US20120014892A1 - Nail-hardening cosmetic composition, use of aldehydes to harden and strengthen nails, and method for applying same - Google Patents
Nail-hardening cosmetic composition, use of aldehydes to harden and strengthen nails, and method for applying same Download PDFInfo
- Publication number
- US20120014892A1 US20120014892A1 US13/257,081 US201013257081A US2012014892A1 US 20120014892 A1 US20120014892 A1 US 20120014892A1 US 201013257081 A US201013257081 A US 201013257081A US 2012014892 A1 US2012014892 A1 US 2012014892A1
- Authority
- US
- United States
- Prior art keywords
- cosmetic composition
- nails
- nail
- polish
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 68
- 239000002537 cosmetic Substances 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims abstract description 6
- 150000001299 aldehydes Chemical class 0.000 title claims description 20
- 239000007864 aqueous solution Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 239000000839 emulsion Substances 0.000 claims abstract description 7
- 125000003172 aldehyde group Chemical group 0.000 claims abstract description 6
- JARKCYVAAOWBJS-UHFFFAOYSA-N hexanal Chemical compound CCCCCC=O JARKCYVAAOWBJS-UHFFFAOYSA-N 0.000 claims description 52
- GYHFUZHODSMOHU-UHFFFAOYSA-N nonanal Chemical compound CCCCCCCCC=O GYHFUZHODSMOHU-UHFFFAOYSA-N 0.000 claims description 12
- HFJRKMMYBMWEAD-UHFFFAOYSA-N dodecanal Chemical compound CCCCCCCCCCCC=O HFJRKMMYBMWEAD-UHFFFAOYSA-N 0.000 claims description 8
- OFHHDSQXFXLTKC-UHFFFAOYSA-N 10-undecenal Chemical compound C=CCCCCCCCCC=O OFHHDSQXFXLTKC-UHFFFAOYSA-N 0.000 claims description 7
- KMPQYAYAQWNLME-UHFFFAOYSA-N Undecanal Natural products CCCCCCCCCCC=O KMPQYAYAQWNLME-UHFFFAOYSA-N 0.000 claims description 6
- FXHGMKSSBGDXIY-UHFFFAOYSA-N heptanal Chemical compound CCCCCCC=O FXHGMKSSBGDXIY-UHFFFAOYSA-N 0.000 claims description 6
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 claims description 6
- CWRKZMLUDFBPAO-VOTSOKGWSA-N (e)-dec-4-enal Chemical compound CCCCC\C=C\CCC=O CWRKZMLUDFBPAO-VOTSOKGWSA-N 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 4
- FBJOZYRPJMTSNP-UHFFFAOYSA-N undecanal Chemical compound CCCCCCCCCCC=O.CCCCCCCCCCC=O FBJOZYRPJMTSNP-UHFFFAOYSA-N 0.000 claims description 4
- 230000000699 topical effect Effects 0.000 claims 1
- 210000000282 nail Anatomy 0.000 abstract description 64
- 238000005728 strengthening Methods 0.000 abstract description 8
- 210000004905 finger nail Anatomy 0.000 abstract description 3
- 230000003796 beauty Effects 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- WTEVQBCEXWBHNA-JXMROGBWSA-N geranial Chemical compound CC(C)=CCC\C(C)=C\C=O WTEVQBCEXWBHNA-JXMROGBWSA-N 0.000 description 11
- WTEVQBCEXWBHNA-UHFFFAOYSA-N Citral Natural products CC(C)=CCCC(C)=CC=O WTEVQBCEXWBHNA-UHFFFAOYSA-N 0.000 description 9
- 238000004383 yellowing Methods 0.000 description 8
- 229940043350 citral Drugs 0.000 description 7
- 230000006872 improvement Effects 0.000 description 7
- 238000001727 in vivo Methods 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 239000000499 gel Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 206010020751 Hypersensitivity Diseases 0.000 description 4
- 102000011782 Keratins Human genes 0.000 description 4
- 108010076876 Keratins Proteins 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 206010048886 Onychoclasis Diseases 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 230000007815 allergy Effects 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 231100000370 skin sensitisation Toxicity 0.000 description 3
- 230000009974 thixotropic effect Effects 0.000 description 3
- BYGQBDHUGHBGMD-UHFFFAOYSA-N 2-methylbutanal Chemical compound CCC(C)C=O BYGQBDHUGHBGMD-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- -1 alkenyl radicals Chemical class 0.000 description 2
- 239000013566 allergen Substances 0.000 description 2
- 230000002009 allergenic effect Effects 0.000 description 2
- 208000026935 allergic disease Diseases 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 239000011630 iodine Substances 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- GVZNXUAPPLHUOM-UHFFFAOYSA-N 2-[1-(1-methoxypropan-2-yloxy)propan-2-yloxy]propan-1-ol Chemical compound COCC(C)OCC(C)OC(C)CO GVZNXUAPPLHUOM-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- IHZXTIBMKNSJCJ-UHFFFAOYSA-N 3-{[(4-{[4-(dimethylamino)phenyl](4-{ethyl[(3-sulfophenyl)methyl]amino}phenyl)methylidene}cyclohexa-2,5-dien-1-ylidene)(ethyl)azaniumyl]methyl}benzene-1-sulfonate Chemical compound C=1C=C(C(=C2C=CC(C=C2)=[N+](C)C)C=2C=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S(O)(=O)=O)=C1 IHZXTIBMKNSJCJ-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 235000011437 Amygdalus communis Nutrition 0.000 description 1
- 244000144725 Amygdalus communis Species 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 241000134874 Geraniales Species 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- 229920002884 Laureth 4 Polymers 0.000 description 1
- 244000004005 Nypa fruticans Species 0.000 description 1
- 235000005305 Nypa fruticans Nutrition 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 206010070835 Skin sensitisation Diseases 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- FHNINJWBTRXEBC-UHFFFAOYSA-N Sudan III Chemical compound OC1=CC=C2C=CC=CC2=C1N=NC(C=C1)=CC=C1N=NC1=CC=CC=C1 FHNINJWBTRXEBC-UHFFFAOYSA-N 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000008168 almond oil Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 229960001631 carbomer Drugs 0.000 description 1
- WTEVQBCEXWBHNA-YFHOEESVSA-N citral B Natural products CC(C)=CCC\C(C)=C/C=O WTEVQBCEXWBHNA-YFHOEESVSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 210000000003 hoof Anatomy 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229940061515 laureth-4 Drugs 0.000 description 1
- 230000003902 lesion Effects 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000007959 natural flavoring substance Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229940070720 stearalkonium Drugs 0.000 description 1
- 125000005502 stearalkonium group Chemical group 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
Definitions
- the invention relates to the field of cosmetic compositions for nails, and more particularly cosmetic compositions for strengthening and hardening nails.
