US20110210462A1

US20110210462A1 - Spin-Dyed Gradient-Color Fiber and Method for Fabricating the Same

Info

Publication number: US20110210462A1
Application number: US13/056,549
Authority: US
Inventors: Yi-yung Chen
Original assignee: Individual
Current assignee: Individual
Priority date: 2008-07-31
Filing date: 2008-07-31
Publication date: 2011-09-01
Also published as: EP2309041A4; WO2010012128A1; EP2309041A1; CN102076893A; JP2011529534A

Abstract

The present invention discloses a spin-dyed gradient-color fiber and a method for fabricating the same, wherein at least one component of the fiber is spin-dyed. The present invention obtains gradient color via controlling at least one of the following spinning conditions: (1) colorant quantity: continuously varying quantity of at least one colorant metered by colorant meters; (2) output ratio: continuously varying the output ratio of at least one melt extruder; (3) fineness: varying fineness of the fiber in a stretching way, a false-twisting way or another way.

Description

BACKGROUND OF THE INVENTION

1. Field of the Invention
The present invention relates to a gradient-color fiber and a method for fabricating the same, particularly to a spin-dyed gradient-color thermoplastic fiber and a method for fabricating the same.
2. Description of the Related Art
Gradient-color fiber and fabric is usually fabricated with a pigment-printing or bath-dyeing method. However, pigment printing and bath dyeing generates a great amount of waste water and causes environmental protection problems.
A China patent No. CN2564602Y disclosed a fiber gradient-coloring device, which adopts a spray-dyeing method to obtain gradient-color fiber. However, the prior art has lower productivity and poor color fastness.
A France patent No. FR2682130 disclosed a fiber gradient-coloring technology, wherein fiber are disposed on a supporter and slowly immersed into a dye bath, whereby different parts of fiber are dyed for different lengths of time to have gradient variation of color. However, the prior art is realized with bath dyeing, which generates a great amount of waste water and damages the environment.
A Canada patent disclosed a fabric gradient-coloring technology, wherein different portions of a fabric are respectively disposed at different altitudes and dyed for different lengths of time via gradually releasing the dye solution to obtain gradient variation of color. However, the prior art is realized with bath dyeing and generates a great amount of waste water.
Thus, how to fabricate gradient-color fiber without generating massive waste water has been an important subject in the field concerned.

