US20130026194A1 - Gas generation dispenser apparatus for on-demand fluid delivery - Google Patents
Gas generation dispenser apparatus for on-demand fluid delivery Download PDFInfo
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- US20130026194A1 US20130026194A1 US13/323,341 US201113323341A US2013026194A1 US 20130026194 A1 US20130026194 A1 US 20130026194A1 US 201113323341 A US201113323341 A US 201113323341A US 2013026194 A1 US2013026194 A1 US 2013026194A1
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- gas
- fluid
- chamber
- demand
- expandable
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M5/00—Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
- A61M5/14—Infusion devices, e.g. infusing by gravity; Blood infusion; Accessories therefor
- A61M5/142—Pressure infusion, e.g. using pumps
- A61M5/145—Pressure infusion, e.g. using pumps using pressurised reservoirs, e.g. pressurised by means of pistons
- A61M5/1452—Pressure infusion, e.g. using pumps using pressurised reservoirs, e.g. pressurised by means of pistons pressurised by means of pistons
- A61M5/14526—Pressure infusion, e.g. using pumps using pressurised reservoirs, e.g. pressurised by means of pistons pressurised by means of pistons the piston being actuated by fluid pressure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M11/00—Sprayers or atomisers specially adapted for therapeutic purposes
- A61M11/006—Sprayers or atomisers specially adapted for therapeutic purposes operated by applying mechanical pressure to the liquid to be sprayed or atomised
- A61M11/007—Syringe-type or piston-type sprayers or atomisers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/02—Membranes or pistons acting on the contents inside the container, e.g. follower pistons
- B05B11/025—Membranes or pistons acting on the contents inside the container, e.g. follower pistons with stepwise advancement of the piston, e.g. for spraying a predetermined quantity of content
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/04—Deformable containers producing the flow, e.g. squeeze bottles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/06—Gas or vapour producing the flow, e.g. from a compressible bulb or air pump
- B05B11/061—Gas or vapour producing the flow, e.g. from a compressible bulb or air pump characterised by the means producing the gas or vapour pressure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/10—Apparatus features
- A61L2209/13—Dispensing or storing means for active compounds
- A61L2209/132—Piezo or ultrasonic elements for dispensing
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
- A61L9/12—Apparatus, e.g. holders, therefor
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M5/00—Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
- A61M5/14—Infusion devices, e.g. infusing by gravity; Blood infusion; Accessories therefor
- A61M5/142—Pressure infusion, e.g. using pumps
- A61M2005/14204—Pressure infusion, e.g. using pumps with gas-producing electrochemical cell
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M5/00—Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
- A61M5/14—Infusion devices, e.g. infusing by gravity; Blood infusion; Accessories therefor
- A61M5/142—Pressure infusion, e.g. using pumps
- A61M5/145—Pressure infusion, e.g. using pumps using pressurised reservoirs, e.g. pressurised by means of pistons
- A61M2005/14513—Pressure infusion, e.g. using pumps using pressurised reservoirs, e.g. pressurised by means of pistons with secondary fluid driving or regulating the infusion
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M2205/00—General characteristics of the apparatus
- A61M2205/33—Controlling, regulating or measuring
- A61M2205/3368—Temperature
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M2205/00—General characteristics of the apparatus
- A61M2205/82—Internal energy supply devices
- A61M2205/8206—Internal energy supply devices battery-operated
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M2205/00—General characteristics of the apparatus
- A61M2205/82—Internal energy supply devices
- A61M2205/8218—Gas operated
- A61M2205/8231—Gas operated using electrochemical gas generating device for the driving gas
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M5/00—Devices for bringing media into the body in a subcutaneous, intra-vascular or intramuscular way; Accessories therefor, e.g. filling or cleaning devices, arm-rests
- A61M5/14—Infusion devices, e.g. infusing by gravity; Blood infusion; Accessories therefor
- A61M5/142—Pressure infusion, e.g. using pumps
- A61M5/14244—Pressure infusion, e.g. using pumps adapted to be carried by the patient, e.g. portable on the body
Definitions
- Dispensing devices such as those that periodically deliver a shot of fragrance into the air are well known. These devices have various control and activation systems including batteries and timers.
- the mechanisms for delivering the shot may include aerosol type devices that operate over a large range of pressures and piezo pumps.
- Conventional gas cells are used for generating gases such as hydrogen from liquids such as water at relatively slow rates in which a volume of gas is generated slowly for periodic use of the gas for motive or other purposes. These gas cells are used in fluid delivery systems that operate automatically. For example, some conventional gas cells in fluid delivery systems continuously generate gas at a slow rate over a long period of time. A build-up in pressure provides a motive force for causing the fluid to exit from a storage chamber. The force is typically automatically applied at predetermined time intervals under the control of a timer and other controls for automatic, periodic delivery of the fluid.
- Conventional fluid delivery systems that utilize gas cells are deficient in accounting for changes in environmental or system conditions. For example, as a volume of a gas chamber in a conventional fluid delivery system increases over time, the generation of the gas at a constant rate has a changing effect on the fluid delivery over time due to changes in atmospheric pressure, temperature, or other environmental conditions. Changes in pressure of contained gas due to changes in temperature or elevation typically impact the amount of fluid delivered by conventional gas generation fluid delivery systems such that these systems lack consistency under changing operating conditions.
- a method of dispensing a fluid includes generating a gas from a liquid. The method also includes directing the gas to an expandable gas chamber to expand a volume of the expandable gas chamber. The method includes reducing a volume of a fluid chamber in response to expansion of the expandable gas chamber to dispense an amount of the fluid from the fluid chamber. The method also includes removing the gas from the expandable gas chamber to collapse the expandable gas chamber. Other embodiments of the method are also described.
- an on-demand fluid dispenser includes an expandable gas chamber.
- the expandable gas chamber includes a moveable plunger forming a wall of the expandable gas chamber.
- the moveable plunger also forms a wall of the fluid chamber.
- An on-demand gas cell is configured to generate the gas on demand and to direct the gas to the expandable gas chamber to expand the expandable gas chamber. In this case, expansion of the expandable gas chamber moves the moveable plunger to reduce a volume of the fluid chamber and to dispense an amount of fluid from the fluid chamber.
- a power source may be connected to the gas cell, and a switch may be coupled to the power source to activate the gas cell.
- Other embodiments of the on-demand fluid dispenser are also described.
- FIG. 1 is an exemplary perspective view of one embodiment of an on-demand fluid dispenser.
- FIG. 2 is a diagrammatic sectional view of another embodiment of an on-demand fluid dispenser.
- FIG. 3 is a schematic diagram of one embodiment of an electrical circuit that may be incorporated in an embodiment of the on-demand fluid dispenser.
- FIGS. 4A-4C are diagrammatic partial sectional views illustrating an embodiment of a process for dispensing fluid from an on-demand fluid dispenser.
- FIGS. 5A-5J are detailed views of the indicated regions in FIG. 4B illustrating examples of alternative mechanisms for inhibiting movement of an element of the on-demand fluid dispenser in one direction relative to another element of the dispenser.
- FIGS. 6A-6C are diagrammatic sectional views of a variety of combinations of elements and methods that may be implemented in embodiments of the on-demand fluid dispenser.
- FIG. 7 is a diagrammatic sectional view of a piezo valve that may be incorporated in embodiments of the on-demand fluid dispenser.
- FIG. 1 is an exemplary perspective view of one embodiment of an on-demand fluid dispenser 10 .
- dispenser is generally used herein to describe embodiments of the on-demand fluid dispensers, and the terms “dispenser” and “on-demand fluid dispenser” are used interchangeably, in many instances. However, some embodiments of the dispenser may be implemented without the on-demand capability while maintaining other characteristics of embodiments described herein.
- a user 15 may grasp the dispenser 10 in any comfortable manner
- a syringe type of grip is illustrated, although other grips may be used depending on the configuration of the on-demand fluid dispenser 10 .
- a button 20 may be located on a longitudinal end or on a side of the dispenser 10 without loss of meaning or functionality. As shown, the user 15 may press the button 20 to actuate the dispenser 10 , and dispense a fluid 25 in accordance with at least some of the details described herein.
- operating conditions With a gas generation mechanism and mechanisms for inhibiting the impact of variations in conditions in the environment and in the conditions in the dispenser system itself (referred to collectively herein as operating conditions), a reliable dispenser 10 is made possible.
- FIG. 2 is a diagrammatic sectional view of another embodiment of an on-demand fluid dispenser 30 .
- the dispenser 30 may include at least some of the features and characteristics that are presented in the U.S. Provisional Patent Application Ser. No. 60/912,463, filed Apr. 18, 2007, which is incorporated herein by reference.
- the dispenser 30 has a housing 33 and a button 20 similar to the button 20 shown in FIG. 1 .
- the button 20 may be urged away from leads 36 by a resilient element 39 .
- the leads 36 are connected to a printed circuit board or other substrate 42 , which may support an electronic controller (described below) for the dispenser 30 .
- a battery or other power source 45 is connected to the substrate 42 for providing power to the dispenser 30 through operation of the electronic controller in response to an input signal when the user presses the button 20 .
- the button 20 and leads 36 form part of a momentary switch that includes a timer so that pressing the switch for any length of time results in a predetermined actuation time.
- the switch may be a continuous switch that actuates the dispenser 20 continuously for as long as the user 15 actuates the switch.
- the electronic controller delivers power to a gas cell 48 , which then produces gas 50 from a liquid (not shown in FIG. 2 ).
- the gas 50 is directed into an expandable gas chamber 51 .
- the pressure of the gas 50 causes the expandable gas chamber 51 to expand.
- a plunger or first movable wall 54 moves away from the gas cell 48 and toward a front end of the dispenser 30 by the increased pressure of the gas 50 in the expandable gas chamber 51 .
- the plunger wall 54 reduces a volume in a fluid chamber 57 .
- a flexible bag 60 containing a fluid 63 to be dispensed is positioned in the fluid chamber 57 .
- Some embodiments of the dispenser 30 include a mechanism for reducing an impact of operating conditions. Some exemplary mechanisms are described herein. Environmental changes such as changes in temperature or elevation may cause changes in operating conditions such as a pressure or a volume of an enclosed chamber. Changes in ambient pressure affect the pressure differential between an interior of a chamber and an exterior of the chamber. Thus, environmental changes have the effect of causing changes in rates of flow of gases and liquids within the dispenser 30 . Hence, without a mechanism for reducing the impact of the operating conditions of the dispenser 30 , inconsistencies in the amount of dispensed fluid would likely be caused by changes in the environment. The mechanism for reducing the impact of these operating conditions generally controls flow based on pressures such that variations in the operating conditions are inhibited from affecting the amount of the fluid dispensed.
- the dispenser 30 may include a removable cover 75 for engaging an end of the bag 60 around the outlet 66 .
- the bag may have a front end plate 78 of a relatively stiff material.
- the front end plate 78 may act as a stop for engaging the cover 75 .
- a fluid to be dispensed may be placed directly in the fluid chamber 57 without a flexible bag to contain the fluid.
- the configuration shown in FIG. 2 facilitates replacement of a fluid in the dispenser 30 since the cover 75 can easily be removed, for example, to remove an empty bag and to position a full bag for continued use.
- FIG. 3 is a schematic diagram of one embodiment of an electrical circuit 81 that may be incorporated in an embodiment of the on-demand fluid dispenser 30 .
- an electronic controller may include a simple circuit 81 having a switch 84 that includes the leads 36 , power source 45 , and a capacitor 87 .
- the button 20 When the button 20 is pressed, it closes the circuit 81 and actuates the dispenser 30 in which the circuit 81 is disposed.
