US20130081254A1 - Boronized laying pipe - Google Patents

Boronized laying pipe Download PDF

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Publication number
US20130081254A1
US20130081254A1 US13/685,952 US201213685952A US2013081254A1 US 20130081254 A1 US20130081254 A1 US 20130081254A1 US 201213685952 A US201213685952 A US 201213685952A US 2013081254 A1 US2013081254 A1 US 2013081254A1
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Prior art keywords
pipe
laying
interior
boronized layer
boronized
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Abandoned
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US13/685,952
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Keith Fiorucci
Chris Lashua
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Siemens Industry Inc
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Siemens Industry Inc
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Priority to US13/685,952 priority Critical patent/US20130081254A1/en
Publication of US20130081254A1 publication Critical patent/US20130081254A1/en
Assigned to SIEMENS INDUSTRY, INC. reassignment SIEMENS INDUSTRY, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: FIORUCCI, KEITH, LASHUA, CHRISTOPHER
Abandoned legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/22Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to internal surfaces, e.g. of tubes
    • B05D7/222Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to internal surfaces, e.g. of tubes of pipes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21CMANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
    • B21C47/00Winding-up, coiling or winding-off metal wire, metal band or other flexible metal material characterised by features relevant to metal processing only
    • B21C47/02Winding-up or coiling
    • B21C47/10Winding-up or coiling by means of a moving guide
    • B21C47/14Winding-up or coiling by means of a moving guide by means of a rotating guide, e.g. laying the material around a stationary reel or drum
    • B21C47/143Winding-up or coiling by means of a moving guide by means of a rotating guide, e.g. laying the material around a stationary reel or drum the guide being a tube
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D7/00Bending rods, profiles, or tubes
    • B21D7/16Auxiliary equipment, e.g. for heating or cooling of bends
    • B21D7/162Heating equipment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23PMETAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P11/00Connecting or disconnecting metal parts or objects by metal-working techniques not otherwise provided for 
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/36Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases using ionised gases, e.g. ionitriding
    • C23C8/38Treatment of ferrous surfaces
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/60Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes
    • C23C8/62Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes only one element being applied
    • C23C8/68Boronising
    • C23C8/70Boronising of ferrous surfaces
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49826Assembling or joining
    • Y10T29/49888Subsequently coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4998Combined manufacture including applying or shaping of fluent material
    • Y10T29/49982Coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4998Combined manufacture including applying or shaping of fluent material
    • Y10T29/49982Coating
    • Y10T29/49986Subsequent to metal working