- Patent GB 1 183 513 indicates that the hardening action of aldehydes on the nails decreases when the number of carbon atoms increases. It recommends the use of C 1 to C 4 monoaldehydes, more particularly acetaldehyde, or dialdehydes for strengthening the keratin of the nails, at contents between 3% and 5%.
- Citral in the form of a mixture of its two isomers geranial and neral, described in patent EP 1 408 917, is certainly also recognized for its nail-hardening action, but may cause sensitization by skin contact and is classed among the detected allergens (according to the list of allergenic substances cited in the 7 th amendment of European Directive 76/768/EEC). It is therefore used less and less in cosmetics. Moreover, these molecules comprise a double bond, which makes citral UV-sensitive, and therefore subject to yellowing.
- a first objective of the invention is therefore to propose the implementation and use of a family of compounds for strengthening the keratin structure of the nail by hardening it, which does not have the drawbacks mentioned above.
- Another objective of the invention is to propose compounds that are not sensitive to aging, and especially to yellowing.
- Yet another objective of the invention is to propose a compound for hardening nails that does not have an odor that is unpleasant for the user, at concentrations below a few percent by weight.
- the present invention proposes the use, as a nail hardening agent, of a monoaldehyde of formula (I): R—CHO, R being a linear C 5 -C 12 alkyl radical, or a C 5 -C 12 alkenyl having a double bond that is not conjugated with the —CHO aldehyde group, preferably not belonging to the list of allergenic substances cited in the 7 th amendment of European Directive 76/768/EEC.
- aldehydes do not exhibit yellowing over time and do not have an odor that is unpleasant for the user, at concentrations less than or equal to 1% by weight.
- the aldehyde of formula (I) can be used in a cosmetic composition for nails.
- said cosmetic composition contains a concentration of aldehyde of formula (I) of less than or equal to 1% by weight, preferably less than or equal to 0.5% by weight. More advantageously, the cosmetic composition contains a concentration of aldehyde of formula (I) of less than or equal to 0.1% by weight, preferably less than or equal to 0.05% by weight.
- the aldehyde of formula (I) may advantageously be chosen from hexanal, heptanal, octanal, nonanal, dodecanal, trans-4-decenal, undecanal and undecylenic aldehyde, or a mixture thereof.
- aldehydes have the advantage of not presenting any health risk (sensitization, allergy, toxicity, nor carcinogenic effect, unlike certain active agents from the prior art).
- hexanal which is used in the agri-food sector in particular for flavoring beverages, has proved to be active as a nail hardener.
- Hexanal which may be derived from enzymatic treatments of sunflower oil, is already known as a natural flavoring substance.
- the aldehyde of formula (I) may be incorporated into a cosmetic composition which may be a film-forming composition, such as a colored or colorless nail polish, a polish base coat or a peelable polish, or may be in the form of an aqueous solution or emulsion, a care oil, or a gel.
- Film-forming cosmetic compositions, such as polishes are preferred since they can remain on the nail in a lasting manner.
- the present invention also relates to any cosmetic composition for the nails, containing a concentration of less than or equal to 1% by weight of at least one monoaldehyde of formula (I) as a nail hardening agent, and preferably being in the form of a colored or colorless nail polish, a polish base coat, a peelable polish, a care oil, an aqueous solution or emulsion, or a gel.
- a concentration of less than or equal to 1% by weight of at least one monoaldehyde of formula (I) as a nail hardening agent preferably being in the form of a colored or colorless nail polish, a polish base coat, a peelable polish, a care oil, an aqueous solution or emulsion, or a gel.
- the present invention also relates to a process for hardening the nails, especially cracked, thin, brittle, soft or split nails, consisting in applying topically to said nails and/or the periphery thereof, a monoaldehyde of formula (I): R—CHO, R being a linear C 5 -C 12 alkyl radical, or a C 5 -C 12 alkenyl having a double bond that is not conjugated with the —CHO aldehyde group.
