or filaments individually handled
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/34—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/576—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/01—Stain or soil resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23907—Pile or nap type surface or component
    • Y10T428/23957—Particular shape or structure of pile
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2922—Nonlinear [e.g., crimped, coiled, etc.]
    • Y10T428/2925—Helical or coiled

Definitions

  • the invention relates to anti-soil application processes for bulk continuous filament (BCF) carpet and related textile fabrics, and specifically, to processes for applying anti-soil compositions on BCF yarns during cable or air twisting processes prior to weaving, knitting or tufting.
  • the process foregoes the need to treat carpets and other textiles made from the BCF yarn, thus eliminating costly and environmentally unfavorable dyeing and low pH chemical treatment processes.
  • Also disclosed herein are systems used to apply the anti-soil formulations to the BCF yarn, and soil repellant yarns, and carpets with improved anti-soil properties made from the BCF yarn of the disclosed process.
  • Stain blocker e.g. acid dye blocker
  • anti-soil with fluorochemicals are traditionally used.
  • polyester carpets, such as 2GT and 3GT carpets, and polypropylene carpets anti-soil chemistry may be applied topically to the tufted carpet as part of the carpet finishing process.
  • Polyester and polypropylene carpets typically do not require a stain blocker treatment because of inherent stain resistance to acid dyes and stains owing to their lack of amine end groups that function as acid dye sites.
  • Topical application at the carpet mill can be in the form of exhaust application and spray application.
  • Exhaust application i.e. flex-nip process at high (300-400 wt. %) wet pick-up
  • Exhaust applications typically use higher amounts of water and energy to dry and cure the carpet than do spray applications.
  • Spray-on fluorochemical products are designed to use less water and energy than exhaust applications, but they do not impart anti-soil properties that are as good as those provided by the exhaust applications owing to limited depth of penetration into the fabric, especially deep pile fabrics and those incorporating the tightly twisted yarns that are now becoming more popular.
  • the carpet is also steamed and dyed first, steamed again, rinsed and extracted; and then a blend of SB and FC is applied together at high wet pick up, after which the carpet and chemicals are exposed once again to steam to fix the treatment, followed by drying.
  • SB and FC are applied together at high wet pick up, after which the carpet and chemicals are exposed once again to steam to fix the treatment, followed by drying.
  • low pH solutions, excess water, and energy are required for the SB and FC to penetrate the carpet and achieve uniform coverage.
  • the typical prior art process is as follows: BCF yarn ⁇ Twist ⁇ heat set ⁇ tufting ⁇ carpet ⁇ dye ⁇ stain block/anti-soil.
  • Carpets have also long been constructed of dyed or pigmented yarns, which constructions are treated in numerous possible ways, including the options of further dyeing, and the application of stain and/or soil resistant compositions with the concomitant use of steam and rinse water, as in the processes described above.
  • the invention disclosed herein provides a process to make textile fabrics, especially tufted articles, without the requirement for subsequent stain and soil resistant chemistry application, thus avoiding the cost and waste of steam fixing and rinsing attendant with such large-scale fabric applications.
  • the process involves application of topical chemistries to dyed or pigmented yarns immediately after twisting or cabling one or more such yarns together.
  • the chemistries are then heat-set onto the twisted yarn under dry conditions, and the twisted yarn subsequently weaved or tufted into a finished fabric or carpet.
  • Novel systems that enable the efficient application of topical chemistries to yarn subsequent to twisting and prior to winding and heat-setting are also disclosed.
  • the disclosed process uses an atopical chemistry composition applicator positioned within a mechanical twisting process downstream of the twisted yarn take-up reel and upstream of the yarn winder.
  • the disclosed process moves the backend, large scale and wasteful anti-soil application step, and if necessary, stain block application step, up front during yarn twisting.
  • the carpet manufacturing process now becomes: BCF yarn ⁇ twist ⁇ FC (and optional SB) ⁇ heat set (optionally dry heat set) ⁇ tufting ⁇ carpet.
