US20140061603A1 - Display panel and manufacturing method of the same - Google Patents
Display panel and manufacturing method of the same Download PDFInfo
- Publication number
- US20140061603A1 US20140061603A1 US13/779,319 US201313779319A US2014061603A1 US 20140061603 A1 US20140061603 A1 US 20140061603A1 US 201313779319 A US201313779319 A US 201313779319A US 2014061603 A1 US2014061603 A1 US 2014061603A1
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- United States
- Prior art keywords
- layer
- emission
- display panel
- encapsulation layer
- counter electrode
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- Abandoned
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 238000005538 encapsulation Methods 0.000 claims abstract description 61
- 238000000034 method Methods 0.000 claims description 39
- 239000011521 glass Substances 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 18
- GCFDVEHYSAUQGL-UHFFFAOYSA-J fluoro-dioxido-oxo-$l^{5}-phosphane;tin(4+) Chemical class [Sn+4].[O-]P([O-])(F)=O.[O-]P([O-])(F)=O GCFDVEHYSAUQGL-UHFFFAOYSA-J 0.000 claims description 16
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 claims description 16
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- 230000000903 blocking effect Effects 0.000 claims description 8
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- 238000002844 melting Methods 0.000 claims description 8
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- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
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- 239000011368 organic material Substances 0.000 description 5
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- 239000011651 chromium Substances 0.000 description 3
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- 239000000377 silicon dioxide Substances 0.000 description 3
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- 229910052779 Neodymium Inorganic materials 0.000 description 2
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- 238000001505 atmospheric-pressure chemical vapour deposition Methods 0.000 description 2
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- 229910003437 indium oxide Inorganic materials 0.000 description 2
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
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- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical compound [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
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- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 238000005224 laser annealing Methods 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- IBHBKWKFFTZAHE-UHFFFAOYSA-N n-[4-[4-(n-naphthalen-1-ylanilino)phenyl]phenyl]-n-phenylnaphthalen-1-amine Chemical compound C1=CC=CC=C1N(C=1C2=CC=CC=C2C=CC=1)C1=CC=C(C=2C=CC(=CC=2)N(C=2C=CC=CC=2)C=2C3=CC=CC=C3C=CC=2)C=C1 IBHBKWKFFTZAHE-UHFFFAOYSA-N 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
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- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H01L51/5253—
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/84—Passivation; Containers; Encapsulations
- H10K50/844—Encapsulations
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
- H01L33/52—Encapsulations
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/805—Electrodes
- H10K50/82—Cathodes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/84—Passivation; Containers; Encapsulations
- H10K50/842—Containers
- H10K50/8423—Metallic sealing arrangements
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/84—Passivation; Containers; Encapsulations
- H10K50/842—Containers
- H10K50/8426—Peripheral sealing arrangements, e.g. adhesives, sealants
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/1201—Manufacture or treatment
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/122—Pixel-defining structures or layers, e.g. banks
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/123—Connection of the pixel electrodes to the thin film transistors [TFT]
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/87—Passivation; Containers; Encapsulations
- H10K59/873—Encapsulations
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K2102/00—Constructional details relating to the organic devices covered by this subclass
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K2102/00—Constructional details relating to the organic devices covered by this subclass
- H10K2102/301—Details of OLEDs
- H10K2102/361—Temperature
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/805—Electrodes
- H10K59/8052—Cathodes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/87—Passivation; Containers; Encapsulations
- H10K59/871—Self-supporting sealing arrangements
- H10K59/8721—Metallic sealing arrangements
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/831—Aging
Definitions
- the described technology generally relates to an apparatus and a manufacturing method, and more particularly, to a display panel and a manufacturing method of the same.
- An organic light emitting display apparatus includes a positive electrode, a negative electrode, and an organic emission layer formed between the positive and negative electrodes where electrons and holes are re-combined in the organic emission layer so as to emit light.
- organic light emitting display may include a self-emissive display apparatus including a display panel to emit light as described above.
- a self-emissive display panel may have excellent characteristics as a display device due to a wide viewing angle, a fast response speed, and low power consumption as well as a light weight and a small thickness.
- a display panel for displaying full colors may employ an optical resonance structure for varying an optical length of a wavelength emitted from an organic emission layer of each of different color pixels, for example, red, green, and blue pixels.
- the present embodiments provide a display panel capable of preventing penetration of oxygen and moisture and broadening a life time, and a manufacturing method of the same.
- Some embodiments provide a display panel including a non-emission region layer having a plurality of emission regions and a connection region that is open to connect adjacent emission regions; an organic emission layer formed in each of the plurality of emission regions; a counter electrode formed in the emission regions and the connection region; and an encapsulation layer formed on the counter electrode.
- the counter electrode may include a plurality of first counter electrodes individually formed on the organic emission layers; and a second counter electrode formed in the connection region.
- the encapsulation layer may be formed of a low liquidus temperature material.
- the low liquidus temperature material may include at least one of tin fluorophosphates glass, tungsten-doped tin fluorophosphates glass, chalcogenide glass, tellurite glass, borate glass, and phosphate glass.
- the tin fluorophosphates glass may include 20 to 80 weight % of tin (Sn), 2 to 20 weight % of phosphorus (P), 3 to 20 weight % of oxygen (O), and 10 to 36 weight % of fluorine (F).
- the encapsulation layer may have a melting point equal to or less than 200° C. In some embodiments, the encapsulation layer may have a melting point in the range of from about 150° C. to about 200° C.
- Some embodiments provide a manufacturing method of a display panel, the method including forming a non-emission region layer having a plurality of emission regions and a connection region that is open to connect adjacent emission regions; a second step of forming an encapsulation layer on the non-emission region layer where the plurality of emission regions and the connection region are not formed; a third step of forming an organic emission layer in each of the emission regions; and a fourth step of forming a counter electrode in the emission regions and the connection region, and melting the encapsulation layer to seal the counter electrode.
- the second step may include a step of forming a mask for blocking the emission regions and the connection region; and a step of patterning the encapsulation layer on the non-emission region layer by using the mask.
- the encapsulation layer may be formed on at least a portion of the non-emission region layer.
- the fourth step may include a step of tilting the non-emission region layer, the encapsulation layer, and the organic emission layer by a certain angle with respect to a ground surface.
- the fourth step may include a step of melting the encapsulation layer to a temperature equal to or less than 200° C.
- the counter electrode may include a plurality of first counter electrodes individually formed on the organic emission layers; and a second counter electrode for connecting the plurality of first counter electrodes.
- the encapsulation layer may be formed of a low liquidus temperature material.