- the aldehyde of formula (I) is advantageously present in a cosmetic composition for nails, it being possible for this cosmetic composition to be in particular in the form of a colored or colorless nail polish, a polish base coat, a peelable polish, a care oil, an aqueous solution or emulsion, or a gel.
- the concentration of the various constituents is expressed as % by weight of the total weight of the cosmetic composition.
- a cosmetic composition in the form of a thixotropic polish was prepared from the following constituents:
- This composition is here in the form of a polish, which is colorless and transparent after application to the nail, having a solids content equal to 31.3% by weight (measured at 100° C.).
- One or more dyestuffs chosen from pigments, soluble dyes and decorative particles, such as nacres and flakes, may be added.
- Hexanal at this concentration, does not have an odor that is unpleasant for the user.
- composition from example 1 was the subject of in vivo tests on a panel of 22 people aged at least 30 years old, over four weeks, in order to evaluate the efficacy and tolerance. None of the people tested had a lesion in the vicinity of the target zones (here the periphery of the fingernails), nor a dermatological condition. The polish was applied under normal usage conditions (namely three applications per week). These results are presented in the table below:
- the tolerance was evaluated 30 minutes after application and at the end of the four-week test. No clinical signs of intolerance were observed, nor experienced by the people tested. No allergy symptoms were observed.
- composition of example 1 and also a composition is identical to that of example 1, but in which the hexanal has been replaced by citral, in the same concentrations, were the subject of in vivo tests on a new panel of 22 people under the same conditions as those of the tests from example 1. Each person applied the composition with hexanal to the nails of one hand, and the composition with citral to the nails of the other hand. The right hand/left hand choice was random.
- Hexanal is therefore more suitable for strengthening the nail than citral.
- the colored, transparent, film-forming composition in which the proportion of hexanal is 0.20%, comprises the following constituents:
- Hexanal is incorporated into a care oil for strengthening the nail, having the following formulation:
- the hexanal is incorporated into a care gel, also at a concentration of 0.01% by weight.
- Phenonip® is a trademarked preservative product from the company Nipa that contains a mixture of paraben in solution in phenoxyethanol.
- Hexanal may also be effective in an aqueous-based care polish, constituted of:
- This polish adheres weakly to the nail and is detached from the nail by peeling (peelable polish). It may be used as an overnight care product.
- hexanal may be incorporated into cosmetic compositions of different natures [all the above cosmetic compositions including hexanal at low concentrations, here less than or equal to 0.05% by weight] and that it has a strengthening and hardening effect on the nails.
- Various aliphatic aldehydes were incorporated into a cosmetic composition, having a formulation corresponding to example 2, at concentrations respectively of 0.001%, 0.002%, 0.005% and 0.01%.
- the aging, and in particular the tendency toward yellowing, of each composition were tested.
- the various tests performed comprise holding for one month in an oven at 45° C. and four months in an oven at 50° C., and also exposure to “SUNTEST CPS+”, i.e. in a sealed chamber, regulated at 50° C. under a 500 Watt/m 2 UV/visible lamp for 3 ⁇ 10 hours.
- the yellowing was evaluated relative to control compositions having identical formulations, kept at room temperature (20-25° C.), in the dark, for the same duration.
- compositions containing concentrations of 0.01% of methylbutyraldehyde or of undecylenic aldehyde exhibited yellowing after one month in an oven at 45° C.
- Hexanal, nonanal, trans-4-decenal and undecanal did not exhibit yellowing at the same concentrations (0.01% by weight).
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
A cosmetic composition for nails containing a concentration less than or equal to 1 wt % of at least one monoaldehyde of the formula (I): R—CHO, where R is a C5-C12 linear alkyl radical or a C5-C12 alkenyl with an unconjugated double bond to the —CHO aldehyde group, as nail hardening agent, and provided in the form of a colored or colorless fingernail polish, a polish undercoat, a peelable polish, a beauty oil, an emulsion or an aqueous solution, or a gel. Also the use of aldehydes of the formula (I) for hardening and strengthening nails and to a method for applying same.
Description
- The invention relates to the field of cosmetic compositions for nails, and more particularly cosmetic compositions for strengthening and hardening nails.
- It is well known that nails, which are composed of keratin, are sometimes weakened, brittle, split or cracked. Besides degrading the esthetic appearance of these nails, this results in considerable inconvenience for a person in their daily life, mainly when these defects relate to fingernails: catching on textiles or clothing, aggravating cracks each time something is gripped, etc.
- To date, various solutions have been provided for this problem, but the latter are either not perfect, or generate other drawbacks. Mention may thus be made of the following:
- The use of formaldehyde, in proportions that may range up to 5% by weight in the cosmetic composition, has been known for a long time. However, this compound is now monitored very closely due to its toxic effects on the body, with proven carcinogenic effects. This molecule is moreover a powerful allergen.
- The use of glyoxal, a dialdehyde, was described in patent GB 2 196 978 as early as 1986. This product is however harmful by inhalation, irritating to the skin and the eyes, and may cause skin sensitization.
