US20120325653A1 - Hydrogen Producing Apparatus - Google Patents
Hydrogen Producing Apparatus Download PDFInfo
- Publication number
- US20120325653A1 US20120325653A1 US13/205,691 US201113205691A US2012325653A1 US 20120325653 A1 US20120325653 A1 US 20120325653A1 US 201113205691 A US201113205691 A US 201113205691A US 2012325653 A1 US2012325653 A1 US 2012325653A1
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- Prior art keywords
- heater
- auxiliary
- radiator
- hydrogen
- temperature
- Prior art date
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 131
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 131
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 121
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- 239000007788 liquid Substances 0.000 description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 41
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 36
- 239000001301 oxygen Substances 0.000 description 36
- 229910052760 oxygen Inorganic materials 0.000 description 36
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 18
- 150000002431 hydrogen Chemical class 0.000 description 10
- 239000000446 fuel Substances 0.000 description 9
- 239000012530 fluid Substances 0.000 description 8
- 238000010586 diagram Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 239000002440 industrial waste Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B15/00—Operating or servicing cells
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Definitions
- the present invention relates to a hydrogen producing device and, more particularly, to a hydrogen producing apparatus using liquid water to produce liquid hydrogen.
- Hydrogen energy plays an important role in the future development of new energy, because hydrogen energy is light and not toxic, has excellent thermal conductivity, and can be converted into different forms for easy storage and transportation.
- FIG. 1 shows a conventional hydrogen producing apparatus 9 including a compressor 91 , a cooler 92 , and a turbine 93 .
- the compressor 91 , the cooler 92 , and the turbine 93 are connected in sequence by a piping.
- normal pressure/normal temperature (about 1 atm/300K) gaseous hydrogen H 2 (g) is introduced into the compressor 91 and turns into high pressure/high temperature (about 20 atm/800K) gaseous hydrogen. Then, the high pressure/high temperature gaseous hydrogen flows into the cooler 92 and cooled to lower the temperature while the pressure remains the same.
- low pressure/low temperature liquid hydrogen H 2 (l) is obtained and stored for use.
- the conventional hydrogen producing device 9 produces liquid hydrogen from gaseous hydrogen.
- the compressor 91 due to the bond strength of gaseous hydrogen in which hydrogen molecules normally exist in the gaseous state, the compressor 91 must consume considerable energy to compress normal pressure/normal temperature gaseous hydrogen into high pressure/high temperature gaseous hydrogen.
- the conventional hydrogen producing device 9 is not economic and can not fulfill the need of saving energy and reducing emission of carbon in the modern times.
- the conventional hydrogen producing device 9 using gaseous hydrogen as the reactant for obtaining liquid hydrogen can not be utilized to produce other products. As a result, the conventional hydrogen producing device 9 has limited function and, thus, provides limited utility.
- the conventional hydrogen producing device 9 includes the disadvantages of waste of energy and low utility. Improvement to the conventional hydrogen producing device 9 is required.
- An objective of the present invention is to provide a hydrogen producing device using liquid water that is compressed and heated and then electrolyzed to produce liquid hydrogen, effectively saving energy.
- Another objective of the present invention is to provide a hydrogen producing device that uses liquid water to produce liquid hydrogen and liquid oxygen, effectively enhancing utility.
- the present invention fulfills the above objectives by providing a hydrogen producing device including a pump, a heating assembly, an electrolyser, at least one radiator, and a converting unit.
- the heating assembly includes at least one front heater, a middle heater, and a solar heater.
- the at least one front heater is connected to the pump.
- the middle heater is located between the at least one front heater and the solar heater.
- the electrolyser is connected to the solar heater.
- the at least one radiator is connected to the electrolyser and the at least one front heater.
- the electrolyser is located between the solar heater and the at least one radiator.
- the converting unit is connected to the at least one radiator.
- the hydrogen producing apparatus can further include at least one auxiliary radiator and an auxiliary converting unit.
- the at least one auxiliary radiator is located between the electrolyser and the auxiliary converting unit.
- the at least one auxiliary radiator is connected to the at least one front heater.
- FIG. 1 shows a schematic diagram of a conventional hydrogen producing apparatus.
- FIG. 2 shows a schematic diagram of a hydrogen producing apparatus of a first embodiment according to the present invention.
- FIG. 3 shows a schematic diagram of a hydrogen producing apparatus of a second embodiment according to the present invention.
- FIG. 4 shows a schematic diagram of a hydrogen producing apparatus of a third embodiment according to the present invention.
- normal temperature means the temperature of 300K, which can be appreciated by one having ordinary skill in the art.
- high temperature referred to hereinafter means a temperature higher than the “normal temperature”.
- low temperature referred to hereinafter means a temperature lower than the “normal temperature”.
- normal pressure means 1 atm, which can be appreciated by one having ordinary skill in the art.
- high pressure referred to hereinafter means a pressure higher than the “normal pressure”.
- low pressure referred to hereinafter means a pressure lower than the “normal pressure”.
- a hydrogen producing apparatus of a first embodiment includes a pump 1 , a heating assembly 2 , an electrolyser 3 , at least one radiator 4 , and a converting unit 5 .
- the pump 1 , the heating assembly 2 , the electrolyser 3 , the at least one radiator 4 , and the converting unit 5 are connected in sequence by a first piping.
- the pump 1 is used to compress normal temperature/normal pressure liquid water H 2 O(l) (hereinafter referred to as “first liquid water”) into normal temperature/high pressure liquid water (hereinafter referred to as “second liquid water”). Namely, the pump 1 increases the pressure of the liquid water while the temperature of the liquid water remains the same. In this embodiment, the pump 1 compresses the first liquid water having a pressure of 1 atm and having a temperature of 300K into the second liquid water having a pressure of 20 atm and having a temperature of 300K.
- the heating assembly 2 includes at least one front heater 21 , a middle heater 22 , and a solar heater 23 .
- the at least one front heater 21 , the middle heater 22 , and the solar heater 23 are connected in sequence by the first piping. Namely, the at least one front heater 21 is connected to the pump 1 , and the middle heater 22 is located between the at least one front heater 21 and the solar heater 23 .
- the at least one front heater 21 can be connected to the at least one radiator 4 to utilize the heat q released by the at least one radiator 4 while high temperature/high pressure gaseous hydrogen flows through the at least one radiator 4 so as to heat the second liquid water to a first temperature, which will be described in detail hereinafter.
- the middle heater 22 can utilize heat Q 1 obtained from burning natural gas or kerosene to increase the temperature of the liquid water from the first temperature to a second temperature.
- the solar heater 23 utilizes the heat Q 2 of solar energy to increase the temperature of the liquid water from the second temperature to a third temperature, obtaining high temperature/high pressure liquid water (hereinafter referred to as “third liquid water”) and assuring the thermodynamic state of the third liquid water to reach the critical point.