- the low liquidus temperature material may include at least one of tin fluorophosphates glass, tungsten-doped tin fluorophosphates glass, chalcogenide glass, tellurite glass, borate glass, and phosphate glass.
- the tin fluorophosphates glass may include 20 to 80 weight % of tin (Sn), 2 to 20 weight % of phosphorus (P), 3 to 20 weight % of oxygen (O), and 10 to 36 weight % of fluorine (F).
- FIG. 1 is a cross-sectional view of a display panel according to an aspect of the present embodiments.
- FIGS. 2 through 18 are diagrams for describing a manufacturing method of the display panel illustrated in FIG. 1 .
- the term “and/or” includes any and all combinations of one or more of the associated listed items. Expressions such as “at least one of,” when preceding a list of elements, modify the entire list of elements and do not modify the individual elements of the list.
- FIG. 1 is a cross-sectional view of a display panel 1000 according to an embodiment.
- the display panel 1000 may include a non-emission region layer 100 in which a plurality of emission regions 100 a are formed.
- the non-emission region layer 100 may include a connection region (not shown) that is open to connect the emission regions 100 a .
- the connection region may be formed as a groove in the non-emission region layer 100 .
- the display panel 1000 may include an organic emission layer 200 formed each of in the emission regions 100 a.
- the display panel 1000 may include a counter electrode 300 formed on the non-emission region layer 100 to connect adjacent emission regions 100 a .
- the counter electrode 300 may include a plurality of first counter electrodes 310 individually formed on the organic emission layers 200 , and a second counter electrode 330 formed in the connection region. The first and second counter electrodes 310 and 330 will be described in detail below.
- the second counter electrode 330 may be formed in the connection region of the non-emission region layer 100 where the emission regions 100 a are not formed. In some embodiments, the second counter electrode 330 may connect the first counter electrodes 310 formed in the emission regions 100 a.
- the display panel 1000 may include an encapsulation layer 400 formed on the counter electrode 300 .
- the encapsulation layer 400 may be patterned and bonded onto only a portion where the counter electrode 300 is not formed and then may be melted by heat so as to cover the counter electrode 300 .
- the encapsulation layer 400 may be formed on the non-emission region layer 100 where the emission regions 100 a and the connection region are not formed.
- the encapsulation layer 400 may be formed of a low liquidus temperature (LLT) material.
- the encapsulation layer 400 may include at least one of tin fluorophosphates glass, tungsten-doped tin fluorophosphates glass, chalcogenide glass, tellurite glass, borate glass, and phosphate glass.
- the tin fluorophosphates glass may include 20 to 80 weight % of tin (Sn), 2 to 20 weight % of phosphorus (P), 3 to 20 weight % of oxygen (O), and 10 to 36 weight % of fluorine (F).
- the encapsulation layer 400 may have a melting point equal to or less than 200° C. Accordingly, if the encapsulation layer 400 is formed and then is melted, damage of components of the display panel 1000 due to heat may be prevented.
- a manufacturing method of the display panel 1000 will now be described in detail.
- FIGS. 2 through 18 are diagrams for describing a manufacturing method of the display panel illustrated in FIG. 1 .
- the non-emission region layer 100 may be formed.
- a buffer layer 110 and a semiconductor layer 120 may be sequentially formed on a substrate 10 .
- the substrate 10 may be formed of a transparent glass material including SiO 2 as a main component.
- the buffer layer 110 including, for example, SiO 2 and/or SiN x may be formed on the substrate 10 to planarize the substrate 10 and to prevent penetration of an impure element.
- the buffer layer 110 and the semiconductor layer 120 may be vapor-deposited by using various vapor deposition methods such as plasma enhanced chemical vapor deposition (PECVD), atmospheric pressure chemical vapor deposition (APCVD), and low pressure chemical vapor deposition (LPCVD).
- PECVD plasma enhanced chemical vapor deposition
- APCVD atmospheric pressure chemical vapor deposition
- LPCVD low pressure chemical vapor deposition
- the semiconductor layer 120 may be vapor-deposited on the buffer layer 110 .
- the semiconductor layer 120 may be formed of amorphous silicon or poly silicon.
- poly silicon may be formed by crystallizing amorphous silicon.
- a method of crystallizing amorphous silicon includes various methods such as rapid thermal annealing (RTA), solid phase crystallization (SPC), excimer laser annealing (ELA), metal induced crystallization (MIC), metal induced lateral crystallization (MILC), and sequential lateral solidification (SLS).
- a first photoresist P 1 is coated on the semiconductor layer 120 , and a first mask process is performed by using a first photomask M 1 including light blocking parts M 11 and light transmitting parts M 12 .
- the first photomask M 1 may be exposed to light by using an exposure device (not shown) and then a series of processes such as developing, etching, and stripping or ashing are performed.
- the semiconductor layer 120 is formed as an active layer 121 of a thin film transistor (TFT).
- the semiconductor layer 120 is patterned into a first electrode 122 of a capacitor which is formed of the same material as and at the same level as the active layer 121 .
- the etching method is not limited to positive lithography to etch portions corresponding to the light transmitting parts M 12 as shown in in FIGS. 3 and 4 , and negative lithography may also be used to etch portions corresponding to the light blocking parts M 11 .
- negative lithography may also be used to etch portions corresponding to the light blocking parts M 11 .
- the above principle is also applied to the following processes.
- a first insulating layer 130 , a first transparent conductive layer 140 , and a first metal layer 150 are sequentially stacked on the structure of FIG. 4 .
- the first insulating layer 130 may include a single or multiple layers of SiO 2 , SiN x , etc. and functions as a gate insulating layer of the TFT and a dielectric layer of the capacitor.
- the first transparent conductive layer 140 may include at least one selected from the group consisting of indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide (ZnO), indium oxide (In 2 O 3 ), indium gallium oxide (IGO), and aluminium zinc oxide (AZO).
- ITO indium tin oxide
- IZO indium zinc oxide
- ZnO zinc oxide
- IGO indium gallium oxide
- AZO aluminium zinc oxide
- the first metal layer 150 may include at least one metal selected from the group consisting of aluminum (Al), platinum (Pt), palladium (Pd), silver (Ag), magnesium (Mg), gold (Au), nickel (Ni), neodymium (Nd), iridium (Ir), chromium (Cr), lithium (Li), calcium (Ca), molybdenum (Mo), titanium (Ti), tungsten (W), and copper (Cu).
- the first metal layer 150 shown in FIG. 5 may include Al.
- the first metal layer 150 may include a plurality of metal layers 150 a , 150 b , and 150 c .
- Al may be used to form the metal layer 150 b in the middle and Mo is used to form the metal layers 150 a and 150 c at the top and the bottom, thereby forming a triple layer structure of Mo/Al/Mo.