- an electrical potential is formed across anode 90 and cathode 93 .
- the anode 90 and cathode 93 engage opposite surfaces of an electrolyte membrane 96 .
- the electrolyte membrane 96 can have liquid such as water therein and is formed of a material that facilitates electrolytic activity.
- the material may include one or more of a variety of water-absorbent polymeric materials including, but not limited to, NAFION® (a DuPont registered trademark) for example. Other embodiments may use other types of materials, including micro-porous materials, ion-exchange materials, and non-woven polymer materials.
- the electrodes 90 , 93 may be formed of a metallic wool or mesh material including one or more of a variety of materials including, but not limited to, platinum and platinum coated materials.
- the membrane 96 and/or the electrodes may have large surface areas. As such, a relatively large current is set up across the electrolyte membrane 96 .
- the power source 45 is sufficient to set up a current that will transfer energy to the water molecules at interfaces between the electrodes 90 , 93 and the electrolyte membrane 96 .
- the water molecules subsequently separate into hydrogen and oxygen molecules that are in a gas state and form the gas 50 , as described with regard to FIG. 1 .
- Other, more specialized, electronic controllers may be substituted for the electronic controller implemented by circuit 81 .
- controllers with timers, sensors, memory, and adjustable settings may be implemented.
- FIGS. 4A-4C are diagrammatic partial sectional views illustrating an embodiment of a process for dispensing fluid from an on-demand fluid dispenser 30 .
- FIGS. 4A-4C show respective operations of the process that is included with at least some of the apparatuses and methods described herein.
- FIG. 4A shows the first movable wall 54 (i.e., the plunger) near a second movable wall 102 .
- the second movable wall 102 may be termed a follower, and may be formed at least in part by one or both of the gas cell 48 and the substrate 42 . Alternatively, another structure may be used to form the follower 102 .
- the movable walls 54 , 102 seal the chambers on respective opposite sides of the first movable wall 54 .
- the movable walls 54 , 102 are in close proximity to each other with little or no gas between them such that the expandable gas chamber 51 has a relatively small volume.
- the pressure between the movable walls 54 , 102 increases and applies a force to the walls 54 , 102 in opposite directions away from each other.
- the second movable wall 102 is inhibited from movement away from the first movable wall 54 by any of a variety of mechanisms that are described below.
- the first movable wall 54 is caused to move away from the second movable wall 102 in a forward direction 105 toward the fluid chamber 57 .
- the movable walls 54 , 102 are either passively urged to move toward each other, for example, by ambient pressure or actively urged together, for example, by a spring or pump. Additionally, the first movable wall 54 is also inhibited from movement toward the second movable wall 102 , in a backward direction that is away from the fluid chamber 57 , by any of a variety of mechanisms that are described below. Therefore, the second movable wall 102 is drawn toward the first movable wall 54 as indicated by arrow 108 in FIG. 4C . The operations shown in FIGS.
- 4A-4C may be repeated in an iterative manner so that the movable walls 54 , 102 move forward one at a time (to the right as viewed in FIGS. 4A-4C ). In this way, the movement of the walls 54 , 102 is one-way, or unidirectional, in the forward direction.
- the dispenser 30 includes an outlet valve 111 in the outlet 66 .
- This valve 111 may be a one-way valve or check valve that allows passage of the fluid 63 out of the fluid chamber 57 and inhibits backflow of the fluid 63 or air into the fluid chamber 57 . Since air and other fluid cannot enter the fluid chamber 57 through the outlet 66 , a hydrostatic condition is created in which chamber 57 is held at generally constant volume between iterations of movement of the first movable wall 54 . Thus, the valve 111 provides a mechanism that inhibits movement of the first movable wall 54 in a backward direction. Similarly, a one-way gas chamber valve 114 may be provided through the second movable wall 102 .
- the one-way gas chamber valve 114 may be a pressure sensitive valve such that when gas is being generated, the pressure sensitive one-way gas chamber valve 114 inhibits passage of the gas out through the second movable wall 102 .
- the one-way gas chamber valve 114 may be automatically opened to allow passage of the produced gas out through the second movable wall 102 .
- a balance of the pressures on opposite sides of the second movable wall 102 may provide a mechanism that inhibits movement of the second movable wall 102 in a backward direction when the valve 114 is closed.
- one or more one-way valves in one or more of the first movable wall 54 and side walls of the housing 33 may be substituted for the one-way gas chamber valve 114 .
- the valve 114 may be a manually activated valve or an automatic electrically activated valve, such as a solenoid valve or a piezo valve that are described in greater detail below.
- the valve 114 may be another kind of valve.
- FIGS. 5A-5J are detailed views of the indicated regions in FIG. 4B illustrating examples of alternative mechanisms for inhibiting movement of an element of the on-demand fluid dispenser 30 in one direction relative to another element of the dispenser 30 .
- FIGS. 5A and 5B are detailed diagrammatic sectional views of exemplary structures that may be applied in the indicated regions of FIG. 4B .
- the exemplary structures may be applied to either or both of the movable walls 54 and 102 and/or corresponding portions of an inner surface of the housing 33 .
- FIG. 5A shows a pawl and ratchet mechanism for inhibiting movement of the first or second movable wall(s) 54 , 102 relative to the housing 33 .
- a pawl 117 may be pivotally supported on the movable wall(s) 54 , 102 and a set of teeth 118 may be provided on the inner surface of the housing 33 .
- the angle of the pawl 117 and teeth 118 , and their relative spacing, may be such that movement of the movable wall(s) 54 , 102 is enabled in a forward direction 121 and inhibited in a backward direction relative to the housing 33 .
- the mechanism is a mechanism for causing unidirectional progression of the movable wall(s) 54 , 102 .
- An o-ring 124 of a resilient material may be additionally provided to form a seal between the movable member(s) 54 , 102 and the housing 33 .
- a flange 125 may be provided by itself, as shown in the detailed view of FIG. 5B .
- the flange 125 may have a height and flexibility that enables the flange 125 to be bent and lie nicely in one direction when engaged by an inner surface of the housing 33 .
- the flange 125 creates a seal and enables movement of the movable member(s) or wall(s) 54 , 102 to which it is applied in the forward direction 121 .
- the flange 125 may resist bending in the other direction.
- a force in an opposite backward direction will cause a wedging effect of the flange between the movable wall(s) 54 , 102 and the inner surface of the housing 33 .
- the o-ring 124 and flange 125 are interchangeable as to their sealing function.
- the flange 125 may be formed integrally as one piece with the movable wall(s) 54 , 102 , or may be added onto the movable wall(s) 54 , 102 .
- a shaped o-ring 224 may be configured with a structure to resist movement in the backward direction when engaged with the teeth 118 .
- the material of the shaped o-ring 224 may be elastomeric such that the shaped o-ring 224 forms a seal and resists backward movement at the same time.
- torsion springs 227 may be supported on the movable wall 54 , 102 and engage the teeth 118 with a force in a direction 230 to inhibit backward movement of the movable wall(s) 54 , 102 .
- An o-ring 124 may be held in a groove 233 and form a seal similar to the o-ring 124 of the embodiment shown in FIG. 5A .
- flexible fins 236 may be integrally molded with the movable wall(s) 54 , 102 , as is shown in FIG. 5E .
- FIG. 5F shows a further alternative embodiment in which a sleeve 239 of rubber or other flexible material may be supported on an outer surface of the movable wall(s) 54 , 102 .
- the sleeve 239 may have one or more flanges 242 that function to seal and inhibit movement of the movable wall(s) 54 , 102 in the backward direction while allowing movement of the wall(s) 54 , 102 in the forward direction.
- the sleeve 239 may be glued or vulcanized onto the outer surface of the movable wall(s) 54 , 102 .
- FIGS. 5G-5H show diagrammatic sectional views of mechanisms for causing unidirectional progression of the movable wall(s) 54 , 102 that may be incorporated in place of any of the embodiments shown in FIGS. 5A-5F , as applied to the indicated regions of FIG. 4B
- the mechanisms of FIGS. 5G-5J are configured to cause sealing of the movable walls 54 , 102 about their edges relative to the inner surface of the housing 33 .
- the movable wall(s) 54 , 102 have a tapered groove 245 in an outer edge.
- a flexible wedge ring 248 is received in the groove 245 .
- the movable wall(s) 54 , 102 As a force is applied to the movable wall(s) 54 , 102 in a direction of arrow 251 , the movable wall(s) 54 , 102 are moved so that a deeper end of the tapered groove 245 receives the wedge ring 248 .
- the wedge ring 248 travels relative to the movable wall(s) 54 , 102 along a bottom of the tapered groove 245 in a direction of arrow 254 .
- the wedge ring 248 Since the diameter of the tapered groove 245 decreases in a direction of the arrow 254 , the wedge ring 248 is permitted to contract slightly in a radially inward direction such that flanges or ribs 257 are compressed only slightly to maintain a seal between the movable wall(s) 54 , 102 and the housing 33 . With the wedge ring 248 in the position shown in FIG. 5G , the movable wall is permitted to move in a forward direction corresponding to the direction of arrow 251 while maintaining the seal.
- Movement of the movable wall(s) 54 , 102 in the direction of arrow 251 may occur when, for example, a generated gas expands the expandable gas chamber 51 and pushes movable wall 54 or when a spring urges movable wall 102 toward the movable wall 54 to contract the expandable gas chamber 51 .
- a force acts in a backward direction as indicated by arrow 260 in FIG. 5H
- the movable wall(s) 54 , 102 move back slightly such that a shallow end of the tapered groove 245 causes the wedge ring 248 to stretch radially outward and more firmly engage the inner surface of the housing 33 .
- the wedge ring 248 travels relative to the movable wall 54 , 102 in a direction of the arrow 263 .
- this position shown in FIG. 5H
- the flanges or ribs 257 are deformed and the contact between the ribs 257 and the inner surface of the housing 33 is increased.
- friction between the wedge ring 248 and the housing 33 is increased and movement of the wedge ring 248 and the movable wall(s) 54 , 102 in a backward direction is inhibited.
- repeated iterations of forces in the forward and backward directions on the movable wall(s) 54 , 102 will cause generally incremental forward movement of the movable walls 54 , 102 while inhibiting all but slight movement in the backward direction.
- FIGS. 5I and 5J are diagrammatic section views of details of a mechanism that functions similarly to those shown and described with regard to FIGS. 5G and 5H . These details may be alternatively applied to the indicated regions of FIG. 4B .
- a primary difference in the mechanism of FIGS. 5I and 5H is that it has an o-ring 124 instead of the wedge ring 248 shown in FIGS. 5G and 5H . Otherwise, the structure and function of the mechanism for causing unidirectional movement of FIGS. 5I and 5J is substantially similar to that of FIGS. 5G and 5H . However, FIG.
- 5I shows a force in the backward direction 266 , which would initially be applied to the follower or second movable wall 102 during expansion of the gas in the expandable gas chamber 51 .
- the tapered groove 245 has been moved slightly backward until the o-ring 124 is stretched and pressed such that it grips the inner surface of the housing 33 sufficiently to stop or lock the o-ring 124 and movable wall 102 against further backward movement.
- the same locking occurs when applied to the first movable wall 54 during a contraction of the expandable gas chamber 51 , for example.
- FIGS. 6A-6C are diagrammatic sectional views of a variety of combinations of elements and methods that may be implemented in embodiments of the on-demand fluid dispenser 30 .
- the dispensers 30 of FIGS. 6A-6C show a variety of elements that may be applied to any embodiment of the dispenser 30 without limitation.
