US20110210462A1 - Spin-Dyed Gradient-Color Fiber and Method for Fabricating the Same - Google Patents
Spin-Dyed Gradient-Color Fiber and Method for Fabricating the Same Download PDFInfo
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- US20110210462A1 US20110210462A1 US13/056,549 US200813056549A US2011210462A1 US 20110210462 A1 US20110210462 A1 US 20110210462A1 US 200813056549 A US200813056549 A US 200813056549A US 2011210462 A1 US2011210462 A1 US 2011210462A1
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/04—Pigments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/06—Dyes
Definitions
- the present invention relates to a gradient-color fiber and a method for fabricating the same, particularly to a spin-dyed gradient-color thermoplastic fiber and a method for fabricating the same.
- Gradient-color fiber and fabric is usually fabricated with a pigment-printing or bath-dyeing method.
- pigment printing and bath dyeing generates a great amount of waste water and causes environmental protection problems.
- a China patent No. CN2564602Y disclosed a fiber gradient-coloring device, which adopts a spray-dyeing method to obtain gradient-color fiber.
- the prior art has lower productivity and poor color fastness.
- a France patent No. FR2682130 disclosed a fiber gradient-coloring technology, wherein fiber are disposed on a supporter and slowly immersed into a dye bath, whereby different parts of fiber are dyed for different lengths of time to have gradient variation of color.
- the prior art is realized with bath dyeing, which generates a great amount of waste water and damages the environment.
- a Canada patent disclosed a fabric gradient-coloring technology, wherein different portions of a fabric are respectively disposed at different altitudes and dyed for different lengths of time via gradually releasing the dye solution to obtain gradient variation of color.
- the prior art is realized with bath dyeing and generates a great amount of waste water.
- One objective of the present invention is to provide a spin-dyed gradient-color fiber and a method for fabricating the same to solve the abovementioned problems, wherein at least one component of fiber is spin-dyed to attain gradient color via controlling at least one spinning condition, whereby a gradient-color fiber can be efficiently produced without generating massive waste water.
- the present invention proposes a spin-dyed gradient-color fiber and a method for fabricating the same, which are characterized in that at least one component of a thermoplastic fiber is spin-dyed with the dye quantity being gradually varied to attain gradient variation of color.
- the present invention is applied to spin-dyed thermoplastic fiber and realized via controlling at least one of the following spinning conditions:
- Colorant quantity continuously varying quantity of at least one colorant metered by colorant meters when a monocomponent or a conjugate fiber containing at least two components is spin-dyed in at least one melt extruder;
- Drawing rate continuously varying the drawing rate of at least one component of a monocomponent or a conjugate fiber containing at least two components when the monocomponent or conjugate fiber is spin-dyed in at least one melt extruder;
- Output Ratio continuously varying the output ratio of at least one component of a monocomponent or a conjugate fiber containing at least two components when the monocomponent or conjugate fiber is spin-dyed in at least one melt extruder.
- thermoplastic fiber used in the present invention is made of a thermoplastic resin selected from a group consisting of polyester resins, polyester copolymers, polyamide resins, polyamide copolymers, polypropylene resins, polypropylene copolymers, polyethylene resins, polyethylene copolymers, and combinations thereof.
- thermoplastic fiber When a thermoplastic fiber is colored with a pigment or dye, the color tint varies with the quantity of the pigment or dye. Via continuously varying the quantity of the pigment or dye, the fiber will have gradient color.
- the quantity of a pigment or dye is controlled via the following methods:
- Gradient color of a thermoplastic fiber can be alternatively obtained via continuously varying the fineness of the thermoplastic fiber when the thermoplastic fiber is spin-dyed with at least one pigment or dye.
- the fineness of a thermoplastic fiber can be varied via the following methods:
- thermoplastic fiber and the fabric made thereof can be obtained via controlling at least one of the following spinning conditions:
- Colorant quantity continuously and periodically varying at least one colorant quantity metered by colorant meters
- thermoplastic fiber is spin-dyed with at least one pigment or dye.
- the greater the output ratio of the melt extruder of the spin-dyed component the deeper the color.
- the smaller the output ratio of the melt extruder of the spin-dyed component the lighter the color. Continuously varying the output ratio generates gradient variation of color strength.
- thermoplastic conjugate fiber are spin-dyed with an identical colorant (such as a pigment or a dye) and that the concentrations of the pigment or dye are different for the at least two components.
- concentrations of the pigment or dye are different for the at least two components.
- the smaller the output ratio of the melt extruder of a component spin-dyed with a higher concentration the lighter the color.
- the method can generate gradient variation of color strength, the range of color strength variation is limited.
- thermoplastic fiber are respectively spin-dyed with different colorants (such as pigments or dyes).
- different colorants such as pigments or dyes.
- the greater the output ratio of the melt extruder of one of the at least two spin-dyed components the closer the hue of the thermoplastic fiber to that of the component.
- the smaller the output ratio of the melt extruder of one of the at least two spin-dyed components the closer the hue of the thermoplastic fiber to that of another component.
- the proportion of the components is varied continuously, the hue of the thermoplastic fiber is also varied continuously. Via continuously varying the output ratios of the components, a gradient-color conjugate fiber having hue variation is obtained.
- thermoplastic fiber is spin-dyed with at least one colorant (such as a pigment or dye).