- a single front heater 21 is mounted between the pump 1 and the middle heater 22 .
- the front heater 21 utilizes the heat q released from the enthalpy of the high temperature/high pressure gaseous hydrogen obtained from electrolysis to heat the second liquid water from 300K to 600K (the first temperature).
- the middle heater 22 increases the temperature of the liquid water from 600K to 1000K (the second temperature).
- the solar heater 23 increases the temperature of the liquid water from 1000K to 1010K (the third temperature).
- the electrolyser 3 can be of any structure capable of electrolyzing the third liquid water at the critical point to produce high temperature/high pressure gaseous hydrogen H 2 (g) and high temperature/high pressure gaseous oxygen O 2 (g) and capable of directing the gaseous hydrogen and the gaseous oxygen into different pipes.
- the electrolyser 3 cooperates with the solar heater 23 to electrolyze the third liquid water.
- a catalyst is added into the third liquid water to produce the gaseous hydrogen and the gaseous oxygen.
- the electrolyser 3 includes an input 31 , a first output 32 , and a second output 32 .
- the input 31 is connected to the solar heater 23 .
- the first output 32 is connected to the at least one radiator 4 for outputting high temperature/high pressure gaseous hydrogen (hereinafter referred to as “first gaseous hydrogen”).
- the second output 33 is connected to another pipe (not shown) for outputting high temperature/high pressure gaseous oxygen (hereinafter referred to as “first gaseous oxygen”).
- first gaseous oxygen high temperature/high pressure gaseous oxygen
- the temperature and pressure of the gaseous hydrogen and the gaseous oxygen are the same as those of the third liquid water after passing through the electrolyser 3 . Namely, gaseous hydrogen and gaseous oxygen having a pressure of 20 atm and having a temperature of 1010K are obtained through the electrolyser 3 .
- the at least one radiator 4 is utilized to release the heat q of the first gaseous hydrogen, reducing the temperature of the first gaseous hydrogen while the pressure of the first gaseous hydrogen remains the same.
- the number of the at least one radiator 4 can be the same as that of the at least one front heater 21 , and each radiator 4 is connected to a corresponding front heater 21 .
- the number of the at least one radiator 4 can be larger than that of the at least one front heater 21 according to need.
- the heat q of the first gaseous hydrogen can be applied to any suitable member or any suitable situation.
- the number of the at least one radiator 4 is the same as that of the at least one front heater 21 . Specifically, only one radiator 4 is used in this embodiment.
- the first gaseous hydrogen having a pressure of 20 atm and having a temperature of 1010K is converted into a second gaseous hydrogen having a pressure of 20 atm and having a temperature of 300K after passing through the radiator 4 .
- the front heater 21 and the radiator 4 together form a heat exchanger to preheat the second liquid water to the first temperature, so that a small amount of energy is required by the middle heater 22 for increasing the liquid water from the first temperature to the second temperature, saving the energy consumed by the middle heater 22 .
- the converting unit 5 converts the second gaseous hydrogen into low temperature/low pressure liquid hydrogen H 2 (l) and low temperature/low pressure gaseous hydrogen H 2 (g).
- the liquid hydrogen can be stored for use, achieving production of hydrogen.
- the gaseous hydrogen can be directed into an anodic passageway of a fuel cell (not shown) for outputting electricity to the electrolyser 3 through electrochemical reaction.
- the converting unit 5 includes a turbine 51 and a rear heater 52 .
- the turbine 51 is located between the radiator 4 and the rear heater 52 .
- the rear heater 52 is located between the turbine 51 and a separator (not shown).
- the turbine 51 is used to expand the second gaseous hydrogen and to reduce the pressure and the temperature of the second gaseous hydrogen, converting the second gaseous hydrogen into a mixture of liquid hydrogen (hereinafter referred to as “first liquid hydrogen”) and gaseous hydrogen (hereinafter referred to as “the third gaseous hydrogen”). Both of the first liquid hydrogen and the third gaseous hydrogen have a much lower temperature and a low pressure.
- the rear heater 52 can utilize the heat Q 3 obtained from ordinary industrial waste heat to heat the first liquid hydrogen and the third gaseous hydrogen at a constant pressure, converting the first liquid hydrogen into low temperature/low pressure liquid hydrogen (hereinafter referred to as “second liquid hydrogen”) and converting the third gaseous hydrogen into low temperature/low pressure gaseous hydrogen (hereinafter referred to as “fourth gaseous hydrogen”). Note that when the second gaseous hydrogen enters the turbine 51 , the turbine 51 outputs shaft power to drive a heat machine (not shown).
- the turbine 51 converts the second gaseous hydrogen having a pressure of 20 atm and having a temperature of 300K into the first liquid hydrogen and the third gaseous hydrogen both having a pressure of 0.1 atm and having a temperature of 20K.
- the rear heater 52 heats the first liquid hydrogen at a constant pressure to convert the first liquid hydrogen into the second liquid hydrogen having a pressure of 0.1 atm and having a temperature of 66K.
- the rear heater 52 heats the third gaseous hydrogen at a constant pressure to convert the third gaseous hydrogen into the fourth gaseous hydrogen having a pressure of 0.1 atm and having a temperature of 66K.
- the first liquid water having a pressure of 1 atm and having a temperature of 300K is introduced into the pump 1 and compressed at a constant temperature to obtain the second liquid water having a pressure of 20 atm and having a temperature of 300K.
- the second liquid water having a pressure of 20 atm and having a temperature of 300K is heated by the middle heater 22 to 1000K at a constant pressure and then heated by the solar heater 23 at a constant pressure, obtaining the third liquid water having a pressure of 20 atm and having a temperature of 1010K.
- the first output 32 of the electrolyser 3 directs the first gaseous hydrogen having a pressure of 20 atm and having a temperature of 1010K to the radiator 4 , and the radiator 4 transmits the heat q of the first gaseous hydrogen into the front heater 21 .
- the front heater 21 preheats the second liquid water having a pressure of 20 atm and having a temperature of 300K to 600K by using the heat q.
- the middle heater 22 heats the second liquid water to 1000K, saving the energy consumed by the middle heater 22 .
- the radiator 4 discharges the first gaseous hydrogen having a pressure of 20 atm and having a temperature of 1010K
- the second gaseous hydrogen having a pressure of 20 atm and having a temperature of 300K is directed into the turbine 51 and expands in the turbine 51 to reduce the pressure and temperature, obtaining the first liquid hydrogen and the third gaseous hydrogen both having a pressure of 0.1 atm and having a temperature of 20K.