- FIG. 6A shows a permeable region 127 which may be integral with or added onto one or more of the movable walls 54 , 102 and a sidewall of the dispenser 30 .
- the housing 33 itself could be formed of the permeable material, or a long strip of permeable material forming a permeable region 127 shown in dashed lines in FIG. 6A may be provided along a length of the housing 33 .
- the permeable region 127 may include a material such as polypropylene or some other material that is permeable to the gas that is being generated, for example oxygen or hydrogen gas, yet relatively impermeable to the source liquid.
- the permeability is such that pressure builds up quickly during generation of the gas and then slowly dissipates as the gas molecules escape through the permeable material.
- the expandable gas chamber 51 will collapse as the pressure drops and substantially equalizes to the ambient air pressure outside the housing 33 . Collapse of the expandable gas chamber 51 may be speeded by a pump and/or spring.
- the outlet 66 may have the outlet valve 111 described above.
- the walls may have additional valves and/or mechanisms for inhibiting movement of the movable walls 54 , 102 in a backward direction as described above. As shown in FIGS. 6A-6C , the walls 54 , 102 will move one after another in a forward direction to the right as indicated by the arrows 130 , 131 .
- the dashed arrows 133 , 134 indicate that in accordance with some embodiments the movable walls 54 , 102 may be moved in a backward direction when the dispenser 30 is being reset and refilled.
- FIG. 6B shows the dispenser 30 with a pump 137 for actively removing the gas after it has been generated and expanded the expandable gas chamber 51 .
- the pump 137 may be incorporated together with a valve or a permeable region on any of the walls forming the expandable gas chamber 51 .
- the pump 137 may be a manually or electrically powered pump. In any case, the pump 137 speeds removal of the gas and contributes to the frequency with which the on-demand activation of the dispenser 30 may be effectuated.
- no valve is shown on the outlet 66 .
- a valve 111 may not be needed when the fluid being dispensed from the fluid chamber 57 is highly viscous, for example.
- a valve 111 may be included in the outlet 66 without limitation.
- FIG. 6C shows the dispenser 30 with a solenoid valve or other gas release mechanism 140 on the second movable wall 102 for releasing gas from an interior to an exterior of the expandable gas chamber 51 .
- the gas release mechanism 140 could alternatively be located on a sidewall of the housing 33 in a portion of the housing corresponding to the expandable gas chamber 51 or any of the walls forming the expandable gas chamber 51 .
- the gas release mechanism 140 may include a valve such as valve 114 shown in FIGS. 4A-4C .
- the gas release mechanism 140 may be operated to release the gas after it has been generated and after it has expanded the expandable gas chamber 51 .
- the gas release mechanism 140 may alternatively include an ionic transport pump that is an electrochemical solid state ionic transport gas pump that has no moving parts.
- the gas release mechanism may include an electrochemical liquid generator to convert the gas in the expandable gas chamber 51 back into a liquid in response to the operation of dispensing the amount of fluid from the fluid chamber 57 .
- the converted liquid may be stored in a liquid storage reserve (not shown) for regeneration of a gas from the converted liquid.
- the on-demand fluid dispenser 30 may thus convert the gas back into a liquid for reuse in a gas cell generator to generate additional gas in a repeating cycle by utilizing an electrochemical reaction of chemical components within the gas.
- the methods may include dispensing in response to a user input for on-demand dispensing.
- one or more springs or other resilient biasing element 143 may be connected to the movable walls 54 , 102 to draw them together. It is to be understood that such biasing elements 143 may be used in conjunction with a permeable region or a valve in any of the walls forming the expandable gas chamber 51 .
- a proximity switch (not shown) may be incorporated in the movable walls such that a valve may be automatically opened when a predetermined amount of gas has been generated and has expanded the expandable gas chamber 51 to a predetermined volume at which the walls are sufficiently separated to activate the proximity switch.
- the resilient biasing element(s) 143 may be replaced by magnetic elements in the form of permanent magnets or electromagnetic coils mounted in or on the movable walls 54 , 102 .
- the magnetic elements may exert attractive forces on each other such that the movable walls are drawn together.
- the resilient biasing element(s) 143 or magnetic elements may be applied in a manner that they push the second movable wall 102 instead of pulling it.
- the magnetic and/or electromagnetic forces can be actively or passively applied to collapse the expandable gas chamber.
- the outlet 66 may alternatively include a duckbill valve 146 .
- FIG. 7 is a diagrammatic sectional view of a piezo valve 272 that may be incorporated in embodiments of the on-demand fluid dispenser 30 .
- the piezo valve 272 may be provided in addition to any of the gas release mechanisms 127 , 137 , 140 of FIGS. 6A-6C .
- These gas release mechanisms generally include some kind of valve or opening located in a wall for releasing a gas through the wall.
- the valve 114 shown in FIGS. 4A-4C extends through a wall of the gas cell 48 , which may at least form part of the second movable wall 102 .
- the valve 114 may form an opening through the substrate 42 , which may at least form part of the second movable wall 102 .
- the valve 114 may take the form of a solenoid valve or the piezo valve 272 shown in FIG. 7 .
- the piezo valve 272 may include a piezo element 275 electrically connected to a power source such as power source 45 by an electronic controller or switch.
- An opening 278 through the second movable wall 102 (or another wall) may have a valve seat 281 connected in surrounding sealing relation to the opening 278 .
- the piezo element 275 when it is energized, it is shortened as shown in solid lines. The energized shortened condition allows passage of gas as indicated by arrows 284 .
- the piezo element 275 lengthens and engages the valve seat 281 , as shown by dashed lines 287 in FIG. 7 .
- the piezo valve 272 may be opened and closed by energizing and de-energizing the piezo element.
- embodiments of the on-line fluid dispenser or method of dispensing a fluid provide a balance between collapsing the expandable gas chamber while substantially maintaining the volume of the fluid chamber. That is, the mechanism for collapsing the expandable gas chamber does not also cause the fluid chamber to collapse. Rather, after the expandable gas chamber has been collapsed, generation of gas causes the fluid chamber to at least partially compress.
- generating gas includes generating the gas at a gas generation rate that is higher than a gas removal rate during the operation of removing the gas from the expandable gas chamber. This aspect enables the dispensers and methods in accordance with certain embodiments to be “on-demand.”
- this on-demand feature may be combined with a continuous gas generation mechanism that continuously generates a reserve of the gas.
- the rapid generation of gas acts in an additive manner to provide a bolus effect of delivering fluid automatically and periodically by the continuous gas generation mechanism, and delivering fluid on-demand as a user activates the dispenser.
- the operation of generating may include generating a volume of gas in a first range from about one to one hundred microliters for a single delivery of fluid from the fluid chamber for a single delivery of fluid from the fluid chamber.
- generating the gas may include generating a volume of gas in a range from approximately twenty to approximately fifty microliters for the single delivery, which may take place over a period of approximately three seconds.
- a volume in these ranges may be generated in a range from one to six seconds.
- the period of generation could be any number within this range, such as five seconds.
- the method may include dispensing the fluid between about one hundred and fifty thousand times.
- the method may include dispensing fluid between about four thousand and fifteen thousand times from the dispenser 30 .
- the dispenser 30 may dispense fluid a substantial number of times potentially using a single liquid source and/or fluid source.
- dispensing may include generating the gas to repeatedly dispense the amount of the fluid at substantially regular, discrete intervals such as by a momentary switch.
- the method may include generating gas continuously such as by depressing a continuous switch. In any case, generating the gas to dispense the fluid on demand may be in response to a user input.
- the on-demand dispensing apparatus and method provides long life over many iterations and/or plural refills.
- the apparatus and method enables easy portability through compactness.
- the apparatus and method is capable of consistently delivering a determined amount of a fluid in a variety of environmental or system conditions.
- the on-demand dispensing apparatus and method in accordance with the disclosed embodiments may be utilized in a wide variety of applications and environments.
- the fluids that can be dispensed by the dispensing apparatus and method are limitless.
- the dispensers disclosed herein may receive fragrances or other fluids in their fluid chambers for dispensing.
- the dispensers may be used to dispense “beneficial agents” such as medicaments and pharmaceutical agents.
- the dispenser may be a unitary device supported in a housing that includes the expandable gas chamber, the fluid chamber, the power source, and the switch.
- the housing may be cylindrical, and have one or more resilient member or element configured to move the second moveable wall in a single direction along a substantially linear path to collapse the expandable gas chamber in response to the amount of fluid being dispensed from the fluid chamber.
- the movable walls may be in the form of movable plungers each having a flexible seal coupled to the moveable plunger to seal the fluid chamber and the expandable gas chamber.
- the first movable plunger may form a common wall between the expandable gas chamber and the fluid chamber.
- a first movable plunger may be formed of a first movable structure or wall
- a second movable plunger may be formed of a second moveable structure forming a second wall of the expandable gas chamber. Removal of the gas from the expandable gas chamber moves the second moveable structure to collapse the expandable gas chamber.
- Other embodiments may be implemented with fewer or more structural components or functional parts.
- the electronic controller may be configured to operate a gas release valve, which may take the form of the solenoid valve or piezo valve described above.
- a gas release valve which may take the form of the solenoid valve or piezo valve described above.
- the electronic controller can release gas from the expandable gas chamber in response to the amount of fluid being dispensed from the fluid chamber either automatically or under user control.
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Abstract
An on-demand fluid dispenser to dispense fluid in response to gas generation by a gas cell. The on-demand fluid dispenser includes an expandable gas chamber, a fluid chamber, and an on-demand gas cell. The expandable gas chamber includes a moveable plunger forming a wall of the expandable gas chamber. The moveable plunger also forms a wall of the fluid chamber. The on-demand gas cell is configured to generate the gas on demand. The on-demand gas cell is also configured to direct the gas to the expandable gas chamber to expand the expandable gas chamber. Expansion of the expandable gas chamber moves the moveable plunger to reduce a volume of the fluid chamber and to dispense an amount of fluid from the fluid chamber.
Description
- This is a divisional application of, and claims priority to, U.S. application Ser. No. 11/923,490, filed Oct. 24, 2007, which claimed priority U.S. Provisional Patent Application No. 60/912,463, filed on Apr. 18, 2007. Both of these applications are incorporated by reference herein in their entirety.
- Dispensing devices such as those that periodically deliver a shot of fragrance into the air are well known. These devices have various control and activation systems including batteries and timers. The mechanisms for delivering the shot may include aerosol type devices that operate over a large range of pressures and piezo pumps.
- Conventional gas cells are used for generating gases such as hydrogen from liquids such as water at relatively slow rates in which a volume of gas is generated slowly for periodic use of the gas for motive or other purposes. These gas cells are used in fluid delivery systems that operate automatically. For example, some conventional gas cells in fluid delivery systems continuously generate gas at a slow rate over a long period of time. A build-up in pressure provides a motive force for causing the fluid to exit from a storage chamber. The force is typically automatically applied at predetermined time intervals under the control of a timer and other controls for automatic, periodic delivery of the fluid.
- Conventional fluid delivery systems that utilize gas cells are deficient in accounting for changes in environmental or system conditions. For example, as a volume of a gas chamber in a conventional fluid delivery system increases over time, the generation of the gas at a constant rate has a changing effect on the fluid delivery over time due to changes in atmospheric pressure, temperature, or other environmental conditions. Changes in pressure of contained gas due to changes in temperature or elevation typically impact the amount of fluid delivered by conventional gas generation fluid delivery systems such that these systems lack consistency under changing operating conditions.
