US20120055078A1

US20120055078A1 - Low-carbon high-hydrogen fuels

Info

Publication number: US20120055078A1
Application number: US12/807,534
Authority: US
Inventors: Xiqi Ma
Original assignee: BIOMAGNETICS DIAGNOSTICS CORP
Current assignee: BIOMAGNETICS DIAGNOSTICS CORP
Priority date: 2010-09-08
Filing date: 2010-09-08
Publication date: 2012-03-08
Also published as: WO2012033528A1

Abstract

A low-carbon high-hydrogen fuel: which comprises a combination of additives, base oil, diesel fuel.

Description

FIELD OF THE INVENTION

The present invention relates to a low-carbon high-hydrogen fuel: which comprises a combination of additives, base oil, diesel fuel.

BACKGROUND OF THE INVENTION

China's ability to provide for its own needs is limited by the fact that its proven oil reserves are small in relation to its consumption. Since 2008, the increased domestic demand and the global soaring oil prices made this situation worse. The severe shortage of global oil, gas, diesel, and fuel supply, especially these low-carbon fuel, diesel, fuel oil. In order to meet the growing economies, and to solve the problem of diesel shortage, many countries introduced energy policies to encourage low-carbon, energy conservation and alternative energy fuels development. Methanol, ethanol type gasoline, diesel, fuel oil are some of the most promising, alternative energy sources.
In 2002, a study was begun to study alcohol-based class diesel blended fuel. During both laboratory and vehicle testing, a number of problems were encountered—difference in the solubility with diesel oil, low horsepower, easily emulsified, and troubles in maintaining the original structure of a vehicle, etc. This is also the most common problem encountered by most international research institutions, enterprises and individuals in the studying and development of such type of fuels. The key to address these problems is the core technology in formulating the oil additive.

SUMMARY OF THE INVENTION

The present invention relates to a low-carbon, high hydrogen fuel which comprises a combination of additives, base oil and diesel fuel.
It is an object of the present invention for the additives to comprise: composition #one comprising: alkene acid 18: 50%-75%; refined naphthenic acid: 5%-20%, ammonia: 5%-20%, methanol: 15%-35%, ethanol: 5-20%, diethanolamine: 1-6%, alkylphenol ethoxylates: 2-10%, alcohol C-12: 1-5%.
It is an object of the present invention for the additives to further comprise composition #2, which comprises composition #one: 25%, alkyl Kenai: 10-20%, isobutyl alcohol: 15-65%, fatty acid methyl ester: 15-35%.
It is an object of the present invention for the additives to further comprise composition #3 which comprises: composition #1: 20%, oleic acid: 5-20%, dimethylbenzene(xylene): 10-25%, butylated hydroxytoluene: 3-18%, kerosene: 15-25%, fatty acid methyl ester: 10-25%.
It is an object of the present invention for the additives to comprise the combination of composition 1, 2, and 3.
It is an object of the present invention for the base oils to comprise the composition #1: 15%-35%, oleic acid: 5%-15%, fatty acid methyl ester: 20%-35%.
It is an object of the present invention for the base oil to comprise composition #2: 12-30%, composition #3: 10-25%, methanol: 15%-50%, ethanol: 8%-25%, biomass molasses solution: 5%-55%.
It is an object of the present invention for the low-carbon, high hydrogen fuel to comprise base oil: 25-50%, diesel oil: 40-60%, and composition #3: 10%-20%.
The present invention relates to a low-carbon, high-hydrogen diesel additive, and low-carbon, high-hydrogen hybrid fuel diesel.
The present invention relates solving the existing technical problems in the use of alcohol-based class diesel-higher corrosive characteristics, swelling, cold starting problems, slow speed post-heat treatment, water stratification, low heating value, power down, the tendency to cause wet stacking when a diesel engine is left idling for prolonged periods of time, difficult to start up etc.