  • the disclosed process is as effective, or even more effective, than processes of the prior art in terms of fabric soil resistance.
  • the process of the disclosed invention is counter intuitive since treating the carpet yarn prior to heat setting and tufting is known to affect the quality of the finished carpet, particularly during dyeing. Further, the inventive process is also counter intuitive because soil resistant compositions tend to be very difficult to apply uniformly to twisted yarn bundles at the usual line speed without substantial waste. Moreover, the disclosed process is counter intuitive because the prior art yarn twisting apparatuses have not previously accepted topical chemistry applications to twisted yarn prior to winding. However, as shown below, Nylon carpets manufactured with the treated BCF yarn show superior anti-soil properties over the same carpets without such treatment.
  • the anti-soil composition can be comprised of a high specific surface energy chemical or other material, for example a fluorochemical that imparts high specific surface energy properties such as high contact angles for water and oil, or even a non-fluorochemical particulate material having similar properties.
  • the anti-soil composition can further comprise an anti-stain component.
  • an untufted, twisted BCF yarn comprising an anti-soil component
  • said anti-soil component is present on said twisted BCF yarn prior to tufting the BCF yarn.
  • the anti-soil component is present at an on weight of fiber from about 100 ppm to about 1000 ppm.
  • the yarn can comprise polyamide fiber and/or have polymer components selected from polyester and polypropylene.
  • the yarn can be tufted and manufactured into carpet or fabrics.
  • a system for applying an anti-soil composition to twisted BCF fiber comprises: (a) a first yarn take-up device that receives at least two individual yarn members and transmits a single yarn member; (b) an anti-soil composition applicator disposed downstream of said yarn take-up device that applies said anti-soil composition to said single yarn member; and (c) a second yarn take-up device that receives said single yarn member.
  • the anti-soil composition can be comprised of a high specific surface energy chemical or other material, for example a fluorochemical that imparts high specific surface energy properties such as high contact angles for water and oil, or even a non-fluorochemical particulate material having similar properties.
  • the anti-soil composition can further comprise an anti-stain component.
  • FIG. 1 shows the current cable twisting process
  • FIG. 2 shows one aspect of the disclosed process.
  • OWF On weight of fiber: The amount of chemistry that was applied as a % of weight of fiber.
  • WPU Weight pick-up
  • a process for treating twisted BCF yarn comprising contacting the BCF yarn with an anti-soil composition while said yarn is in motion and prior to contacting and winding the yarn onto a take-up reel or winder to create a yarn package or cake.
  • the anti-soil composition comprises an anti-soil component and is adapted to be applied onto twisted BCF yarn at a wet pick-up of between about 5 wt. % and about 50 wt. %., including between about 10 wt. % and about 30 wt %, about 20 wt. % to about 30 wt. %, and about 10 wt. % to about 20 wt. %.
  • the twisted BCF yarn can be optionally heat set after contacting the yarn with the anti-soil composition.
  • Heat setting temperatures can range from about 125° C. to about 200° C., including from about 160° C. to about 195° C.
  • Heat setting dwell times can range from about 0.5 to about 4 minutes, including from about 0.5 to about 3 minute and from about 0.5 to about 1 minute.
  • Anti-soil components for use in the disclosed anti-soil compositions impart high specific surface energy properties such as high contact angles for water and oil (e.g. water and oil “beads up” on surfaces treated by it).
  • the anti-soil component can comprise a fluorochemical dispersion, which dispersion may be predominantly either cationic or anionic, including those selected from the group consisting of fluorochemical allophanates, fluorochemical polyacrylates, fluorochemical urethanes, fluorochemical carbodiimides, fluorochemical quanidines, and fluorochemicals incorporating C-2 to C-8 chemistries.
  • the fluorochemical can have less than or equal to eight fluorinated carbons, including less than or equal to six fluorinated carbons.
  • Example fluorochemical anti-soil components include: DuPont TLF 10816 and 10894; Daikin TG 2511, and DuPont Capstone RCP.