- Each of the first liquid hydrogen and the third gaseous hydrogen is heated by the rear heater 52 at a constant pressure to obtain the second liquid hydrogen and the fourth gaseous hydrogen both having a pressure of 0.1 atm and having a temperature of 66K, obtaining hydrogen energy having characteristics of light weight, excellent thermal conductivity, non toxicity, and capability of conversion into different forms for easy storage and transportation.
- the main feature of the hydrogen producing apparatus according to the present invention is that since the bond strength of liquid water is much weaker than that of the gaseous hydrogen, it is much easier to compress the normal temperature/normal pressure liquid water into normal temperature/high pressure at a constant temperature. The energy consumed by the pump 1 is, thus, saved. Furthermore, by the cooperation of the solar heater 23 and the heat exchanger that is comprised of the front heater 21 and the radiator 4 , the liquid water can be heated in an environment close to the critical state with a small amount of energy, such that high temperature/high pressure liquid water can be electrolyzed to produce high temperature/high pressure gaseous hydrogen. As such, the hydrogen producing apparatus according to the present invention can effectively save energy.
- FIG. 3 shows a hydrogen producing apparatus of a second embodiment according to the present invention.
- the converting unit 5 of the second embodiment further includes a separator 53 .
- the second embodiment includes at least one auxiliary radiator 6 , an auxiliary converting unit 7 , and a fuel cell P.
- the second output 33 of the electrolyser 3 utilizes a second piping to connect the at least one auxiliary radiator 6 and the auxiliary converting unit 7 in sequence.
- the fuel cell P is connected to the converting unit 5 and the auxiliary converting unit 7 .
- the separator 53 is connected to the rear heater 52 and the fuel cell P.
- the rear heater 52 is located between the turbine 51 and the separator 53 .
- the separator 53 directs the second liquid hydrogen into a storage unit (not shown) for storage purposes and directs the fourth gaseous hydrogen to the anodic passageway of the fuel cell P.
- the at least one auxiliary radiator 6 discharges the heat q′ of the first gaseous oxygen to reduce the temperature of the first gaseous oxygen at a constant pressure, obtaining normal temperature/high pressure gaseous oxygen (hereinafter referred to as “second gaseous oxygen”).
- second gaseous oxygen normal temperature/high pressure gaseous oxygen
- the number of the at least one auxiliary radiator 6 can be equal to that of the at least one front heater 21 , and each auxiliary radiator 6 is connected to a corresponding front heater 21 .
- the number of the at least one auxiliary radiator 6 can be more than that of the at least one front heater 21 .
- the heat q′ of the first gaseous oxygen can be applied to any suitable member or any suitable situation.
- the number of the at least one auxiliary radiator 6 is the same as that of the at least one front heater 21 .
- only one auxiliary radiator 6 is used in this embodiment.
- the first gaseous oxygen having a pressure of 20 atm and having a temperature of 1010K is converted into the second gaseous oxygen having a pressure of 20 atm and having a temperature of 300K after passing through the auxiliary radiator 6 .
- the front heater 21 , the radiator 4 , and the auxiliary radiator 6 together form a heat exchanger to preheat the second liquid water to the first temperature, so that a small amount of energy is required by the middle heater 22 for increasing the liquid water from the first temperature to the second temperature.
- the auxiliary converting unit 7 converts the second gaseous oxygen into normal temperature/low pressure liquid oxygen O 2 (l) and normal temperature/low pressure gaseous oxygen O 2 (g).
- the liquid oxygen can be stored for use, increasing the utility of the hydrogen producing apparatus.
- the gaseous oxygen can be directed into a cathodic passageway of the fuel cell P.
- the auxiliary converting unit 7 includes an auxiliary turbine 71 , an auxiliary rear heater 72 , and an auxiliary separator 73 .
- the auxiliary turbine 71 is mounted between the auxiliary radiator 6 and the auxiliary rear heater 72 .
- the auxiliary rear heater 72 is located between the auxiliary turbine 71 and the auxiliary separator 73 .
- the auxiliary turbine 71 is used to expand the second gaseous oxygen and to reduce the pressure and the temperature of the second gaseous oxygen, converting the second gaseous oxygen into a mixture of low temperature/low pressure liquid oxygen (hereinafter referred to as “first liquid oxygen”) and low/temperature/low pressure gaseous oxygen (hereinafter referred to as “the third gaseous oxygen”).
- the auxiliary rear heater 72 can utilize the heat Q 4 obtained from ordinary industrial waste heat to heat the first liquid oxygen and the third gaseous oxygen at a constant pressure, converting the first liquid oxygen into normal temperature/low pressure liquid oxygen (hereinafter referred to as “second liquid oxygen”) and converting the third gaseous oxygen into normal temperature/low pressure gaseous oxygen (hereinafter referred to as “fourth gaseous oxygen”).
- the auxiliary separator 73 is connected to the auxiliary rear heater 72 and the fuel cell P. Furthermore, the auxiliary rear heater 72 is located between the auxiliary turbine 71 and the auxiliary separator 73 .
- the auxiliary separator 73 directs the second liquid oxygen into a storage unit (not shown) for storage purposes and directs the fourth gaseous oxygen into the cathodic passageway of the fuel cell P. Note that when the second gaseous oxygen enters the auxiliary turbine 71 , the auxiliary turbine 71 outputs shaft power to drive a heat machine (not shown).
- the auxiliary turbine 71 converts the second gaseous oxygen having a pressure of 20 atm and having a temperature of 300K into the first liquid oxygen and the third gaseous oxygen both having a pressure of 0.1 atm and having a temperature of 66K.
- the auxiliary rear heater 72 heats the first liquid oxygen at a constant pressure to convert the first liquid oxygen into the second liquid oxygen having a pressure of 0.1 atm and having a temperature of 300K.
- the auxiliary rear heater 72 heats the third gaseous oxygen at a constant pressure to convert the third gaseous oxygen into the fourth gaseous oxygen having a pressure of 0.1 atm and having a temperature of 300K.
- the second embodiment of the hydrogen producing device according to the present invention further produces normal temperature/low pressure liquid oxygen and further saves the energy consumed by the middle heater 22 . Furthermore, the electrolyser 3 is activated by the fuel cell P in the second embodiment.
- FIG. 4 shows a third embodiment of a hydrogen producing apparatus according to the present invention.
- the converting unit 5 in the third embodiment is connected to a first heat machine 8 a
- the auxiliary converting unit 7 is connected to a second heat machine 8 b.
- more than one front heater 21 more than one radiator 4 , and more than one auxiliary radiator 6 are used.
- a first front heater 21 a and a second front heater 21 b are mounted between the pump 1 and the middle heater 22 .