- the total amount of all the colorants used in the component is 0.01-10 wt % of the component.
- the present invention is characterized in obtaining gradient variation of color strength of a fiber via continuously and periodically varying at least one colorant quantity metered by colorant meters, continuously and periodically varying the output ratio of at least one melt extruder, or continuously and periodically varying the fineness of a fiber with a stretching method, a false-twisting method or another method.
- the present invention applies to any thermoplastic fiber. Via controlling at least one spinning condition of a spin-dyed component of a fiber, the present invention can mass-fabricate a gradient-color fiber and a fabric thereof without generating massive waste water.
- FIG. 1 shows a linear relationship of spinning time and a colorant quantity metered by a colorant meter
- FIG. 2 shows a nonlinear relationship of spinning time and a colorant quantity metered by a colorant meter
- FIG. 3 shows a linear relationship of spinning time and fiber fineness
- FIG. 4 shows a nonlinear relationship of spinning time and fiber fineness
- FIG. 5 shows a linear relationship of spinning time and an output ratio of a melt extruder
- FIG. 6 shows a nonlinear relationship of spinning time and an output ratio of a melt extruder.
- thermoplastic fiber having at least one component spin-dyed in a melt extruder with at least one pigment or dye obtains gradient variation of color appearance via at least one of the following methods:
- the present invention can obtain a gradient-color fiber.
- a fiber when a component of a fiber is spin-dyed, the total amount of all the colorants used in the component is 0.01-10wt % of the component.
- a fiber can be fabricated with various spinning methods, including a melt spray spinning method and methods to fabricate a staple fiber, a monocomponent filament yarn, a multicomponent filament yarn, and BCF (Bulked Continuous Filament).
- the fiber can be further processed with a stretching method or a false-twisting method.
- the spin-dyed fiber is made of thermoplastic polymeric materials.
- Each of the components of a fiber is made of a material selected from a group consisting of polyester resins, polyester copolymers, polyamide resins, polyamide copolymers, polypropylene resins, polypropylene copolymers, polyethylene resins, polyethylene copolymers, and combinations thereof.
- a heat stabilizer, an antifire agent or an antiseptic agent may be added to any single component according to requirement.
- a conjugate fiber can be fabricated with various conjugate methods, including a side-by-side compositing method, a sheath-core compositing method, a sea-island compositing method, a deformed sheath-core compositing method, and a partially-protruding sheath-core compositing method.
- comparison of hue (L, a, b) or color intensity is realized via sampling a fiber fabricated in a specified time interval, winding the fiber sample around a white cardboard, obtaining hue or color intensity with a Datacolor SF600 spectrometer under a D65 light source having wavelengths of 400-700nm, wherein L denotes the lightness in a CIE model, a the chroma from green to red, b the chroma from blue to yellow.
- a spin-dyed gradient-color monocomponent polyester fiber is used to exemplify the effect of the present invention.
- the abovementioned fiber contains 0.3 wt % of a semi-dull PET resin and is spin-dyed by two colorant meters.
- Colorant Meter A meters a colorant Solvent Blue 45 by a concentration of 0.4 wt % of the fiber in the initial 480 seconds. Then, the concentration of the colorant Solvent Blue 45 is gradually increased to 0.56 wt % of the fiber.
- Colorant Meter B meters a colorant Carbon Black by a concentration of 0.6 wt % of the fiber in the initial 480 seconds. Then, the concentration of the colorant Carbon Black is gradually decreased to 0.36 wt % of the fiber.
- the spinning conditions include a fusion temperature of 285° C., a spinning speed of 3200 m/min, POY (Partially Oriented Yarn), and 3.3 Denier per PET fiber.
- the following table shows the comparison of hue (L, a, b) and color intensity of the initial fiber and the fiber sampled at a section 25600 m away from the beginning (at the 480 th second from the beginning).
- the table shows that a gradient-color fiber is obtained via continuously varying the concentrations of colorants metered by colorant meters.
- a full-stretched spin-dyed gradient-color conjugate polyester fiber is used to exemplify the effect of the present invention.
- Component A of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Pigment Red 214 by a concentration of 0.6 wt % of Component A.
- Component B of the conjugate fiber is made of a polyester resin without spin-dyeing.
- the output ratio of Component A from Melt Extruder A is 60% of the total output of the conjugate fiber.
- the output ratio of Component A is gradually increased to 70% of the total output of the conjugate fiber within 90 seconds.
- the output ratio of Component B from Melt Extruder B is 40% of the total output of the conjugate fiber.
- the output ratio of Component B is gradually decreased to 30% of the total output of the conjugate fiber within 90 seconds.
- the spinning conditions include a fusion temperature of 285° C., a spinning speed of 4500 m/min, a drawing rate of 290%, and 3.0 Denier per PET conjugate fiber at the beginning.
- the following table shows the comparison of hue ((L, a, b) and color intensity of the initial fiber and the fiber sampled at a section 6750 m away from the beginning (at the 90 th second from the beginning).
- the table shows that a gradient-color conjugate fiber is obtained via continuously varying the output ratio of the components.
- Embodiment III a spin-dyed gradient-color conjugate polyester fiber is used to exemplify the effect of the present invention.
- Component A of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant titanium dioxide by a concentration of 1.7 wt % of Component A.
- Component B of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Solvent Red 135 by a concentration of 0.8 wt % of Component B.