- The use of glutaraldehyde is described in patent GB 2 250 196 in combination with a water-soluble aluminum salt for hardening horses' hooves, which are also composed of keratin. However, it turns out that this aldehyde is toxic by inhalation and if swallowed, may cause burns, and may cause sensitization by skin contact: it therefore appears quite unsuitable for human nails.
- Patent GB 1 183 513 indicates that the hardening action of aldehydes on the nails decreases when the number of carbon atoms increases. It recommends the use of C1 to C4 monoaldehydes, more particularly acetaldehyde, or dialdehydes for strengthening the keratin of the nails, at contents between 3% and 5%.
- Citral (in the form of a mixture of its two isomers geranial and neral), described in patent EP 1 408 917, is certainly also recognized for its nail-hardening action, but may cause sensitization by skin contact and is classed among the detected allergens (according to the list of allergenic substances cited in the 7th amendment of European Directive 76/768/EEC). It is therefore used less and less in cosmetics. Moreover, these molecules comprise a double bond, which makes citral UV-sensitive, and therefore subject to yellowing.
- This long list of drawbacks relating to the aldehydes used in cosmetic compositions for nails has encouraged those skilled in the art to research other types of non-aldehyde molecules for hardening and strengthening human nails.
- Among the other nail hardeners, document U.S. Pat. No. 4,919,920 describes the incorporation of iodine or fluorine in the form of ions in an aqueous cosmetic composition with no organic solvent, optionally in the presence of a polyol such as glycerol. Such a use is not suitable for nail polishes that comprise a large organic solvent phase. Iodine may also cause allergies in certain users.
- There remains therefore a real need to find a compound for hardening nails that overcomes the aforementioned drawbacks and that can be used in diverse cosmetic compositions, that is to say cosmetic compositions of different natures, namely polish, gels or care oils for example.
- A first objective of the invention is therefore to propose the implementation and use of a family of compounds for strengthening the keratin structure of the nail by hardening it, which does not have the drawbacks mentioned above.
- Another objective of the invention is to propose compounds that are not sensitive to aging, and especially to yellowing.
- Yet another objective of the invention is to propose a compound for hardening nails that does not have an odor that is unpleasant for the user, at concentrations below a few percent by weight.
- For this purpose, the present invention proposes the use, as a nail hardening agent, of a monoaldehyde of formula (I): R—CHO, R being a linear C5-C12 alkyl radical, or a C5-C12 alkenyl having a double bond that is not conjugated with the —CHO aldehyde group, preferably not belonging to the list of allergenic substances cited in the 7th amendment of European Directive 76/768/EEC.
- Indeed, it has been observed, surprisingly and contrary to the indications from the prior art (in particular from patent GB 1 183 513) that monoaldehydes having alkyl or alkenyl radicals comprising from 5 to 12 carbon atoms exhibit nail-hardening properties.
- Moreover, these aldehydes do not exhibit yellowing over time and do not have an odor that is unpleasant for the user, at concentrations less than or equal to 1% by weight. Thus, the aldehyde of formula (I) can be used in a cosmetic composition for nails.
- Advantageously, said cosmetic composition contains a concentration of aldehyde of formula (I) of less than or equal to 1% by weight, preferably less than or equal to 0.5% by weight. More advantageously, the cosmetic composition contains a concentration of aldehyde of formula (I) of less than or equal to 0.1% by weight, preferably less than or equal to 0.05% by weight.
- It has also been observed that the nail-hardening properties are present even at concentrations of less than or equal to 0.01% by weight of aldehyde of formula (I).
- The aldehyde of formula (I) may advantageously be chosen from hexanal, heptanal, octanal, nonanal, dodecanal, trans-4-decenal, undecanal and undecylenic aldehyde, or a mixture thereof.
- These aldehydes have the advantage of not presenting any health risk (sensitization, allergy, toxicity, nor carcinogenic effect, unlike certain active agents from the prior art).
- For example, surprisingly, hexanal, which is used in the agri-food sector in particular for flavoring beverages, has proved to be active as a nail hardener. Hexanal, which may be derived from enzymatic treatments of sunflower oil, is already known as a natural flavoring substance.
- According to the present invention, the aldehyde of formula (I) may be incorporated into a cosmetic composition which may be a film-forming composition, such as a colored or colorless nail polish, a polish base coat or a peelable polish, or may be in the form of an aqueous solution or emulsion, a care oil, or a gel. Film-forming cosmetic compositions, such as polishes, are preferred since they can remain on the nail in a lasting manner.
- The present invention also relates to any cosmetic composition for the nails, containing a concentration of less than or equal to 1% by weight of at least one monoaldehyde of formula (I) as a nail hardening agent, and preferably being in the form of a colored or colorless nail polish, a polish base coat, a peelable polish, a care oil, an aqueous solution or emulsion, or a gel.
- Studies of the efficacy of said compositions show that these aldehydes are active on several levels with respect to nail defects: cracked nails, thin nails, brittle nails, split nails, hardness of the nail, weakness of the nail, without causing allergic reactions.
- The present invention also relates to a process for hardening the nails, especially cracked, thin, brittle, soft or split nails, consisting in applying topically to said nails and/or the periphery thereof, a monoaldehyde of formula (I): R—CHO, R being a linear C5-C12 alkyl radical, or a C5-C12 alkenyl having a double bond that is not conjugated with the —CHO aldehyde group. The aldehyde of formula (I) is advantageously present in a cosmetic composition for nails, it being possible for this cosmetic composition to be in particular in the form of a colored or colorless nail polish, a polish base coat, a peelable polish, a care oil, an aqueous solution or emulsion, or a gel.
