US20120282396A1

US20120282396A1 - Opaquely colored, infra-red plastics molding composition and methods of making the opaquely colored, infra-red plastics molding compostion

Info

Publication number: US20120282396A1
Application number: US13/422,274
Authority: US
Inventors: Klaus Schultes; Ernst Becker; Ursula Golchert; Elisabeth Clamer
Original assignee: Evonik Roehm GmbH
Current assignee: Evonik Roehm GmbH
Priority date: 2004-12-01
Filing date: 2012-03-16
Publication date: 2012-11-08
Also published as: SG190641A1; CN101040000A; US20090176928A1; SG132839A1; KR100875050B1; RU2357985C2; US8378021B2; CA2584660A1; TWI374905B; RU2007124488A; SG157396A1; EP1817375A1; BRPI0516664A; DE102004058083A1; HK1109163A1; TW200628526A; KR20070110259A; CN100564442C; MX2007005726A; WO2006058584A1

Abstract

The invention relates to subduedly colored (brown, gray, black, green), infrared reflecting PMMA compounds which can be applied to other plastic compounds as an IR barrier layer

Description

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. application Ser. No. 11/720,653 filed Jun. 1, 2007, which is a National Stage of PCT/EP05/11408 filed Oct. 25, 2005 and claims the benefit of DE 10 2004 058 083.9 filed Dec. 1, 2004.

BACKGROUND OF THE INVENTION

1. Field of the Invention
The invention relates to opaquely colored, infrared-reflective poly(meth)acrylate molding compositions which can be applied as IR-barrier layer to further plastics moldings.
2. Prior Art
Because PMMA has very good properties, the corresponding molding compositions are, inter alia, processed to give coextruded layers, or processed as outer layers of in-mould-coated parts. These layers serve as outer layer inter alia of foils, of sheets, of profiles and of pipes, of which the main component or backing layer is composed to some extent of other plastics. These plastics, e.g. PVC, polystyrene, polycarbonate, ABS and ASA, have further important properties, such as impact resistance and/or low price.
Examples of applications for these coextrudates or in-mould-coated articles are construction applications, such as drainpipes and window frames; automobile applications, such as roof modules, external and internal protective coverings (panels), spoilers and mirror housings; household and sports applications, e.g. protective coverings on tools, external panels for boats and ski foils.
It is known that opaquely colored poly(meth)acrylate (PMMA) molding compositions can be used for weathering-protection of plastics moldings composed of, for example, polyvinyl chloride (PVC).
The coated plastics molding is then provided with a colorant such as TiO₂, which reflects the IR radiation at the boundary layer of the two plastics moldings and thus prevents excessive heating of the article.
DE 27 19 170 (Dynamit Nobel) describes a process for protection of PVC layers from the effects of sunlight via a layer which has been durably applied to the PVC layer and which has been equipped not only with UV stabilizers but also with IR reflectors. The IR reflectors used comprise bleaching chromate molybdate red, molybdate orange, chromium oxide green antimony sulfide, cadmium sulfoselenide, cadmium sulfide, anthraquinone black pigment, anthraquinone dark blue pigment, monoazo pigment or phthalocyanines. Some of these pigments are no longer approved. A PMMA not specified in any further detail is described as material for the outer layer. DE 26 05 325 (Dynamit Nobel) likewise describes a process for protection of PVC surfaces, and the protective layer applied is colored sufficiently opaquely to achieve maximum reflectance in the IR region and minimum permeability in the UV region. The objective is achieved via the use of at least one IR-reflective black pigment or IR-reflective color pigment. For the darker color pigments, no predominantly IR-absorptive pigments are used. The pigment used in the examples comprises titanium dioxide or anthraquinone black in combination with a UV absorber.
WO 00/24817 (Ferro) describes corundum-hematite structures into which oxides of aluminum, of antimony, of bismuth, of boron, of chromium, of cobalt, of gallium, of indium, of iron, of lanthanum, of lithium, of magnesium, of manganese, of molybdenum, of neodymium, of nickel, of niobium, of silicon, or of tin have been bound.

OBJECT

The desire for dark-colored plastic moldings for outdoor applications requires solution of some problems:

- the plastics molding must be weather-resistant—irrespective of the coloring
- there must be good and durable adhesion between outer layer and plastics molding to be coated
- heating of the plastics moldings via direct sunlight may not exceed a permissible extent. The amount of heating may not become so great that the article expands unacceptably and temperatures above the glass transition temperature of the molding are reached. By way of example, this can cause irreversible warping of a window frame and prevent its subsequent opening
- the color pigments used must themselves likewise be weathering-resistant, and also toxicologically non-hazardous and inexpensive.