- the first metal layer 150 is not limited thereto, and may be formed by using various materials and various layers.
- a second photoresist P 2 may be coated on the first metal layer 150 , and a second mask process is performed by using a second photomask M 2 including light blocking parts M 21 and light transmitting parts M 22 .
- the first transparent conductive layer 140 and the first metal layer 150 are respectively patterned into a base layer 141 and 151 of a pixel electrode, a gate electrode 143 and 153 of the TFT, and a second electrode 145 and 155 of the capacitor.
- the active layer 121 may be doped with an ion impurity by using the gate electrode 143 and 153 formed due to the second mask process, as a self align mask.
- the active layer 121 includes source and drain regions 121 a and 121 b doped with the ion impurity, and a channel region 121 c located therebetween.
- the source and drain regions 121 a and 121 b may be formed without using an additional photomask by using the gate electrode 143 and 153 as a self align mask.
- a second insulating layer 160 and a third photoresist P 3 are coated on the structure formed as a result of the second mask process, and a third mask process is performed by using a third photomask M 3 including light blocking parts M 31 and light transmitting parts M 32 .
- a first opening H 1 for exposing the base layer 141 and 151 of the pixel electrode, contact holes H 3 and H 4 for exposing the source and drain regions 121 a and 121 b of the TFT, and a second opening H 5 for exposing the second electrode 145 and 155 of the capacitor are formed in the second insulating layer 160 as a result of the third mask process.
- a via hole H 2 penetrating through the second insulating layer 160 may also be formed in the third mask process between the first opening H 1 and the contact holes H 3 and H 4 .
- a second metal layer 190 and a fourth photoresist P 4 are formed on the structure of FIG. 10 , and a fourth mask process may be performed by using a fourth photomask M 4 including light blocking parts M 41 and light transmitting parts M 42 .
- the second metal layer 190 may include at least one metal selected from the group consisting of Al, Pt, Pd, Ag, Mg, Au, Ni, Nd, Ir, Cr, Li, Ca, Mo, Ti, W, and Cu.
- the second metal layer 190 shown in FIG. 11 may include Al.
- a portion of the second metal layer 190 and a portion of the first metal layer 151 of the pixel electrode, which may be formed of the same material as the second metal layer 190 , in the first opening H 1 are etched together, the first transparent conductive layer 141 of the pixel electrode may be exposed.
- a portion of the second metal layer 190 and the first metal layer 155 of the capacitor in the second opening H 5 may be etched together.
- portions of the second metal layer 190 formed in the via hole H 2 and the contact holes H 3 and H 4 of the second insulating layer 160 form source and drain electrodes 191 and 193 .
- a source and drain electrodes 191 and 193 are filled in the via hole H 2 and the contact holes H 3 and H 4 .
- the source electrode 191 contacts the source region 121 a and the first metal layer 151 a that remains on the pixel electrode under the second insulating layer 160
- the drain electrode 193 contacts the drain region 121 b.
- a third insulating layer 170 may be formed on the structure of FIG. 12 , and a fifth mask process may be performed by using a fifth photomask M 5 including light blocking parts M 51 and light transmitting parts M 52 .
- the third insulating layer 170 may be formed as an organic insulating layer or an inorganic insulating layer.
- a pixel defining layer may be formed on the source and drain electrodes 191 and 193 and edges of the first transparent conductive layer 141 .
- the pixel defining layer exposes the first transparent conductive layer 141 of the pixel electrode.
- the emission regions 100 a may be formed if the pixel defining layer exposes the first transparent conductive layer 141 of the pixel electrode. In some embodiments, the emission regions 100 a may be formed to be partially open. Here, in addition to the emission regions 100 a , a connection region 100 b may be formed. In some embodiments, the connection region 100 b may be formed similarly to the above-described method of forming the emission regions 100 a.
- the non-emission region layer 100 is not limited to the above-described method and may be formed by using various methods. For example, although the number of masks is limited in the above description, the non-emission region layer 100 may be formed by using a different number and different forms of masks.
- the encapsulation layer 400 may be formed on the non-emission region layer 100 . In some embodiments, the encapsulation layer 400 may be formed on the non-emission region layer 100 where the emission regions 100 a and the connection region 100 b are not formed.
- the encapsulation layer 400 may include a low liquidus temperature material and may be patterned on the non-emission region layer 100 .
- the encapsulation layer 400 may be formed on the non-emission region layer 100 by using a mask.
- the mask may cover a portion where the counter electrode 300 is formed when the encapsulation layer 400 is formed.
- the encapsulation layer 400 may be formed by using a general lithography process when the encapsulation layer 400 is patterned. Accordingly, the encapsulation layer 400 may be patterned on the non-emission region layer 100 where the counter electrode 300 is not formed. In some embodiments, the encapsulation layer 400 may be formed on the non-emission region layer 100 where the emission regions 100 a and the connection region 100 b are not formed.
- the encapsulation layer 400 may be formed on the non-emission region layer 100 in various forms. In some embodiments, the encapsulation layer 400 may be formed on the non-emission region layer 100 in the form of strips. For example, the encapsulation layer 400 may be formed between the emission regions 100 a.
- the encapsulation layer 400 may be formed on the non-emission region layer 100 in the form of Islands.
- the encapsulation layer 400 may be formed on only portions of regions between the emission regions 100 a , and patterns of the encapsulation layer 400 may be spaced apart from each other by a certain distance.
- the organic emission layer 200 and the counter electrode 300 are formed above the pixel electrode.
- the organic emission layer 200 may be formed of a low-molecular or high-molecular organic material.
- the organic emission layer 200 may be included in an intermediate layer (not shown) if the organic emission layer 200 is formed of a low-molecular organic material.
- the intermediate layer may be formed on the pixel electrode and the non-emission region layer 100 .
- a hole transporting layer (HTL), a hole injection layer (HIL), etc. may be stacked in a direction toward the pixel electrode, and an electron transporting layer (ETL), an electron injection layer (EIL), etc. are stacked in a direction toward a second electrode layer.
- HTL hole transporting layer
- HIL hole injection layer
- ETL electron transporting layer
- EIL electron injection layer
- various layers may be stacked according to necessity.
- various organic materials such as copper phthalocyanine (CuPc), N,N′-Di(naphthalene-1-yl)-N,N′-diphenyl-benzidine (NPB), and tris-8-hydroxyquinoline aluminum (Alq3) may be used.
- the organic emission layer 200 is formed of a high-molecular organic material, as the intermediate layer, only an HTL may be in a direction toward the pixel electrode with respect to the organic emission layer 200 .