- In one embodiment, a method of dispensing a fluid includes generating a gas from a liquid. The method also includes directing the gas to an expandable gas chamber to expand a volume of the expandable gas chamber. The method includes reducing a volume of a fluid chamber in response to expansion of the expandable gas chamber to dispense an amount of the fluid from the fluid chamber. The method also includes removing the gas from the expandable gas chamber to collapse the expandable gas chamber. Other embodiments of the method are also described.
- In one embodiment, an on-demand fluid dispenser includes an expandable gas chamber. The expandable gas chamber includes a moveable plunger forming a wall of the expandable gas chamber. The moveable plunger also forms a wall of the fluid chamber. An on-demand gas cell is configured to generate the gas on demand and to direct the gas to the expandable gas chamber to expand the expandable gas chamber. In this case, expansion of the expandable gas chamber moves the moveable plunger to reduce a volume of the fluid chamber and to dispense an amount of fluid from the fluid chamber. Additionally, a power source may be connected to the gas cell, and a switch may be coupled to the power source to activate the gas cell. Other embodiments of the on-demand fluid dispenser are also described.
- Other aspects and advantages of embodiments of the present invention will become apparent from the following detailed description, taken in conjunction with the accompanying drawings, which are illustrated by way of example of the various principles and embodiments of the invention.
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FIG. 1 is an exemplary perspective view of one embodiment of an on-demand fluid dispenser. -
FIG. 2 is a diagrammatic sectional view of another embodiment of an on-demand fluid dispenser. -
FIG. 3 is a schematic diagram of one embodiment of an electrical circuit that may be incorporated in an embodiment of the on-demand fluid dispenser. -
FIGS. 4A-4C are diagrammatic partial sectional views illustrating an embodiment of a process for dispensing fluid from an on-demand fluid dispenser. -
FIGS. 5A-5J are detailed views of the indicated regions inFIG. 4B illustrating examples of alternative mechanisms for inhibiting movement of an element of the on-demand fluid dispenser in one direction relative to another element of the dispenser. -
FIGS. 6A-6C are diagrammatic sectional views of a variety of combinations of elements and methods that may be implemented in embodiments of the on-demand fluid dispenser. -
FIG. 7 is a diagrammatic sectional view of a piezo valve that may be incorporated in embodiments of the on-demand fluid dispenser. - Throughout the description, similar reference numbers may be used to identify similar elements.
- In the following description, specific details of various embodiments are provided. However, some embodiments may be practiced with less than all of these specific details. In other instances, certain methods, procedures, components, structures, and/or functions are described in no more detail than to enable the various embodiments of the invention, for the sake of brevity and clarity. It is to be understood that the features shown and described with regard to the various embodiments may be combined by adding or substituting in any combination without limitation.
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FIG. 1 is an exemplary perspective view of one embodiment of an on-demand fluid dispenser 10. It is to be understood that the term “dispenser” is generally used herein to describe embodiments of the on-demand fluid dispensers, and the terms “dispenser” and “on-demand fluid dispenser” are used interchangeably, in many instances. However, some embodiments of the dispenser may be implemented without the on-demand capability while maintaining other characteristics of embodiments described herein. - In the depicted embodiment, a
user 15 may grasp thedispenser 10 in any comfortable manner InFIG. 1 , a syringe type of grip is illustrated, although other grips may be used depending on the configuration of the on-demand fluid dispenser 10. Abutton 20 may be located on a longitudinal end or on a side of thedispenser 10 without loss of meaning or functionality. As shown, theuser 15 may press thebutton 20 to actuate thedispenser 10, and dispense afluid 25 in accordance with at least some of the details described herein. With a gas generation mechanism and mechanisms for inhibiting the impact of variations in conditions in the environment and in the conditions in the dispenser system itself (referred to collectively herein as operating conditions), areliable dispenser 10 is made possible. -
FIG. 2 is a diagrammatic sectional view of another embodiment of an on-demand fluid dispenser 30. Thedispenser 30 may include at least some of the features and characteristics that are presented in the U.S. Provisional Patent Application Ser. No. 60/912,463, filed Apr. 18, 2007, which is incorporated herein by reference. As shown, thedispenser 30 has ahousing 33 and abutton 20 similar to thebutton 20 shown inFIG. 1 . Thebutton 20 may be urged away fromleads 36 by aresilient element 39. Theleads 36 are connected to a printed circuit board orother substrate 42, which may support an electronic controller (described below) for thedispenser 30. A battery orother power source 45 is connected to thesubstrate 42 for providing power to thedispenser 30 through operation of the electronic controller in response to an input signal when the user presses thebutton 20. In one embodiment, thebutton 20 and leads 36 form part of a momentary switch that includes a timer so that pressing the switch for any length of time results in a predetermined actuation time. Alternatively, the switch may be a continuous switch that actuates thedispenser 20 continuously for as long as theuser 15 actuates the switch. - In one embodiment, the electronic controller delivers power to a
gas cell 48, which then producesgas 50 from a liquid (not shown inFIG. 2 ). Thegas 50 is directed into anexpandable gas chamber 51. The pressure of thegas 50 causes theexpandable gas chamber 51 to expand. As a result, a plunger or firstmovable wall 54 moves away from thegas cell 48 and toward a front end of thedispenser 30 by the increased pressure of thegas 50 in theexpandable gas chamber 51. As theplunger 54 moves away from thegas cell 48 within thedispenser 30, theplunger wall 54 reduces a volume in afluid chamber 57. In the embodiment illustrated inFIG. 2 , aflexible bag 60 containing a fluid 63 to be dispensed is positioned in thefluid chamber 57. Thus, when theplunger 54 moves forward, it compresses thebag 60 and displaces an amount of the fluid 63 out through anoutlet 66 in a direction ofarrow 67. - Some embodiments of the
dispenser 30 include a mechanism for reducing an impact of operating conditions. Some exemplary mechanisms are described herein. Environmental changes such as changes in temperature or elevation may cause changes in operating conditions such as a pressure or a volume of an enclosed chamber. Changes in ambient pressure affect the pressure differential between an interior of a chamber and an exterior of the chamber. Thus, environmental changes have the effect of causing changes in rates of flow of gases and liquids within thedispenser 30. Hence, without a mechanism for reducing the impact of the operating conditions of thedispenser 30, inconsistencies in the amount of dispensed fluid would likely be caused by changes in the environment. The mechanism for reducing the impact of these operating conditions generally controls flow based on pressures such that variations in the operating conditions are inhibited from affecting the amount of the fluid dispensed. - The
dispenser 30 may include aremovable cover 75 for engaging an end of thebag 60 around theoutlet 66. The bag may have afront end plate 78 of a relatively stiff material. Thefront end plate 78 may act as a stop for engaging thecover 75. In an alternative embodiment, a fluid to be dispensed may be placed directly in thefluid chamber 57 without a flexible bag to contain the fluid. However, the configuration shown inFIG. 2 facilitates replacement of a fluid in thedispenser 30 since thecover 75 can easily be removed, for example, to remove an empty bag and to position a full bag for continued use. These features may be applied singly or together in any combination with other embodiments disclosed herein without limitation. -
FIG. 3 is a schematic diagram of one embodiment of anelectrical circuit 81 that may be incorporated in an embodiment of the on-demand fluid dispenser 30. With reference toFIG. 3 , an electronic controller may include asimple circuit 81 having aswitch 84 that includes theleads 36,power source 45, and acapacitor 87. When thebutton 20 is pressed, it closes thecircuit 81 and actuates thedispenser 30 in which thecircuit 81 is disposed. When activated, an electrical potential is formed acrossanode 90 andcathode 93. In one embodiment, theanode 90 andcathode 93 engage opposite surfaces of anelectrolyte membrane 96. Theelectrolyte membrane 96 can have liquid such as water therein and is formed of a material that facilitates electrolytic activity. The material may include one or more of a variety of water-absorbent polymeric materials including, but not limited to, NAFION® (a DuPont registered trademark) for example. Other embodiments may use other types of materials, including micro-porous materials, ion-exchange materials, and non-woven polymer materials. Theelectrodes membrane 96 and/or the electrodes may have large surface areas. As such, a relatively large current is set up across theelectrolyte membrane 96. Thepower source 45 is sufficient to set up a current that will transfer energy to the water molecules at interfaces between theelectrodes electrolyte membrane 96. The water molecules subsequently separate into hydrogen and oxygen molecules that are in a gas state and form thegas 50, as described with regard toFIG. 1 . Other, more specialized, electronic controllers may be substituted for the electronic controller implemented bycircuit 81. For example, controllers with timers, sensors, memory, and adjustable settings may be implemented. -
FIGS. 4A-4C are diagrammatic partial sectional views illustrating an embodiment of a process for dispensing fluid from an on-demand fluid dispenser 30.FIGS. 4A-4C show respective operations of the process that is included with at least some of the apparatuses and methods described herein. For example,FIG. 4A shows the first movable wall 54 (i.e., the plunger) near a secondmovable wall 102. The secondmovable wall 102 may be termed a follower, and may be formed at least in part by one or both of thegas cell 48 and thesubstrate 42. Alternatively, another structure may be used to form thefollower 102. Themovable walls movable wall 54. InFIG. 4A , themovable walls expandable gas chamber 51 has a relatively small volume. When thedispenser 30 is actuated and thegas 50 is generated by thegas generation cell 48, the pressure between themovable walls walls movable wall 102 is inhibited from movement away from the firstmovable wall 54 by any of a variety of mechanisms that are described below. Thus, as shown inFIG. 4B , the firstmovable wall 54 is caused to move away from the secondmovable wall 102 in aforward direction 105 toward thefluid chamber 57. When thegas 50 is removed or permitted to escape from theexpandable gas chamber 51, themovable walls movable wall 54 is also inhibited from movement toward the secondmovable wall 102, in a backward direction that is away from thefluid chamber 57, by any of a variety of mechanisms that are described below. Therefore, the secondmovable wall 102 is drawn toward the firstmovable wall 54 as indicated byarrow 108 inFIG. 4C . The operations shown inFIGS. 4A-4C may be repeated in an iterative manner so that themovable walls FIGS. 4A-4C ). In this way, the movement of thewalls - As shown in FIGS. 2 and 4A-4C, the
dispenser 30 includes anoutlet valve 111 in theoutlet 66. Thisvalve 111 may be a one-way valve or check valve that allows passage of the fluid 63 out of thefluid chamber 57 and inhibits backflow of the fluid 63 or air into thefluid chamber 57. Since air and other fluid cannot enter thefluid chamber 57 through theoutlet 66, a hydrostatic condition is created in whichchamber 57 is held at generally constant volume between iterations of movement of the firstmovable wall 54. Thus, thevalve 111 provides a mechanism that inhibits movement of the firstmovable wall 54 in a backward direction. Similarly, a one-waygas chamber valve 114 may be provided through the secondmovable wall 102. The one-waygas chamber valve 114 may be a pressure sensitive valve such that when gas is being generated, the pressure sensitive one-waygas chamber valve 114 inhibits passage of the gas out through the secondmovable wall 102. When the gas has expanded a volume of theexpandable gas chamber 51 and the pressure in theexpandable gas chamber 51 has dropped below a predetermined threshold, then the one-waygas chamber valve 114 may be automatically opened to allow passage of the produced gas out through the secondmovable wall 102. As may be appreciated, by providing a sealed enclosure on a backward side of the secondmovable wall 102, a balance of the pressures on opposite sides of the secondmovable wall 102 may provide a mechanism that inhibits movement of the secondmovable wall 102 in a backward direction when thevalve 114 is closed. Alternatively, one or more one-way valves in one or more of the firstmovable wall 54 and side walls of thehousing 33 may be substituted for the one-waygas chamber valve 114. For example, thevalve 114 may be a manually activated valve or an automatic electrically activated valve, such as a solenoid valve or a piezo valve that are described in greater detail below. Also, thevalve 114 may be another kind of valve. -