SUMMARY OF THE INVENTION

One objective of the present invention is to provide a spin-dyed gradient-color fiber and a method for fabricating the same to solve the abovementioned problems, wherein at least one component of fiber is spin-dyed to attain gradient color via controlling at least one spinning condition, whereby a gradient-color fiber can be efficiently produced without generating massive waste water.
To achieve the abovementioned objective, the present invention proposes a spin-dyed gradient-color fiber and a method for fabricating the same, which are characterized in that at least one component of a thermoplastic fiber is spin-dyed with the dye quantity being gradually varied to attain gradient variation of color. The present invention is applied to spin-dyed thermoplastic fiber and realized via controlling at least one of the following spinning conditions:
(1) Colorant quantity: continuously varying quantity of at least one colorant metered by colorant meters when a monocomponent or a conjugate fiber containing at least two components is spin-dyed in at least one melt extruder;
(2) Drawing rate: continuously varying the drawing rate of at least one component of a monocomponent or a conjugate fiber containing at least two components when the monocomponent or conjugate fiber is spin-dyed in at least one melt extruder; and
(3) Output Ratio: continuously varying the output ratio of at least one component of a monocomponent or a conjugate fiber containing at least two components when the monocomponent or conjugate fiber is spin-dyed in at least one melt extruder.
The thermoplastic fiber used in the present invention is made of a thermoplastic resin selected from a group consisting of polyester resins, polyester copolymers, polyamide resins, polyamide copolymers, polypropylene resins, polypropylene copolymers, polyethylene resins, polyethylene copolymers, and combinations thereof.
When a thermoplastic fiber is colored with a pigment or dye, the color tint varies with the quantity of the pigment or dye. Via continuously varying the quantity of the pigment or dye, the fiber will have gradient color. The quantity of a pigment or dye is controlled via the following methods:
(1) Continuously and periodically varying colorant quantities metered by colorant meters;
(2) Continuously and periodically varying the output ratio of at least one melt extruder when the component is spin-dyed in the melt extruder; and
(3) A combination of the abovementioned methods.
Gradient color of a thermoplastic fiber can be alternatively obtained via continuously varying the fineness of the thermoplastic fiber when the thermoplastic fiber is spin-dyed with at least one pigment or dye. The fineness of a thermoplastic fiber can be varied via the following methods:
(1) Continuously and periodically varying the total output ratio of the melt extruders via continuously and periodically varying the output ratio of at least one of the melt extruders;
(2) Continuously and periodically varying the drawing rate of the thermoplastic fiber with a stretching method, a false-twisting method or another method; and (3) A combination of the abovementioned methods.
In summary, when at least one component of a thermoplastic fiber is spin-dyed, gradient color of the thermoplastic fiber and the fabric made thereof can be obtained via controlling at least one of the following spinning conditions:
(1) Colorant quantity: continuously and periodically varying at least one colorant quantity metered by colorant meters;
(2) Output ratio: continuously and periodically varying the output ratio of at least one melt extruder with the total output ratio remaining constant or varying continuously; and (3) Fineness: continuously and periodically varying the fineness of the thermoplastic fiber via a stretching method, a false-twisting method or another method.
Different methods mentioned above generate different gradient effects. Some methods do not generate obvious variation of hue but only result in variation of color strength. Some methods generate obvious gradient variation of hue. The details thereof are further demonstrated below.
(1) If there is only a single colorant metered by a colorant meter, continuously varying the quantity of the single colorant results in only gradient variation of color strength. If at least two colorants are respectively metered by colorant meters, continuously varying the quantity of at least one of the colorants obtains obvious gradient variation of hue.
(2) Suppose that only a component of a thermoplastic fiber is spin-dyed with at least one pigment or dye. The greater the output ratio of the melt extruder of the spin-dyed component, the deeper the color. The smaller the output ratio of the melt extruder of the spin-dyed component, the lighter the color. Continuously varying the output ratio generates gradient variation of color strength.
Suppose that at least two components of a thermoplastic conjugate fiber are spin-dyed with an identical colorant (such as a pigment or a dye) and that the concentrations of the pigment or dye are different for the at least two components. The greater the output ratio of the melt extruder of a component spin-dyed with a higher concentration, the deeper the color. The smaller the output ratio of the melt extruder of a component spin-dyed with a higher concentration, the lighter the color. Although the method can generate gradient variation of color strength, the range of color strength variation is limited.
Suppose that at least two components of a thermoplastic fiber are respectively spin-dyed with different colorants (such as pigments or dyes). The greater the output ratio of the melt extruder of one of the at least two spin-dyed components, the closer the hue of the thermoplastic fiber to that of the component. The smaller the output ratio of the melt extruder of one of the at least two spin-dyed components, the closer the hue of the thermoplastic fiber to that of another component. When the proportion of the components is varied continuously, the hue of the thermoplastic fiber is also varied continuously. Via continuously varying the output ratios of the components, a gradient-color conjugate fiber having hue variation is obtained.
(3) Suppose that at least one component of a thermoplastic fiber is spin-dyed with at least one colorant (such as a pigment or dye). The smaller the drawing rate in stretching or false-twisting, the greater the fineness (the Denier count) of the fiber, and the higher the color strength. The greater the drawing rate in stretching or false-twisting, the smaller the fineness (the Denier count) of the fiber, and the lower the color strength. Via continuously varying the drawing rate, a fiber with gradient variation of color strength is obtained.
In the present invention, when a component of a fiber is spin-dyed, the total amount of all the colorants used in the component is 0.01-10 wt % of the component.
The present invention is characterized in obtaining gradient variation of color strength of a fiber via continuously and periodically varying at least one colorant quantity metered by colorant meters, continuously and periodically varying the output ratio of at least one melt extruder, or continuously and periodically varying the fineness of a fiber with a stretching method, a false-twisting method or another method. The present invention applies to any thermoplastic fiber. Via controlling at least one spinning condition of a spin-dyed component of a fiber, the present invention can mass-fabricate a gradient-color fiber and a fabric thereof without generating massive waste water.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows a linear relationship of spinning time and a colorant quantity metered by a colorant meter; FIG. 2 shows a nonlinear relationship of spinning time and a colorant quantity metered by a colorant meter;

FIG. 3 shows a linear relationship of spinning time and fiber fineness;

FIG. 4 shows a nonlinear relationship of spinning time and fiber fineness;

FIG. 5 shows a linear relationship of spinning time and an output ratio of a melt extruder; and

FIG. 6 shows a nonlinear relationship of spinning time and an output ratio of a melt extruder.