- the HTL may be formed of poly-(2,4)-ethylene-dihydroxythiophene (PEDOT) or polyaniline (PANI) and may be formed by using an inkjet printing method or a spin coating method.
- PEDOT poly-(2,4)-ethylene-dihydroxythiophene
- PANI polyaniline
- PV poly-phenylenevinylene
- a color pattern may be formed by using a general method such as an inkjet printing method, a spin coating method, or a thermal transfer printing method using a laser.
- the intermediate layer including the organic emission layer 200 may realize an optical resonance structure by varying the thickness of the organic emission layer 200 or the thickness of another organic emission layer (not shown) other than the organic emission layer 200 , according to pixels.
- the counter electrode 300 may be vapor-deposited on the non-emission region layer 100 after the organic emission layer 200 is formed as described above, as a common electrode. In some embodiments, as described above in relation to FIG. 1 , the counter electrode 300 may include the first counter electrodes 310 formed on the organic emission layers 200 , and the second counter electrode 330 formed between patterns of the encapsulation layer 400 .
- the first counter electrodes 310 may be formed on the organic emission layers 200 , and the second counter electrode 330 may connect the first counter electrodes 310 if the counter electrode 300 is formed as described above.
- the first counter electrodes 310 may be formed in the emission regions 100 a
- the second counter electrode 330 may be formed in the connection region 100 b .
- the second counter electrode 330 may be formed on the non-emission region layer 100 where the encapsulation layer 400 is not formed, as well as in the connection region 100 b.
- the emission regions 100 a and the connection region 100 b may be coated with the counter electrode 300 .
- the counter electrode 300 may be coated in the connection region 100 b to connect adjacent emission regions 100 a.
- the encapsulation layer 400 may be formed in the form of strips as described above in relation to FIG. 16A , and then the counter electrode 300 may be formed. In some embodiments, the counter electrode 300 may be coated on the non-emission region layer 100 where the encapsulation layer 400 is not formed.
- the counter electrode 300 may be formed in the emission regions 100 a and the connection region 100 b , and may also be formed near the emission regions 100 a where the encapsulation layer 400 is not formed.
- the counter electrode 300 may connect the first counter electrodes 310 formed in adjacent emission regions 100 a , to the second counter electrode 330 .
- the first counter electrodes 310 formed in the emission regions 100 a may be larger than the emission regions 100 a and thus adjacent first counter electrodes 310 may be connected to each other.
- the counter electrode 300 may also be formed on the non-emission region layer 100 where the encapsulation layer 400 is not formed.
- first counter electrodes 310 are connected to the second counter electrode 330 and the counter electrode 300 is formed, as described above, on the non-emission region layer 100 where the encapsulation layer 400 is not formed, adjacent first counter electrodes 310 may be connected to each other.
- the pixel electrode is used as an anode and the counter electrode 300 is used as a cathode, or vice versa.
- the counter electrode 300 may be formed as a reflective electrode including a reflective material and may function as a reflective mirror for reflecting light emitted from the organic emission layer 200 in order to realize an optical resonance structure.
- the counter electrode 300 may include at least one selected from the group consisting of aluminum (Al), magnesium (Mg), lithium (Li), calcium (Ca), lithium fluoride/calcium (LiF/Ca), and lithium fluoride/aluminum (LiF/Al).
- the display panel 1000 may be exposed to an environment equal to or less than 200° C. In this case, if the display panel 1000 is exposed as described above, the encapsulation layer 400 formed on the counter electrode 300 may be melted.
- the encapsulation layer 400 may flow toward the counter electrode 300 .
- the display panel 1000 may repeatedly rotate horizontally or vertically when the display panel 1000 is tilted by a certain angle as described above.
- the encapsulation layer 400 may cover surfaces of the first counter electrodes 310 and the second counter electrode 330 formed in the emission regions 100 a if the display panel 1000 moves as described above.
- the encapsulation layer 400 is formed as described above, during the encapsulation layer 400 is formed to seal the counter electrode 300 and the organic emission layer 200 , the organic emission layer 200 that is vulnerable to heat may be prevented from being damaged due to heat.
- the counter electrode 300 may be simply and rapidly sealed during the manufacturing method of the display panel 1000 . In some embodiments, a high reliability against an external impact may be ensured and a life time of the display panel 1000 may be increased since a low liquidus temperature material is used in sealing.
- Some embodiments provide a counter electrode that may be simply and rapidly sealed. Also, since a low liquidus temperature material is used in sealing, a high reliability against an external impact may be ensured and a life time of a display panel may be increased.
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Abstract
In one aspect, a display panel and a manufacturing method of the same is provided. The display panel includes a non-emission region layer having a plurality of emission regions and a connection region that is open to connect adjacent emission regions; an organic emission layer formed in each of the plurality of emission regions; a counter electrode formed in the emission regions and the connection region; and an encapsulation layer formed on the counter electrode.
Description
- This application claims priority to and the benefit of Korean Patent Application No. 10-2012-0096787, filed on Aug. 31, 2012 in the Korean Intellectual Property Office, the disclosure of which is incorporated herein by reference in its entirety.
- 1. Field
- The described technology generally relates to an apparatus and a manufacturing method, and more particularly, to a display panel and a manufacturing method of the same.
- 2. Description of the Related Technology
- An organic light emitting display apparatus includes a positive electrode, a negative electrode, and an organic emission layer formed between the positive and negative electrodes where electrons and holes are re-combined in the organic emission layer so as to emit light.
- Also, organic light emitting display may include a self-emissive display apparatus including a display panel to emit light as described above. Such self-emissive display panel may have excellent characteristics as a display device due to a wide viewing angle, a fast response speed, and low power consumption as well as a light weight and a small thickness.
- Additionally, a display panel for displaying full colors may employ an optical resonance structure for varying an optical length of a wavelength emitted from an organic emission layer of each of different color pixels, for example, red, green, and blue pixels.
- The present embodiments provide a display panel capable of preventing penetration of oxygen and moisture and broadening a life time, and a manufacturing method of the same.
- Some embodiments provide a display panel including a non-emission region layer having a plurality of emission regions and a connection region that is open to connect adjacent emission regions; an organic emission layer formed in each of the plurality of emission regions; a counter electrode formed in the emission regions and the connection region; and an encapsulation layer formed on the counter electrode.
- In some embodiments, the counter electrode may include a plurality of first counter electrodes individually formed on the organic emission layers; and a second counter electrode formed in the connection region.
- In some embodiments, the encapsulation layer may be formed of a low liquidus temperature material.