- the output ratio of Component A from Melt Extruder A is 30% of the total output of the conjugate fiber.
- the output ratio of Component A is gradually increased to 50% of the total output of the conjugate fiber within 120 seconds.
- the output ratio of Component B from Melt Extruder B is 70% of the total output of the conjugate fiber.
- the output ratio of Component B is gradually decreased to 50% of the total output of the conjugate fiber within 120 seconds.
- the spinning conditions include a fusion temperature of 285° C., a spinning speed of 3200 m/min, POY (Partially Oriented Yarn), and 4.5 Denier per PET conjugate fiber at the beginning.
- the following table shows the comparison of hue (L, a, b) and color intensity of the initial fiber and the fibers respectively sampled at sections 3200 m and 6400 m away from the beginning (at the 60 th second and 120 th second from the beginning).
- the table shows that a gradient-color conjugate fiber is obtained via continuously varying the output ratios of the components.
- Embodiment IV a spin-dyed gradient-color conjugate polyester fiber is used to exemplify the effect of the present invention.
- Component A of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Pigment Blue 15:3 by a concentration of 0.48 wt % of Component A and a colorant titanium dioxide by a concentration of 0.3 wt % of Component A.
- Component B of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Carbon Black by a concentration of 0.96 wt % of Component B.
- the output ratio of Component A from Melt Extruder A is 50% of the total output of the conjugate fiber.
- the output ratio of Component A is gradually increased to 80% of the total output of the conjugate fiber within 180 seconds.
- the output ratio of Component B from Melt Extruder B is 50% of the total output of the conjugate fiber.
- the output ratio of Component B is gradually decreased to 20% of the total output of the conjugate fiber within 180 seconds.
- the spinning conditions include a fusion temperature of 285° C., a spinning speed of 3200 m/min, POY (Partially Oriented Yarn), and 5.0 Denier per PET conjugate fiber at the beginning.
- the following table shows the comparison of hue (L, a, b) and color intensity of the initial fiber and the fibers respectively sampled at sections 3200 m, 6400 m and 9600 m away from the beginning (at the 60 th second, the 120 th second and the 180 th second from the beginning).
- the table shows that a gradient-color conjugate fiber is obtained via continuously varying the output ratios of the components.
- Embodiment V a spin-dyed gradient-color conjugate polyester fiber is used to exemplify the effect of the present invention.
- Component A of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Pigment Red 214 by a concentration of 0.51 wt % of Component A and a colorant titanium dioxide by a concentration of 0.3 wt % of Component A.
- Component B of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Disperse Violet 57 by a concentration of 0.17 wt % of Component B and a colorant titanium dioxide by a concentration of 0.3 wt % of Component B.
- the output ratio of Component A from Melt Extruder A is 50% of the total output of the conjugate fiber.
- the output ratio of Component A is gradually increased to 80% of the total output of the conjugate fiber within 180 seconds.
- the output ratio of Component B from Melt Extruder B is 50% of the total output of the conjugate fiber.
- the output ratio of Component B is gradually decreased to 20% of the total output of the conjugate fiber within 180 seconds.
- the spinning conditions include a fusion temperature of 285° C., a spinning speed of 3200 m/min, POY (Partially Oriented Yarn), and 4.5 Denier per PET conjugate fiber at the beginning.
- the following table shows the comparison of hue (L, a, b) and color intensity of the initial fiber and the fibers respectively sampled at sections 3200 m, 6400 m and 9600 m away from the beginning (at the 60 th second, the 120 th second and the 180 th second from the beginning).
- the table shows that a gradient-color conjugate fiber is obtained via continuously varying the output ratios of the components.
- Embodiment VI a spin-dyed gradient-color conjugate polyamide (Nylon) fiber is used to exemplify the effect of the present invention.
- Component A of the conjugate fiber is made of a polyamide resin and spin-dyed with a colorant Pigment Blue 15:3 by a concentration of 0.5 wt % of Component A.
- Component B of the conjugate fiber is made of a polyamide resin and spin-dyed with a colorant Pigment Green 7 by a concentration of 0.5 wt % of Component B.
- the output ratio of Component A from Melt Extruder A is 50% of the total output of the conjugate fiber.
- the output ratio of Component A is gradually increased to 80% of the total output of the conjugate fiber within 180 seconds.
- the output ratio of Component B from Melt Extruder B is 50% of the total output of the conjugate fiber.
- the output ratio of Component B is gradually decreased to 20% of the total output of the conjugate fiber within 180 seconds.
- the spinning conditions include a fusion temperature of 2805° C., a spinning speed of 4300 m/min, an drawing rate of 250%, and 4.5 Denier per polyamide conjugate fiber at the beginning.
- the following table shows the comparison of hue (L, a, b) and color intensity of the initial fiber and the fibers respectively sampled at sections 4300 m, 8600 m and 12900 m away from the beginning (at the 60 th second, the 120 th second and the 180 th second from the beginning).
- the table shows that a gradient-color conjugate fiber is obtained via continuously varying the output ratios of the components.
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Abstract
The present invention discloses a spin-dyed gradient-color fiber and a method for fabricating the same, wherein at least one component of the fiber is spin-dyed. The present invention obtains gradient color via controlling at least one of the following spinning conditions: (1) colorant quantity: continuously varying quantity of at least one colorant metered by colorant meters; (2) output ratio: continuously varying the output ratio of at least one melt extruder; (3) fineness: varying fineness of the fiber in a stretching way, a false-twisting way or another way.