Further objects achieved by the inventive formulation are:
the colored molding compositions are to have good processibility
the formulation is to be stable at the processing temperatures.

BRIEF SUMMARY OF INVENTION

If various infrared-reflective, inorganic color pigments are used in a PMMA molding composition, these molding compositions can be used to produce dark-colored plastics moldings, and other plastics moldings can be coated with the abovementioned PMMA molding compositions, these having a markedly lower heating rate on insolation than moldings which are composed of conventionally dark-colored PMMA or have been coated with the same.
It has now been found that use of pigments of the following classes as described in Table 1

TABLE 1

Pigments that do not invoke excessive heating in sunlight
in plastic moldings.

CAS Number	C.I. Name	C.I. Number	Chemical name

68186-85-6	C.I. Pigment	C.I. 77377	Cobalt titanite
	Green 50		green spinel
68909 79 5	C.I. Pigment	C.I. 77288	Chromium oxide
	Green 17
109414-04-2	C.I. Pigment		Chromium iron
	Brown 29		oxide
68187-09-7	C.I. Pigment	C.I. 77501	Iron chromite
	Brown 35		brown spinel
71631-15-7	C.I. Pigment	C.I. 77504	Nickel iron chromite
	Black 30		black spinel

- C.I. nomenclature according to Colour Index, The Society of Dyers and Colourists (SDC)
  in PMMA molding compositions permits preparation of opaquely dark-colored molding compositions without excessive heating in sunlight of the plastics moldings equipped therewith or of moldings produced with these materials. The property “dark” can be defined via the L* value according to DIN 6174 (01/1979): Farbmetrische Bestimmung von Farbabständen bei Körperfarben nach der CieLab-formel [Colourimetric determination of colour differences for mass tone colours by the CieLab formula]. The CieLab L* value for the opaquely dark-colored molding compositions is below 51, preferably below 41 and very particularly preferably below 31.

BRIEF DESCRIPTION OF THE SEVERAL DRAWINGS

FIG. 1 depicts spectral graphs of reflectance [%] versus wavelength [mm] for Comparison 1, Comparison 2 and Inventive Example 1.

FIG. 2 depicts spectral graphs of reflectance [%] versus wavelength [mm] for Comparison 3, Comparison 4 and Inventive Example 4.

FIG. 3 depicts spectral graphs of reflectance [%] versus wavelength [mm], without white background, for Comparison 1, Comparison 2 and Inventive Example 1.

DETAILED DESCRIPTION OF THE INVENTION

The amounts of the pigments or of their mixtures incorporated into the molding compositions are from 0.05 to 5.0% by weight preferably from 0.075 to 3.0% by weight and very particularly preferably from 0.1 to 2% by weight.
Further colorants which are suitable for coloring of PMMA molding compositions may be used additionally to vary the colour. These colorants may be either IR-reflective—e.g. titanium dioxide—or else non-IR-reflective. The proportion of these additional colorants may be from 0 to 3.0%, preferably from 0 to 2.5% by weight and particularly preferably from 0 to 2.0% by weight, based on the molding composition.
Dark colour shades are

- brown
- gray
- green and
- black
  and mixed shades are also possible.

EXAMPLES

The molding composition Plexiglas® 7N is used as PMMA component. It is available commercially from Rohm GmbH & Co. KG.
The molding compositions of the present invention comprise poly(meth)acrylates. The expression (meth)acrylates encompasses methacrylates and acrylates and also mixtures of the two.
Poly(meth)acrylates are known to the person skilled in the art. These polymers are generally obtained via free-radical polymerization of mixtures which comprise (meth)acrylates.
These monomers are well known. Among these monomers are, inter alia, (meth)acrylates which derive from saturated alcohols, e.g. methyl (meth)acrylate, ethyl (meth)acrylate, propyl (meth)acrylate, n-butyl (meth)acrylate, tert-butyl (meth)acrylate, pentyl (meth)acrylate and 2-ethylhexyl (meth)acrylate; (meth)acrylates which derive from unsaturated alcohols, e.g. oleyl (meth)acrylate, 2-propynyl (meth)acrylate, allyl (meth)acrylate, vinyl (meth)acrylate; aryl (meth)acrylates, such as benzyl (meth)acrylate or phenyl (meth)acrylate, where each of the aryl radicals may be unsubstituted or have up to four substituents; cycloalkyl (meth)acrylates, such as 3-vinylcyclohexyl (meth)acrylate, bornyl (meth)acrylate, hydroxyalkyl (meth)acrylates, such as 3-hydroxypropyl (meth)acrylate,