- In some embodiments, the low liquidus temperature material may include at least one of tin fluorophosphates glass, tungsten-doped tin fluorophosphates glass, chalcogenide glass, tellurite glass, borate glass, and phosphate glass.
- In some embodiments, the tin fluorophosphates glass may include 20 to 80 weight % of tin (Sn), 2 to 20 weight % of phosphorus (P), 3 to 20 weight % of oxygen (O), and 10 to 36 weight % of fluorine (F).
- In some embodiments, the encapsulation layer may have a melting point equal to or less than 200° C. In some embodiments, the encapsulation layer may have a melting point in the range of from about 150° C. to about 200° C.
- Some embodiments provide a manufacturing method of a display panel, the method including forming a non-emission region layer having a plurality of emission regions and a connection region that is open to connect adjacent emission regions; a second step of forming an encapsulation layer on the non-emission region layer where the plurality of emission regions and the connection region are not formed; a third step of forming an organic emission layer in each of the emission regions; and a fourth step of forming a counter electrode in the emission regions and the connection region, and melting the encapsulation layer to seal the counter electrode.
- In some embodiments, the second step may include a step of forming a mask for blocking the emission regions and the connection region; and a step of patterning the encapsulation layer on the non-emission region layer by using the mask.
- In some embodiments, the encapsulation layer may be formed on at least a portion of the non-emission region layer.
- In some embodiments, the fourth step may include a step of tilting the non-emission region layer, the encapsulation layer, and the organic emission layer by a certain angle with respect to a ground surface.
- In some embodiments, the fourth step may include a step of melting the encapsulation layer to a temperature equal to or less than 200° C.
- In some embodiments, the counter electrode may include a plurality of first counter electrodes individually formed on the organic emission layers; and a second counter electrode for connecting the plurality of first counter electrodes.
- In some embodiments, the encapsulation layer may be formed of a low liquidus temperature material.
- In some embodiments, the low liquidus temperature material may include at least one of tin fluorophosphates glass, tungsten-doped tin fluorophosphates glass, chalcogenide glass, tellurite glass, borate glass, and phosphate glass.
- In some embodiments, the tin fluorophosphates glass may include 20 to 80 weight % of tin (Sn), 2 to 20 weight % of phosphorus (P), 3 to 20 weight % of oxygen (O), and 10 to 36 weight % of fluorine (F).
- The above and other features and advantages of the present embodiments will become more apparent by describing in detail exemplary embodiments thereof with reference to the attached drawings in which:
-
FIG. 1 is a cross-sectional view of a display panel according to an aspect of the present embodiments; and -
FIGS. 2 through 18 are diagrams for describing a manufacturing method of the display panel illustrated inFIG. 1 . - Hereinafter, the present disclosure will be described in detail by explaining aspects of the embodiments with reference to the attached drawings. The invention may, however, be embodied in many different forms and should not be construed as being limited to the embodiments set forth herein; rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the concept of the invention to one of ordinary skill in the art. The terminology used herein is for the purpose of describing particular embodiments and is not intended to limit the invention. As used herein, the singular forms “a”, “an”, and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof. It will be understood that, although the terms first, second, third, etc., may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections should not be limited by these terms. These terms are only used to distinguish one element, component, region, layer or section from another element, component, region, layer or section.
- As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items. Expressions such as “at least one of,” when preceding a list of elements, modify the entire list of elements and do not modify the individual elements of the list.
-
FIG. 1 is a cross-sectional view of adisplay panel 1000 according to an embodiment. - Referring to
FIG. 1 , thedisplay panel 1000 may include anon-emission region layer 100 in which a plurality ofemission regions 100 a are formed. In some embodiments, thenon-emission region layer 100 may include a connection region (not shown) that is open to connect theemission regions 100 a. Particularly, the connection region may be formed as a groove in thenon-emission region layer 100. - In some embodiments, the
display panel 1000 may include anorganic emission layer 200 formed each of in theemission regions 100 a. - In some embodiments, the
display panel 1000 may include acounter electrode 300 formed on thenon-emission region layer 100 to connectadjacent emission regions 100 a. In some embodiments, thecounter electrode 300 may include a plurality offirst counter electrodes 310 individually formed on theorganic emission layers 200, and asecond counter electrode 330 formed in the connection region. The first andsecond counter electrodes - In some embodiments, the
second counter electrode 330 may be formed in the connection region of thenon-emission region layer 100 where theemission regions 100 a are not formed. In some embodiments, thesecond counter electrode 330 may connect thefirst counter electrodes 310 formed in theemission regions 100 a. - In some embodiments, the
display panel 1000 may include anencapsulation layer 400 formed on thecounter electrode 300. In some embodiments, theencapsulation layer 400 may be patterned and bonded onto only a portion where thecounter electrode 300 is not formed and then may be melted by heat so as to cover thecounter electrode 300. In some embodiments, theencapsulation layer 400 may be formed on thenon-emission region layer 100 where theemission regions 100 a and the connection region are not formed. - In some embodiments, the
encapsulation layer 400 may be formed of a low liquidus temperature (LLT) material. In some embodiments, theencapsulation layer 400 may include at least one of tin fluorophosphates glass, tungsten-doped tin fluorophosphates glass, chalcogenide glass, tellurite glass, borate glass, and phosphate glass. - In some embodiments, the tin fluorophosphates glass may include 20 to 80 weight % of tin (Sn), 2 to 20 weight % of phosphorus (P), 3 to 20 weight % of oxygen (O), and 10 to 36 weight % of fluorine (F).