Description
- 1. Field of the Invention
- The present invention relates to a gradient-color fiber and a method for fabricating the same, particularly to a spin-dyed gradient-color thermoplastic fiber and a method for fabricating the same.
- 2. Description of the Related Art
- Gradient-color fiber and fabric is usually fabricated with a pigment-printing or bath-dyeing method. However, pigment printing and bath dyeing generates a great amount of waste water and causes environmental protection problems.
- A China patent No. CN2564602Y disclosed a fiber gradient-coloring device, which adopts a spray-dyeing method to obtain gradient-color fiber. However, the prior art has lower productivity and poor color fastness.
- A France patent No. FR2682130 disclosed a fiber gradient-coloring technology, wherein fiber are disposed on a supporter and slowly immersed into a dye bath, whereby different parts of fiber are dyed for different lengths of time to have gradient variation of color. However, the prior art is realized with bath dyeing, which generates a great amount of waste water and damages the environment.
- A Canada patent disclosed a fabric gradient-coloring technology, wherein different portions of a fabric are respectively disposed at different altitudes and dyed for different lengths of time via gradually releasing the dye solution to obtain gradient variation of color. However, the prior art is realized with bath dyeing and generates a great amount of waste water.
- Thus, how to fabricate gradient-color fiber without generating massive waste water has been an important subject in the field concerned.
- One objective of the present invention is to provide a spin-dyed gradient-color fiber and a method for fabricating the same to solve the abovementioned problems, wherein at least one component of fiber is spin-dyed to attain gradient color via controlling at least one spinning condition, whereby a gradient-color fiber can be efficiently produced without generating massive waste water.
- To achieve the abovementioned objective, the present invention proposes a spin-dyed gradient-color fiber and a method for fabricating the same, which are characterized in that at least one component of a thermoplastic fiber is spin-dyed with the dye quantity being gradually varied to attain gradient variation of color. The present invention is applied to spin-dyed thermoplastic fiber and realized via controlling at least one of the following spinning conditions:
- (1) Colorant quantity: continuously varying quantity of at least one colorant metered by colorant meters when a monocomponent or a conjugate fiber containing at least two components is spin-dyed in at least one melt extruder;
- (2) Drawing rate: continuously varying the drawing rate of at least one component of a monocomponent or a conjugate fiber containing at least two components when the monocomponent or conjugate fiber is spin-dyed in at least one melt extruder; and
- (3) Output Ratio: continuously varying the output ratio of at least one component of a monocomponent or a conjugate fiber containing at least two components when the monocomponent or conjugate fiber is spin-dyed in at least one melt extruder.
- The thermoplastic fiber used in the present invention is made of a thermoplastic resin selected from a group consisting of polyester resins, polyester copolymers, polyamide resins, polyamide copolymers, polypropylene resins, polypropylene copolymers, polyethylene resins, polyethylene copolymers, and combinations thereof.
- When a thermoplastic fiber is colored with a pigment or dye, the color tint varies with the quantity of the pigment or dye. Via continuously varying the quantity of the pigment or dye, the fiber will have gradient color. The quantity of a pigment or dye is controlled via the following methods:
- (1) Continuously and periodically varying colorant quantities metered by colorant meters;
- (2) Continuously and periodically varying the output ratio of at least one melt extruder when the component is spin-dyed in the melt extruder; and
- (3) A combination of the abovementioned methods.
- Gradient color of a thermoplastic fiber can be alternatively obtained via continuously varying the fineness of the thermoplastic fiber when the thermoplastic fiber is spin-dyed with at least one pigment or dye. The fineness of a thermoplastic fiber can be varied via the following methods:
- (1) Continuously and periodically varying the total output ratio of the melt extruders via continuously and periodically varying the output ratio of at least one of the melt extruders;
- (2) Continuously and periodically varying the drawing rate of the thermoplastic fiber with a stretching method, a false-twisting method or another method; and (3) A combination of the abovementioned methods.
- In summary, when at least one component of a thermoplastic fiber is spin-dyed, gradient color of the thermoplastic fiber and the fabric made thereof can be obtained via controlling at least one of the following spinning conditions:
- (1) Colorant quantity: continuously and periodically varying at least one colorant quantity metered by colorant meters;
- (2) Output ratio: continuously and periodically varying the output ratio of at least one melt extruder with the total output ratio remaining constant or varying continuously; and (3) Fineness: continuously and periodically varying the fineness of the thermoplastic fiber via a stretching method, a false-twisting method or another method.
- Different methods mentioned above generate different gradient effects. Some methods do not generate obvious variation of hue but only result in variation of color strength. Some methods generate obvious gradient variation of hue. The details thereof are further demonstrated below.
- (1) If there is only a single colorant metered by a colorant meter, continuously varying the quantity of the single colorant results in only gradient variation of color strength. If at least two colorants are respectively metered by colorant meters, continuously varying the quantity of at least one of the colorants obtains obvious gradient variation of hue.
- (2) Suppose that only a component of a thermoplastic fiber is spin-dyed with at least one pigment or dye. The greater the output ratio of the melt extruder of the spin-dyed component, the deeper the color. The smaller the output ratio of the melt extruder of the spin-dyed component, the lighter the color. Continuously varying the output ratio generates gradient variation of color strength.