  • Non-fluorinated anti-soil components can include: silicones, silsesquioxanes and fluorosilanated and fluoroalkylated particulates, anionic non-fluorinated surfactants and anionic hydrotrope non-fluorinated surfactants, including sulfonates, sulfates, phosphates and carboxylates. (See U.S. Pat. No. 6,824,854, herein incorporated by reference).
  • the anti-soil compositions can also have an optional stain blocker component comprising an acidic moiety which associates with polymer amine end groups and protects them from staining by acidic dye stains.
  • the general category of chemicals suitable to the process of the instant invention can comprise any chemical that blocks positively charged dye sites.
  • Stain blockers are available in various forms such as syntans, sulfonated novolacs, or sulfonated aromatic aldehyde condensation products (SACs), and/or reaction products of formaldehyde, phenol, polymethacrylic acid, maleic anyhydride, and sulfonic acid.
  • the stain blocker is typically water soluble and generally penetrates the fiber while the anti-soil, usually a fluorochemical, is a non-water soluble dispersion that coats the surface of fiber.
  • stain blockers include, but are not limited to: phenol formaldehyde polymers or copolymers such as CEASESTAIN and STAINAWAY (from American Emulsions Company, Inc., Dalton, Ga.), MESITOL (from Bayer Corporation, Rock Hill, N.C.), ERIONAL (from Ciba Corporation, Greensboro, N.C.), INTRATEX (from Crompton & Knowles Colors, Inc., Charlotte, N.C.), STAINKLEER (from Dyetech, Inc., Dalton, Ga.), LANOSTAIN (from Lenmar Chemical Corporation, Dalton, Ga.), and SR-300, SR-400, and SR-500 (from E. I.
  • polymers of methacrylic acid such as the SCOTCHGARD FX series carpet protectors (from 3M Company, St. Paul Minn.); sulfonated fatty acids from Rockland React-Rite, Inc., Rockmart, Ga.); and stain resist chemistries from ArrowStar LLC, Dalton and Tri-Tex, Canada.
  • the anti-soil composition is adapted to contact the twisted BCF yarn while it is in motion and prior to contacting the take-up reel or winder. Further, the anti-soil composition can be at a neutral pH (e.g. 6 to 8) because the yarn can be optionally heat set after application of the composition. The process foregoes the need for harsh low pH chemicals.
  • any suitable device that applies wet ingredients to a dry substrate can perform the contacting.
  • Such devices include, but are not limited to: applicator pad, ceramic tip, ceramic ring, nip rollers, wet-wick, dip-tank, sprayer, and mister.
  • the contacting can be done by one or more devices, where each device can be the same or different.
  • two, three, or more application devices can be used to apply the anti-soil composition at different points in the process.
  • one or more application devices can apply an anti-soil component and one or more separate devices an anti-stain component. Multiple application devices and locations can provide better application uniformity when using certain BCF yarns.
  • the wet pick-up of anti-soil composition is between about 5 wt. % and about 50 wt. %., including between about 10 wt. % and about 30 wt %, about 20 wt. % to about 30 wt. %, and about 10 wt. % to about 20 wt. %.
  • the resulting twisted BCF yarn if a fluorine based anti-soil component is used, can have an on weight of fiber from about 100 ppm to about 1000 ppm fluorine, including from about 100 to about 500 ppm fluorine, from about 200 to about 400 ppm, and from about 100 ppm to about 300 ppm fluorine.
  • the anti-soil composition further comprises a stain blocker, it is present on weight of fiber from about 500 ppm to about 4%, including from about 1000 ppm to about 3%, from about 0.5% to about 2%, and from about 0.5% to about 1%.
  • Common stain blockers use sulfonated moieties as part of the chemistry, which results in the presence of sulfur on the treated fiber.
  • the sulfur content can range from about 50 ppm with 5% stain blocker to about 1 ppm with 0.1% stain blocker on weight of fiber.
  • the sulfur content on weight of fiber will range from about 0.5 ppm to about 40 ppm, including from about 1 ppm to about 30 ppm, from about 5 ppm to about 20 ppm, and from about 5 ppm to about 10 ppm.