- In some embodiments, the
encapsulation layer 400 may have a melting point equal to or less than 200° C. Accordingly, if theencapsulation layer 400 is formed and then is melted, damage of components of thedisplay panel 1000 due to heat may be prevented. - A manufacturing method of the
display panel 1000 will now be described in detail. -
FIGS. 2 through 18 are diagrams for describing a manufacturing method of the display panel illustrated inFIG. 1 . - Referring to
FIGS. 2 through 18 , in order to manufacture thedisplay panel 1000, initially, thenon-emission region layer 100 may be formed. In some embodiments, abuffer layer 110 and asemiconductor layer 120 may be sequentially formed on asubstrate 10. - Referring to
FIG. 2 , thesubstrate 10 may be formed of a transparent glass material including SiO2 as a main component. In some embodiments, thebuffer layer 110 including, for example, SiO2 and/or SiNx may be formed on thesubstrate 10 to planarize thesubstrate 10 and to prevent penetration of an impure element. - In some embodiments, the
buffer layer 110 and thesemiconductor layer 120 may be vapor-deposited by using various vapor deposition methods such as plasma enhanced chemical vapor deposition (PECVD), atmospheric pressure chemical vapor deposition (APCVD), and low pressure chemical vapor deposition (LPCVD). - In some embodiments, the
semiconductor layer 120 may be vapor-deposited on thebuffer layer 110. In some embodiments, thesemiconductor layer 120 may be formed of amorphous silicon or poly silicon. In some embodiments, poly silicon may be formed by crystallizing amorphous silicon. A method of crystallizing amorphous silicon includes various methods such as rapid thermal annealing (RTA), solid phase crystallization (SPC), excimer laser annealing (ELA), metal induced crystallization (MIC), metal induced lateral crystallization (MILC), and sequential lateral solidification (SLS). - Referring to
FIG. 3 , a first photoresist P1 is coated on thesemiconductor layer 120, and a first mask process is performed by using a first photomask M1 including light blocking parts M11 and light transmitting parts M12. - Although not shown in
FIG. 3 , in some embodiments of the first mask process, the first photomask M1 may be exposed to light by using an exposure device (not shown) and then a series of processes such as developing, etching, and stripping or ashing are performed. - Referring to
FIG. 4 , as a result of the first mask process, thesemiconductor layer 120 is formed as anactive layer 121 of a thin film transistor (TFT). In some embodiments, thesemiconductor layer 120 is patterned into afirst electrode 122 of a capacitor which is formed of the same material as and at the same level as theactive layer 121. - In some embodiments, the etching method is not limited to positive lithography to etch portions corresponding to the light transmitting parts M12 as shown in in
FIGS. 3 and 4 , and negative lithography may also be used to etch portions corresponding to the light blocking parts M11. The above principle is also applied to the following processes. - In some embodiments, as illustrated in
FIG. 5 , a first insulatinglayer 130, a first transparentconductive layer 140, and afirst metal layer 150 are sequentially stacked on the structure ofFIG. 4 . - In some embodiments, the first insulating
layer 130 may include a single or multiple layers of SiO2, SiNx, etc. and functions as a gate insulating layer of the TFT and a dielectric layer of the capacitor. - In some embodiments, the first transparent
conductive layer 140 may include at least one selected from the group consisting of indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide (ZnO), indium oxide (In2O3), indium gallium oxide (IGO), and aluminium zinc oxide (AZO). - In some embodiments, the
first metal layer 150 may include at least one metal selected from the group consisting of aluminum (Al), platinum (Pt), palladium (Pd), silver (Ag), magnesium (Mg), gold (Au), nickel (Ni), neodymium (Nd), iridium (Ir), chromium (Cr), lithium (Li), calcium (Ca), molybdenum (Mo), titanium (Ti), tungsten (W), and copper (Cu). In some embodiments, thefirst metal layer 150 shown inFIG. 5 may include Al. - In some embodiments, the
first metal layer 150 may include a plurality ofmetal layers first metal layer 150 is not limited thereto, and may be formed by using various materials and various layers. - Referring to
FIG. 6 , a second photoresist P2 may be coated on thefirst metal layer 150, and a second mask process is performed by using a second photomask M2 including light blocking parts M21 and light transmitting parts M22. - As a result of the second mask process, as illustrated in
FIG. 7 , the first transparentconductive layer 140 and thefirst metal layer 150 are respectively patterned into abase layer gate electrode second electrode - In some embodiments, referring to
FIG. 8 , theactive layer 121 may be doped with an ion impurity by using thegate electrode active layer 121 includes source and drainregions channel region 121 c located therebetween. In some embodiments, the source and drainregions gate electrode - In some embodiments, as illustrated in
FIG. 9 , a second insulatinglayer 160 and a third photoresist P3 are coated on the structure formed as a result of the second mask process, and a third mask process is performed by using a third photomask M3 including light blocking parts M31 and light transmitting parts M32. - Referring to
FIG. 10 , in some embodiments, a first opening H1 for exposing thebase layer regions second electrode layer 160 as a result of the third mask process. - In some embodiments, a via hole H2 penetrating through the second insulating
layer 160 may also be formed in the third mask process between the first opening H1 and the contact holes H3 and H4. - In some embodiments, referring to
FIG. 11 , asecond metal layer 190 and a fourth photoresist P4 are formed on the structure ofFIG. 10 , and a fourth mask process may be performed by using a fourth photomask M4 including light blocking parts M41 and light transmitting parts M42. - In some embodiments, the
second metal layer 190 may include at least one metal selected from the group consisting of Al, Pt, Pd, Ag, Mg, Au, Ni, Nd, Ir, Cr, Li, Ca, Mo, Ti, W, and Cu. In some embodiments, thesecond metal layer 190 shown inFIG. 11 may include Al. - In some embodiments, including a fourth mask process, a portion of the
second metal layer 190 and a portion of thefirst metal layer 151 of the pixel electrode, which may be formed of the same material as thesecond metal layer 190, in the first opening H1 are etched together, the first transparentconductive layer 141 of the pixel electrode may be exposed. In some embodiments, a portion of thesecond metal layer 190 and thefirst metal layer 155 of the capacitor in the second opening H5 may be etched together. - In some embodiments, portions of the
second metal layer 190 formed in the via hole H2 and the contact holes H3 and H4 of the second insulatinglayer 160 form source and drainelectrodes - In some embodiments, referring to
FIG. 12 , a source and drainelectrodes source electrode 191 contacts thesource region 121 a and thefirst metal layer 151 a that remains on the pixel electrode under the second insulatinglayer 160, and thedrain electrode 193 contacts thedrain region 121 b. - After that, as illustrated in
FIG. 13 , a thirdinsulating layer 170 may be formed on the structure ofFIG. 12 , and a fifth mask process may be performed by using a fifth photomask M5 including light blocking parts M51 and light transmitting parts M52. In some embodiments, the third insulatinglayer 170 may be formed as an organic insulating layer or an inorganic insulating layer. - Referring to
FIGS. 14A and 14B , as a result of the fifth mask process, a pixel defining layer may be formed on the source and drainelectrodes conductive layer 141. The pixel defining layer exposes the first transparentconductive layer 141 of the pixel electrode. - In some embodiments, the