- Suppose that at least two components of a thermoplastic conjugate fiber are spin-dyed with an identical colorant (such as a pigment or a dye) and that the concentrations of the pigment or dye are different for the at least two components. The greater the output ratio of the melt extruder of a component spin-dyed with a higher concentration, the deeper the color. The smaller the output ratio of the melt extruder of a component spin-dyed with a higher concentration, the lighter the color. Although the method can generate gradient variation of color strength, the range of color strength variation is limited.
- Suppose that at least two components of a thermoplastic fiber are respectively spin-dyed with different colorants (such as pigments or dyes). The greater the output ratio of the melt extruder of one of the at least two spin-dyed components, the closer the hue of the thermoplastic fiber to that of the component. The smaller the output ratio of the melt extruder of one of the at least two spin-dyed components, the closer the hue of the thermoplastic fiber to that of another component. When the proportion of the components is varied continuously, the hue of the thermoplastic fiber is also varied continuously. Via continuously varying the output ratios of the components, a gradient-color conjugate fiber having hue variation is obtained.
- (3) Suppose that at least one component of a thermoplastic fiber is spin-dyed with at least one colorant (such as a pigment or dye). The smaller the drawing rate in stretching or false-twisting, the greater the fineness (the Denier count) of the fiber, and the higher the color strength. The greater the drawing rate in stretching or false-twisting, the smaller the fineness (the Denier count) of the fiber, and the lower the color strength. Via continuously varying the drawing rate, a fiber with gradient variation of color strength is obtained.
- In the present invention, when a component of a fiber is spin-dyed, the total amount of all the colorants used in the component is 0.01-10 wt % of the component.
- The present invention is characterized in obtaining gradient variation of color strength of a fiber via continuously and periodically varying at least one colorant quantity metered by colorant meters, continuously and periodically varying the output ratio of at least one melt extruder, or continuously and periodically varying the fineness of a fiber with a stretching method, a false-twisting method or another method. The present invention applies to any thermoplastic fiber. Via controlling at least one spinning condition of a spin-dyed component of a fiber, the present invention can mass-fabricate a gradient-color fiber and a fabric thereof without generating massive waste water.
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FIG. 1 shows a linear relationship of spinning time and a colorant quantity metered by a colorant meter;FIG. 2 shows a nonlinear relationship of spinning time and a colorant quantity metered by a colorant meter; -
FIG. 3 shows a linear relationship of spinning time and fiber fineness; -
FIG. 4 shows a nonlinear relationship of spinning time and fiber fineness; -
FIG. 5 shows a linear relationship of spinning time and an output ratio of a melt extruder; and -
FIG. 6 shows a nonlinear relationship of spinning time and an output ratio of a melt extruder. - Below, embodiments are used to demonstrate the technical contents of the present invention in detail. However, it should be understood that the embodiments are only to exemplify the present invention but not to limit the scope of the present invention. The present invention is characterized in that a thermoplastic fiber having at least one component spin-dyed in a melt extruder with at least one pigment or dye obtains gradient variation of color appearance via at least one of the following methods:
- (1) Gradually varying at least one colorant quantity metered by at least one colorant meter according to a linear relationship (as shown in
FIG. 1 ) or a nonlinear relationship (as shown inFIG. 2 ), wherein inFIG. 1 andFIG. 2 , the horizontal axis denotes the spinning time, and the vertical axis denotes the colorant quantity metered by the colorant meter (the effect thereof is further described in Embodiment I); - (2) Continuously varying the drawing rate of a fiber in stretching or false twisting to gradually vary the fineness of the fiber and obtain gradient variation of the color strength of the fiber, wherein the fineness can be varied according to a linear relationship (as shown in
FIG. 3 ) or a nonlinear relationship (as shown inFIG. 4 ), and wherein inFIG. 3 andFIG. 4 , the horizontal axis denotes the spinning time, and the vertical axis denotes the fineness of the fiber; - (3) Gradually varying the output rate of a melt extruder of a monocomponent fiber according to a linear relationship (as shown in
FIG. 5 ) or a nonlinear relationship (as shown inFIG. 6 ), wherein inFIG. 5 andFIG. 6 , the horizontal axis denotes the spinning time, and the vertical axis denotes the output rate; - (4) Gradually varying the output ratio of at least one melt extruder of a component of a conjugate fiber according to a linear relationship (as shown in
FIG. 5 ) or a nonlinear relationship (as shown inFIG. 6 ) (the effect thereof is further described in from Embodiment II to Embodiment VI); - (5) A combination of at least two of the abovementioned methods.
- Via continuously varying the colorant quantity metered by at least one colorant meter, continuously varying the output ratio of at least one melt extruder, or continuously varying the fineness of a fiber with a stretching method, a false-twisting method or another method, the present invention can obtain a gradient-color fiber.
- In the present invention, when a component of a fiber is spin-dyed, the total amount of all the colorants used in the component is 0.01-10wt % of the component. In the present invention, a fiber can be fabricated with various spinning methods, including a melt spray spinning method and methods to fabricate a staple fiber, a monocomponent filament yarn, a multicomponent filament yarn, and BCF (Bulked Continuous Filament). The fiber can be further processed with a stretching method or a false-twisting method.