- the first front heater 21 a is connected to the pump 1
- the second front heater 21 b is connected to the middle heater 22 .
- Four radiators 4 are used in this embodiment.
- first, second, third, and fourth radiators 4 a, 4 b, 4 c, and 4 d are connected in sequence to the first output 32 of the electrolyser 3 .
- the fourth radiator 4 d is connected to the turbine 51 .
- Two auxiliary radiators 6 are used in this embodiment. Specifically, first and second auxiliary radiators 6 are connected in sequence to the second output 33 of the electrolyser 3 .
- the second auxiliary radiator 6 is connected to the auxiliary turbine 71 .
- the first front heater 21 a is connected to the second radiator 4 b and the second auxiliary radiator 6 b and that the second front heater 21 b is connected to the first radiator 4 a and the first auxiliary radiator 6 a.
- the heat of first gaseous hydrogen and the first gaseous oxygen can be discharged in a multi-level manner, such that the first and second front heaters 21 a and 21 b can heat the first liquid water at a constant pressure in a multi-level manner.
- the fourth radiator 4 d is connected to the auxiliary rear heater 72 of the auxiliary converting unit 7 , such that the heat released during the constant-pressure heating procedure of the first gaseous hydrogen can be utilized to heat the first liquid oxygen and the third gaseous oxygen.
- the energy consumed by the auxiliary rear heater 72 can be saved.
- the first heat machine 8 a is connected to the turbine 51 of the converting unit 5 , such that the shaft work outputted by the turbine 51 drives the first heat machine 8 a.
- the first heat machine 8 a can supply power to any member or any place.
- the first heat machine 8 a includes a first compressor 81 a, a first evaporator 82 a, a first steam turbine 83 a, and a first condenser 84 a.
- the first compressor 81 a, the first evaporator 82 a, the first steam turbine 83 a, and the first condenser 84 a are connected with each other in sequence by a piping filled with a first working fluid.
- the first compressor 81 a is connected to the turbine 51 .
- the shaft work outputted by the turbine 51 can drive the first compressor 81 a to compress the first working fluid so that the first working fluid can undergo a first power cycle to cause the first steam turbine 83 a to output shaft work W 1 .
- the first condenser 84 a is connected to the second front heater 21 b in this embodiment, so that the low-quality sensible heat of the first working fluid can be discharged to the second front heater 21 b, saving the energy consumed by the middle heater 22 .
- the second heat machine 8 b is connected to the auxiliary turbine 71 of the auxiliary converting unit 7 .
- the shaft work outputted by the auxiliary turbine 71 can drive the second heat machine 8 b to provide power to any member or any place.
- the second heat machine 8 b includes a second compressor 81 b, a second evaporator 82 b, a second steam turbine 83 b, and a second condenser 84 b.
- the second compressor 81 b, the second evaporator 82 b, the second steam turbine 83 b, and the second condenser 84 b are connected with each other in sequence by a piping filled with a second working fluid.
- the second compressor 81 b is connected to the auxiliary turbine 71 .
- the shaft work outputted by the auxiliary turbine 71 can drive the second compressor 81 b to compress the second working fluid so that the second working fluid can undergo a second power cycle to cause the second steam turbine 83 b to output shaft work W 2 .
- the second evaporator 82 b is connected to the third radiator 4 c to receive the heat discharged by the third radiator 4 c, effectively saving the energy supplied to the second heat machine 8 b.
- the second condenser 84 b is connected to the first front heater 21 a, so that the low-quality sensible heat of the second working fluid can be discharged to the first front heater 21 a, significantly saving the energy consumed by the middle heater 22 .
- the third embodiment of the hydrogen producing device utilizes the shaft work outputted by the turbine 51 and the auxiliary turbine 71 to drive the first and second heat machines 8 a and 8 b to operate. Furthermore, the first and second heat machines 8 a and 8 b can undergo heat exchange with the first and second front heaters 21 a and 21 b to save the energy consumed by the middle heater 22 .
- the hydrogen producing apparatus according to the present invention can produce liquid hydrogen and liquid oxygen at the same time.
- the hydrogen producing apparatus according to the present invention effectively saves energy and provides enhanced utility.
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Abstract
A hydrogen producing apparatus includes a pump, a heating assembly, an electrolyser, at least one radiator, and a converting unit. The heating assembly includes at least one front heater, a middle heater, and a solar heater. The at least one front heater is connected to the pump. The middle heater is located between the at least one front heater and the solar heater. The electrolyser is connected to the solar heater. The at least one radiator is connected to the electrolyser and the at least one front heater. The electrolyser is located between the solar heater and the at least one radiator. The converting unit is connected to the at least one radiator.
Description
- 1. Field of the Invention
- The present invention relates to a hydrogen producing device and, more particularly, to a hydrogen producing apparatus using liquid water to produce liquid hydrogen.
- 2. Description of the Related Art
- To reduce consumption of petroleum and emission of carbon, development of new energy is gradually booming due to the rise of the environmental protection. Hydrogen energy plays an important role in the future development of new energy, because hydrogen energy is light and not toxic, has excellent thermal conductivity, and can be converted into different forms for easy storage and transportation.
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FIG. 1 shows a conventionalhydrogen producing apparatus 9 including acompressor 91, acooler 92, and aturbine 93. Thecompressor 91, thecooler 92, and theturbine 93 are connected in sequence by a piping. In production of hydrogen, normal pressure/normal temperature (about 1 atm/300K) gaseous hydrogen H2(g) is introduced into thecompressor 91 and turns into high pressure/high temperature (about 20 atm/800K) gaseous hydrogen. Then, the high pressure/high temperature gaseous hydrogen flows into thecooler 92 and cooled to lower the temperature while the pressure remains the same. After the high pressure gaseous hydrogen passes through theturbine 93, low pressure/low temperature liquid hydrogen H2(l) is obtained and stored for use. - The conventional
hydrogen producing device 9 produces liquid hydrogen from gaseous hydrogen. However, due to the bond strength of gaseous hydrogen in which hydrogen molecules normally exist in the gaseous state, thecompressor 91 must consume considerable energy to compress normal pressure/normal temperature gaseous hydrogen into high pressure/high temperature gaseous hydrogen. Thus, the conventionalhydrogen producing device 9 is not economic and can not fulfill the need of saving energy and reducing emission of carbon in the modern times. Furthermore, the conventionalhydrogen producing device 9 using gaseous hydrogen as the reactant for obtaining liquid hydrogen can not be utilized to produce other products. As a result, the conventionalhydrogen producing device 9 has limited function and, thus, provides limited utility. - As a whole, the conventional
hydrogen producing device 9 includes the disadvantages of waste of energy and low utility. Improvement to the conventionalhydrogen producing device 9 is required. - An objective of the present invention is to provide a hydrogen producing device using liquid water that is compressed and heated and then electrolyzed to produce liquid hydrogen, effectively saving energy.