FIGS. 5A-5J are detailed views of the indicated regions inFIG. 4B illustrating examples of alternative mechanisms for inhibiting movement of an element of the on-demand fluid dispenser 30 in one direction relative to another element of thedispenser 30.FIGS. 5A and 5B are detailed diagrammatic sectional views of exemplary structures that may be applied in the indicated regions ofFIG. 4B . The exemplary structures may be applied to either or both of themovable walls housing 33.FIG. 5A shows a pawl and ratchet mechanism for inhibiting movement of the first or second movable wall(s) 54, 102 relative to thehousing 33. Thus, apawl 117 may be pivotally supported on the movable wall(s) 54, 102 and a set ofteeth 118 may be provided on the inner surface of thehousing 33. The angle of thepawl 117 andteeth 118, and their relative spacing, may be such that movement of the movable wall(s) 54, 102 is enabled in aforward direction 121 and inhibited in a backward direction relative to thehousing 33. Thus, the mechanism is a mechanism for causing unidirectional progression of the movable wall(s) 54, 102. An o-ring 124 of a resilient material may be additionally provided to form a seal between the movable member(s) 54, 102 and thehousing 33. Alternatively, aflange 125 may be provided by itself, as shown in the detailed view ofFIG. 5B . Theflange 125 may have a height and flexibility that enables theflange 125 to be bent and lie nicely in one direction when engaged by an inner surface of thehousing 33. Theflange 125 creates a seal and enables movement of the movable member(s) or wall(s) 54, 102 to which it is applied in theforward direction 121. On the other hand, theflange 125 may resist bending in the other direction. Thus, a force in an opposite backward direction will cause a wedging effect of the flange between the movable wall(s) 54, 102 and the inner surface of thehousing 33. Thus, a radial force and friction is increased and movement of the movable member(s) 54, 102 in the backward direction is inhibited. As may be appreciated, the o-ring 124 andflange 125 are interchangeable as to their sealing function. Theflange 125 may be formed integrally as one piece with the movable wall(s) 54, 102, or may be added onto the movable wall(s) 54, 102. - Alternatively, details for the indicated regions of
FIG. 4B may be applied in accordance with any ofFIGS. 5C-5F to provide other mechanisms for causing unidirectional progression. As shown in the diagrammatic sectional view ofFIG. 5C , a shaped o-ring 224 may be configured with a structure to resist movement in the backward direction when engaged with theteeth 118. The material of the shaped o-ring 224 may be elastomeric such that the shaped o-ring 224 forms a seal and resists backward movement at the same time. In another alternative shown inFIG. 5D , torsion springs 227 may be supported on themovable wall teeth 118 with a force in adirection 230 to inhibit backward movement of the movable wall(s) 54, 102. An o-ring 124 may be held in agroove 233 and form a seal similar to the o-ring 124 of the embodiment shown inFIG. 5A . Further alternatively,flexible fins 236 may be integrally molded with the movable wall(s) 54, 102, as is shown inFIG. 5E . Theseflexible fins 236 may be angled to engage theteeth 118 to inhibit movement in the backward direction, but to allow forward movement of thefins 236 and the movable wall(s) 54, 102.FIG. 5F shows a further alternative embodiment in which asleeve 239 of rubber or other flexible material may be supported on an outer surface of the movable wall(s) 54, 102. Thesleeve 239 may have one ormore flanges 242 that function to seal and inhibit movement of the movable wall(s) 54, 102 in the backward direction while allowing movement of the wall(s) 54, 102 in the forward direction. Thesleeve 239 may be glued or vulcanized onto the outer surface of the movable wall(s) 54, 102. - In another embodiment,
FIGS. 5G-5H show diagrammatic sectional views of mechanisms for causing unidirectional progression of the movable wall(s) 54, 102 that may be incorporated in place of any of the embodiments shown inFIGS. 5A-5F , as applied to the indicated regions ofFIG. 4B Like the previously described embodiments, the mechanisms ofFIGS. 5G-5J are configured to cause sealing of themovable walls housing 33. For example, inFIG. 5G , the movable wall(s) 54, 102 have a taperedgroove 245 in an outer edge. Aflexible wedge ring 248 is received in thegroove 245. As a force is applied to the movable wall(s) 54, 102 in a direction ofarrow 251, the movable wall(s) 54, 102 are moved so that a deeper end of the taperedgroove 245 receives thewedge ring 248. Alternatively stated, thewedge ring 248 travels relative to the movable wall(s) 54, 102 along a bottom of the taperedgroove 245 in a direction ofarrow 254. Since the diameter of the taperedgroove 245 decreases in a direction of thearrow 254, thewedge ring 248 is permitted to contract slightly in a radially inward direction such that flanges orribs 257 are compressed only slightly to maintain a seal between the movable wall(s) 54, 102 and thehousing 33. With thewedge ring 248 in the position shown inFIG. 5G , the movable wall is permitted to move in a forward direction corresponding to the direction ofarrow 251 while maintaining the seal. Movement of the movable wall(s) 54, 102 in the direction ofarrow 251 may occur when, for example, a generated gas expands theexpandable gas chamber 51 and pushesmovable wall 54 or when a spring urgesmovable wall 102 toward themovable wall 54 to contract theexpandable gas chamber 51. However, when a force acts in a backward direction as indicated byarrow 260 inFIG. 5H , the movable wall(s) 54, 102 move back slightly such that a shallow end of the taperedgroove 245 causes thewedge ring 248 to stretch radially outward and more firmly engage the inner surface of thehousing 33. Alternatively stated, thewedge ring 248 travels relative to themovable wall arrow 263. In this position (shown inFIG. 5H ) the flanges orribs 257 are deformed and the contact between theribs 257 and the inner surface of thehousing 33 is increased. Thus, friction between thewedge ring 248 and thehousing 33 is increased and movement of thewedge ring 248 and the movable wall(s) 54, 102 in a backward direction is inhibited. As may be appreciated, repeated iterations of forces in the forward and backward directions on the movable wall(s) 54, 102 will cause generally incremental forward movement of themovable walls -
FIGS. 5I and 5J are diagrammatic section views of details of a mechanism that functions similarly to those shown and described with regard toFIGS. 5G and 5H . These details may be alternatively applied to the indicated regions ofFIG. 4B . A primary difference in the mechanism ofFIGS. 5I and 5H is that it has an o-ring 124 instead of thewedge ring 248 shown inFIGS. 5G and 5H . Otherwise, the structure and function of the mechanism for causing unidirectional movement ofFIGS. 5I and 5J is substantially similar to that ofFIGS. 5G and 5H . However,FIG. 5I shows a force in thebackward direction 266, which would initially be applied to the follower or secondmovable wall 102 during expansion of the gas in theexpandable gas chamber 51. In this position, the taperedgroove 245 has been moved slightly backward until the o-ring 124 is stretched and pressed such that it grips the inner surface of thehousing 33 sufficiently to stop or lock the o-ring 124 andmovable wall 102 against further backward movement. The same locking occurs when applied to the firstmovable wall 54 during a contraction of theexpandable gas chamber 51, for example. As shown inFIG. 5J , in a subsequent operation when the movable wall(s) 54, 102 have a force applied in the forward direction 269, a deep end of the taperedgroove 245 is moved over the o-ring 124, permitting the o-ring 124 to contract and reduce its frictional engagement with the inner surface of thehousing 33. In the position shown inFIG. 5J , the o-ring 124 forms a seal between the movable wall(s) 54, 102 and thehousing 33 while permitting sliding movement of the o-ring 124 and movable wall(s) 54, 102 in the forward direction. -
FIGS. 6A-6C are diagrammatic sectional views of a variety of combinations of elements and methods that may be implemented in embodiments of the on-demand fluid dispenser 30. Thedispensers 30 ofFIGS. 6A-6C show a variety of elements that may be applied to any embodiment of thedispenser 30 without limitation. For example,FIG. 6A shows apermeable region 127 which may be integral with or added onto one or more of themovable walls dispenser 30. It is to be understood that thehousing 33 itself could be formed of the permeable material, or a long strip of permeable material forming apermeable region 127 shown in dashed lines inFIG. 6A may be provided along a length of thehousing 33. Thepermeable region 127 may include a material such as polypropylene or some other material that is permeable to the gas that is being generated, for example oxygen or hydrogen gas, yet relatively impermeable to the source liquid. However, the permeability is such that pressure builds up quickly during generation of the gas and then slowly dissipates as the gas molecules escape through the permeable material. After expansion during gas generation, theexpandable gas chamber 51 will collapse as the pressure drops and substantially equalizes to the ambient air pressure outside thehousing 33. Collapse of theexpandable gas chamber 51 may be speeded by a pump and/or spring. Theoutlet 66 may have theoutlet valve 111 described above. The walls may have additional valves and/or mechanisms for inhibiting movement of themovable walls FIGS. 6A-6C , thewalls arrows arrows movable walls dispenser 30 is being reset and refilled. -
FIG. 6B shows thedispenser 30 with apump 137 for actively removing the gas after it has been generated and expanded theexpandable gas chamber 51. Thepump 137 may be incorporated together with a valve or a permeable region on any of the walls forming theexpandable gas chamber 51. Thepump 137 may be a manually or electrically powered pump. In any case, thepump 137 speeds removal of the gas and contributes to the frequency with which the on-demand activation of thedispenser 30 may be effectuated. In the embodiment ofFIG. 6B , no valve is shown on theoutlet 66. Avalve 111 may not be needed when the fluid being dispensed from thefluid chamber 57 is highly viscous, for example. On the other hand, avalve 111 may be included in theoutlet 66 without limitation. -
FIG. 6C shows thedispenser 30 with a solenoid valve or othergas release mechanism 140 on the secondmovable wall 102 for releasing gas from an interior to an exterior of theexpandable gas chamber 51. Thegas release mechanism 140 could alternatively be located on a sidewall of thehousing 33 in a portion of the housing corresponding to theexpandable gas chamber 51 or any of the walls forming theexpandable gas chamber 51. Thegas release mechanism 140 may include a valve such asvalve 114 shown inFIGS. 4A-4C . Thegas release mechanism 140 may be operated to release the gas after it has been generated and after it has expanded theexpandable gas chamber 51. Thegas release mechanism 140 may alternatively include an ionic transport pump that is an electrochemical solid state ionic transport gas pump that has no moving parts. Further alternatively, the gas release mechanism may include an electrochemical liquid generator to convert the gas in theexpandable gas chamber 51 back into a liquid in response to the operation of dispensing the amount of fluid from thefluid chamber 57. The converted liquid may be stored in a liquid storage reserve (not shown) for regeneration of a gas from the converted liquid. The on-demand fluid dispenser 30 may thus convert the gas back into a liquid for reuse in a gas cell generator to generate additional gas in a repeating cycle by utilizing an electrochemical reaction of chemical components within the gas. In any case, the methods may include dispensing in response to a user input for on-demand dispensing. - As shown in
FIG. 6C , instead of a pump, one or more springs or otherresilient biasing element 143 may be connected to themovable walls such biasing elements 143 may be used in conjunction with a permeable region or a valve in any of the walls forming theexpandable gas chamber 51. A proximity switch (not shown) may be incorporated in the movable walls such that a valve may be automatically opened when a predetermined amount of gas has been generated and has expanded theexpandable gas chamber 51 to a predetermined volume at which the walls are sufficiently separated to activate the proximity switch. The resilient biasing element(s) 143 may be replaced by magnetic elements in the form of permanent magnets or electromagnetic coils mounted in or on themovable walls movable wall 102 instead of pulling it. The magnetic and/or electromagnetic forces can be actively or passively applied to collapse the expandable gas chamber. As depicted inFIG. 6C , theoutlet 66 may alternatively include aduckbill valve 146. -
FIG. 7 is a diagrammatic sectional view of apiezo valve 272 that may be incorporated in embodiments of the on-demand fluid dispenser 30. Thepiezo valve 272 may be provided in addition to any of thegas release mechanisms FIGS. 6A-6C . These gas release mechanisms generally include some kind of valve or opening located in a wall for releasing a gas through the wall. For example, thevalve 114 shown inFIGS. 4A-4C extends through a wall of thegas cell 48, which may at least form part of the secondmovable wall 102. Alternatively, thevalve 114 may form an opening through thesubstrate 42, which may at least form part of the secondmovable wall 102. Thevalve 114 may take the form of a solenoid valve or thepiezo valve 272 shown inFIG. 7 . Thepiezo valve 272 may include apiezo element 275 electrically connected to a power source such aspower source 45 by an electronic controller or switch. Anopening 278 through the second movable wall 102 (or another wall) may have avalve seat 281 connected in surrounding sealing relation to theopening 278. Thus, when thepiezo element 275 is energized, it is shortened as shown in solid lines. The energized shortened condition allows passage of gas as indicated byarrows 284. When it is de-energized, thepiezo element 275 lengthens and engages thevalve seat 281, as shown by dashedlines 287 inFIG. 7 . Thus, thepiezo valve 272 may be opened and closed by energizing and de-energizing the piezo element. - In one aspect, embodiments of the on-line fluid dispenser or method of dispensing a fluid provide a balance between collapsing the expandable gas chamber while substantially maintaining the volume of the fluid chamber. That is, the mechanism for collapsing the expandable gas chamber does not also cause the fluid chamber to collapse. Rather, after the expandable gas chamber has been collapsed, generation of gas causes the fluid chamber to at least partially compress.