- In the present invention, the spin-dyed fiber is made of thermoplastic polymeric materials. Each of the components of a fiber is made of a material selected from a group consisting of polyester resins, polyester copolymers, polyamide resins, polyamide copolymers, polypropylene resins, polypropylene copolymers, polyethylene resins, polyethylene copolymers, and combinations thereof. A heat stabilizer, an antifire agent or an antiseptic agent may be added to any single component according to requirement.
- In the present invention, a conjugate fiber can be fabricated with various conjugate methods, including a side-by-side compositing method, a sheath-core compositing method, a sea-island compositing method, a deformed sheath-core compositing method, and a partially-protruding sheath-core compositing method.
- Below, embodiments are used to exemplify the effects of the present invention. In the embodiments, comparison of hue (L, a, b) or color intensity is realized via sampling a fiber fabricated in a specified time interval, winding the fiber sample around a white cardboard, obtaining hue or color intensity with a Datacolor SF600 spectrometer under a D65 light source having wavelengths of 400-700nm, wherein L denotes the lightness in a CIE model, a the chroma from green to red, b the chroma from blue to yellow.
- In Embodiment I, a spin-dyed gradient-color monocomponent polyester fiber is used to exemplify the effect of the present invention. The abovementioned fiber contains 0.3 wt % of a semi-dull PET resin and is spin-dyed by two colorant meters.
- In this embodiment, Colorant Meter A meters a colorant Solvent Blue 45 by a concentration of 0.4 wt % of the fiber in the initial 480 seconds. Then, the concentration of the colorant Solvent Blue 45 is gradually increased to 0.56 wt % of the fiber. Colorant Meter B meters a colorant Carbon Black by a concentration of 0.6 wt % of the fiber in the initial 480 seconds. Then, the concentration of the colorant Carbon Black is gradually decreased to 0.36 wt % of the fiber.
- The spinning conditions include a fusion temperature of 285° C., a spinning speed of 3200 m/min, POY (Partially Oriented Yarn), and 3.3 Denier per PET fiber.
- The following table shows the comparison of hue (L, a, b) and color intensity of the initial fiber and the fiber sampled at a section 25600 m away from the beginning (at the 480th second from the beginning). The table shows that a gradient-color fiber is obtained via continuously varying the concentrations of colorants metered by colorant meters.
-
Hue (L, a, b), Color strength L a b Color intensity Sample taken at the beginning 25.60 −0.41 −3.77 As Standard Sample taken at a section 27.55 −0.38 −6.53 83.7% 25600 m away from the beginning - In Embodiment II, a full-stretched spin-dyed gradient-color conjugate polyester fiber is used to exemplify the effect of the present invention. Component A of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Pigment Red 214 by a concentration of 0.6 wt % of Component A. Component B of the conjugate fiber is made of a polyester resin without spin-dyeing.
- At the beginning, the output ratio of Component A from Melt Extruder A is 60% of the total output of the conjugate fiber. The output ratio of Component A is gradually increased to 70% of the total output of the conjugate fiber within 90 seconds. At the beginning, the output ratio of Component B from Melt Extruder B is 40% of the total output of the conjugate fiber. The output ratio of Component B is gradually decreased to 30% of the total output of the conjugate fiber within 90 seconds.
- The spinning conditions include a fusion temperature of 285° C., a spinning speed of 4500 m/min, a drawing rate of 290%, and 3.0 Denier per PET conjugate fiber at the beginning.
- The following table shows the comparison of hue ((L, a, b) and color intensity of the initial fiber and the fiber sampled at a section 6750 m away from the beginning (at the 90th second from the beginning). The table shows that a gradient-color conjugate fiber is obtained via continuously varying the output ratio of the components.
-
Hue (L, a, b), Color strength L a b Color intensity Sample taken at the 50.58 42.21 17.81 As Standard beginning Sample taken at a section 49.48 43.30 19.44 114.3% 6750 m away from the beginning - In Embodiment III, a spin-dyed gradient-color conjugate polyester fiber is used to exemplify the effect of the present invention.
- Component A of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant titanium dioxide by a concentration of 1.7 wt % of Component A. Component B of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Solvent Red 135 by a concentration of 0.8 wt % of Component B.
- At the beginning, the output ratio of Component A from Melt Extruder A is 30% of the total output of the conjugate fiber. The output ratio of Component A is gradually increased to 50% of the total output of the conjugate fiber within 120 seconds. At the beginning, the output ratio of Component B from Melt Extruder B is 70% of the total output of the conjugate fiber. The output ratio of Component B is gradually decreased to 50% of the total output of the conjugate fiber within 120 seconds.
- The spinning conditions include a fusion temperature of 285° C., a spinning speed of 3200 m/min, POY (Partially Oriented Yarn), and 4.5 Denier per PET conjugate fiber at the beginning.
- The following table shows the comparison of hue (L, a, b) and color intensity of the initial fiber and the fibers respectively sampled at sections 3200 m and 6400 m away from the beginning (at the 60th second and 120th second from the beginning). The table shows that a gradient-color conjugate fiber is obtained via continuously varying the output ratios of the components.
-
Hue (L, a, b), Color strength L a b Color intensity Sample taken at the 53.95 43.69 28.61 As Standard beginning Sample taken at a section 57.16 41.97 24.77 72.0% 3200 m away from the beginning Sample taken at a section 60.61 38.79 20.85 49.9% 6400 m away from the beginning - In Embodiment IV, a spin-dyed gradient-color conjugate polyester fiber is used to exemplify the effect of the present invention.