- Another objective of the present invention is to provide a hydrogen producing device that uses liquid water to produce liquid hydrogen and liquid oxygen, effectively enhancing utility.
- The present invention fulfills the above objectives by providing a hydrogen producing device including a pump, a heating assembly, an electrolyser, at least one radiator, and a converting unit. The heating assembly includes at least one front heater, a middle heater, and a solar heater. The at least one front heater is connected to the pump. The middle heater is located between the at least one front heater and the solar heater. The electrolyser is connected to the solar heater. The at least one radiator is connected to the electrolyser and the at least one front heater. The electrolyser is located between the solar heater and the at least one radiator. The converting unit is connected to the at least one radiator.
- The hydrogen producing apparatus according to the present invention can further include at least one auxiliary radiator and an auxiliary converting unit. The at least one auxiliary radiator is located between the electrolyser and the auxiliary converting unit. The at least one auxiliary radiator is connected to the at least one front heater. Thus, normal temperature/low pressure liquid oxygen can be produced.
- The present invention will become clearer in light of the following detailed description of illustrative embodiments of this invention described in connection with the drawings.
- The illustrative embodiments may best be described by reference to the accompanying drawings where:
-
FIG. 1 shows a schematic diagram of a conventional hydrogen producing apparatus. -
FIG. 2 shows a schematic diagram of a hydrogen producing apparatus of a first embodiment according to the present invention. -
FIG. 3 shows a schematic diagram of a hydrogen producing apparatus of a second embodiment according to the present invention. -
FIG. 4 shows a schematic diagram of a hydrogen producing apparatus of a third embodiment according to the present invention. - All figures are drawn for ease of explanation of the basic teachings of the present invention only; the extensions of the figures with respect to number, position, relationship, and dimensions of the parts to form the preferred embodiments will be explained or will be within the skill of the art after the following teachings of the present invention have been read and understood. Further, the exact dimensions and dimensional proportions to conform to specific force, weight, strength, and similar requirements will likewise be within the skill of the art after the following teachings of the present invention have been read and understood.
- The term “normal temperature” referred to hereinafter means the temperature of 300K, which can be appreciated by one having ordinary skill in the art. The term “high temperature” referred to hereinafter means a temperature higher than the “normal temperature”. The term “low temperature” referred to hereinafter means a temperature lower than the “normal temperature”.
- The term “normal pressure” referred to hereinafter means 1 atm, which can be appreciated by one having ordinary skill in the art. The term “high pressure” referred to hereinafter means a pressure higher than the “normal pressure”. The term “low pressure” referred to hereinafter means a pressure lower than the “normal pressure”.
- With reference to
FIG. 2 , a hydrogen producing apparatus of a first embodiment according to the present invention includes apump 1, aheating assembly 2, anelectrolyser 3, at least oneradiator 4, and a convertingunit 5. Thepump 1, theheating assembly 2, theelectrolyser 3, the at least oneradiator 4, and the convertingunit 5 are connected in sequence by a first piping. - The
pump 1 is used to compress normal temperature/normal pressure liquid water H2O(l) (hereinafter referred to as “first liquid water”) into normal temperature/high pressure liquid water (hereinafter referred to as “second liquid water”). Namely, thepump 1 increases the pressure of the liquid water while the temperature of the liquid water remains the same. In this embodiment, thepump 1 compresses the first liquid water having a pressure of 1 atm and having a temperature of 300K into the second liquid water having a pressure of 20 atm and having a temperature of 300K. - The
heating assembly 2 includes at least onefront heater 21, amiddle heater 22, and asolar heater 23. The at least onefront heater 21, themiddle heater 22, and thesolar heater 23 are connected in sequence by the first piping. Namely, the at least onefront heater 21 is connected to thepump 1, and themiddle heater 22 is located between the at least onefront heater 21 and thesolar heater 23. Note that the at least onefront heater 21 can be connected to the at least oneradiator 4 to utilize the heat q released by the at least oneradiator 4 while high temperature/high pressure gaseous hydrogen flows through the at least oneradiator 4 so as to heat the second liquid water to a first temperature, which will be described in detail hereinafter. Themiddle heater 22 can utilize heat Q1 obtained from burning natural gas or kerosene to increase the temperature of the liquid water from the first temperature to a second temperature. Thesolar heater 23 utilizes the heat Q2 of solar energy to increase the temperature of the liquid water from the second temperature to a third temperature, obtaining high temperature/high pressure liquid water (hereinafter referred to as “third liquid water”) and assuring the thermodynamic state of the third liquid water to reach the critical point. - In this embodiment, a single
front heater 21 is mounted between thepump 1 and themiddle heater 22. Thefront heater 21 utilizes the heat q released from the enthalpy of the high temperature/high pressure gaseous hydrogen obtained from electrolysis to heat the second liquid water from 300K to 600K (the first temperature). Themiddle heater 22 increases the temperature of the liquid water from 600K to 1000K (the second temperature). Thesolar heater 23 increases the temperature of the liquid water from 1000K to 1010K (the third temperature). - The
electrolyser 3 can be of any structure capable of electrolyzing the third liquid water at the critical point to produce high temperature/high pressure gaseous hydrogen H2(g) and high temperature/high pressure gaseous oxygen O2(g) and capable of directing the gaseous hydrogen and the gaseous oxygen into different pipes. In this embodiment, theelectrolyser 3 cooperates with thesolar heater 23 to electrolyze the third liquid water. A catalyst is added into the third liquid water to produce the gaseous hydrogen and the gaseous oxygen. Specifically, theelectrolyser 3 includes aninput 31, afirst output 32, and asecond output 32. Theinput 31 is connected to thesolar heater 23. Thefirst output 32 is connected to the at least oneradiator 4 for outputting high temperature/high pressure gaseous hydrogen (hereinafter referred to as “first gaseous hydrogen”). Thesecond output 33 is connected to another pipe (not shown) for outputting high temperature/high pressure gaseous oxygen (hereinafter referred to as “first gaseous oxygen”). Note that the temperature and pressure of the gaseous hydrogen and the gaseous oxygen are the same as those of the third liquid water after passing through theelectrolyser 3. Namely, gaseous hydrogen and gaseous oxygen having a pressure of 20 atm and having a temperature of 1010K are obtained through theelectrolyser 3. - The at least one