- The following examples make it possible to illustrate the present invention in a non-limiting manner. In all of the formulations, the concentration of the various constituents is expressed as % by weight of the total weight of the cosmetic composition.
- A cosmetic composition in the form of a thixotropic polish was prepared from the following constituents:
-
Butyl acetate 41.00 Ethyl acetate 20.60 Nitrocellulose 14.00 Polyester resin 9.50 Acetyl tributyl citrate 6.00 Isopropyl alcohol 6.00 Stearalkonium bentonite 1.30 Styrene/acrylic resin 1.30 Benzophenone-1 0.20 Polyvinyl butyral 0.05 Hexanal 0.05 100.00 - This composition is here in the form of a polish, which is colorless and transparent after application to the nail, having a solids content equal to 31.3% by weight (measured at 100° C.). One or more dyestuffs chosen from pigments, soluble dyes and decorative particles, such as nacres and flakes, may be added.
- The following were tested:
-
- The gloss: 87 (on a scale of 100). It is measured with a Minolta 268 glossmeter (angle of incidence 60°) for an application made on a LENETA type card.
- The hardness, measured using a “Persoz” pendulum on the dry film formed by applying a 100 μm thick layer of the above composition onto a glass plate, dried overnight at room temperature (20° C.), the value obtained is 210 seconds.
- Good adhesion to glass with a value between 0 and 1 (on a scale of 5). The film of polish formed on glass is scratched in a crosshatched manner with a six-blade comb of SHEEN 750/1 type. An adhesive tape applied over the scratches is torn off, and it is observed that less than 5% of the surface of the film is torn off.
- The viscosities, measured using a Brookfield LVT viscometer with a No. 3 spindle at 25° C. at 6 rpm and at 60 rpm for one minute, had the following values: (in mPa·s, respectively at 6 rpm-60 rpm-6 rpm) 2400-960-1350. This corresponds to a good spreadability of the polish.
- Hexanal, at this concentration, does not have an odor that is unpleasant for the user.
- The composition from example 1 was the subject of in vivo tests on a panel of 22 people aged at least 30 years old, over four weeks, in order to evaluate the efficacy and tolerance. None of the people tested had a lesion in the vicinity of the target zones (here the periphery of the fingernails), nor a dermatological condition. The polish was applied under normal usage conditions (namely three applications per week). These results are presented in the table below:
-
TABLE 1 Number of subjects having observed an improvement (number of subjects tested: 22) Moder- Very Improvement Slight ate Substantial substantial Total Nail weakness 6 7 2 3 18/22 = 82% Cracked nail 7 1 0 1 9/14 = 64% Thin nail 8 2 4 2 16/22 = 73% Relief of the 7 1 3 0 11/22 = 50% nail plate Brittle nail 5 3 4 3 15/22 = 68% Split nail 5 4 3 2 14/20 = 70% Nail hardness 3 5 5 5 18/22 = 82% Overall 3 3 9 5 20/22 = 91% improvement in nail quality Tolerance to Good for all subjects the product - The tolerance was evaluated 30 minutes after application and at the end of the four-week test. No clinical signs of intolerance were observed, nor experienced by the people tested. No allergy symptoms were observed.
- Moreover, more than 90% of subjects noticed an overall improvement in the quality of their nails. These results demonstrate the in vivo nail-hardening properties of hexanal, at low concentration (0.05% by weight).
- Furthermore, the overall cosmetic qualities of the composition received a very favorable assessment (average marks between 16 and 17/20).
- The composition of example 1 and also a composition is identical to that of example 1, but in which the hexanal has been replaced by citral, in the same concentrations, were the subject of in vivo tests on a new panel of 22 people under the same conditions as those of the tests from example 1. Each person applied the composition with hexanal to the nails of one hand, and the composition with citral to the nails of the other hand. The right hand/left hand choice was random.
- The results of the comparative tests show that hexanal is between 8% and 20% superior to citral from the point of view of the improvement in:
-
- nail weakness (+18%)
- brittle nails (+10%)
- nail hardness (+8.5%).
- Hexanal is therefore more suitable for strengthening the nail than citral.
- A cosmetic composition in the form of a thixotropic polish identical to the composition of example 1, replacing the hexanal with dodecanal.
- The results of the in vivo tests performed on a panel of 21 people under the same conditions as the tests from example 1 showed that more than half the subjects observed an overall improvement in the condition of their nails, especially as regards nail weakness, thin nails, brittle nails, and nail hardness. The marks of general satisfaction with the cosmetic composition oscillated between 16.9 and 18.3/20.
- A cosmetic composition in the form of a thixotropic polish identical to the composition of example 1, replacing the hexanal with undecylenic aldehyde (10-undecenal).
- The results of the in vivo tests performed on a panel of 21 people under the same conditions as the tests from example 1 showed that more than half the subjects observed an overall improvement in the condition of their nails, especially as regards nail weakness, thin nails, split nails, and nail hardness. The marks of general satisfaction with the cosmetic composition oscillated between 16 and 17.3/20.