DETAILED DESCRIPTION OF THE INVENTION

The present invention relates to a low-cost low-carbon, energy saving, low-emission low-carbon high-hydrogen “green” fuel additives. A number of substance materials described herein have the advantages of low-carbon, alternative oil, low emissions.
By continuously optimizing the ratio of raw materials, the finished product can be prepared by the following ration:
Composition #1: alkene acid 18: 50%-75%, refined napthenic acid: 5%-20%, ammonia: 5%-15%, methanol: 15%-35%, ethanol: 5-20%, diethanolamine: 1-6%, alkylphenol ethoxylates: 2-10%, alcohol C-12: 1-5%.
Composition #2: composition #1: 25%, alkyl Kenai: 10-20%, isobutyl alcohol: 15-65%, fatty acid methyl ester: 15-35%.
Composition #3: composition #1: 20%, oleic acid: 5-20%, dimethylbenzene(xylene): 10-25%, butylated hydroxytoluene: 3-18%, kerosene: 15-25%, fatty acid methyl ester: 10-25%.
The above low-carbon high-hydrogen diesel fuel additive formulation: is made by pouring the various raw materials into the mixing tank following the above order. When the proportion of each component material filling is complete, mixing the mixture, let it stand for about an hour, then the finished products is ready for use.
In an embodiment, the invention comprises blending a certain percentage of the additive in order to make the low-carbon high-hydrogen hybrid fuel base oil. It is formulated and prepared by mixing all materials by following each volume ratio:
Composition #1 additives 15-35%, oleic acid, 5-15%, 20-35% fatty acid methyl ester, does 15-30% composition #2. composition #3: 10-25%, 15-50% methanol, ethanol, 8-25%, 15-55% of biomass molasses solution.
Low-carbon, low-carbon high-hydrogen diesel fuel blend component preparation: low-carbon high-hydrogen blended diesel fuel base oil mixture: 25-50%, diesel: 40-60%, composition #3: 10-20%.
The present invention of low-carbon high-hydrogen diesel fuel additive is prepared by mixing raw materials described above. It is an effective solution to the problems of alcohol-based class diesel fuel-higher corrosive characteristic, swelling, cold starting problems, slow speed post-heat treatment, water stratification, low heating value, power down, the tendency to cause wet stacking when a diesel engine is left idling for prolonged periods of time, difficult to start up and other technical problems.
Using the low-carbon high-hydrogen diesel fuel additive and synthetic low-carbon high-hydrogen diesel hybrid fuels, the advantages are as followings:

(1) Clear and transparent in appearance, similar to petroleum diesel in color;
(2) The ration to diesel can be arbitrarily flexible
(3) Easy to use, no modifications needed to diesel vehicles engines, the pure diesel and the low-carbon high-hydrogen hybrid diesel fuels can be alternately used proportionally.
(4) As the additive amount is relatively reasonable, both laboratory and vehicle testing have shown that it helps fast start, and is conducive to the combustion engine. After running 500 km, the inspection show no sign of any engine combustion process plug nozzle phenomenon. After 1,500 kilometers, all components inside the piston-cylinder diesel engine appear smooth;
(5) The above vehicle test showed: its power, start of, fuel consumption is similar to this pure diesel fuel.
(6) Detected by the cleaner exhaust emissions, exhaust smoke and particulate emissions are 60% less than pure diesel fuel burn, zero emissions.
(7) Respectively, mixing -#, -10#, and diesel oil into the appropriate low-carbon high-hydrogen mixture of diesel fuel, after being storied into 0 C, −10 C, the mixture stays in a transparent liquid form; When this low-carbon high-hydrogen mixture of diesel fuel is being heated up to 60-70 C, it still keeps its transparent form. It shows a good weather ability, so it can perform well under both the low-temperature and high-temperature.
(8) Some sample of such low-carbon high-hydrogen hybrid fuel based diesel oil formulated in October 2008, still remains clear and transparent form today. This product could be mass-produced and stored in a large-scale storage up to one year.

In a preferred embodiment, the composition comprises 15% of composition #1, 5% oleic acid, 10% fatty acid methyl ether, 10% composition #2, 10% composition #3, 20% methanol, 8% ethanol and 22% biomass molasses solution.