3,4-dihydroxybutyl (meth)acrylate,
2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate;
glycol di(meth)acrylates, such as 1,4-butanediol di(meth)acrylate,
(meth)acrylates of ether alcohols, such as tetrahydrofurfuryl (meth)acrylate, vinyloxyethoxyethyl (meth)acrylate; amides and nitriles of (meth)acrylic acid, such as N-(3-dimethylaminopropyl)(meth)acrylamide,
N-(diethylphosphono)(meth)acrylamide,
1-methacryloylamido-2-methyl-2-propanol;

sulfur-containing methacrylates, such as ethylsulfinylethyl (meth)acrylate,
4-thiocyanatobutyl (meth)acrylate, ethylsulfonylethyl (meth)acrylate, thiocyanatomethyl (meth)acrylate, methylsulfinylmethyl (meth)acrylate, bis ((meth)acryloyloxyethyl)sulfide; multifunctional (meth)acrylates, such as trimethyloylpropane tri(meth)acrylate.
The formulations to be polymerized may also comprise, alongside the (meth)acrylates set out above, further unsaturated monomers copolymerizable with the abovementioned (meth)acrylates. The amount generally used of these compounds is from 0 to 50% by weight, preferably from 0 to 40% by weight and particularly preferably from 0 to 20% by weight, based on the weight of the monomers, and the comonomers here may be used individually or in the form of a mixture.
Among these are, inter alia, 1-alkenes, such a 1-hexene, 1-heptene; branched alkenes, such as vinylcyclohexane, 3,3-dimethyl-1-propene, 3-methyl-1-diisobutylene, 4-methyl-1-pentene;
acrylonitrile; vinyl esters, such as vinyl acetate; styrene, substituted styrenes having one alkyl substituent in the side chain, e.g. α-methylstyrene and α-ethylstyrene, substituted styrenes having one alkyl substituent on the ring, e.g. vinyltoluene and p-methylstyrene, halogenated styrenes, such as monochlorostyrenes, dichlorostyrenes, tribromostyrenes, and tetrabromostyrenes; heterocyclic vinyl compounds, such as 2-vinylpyridine, 3-vinylpyridine, 2-methyl-5-vinylpyridine, 3-ethyl-4-vinylpyridine, 2,3-dimethyl-5-vinylpyridine, vinylpyrimidine, vinylpiperidine, 9-vinylcarbazole, 3-vinylcarbazole, 4-vinylcarbazole, 1-vinylimidazole, 2-methyl-1-vinylimidazole, N-vinylpyrrolidone, 2-vinylpyrrolidone, N-vinylpyrrolidine, 3-vinylpyrrolidine, N-vinylcaprolactam, N-vinylbutyrolactam, vinyloxolane, vinylfuran, vinylthiophene, vinylthiolane, vinylthiazoles, and hydrogenated vinylthiazoles, vinyloxazoles and hydrogenated vinyloxazoles;
vinyl and isoprenyl ethers;
maleic acid derivatives, such as maleic anhydride, methylmaleic anhydride, maleimide, methylmaleimide; and dienes, such as divinylbenzene.
The polymerization is generally initiated by known free-radical initiators. Examples of preferred initiators are the azo initiators well known to persons skilled in the art, e.g. AIBN and 1,1-azobis(cyclohexanecarbonitrile), and also peroxy compounds, such as methyl ethyl ketone peroxide, acetylacetone peroxide, dilauryl peroxide, tert-butyl per-2-ethylhexanoate, ketone peroxide, methyl isobutyl ketone peroxide, cyclohexanone peroxide, diberizoyl peroxide, tert-butyl peroxybenzoate, tert-butylperoxy isopropyl carbonate, 2,5-bis(2-ethylhexanoylperoxy)-2,5-dimethylhexane, tert-butylperoxy 2-ethylhexanoate, tert-butylperoxy 3,5,5-trimethylhexanoate, dicumyl peroxide, 1,1-bis(tert-butylperoxy)cyclohexane, 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane, cumyl hydroperoxide, tert-butyl hydroperoxide, bis(4-tert-butylcyclohexyl) peroxydicarbonate, mixtures of two or more of the abovementioned compounds with one another, and also mixtures of the abovementioned compounds with compounds not mentioned which can likewise form free radicals.
The amount often used of these compounds is from 0.1 to 10% by weight, preferably from 0.5 to 3% by weight, based on the total weight of the monomers.
Preferred poly(meth)acrylates are obtainable via polymerization of mixtures which comprise at least 20% by weight, in particular at least 60% by weight and particularly preferably at least 80% by weight, of methyl methacrylate, based in each case on the total weight of the monomers to be polymerized.
Use may be made here of various poly(meth)acrylates which differ, for example, in molecular weight or in monomer formulation.
The molding compositions may moreover comprise further polymers in order to modify properties. Among these are, inter alia, polyacrylonitriles, polystyrenes, polyethers, polyesters, polycarbonates and polyvinyl chlorides. These polymers may be used individually or in the form of a mixture, and it is also possible here to add, to the molding compositions, copolymers which are derivable from the abovementioned polymers. Among these are, in particular, styrene-acrylonitrile polymers (SANs), the amount of which added to the molding compositions is preferably up to 45% by weight.
Particularly preferred styrene-acrylonitrile polymers may be obtained via polymerization of mixtures composed of
from 70 to 92% by weight of styrene
from 8 to 30% by weight of acrylonitrile
from 0 to 22% by weight of further comonomers, based in each case on the total weight of the monomers to be polymerized.
In particular embodiments, the proportion of the poly(meth)acrylates is at least 20% by weight, preferably at least 60% by weight and particularly preferably at least 80% by weight.
Particularly preferred molding compositions of type are available commercially with the trade mark PLEXIGLAS® from Rohm GmbH & Co. KG.
The weight-average molecular weight Mw of the homo- and/or copolymers to be used according to the invention as matrix polymers can vary widely, the molecular weight usually being matched to the intended use and the method of processing of the molding composition.
However, it is generally in the range from 20 000 to 1 000 000 g/mol, preferably from 50 000 to 500 000 g/mol and particularly preferably from 80 000 to 300 000 g/mol, with no intended resultant restriction.
The following substances were use as colorants:

- Cromophtal Brown 5R, Ciba Specialty Chemicals
- Sandoplast Red Violet R, Clariant
- Thermoplast Blue 684, BASF
- Ultramarine Blue 31, Nubiola
- Bayferrox 180 M, Bayer
- Bayferrox 645 T, Bayer
- Microlith Green GA, Ciba speciality Chemicals
- Pigment black FW1, Degussa
- PK 24-10204, Ferro
- PK 10456, Ferro
- Titanium dioxide CL 2220, Kronos

Coloring of Molding Compositions

Colorants and molding compositions were homogenized by roll-milling. The formulations for the individual examples have been documented in Table 2. A Plexiglas® Plexiglas GS White 003 sheet (40 mm*21 mm) of thickness 3 mm was also used (see testing of molding compositions). 1.5% of titanium dioxide C1 2220 is present as colorant, IR-reflective pigment in the cast sheet composed of PMMA.
PLEXIGLAS® 7N provides the residual amounts to give 100% by weight.

TABLE 2

Formulations for Examples and Comparative Examples

	Comp.	Comp.	Comp.	Comp.	Inv.	Inv.	Inv.	Inv.
Formulation	Ex. 1	Ex. 2	Ex. 3	Ex. 4	Ex. 1	Ex. 2	Ex. 3	Ex. 4

Chromophtal Brown 5R	0.90%
Sandoplast Red Violet R	0.17%
Thermoplast Blue 684	0.10%
Ultramarine Blue 31		0.65%
Bayferrox 180 M		0.33%
Bayferrox 645 T		0.18%
Microlith Green GA		0.10%
Pigment black FW1			1.00%
Thermoplast Black X70				0.60%
Printex 104 V				0.09%
PK 24-10204					1%	0.80%	9.60%
PK 10456								1%

Percentages in Table 1 are weight percentages, with ingredients that are present in each individual composition having weight percentages associated with the ingredients. The total weight percentage of each composition is 100 wt. %, with the remaining ingredient, Plexiglas ® 7N, being present in an amount such that the total weight percentages of all ingredients add up to 100 wt. %.

Testing of Molding Compositions

A press was used to produce pressed plaques of thickness 0.5 mm from the colored molding compositions. The corresponding test specimens were tested by the following methods:

Heating behavior: The specimen of diameter 50 mm and thickness 0.5 mm was placed on a Rohacell® cube of edge length 50 mm. A thermocouple of diameter of 0.5 mm was fixed under the centre of the specimen with Tesa® film. A Plexiglas® GS White 003 sheet (40 mm*21 mm) had been impressed into the Rohacell®. The specimen with thermocouple was secured onto this using double-sided-adhesive Tesa® Fotostrip. The specimen was irradiated using a 60 W incandescent lamp regulated with 220 V (AC voltage stabilizer). Vertical distance between lower edge of glass bulb and specimen 50 mm. The temperature was read off after 20 minutes of irradiation. Heating was measured by a method based on the standard ASTM D4803-97.
Light reflectance: Spectra measured on Perkin Elmer Lambda 19. For this, the specimens were measured with and sometimes without the Plexiglas GS White 003 sheet of thickness 3 mm.

