US2013300A - Detergent composition - Google Patents
Detergent composition Download PDFInfo
- Publication number
- US2013300A US2013300A US618937A US61893732A US2013300A US 2013300 A US2013300 A US 2013300A US 618937 A US618937 A US 618937A US 61893732 A US61893732 A US 61893732A US 2013300 A US2013300 A US 2013300A
- Authority
- US
- United States
- Prior art keywords
- cetyl
- sodium salt
- detergent composition
- cleansing
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 13
- 239000003599 detergent Substances 0.000 title description 10
- 159000000000 sodium salts Chemical class 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 8
- 239000003292 glue Substances 0.000 description 7
- 239000004753 textile Substances 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- -1 octadecenyl (oleyl) sulfoacetate Chemical compound 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 3
- XVRAUHBYNXSTLA-UHFFFAOYSA-N hexadecoxy(phenyl)methanesulfonic acid Chemical compound S(=O)(=O)(O)C(C1=CC=CC=C1)OCCCCCCCCCCCCCCCC XVRAUHBYNXSTLA-UHFFFAOYSA-N 0.000 description 3
- 229940049964 oleate Drugs 0.000 description 3
- 238000009991 scouring Methods 0.000 description 3
- YYRBJXOSDFMWTC-UHFFFAOYSA-N 2-hexadecoxy-2-oxoethanesulfonic acid Chemical compound CCCCCCCCCCCCCCCCOC(=O)CS(O)(=O)=O YYRBJXOSDFMWTC-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- XQITUXIEASXIMZ-UHFFFAOYSA-N 2-sulfooctadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(C(O)=O)S(O)(=O)=O XQITUXIEASXIMZ-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000001828 Gelatine Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- XRHLZSKWHCZJFM-UHFFFAOYSA-N hexadecoxymethylbenzene Chemical compound CCCCCCCCCCCCCCCCOCC1=CC=CC=C1 XRHLZSKWHCZJFM-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- AGGIJOLULBJGTQ-UHFFFAOYSA-L sulfonatoacetate Chemical compound [O-]C(=O)CS([O-])(=O)=O AGGIJOLULBJGTQ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
Definitions
- An object of detergent compositions containing compounds of Other objects will appear hereinafter.
- my invention comprises admixing a 20 vide a detergent composition which is adapted to which cleansing bath or solution is particularly adapted for cleansing textile materials and particularly wool and woolen materia
- a 20 vide a detergent composition which is adapted to which cleansing bath or solution is particularly adapted for cleansing textile materials and particularly wool and woolen materia
- My invention is based upon my discovery that,
- the glue and the detergent substance may be added separately or together to the water, without previous admixture, with the production of satisfactory cleansing solutions or baths.
- long chain detergent substances 45 which may be employed in accordance with my invention, I may mention: the sodium salt of cetyl benzyl ether sulfonic acid, the sodium salt of cetyl sulfoacetate, the sodium salt of octadecenyl (oleyl) sulfoacetate, the sodium salt of beta-sulfoethyl oleate.
- Example 1 A dry composition is made by incorporating together, e. g., by milling, 1 part of the sodium salt of cetyl sulfobenzyl ether and 9 parts of glue.
- Example 2 parts of glue are added to a wool scouring bath consisting'oi 2 parts of the sodium salt of cetyl sulfoacetate in 1000 parts of water.
- the scouring bath shows, a surprising increase in securing efliciency. 10
- the compounds referred to may be made from commercially available alcohols, i. e., the respective derivatives may be made irom the commercially available cetyl, oleyl, and the like alcohols, or from alcohols obtainable from sperm oil or by the reduction of fatty acids and acid mixtures obtained from other sources and such compounds may be employed in the crude state as well as m in the purified state.
- compositions or cleaning baths composed of certain specific compounds, in specific propo ons, it will be readily 2s understood by those skilled in the art that the compounds and proportions employed may be widely varied without departing from the spirit of my invention. Accordingly, the scope of my invention is to be limited solely by the appended claims construed as broadly as is permissible-in 39 view of the prior art.
- a detergent composition suitable for addition to cleansing baths for textile fibers comprising substantially the sodium salt of beta-sulfoethyl oleate, and glue.
- a detergent composition suitable for addition to cleansing baths for textile fibers comprising substantially the sodium salt or cetyl sulfo- 40 benzyl ether, and glue.
- a dry composition suitable for addition to cleansing baths for textile fibers comprising substantially about one part of the sodium salt of cetyl sulfobenzyl ether, and about nine parts of 4 glue.
- a detergent composition for textile fibers comprising a compound selected from the group consisting of the alkali-metal salts of cetyl-suitobenzyl ether, cetyl-sulfo-acetate, octadec'enyl- 'sulfoacetate and beta-sulloethyl-oleate, and a protective colloid selected from the group consisting of glue, gelatine' and islnglass.
- a cleansing bathfor textile fiber comprising an aqueous solution of a. composition as defined in claim 4.
Description
- Patented Sept, 3, 195
2,013,300 DETEltGENT CQMPQSI'EION Charles Dunbar, Middleton, England; assignor to Imperial Chemical Industries ted, a corporation oi Great Britain No Drag. Application June 23, 1932, Se
No. 618,937.. In Great Britain Jilly 9, 1931 5 Claims.
' This invention relates 'to detergent composi= tions and particularly to compositions containing a compound which comprises a long 'alkyl chain and one or more sulfonic groups and a d substance adapted to increase the detergent properties of such compound. An object of detergent compositions containing compounds of Other objects will appear hereinafter.
These objects may be accomplished according 15 to my invention which comprises admixing a 20 vide a detergent composition which is adapted to which cleansing bath or solution is particularly adapted for cleansing textile materials and particularly wool and woolen materia My invention is based upon my discovery that,
method of manufacturing the cleansing solution,
4 as the glue and the detergent substance may be added separately or together to the water, without previous admixture, with the production of satisfactory cleansing solutions or baths.
As suitable long chain detergent substances 45 which may be employed in accordance with my invention, I may mention: the sodium salt of cetyl benzyl ether sulfonic acid, the sodium salt of cetyl sulfoacetate, the sodium salt of octadecenyl (oleyl) sulfoacetate, the sodium salt of beta-sulfoethyl oleate.
In order to more clearly illustrate my invention and the preferred mode in which I contemplate carrying the same into effect, the following examples are given:
Example 1.--A dry composition is made by incorporating together, e. g., by milling, 1 part of the sodium salt of cetyl sulfobenzyl ether and 9 parts of glue.
10 parts of this mixture are dissolved in 1000 parts of water to give a solution possessing a much more potent scouring action than is shown by the solution of 1 part of the sodium salt of cetyl sulfobenzyl ether in 1000 parts of water.
Example 2.- parts of glue are added to a wool scouring bath consisting'oi 2 parts of the sodium salt of cetyl sulfoacetate in 1000 parts of water. The scouring bath shows, a surprising increase in securing efliciency. 10
While the strict chemical nomenclature'has been employed, it will be understood that the compounds referred to may be made from commercially available alcohols, i. e., the respective derivatives may be made irom the commercially available cetyl, oleyl, and the like alcohols, or from alcohols obtainable from sperm oil or by the reduction of fatty acids and acid mixtures obtained from other sources and such compounds may be employed in the crude state as well as m in the purified state.
While I have disclosed compositions or cleaning baths composed of certain specific compounds, in specific propo ons, it will be readily 2s understood by those skilled in the art that the compounds and proportions employed may be widely varied without departing from the spirit of my invention. Accordingly, the scope of my invention is to be limited solely by the appended claims construed as broadly as is permissible-in 39 view of the prior art.
I claim:
1. A detergent composition suitable for addition to cleansing baths for textile fibers comprising substantially the sodium salt of beta-sulfoethyl oleate, and glue.
2. A detergent composition suitable for addition to cleansing baths for textile fibers comprising substantially the sodium salt or cetyl sulfo- 40 benzyl ether, and glue.
3. A dry composition suitable for addition to cleansing baths for textile fibers comprising substantially about one part of the sodium salt of cetyl sulfobenzyl ether, and about nine parts of 4 glue.
4. A detergent composition for textile fibers comprising a compound selected from the group consisting of the alkali-metal salts of cetyl-suitobenzyl ether, cetyl-sulfo-acetate, octadec'enyl- 'sulfoacetate and beta-sulloethyl-oleate, and a protective colloid selected from the group consisting of glue, gelatine' and islnglass.
5. A cleansing bathfor textile fiber comprising an aqueous solution of a. composition as defined in claim 4.
. CHARLES DUNBAR.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2013300X | 1931-07-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2013300A true US2013300A (en) | 1935-09-03 |
Family
ID=10896055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US618937A Expired - Lifetime US2013300A (en) | 1931-07-09 | 1932-06-23 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2013300A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018153772A1 (en) | 2017-02-27 | 2018-08-30 | Ge Healthcare Bioprocess R&D Ab | A separation matrix and a method of separating antibodies |
-
1932
- 1932-06-23 US US618937A patent/US2013300A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018153772A1 (en) | 2017-02-27 | 2018-08-30 | Ge Healthcare Bioprocess R&D Ab | A separation matrix and a method of separating antibodies |
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