radiator 4 is utilized to release the heat q of the first gaseous hydrogen, reducing the temperature of the first gaseous hydrogen while the pressure of the first gaseous hydrogen remains the same. Note that the number of the at least oneradiator 4 can be the same as that of the at least onefront heater 21, and eachradiator 4 is connected to a correspondingfront heater 21. However, the number of the at least oneradiator 4 can be larger than that of the at least onefront heater 21 according to need. Thus, in addition to releasing the heat q of the first gaseous hydrogen to the at least onefront heater 21, the heat q of the first gaseous hydrogen can be applied to any suitable member or any suitable situation. - In this embodiment, the number of the at least one
radiator 4 is the same as that of the at least onefront heater 21. Specifically, only oneradiator 4 is used in this embodiment. The first gaseous hydrogen having a pressure of 20 atm and having a temperature of 1010K is converted into a second gaseous hydrogen having a pressure of 20 atm and having a temperature of 300K after passing through theradiator 4. Of more importance, thefront heater 21 and theradiator 4 together form a heat exchanger to preheat the second liquid water to the first temperature, so that a small amount of energy is required by themiddle heater 22 for increasing the liquid water from the first temperature to the second temperature, saving the energy consumed by themiddle heater 22. - The converting
unit 5 converts the second gaseous hydrogen into low temperature/low pressure liquid hydrogen H2(l) and low temperature/low pressure gaseous hydrogen H2(g). Thus, the liquid hydrogen can be stored for use, achieving production of hydrogen. The gaseous hydrogen can be directed into an anodic passageway of a fuel cell (not shown) for outputting electricity to theelectrolyser 3 through electrochemical reaction. Specifically, the convertingunit 5 includes aturbine 51 and arear heater 52. Theturbine 51 is located between theradiator 4 and therear heater 52. Therear heater 52 is located between theturbine 51 and a separator (not shown). Theturbine 51 is used to expand the second gaseous hydrogen and to reduce the pressure and the temperature of the second gaseous hydrogen, converting the second gaseous hydrogen into a mixture of liquid hydrogen (hereinafter referred to as “first liquid hydrogen”) and gaseous hydrogen (hereinafter referred to as “the third gaseous hydrogen”). Both of the first liquid hydrogen and the third gaseous hydrogen have a much lower temperature and a low pressure. Therear heater 52 can utilize the heat Q3 obtained from ordinary industrial waste heat to heat the first liquid hydrogen and the third gaseous hydrogen at a constant pressure, converting the first liquid hydrogen into low temperature/low pressure liquid hydrogen (hereinafter referred to as “second liquid hydrogen”) and converting the third gaseous hydrogen into low temperature/low pressure gaseous hydrogen (hereinafter referred to as “fourth gaseous hydrogen”). Note that when the second gaseous hydrogen enters theturbine 51, theturbine 51 outputs shaft power to drive a heat machine (not shown). - In this embodiment, the
turbine 51 converts the second gaseous hydrogen having a pressure of 20 atm and having a temperature of 300K into the first liquid hydrogen and the third gaseous hydrogen both having a pressure of 0.1 atm and having a temperature of 20K. Therear heater 52 heats the first liquid hydrogen at a constant pressure to convert the first liquid hydrogen into the second liquid hydrogen having a pressure of 0.1 atm and having a temperature of 66K. Also, therear heater 52 heats the third gaseous hydrogen at a constant pressure to convert the third gaseous hydrogen into the fourth gaseous hydrogen having a pressure of 0.1 atm and having a temperature of 66K. - With reference to
FIG. 2 , in production of hydrogen by the hydrogen producing apparatus according to the present invention, the first liquid water having a pressure of 1 atm and having a temperature of 300K is introduced into thepump 1 and compressed at a constant temperature to obtain the second liquid water having a pressure of 20 atm and having a temperature of 300K. At the initial stage of the operation, before theradiator 4 discharges the heat q obtained from high temperature electrolysis to thefront heater 21, the second liquid water having a pressure of 20 atm and having a temperature of 300K is heated by themiddle heater 22 to 1000K at a constant pressure and then heated by thesolar heater 23 at a constant pressure, obtaining the third liquid water having a pressure of 20 atm and having a temperature of 1010K. After the third liquid water flows into theelectrolyser 3 and reacts with the catalyst in the critical state, thefirst output 32 of theelectrolyser 3 directs the first gaseous hydrogen having a pressure of 20 atm and having a temperature of 1010K to theradiator 4, and theradiator 4 transmits the heat q of the first gaseous hydrogen into thefront heater 21. At the middle stage of the operation, thefront heater 21 preheats the second liquid water having a pressure of 20 atm and having a temperature of 300K to 600K by using the heat q. Then, themiddle heater 22 heats the second liquid water to 1000K, saving the energy consumed by themiddle heater 22. - After the
radiator 4 discharges the first gaseous hydrogen having a pressure of 20 atm and having a temperature of 1010K, the second gaseous hydrogen having a pressure of 20 atm and having a temperature of 300K is directed into theturbine 51 and expands in theturbine 51 to reduce the pressure and temperature, obtaining the first liquid hydrogen and the third gaseous hydrogen both having a pressure of 0.1 atm and having a temperature of 20K. Each of the first liquid hydrogen and the third gaseous hydrogen is heated by therear heater 52 at a constant pressure to obtain the second liquid hydrogen and the fourth gaseous hydrogen both having a pressure of 0.1 atm and having a temperature of 66K, obtaining hydrogen energy having characteristics of light weight, excellent thermal conductivity, non toxicity, and capability of conversion into different forms for easy storage and transportation. - The main feature of the hydrogen producing apparatus according to the present invention is that since the bond strength of liquid water is much weaker than that of the gaseous hydrogen, it is much easier to compress the normal temperature/normal pressure liquid water into normal temperature/high pressure at a constant temperature. The energy consumed by the
pump 1 is, thus, saved. Furthermore, by the cooperation of thesolar heater 23 and the heat exchanger that is comprised of thefront heater 21 and theradiator 4, the liquid water can be heated in an environment close to the critical state with a small amount of energy, such that high temperature/high pressure liquid water can be electrolyzed to produce high temperature/high pressure gaseous hydrogen. As such, the hydrogen producing apparatus according to the present invention can effectively save energy. -
FIG. 3 shows a hydrogen producing apparatus of a second embodiment according to the present invention. Compared to the first embodiment, the convertingunit 5 of the second embodiment further includes aseparator 53. Furthermore, the second embodiment includes at least oneauxiliary radiator 6, anauxiliary converting unit 7, and a fuel cell P. Thesecond output 33 of theelectrolyser 3 utilizes a second piping to connect the at least oneauxiliary radiator 6 and the auxiliary convertingunit 7 in sequence. The fuel cell P is connected to the convertingunit 5 and the auxiliary convertingunit 7. - The