  • Sulfur content can be determined by x-ray diffraction or other methods.
  • the anti-soil composition can further comprise a component selected from the group consisting of: odor control agents, anti-microbial agents, anti-fungal agents, fragrance agents, bleach resist agents, softeners, and UV stabilizers.
  • the twisted BCF yarn can be made from polyamide fibers, such as those made from nylon 6,6, nylon 6, nylon 4,6, nylon 6,10, nylon 10,10, nylon 12, its copolymers, and blends thereof. Further, the twisted BCF yarn can also have additional polymer components, such as polyester and/or polyolefin components.
  • the polyolefin component can be polypropylene.
  • the additional polymer components can be incorporated with the polyamide (by melt-blend or co-polymerization) prior to making a polyamide fiber (e.g. a polyamide/polyester fiber), or can be stand-alone fibers that are twisted with the polyamide fibers to make the twisted BCF yarn.
  • the BCF yarn can be manufactured with olefin, polyamide, and/or polyester polymer components.
  • An unexpected benefit of the disclosed process has been discovered in that, whereas a small amount of anti-soil composition is applied compared to known exhaust processes, a high anti-soil component content, such as fluorine, is achieved on the surface of the yarn.
  • the anti-soil composition applied in the process of the disclosed invention can be either fluorochemical or non-fluorochemical based, or a mixture of fluorochemical or fluoropolymer material with non-fluorinated soil resistant materials.
  • the disclosed process may be applied to yarns that do not require subsequent dyeing, having either a pigment or pigment included in their composition prior to twisting.
  • the pigmented yarns can be made by solution dyed as well as cationic and anionic dyed fibers.
  • Yarns suitable for use in the process may further comprise inherent stain resistance, whether by base composition as in the case of polypropylene or polyester, or by the inclusion of strong acid functionality in the polymer composition of the yarn, as in the case of nylon.
  • Use of dyed or pigmented yarns (i.e. colored yarns) with the disclosed process eliminates the need for subsequent dyeing and enables the creation of colored carpets that are soil resistant, without the need for subsequent dyeing and soil resistant chemical application.
  • the twisted BCF yarn made with the various aspects of the disclosed process, by itself or blended with non-treated fibers and yarns, can be tufted and manufactured into carpets or fabrics.
  • Carpets made with the twisted BCF yarn exhibit an oil repellency rating of 5 or higher and a water repellency rating of 5 or higher.
  • the disclosed process can also be advantageously applied in certain processes where a styling advantage might be derived from differential dyeing and finishing after carpet formation.
  • a soil resistant or stain resistant twisted yarn of the disclosed invention could optionally be tufted into a carpet among untreated yarns prior to dyeing, thus creating an aesthetic alternative.
  • the system includes: (a) a first yarn take-up device that receives at least two individual yarn members and transmits a single yarn member; (b) an anti-soil composition applicator disposed downstream of the first yarn take-up device that applies the anti-soil composition to the single yarn member; and (c) a second yarn take-up device that receives the single yarn member.
  • the first yarn take-up device can be a take-up roll or reel that can twist the at least two individual yarn members into a single yarn member.
  • the individual yarn members can be single filaments or fibers, or yarns made from a plurality of filaments or fibers.
  • the applicator can be any suitable device that applies wet ingredients to a dry substrate, including, but not limited to: applicator pad, nip rollers, wet-wick, dip-tank, sprayer, and mister.
  • the wet pick-up of composition is between about 5 wt. % and about 50 wt. %., including between about 10 wt. % and about 30 wt %, about 20 wt. % to about 30 wt. %, and about 10 wt. % to about 20 wt. %.
  • the resulting twisted BCF yarn if a fluorine based anti-soil component is used, can have an on weight of fiber from about 100 ppm to about 1000 ppm fluorine, including from about 100 to about 500 ppm fluorine, from about 200 to about 400 ppm, and from about 100 ppm to about 300 ppm fluorine. If the anti-soil composition further comprises a stain blocker, it is present on weight of fiber from about 500 ppm to about 4%, including from about 1000 ppm to about 3%, from about 0.5% to about 2%, and from about 0.5% to about 1%.