- The colored, transparent, film-forming composition, in which the proportion of hexanal is 0.20%, comprises the following constituents:
-
Ethyl acetate 40.00 Butyl acetate 26.5796 Nitrocellulose 14.00 Polyester resin 7.00 Acetyl tributyl citrate 6.20 Isopropyl alcohol 6.00 Hexanal 0.20 Polyvinyl butyral 0.02 Red 17 0.0002 Violet 2 0.0002 - Hexanal is incorporated into a care oil for strengthening the nail, having the following formulation:
-
Sweet almond oil 98.99 Fragrance 1.00 Hexanal 0.01 - In this example, the hexanal is incorporated into a care gel, also at a concentration of 0.01% by weight.
-
Water 83.59 Glycerol 5.00 Propylene glycol 5.00 Trisodium phosphate 3.80 Carbomer 0.90 Laureth 4 0.80 Phenonip ® 0.70 Fragrance 0.20 Hexanal 0.01 - Phenonip® is a trademarked preservative product from the company Nipa that contains a mixture of paraben in solution in phenoxyethanol.
- Hexanal may also be effective in an aqueous-based care polish, constituted of:
-
Water 54.80 Polyvinyl acetate 40.00 PPG 3 methyl ether 3.00 Ammonium citrate 0.60 Titanium oxide 0.55 Phenonip ® 0.50 PEG 12 dimethicone 0.30 Styrene/acrylic copolymer 0.15 DC Red 30 0.05 Hexanal 0.05 - This polish adheres weakly to the nail and is detached from the nail by peeling (peelable polish). It may be used as an overnight care product.
- The various examples above showed that hexanal may be incorporated into cosmetic compositions of different natures [all the above cosmetic compositions including hexanal at low concentrations, here less than or equal to 0.05% by weight] and that it has a strengthening and hardening effect on the nails.
- Various aliphatic aldehydes were incorporated into a cosmetic composition, having a formulation corresponding to example 2, at concentrations respectively of 0.001%, 0.002%, 0.005% and 0.01%.
- These were methylbutyraldehyde (by way of comparison), hexanal, nonanal, trans-4-decenal, undecanal and undecylenic aldehyde.
- The aging, and in particular the tendency toward yellowing, of each composition were tested. The various tests performed comprise holding for one month in an oven at 45° C. and four months in an oven at 50° C., and also exposure to “SUNTEST CPS+”, i.e. in a sealed chamber, regulated at 50° C. under a 500 Watt/m2 UV/visible lamp for 3×10 hours.
- The yellowing was evaluated relative to control compositions having identical formulations, kept at room temperature (20-25° C.), in the dark, for the same duration.
- All the polishes tested remained fluid over time and were spread easily and in the same way as the controls.
- The compositions containing concentrations of 0.01% of methylbutyraldehyde or of undecylenic aldehyde exhibited yellowing after one month in an oven at 45° C.
- Hexanal, nonanal, trans-4-decenal and undecanal did not exhibit yellowing at the same concentrations (0.01% by weight).
Claims (14)
1. A nail hardening agent, comprising: a monoaldehyde of formula (I): R—CHO, R being a linear C5-C12 alkyl radical, or a C5-C12 alkenyl having a double bond that is not conjugated with the —CHO aldehyde group.
2. A cosmetic composition for nails comprising the nail hardening agent of claim 1 .
3. The cosmetic composition as claimed in claim 2 , characterized in that the cosmetic composition contains a concentration of aldehyde of formula (I) of less than or equal to 1% by weight, preferably less than or equal to 0.5% by weight.
4. The cosmetic composition as claimed in claim 2 , characterized in that the cosmetic composition contains a concentration of aldehyde of formula (I) of less than or equal to 0.1% by weight, preferably less than or equal to 0.05% by weight.
5. The cosmetic composition as claimed in claim 2 , characterized in that the composition contains a concentration of aldehyde of formula (I) of less than or equal to 0.01% by weight.
6. The cosmetic composition as claimed in claim 2 , characterized in that the aldehyde of formula (I) is chosen from hexanal, heptanal, octanal, nonanal, dodecanal, trans-4-decenal, undecanal and undecylenic aldehyde, or a mixture thereof.
7. The cosmetic composition as claimed in claim 2 , characterized in that the cosmetic composition is a film-forming composition, such as a colored or colorless nail polish, a polish base coat, or a peelable polish.
8. The cosmetic composition as claimed in claim 2 , characterized in that the cosmetic composition for the nails is in the form of an aqueous solution or emulsion, a care oil, or a gel.
9. A cosmetic composition for topical application to the nails, characterized in that it contains a concentration of less than or equal to 1% by weight of at least one monoaldehyde of formula (I): R—CHO, R being a linear C5-C12 alkyl radical, or a C5-C12 alkenyl having a double bond that is not conjugated with the —CHO aldehyde group, as a nail hardening agent.
10. The cosmetic composition for the nails as claimed in claim 9 , characterized in that it is in the form of a colored or colorless nail polish, a polish base coat, a peelable polish, a care oil, an aqueous solution or emulsion, or a gel.
11. A process for hardening the nails, especially cracked, thin, brittle, soft or split nails, consisting in applying topically to said nails and/or the periphery thereof, a monoaldehyde of formula (I): R—CHO, R being a linear C5-C12 alkyl radical, or a C5-C12 alkenyl having a double bond that is not conjugated with the —CHO aldehyde group.