Specific Implementations

More Examples of Implementations

Example of Implementation 1, Low-Carbon, High-Hydrogen Diesel Fuel Additive Composition #1 Preparation Synthesis

First pouring 50%-75% alkene acid 18, 5%-20% refined napthenic acid, 5%-15% ammonia, 15%-35% methanol, 5-20% ethanol, 1-6% diethanolamine, 2-10% alkylphenol ethoxylates, 1-5% alcohol C-12 into the mixing tank, stirring for about 10 minutes, then pumping the mixture into the finished product tank. Let it standing for about an hour, and then it is ready for use.

Example of Implementation 2, Low-Carbon High-Hydrogen Diesel Hybrid Fuel Composition #2 Preparation Synthesis

First pouring 25% composition #1, 10-20% alkyl Kenai, 15-65% isobutyl alcohol, 15-35% fatty acid methyl ester into the mixing tank, stirring for about 10 minutes, then transferring the mixture into the finished product tank, let it standing for about an hour, then it is ready for use.

Example of Implementation 3, Low-Carbon High-Hydrogen Diesel Hybrid Fuel Composition #3 Preparation Synthesis

Pumping 20% composition #1, 5-20% oleic acid, 10-25% xylene, 3-18% butylated hydroxytoluene, 15-25% kerosene, 10-25% fatty acid methyl ester into the mixing tank, then transferring the mixture into the finished product tank, let it standing for about an hour, and then it is ready for use.

Example of Implementation 4, Low-Carbon High-Hydrogen Diesel Fuel Blends Synthesis And the Proportion of Preparation

According to the following formula, the export pipeline monitored by digital control system pumps the low-carbon high-hydrogen hybrid fuel base oil, diesel fuel and low-carbon high-hydrogen diesel fuel additive from the respective tanks by flow ratio, into the mixing tank, a synthesis of the pump in the pipe then transfers to the product into the finished product tank (the installation system designed solely for the invention can be mass-produced). Then the product can be used directly after standing for six hours.
Low-carbon high-hydrogen diesel fuel blend base oil: 25%, diesel: 60%, composition #3: 15%.

Example of Implementation 5, A Low-Carbon High-Hydrogen-Diesel Fuel Blends Synthetic Preparation of Methods And Ratio

According to the following formula, the export pipeline monitored by the digital control system pumps the low-carbon high-hydrogen hybrid fuel base oil, diesel fuel and low-carbon high-hydrogen diesel fuel additive from the respective tanks by flow ratio, into the mixing tank, a synthesis of the pump in the pipe then transfers the product into the finished product tank (the installation system designed solely for the invention can be mass-produced). Then the product can be used directly after standing for six hours. Low-carbon high-hydrogen diesel fuel blend base oil: 45%, diesel: 40%, composition #3: 15%.
Implementation of Example 6: low-carbon high-hydrogen-diesel fuel blends synthesis and the proportion of preparation:
According to the following formula, the export pipeline monitored by the digital control system pumps the low-carbon high-hydrogen hybrid fuel base oil, diesel fuel and low-carbon high-hydrogen diesel fuel additive from the respective tanks by flow ration, into the mixing tank, a synthesis of the pump in the pipe then transfers the product into the finished product tank (the installation system designed solely for the invention can be mass-produced). Then the product can be used directly after standing for six hours. Low-carbon hydrogen diesel fuel blend base oil: 50%, diesel: 30%, composition #3t: 20%.
In General, all of the above described low-carbon high-hydrogen fuel is a mixture of the following materials by following a certain formula: Low-carbon high-hydrogen diesel fuel blend base oil: 25-50%, diesel: 40-60%, low-carbon high-hydrogen diesel fuel additive: 10-%-20%.

Claims

1. A low-carbon, high hydrogen fuel which comprises

additives,

base oil and

diesel fuel.