  • the second yarn take-up device can be a winder.
  • FIG. 1 shows the current cable twisting process.
  • creel yarn 10 and bucket yarn 15 which is fed at a spindle speed of 7000 rpm, pass through an anti-balloon device 20 and onto a take-up roll 25 . From here, the twisted yarn 30 is wound up on a winder 35 .
  • FIG. 2 shows one aspect of the disclosed process.
  • creel yarn 110 and bucket yarn 115 which is fed at a spindle speed of 7000 rpm, pass through anti-balloon device 120 and onto a take-up roll 125 .
  • An anti-soil composition applicator 140 is disposed downstream of take-up roll 125 , which applies an anti-soil component to the twisted yarn 130 . From here, the twisted and treated yarn is wound up on a winder 135 .
  • nylon 6,6 carpets made from two 922 denier beige color solution dyed BCF fibers that have been treated various aspects of the process disclosed above and similar fibers with no treatment. Selection of alternative anti-soil components and stain blocker components, fibers and textiles having different surface chemistries will necessitate minor adjustments to the variables herein described.
  • Acid dye stain resistance is evaluated using a procedure modified from the American Association of Textile Chemists and Colorists (AATCC) Method 175-2003, “Stain Resistance: Pile Floor Coverings.” 9 wt % of aqueous staining solution is prepared, according to the manufacturer's directions, by mixing cherry-flavored KOOL-AID® powder (Kraft/General Foods, White Plains, N.Y., a powdered drink mix containing, inter alia, FD&C Red No. 40). A carpet sample (4 ⁇ 6-inch) is placed on a flat non-absorbent surface. A hollow plastic 2-inch (5.1 cm) diameter cup is placed tightly over the carpet sample.
  • AATCC American Association of Textile Chemists and Colorists
  • KOOL-AID® staining solution Twenty ml of the KOOL-AID® staining solution is poured into the cup and the solution is allowed to absorb completely into the carpet sample. The cup is removed and the stained carpet sample is allowed to sit undisturbed for 24 hours. Following incubation, the stained sample is rinsed thoroughly under cold tap water, excess water is removed by centrifugation, and the sample is dried in air. The carpet sample was visually inspected and rated for staining according to the FD&C Red No. 40 Stain Scale described in AATCC Method 175-2003. Stain resistance is measured using a 1-10 scale. An undetectable test staining is accorded a value of 10.
  • the repellency rating of the sample is the highest rating number liquid used to pass the repellency test. Carpets with a rating of 4 or higher have good anti-soiling properties. Without anti-soil treatment, most nylon carpets have a rating of 1 for both oil and water repellency.
  • Two 922 denier beige color solution dyed Nylon 66 BCF made from cationic dyeable polymer were cable twisted on a Volkman at 7000 rpm to form a 6.0 tpi two ply yarn using the process described in FIG. 1 .
  • the winding speed was about 50 ypm.
  • the cable twisted yarn was subsequently heat-set on a Suessen with 200° C. dry air.
  • the holdup time in the channel was about 60 seconds.
  • the heat treated yarn was converted into a 35 oz per square yard, 1/12 gauge, 3 ⁇ 8′′ pile height cut pile carpet.
  • Two 922 denier beige color solution dyed Nylon 66 BCF made from cationic dyeable polymer were cable twisted on a Volkman at 7000 rpm to form a 6.0 tpi two ply yarn using the process described in FIG. 2 .
  • the winding speed was about 50 ypm.
  • a chemical applicator was inserted between the take up roll and winder as described in FIG. 3 option A.
  • a 1 ⁇ 2 inch wide cotton wick (Wet Wick by Perperell MA) was used to apply 50% A-201 anti-soil chemical onto the cable twisted yarn at a wet-pickup of about 20 wt %.
  • the cable twisted yarn went through the wet wick at about 50 ypm.
  • the cable twisted yarn was subsequently heat-set on a Suessen with 200° C. dry air.