DETAILED DESCRIPTION OF THE INVENTION

Below, embodiments are used to demonstrate the technical contents of the present invention in detail. However, it should be understood that the embodiments are only to exemplify the present invention but not to limit the scope of the present invention. The present invention is characterized in that a thermoplastic fiber having at least one component spin-dyed in a melt extruder with at least one pigment or dye obtains gradient variation of color appearance via at least one of the following methods:
(1) Gradually varying at least one colorant quantity metered by at least one colorant meter according to a linear relationship (as shown in FIG. 1) or a nonlinear relationship (as shown in FIG. 2), wherein in FIG. 1 and FIG. 2, the horizontal axis denotes the spinning time, and the vertical axis denotes the colorant quantity metered by the colorant meter (the effect thereof is further described in Embodiment I);
(2) Continuously varying the drawing rate of a fiber in stretching or false twisting to gradually vary the fineness of the fiber and obtain gradient variation of the color strength of the fiber, wherein the fineness can be varied according to a linear relationship (as shown in FIG. 3) or a nonlinear relationship (as shown in FIG. 4), and wherein in FIG. 3 and FIG. 4, the horizontal axis denotes the spinning time, and the vertical axis denotes the fineness of the fiber;
(3) Gradually varying the output rate of a melt extruder of a monocomponent fiber according to a linear relationship (as shown in FIG. 5) or a nonlinear relationship (as shown in FIG. 6), wherein in FIG. 5 and FIG. 6, the horizontal axis denotes the spinning time, and the vertical axis denotes the output rate;
(4) Gradually varying the output ratio of at least one melt extruder of a component of a conjugate fiber according to a linear relationship (as shown in FIG. 5) or a nonlinear relationship (as shown in FIG. 6) (the effect thereof is further described in from Embodiment II to Embodiment VI);
(5) A combination of at least two of the abovementioned methods.
Via continuously varying the colorant quantity metered by at least one colorant meter, continuously varying the output ratio of at least one melt extruder, or continuously varying the fineness of a fiber with a stretching method, a false-twisting method or another method, the present invention can obtain a gradient-color fiber.
In the present invention, when a component of a fiber is spin-dyed, the total amount of all the colorants used in the component is 0.01-10wt % of the component. In the present invention, a fiber can be fabricated with various spinning methods, including a melt spray spinning method and methods to fabricate a staple fiber, a monocomponent filament yarn, a multicomponent filament yarn, and BCF (Bulked Continuous Filament). The fiber can be further processed with a stretching method or a false-twisting method.
In the present invention, the spin-dyed fiber is made of thermoplastic polymeric materials. Each of the components of a fiber is made of a material selected from a group consisting of polyester resins, polyester copolymers, polyamide resins, polyamide copolymers, polypropylene resins, polypropylene copolymers, polyethylene resins, polyethylene copolymers, and combinations thereof. A heat stabilizer, an antifire agent or an antiseptic agent may be added to any single component according to requirement.
In the present invention, a conjugate fiber can be fabricated with various conjugate methods, including a side-by-side compositing method, a sheath-core compositing method, a sea-island compositing method, a deformed sheath-core compositing method, and a partially-protruding sheath-core compositing method.
Below, embodiments are used to exemplify the effects of the present invention. In the embodiments, comparison of hue (L, a, b) or color intensity is realized via sampling a fiber fabricated in a specified time interval, winding the fiber sample around a white cardboard, obtaining hue or color intensity with a Datacolor SF600 spectrometer under a D65 light source having wavelengths of 400-700nm, wherein L denotes the lightness in a CIE model, a the chroma from green to red, b the chroma from blue to yellow.