2. The fuel of claim 1 wherein said additives comprise:

a first composition comprising: alkene acid 18: 50%-75%; refined naphthenic acid: 5%-20%, ammonia: 5%-20%, methanol: 15%-35%, ethanol: 5-20%, diethanolamine: 1-6%, alkylphenol ethoxylates: 2-10%, alcohol C-12: 1-5%;

a second composition comprising: said first composition: 25%, alkyl Kenai: 10-20%, isobutyl alcohol: 15-65%, fatty acid methyl ester: 15-35%. and/or

a third composition which comprises: said first composition: 20%, oleic acid: 5-20%, dimethylbenzene(xylene): 10-25%, butylated hydroxytoluene: 3-18%, kerosene: 15-25%, fatty acid methyl ester: 10-25%.

3. The fuel of claim 1 wherein said base oil comprises:

comprise the composition comprising 15%-35%, of (alkene acid 18: 50%-75%; refined naphthenic acid: 5%-20%, ammonia: 5%-20%, methanol: 15%-35%, ethanol: 5-20%, diethanolamine: 1-6%, alkylphenol ethoxylates: 2-10%, alcohol C-12: 1-5%);

oleic acid: 5%-15%,

fatty acid methyl ester: 20%-35%.

4. The fuel of claim 1 wherein said base oil comprises:

12-30% of (a first composition comprising: alkene acid 18: 50%-75%; refined naphthenic acid: 5%-20%, ammonia: 5%-20%, methanol: 15%-35%, ethanol: 5-20%, diethanolamine: 1-6%, alkylphenol ethoxylates: 2-10%, alcohol C-12: 1-5%; and

a second composition comprising: said first composition: 25%, alkyl Kenai: 10-20%, isobutyl alcohol: 15-65%, fatty acid methyl ester: 15-35%.);

10-25% of ((said first composition: 20%, oleic acid: 5-20%, dimethylbenzene(xylene): 10-25%, butylated hydroxytoluene: 3-18%, kerosene: 15-25%, fatty acid methyl ester: 10-25%);

methanol: 15%-50%, ethanol: 8%-25%, biomass molasses solution: 5%-55%.

5. A low-carbon, high hydrogen fuel which comprises

25-50% of a base oil,

40-60% of diesel oil: and

10%-20% of (alkene acid 18: 50%-75%; refined naphthenic acid: 5%-20%, ammonia:

5%-20%, methanol: 15%-35%, ethanol: 5-20%, diethanolamine: 1-6%, alkylphenol ethoxylates: 2-10%, alcohol C-12: 1-5%;

oleic acid: 5-20%, dimethylbenzene(xylene): 10-25%, butylated hydroxytoluene: 3-18%, kerosene: 15-25%, fatty acid methyl ester: 10-25%.

6. A method of making a low-carbon, high hydrogen fuel additive comprising:

pouring a first composition comprising: alkene acid 18: 50%-75%; refined naphthenic acid: 5%-20%, ammonia: 5%-20%, methanol: 15%-35%, ethanol: 5-20%, diethanolamine: 1-6%, alkylphenol ethoxylates: 2-10%, alcohol C-12: 1-5%; a second composition comprising: said first composition: 25%, alkyl Kenai: 10-20%, isobutyl alcohol: 15-65%, fatty acid methyl ester: 15-35%. and a third composition which comprises: said first composition: 20%, oleic acid: 5-20%, dimethylbenzene(xylene): 10-25%, butylated hydroxytoluene: 3-18%, kerosene: 15-25%, fatty acid methyl ester: 10-25%. into a mixing tank;

mixing said compositions;

letting said composition stand for about an hour;

using finished product.

7. The method of claim 6 further comprising mixing said finished product with a base oil comprising said first composition in a ratio of 15-35%, oleic acid, 5-15%, 20-35% fatty acid methyl ester, 15-30% of said second composition and 10-25% of said third composition: 10-25%, 15-50% methanol, ethanol, 8-25%, 15-55% of biomass molasses solution.