The results for heating behavior of the test specimens can be seen in Table 3.

TABLE 3

Heating behavior of Examples and Comparative Examples

	Temperature after
	irradiation. Measurement using
	NiCr—Ni thermocouple of diameter
	0.5 mm with Testo 950 indicator

	L* value	a* value	b* value	D65/10;	D65/10;	D65/10;
	D65/10;	D65/10;	D65/10;	reflection;	reflection;	reflection;
	reflection;	reflection;	reflection;	heating;	heating;	heating;
	heating;	heating;	heating;	CieLab	CieLab	CieLab
SPECIMEN	CieLab	CieLab	CieLab	[° C./20 min]	[° C.]	[° C.]

Comparison 1 (brown,	30.1	3.3	4.1	31.0	55.0	24.0
organic, IR-transparent)
Comparison 2 (brown,	28.2	3.4	1.9	35.1	57.3	22.2
inorganic, IR-absorbent)
Inventive example 1	28.3	4.5	2.2	29.4	53.3	23.9
(brown)
Inventive example 2	27.2	3.9	1.8	32.3	56.0	23.7
(brown)
Inventive example 3	27.7	4.0	1.9	31.7	55.6	23.9
(brown)
Comparison 3 (black,	24.3	0.0	−0.8	43.8	67.7	23.9
inorganic, IR-absorbent)
Comparison 4 (black,	24.0	−0.1	−0.9	42.8	66.8	24.0
inorganic, IR-absorbent)
Example 4 (black)	26.1	1.3	0.6	37.4	61.4	24.0

The reflectance spectra can be seen in Table 3 (brown colours with Plexiglas GS White 003 sheet of thickness 3 mm), Table 4 (black colours with Plexiglas GS White 003 sheet of thickness 3 mm), and Table 5 (brown colours without Plexiglas GS White 003 sheet of thickness 3 mm).
The examples clearly reveal the improvements achieved via the invention described here:

- Table 2 shows that the heating rate for the inventive brown pressed plaques (inventive Examples 1, 2, 3) is better than comparison 2 (brown pressed plaques produced using an inorganically IR-absorbent colorant) and comparable with comparison 1 (colorant used here being IR-transparent—IR reflection taking place at the white Plexiglas GS sheet). From the inventive black pressed plaques (inventive Example 4), it can also be seen that the heating rate here is clearly better (lower) than for comparisons 3 and 4.
- Table 3 and 4 clearly show that, based on the respective shade, the inventive pressed plaques clearly reflect IR light (wavelength >700 mm) better than the comparisons. Comparison 1 is an exception here—however, the reflection here takes place at the white Plexiglas® GS sheet.
- Table 5 clearly shows that even without the underlying Plexiglas® GS sheet, the inventive brown pressed plaques clearly reflect the IR light better than the comparisons.

Claims

1-9. (canceled)

10. An IR-reflective opaquely dark-colored molding composition comprising:

(a) from 95 to 99.5% by weight, based on the total weight of the composition, of polymethyl (meth)acrylate; and

(b) from 5 to 0.5% by weight, based on the total weight of the composition, of an IR-reflective pigment selected from the group consisting of cobalt titanite green spinel having the CAS Number 68186-85-6, chromium oxide having the CAS Number 68909-79-5, iron chromite brown spinel having the CAS Number 68187-09-7, chromium iron oxide having the CAS Number 109414-04-2, nickel iron chromite black spinel having the CAS Number 71631-15-7, and combinations thereof,

wherein the dark-colored molding composition, when irradiated with a 60 W incandescent bulb with a voltage of 220 V, at a distance of 50 mm from the dark-colored molding composition, for 20 minutes, shows a temperature increase of 50° C. or less, and wherein the dark colored molding composition has a Cielab L* value below 41.

11. The molding composition of claim 10, comprising the IR-reflective pigment cobalt titanite green spinel having the CAS Number 68186-85-6.

12. The molding composition of claim 10, comprising the IR-reflective pigment chromium oxide having the CAS Number 1308-38-9.

13. The molding composition of claim 10, comprising the IR-reflective pigment iron chromite brown spinel having the CAS Number 68187-09-7.

14. The molding composition of claim 10, comprising the IR-reflective pigment chromium iron oxide having the CAS Number 109414-04-2.

15. The molding composition of claim 10, comprising the IR-reflective pigment nickel iron chromite black spinel having the CAS Number 71631-15-7.

16. A method of producing a dark-colored plastic molding, the method comprising

coating a plastic molding with one or more layers of the dark-colored molding composition according to claim 10.