- In another aspect of embodiments of the method of dispensing a liquid, generating gas includes generating the gas at a gas generation rate that is higher than a gas removal rate during the operation of removing the gas from the expandable gas chamber. This aspect enables the dispensers and methods in accordance with certain embodiments to be “on-demand.”
- It is to be understood that this on-demand feature may be combined with a continuous gas generation mechanism that continuously generates a reserve of the gas. In this embodiment, the rapid generation of gas acts in an additive manner to provide a bolus effect of delivering fluid automatically and periodically by the continuous gas generation mechanism, and delivering fluid on-demand as a user activates the dispenser.
- In the on-demand aspect of the embodiments described herein, the operation of generating may include generating a volume of gas in a first range from about one to one hundred microliters for a single delivery of fluid from the fluid chamber for a single delivery of fluid from the fluid chamber. Alternatively, generating the gas may include generating a volume of gas in a range from approximately twenty to approximately fifty microliters for the single delivery, which may take place over a period of approximately three seconds. A volume in these ranges may be generated in a range from one to six seconds. The period of generation could be any number within this range, such as five seconds. Even with a very small easily portable dispenser, the method may include dispensing the fluid between about one hundred and fifty thousand times. Alternatively, the method may include dispensing fluid between about four thousand and fifteen thousand times from the
dispenser 30. In other words, thedispenser 30 may dispense fluid a substantial number of times potentially using a single liquid source and/or fluid source. In this regard, dispensing may include generating the gas to repeatedly dispense the amount of the fluid at substantially regular, discrete intervals such as by a momentary switch. Alternatively, the method may include generating gas continuously such as by depressing a continuous switch. In any case, generating the gas to dispense the fluid on demand may be in response to a user input. - The on-demand dispensing apparatus and method provides long life over many iterations and/or plural refills. In one aspect, the apparatus and method enables easy portability through compactness. In another aspect, the apparatus and method is capable of consistently delivering a determined amount of a fluid in a variety of environmental or system conditions.
- The on-demand dispensing apparatus and method in accordance with the disclosed embodiments may be utilized in a wide variety of applications and environments. The fluids that can be dispensed by the dispensing apparatus and method are limitless. For example, the dispensers disclosed herein may receive fragrances or other fluids in their fluid chambers for dispensing. By way of further example, the dispensers may be used to dispense “beneficial agents” such as medicaments and pharmaceutical agents.
- The dispenser may be a unitary device supported in a housing that includes the expandable gas chamber, the fluid chamber, the power source, and the switch. The housing may be cylindrical, and have one or more resilient member or element configured to move the second moveable wall in a single direction along a substantially linear path to collapse the expandable gas chamber in response to the amount of fluid being dispensed from the fluid chamber. The movable walls may be in the form of movable plungers each having a flexible seal coupled to the moveable plunger to seal the fluid chamber and the expandable gas chamber. The first movable plunger may form a common wall between the expandable gas chamber and the fluid chamber. Hence, a first movable plunger may be formed of a first movable structure or wall, and a second movable plunger may be formed of a second moveable structure forming a second wall of the expandable gas chamber. Removal of the gas from the expandable gas chamber moves the second moveable structure to collapse the expandable gas chamber. Other embodiments may be implemented with fewer or more structural components or functional parts.
- The electronic controller may be configured to operate a gas release valve, which may take the form of the solenoid valve or piezo valve described above. Thus, the electronic controller can release gas from the expandable gas chamber in response to the amount of fluid being dispensed from the fluid chamber either automatically or under user control.
- Reference throughout this specification to “one embodiment,” “an embodiment,” or similar language means that the described feature, operation, structure, or characteristic may be implemented in at least one embodiment. Thus, the phrases “in one embodiment,” “in an embodiment,” and similar phrases throughout this specification may, but do not necessarily, refer to the same embodiment.
- Furthermore, the described features, operations, structures, or characteristics of the described embodiments may be combined in any suitable manner. Hence, the numerous details provided here, such as examples of electrode configurations, housing configurations, chamber configurations, and so forth, provide an understanding of several embodiments of methods of dispensing a fluid and on-demand fluid dispensers. However, some embodiments may be practiced without one or more of the specific details, or with other features operations, components, materials, and so forth. In other instances, well-known structures, materials, or operations are not shown or described in at least some of the figures for the sake of brevity and clarity.
- Although specific embodiments have been described and illustrated, the invention is not to be limited to the specific forms or arrangements of parts so described and illustrated. The scope of the invention is to be defined by the claims appended hereto and their equivalents.
Claims (8)
1. An on-demand fluid dispenser comprising:
an expandable gas chamber comprising a first moveable structure forming a first wall of the expandable gas chamber and moving along a linear path, the first moveable structure comprising a first mechanism to inhibit movement of the first moveable structure in a backward direction along the linear path;
a second moveable structure forming a second wall of the expandable gas chamber and moving along the linear path, the second moveable structure comprising a second mechanism to inhibit movement of the second moveable structure in the backward direction along the linear path;
a fluid chamber, wherein the first moveable structure forms a wall of the fluid chamber; and
an on-demand gas cell to generate a gas on demand and to direct the gas to the expandable gas chamber to expand the expandable gas chamber, wherein expansion of the expandable gas chamber moves the first moveable structure in a forward direction along the linear path to reduce a volume of the fluid chamber and to dispense an amount of fluid from the fluid chamber, and contraction of the expandable gas chamber moves the second moveable structure in the forward direction along the linear path.
2. The on-demand fluid dispenser of claim 1 , further comprising:
a power source connected to the on-demand gas cell; and
a switch coupled to the power source, the switch configured to activate the on-demand gas cell, wherein the on-demand gas cell is configured to produce a volume of gas in a range from about twenty to fifty microliters in approximately three seconds.
3. The on-demand fluid dispenser of claim 1 , further comprising a gas permeable element forming at least a portion of a wall of the expandable gas chamber, wherein the gas permeates out of the expandable gas chamber through the gas permeable element.
4. The on-demand fluid dispenser of claim 1 , further comprising a solenoid valve coupled to a wall of the expandable gas chamber, wherein the solenoid valve is configured to open to release the gas from the expandable gas chamber.
5. The on-demand fluid dispenser of claim 1 , further comprising a pump coupled to the expandable gas chamber, wherein the pump is configured to pump the gas out of the expandable gas chamber to contract the expandable gas chamber.
6. The on-demand fluid dispenser of claim 1 , wherein the on-demand gas cell moves with the second moveable structure.
7. The on-demand fluid dispenser of claim 6 , further comprising:
an outlet coupled to the fluid chamber to dispense the fluid from the fluid chamber; and
a valve coupled to the outlet to inhibit a flow of fluid back into the fluid chamber.
8. The on-demand fluid dispenser of claim 6 , wherein the on-demand gas cell is physically coupled to the second moveable structure.
Priority Applications (1)
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US13/323,341 US20130026194A1 (en) | 2007-04-18 | 2011-12-12 | Gas generation dispenser apparatus for on-demand fluid delivery |
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US13/323,341 US20130026194A1 (en) | 2007-04-18 | 2011-12-12 | Gas generation dispenser apparatus for on-demand fluid delivery |
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US13/323,332 Expired - Fee Related US8353426B2 (en) | 2007-04-18 | 2011-12-12 | Gas generation dispenser method for on-demand fluid delivery |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100176214A1 (en) * | 2009-01-13 | 2010-07-15 | Joshi Ashok V | Greeting card fragrance delivery system |
US8939435B2 (en) | 2011-06-03 | 2015-01-27 | Microlin, Llc | Device for delivery of volatile liquids to gaseous environment utilizing a gas generating cell |
US20170236421A1 (en) * | 2014-11-11 | 2017-08-17 | Harman International Industries, Incorporated | Trajectory detection |
US10390563B2 (en) | 2013-03-22 | 2019-08-27 | Altria Client Services Llc | Electronic smoking article |
Families Citing this family (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7614568B2 (en) * | 2000-08-24 | 2009-11-10 | Microlin, Llc | Device employing gas generating cell for facilitating controlled release of fluid into ambient environment |
US8408900B2 (en) * | 2009-07-08 | 2013-04-02 | Triune Ip Llc | Electrochemical dispensing apparatus and method |
US8257295B2 (en) | 2009-09-21 | 2012-09-04 | Alcon Research, Ltd. | Intraocular pressure sensor with external pressure compensation |
WO2011137124A1 (en) | 2010-04-26 | 2011-11-03 | Geno Llc | Delivery of ultra pure nitric oxide (no) |
US8840578B2 (en) * | 2011-12-09 | 2014-09-23 | Alcon Research, Ltd. | Multilayer membrane actuators |
WO2013090231A1 (en) | 2011-12-13 | 2013-06-20 | Alcon Research, Ltd. | Active drainage systems with dual-input pressure-driven valves |
US9339187B2 (en) | 2011-12-15 | 2016-05-17 | Alcon Research, Ltd. | External pressure measurement system and method for an intraocular implant |
US20180326111A1 (en) * | 2012-08-24 | 2018-11-15 | Microlin, Llc | Aerosol-free, spill-resistant volatile fluid dispensing device |
KR101723319B1 (en) * | 2012-10-12 | 2017-04-04 | 일라이 릴리 앤드 캄파니 | Chemical engines and methods for their use, especially in the injection of highly viscous fluids |
US9321581B2 (en) * | 2012-10-12 | 2016-04-26 | Eli Lilly And Company | Process and device for delivery of fluid by chemical reaction |
US9528633B2 (en) | 2012-12-17 | 2016-12-27 | Novartis Ag | MEMS check valve |
US9295389B2 (en) | 2012-12-17 | 2016-03-29 | Novartis Ag | Systems and methods for priming an intraocular pressure sensor in an intraocular implant |
US9572712B2 (en) | 2012-12-17 | 2017-02-21 | Novartis Ag | Osmotically actuated fluidic valve |
MX2015013513A (en) * | 2013-03-22 | 2016-10-26 | Altria Client Services Llc | Electronic smoking article. |
US9220303B2 (en) * | 2013-05-08 | 2015-12-29 | Shenzhen First Union Technology Co., Ltd. | Cartridge, atomizing device and electronic cigarette having same |
US9877511B2 (en) | 2013-07-24 | 2018-01-30 | Altria Client Services Llc | Electronic smoking article |
WO2015021015A1 (en) * | 2013-08-05 | 2015-02-12 | Johns Nicholas P | Method and apparatus for delivering fluid to an individual |
US9226851B2 (en) | 2013-08-24 | 2016-01-05 | Novartis Ag | MEMS check valve chip and methods |
DE102014223622A1 (en) * | 2013-11-20 | 2015-05-21 | MAHLE Behr GmbH & Co. KG | Scenting system for a motor vehicle |
US9642397B2 (en) * | 2014-03-31 | 2017-05-09 | Westfield Limited (Ltd.) | Personal vaporizer with liquid supply by suction |
US9686976B2 (en) | 2015-03-02 | 2017-06-27 | Bayer Cropscience Lp | Variable metered airless applicator with cartridge |
GB2536259A (en) * | 2015-03-11 | 2016-09-14 | Linde Ag | A device for atomising a liquid |
US10258085B2 (en) * | 2015-05-14 | 2019-04-16 | Westfield Limited (Ltd.) | System and method for vaporizing fluids by combustion |
EP3162229B1 (en) * | 2015-10-28 | 2022-03-30 | Fontem Holdings 1 B.V. | Electronic smoking device with a variable-volume liquid reservoir |
RU2722763C2 (en) * | 2015-12-22 | 2020-06-03 | Филип Моррис Продактс С.А. | Electrically-driven system generating an aerosol with a liquid pump |
US10412996B2 (en) | 2015-12-22 | 2019-09-17 | Altria Client Services Llc | Cartridge for pump-operated aerosol-generating system |
USD901664S1 (en) * | 2016-10-28 | 2020-11-10 | Energizer Brands II, LLC | Air freshener |
CN109952040B (en) * | 2016-11-29 | 2021-07-06 | 菲利普莫里斯生产公司 | Aerosol generating system and method |
CA3049890C (en) | 2017-02-17 | 2022-07-12 | Eli Lilly And Company | Processes and devices for delivery of fluid by chemical reaction |
JP6971385B2 (en) | 2017-09-08 | 2021-11-24 | イーライ リリー アンド カンパニー | A system for controlling gas generation in drug delivery devices |
IT201800004075A1 (en) * | 2018-03-31 | 2019-10-01 | Carla Iannone | Laser micro-sprayer |
US11931551B2 (en) * | 2018-04-09 | 2024-03-19 | Becton Dickinson France | Medical injection system |
GB201808483D0 (en) * | 2018-05-23 | 2018-07-11 | Nicoventures Trading Ltd | Electronic vapour provision system with aerosolisable substrate material dispensing arrangement |
EP4034196A2 (en) * | 2019-09-23 | 2022-08-03 | Battelle Memorial Institute | Apparatus and methods of chemically-powered fluid flow systems |
GB202002898D0 (en) * | 2020-02-28 | 2020-04-15 | Nicoventures Trading Ltd | Aerosol provision system |
DE102020127440A1 (en) * | 2020-08-06 | 2022-02-10 | Atlas Copco Ias Gmbh | Device for conveying viscous material |
TWI806182B (en) * | 2020-11-18 | 2023-06-21 | 潔霺生醫科技股份有限公司 | Multi-stage gas actuated medicine supply device and method |
USD969292S1 (en) * | 2021-01-27 | 2022-11-08 | Daxin Yu | Air freshener |
DE102021127255A1 (en) | 2021-10-20 | 2023-04-20 | Daniel Diggelmann | Diffuser, in particular fragrance dispenser, and use of a diffuser |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4969874A (en) * | 1987-05-18 | 1990-11-13 | Disetronic Ag | Infusion device |
US5492534A (en) * | 1990-04-02 | 1996-02-20 | Pharmetrix Corporation | Controlled release portable pump |
US20050035143A1 (en) * | 2003-08-15 | 2005-02-17 | Peter Massaro | Method and apparatus for handling small volume fluid samples |
Family Cites Families (117)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2481296A (en) * | 1949-09-06 | Vaporizing device | ||
US575365A (en) | 1897-01-19 | mayer | ||
US446953A (en) | 1891-02-24 | Vaporizer | ||
US806844A (en) | 1905-02-06 | 1905-12-12 | Morris B Rosenstock | Feeding device for liquids. |
US957449A (en) | 1908-09-30 | 1910-05-10 | West Disinfecting Co | Disinfectant-holder. |
US976992A (en) | 1908-12-02 | 1910-11-29 | Pierre Claude Francois Effantin | Disinfecting apparatus. |
GB191400142A (en) | 1913-01-07 | 1914-07-09 | Robert Simon Weill | Improvements in or relating to Evaporating Devices for Scent and other Liquids. |
US1099720A (en) * | 1913-04-07 | 1914-06-09 | L B Alford | Disinfecting apparatus. |
US1222756A (en) | 1916-12-14 | 1917-04-17 | Arthur J Griner | Disinfecting apparatus. |
US1921821A (en) * | 1932-05-06 | 1933-08-08 | Walter E Higgins | Insect repeller |
US2236525A (en) * | 1939-11-27 | 1941-04-01 | Robert E Davis | Gas detector |
US2219959A (en) * | 1940-02-01 | 1940-10-29 | Robert E Laidley | Humidifying device |
US2710164A (en) | 1952-06-16 | 1955-06-07 | Miller Mfg Co | Self-closing valve and seal |
US2670236A (en) * | 1952-12-08 | 1954-02-23 | George W Bradburn | Effusing device |
US2740662A (en) | 1954-01-29 | 1956-04-03 | Emily M Scott | Ear attachment |
US2867360A (en) * | 1956-08-20 | 1959-01-06 | Zenith Proc Corp | Self-timing dispenser for vaporizable organic liquids |
US2801879A (en) * | 1956-08-28 | 1957-08-06 | Richard A Fisch | Vapor dispensing device |
US2991517A (en) * | 1957-07-19 | 1961-07-11 | William C Bundy | Deodorant dispensing apparatus |
US3127786A (en) | 1960-12-13 | 1964-04-07 | Wooley William Hubert | Detent for a self-closing water faucet |
DK106956C (en) * | 1960-12-29 | 1967-04-03 | Ciba Geigy | Apparatus for prolonged, uniform release of liquid active substances, preferably insecticides. |
FR2082589A6 (en) | 1964-03-28 | 1971-12-10 | Gentil Albert | Liquid evaporation system - for release of insecticidal vapour etc |
FR1430879A (en) * | 1964-03-28 | 1966-03-11 | evaporation of liquids at constant flow and feed level | |
US3254841A (en) * | 1964-05-12 | 1966-06-07 | Sr Frank E De Loncker | Fluid diffuser device having a triangular shaped container |
US3685734A (en) * | 1971-02-19 | 1972-08-22 | Minnesota Mining & Mfg | Controlled fragrance release device |
US3804592A (en) * | 1972-02-16 | 1974-04-16 | Nilodor Co Inc | Timed drop applicator |
US4017030A (en) * | 1974-10-31 | 1977-04-12 | Albany International Corporation | Devices for controlled release of vapors |
US3955930A (en) * | 1975-04-07 | 1976-05-11 | Justin Joel Shapiro | Automatic dilutor having coupled diluent and reagent plungers |
BR7706576A (en) * | 1976-10-05 | 1978-06-27 | Valmet Oy | MEANS TO DAMAGE PRESSURE DISTURBANCES IN THE FLOW OF A PULP SUSPENSION (F) IN A PAPER MAKING MACHINE |
US4158440A (en) | 1976-10-12 | 1979-06-19 | The Ridson Manufacturing Company | Device for releasing a volatile substance in a controlled manner |
US4166478A (en) * | 1977-12-21 | 1979-09-04 | Kazuo Sugimura | Accumulator having a bladder to be filled with liquid |
US4328843A (en) * | 1978-02-27 | 1982-05-11 | Minoru Fujii | Pressurized dispensers for dispensing products utilizing a pressure transfer fluid |
US4294778A (en) * | 1978-10-18 | 1981-10-13 | Georgia-Pacific Corporation | Evaporative dispenser |
US4265373A (en) * | 1979-05-23 | 1981-05-05 | Stoody William R | Pressurized dispenser with dip tube extending through sac-in-can |
US4408635A (en) * | 1980-02-14 | 1983-10-11 | Liquid Dynamics, Inc. | Hydropneumatic pulse interceptor |
US4312347A (en) * | 1980-02-25 | 1982-01-26 | Iowa State University Research Foundation, Inc. | Positive pressure drug releasing device |
JPS5742438Y2 (en) * | 1980-07-11 | 1982-09-18 | ||
US4477414A (en) * | 1981-05-20 | 1984-10-16 | Fumakilla Limited | Evaporative container |
NL8104354A (en) * | 1981-09-22 | 1983-04-18 | Wijbren Jouwsma | LAMINARY FLOW ELEMENT. |
US4399942A (en) * | 1981-11-09 | 1983-08-23 | Gc Industries | Gas emitting device |
US4522698A (en) * | 1981-11-12 | 1985-06-11 | Maget Henri J R | Electrochemical prime mover |
US4468220A (en) * | 1982-04-05 | 1984-08-28 | Milliken Research Corporation | Low flow constant rate pump |
EP0094499B2 (en) * | 1982-05-15 | 1992-03-04 | Globol-Werk GmbH | Vaporizer for insecticides, aromatics and/or other volatile active substances |