- Component A of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Pigment Blue 15:3 by a concentration of 0.48 wt % of Component A and a colorant titanium dioxide by a concentration of 0.3 wt % of Component A. Component B of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Carbon Black by a concentration of 0.96 wt % of Component B.
- At the beginning, the output ratio of Component A from Melt Extruder A is 50% of the total output of the conjugate fiber. The output ratio of Component A is gradually increased to 80% of the total output of the conjugate fiber within 180 seconds. At the beginning, the output ratio of Component B from Melt Extruder B is 50% of the total output of the conjugate fiber. The output ratio of Component B is gradually decreased to 20% of the total output of the conjugate fiber within 180 seconds.
- The spinning conditions include a fusion temperature of 285° C., a spinning speed of 3200 m/min, POY (Partially Oriented Yarn), and 5.0 Denier per PET conjugate fiber at the beginning.
- The following table shows the comparison of hue (L, a, b) and color intensity of the initial fiber and the fibers respectively sampled at sections 3200 m, 6400 m and 9600 m away from the beginning (at the 60th second, the 120th second and the 180th second from the beginning). The table shows that a gradient-color conjugate fiber is obtained via continuously varying the output ratios of the components.
-
Hue (L, a, b), Color strength L a b Color intensity Sample taken at the 25.76 −0.89 −1.8 As Standard beginning Sample taken at a section 26.21 −1.44 −3.18 94.8% 3200 m away from the beginning Sample taken at a section 29.51 −2.95 −6.39 71.6% 6400 m away from the beginning Sample taken at a section 31.27 −4.1 −9.74 61.5% 9600 m away from the beginning - In Embodiment V, a spin-dyed gradient-color conjugate polyester fiber is used to exemplify the effect of the present invention.
- Component A of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Pigment Red 214 by a concentration of 0.51 wt % of Component A and a colorant titanium dioxide by a concentration of 0.3 wt % of Component A. Component B of the conjugate fiber is made of a polyester resin and spin-dyed with a colorant Disperse Violet 57 by a concentration of 0.17 wt % of Component B and a colorant titanium dioxide by a concentration of 0.3 wt % of Component B. At the beginning, the output ratio of Component A from Melt Extruder A is 50% of the total output of the conjugate fiber. The output ratio of Component A is gradually increased to 80% of the total output of the conjugate fiber within 180 seconds. At the beginning, the output ratio of Component B from Melt Extruder B is 50% of the total output of the conjugate fiber. The output ratio of Component B is gradually decreased to 20% of the total output of the conjugate fiber within 180 seconds.
- The spinning conditions include a fusion temperature of 285° C., a spinning speed of 3200 m/min, POY (Partially Oriented Yarn), and 4.5 Denier per PET conjugate fiber at the beginning.
- The following table shows the comparison of hue (L, a, b) and color intensity of the initial fiber and the fibers respectively sampled at sections 3200 m, 6400 m and 9600 m away from the beginning (at the 60th second, the 120th second and the 180th second from the beginning). The table shows that a gradient-color conjugate fiber is obtained via continuously varying the output ratios of the components.
-
Hue (L, a, b), Color strength L a b Color intensity Sample taken at the beginning 39.78 19.22 −7.85 As Standard Sample taken at a section 40.92 23.94 −0.42 109.5% 3200 m away from the beginning Sample taken at a section 41.31 26.72 5.40 122.6% 6400 m away from the beginning Sample taken at a section 43.38 30.36 10.26 123.1% 9600 m away from the beginning - In Embodiment VI, a spin-dyed gradient-color conjugate polyamide (Nylon) fiber is used to exemplify the effect of the present invention.
- Component A of the conjugate fiber is made of a polyamide resin and spin-dyed with a colorant Pigment Blue 15:3 by a concentration of 0.5 wt % of Component A. Component B of the conjugate fiber is made of a polyamide resin and spin-dyed with a colorant Pigment Green 7 by a concentration of 0.5 wt % of Component B.
- At the beginning, the output ratio of Component A from Melt Extruder A is 50% of the total output of the conjugate fiber. The output ratio of Component A is gradually increased to 80% of the total output of the conjugate fiber within 180 seconds. At the beginning, the output ratio of Component B from Melt Extruder B is 50% of the total output of the conjugate fiber. The output ratio of Component B is gradually decreased to 20% of the total output of the conjugate fiber within 180 seconds.
- The spinning conditions include a fusion temperature of 2805° C., a spinning speed of 4300 m/min, an drawing rate of 250%, and 4.5 Denier per polyamide conjugate fiber at the beginning.
- The following table shows the comparison of hue (L, a, b) and color intensity of the initial fiber and the fibers respectively sampled at sections 4300 m, 8600 m and 12900 m away from the beginning (at the 60th second, the 120th second and the 180th second from the beginning). The table shows that a gradient-color conjugate fiber is obtained via continuously varying the output ratios of the components.
-
Hue (L, a, b), Color strength L a b Color intensity Sample taken at the 45.91 −29.22 −18.28 As Standard beginning Sample taken at a section 46.29 −26.63 −24.27 93.0% 4300 m away from the beginning Sample taken at a section 45.53 −24.77 −26.88 95.1% 8600 m away from the beginning Sample taken at a section 47.51 −24.05 −30.54 83.4% 12900 m away from the beginning - The embodiments described above are only to exemplify the present invention but not to limit the scope of the present invention. Any equivalent modification or variation according to the claims and specification of the present invention is to be also included within the scope of the present invention.