12. The process as claimed in claim 11 , characterized in that the aldehyde of formula (I) is present in a cosmetic composition for nails.
13. The process as claimed in claim 12 , characterized in that the cosmetic composition is in the form of a colored or colorless nail polish, a polish base coat, a peelable polish, a care oil, an aqueous solution or emulsion, or a gel.
14. The nail hardening agent as claimed in claim 1 , characterized in that the aldehyde of formula (I) is chosen from hexanal, heptanal, octanal, nonanal, dodecanal, trans-4-decenal, undecanal and undecylenic aldehyde, or a mixture thereof.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0901522 | 2009-03-30 | ||
FR0901522A FR2943533B1 (en) | 2009-03-30 | 2009-03-30 | CURING COSMETIC COMPOSITION FOR NAILS |
PCT/FR2010/050579 WO2010112751A2 (en) | 2009-03-30 | 2010-03-30 | Nail-hardening cosmetic composition, use of aldehydes to harden and strengthen nails, and method for applying same |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2010/050579 A-371-Of-International WO2010112751A2 (en) | 2009-03-30 | 2010-03-30 | Nail-hardening cosmetic composition, use of aldehydes to harden and strengthen nails, and method for applying same |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US14/275,909 Division US9211242B2 (en) | 2009-03-30 | 2014-05-13 | Nail-hardening cosmetic composition, use of aldehydes to harden and strengthen nails, and method for applying same |
Publications (1)
Publication Number | Publication Date |
---|---|
US20120014892A1 true US20120014892A1 (en) | 2012-01-19 |
Family
ID=41226632
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/257,081 Abandoned US20120014892A1 (en) | 2009-03-30 | 2010-03-30 | Nail-hardening cosmetic composition, use of aldehydes to harden and strengthen nails, and method for applying same |
US14/275,909 Active US9211242B2 (en) | 2009-03-30 | 2014-05-13 | Nail-hardening cosmetic composition, use of aldehydes to harden and strengthen nails, and method for applying same |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US14/275,909 Active US9211242B2 (en) | 2009-03-30 | 2014-05-13 | Nail-hardening cosmetic composition, use of aldehydes to harden and strengthen nails, and method for applying same |
Country Status (7)
Country | Link |
---|---|
US (2) | US20120014892A1 (en) |
EP (1) | EP2413887B1 (en) |
DK (1) | DK2413887T3 (en) |
ES (1) | ES2527585T3 (en) |
FR (1) | FR2943533B1 (en) |
PL (1) | PL2413887T3 (en) |
WO (1) | WO2010112751A2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019014195A1 (en) * | 2017-07-10 | 2019-01-17 | Coty Inc. | Nail hardening composition and method of use |
US11400040B2 (en) | 2017-03-13 | 2022-08-02 | Fiabila Sas | Nail varnish compositions |
US11571380B2 (en) | 2016-03-08 | 2023-02-07 | Fiabila Sas | Compositions for nail varnish |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10045928B2 (en) | 2016-09-29 | 2018-08-14 | Mycone Dental Supply Company, Inc. | Non-aqueous peelable nail polish |
FR3080535B1 (en) | 2018-04-25 | 2020-06-26 | Fiabila | COSMETIC COMPOSITION OF VARNISH WITH NON-AQUEOUS THIXOTROPIC NAILS CONTAINING A HARDENING AGENT FOR NAILS, USE AND METHOD OF IMPLEMENTATION |
EP4374736A2 (en) | 2020-11-05 | 2024-05-29 | Brilliance of Beauty, Inc. | Light-curable artificial nails, methods of preparation and methods of use thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001039739A1 (en) * | 1999-12-03 | 2001-06-07 | Pierre Fabre Dermo-Cosmetique | Retinaldehyde combination with antifungal activity |
US20020192247A1 (en) * | 2001-04-26 | 2002-12-19 | Lyle Theisen | Thermochromic/photochromic cosmetic compositions |
US20030124154A1 (en) * | 2001-05-21 | 2003-07-03 | Amato Steven W. | Cosmetic films |
WO2008138547A2 (en) * | 2007-05-11 | 2008-11-20 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Improved infant formula containing an aroma composition for use as fragrance |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB730095A (en) * | 1951-02-16 | 1955-05-18 | Paul Baudecroux | Improvements in finger nail enamel compositions and production thereof |
LU50992A1 (en) | 1966-04-28 | 1967-10-30 | ||
JPS6391314A (en) | 1986-09-25 | 1988-04-22 | プロ−・インコ−ポレ−テッド | Nail reinforcing cosmetic composition and use |
US4919920A (en) | 1989-03-15 | 1990-04-24 | Devos John B | Method of hardening and strengthening keratin and composition |
WO1991007942A1 (en) * | 1989-11-30 | 1991-06-13 | Avon Products, Inc. | Nail hardening compositions |
GB2250196B (en) | 1990-11-20 | 1994-05-25 | John Napier Beatson Irving | Method of hardening a hoof and waterproofing composition |