Definitions

  • aspects of the present invention relate generally to the laying pipes employed in rolling mill laying heads to form hot rolled products into helical ring formations, and, more particularly, with improving the resistance of such pipes to frictional wear caused by contact with the hot rolled products.
  • billets are reheated in a furnace 10 .
  • the heated billets are extracted from the furnace and rolled through a roughing mill 12 , an intermediate mill 14 , and a finishing mill 16 followed in some cases by a reducing/sizing mill (not shown).
  • the finished products are then directed to a laying head 18 where they are formed into rings 20 .
  • the rings are deposited on a conveyor 22 for transport to a reforming station 24 where they are gathered into coils. While in transit on the conveyor, the rings are subjected to controlled cooling designed to achieve selected metallurgical properties.
  • the laying head 18 includes a hollow quill 26 containing a curved laying pipe 28 .
  • a bevel gear set 30 powered by a motor 32 serves to rotatably drive the quill and laying pipe about an axis “A”.
  • a primary objective of the present invention is to increase the resistance of laying pipes to frictional wear occasioned by contact with hot rolled products, and thereby increase the useful life of such pipes.
  • a companion objective of the present invention is to make it possible to reduce the bore size of the laying pipes and thereby improve product guidance and the consistency of ring formation resulting from such bore size reductions.
  • the aforesaid objectives are achieved by subjecting the laying pipe to a boronizing process in which boron atoms are diffused into the interior pipe surface to provide a wear resistant boronized layer.
  • FIG. 1 is a diagrammatic illustration of a typical rolling mill layout
  • FIG. 2 diagrammatically illustrates the mill laying head and associated mill components
  • FIG. 3 is a side elevated view of a laying pipe in accordance with the present invention.
  • FIG. 4 is a cross sectional view on an enlarged scale taken along line 4 - 4 of FIG. 3 , showing a product being guided by the laying pipe, and with dimensions exaggerated for purposes of illustration.
  • a laying pipe 28 in accordance with the present invention is configured for rotation about axis A.
  • the pipe has an entry and 28 a aligned on axis A to receive a hot rolled product, with a curved section 28 b leading to a delivery end 28 c spaced radially from axis A.
  • the curved section defines a guide path configured to form the product into a helical formation of rings (as shown at 20 in FIGS. 1 and 2 ).
  • the laying pipe comprises a ferrous wall 34 , with an interior surface layer 36 against which a hot rolled product P is confined for movement along the guide path defined by the pipe.
  • the ferrous wall 34 has a hardness of between about 330-430 knoop (HK 100 ).
  • the interior surface layer 36 comprises a wear resistant boronized layer with an elevated hardness of between about 1600-2300 knoop (HK 100 ).
  • the boronized layer 36 results from subjecting the interior pipe surface to a thermochemical treatment in which boron atoms are diffused into the interior surface of the ferrous wall 34 .
  • the laying pipe 28 is formed by heating a straight ferrous tube to an elevated temperature of between about 840-1050° C., then bending the tube into the desired shape of a laying pipe, and then cooling the thus bent tube back to ambient temperature.
  • the boronized layer 36 may be formed on the interior tube surface either before or subsequent to the bending process.
  • the increase hardness of the boronized layer 36 dramatically increases resistance to frictional wear occasioned by contact with hot roll products passing through the laying pipe.
  • the increased hardness of the boronized layer 36 allows those skilled in the art to dramatically decrease the bore size of the laying pipe, with attendant improved guidance and ring formation at beneficially increased speeds.
  • laying pipes with inside diameters D i of about 20 mm. can be used to coil products having diameters D p ranging from 4-12 mm. This is to be contrasted with what has heretofore been conventional practice, where laying pipes with inside diameters of about 34 mm. have been employed to coil the same range of product sizes.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Winding, Rewinding, Material Storage Devices (AREA)
  • Heat Treatment Of Steel (AREA)
  • Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)

Abstract

A laying pipe for use in the laying head of a rolling mill is configured for rotation about an axis, with an entry end aligned on that axis to receive a hot rolled product, and with a curved section leading to a delivery end spaced radially from that axis. The curved section defines a guide path configured to form the hot rolled product into a helical formation of rings. The laying pipe comprises a tubular ferrous wall having an interior surface comprising a wear resistant boronized layer against which the hot rolled product is confined for movement along the guide path. A method of enhancing the wear resistance of the laying pipe comprises forming a wear resistant boronized layer on at least one of the interior and exterior surfaces of said pipe.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • This application is a divisional of U.S. patent application Ser. No. 12/897,083, filed 4 Oct. 2010, now U.S. Pat. No. 8,316,679, issued 27 Nov. 2012, the entire contents and substance of which are hereby incorporated by reference.
  • BACKGROUND
  • 1. Field
  • Aspects of the present invention relate generally to the laying pipes employed in rolling mill laying heads to form hot rolled products into helical ring formations, and, more particularly, with improving the resistance of such pipes to frictional wear caused by contact with the hot rolled products.
  • 2. Description of Related Art
  • In a typical rod rolling mill, as depicted diagrammatically in FIG. 1, billets are reheated in a furnace 10. The heated billets are extracted from the furnace and rolled through a roughing mill 12, an intermediate mill 14, and a finishing mill 16 followed in some cases by a reducing/sizing mill (not shown). The finished products are then directed to a laying head 18 where they are formed into rings 20. The rings are deposited on a conveyor 22 for transport to a reforming station 24 where they are gathered into coils. While in transit on the conveyor, the rings are subjected to controlled cooling designed to achieve selected metallurgical properties.
  • As depicted diagrammatically in FIG. 2, the laying head 18 includes a hollow quill 26 containing a curved laying pipe 28. A bevel gear set 30 powered by a motor 32 serves to rotatably drive the quill and laying pipe about an axis “A”.
  • Over the last several decades, the delivery speeds of rod rolling mills have increased dramatically. For example, mills now have the capability of rolling 5.5 mm rod at speeds of 110 m/sec. and higher. At such speeds, the hot rolled products exert a punishing effect on the laying pipes, causing internal pipe surfaces to undergo rapid localized wear and premature failure. Also, as the laying pipes wear, their ability to deliver a stable ring pattern to the conveyor 22 deteriorates. Unstable ring patterns disturb cooling uniformity and also contribute to coiling mishaps, commonly referred to as “cobbling”, at the reforming station. Frequent and costly mill shutdowns are required to replace prematurely worn laying pipes and to address problems associated with cobbling at the reforming station.
  • Those skilled in the art have made repeated attempts at increasing the useful life of laying pipes. For example, as disclosed in U.S. Pat. Nos. 4,074,553 and 5,839,684, it has been proposed to line the laying pipes with wear resistant inserts. U.S. Pat. No. 6,098,909 discloses a different approach where the laying pipe is eliminated in favor of a guide path defined by a spiral groove in the outer surface of a conical insert enclosed by a conical outer casing, with the insert being rotatable within the outer casing to gradually shift the wear pattern on the inner surface of the outer casing.
  • For various reasons, none of these approaches has proven to be a practical solution to the problem of premature pipe wear.
  • Attempts have also been made at carburizing the interior pipe surfaces in order to increase hardness and resistance to wear. However, the carburizing process requires a drastic quenching from elevated processing temperatures, which can distort the pipe curvature. Carburized layers have also been found to be relatively brittle and to temper down at elevated temperatures resulting from exposure to the hot rolled products.
  • For a number of years, it has been well accepted that laying pipes with reduced bore sizes provide a number of significant advantages. By radially constricting the hot rolled products within a smaller space, guidance is improved and the ring pattern delivered to the cooling conveyor is more consistent, making it possible to roll at higher speeds. Unfortunately, however, these advantages have been offset to a large extent by significantly accelerated pipe wear. Thus, in the past, those skilled in the art have deemed it necessary to compromise by employing larger bore laying pipes and rolling at reduced speeds below the rated design speeds of the mills.
  • SUMMARY
  • A primary objective of the present invention is to increase the resistance of laying pipes to frictional wear occasioned by contact with hot rolled products, and thereby increase the useful life of such pipes.
  • A companion objective of the present invention is to make it possible to reduce the bore size of the laying pipes and thereby improve product guidance and the consistency of ring formation resulting from such bore size reductions.
  • The aforesaid objectives are achieved by subjecting the laying pipe to a boronizing process in which boron atoms are diffused into the interior pipe surface to provide a wear resistant boronized layer.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a diagrammatic illustration of a typical rolling mill layout;
  • FIG. 2 diagrammatically illustrates the mill laying head and associated mill components;
  • FIG. 3 is a side elevated view of a laying pipe in accordance with the present invention; and
  • FIG. 4 is a cross sectional view on an enlarged scale taken along line 4-4 of FIG. 3, showing a product being guided by the laying pipe, and with dimensions exaggerated for purposes of illustration.
  • DETAILED DESCRIPTION
  • With reference to FIGS. 3 and 4, a laying pipe 28 in accordance with the present invention is configured for rotation about axis A. The pipe has an entry and 28 a aligned on axis A to receive a hot rolled product, with a curved section 28 b leading to a delivery end 28 c spaced radially from axis A. The curved section defines a guide path configured to form the product into a helical formation of rings (as shown at 20 in FIGS. 1 and 2). As shown in FIG. 4, the laying pipe comprises a ferrous wall 34, with an interior surface layer 36 against which a hot rolled product P is confined for movement along the guide path defined by the pipe. The ferrous wall 34 has a hardness of between about 330-430 knoop (HK100). The interior surface layer 36 comprises a wear resistant boronized layer with an elevated hardness of between about 1600-2300 knoop (HK100).
  • The boronized layer 36 results from subjecting the interior pipe surface to a thermochemical treatment in which boron atoms are diffused into the interior surface of the ferrous wall 34.
  • The laying pipe 28 is formed by heating a straight ferrous tube to an elevated temperature of between about 840-1050° C., then bending the tube into the desired shape of a laying pipe, and then cooling the thus bent tube back to ambient temperature. The boronized layer 36 may be formed on the interior tube surface either before or subsequent to the bending process.
  • The increase hardness of the boronized layer 36 dramatically increases resistance to frictional wear occasioned by contact with hot roll products passing through the laying pipe.
  • Admittedly, and as disclosed for example in U.S. Pat. Nos. 3,673,005 (Kunst); 4,389,439 (Clark et al); and 5,455,068 (Ayes et al), boronizing has been known since at least the early 1970s. Yet, prior to the present invention, no one thought to employ this process to improve the wear resistance of rolling mill laying pipes. This, despite all of the wear related problems that have plagued the rolling mill industry over the last several decades.
  • The increased hardness of the boronized layer 36, and its increased resistance to frictional wear, allows those skilled in the art to dramatically decrease the bore size of the laying pipe, with attendant improved guidance and ring formation at beneficially increased speeds. Thus, as depicted in FIG. 4, by boronizing the interior pipe surface, laying pipes with inside diameters Di of about 20 mm. can be used to coil products having diameters Dp ranging from 4-12 mm. This is to be contrasted with what has heretofore been conventional practice, where laying pipes with inside diameters of about 34 mm. have been employed to coil the same range of product sizes.

Claims (9)

We claim:
1. A method of enhancing the wear resistance of a tubular metal laying pipe to a hot rolled product passing therethrough, comprising forming a wear resistant boronized layer on at least one of the interior and exterior surfaces of said pipe.
2. The method of claim 1, wherein a wear resistant boronized layer is formed on both the interior and exterior surfaces of said pipe.
3. The method of claim 1, wherein the metal of said pipe is selected from the group consisting of ferrous metals, nickel based alloys, titanium based alloys and cobalt based alloys.
4. The method of claim 1, wherein said said boronized layer is the result of a thermochemical treatment in which boron atoms are diffused into the at least one of said surfaces.
5. The method of claim 4, wherein the hardness of said pipe is between about 330 to 430 knoop (HK100), and wherein said boronized layer has an increased hardness of between about 1600 to 2300 knoop (HK100).
6. The method of claim 1, wherein said laying pipe is shaped by a bending process comprising heating a straight tube to an elevated temperature of about 840° C. to 1050° C., bending the thus heated tube into a configuration having an entry end lying on an axis, with a curved section leading from said entry end to a delivery end spaced from said axis, and cooling the thus heated and bent tube to an ambient temperature, at least one of the surfaces of said laying pipe being defined by a boronized layer.
7. The method of claim 6, wherein said boronized layer is formed on at least one of said surfaces of said pipe prior to said bending process.
8. The method of claim 6, wherein said boronized layer is formed on at least one of said surfaces of said pipe following said bending process.
9. The method of claim 1, wherein said laying pipe is fabricated as an assembly of an interior tubular metal wall enclosed within an exterior tubular metal wall, and wherein at least one of the interior and exterior surfaces of said interior and exterior tubular metal walls comprise wear resistant boronized layers.
US13/685,952 2010-10-04 2012-11-27 Boronized laying pipe Abandoned US20130081254A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US13/685,952 US20130081254A1 (en) 2010-10-04 2012-11-27 Boronized laying pipe

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US12/897,083 US8316679B2 (en) 2010-10-04 2010-10-04 Boronized laying pipe
US13/685,952 US20130081254A1 (en) 2010-10-04 2012-11-27 Boronized laying pipe

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EP (1) EP2624975A1 (en)
CN (1) CN103153496B (en)
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RU (1) RU2588940C2 (en)
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US9981297B2 (en) 2015-01-19 2018-05-29 Russula Corporation Coil forming laying head system and method of using
CN110743943A (en) * 2019-10-23 2020-02-04 河北秦合重科金属科技有限公司 Simple laying pipe bender and production process

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US10870912B2 (en) 2017-03-14 2020-12-22 Bwt Llc Method for using boronizing reaction gases as a protective atmosphere during boronizing, and reaction gas neutralizing treatment
WO2018169827A1 (en) 2017-03-14 2018-09-20 Bwt Llc Boronizing powder compositions for improved boride layer quality in oil country tubular goods and other metal articles
WO2020260299A1 (en) * 2019-06-24 2020-12-30 Ab Sandvik Materials Technology A laying head pipe
CN110238205A (en) * 2019-07-06 2019-09-17 北京杜根鸿运科技发展有限公司 A kind of spinneret of self-healing

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US8316679B2 (en) 2012-11-27

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