  • the holdup time in the channel was about 60 seconds.
  • the heatset yarn was analyzed to have 925 ppm Fluorine.
  • the heat treated yarn was converted into a 35 oz per square yard, 1/12 gauge, 3 ⁇ 8′′ pile height cut pile carpet.
  • Two 922 denier beige color solution dyed Nylon 66 BCF made from cationic dyeable polymer were cable twisted on a Volkman at 7000 rpm to form a 6.0 tpi two ply yarn using the process described in FIG. 2 .
  • the winding speed was about 50 ypm.
  • a chemical applicator was inserted between the take up roll and winder as described in FIG. 2 .
  • a 1 ⁇ 2 inch wide cotton wick (Wet Wick by Perperell MA) was used to apply 25% A-201 anti-soil chemical onto the cable twisted yarn.
  • the cable twisted yarn went through the wet wick at about 50 ypm.
  • the cable twisted yarn was subsequently heat-set on a Suessen with 200° C. dry air.
  • the holdup time in the channel was about 60 seconds.
  • the heatset yarn was analyzed to have 445 ppm Fluorine.
  • the heat treated yarn was converted into a 35 oz per square yard, 1/12 gauge, 3 ⁇ 8
  • Two 922 denier beige color solution dyed Nylon 66 BCF made from cationic dyeable polymer were cable twisted on a Volkman at 7000 rpm to form a 6.0 tpi two ply yarn using the process described in FIG. 2 .
  • the winding speed was about 50 ypm.
  • a chemical applicator was inserted between the take up roll and winder as described in FIG. 2 .
  • a 1 ⁇ 2 inch wide cotton wick (Wet Wick by Perperell MA) was used to apply 12.5% A-201 anti-soil chemical onto the cable twisted yarn.
  • the cable twisted yarn went through the wet wick at about 50 ypm.
  • the cable twisted yarn was subsequently heat-set on a Suessen with 200° C. dry air.
  • the holdup time in the channel was about 60 seconds.
  • the heatset yarn was analyzed to have 270 ppm Fluorine.
  • the heat treated yarn was converted into a 35 oz per square yard, 1/12 gauge, 3 ⁇
  • Table 1 below reports the repellency and stain tests of the four examples.
  • carpets made from the treated BCF yarn show excellent and good oil and water repellency ratings. This indicates that the disclosed inventive process is an acceptable replacement to existing exhaust type applications for applying anti-soil compositions to carpets and fabrics.
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CA2849458A1 (en) * 2011-09-26 2013-04-04 Invista Technologies S.A R.L. Processes to dye and treat bcf yarn
AU2013318234A1 (en) * 2012-09-19 2015-03-05 Invista Technologies S.A R.L. Processes to dye and treat BCF yarn
WO2014047143A1 (en) * 2012-09-19 2014-03-27 Invista Technologies S. A. R . L. Processes to dye and treat single bcf yarn
US20150233048A1 (en) * 2012-09-19 2015-08-20 Inivesta North America S.A.R.L. Processes to make water and oil repellent bcf yarn
CN106661827A (zh) * 2014-04-10 2017-05-10 英威达技术有限公司 多色地毯和其制造方法
JP7041518B2 (ja) * 2015-06-12 2022-03-24 サイテック インダストリーズ インコーポレイテッド ベンゾオキサジンエポキシブレンドを含有する硬化性組成物およびそれらの使用
CN106702520A (zh) * 2015-08-06 2017-05-24 江苏开利地毯股份有限公司 拒水抗污型丙纶bcf长丝的生产方法
CN106917170A (zh) * 2017-04-20 2017-07-04 湖北名仁纺织科技有限公司 一种抗污霉碳纤维涤纶线及其生产方法
CN110685046B (zh) * 2019-08-19 2022-04-22 浙江海洋大学 一种防污损抗疲劳的多股单丝混捻网线及其制备方法
CN110923883A (zh) * 2019-12-11 2020-03-27 江苏羽鸣科技有限公司 羽毛纱的制作方法

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