8. The fuel of claim 1 wherein:

said fuel is clear and transparent in appearance.

9. The fuel of claim 1 wherein

said fuel requires no modifications to diesel vehicles engines, and pure diesel and said low-carbon high-hydrogen hybrid diesel fuel is used alternately and proportionally.

10. The fuel of claim 1 wherein said fuel is conducive to a combustion engine.

11. The fuel of claim 1 wherein said fuel is exhaust emissions, exhaust smoke and particulate emissions 60% less than pure diesel fuel burn, and has zero emissions.

12. The fuel of claim 1 wherein said fuel is mass-produced and stored in a large-scale storage up to one year.

13. A method for preparing a low-carbon, high-hydrogen diesel fuel additive comprising:

pouring 50%-75% alkene acid 18, 5%-20% refined napthenic acid, 5%-15% ammonia, 15%-35% methanol, 5-20% ethanol, 1-6% diethanolamine, 2-10% alkylphenol ethoxylates, 1-5% alcohol C-12 into a mixing tank,

stirring for about 10 minutes,

pumping said mixture into a finished product tank;

letting said finished product stand for about an hour,

and then said finished product is ready for use.

14. A method for preparing a low-carbon high-hydrogen diesel fuel additive comprising:

pouring 25% of alkene acid 18: 50%-75%; refined naphthenic acid: 5%-20%, ammonia: 5%-20%, methanol: 15%-35%, ethanol: 5-20%, diethanolamine: 1-6%, alkylphenol ethoxylates: 2-10%, alcohol C-12: 1-5%; 10-20% alkyl Kenai, 15-65% isobutyl alcohol, 15-35% fatty acid methyl ester into the mixing tank,

stirring said mixture for about 10 minutes,

transferring said mixture into a finished product tank;

letting it stand for about an hour,

and then said product is ready for use.

15. A method of preparing a low-carbon high hydrogen diesel fuel additive comprising:

pumping 20% of a composition comprising: (25% of alkene acid 18: 50%-75%; refined naphthenic acid: 5%-20%, ammonia: 5%-20%, methanol: 15%-35%, ethanol: 5-20%, diethanolamine: 1-6%, alkylphenol ethoxylates: 2-10%, alcohol C-12); 5-20% oleic acid, 10-25% xylene, 3-18% butylated hydroxytoluene, 15-25% kerosene, 10-25% fatty acid methyl ester into a mixing tank,

transferring said mixture into a finished product tank,

letting the mixture standing for about an hour,

and then said product is ready for use.

16. A low-carbon high-hydrogen diesel fuel blend comprising:

25% base oil:

60% diesel fuel:

15% (20% (alkene acid 18: 50%-75%; refined naphthenic acid: 5%-20%, ammonia: 5%-20%, methanol: 15%-35%, ethanol: 5-20%, diethanolamine: 1-6%, alkylphenol ethoxylates: 2-10%, alcohol C-12: 1-5%); oleic acid: 5-20%, dimethylbenzene(xylene): 10-25%, butylated hydroxytoluene: 3-18%, kerosene: 15-25%, fatty acid methyl ester: 10-25%).

17. A low-carbon high-hydrogen diesel fuel blend comprising:

45% base oil:

50% diesel fuel:

18. A low-carbon hydrogen diesel fuel blend comprising:

50% base oil:

30% diesel:

20%. (20% (alkene acid 18: 50%-75%; refined naphthenic acid: 5%-20%, ammonia: 5%-20%, methanol: 15%-35%, ethanol: 5-20%, diethanolamine: 1-6%, alkylphenol ethoxylates: 2-10%, alcohol C-12: 1-5%); oleic acid: 5-20%, dimethylbenzene(xylene): 10-25%, butylated hydroxytoluene: 3-18%, kerosene: 15-25%, fatty acid methyl ester: 10-25%).

19. A low-carbon high-hydrogen diesel fuel blend comprising:

25-30% base oil:

40-60% diesel:

10-20% low-carbon high-hydrogen diesel fuel additive.