Claims (7)
1-9. (canceled)
10. A method for fabricating a spin-dyed gradient-color fiber, characterized in performing spin-dyeing in a melt extruder to spin-dye a monocomponent thermoplastic fiber or a multicomponent conjugate thermoplastic fiber containing at least two components, and continuously and periodically varying the output ratio of said melt extruder to provide gradient color for said thermoplastic fiber.
11. The method for fabricating a spin-dyed gradient-color fiber according to claim 10 , wherein said monocomponent thermoplastic fiber or each of said components of said thermoplastic conjugate fiber is made of a material selected from a group consisting of polyester resins, polyester copolymers, polyamide resins, polyamide copolymers, polypropylene resins, polypropylene copolymers, polyethylene resins, polyethylene copolymers, and combinations thereof.
12. A method for fabricating a spin-dyed gradient-color fiber, characterized in respectively performing spin-dyeing in at least two melt extruders with identical colorants wherein at least one said extruder has a colorant concentration different to colorant concentrations of other said extruders to spin-dye a monocomponent thermoplastic fiber or a multicomponent conjugate thermoplastic fiber containing at least two components, and continuously and periodically varying a output ratio of at least one of said melt extruders to provide gradient color for said thermoplastic fiber.
13. The method for fabricating a spin-dyed gradient-color fiber according to claim 12 , wherein said monocomponent thermoplastic fiber or each of said components of said conjugate fiber is made of a material selected from a group consisting of polyester resins, polyester copolymers, polyamide resins, polyamide copolymers, polypropylene resins, polypropylene copolymers, polyethylene resins, polyethylene copolymers, and combinations thereof.
14. A method for fabricating a spin-dyed gradient-color fiber, characterized in respectively performing spin-dyeing in at least two melt extruders with different colorants to spin-dye a monocomponent thermoplastic fiber or a multicomponent conjugate thermoplastic fiber containing at least two components, and continuously and periodically varying a output ratio of at least one of said melt extruders to provide gradient color for said thermoplastic fiber.
15. The method for fabricating a spin-dyed gradient-color fiber according to claim 14 , wherein said monocomponent thermoplastic fiber or each of said components of said thermoplastic fiber is made of a material selected from a group consisting of polyester resins, polyester copolymers, polyamide resins, polyamide copolymers, polypropylene resins, polypropylene copolymers, polyethylene resins, polyethylene copolymers, and combinations thereof.
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PCT/CN2008/001402 WO2010012128A1 (en) | 2008-07-31 | 2008-07-31 | Spun dyeing chromatographic fiber and the preparation method thereof |
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US20110210462A1 true US20110210462A1 (en) | 2011-09-01 |
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US13/056,549 Abandoned US20110210462A1 (en) | 2008-07-31 | 2008-07-31 | Spin-Dyed Gradient-Color Fiber and Method for Fabricating the Same |
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US (1) | US20110210462A1 (en) |
EP (1) | EP2309041A4 (en) |
JP (1) | JP2011529534A (en) |
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WO (1) | WO2010012128A1 (en) |
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CN102517756A (en) * | 2011-12-28 | 2012-06-27 | 无锡诺赛净科技有限公司 | Production method for zero-discharge yarn-dyed and woven fabric |
DE102014113782A1 (en) | 2014-09-23 | 2016-03-24 | Yi-yung Chen | FABRIC WITH A SAME GRADIENT EFFECT |
CN111172789A (en) * | 2020-01-19 | 2020-05-19 | 常州旭荣针织印染有限公司 | Gradually-layered fabric and preparation method thereof |
CN112126992B (en) * | 2020-07-28 | 2021-07-23 | 东华大学 | Preparation method of color gradient fiber |
CN111876841B (en) * | 2020-07-28 | 2022-08-30 | 江苏恒泽复合材料科技有限公司 | Preparation method of color-gradient regenerated polyester fiber |
CN116676676B (en) * | 2023-06-02 | 2024-03-19 | 浙江古纤道股份有限公司 | Processing method of color-changing yarn |
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- 2008-07-31 EP EP08783592A patent/EP2309041A4/en not_active Withdrawn
- 2008-07-31 JP JP2011520301A patent/JP2011529534A/en active Pending
- 2008-07-31 US US13/056,549 patent/US20110210462A1/en not_active Abandoned
- 2008-07-31 CN CN2008801301348A patent/CN102076893A/en active Pending
- 2008-07-31 WO PCT/CN2008/001402 patent/WO2010012128A1/en active Application Filing
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US3769380A (en) * | 1971-05-03 | 1973-10-30 | Cosden Oil & Chem Co | Method for extruding synthetic thermoplastic sheet material having a variegated colored pattern |
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US4301107A (en) * | 1978-08-30 | 1981-11-17 | American Cyanamid Company | Melt-spinning a plurality of acrylonitrile polymer fibers |
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Also Published As
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EP2309041A4 (en) | 2012-01-18 |
WO2010012128A1 (en) | 2010-02-04 |
EP2309041A1 (en) | 2011-04-13 |
CN102076893A (en) | 2011-05-25 |
JP2011529534A (en) | 2011-12-08 |
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