Embodiment I

In Embodiment I, a spin-dyed gradient-color monocomponent polyester fiber is used to exemplify the effect of the present invention. The abovementioned fiber contains 0.3 wt % of a semi-dull PET resin and is spin-dyed by two colorant meters.
In this embodiment, Colorant Meter A meters a colorant Solvent Blue 45 by a concentration of 0.4 wt % of the fiber in the initial 480 seconds. Then, the concentration of the colorant Solvent Blue 45 is gradually increased to 0.56 wt % of the fiber. Colorant Meter B meters a colorant Carbon Black by a concentration of 0.6 wt % of the fiber in the initial 480 seconds. Then, the concentration of the colorant Carbon Black is gradually decreased to 0.36 wt % of the fiber.
The spinning conditions include a fusion temperature of 285° C., a spinning speed of 3200 m/min, POY (Partially Oriented Yarn), and 3.3 Denier per PET fiber.
The following table shows the comparison of hue (L, a, b) and color intensity of the initial fiber and the fiber sampled at a section 25600 m away from the beginning (at the 480^thsecond from the beginning). The table shows that a gradient-color fiber is obtained via continuously varying the concentrations of colorants metered by colorant meters.


Hue (L, a, b), Color strength	L	a	b	Color intensity

Sample taken at the beginning	25.60	−0.41	−3.77	As Standard
Sample taken at a section	27.55	−0.38	−6.53	83.7%
25600 m away from the
beginning

Embodiment II

In Embodiment II, a full-stretched spin-dyed gradient-color conjugate polyester fiber is used to exemplify the effect of the present invention. Component A of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Pigment Red 214 by a concentration of 0.6 wt % of Component A. Component B of the conjugate fiber is made of a polyester resin without spin-dyeing.
At the beginning, the output ratio of Component A from Melt Extruder A is 60% of the total output of the conjugate fiber. The output ratio of Component A is gradually increased to 70% of the total output of the conjugate fiber within 90 seconds. At the beginning, the output ratio of Component B from Melt Extruder B is 40% of the total output of the conjugate fiber. The output ratio of Component B is gradually decreased to 30% of the total output of the conjugate fiber within 90 seconds.
The spinning conditions include a fusion temperature of 285° C., a spinning speed of 4500 m/min, a drawing rate of 290%, and 3.0 Denier per PET conjugate fiber at the beginning.
The following table shows the comparison of hue ((L, a, b) and color intensity of the initial fiber and the fiber sampled at a section 6750 m away from the beginning (at the 90^thsecond from the beginning). The table shows that a gradient-color conjugate fiber is obtained via continuously varying the output ratio of the components.


Hue (L, a, b), Color strength	L	a	b	Color intensity

Sample taken at the	50.58	42.21	17.81	As Standard
beginning
Sample taken at a section	49.48	43.30	19.44	114.3%
6750 m away from the
beginning

Embodiment III

In Embodiment III, a spin-dyed gradient-color conjugate polyester fiber is used to exemplify the effect of the present invention.
Component A of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant titanium dioxide by a concentration of 1.7 wt % of Component A. Component B of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Solvent Red 135 by a concentration of 0.8 wt % of Component B.
At the beginning, the output ratio of Component A from Melt Extruder A is 30% of the total output of the conjugate fiber. The output ratio of Component A is gradually increased to 50% of the total output of the conjugate fiber within 120 seconds. At the beginning, the output ratio of Component B from Melt Extruder B is 70% of the total output of the conjugate fiber. The output ratio of Component B is gradually decreased to 50% of the total output of the conjugate fiber within 120 seconds.
The spinning conditions include a fusion temperature of 285° C., a spinning speed of 3200 m/min, POY (Partially Oriented Yarn), and 4.5 Denier per PET conjugate fiber at the beginning.
The following table shows the comparison of hue (L, a, b) and color intensity of the initial fiber and the fibers respectively sampled at sections 3200 m and 6400 m away from the beginning (at the 60^thsecond and 120^thsecond from the beginning). The table shows that a gradient-color conjugate fiber is obtained via continuously varying the output ratios of the components.