emission regions 100 a may be formed if the pixel defining layer exposes the first transparentconductive layer 141 of the pixel electrode. In some embodiments, theemission regions 100 a may be formed to be partially open. Here, in addition to theemission regions 100 a, aconnection region 100 b may be formed. In some embodiments, theconnection region 100 b may be formed similarly to the above-described method of forming theemission regions 100 a. - The
non-emission region layer 100 is not limited to the above-described method and may be formed by using various methods. For example, although the number of masks is limited in the above description, thenon-emission region layer 100 may be formed by using a different number and different forms of masks. - In some embodiments, referring to
FIGS. 15 through 17 , if theemission regions 100 a may be formed as described above, theencapsulation layer 400 may be formed on thenon-emission region layer 100. In some embodiments, theencapsulation layer 400 may be formed on thenon-emission region layer 100 where theemission regions 100 a and theconnection region 100 b are not formed. - Referring to
FIGS. 15A through 15C , as described above in relation toFIG. 1 , theencapsulation layer 400 may include a low liquidus temperature material and may be patterned on thenon-emission region layer 100. - In some embodiments, the
encapsulation layer 400 may be formed on thenon-emission region layer 100 by using a mask. In some embodiments, the mask may cover a portion where thecounter electrode 300 is formed when theencapsulation layer 400 is formed. - In some embodiments, the
encapsulation layer 400 may be formed by using a general lithography process when theencapsulation layer 400 is patterned. Accordingly, theencapsulation layer 400 may be patterned on thenon-emission region layer 100 where thecounter electrode 300 is not formed. In some embodiments, theencapsulation layer 400 may be formed on thenon-emission region layer 100 where theemission regions 100 a and theconnection region 100 b are not formed. - In some embodiments, referring to
FIG. 16A , theencapsulation layer 400 may be formed on thenon-emission region layer 100 in various forms. In some embodiments, theencapsulation layer 400 may be formed on thenon-emission region layer 100 in the form of strips. For example, theencapsulation layer 400 may be formed between theemission regions 100 a. - In some embodiments, referring to
FIG. 17A , in addition to the above-described form, theencapsulation layer 400 may be formed on thenon-emission region layer 100 in the form of Islands. For example, theencapsulation layer 400 may be formed on only portions of regions between theemission regions 100 a, and patterns of theencapsulation layer 400 may be spaced apart from each other by a certain distance. - In some embodiments, referring to
FIGS. 15D , 15E, 16B, and 17B, theorganic emission layer 200 and thecounter electrode 300 are formed above the pixel electrode. In this case, theorganic emission layer 200 may be formed of a low-molecular or high-molecular organic material. - In some embodiments, the
organic emission layer 200 may be included in an intermediate layer (not shown) if theorganic emission layer 200 is formed of a low-molecular organic material. In some embodiments, the intermediate layer may be formed on the pixel electrode and thenon-emission region layer 100. - As the intermediate layer, with respect to the
organic emission layer 200, a hole transporting layer (HTL), a hole injection layer (HIL), etc. may be stacked in a direction toward the pixel electrode, and an electron transporting layer (ETL), an electron injection layer (EIL), etc. are stacked in a direction toward a second electrode layer. - In addition to the above-mentioned layers, various layers may be stacked according to necessity. In this case, various organic materials such as copper phthalocyanine (CuPc), N,N′-Di(naphthalene-1-yl)-N,N′-diphenyl-benzidine (NPB), and tris-8-hydroxyquinoline aluminum (Alq3) may be used.
- In some embodiments, if the
organic emission layer 200 is formed of a high-molecular organic material, as the intermediate layer, only an HTL may be in a direction toward the pixel electrode with respect to theorganic emission layer 200. In some embodiments, the HTL may be formed of poly-(2,4)-ethylene-dihydroxythiophene (PEDOT) or polyaniline (PANI) and may be formed by using an inkjet printing method or a spin coating method. In this case, poly-phenylenevinylene (PPV)-based and polyfluorene-based high-molecular organic materials may be used, and a color pattern may be formed by using a general method such as an inkjet printing method, a spin coating method, or a thermal transfer printing method using a laser. - In some embodiments, the intermediate layer including the
organic emission layer 200 may realize an optical resonance structure by varying the thickness of theorganic emission layer 200 or the thickness of another organic emission layer (not shown) other than theorganic emission layer 200, according to pixels. - Hereinafter, for convenience of explanation, a representative embodiment when the intermediate layer is not formed will be representatively described in detail.
- In some embodiments, the
counter electrode 300 may be vapor-deposited on thenon-emission region layer 100 after theorganic emission layer 200 is formed as described above, as a common electrode. In some embodiments, as described above in relation toFIG. 1 , thecounter electrode 300 may include thefirst counter electrodes 310 formed on the organic emission layers 200, and thesecond counter electrode 330 formed between patterns of theencapsulation layer 400. - In some embodiments, the
first counter electrodes 310 may be formed on the organic emission layers 200, and thesecond counter electrode 330 may connect thefirst counter electrodes 310 if thecounter electrode 300 is formed as described above. In some embodiments, thefirst counter electrodes 310 may be formed in theemission regions 100 a, and thesecond counter electrode 330 may be formed in theconnection region 100 b. In some embodiments, thesecond counter electrode 330 may be formed on thenon-emission region layer 100 where theencapsulation layer 400 is not formed, as well as in theconnection region 100 b. - In some embodiments, referring to
FIG. 15D , after theencapsulation layer 400 is formed as described above, theemission regions 100 a and theconnection region 100 b may be coated with thecounter electrode 300. In some embodiments, as described above in relation toFIG. 1 , thecounter electrode 300 may be coated in theconnection region 100 b to connectadjacent emission regions 100 a. - In some embodiments, referring to
FIG. 16B , theencapsulation layer 400 may be formed in the form of strips as described above in relation toFIG. 16A , and then thecounter electrode 300 may be formed. In some embodiments, thecounter electrode 300 may be coated on thenon-emission region layer 100 where theencapsulation layer 400 is not formed. - In some embodiments, the
counter electrode 300 may be formed in theemission regions 100 a and theconnection region 100 b, and may also be formed near theemission regions 100 a where theencapsulation layer 400 is not formed. - In some embodiments, the
counter electrode 300 may connect thefirst counter electrodes 310 formed inadjacent emission regions 100 a, to thesecond counter electrode 330. In some embodiments, thefirst counter electrodes 310 formed in theemission regions 100 a may be larger than theemission regions 100 a and thus adjacentfirst counter electrodes 310 may be connected to each other. - Referring to
FIG. 17B , if theencapsulation layer 400 is formed in the form of islands, thecounter electrode 300 may also be formed on thenon-emission region layer 100 where theencapsulation layer 400 is not formed. - In some embodiments, where the