separator 53 is connected to therear heater 52 and the fuel cell P. Therear heater 52 is located between theturbine 51 and theseparator 53. Theseparator 53 directs the second liquid hydrogen into a storage unit (not shown) for storage purposes and directs the fourth gaseous hydrogen to the anodic passageway of the fuel cell P. - The at least one
auxiliary radiator 6 discharges the heat q′ of the first gaseous oxygen to reduce the temperature of the first gaseous oxygen at a constant pressure, obtaining normal temperature/high pressure gaseous oxygen (hereinafter referred to as “second gaseous oxygen”). Note that the number of the at least oneauxiliary radiator 6 can be equal to that of the at least onefront heater 21, and eachauxiliary radiator 6 is connected to a correspondingfront heater 21. However, the number of the at least oneauxiliary radiator 6 can be more than that of the at least onefront heater 21. Thus, in addition to releasing the heat q′ of the first gaseous oxygen to the at least onefront heater 21, the heat q′ of the first gaseous oxygen can be applied to any suitable member or any suitable situation. - In this embodiment, the number of the at least one
auxiliary radiator 6 is the same as that of the at least onefront heater 21. Specifically, only oneauxiliary radiator 6 is used in this embodiment. The first gaseous oxygen having a pressure of 20 atm and having a temperature of 1010K is converted into the second gaseous oxygen having a pressure of 20 atm and having a temperature of 300K after passing through theauxiliary radiator 6. Of more importance, thefront heater 21, theradiator 4, and theauxiliary radiator 6 together form a heat exchanger to preheat the second liquid water to the first temperature, so that a small amount of energy is required by themiddle heater 22 for increasing the liquid water from the first temperature to the second temperature. - The auxiliary converting
unit 7 converts the second gaseous oxygen into normal temperature/low pressure liquid oxygen O2(l) and normal temperature/low pressure gaseous oxygen O2(g). The liquid oxygen can be stored for use, increasing the utility of the hydrogen producing apparatus. The gaseous oxygen can be directed into a cathodic passageway of the fuel cell P. More specifically, theauxiliary converting unit 7 includes anauxiliary turbine 71, an auxiliaryrear heater 72, and anauxiliary separator 73. Theauxiliary turbine 71 is mounted between theauxiliary radiator 6 and the auxiliaryrear heater 72. The auxiliaryrear heater 72 is located between theauxiliary turbine 71 and theauxiliary separator 73. Theauxiliary turbine 71 is used to expand the second gaseous oxygen and to reduce the pressure and the temperature of the second gaseous oxygen, converting the second gaseous oxygen into a mixture of low temperature/low pressure liquid oxygen (hereinafter referred to as “first liquid oxygen”) and low/temperature/low pressure gaseous oxygen (hereinafter referred to as “the third gaseous oxygen”). The auxiliaryrear heater 72 can utilize the heat Q4 obtained from ordinary industrial waste heat to heat the first liquid oxygen and the third gaseous oxygen at a constant pressure, converting the first liquid oxygen into normal temperature/low pressure liquid oxygen (hereinafter referred to as “second liquid oxygen”) and converting the third gaseous oxygen into normal temperature/low pressure gaseous oxygen (hereinafter referred to as “fourth gaseous oxygen”). Theauxiliary separator 73 is connected to the auxiliaryrear heater 72 and the fuel cell P. Furthermore, the auxiliaryrear heater 72 is located between theauxiliary turbine 71 and theauxiliary separator 73. Theauxiliary separator 73 directs the second liquid oxygen into a storage unit (not shown) for storage purposes and directs the fourth gaseous oxygen into the cathodic passageway of the fuel cell P. Note that when the second gaseous oxygen enters theauxiliary turbine 71, theauxiliary turbine 71 outputs shaft power to drive a heat machine (not shown). - In this embodiment, the
auxiliary turbine 71 converts the second gaseous oxygen having a pressure of 20 atm and having a temperature of 300K into the first liquid oxygen and the third gaseous oxygen both having a pressure of 0.1 atm and having a temperature of 66K. The auxiliaryrear heater 72 heats the first liquid oxygen at a constant pressure to convert the first liquid oxygen into the second liquid oxygen having a pressure of 0.1 atm and having a temperature of 300K. Also, the auxiliaryrear heater 72 heats the third gaseous oxygen at a constant pressure to convert the third gaseous oxygen into the fourth gaseous oxygen having a pressure of 0.1 atm and having a temperature of 300K. - In addition to providing the operation and effect of the first embodiment, the second embodiment of the hydrogen producing device according to the present invention further produces normal temperature/low pressure liquid oxygen and further saves the energy consumed by the
middle heater 22. Furthermore, theelectrolyser 3 is activated by the fuel cell P in the second embodiment. -
FIG. 4 shows a third embodiment of a hydrogen producing apparatus according to the present invention. Compared to the second embodiment, the convertingunit 5 in the third embodiment is connected to afirst heat machine 8 a, and the auxiliary convertingunit 7 is connected to asecond heat machine 8 b. - In this embodiment, more than one
front heater 21, more than oneradiator 4, and more than oneauxiliary radiator 6 are used. Specifically, a firstfront heater 21 a and a secondfront heater 21 b are mounted between thepump 1 and themiddle heater 22. The firstfront heater 21 a is connected to thepump 1, and the secondfront heater 21 b is connected to themiddle heater 22. Fourradiators 4 are used in this embodiment. Specifically, first, second, third, andfourth radiators first output 32 of theelectrolyser 3. Thefourth radiator 4 d is connected to theturbine 51. Twoauxiliary radiators 6 are used in this embodiment. Specifically, first and secondauxiliary radiators 6 are connected in sequence to thesecond output 33 of theelectrolyser 3. The secondauxiliary radiator 6 is connected to theauxiliary turbine 71. - Note that the first
front heater 21 a is connected to thesecond radiator 4 b and the secondauxiliary radiator 6 b and that the secondfront heater 21 b is connected to thefirst radiator 4 a and the firstauxiliary radiator 6 a. By such an arrangement, the heat of first gaseous hydrogen and the first gaseous oxygen can be discharged in a multi-level manner, such that the first and secondfront heaters fourth radiator 4 d is connected to the auxiliaryrear heater 72 of the auxiliary convertingunit 7, such that the heat released during the constant-pressure heating procedure of the first gaseous hydrogen can be utilized to heat the first liquid oxygen and the third gaseous oxygen. Thus, the energy consumed by the auxiliaryrear heater 72 can be saved. - The
first heat machine 8 a is connected to theturbine 51 of the convertingunit 5, such that the shaft work outputted by theturbine 51 drives thefirst heat machine 8 a. Thus, thefirst heat machine 8 a can supply power to any member or any place. Specifically, thefirst heat machine 8 a includes afirst compressor 81 a, afirst evaporator 82 a, afirst steam turbine 83 a, and afirst condenser 84 a. Thefirst compressor 81 a, thefirst evaporator 82 a, thefirst steam turbine 83 a, and thefirst condenser 84 a are connected with each other in sequence by a piping filled with a first working fluid. Thefirst compressor 81 a is connected to theturbine 51. Thus, the shaft work outputted by theturbine 51 can drive thefirst compressor 81 a to compress the first working fluid so that the first working fluid can undergo a first power cycle to cause thefirst steam turbine 83 a to output shaft work W1. Note that thefirst condenser 84 a is connected to the secondfront heater 21 b in this embodiment, so that the low-quality sensible heat of the first working fluid can be discharged to the secondfront heater 21 b, saving the energy consumed by themiddle heater 22. - The