Hue (L, a, b), Color strength	L	a	b	Color intensity

Sample taken at the	53.95	43.69	28.61	As Standard
beginning
Sample taken at a section	57.16	41.97	24.77	72.0%
3200 m away from the
beginning
Sample taken at a section	60.61	38.79	20.85	49.9%
6400 m away from the
beginning

Embodiment IV

In Embodiment IV, a spin-dyed gradient-color conjugate polyester fiber is used to exemplify the effect of the present invention.
Component A of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Pigment Blue 15:3 by a concentration of 0.48 wt % of Component A and a colorant titanium dioxide by a concentration of 0.3 wt % of Component A. Component B of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Carbon Black by a concentration of 0.96 wt % of Component B.
At the beginning, the output ratio of Component A from Melt Extruder A is 50% of the total output of the conjugate fiber. The output ratio of Component A is gradually increased to 80% of the total output of the conjugate fiber within 180 seconds. At the beginning, the output ratio of Component B from Melt Extruder B is 50% of the total output of the conjugate fiber. The output ratio of Component B is gradually decreased to 20% of the total output of the conjugate fiber within 180 seconds.
The spinning conditions include a fusion temperature of 285° C., a spinning speed of 3200 m/min, POY (Partially Oriented Yarn), and 5.0 Denier per PET conjugate fiber at the beginning.
The following table shows the comparison of hue (L, a, b) and color intensity of the initial fiber and the fibers respectively sampled at sections 3200 m, 6400 m and 9600 m away from the beginning (at the 60^thsecond, the 120^thsecond and the 180^thsecond from the beginning). The table shows that a gradient-color conjugate fiber is obtained via continuously varying the output ratios of the components.


Hue (L, a, b), Color strength	L	a	b	Color intensity

Sample taken at the	25.76	−0.89	−1.8	As Standard
beginning
Sample taken at a section	26.21	−1.44	−3.18	94.8%
3200 m away from the
beginning
Sample taken at a section	29.51	−2.95	−6.39	71.6%
6400 m away from the
beginning
Sample taken at a section	31.27	−4.1	−9.74	61.5%
9600 m away from the
beginning

Embodiment V

In Embodiment V, a spin-dyed gradient-color conjugate polyester fiber is used to exemplify the effect of the present invention.
Component A of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Pigment Red 214 by a concentration of 0.51 wt % of Component A and a colorant titanium dioxide by a concentration of 0.3 wt % of Component A. Component B of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Disperse Violet 57 by a concentration of 0.17 wt % of Component B and a colorant titanium dioxide by a concentration of 0.3 wt % of Component B. At the beginning, the output ratio of Component A from Melt Extruder A is 50% of the total output of the conjugate fiber. The output ratio of Component A is gradually increased to 80% of the total output of the conjugate fiber within 180 seconds. At the beginning, the output ratio of Component B from Melt Extruder B is 50% of the total output of the conjugate fiber. The output ratio of Component B is gradually decreased to 20% of the total output of the conjugate fiber within 180 seconds.
The spinning conditions include a fusion temperature of 285° C., a spinning speed of 3200 m/min, POY (Partially Oriented Yarn), and 4.5 Denier per PET conjugate fiber at the beginning.
The following table shows the comparison of hue (L, a, b) and color intensity of the initial fiber and the fibers respectively sampled at sections 3200 m, 6400 m and 9600 m away from the beginning (at the 60^thsecond, the 120^thsecond and the 180^thsecond from the beginning). The table shows that a gradient-color conjugate fiber is obtained via continuously varying the output ratios of the components.


Hue (L, a, b), Color strength	L	a	b	Color intensity

Sample taken at the beginning	39.78	19.22	−7.85	As Standard
Sample taken at a section	40.92	23.94	−0.42	109.5%
3200 m away from the
beginning
Sample taken at a section	41.31	26.72	5.40	122.6%
6400 m away from the
beginning
Sample taken at a section	43.38	30.36	10.26	123.1%
9600 m away from the
beginning