first counter electrodes 310 are connected to thesecond counter electrode 330 and thecounter electrode 300 is formed, as described above, on thenon-emission region layer 100 where theencapsulation layer 400 is not formed, adjacentfirst counter electrodes 310 may be connected to each other. - In some embodiments, the pixel electrode is used as an anode and the
counter electrode 300 is used as a cathode, or vice versa. - In some embodiments, the
counter electrode 300 may be formed as a reflective electrode including a reflective material and may function as a reflective mirror for reflecting light emitted from theorganic emission layer 200 in order to realize an optical resonance structure. In some embodiments, thecounter electrode 300 may include at least one selected from the group consisting of aluminum (Al), magnesium (Mg), lithium (Li), calcium (Ca), lithium fluoride/calcium (LiF/Ca), and lithium fluoride/aluminum (LiF/Al). - In some embodiments, referring to
FIGS. 15F , 16C, 17C, and 18, if thecounter electrode 300 is completely formed as described above, thedisplay panel 1000 may be exposed to an environment equal to or less than 200° C. In this case, if thedisplay panel 1000 is exposed as described above, theencapsulation layer 400 formed on thecounter electrode 300 may be melted. - In some embodiments, if the
display panel 1000 is tilted by a certain angle with respect to the ground surface, theencapsulation layer 400 may flow toward thecounter electrode 300. In some embodiments, thedisplay panel 1000 may repeatedly rotate horizontally or vertically when thedisplay panel 1000 is tilted by a certain angle as described above. - In some embodiments, the
encapsulation layer 400 may cover surfaces of thefirst counter electrodes 310 and thesecond counter electrode 330 formed in theemission regions 100 a if thedisplay panel 1000 moves as described above. - If the
encapsulation layer 400 is formed as described above, during theencapsulation layer 400 is formed to seal thecounter electrode 300 and theorganic emission layer 200, theorganic emission layer 200 that is vulnerable to heat may be prevented from being damaged due to heat. - In some embodiments, the
counter electrode 300 may be simply and rapidly sealed during the manufacturing method of thedisplay panel 1000. In some embodiments, a high reliability against an external impact may be ensured and a life time of thedisplay panel 1000 may be increased since a low liquidus temperature material is used in sealing. - Some embodiments provide a counter electrode that may be simply and rapidly sealed. Also, since a low liquidus temperature material is used in sealing, a high reliability against an external impact may be ensured and a life time of a display panel may be increased.
- While embodiments have been particularly shown and described with reference to exemplary embodiments thereof, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the present embodiments as defined by the following claims.
Claims (20)
1. A display panel comprising:
a non-emission region layer having a plurality of emission regions and a connection region that is open to connect adjacent emission regions;
an organic emission layer formed in each of the plurality of emission regions;
a counter electrode formed in the emission regions and the connection region; and
an encapsulation layer formed on the counter electrode.
2. The display panel of claim 1 , wherein the counter electrode comprises:
a plurality of first counter electrodes individually formed on the organic emission layers; and
a second counter electrode formed in the connection region.
3. The display panel of claim 1 , wherein the encapsulation layer is formed of a low liquidus temperature material.
4. The display panel of claim 3 , wherein the low liquidus temperature material comprises at least one of tin fluorophosphates glass, tungsten-doped tin fluorophosphates glass, chalcogenide glass, tellurite glass, borate glass, and phosphate glass.
5. The display panel of claim 4 , wherein the low liquidus temperature material comprises tin fluorophosphates glass and the tin fluorophosphates glass comprises 20 to 80 weight % of tin (Sn), 2 to 20 weight % of phosphorus (P), 3 to 20 weight % of oxygen (O), and 10 to 36 weight % of fluorine (F).
6. The display panel of claim 1 , wherein the encapsulation layer has a melting point equal to or less than 200° C.
7. The display panel of claim 1 , wherein the plurality of emission regions are configured to be partially open.
8. The display panel of claim 1 , wherein the encapsulation layer is discontinuous.
9. The display panel of claim 8 , wherein the encapsulation layer is in the form of islands.
10. The display panel of claim 8 , wherein the encapsulation layer is in the form of strips.
11. The display panel of claim 1 , wherein the counter electrode includes at least one selected from the group consisting of aluminum (Al), magnesium (Mg), lithium (Li), calcium (Ca), lithium fluoride/calcium (LiF/Ca), and lithium fluoride/aluminum (LiF/Al).
12. A manufacturing method of a display panel, the method comprising:
a first step of forming a non-emission region layer having a plurality of emission regions and a connection region that is open to connect adjacent emission regions;
a second step of forming an encapsulation layer on the non-emission region layer where the plurality of emission regions and the connection region are not formed;
a third step of forming an organic emission layer in each of the emission regions; and
a fourth step of forming a counter electrode in the emission regions and the connection region, and melting the encapsulation layer to seal the counter electrode.
13. The method of claim 12 , wherein the second step comprises:
a step of forming a mask for blocking the emission regions and the connection region; and
a step of patterning the encapsulation layer on the non-emission region layer by using the mask.
14. The method of claim 12 , wherein the encapsulation layer is formed on at least a portion of the non-emission region layer.
15. The method of claim 12 , wherein the fourth step comprises a step of tilting the non-emission region layer, the encapsulation layer, and the organic emission layer by a certain angle with respect to a ground surface.
16. The method of claim 12 , wherein the fourth step comprises a step of melting the encapsulation layer to a temperature equal to or less than 200° C.
17. The method of claim 12 , wherein the counter electrode comprises:
a plurality of first counter electrodes individually formed on the organic emission layers; and
a second counter electrode for connecting the plurality of first counter electrodes.
18. The method of claim 12 , wherein the encapsulation layer is formed of a low liquidus temperature material.
19. The method of claim 18 , wherein the low liquidus temperature material comprises at least one of tin fluorophosphates glass, tungsten-doped tin fluorophosphates glass, chalcogenide glass, tellurite glass, borate glass, and phosphate glass.
20. The method of claim 19 , wherein the tin fluorophosphates glass comprises 20 to 80 weight % of tin (Sn), 2 to 20 weight % of phosphorus (P), 3 to 20 weight % of oxygen (O), and 10 to 36 weight % of fluorine (F).
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KR1020120096787A KR102000709B1 (en) | 2012-08-31 | 2012-08-31 | Manufacturing method of a display panel |
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CN103681748B (en) | 2018-09-21 |
TWI577007B (en) | 2017-04-01 |
CN103681748A (en) | 2014-03-26 |
US20150333294A1 (en) | 2015-11-19 |
US9634286B2 (en) | 2017-04-25 |
KR102000709B1 (en) | 2019-09-30 |
KR20140029986A (en) | 2014-03-11 |
TW201409680A (en) | 2014-03-01 |
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Owner name: SAMSUNG DISPLAY CO., LTD., KOREA, REPUBLIC OF Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:KIM, MIN-SOO;PARK, JIN-WOO;HYUN, WON-SIK;REEL/FRAME:029891/0986 Effective date: 20130123 |
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