second heat machine 8 b is connected to theauxiliary turbine 71 of the auxiliary convertingunit 7. Thus, the shaft work outputted by theauxiliary turbine 71 can drive thesecond heat machine 8 b to provide power to any member or any place. Specifically, thesecond heat machine 8 b includes asecond compressor 81 b, asecond evaporator 82 b, asecond steam turbine 83 b, and asecond condenser 84 b. Thesecond compressor 81 b, thesecond evaporator 82 b, thesecond steam turbine 83 b, and thesecond condenser 84 b are connected with each other in sequence by a piping filled with a second working fluid. Thesecond compressor 81 b is connected to theauxiliary turbine 71. Thus, the shaft work outputted by theauxiliary turbine 71 can drive thesecond compressor 81 b to compress the second working fluid so that the second working fluid can undergo a second power cycle to cause thesecond steam turbine 83 b to output shaft work W2. - Note that the
second evaporator 82 b is connected to thethird radiator 4 c to receive the heat discharged by thethird radiator 4 c, effectively saving the energy supplied to thesecond heat machine 8 b. Of more importance, thesecond condenser 84 b is connected to the firstfront heater 21 a, so that the low-quality sensible heat of the second working fluid can be discharged to the firstfront heater 21 a, significantly saving the energy consumed by themiddle heater 22. - In addition to providing the operation and effect of the second embodiment, the third embodiment of the hydrogen producing device according to the present invention utilizes the shaft work outputted by the
turbine 51 and theauxiliary turbine 71 to drive the first andsecond heat machines second heat machines front heaters middle heater 22. - Conclusively, less energy is required to operate the hydrogen producing apparatus according to the present invention, because the energy required for converting normal temperature/normal pressure liquid water into high temperature/high pressure liquid water is much less than that required for converting normal temperature/normal pressure gaseous hydrogen into high temperature/high pressure gaseous hydrogen. Furthermore, the hydrogen producing apparatus according to the present invention can produce liquid hydrogen and liquid oxygen at the same time. Thus, the hydrogen producing apparatus according to the present invention effectively saves energy and provides enhanced utility.
- Thus since the invention disclosed herein may be embodied in other specific forms without departing from the spirit or general characteristics thereof, some of which forms have been indicated, the embodiments described herein are to be considered in all respects illustrative and not restrictive. The scope of the invention is to be indicated by the appended claims, rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are intended to be embraced therein.
Claims (11)
1. A hydrogen producing apparatus comprising:
a pump;
a heating assembly including at least one front heater, a middle heater, and a solar heater, with said at least one front heater connected to the pump, with the middle heater located between said at least one front heater and the solar heater;
an electrolyser connected to the solar heater;
at least one radiator connected to the electrolyser and said at least one front heater, with the electrolyser located between the solar heater and said at least one radiator; and
a converting unit connected to said at least one radiator.
2. The hydrogen producing apparatus as claimed in claim 1 , with the converting unit including a turbine and a rear heater, with the turbine located between said at least one radiator and the rear heater.
3. The hydrogen producing apparatus as claimed in claim 2 , with the converting unit further including a separator, with the separator connected to the rear heater, with the rear heater located between the turbine and the separator.
4. The hydrogen producing apparatus as claimed in claim 2 , with the turbine connected to a first heat machine.
5. The hydrogen producing apparatus as claimed in claim 4 , with the first heat machine including a first condenser, with the first condenser connected to said at least one front heater.
6. The hydrogen producing apparatus as claimed in claim 1 , with the electrolyser including an input, a first output, and a second output, with the input connected to the solar heater, with the first output connected to said at least one radiator, with the second output connected to at least one auxiliary radiator, with said at least one auxiliary radiator connected to said at least one front heater.
7. The hydrogen producing apparatus as claimed in claim 6 , further comprising: an auxiliary converting unit, with said at least one auxiliary radiator located between the auxiliary converting unit and the electrolyser.
8. The hydrogen producing apparatus as claimed in claim 7 , with the auxiliary converting unit including an auxiliary turbine, an auxiliary rear heater, and an auxiliary separator, with the auxiliary turbine located between said at least one auxiliary radiator and the auxiliary rear heater, with the auxiliary rear heater located between the auxiliary turbine and the auxiliary separator, with the auxiliary turbine connected to a second heat machine.
9. The hydrogen producing apparatus as claimed in claim 8 , with the second heat machine including a second condenser, with the second condenser connected to said at least one front heater.
10. The hydrogen producing apparatus as claimed in claim 8 , with said at least one radiator including a plurality of radiators, with one of the plurality of radiators connected to the auxiliary rear heater.
11. The hydrogen producing apparatus as claimed in claim 8 , with said at least one radiator including a plurality of radiators, with the second heat machine further including a second evaporator, with the second evaporator connected to one of the plurality of radiators.
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TW100122048A TW201300575A (en) | 2011-06-23 | 2011-06-23 | Hydrogen production apparatus |
TW100122048 | 2011-06-23 |
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US20080155985A1 (en) * | 1997-12-23 | 2008-07-03 | Gaudencio Aquino Labrador | Heat Energy Recapture And Recycle And Its New Applications |
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JP5403198B2 (en) * | 2005-06-03 | 2014-01-29 | 株式会社Gsユアサ | Hydrogen production apparatus, fuel cell power generation apparatus, electric vehicle, submarine, and hydrogen supply system using the same |
TWM346681U (en) * | 2008-08-05 | 2008-12-11 | wen-zhang Lin | Energy-generation device |
US9415363B2 (en) * | 2009-02-20 | 2016-08-16 | Marine Power Products Corporation | Method and apparatus for efficient on-demand production of H2 and O2 from water using waste heat and environmentally safe metals |
CN101608316B (en) * | 2009-07-27 | 2011-09-07 | 新奥科技发展有限公司 | Device for producing hydrogen through decomposing water |
TWM389121U (en) * | 2010-02-11 | 2010-09-21 | Hsu-Liang Yen | Solar hydrogen generator |
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