US4697549A (en) * | 1982-09-30 | 1987-10-06 | Hair Jakie A | Apparatus for sustained dispensation of a chemical agent |
LU84992A1 (en) * | 1983-09-07 | 1985-06-04 | Wurth Paul Sa | DEVICE FOR DETERMINING THE PROFILE OF THE LOADING SURFACE OF A TANK OVEN |
US4632310A (en) * | 1984-09-27 | 1986-12-30 | S. C. Johnson & Son, Inc. | Automatic door-activated air freshener |
FR2571259B1 (en) * | 1984-10-09 | 1987-02-20 | Reckitt Colman | VOLATILE LIQUID DIFFUSER |
US4886514A (en) * | 1985-05-02 | 1989-12-12 | Ivac Corporation | Electrochemically driven drug dispenser |
US4674494A (en) | 1985-05-10 | 1987-06-23 | The Kendall Company | Humidifying device |
US4871544A (en) * | 1985-08-16 | 1989-10-03 | Alza Corporation | Ruminant dispensing device |
US4966767A (en) * | 1985-08-16 | 1990-10-30 | Alza Corporation | Ruminant dispensing device comprising agent displacement member |
US4753389A (en) | 1987-03-05 | 1988-06-28 | American Felt & Filter Company | System and method for controlled release of vapors |
US4809912A (en) * | 1987-03-27 | 1989-03-07 | Delaire, Inc. | Membrane-gel diffusion device |
US5074252A (en) * | 1988-03-25 | 1991-12-24 | Morgan Jr Charles | Rechargeable insecticide dispenser providing controlled release of an insecticide composition |
US4846003A (en) | 1988-06-08 | 1989-07-11 | Beckman Instruments, Inc. | Acoustic impedance system for pipette tip detection |
US4948047A (en) * | 1988-08-12 | 1990-08-14 | Drackett Company | Air freshener with microporous membrane |
US4995555A (en) * | 1988-11-14 | 1991-02-26 | American Cyanamid Company | Air treatment device and method |
US4917301A (en) * | 1988-11-15 | 1990-04-17 | International Flavors & Fragrances, Inc. | Container with microporous membrane for dispensing vapor from volatile liquid |
US5034229A (en) * | 1988-12-13 | 1991-07-23 | Alza Corporation | Dispenser for increasing feed conversion of hog |
US5143259A (en) * | 1989-11-20 | 1992-09-01 | Williams John E | Non-aerosol dispenser having a manually energizable piston |
US5223266A (en) * | 1990-01-24 | 1993-06-29 | Alza Corporation | Long-term delivery device with early startup |
US5474785A (en) * | 1990-01-24 | 1995-12-12 | Alza Corporation | Delivery system comprising means for controlling internal pressure |
US6004309A (en) * | 1990-03-30 | 1999-12-21 | Alza Corporation | Method and apparatus for controlled environment electrotransport |
US5196002A (en) * | 1990-10-09 | 1993-03-23 | University Of Utah Research Foundation | Implantable drug delivery system with piston acutation |
NL9200414A (en) * | 1992-03-06 | 1993-10-01 | Bronkhorst High Tech Bv | LAMINARY FLOW ELEMENT WITH INTEGRATED TURBULENCE FILTER. |
US5462741A (en) | 1992-08-06 | 1995-10-31 | Alza Corporation | High agent loaded controlled release dispenser |
US5454922A (en) * | 1993-05-07 | 1995-10-03 | Ceramatec, Inc. | Fluid dispensing pump |
US5681435A (en) * | 1993-05-07 | 1997-10-28 | Ceramatec, Inc. | Fluid dispensing pump |
US5427870A (en) * | 1994-09-06 | 1995-06-27 | Ceramatec, Inc. | Gas releasing electrochemical cell for fluid dispensing applications |
US5398851A (en) * | 1993-08-06 | 1995-03-21 | River Medical, Inc. | Liquid delivery device |
US5549037A (en) * | 1994-03-21 | 1996-08-27 | Effervescent Products, Llc | Gas generator attachment |
US5437410A (en) * | 1994-06-20 | 1995-08-01 | Isc, Inc. | Passive fragrance dispenser |
US5538605A (en) * | 1994-09-06 | 1996-07-23 | Ceramatec, Inc. | Solid oxide cathode-based electrochemical oxygen generator for fluid dispensing applications |
US5744014A (en) * | 1994-09-06 | 1998-04-28 | Ceramatec, Inc. | Storage stable electrolytic gas generator for fluid dispensing applications |
WO1996041159A1 (en) * | 1995-06-07 | 1996-12-19 | Ceramatec, Inc. | Gas amplifier |
US5700245A (en) * | 1995-07-13 | 1997-12-23 | Winfield Medical | Apparatus for the generation of gas pressure for controlled fluid delivery |
IL114716A0 (en) * | 1995-07-24 | 1995-11-27 | Ohayon Nissim | Device for the controlled dispensation and evaporation of volatile liquids |
US5591395A (en) | 1995-08-03 | 1997-01-07 | S. C. Johnson & Son, Inc. | Method of disinfecting air |
WO1997009078A1 (en) * | 1995-09-05 | 1997-03-13 | Elan Medical Technologies Limited | Chemically driven liquid delivery pumping device |
US5647515A (en) * | 1995-09-29 | 1997-07-15 | Zwijnenberg; Lambertus Herman | Stepping plunger for air-activated dispensing system |
US6060196A (en) * | 1995-10-06 | 2000-05-09 | Ceramtec, Inc. | Storage-stable zinc anode based electrochemical cell |
US5707499A (en) * | 1995-10-06 | 1998-01-13 | Ceramatec, Inc. | Storage-stable, fluid dispensing device using a hydrogen gas generator |
US5785688A (en) * | 1996-05-07 | 1998-07-28 | Ceramatec, Inc. | Fluid delivery apparatus and method |
US5638868A (en) * | 1996-06-05 | 1997-06-17 | Valcor Engineering | Accumulator |
US5932204A (en) * | 1996-07-26 | 1999-08-03 | Ceramatec, Inc. | Controlled release of substances |
US5765751A (en) * | 1996-07-26 | 1998-06-16 | Ceramatec, Inc. | Controlled release of volatile substances |
US5915925A (en) * | 1997-01-07 | 1999-06-29 | North, Jr.; Howard L. | Pulseless liquid supply system for flow cytometry |
US5899381A (en) * | 1997-02-21 | 1999-05-04 | Ceramatec, Inc. | Electrochemical device for delivery of volatile substances |
US5954268A (en) * | 1997-03-03 | 1999-09-21 | Joshi; Ashok V. | Fluid delivery system |
US6045055A (en) * | 1997-03-03 | 2000-04-04 | Ceramatec, Inc. | Device and method for delivering fluid |
US7614568B2 (en) * | 2000-08-24 | 2009-11-10 | Microlin, Llc | Device employing gas generating cell for facilitating controlled release of fluid into ambient environment |
US6787008B2 (en) * | 2001-10-30 | 2004-09-07 | Microlin, L.C. | Hydrogen generating cell with cathode |
US6283461B1 (en) * | 1997-06-20 | 2001-09-04 | Ceramatec, Inc. | Automatic cyclic fluid delivery device and associated process |
US20070001024A1 (en) * | 1997-06-20 | 2007-01-04 | Microlin, L.C. | Device employing gas generating cell for facilitating controlled release of fluid into ambient environment |
US6923383B1 (en) * | 2000-08-24 | 2005-08-02 | Microlin, L.C. | Controlled release of substances |
US5921251A (en) * | 1997-08-07 | 1999-07-13 | Ceramatec, Inc. | Brush that delivers beneficial agents |
US5951538A (en) * | 1997-08-07 | 1999-09-14 | Ceramatec, Inc. | Gas generating device for delivering beneficial agents to a body cavity |
JPH11248279A (en) * | 1998-03-05 | 1999-09-14 | Aisin Seiki Co Ltd | Pulse tube refrigirating machine |
US6220267B1 (en) * | 1999-01-27 | 2001-04-24 | Ceramatec, Inc. | Apparatus and method for controllably delivering fluid to a second fluid stream |
US6378780B1 (en) * | 1999-02-09 | 2002-04-30 | S. C. Johnson & Son, Inc. | Delivery system for dispensing volatiles |
DE19924807A1 (en) * | 1999-05-29 | 2000-12-07 | Hydac Technology Gmbh | Hydropneumatic pressure accumulator |
ES2185600T3 (en) * | 1999-07-01 | 2003-05-01 | Johnson & Son Inc S C | LIQUID CEBO INSECTICIDE STATION. |
DE10003648A1 (en) * | 2000-01-29 | 2001-08-09 | Hydac Technology Gmbh | Hydropneumatic pressure accumulator |
DE10015616A1 (en) * | 2000-03-29 | 2001-10-04 | Peter Mueller | Injection syringe for use in dentistry, comprises injection tube, an ampoule, a press member which controls the substance flow, and a work unit which acts on the ampoule |
ATE301822T1 (en) * | 2000-05-04 | 2005-08-15 | Sensirion Ag | FLOW SENSOR FOR LIQUIDS |
EP1412017B1 (en) * | 2000-11-30 | 2016-04-13 | Valeritas, Inc. | Fluid delivery and measurement systems and methods |
US20050218074A1 (en) * | 2004-04-06 | 2005-10-06 | Pollock David C | Method and apparatus providing improved throughput and operating life of submerged membranes |
DE10112976A1 (en) * | 2001-03-17 | 2002-10-02 | Hydac Technology Gmbh | Hydropneumatic pressure accumulator |
US6715300B2 (en) * | 2001-04-20 | 2004-04-06 | Igc-Apd Cryogenics | Pulse tube integral flow smoother |
US6491684B1 (en) * | 2001-05-22 | 2002-12-10 | Durect Corporation | Fluid delivery device having a water generating electrochemical/chemical pump and associated method |
JP4108353B2 (en) * | 2002-03-29 | 2008-06-25 | ノードソン コーポレーション | Liquid ejection method and apparatus |
BE1014807A5 (en) * | 2002-04-30 | 2004-04-06 | Groep Stevens International Na | Fluidumaccumulator and method for manufacturing thereof. |
WO2004020005A1 (en) | 2002-08-28 | 2004-03-11 | Guala Dispensing S.P.A. | Device for emanating electro-conductive fluid substances |
US6805306B1 (en) | 2002-10-23 | 2004-10-19 | Huang Jung-Kun | Cylinder rapid engagement device in an electrical spray gun |
US20040135005A1 (en) * | 2002-12-23 | 2004-07-15 | Valois Sas | Fluid dispenser |
JP4221275B2 (en) | 2003-11-10 | 2009-02-12 | トステム株式会社 | Method for using one sash frame for both a single glass panel and a multi-layer glass panel, and an opening device |
FR2863595B1 (en) * | 2003-12-12 | 2006-03-03 | Airlessystems | FLUID PRODUCT DISPENSER. |
US7149417B2 (en) | 2004-02-19 | 2006-12-12 | Joshi Ashok V | Controllable release of a volatile substance |
-
2007
- 2007-10-24 US US11/923,490 patent/US8113390B2/en not_active Expired - Fee Related
-
2008
- 2008-10-23 WO PCT/US2008/080988 patent/WO2009055591A2/en active Application Filing
- 2008-10-23 EP EP08841716.7A patent/EP2212017A4/en not_active Withdrawn
-
2011
- 2011-12-12 US US13/323,341 patent/US20130026194A1/en not_active Abandoned
- 2011-12-12 US US13/323,332 patent/US8353426B2/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4969874A (en) * | 1987-05-18 | 1990-11-13 | Disetronic Ag | Infusion device |
US5492534A (en) * | 1990-04-02 | 1996-02-20 | Pharmetrix Corporation | Controlled release portable pump |
US20050035143A1 (en) * | 2003-08-15 | 2005-02-17 | Peter Massaro | Method and apparatus for handling small volume fluid samples |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100176214A1 (en) * | 2009-01-13 | 2010-07-15 | Joshi Ashok V | Greeting card fragrance delivery system |
US8939435B2 (en) | 2011-06-03 | 2015-01-27 | Microlin, Llc | Device for delivery of volatile liquids to gaseous environment utilizing a gas generating cell |
US10390563B2 (en) | 2013-03-22 | 2019-08-27 | Altria Client Services Llc | Electronic smoking article |
US20170236421A1 (en) * | 2014-11-11 | 2017-08-17 | Harman International Industries, Incorporated | Trajectory detection |
Also Published As
Publication number | Publication date |
---|---|
US8353426B2 (en) | 2013-01-15 |
EP2212017A4 (en) | 2015-01-07 |
US8113390B2 (en) | 2012-02-14 |
WO2009055591A3 (en) | 2009-08-13 |
US20080257915A1 (en) | 2008-10-23 |
EP2212017A2 (en) | 2010-08-04 |
WO2009055591A2 (en) | 2009-04-30 |
US20120145742A1 (en) | 2012-06-14 |
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