Embodiment VI

In Embodiment VI, a spin-dyed gradient-color conjugate polyamide (Nylon) fiber is used to exemplify the effect of the present invention.
Component A of the conjugate fiber is made of a polyamide resin and spin-dyed with a colorant Pigment Blue 15:3 by a concentration of 0.5 wt % of Component A. Component B of the conjugate fiber is made of a polyamide resin and spin-dyed with a colorant Pigment Green 7 by a concentration of 0.5 wt % of Component B.
At the beginning, the output ratio of Component A from Melt Extruder A is 50% of the total output of the conjugate fiber. The output ratio of Component A is gradually increased to 80% of the total output of the conjugate fiber within 180 seconds. At the beginning, the output ratio of Component B from Melt Extruder B is 50% of the total output of the conjugate fiber. The output ratio of Component B is gradually decreased to 20% of the total output of the conjugate fiber within 180 seconds.
The spinning conditions include a fusion temperature of 2805° C., a spinning speed of 4300 m/min, an drawing rate of 250%, and 4.5 Denier per polyamide conjugate fiber at the beginning.
The following table shows the comparison of hue (L, a, b) and color intensity of the initial fiber and the fibers respectively sampled at sections 4300 m, 8600 m and 12900 m away from the beginning (at the 60^thsecond, the 120^thsecond and the 180^thsecond from the beginning). The table shows that a gradient-color conjugate fiber is obtained via continuously varying the output ratios of the components.


Hue (L, a, b), Color strength	L	a	b	Color intensity

Sample taken at the	45.91	−29.22	−18.28	As Standard
beginning
Sample taken at a section	46.29	−26.63	−24.27	93.0%
4300 m away from the
beginning
Sample taken at a section	45.53	−24.77	−26.88	95.1%
8600 m away from the
beginning
Sample taken at a section	47.51	−24.05	−30.54	83.4%
12900 m away from the
beginning

The embodiments described above are only to exemplify the present invention but not to limit the scope of the present invention. Any equivalent modification or variation according to the claims and specification of the present invention is to be also included within the scope of the present invention.

Claims

1-9. (canceled)

10. A method for fabricating a spin-dyed gradient-color fiber, characterized in performing spin-dyeing in a melt extruder to spin-dye a monocomponent thermoplastic fiber or a multicomponent conjugate thermoplastic fiber containing at least two components, and continuously and periodically varying the output ratio of said melt extruder to provide gradient color for said thermoplastic fiber.

11. The method for fabricating a spin-dyed gradient-color fiber according to claim 10, wherein said monocomponent thermoplastic fiber or each of said components of said thermoplastic conjugate fiber is made of a material selected from a group consisting of polyester resins, polyester copolymers, polyamide resins, polyamide copolymers, polypropylene resins, polypropylene copolymers, polyethylene resins, polyethylene copolymers, and combinations thereof.

12. A method for fabricating a spin-dyed gradient-color fiber, characterized in respectively performing spin-dyeing in at least two melt extruders with identical colorants wherein at least one said extruder has a colorant concentration different to colorant concentrations of other said extruders to spin-dye a monocomponent thermoplastic fiber or a multicomponent conjugate thermoplastic fiber containing at least two components, and continuously and periodically varying a output ratio of at least one of said melt extruders to provide gradient color for said thermoplastic fiber.

13. The method for fabricating a spin-dyed gradient-color fiber according to claim 12, wherein said monocomponent thermoplastic fiber or each of said components of said conjugate fiber is made of a material selected from a group consisting of polyester resins, polyester copolymers, polyamide resins, polyamide copolymers, polypropylene resins, polypropylene copolymers, polyethylene resins, polyethylene copolymers, and combinations thereof.

14. A method for fabricating a spin-dyed gradient-color fiber, characterized in respectively performing spin-dyeing in at least two melt extruders with different colorants to spin-dye a monocomponent thermoplastic fiber or a multicomponent conjugate thermoplastic fiber containing at least two components, and continuously and periodically varying a output ratio of at least one of said melt extruders to provide gradient color for said thermoplastic fiber.

15. The method for fabricating a spin-dyed gradient-color fiber according to claim 14, wherein said monocomponent thermoplastic fiber or each of said components of said thermoplastic fiber is made of a material selected from a group consisting of polyester resins, polyester copolymers, polyamide resins, polyamide copolymers, polypropylene resins, polypropylene copolymers, polyethylene resins, polyethylene copolymers, and combinations thereof.