ATE410082T1 (en) * | 2000-11-06 | 2008-10-15 | Japan Tobacco Inc | TOBACCO ODOR DEODORIZER COMPOSITION, TOBACCO ODOR DEODORIZER, AND CIGARETTE AND TOBACCO PACKAGING WITH REDUCED SECONDARY SMOKE ODOR |
JP3877537B2 (en) * | 2001-03-07 | 2007-02-07 | 高砂香料工業株式会社 | Antibacterial agent for oral composition and oral composition containing the same |
FR2827169B1 (en) | 2001-07-10 | 2004-07-09 | Fiabila | HARDENER FOR NAILS |
-
2009
- 2009-03-30 FR FR0901522A patent/FR2943533B1/en active Active
-
2010
- 2010-03-30 WO PCT/FR2010/050579 patent/WO2010112751A2/en active Application Filing
- 2010-03-30 ES ES10718635.5T patent/ES2527585T3/en active Active
- 2010-03-30 US US13/257,081 patent/US20120014892A1/en not_active Abandoned
- 2010-03-30 DK DK10718635.5T patent/DK2413887T3/en active
- 2010-03-30 PL PL10718635T patent/PL2413887T3/en unknown
- 2010-03-30 EP EP10718635.5A patent/EP2413887B1/en active Active
-
2014
- 2014-05-13 US US14/275,909 patent/US9211242B2/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001039739A1 (en) * | 1999-12-03 | 2001-06-07 | Pierre Fabre Dermo-Cosmetique | Retinaldehyde combination with antifungal activity |
US20020192247A1 (en) * | 2001-04-26 | 2002-12-19 | Lyle Theisen | Thermochromic/photochromic cosmetic compositions |
US20030124154A1 (en) * | 2001-05-21 | 2003-07-03 | Amato Steven W. | Cosmetic films |
WO2008138547A2 (en) * | 2007-05-11 | 2008-11-20 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Improved infant formula containing an aroma composition for use as fragrance |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11571380B2 (en) | 2016-03-08 | 2023-02-07 | Fiabila Sas | Compositions for nail varnish |
US11400040B2 (en) | 2017-03-13 | 2022-08-02 | Fiabila Sas | Nail varnish compositions |
WO2019014195A1 (en) * | 2017-07-10 | 2019-01-17 | Coty Inc. | Nail hardening composition and method of use |
US11628148B2 (en) | 2017-07-10 | 2023-04-18 | Wella Operations Us, Llc | Nail hardening composition and method of use |
US11890262B2 (en) | 2017-07-10 | 2024-02-06 | Wella Operations Us, Llc | Nail hardening composition and method of use |
Also Published As
Publication number | Publication date |
---|---|
EP2413887B1 (en) | 2014-10-08 |
US20140248225A1 (en) | 2014-09-04 |
US9211242B2 (en) | 2015-12-15 |
WO2010112751A3 (en) | 2011-09-09 |
ES2527585T3 (en) | 2015-01-27 |
DK2413887T3 (en) | 2015-01-12 |
FR2943533B1 (en) | 2012-10-12 |
FR2943533A1 (en) | 2010-10-01 |
WO2010112751A2 (en) | 2010-10-07 |
EP2413887A2 (en) | 2012-02-08 |
PL2413887T3 (en) | 2015-03-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US9211242B2 (en) | Nail-hardening cosmetic composition, use of aldehydes to harden and strengthen nails, and method for applying same | |
US10721937B1 (en) | Preservative systems and compositions and methods incorporating same | |
RU2652299C2 (en) | Nail compositions | |
JP2004513904A (en) | Polyurethane-containing cosmetics | |
JP6346962B2 (en) | Cosmetic composition for hydrating the skin | |
JP5455292B2 (en) | Skin external composition | |
JP4045240B2 (en) | Manufacturing method for nail cosmetics | |
KR102624838B1 (en) | Improved self-tanning composition | |
JP5494142B2 (en) | Topical skin preparation | |
US20210236412A1 (en) | Cosmetic composition of non-aqueous thixotropic nail varnish containing a nail-hardening agent, use and implementation method | |
JP2001131031A (en) | Composition for scalp and hair | |
EP3498256A1 (en) | Cosmetic formulation for the removal of skin stains | |
KR102106212B1 (en) | hypo-allergenic manicure composition by shellac for nail and toenail and its product method | |
Hylwa et al. | Contact Dermatology | |
JP3503205B2 (en) | Tyrosinase activity inhibitor and skin moisturizer | |
BR112020020481B1 (en) | COSMETIC COMPOSITION OF THIXOTROPIC NAIL ENAMEL CONTAINING A NAIL HARDENING AGENT, USE AND IMPLEMENTATION PROCESS | |
Foti et al. | Common Allergens | |
TW201742614A (en) | Hair care composition with no damage to skin and hair during hair caring and capable of stabilizing hair coloring effect | |
FR2805745A1 (en) | Antifungal and antibacterial nail varnish for the treatment of fungal nail infections, consists of a nitrocellulose in organic solvent and formalin | |
WO2021259554A1 (en) | Biodegradable adhesive composition | |
US20210299022A1 (en) | Composition for the treatment of nail fungus | |
WO2020150138A1 (en) | Sprayable compositions | |
WO1991007942A1 (en) | Nail hardening compositions | |
KR20030036397A (en) | Composition using skin art |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: FIABILA, FRANCE Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:RENARD, CHRISTINE;BONNEVIE, XAVIER;SIGNING DATES FROM 20110907 TO 20110908;REEL/FRAME:026965/0538 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |