US20110192164A1 - Rankine engine with efficient heat exchange system - Google Patents
Rankine engine with efficient heat exchange system Download PDFInfo
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- US20110192164A1 US20110192164A1 US13/087,318 US201113087318A US2011192164A1 US 20110192164 A1 US20110192164 A1 US 20110192164A1 US 201113087318 A US201113087318 A US 201113087318A US 2011192164 A1 US2011192164 A1 US 2011192164A1
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- rankine
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K3/00—Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K15/00—Adaptations of plants for special use
- F01K15/02—Adaptations of plants for special use for driving vehicles, e.g. locomotives
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K25/00—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for
- F01K25/08—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours
- F01K25/10—Plants or engines characterised by use of special working fluids, not otherwise provided for; Plants operating in closed cycles and not otherwise provided for using special vapours the vapours being cold, e.g. ammonia, carbon dioxide, ether
Definitions
- Recharging locations may become as universal as current refueling stations.
- Thermal energy storage is an ideal scenario from an energy usage standpoint, and a direction that is currently and technologically practical to explore.
- Microwave energy conducted through the absorption tube 200 effects a conversion of EM energy into thermal energy, rapidly heating anything in contact with, or inside, the tube 200 .
- the tube 95 has a plurality of perforations or slotted opening 97 through its outer walls 232 .
- the slotted openings 97 allow slurry S circulating thought the heat exchanger 60 to enter, remain, and gradually flow within the central heat absorption/transfer tube 200 .
- the direct gas producing magnetron, with mixing lens is convenient to maintain operating temperature and lower torque rotation of the Rankine expander, particularly an expander as described whereby the input gas can be effectively throttled, i.e. where the expansion events are discernable one from another, either in individual cylinders, or devolving chambers, more so perhaps than in standard issue turbines that require such massive volumes of working gas.
- These gas producing lensed magnetrons could be coupled to individual inlets of reciprocating devices or discretionary chambers of an emulated turbine device, thus keeping rotation of the expander underway.
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- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
Abstract
The rankine engine with efficient heat exchange system provides a rapidly rechargeable thermal energy storage bank operably connected to a heat engine capable of use in an electric power generation facility. Microwave energy is supplied to the system via a network of waveguides. Thermal storage bank has a slurry in a heat exchanger capable of sustaining operation of the engine without requiring the microwave source. The slurry provides a mixture of powdered stainless steel and silicone oils functioning as the working fluid in the hot side of the heat exchanger. The slurry may be heated by plugging the system into standard AC power for a predetermined microwave heat charging duration. A closed, triple-expansion, reciprocating Rankine cycle engine capable of operating under computer control via a high pressure micro-atomized steam working medium is provided to propel the vehicle. A variety of working fluids are capable of powering the Rankine cycle engine.
Description
- This application is a continuation-in-part of U.S. patent application Ser. No. 12/149,670 filed May 6, 2008.
- 1. Field of the Invention
- The present invention relates to heat exchangers, and particularly to a Rankine engine with an efficient heat exchange system that may be used, e.g. to power a vehicle without expending non-renewable fuel (i.e., traditional fossil, alcohol, hydrogen, soy or agriculturally based, etc), to power the engine.
- 2. Description of the Related Art
- Chemical energy in the form of batteries has been used since the dawn of automotive history for storage of electrical energy required to operate the automobile. Modern hybrid automobiles use the rechargeable energy storage system (RESS) with a small diesel or gas engine to turn electrical generating equipment and battery banks. However, batteries are not an optimal energy storage solution due to their poor charge time to discharge ratios and their toxicity upon disposal.
- Microwave radiation has proven to be efficient at heating powdered metals in the sintering process, since powdered metal offers minimum reflectivity. Certain stainless steel alloys exhibit tremendous heat capacity, nearly that of water. Powdered metal in an oil, another semi-viscous media, to produce a slurry may provide a substantial improvement over current thermal energy storage technology because microwave energy is capable of heating the permeable powdered metal/silicone oil or similarly engineered heat retentive slurry in minutes, instead of the hours and significant expense of battery recharging.
- The ability to charge the working fluid of a heat exchanger in minutes instead of hours charging and maintaining/exchanging/replacing batteries may be highly appreciated as current technology hybrid vehicle accrue mileage and extended usage in the real world environment.
- Recharging locations may become as universal as current refueling stations. Thermal energy storage is an ideal scenario from an energy usage standpoint, and a direction that is currently and technologically practical to explore.
- Thus, a rankine engine with efficient heat exchange system solving the aforementioned problems is desired.
- The Rankine engine with efficient heat exchange system has a rapidly rechargeable thermal energy storage bank operably connected to a heat engine capable of propelling a vehicle. Microwave energy is supplied to the system via a network of waveguides.
- The thermal storage bank comprises a slurry in a heat exchanger capable of sustaining operation of the engine without requiring constant powering of the microwave source. The slurry provides a mixture of a compressed powdered metal/ceramic matrix and silicone oils/heat retentive viscous media functioning as the working fluid in the hot side of the heat exchanger. The slurry may be heated (thermally enabled) by plugging the system into standard AC power for a predetermined microwave charging duration.
- A closed, highly insulated, triple-expansion, reciprocating Rankine cycle engine capable of operating under the computer control via a high pressure micro-atomized steam working medium is provided to propel the vehicle. A variety of working fluids are capable of powering the Rankine cycle engine.
- These and other features of the present invention will become readily apparent upon further review of the following specification and drawings.
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FIG. 1 is a diagram of a Rankine engine with efficient heat exchange system according to the present invention. -
FIG. 2A is a partial diagrammatic sectional view of heat exchanger internal components of the Rankine engine with efficient heat exchange system according to the present invention, showing general layout of components and internal geometric configuration of the assembly. -
FIG. 2B is a partial diagrammatic sectional view of heat exchanger components of the Rankine engine with efficient heat exchange system according to the present invention exchanging heat and producing working gas during operation of the engine. -
FIG. 3 is a diagrammatic top view of an automobile equipped with a Rankine engine with efficient heat exchange system according to the present invention. -
FIG. 4 is a diagrammatic view of an enroute charging system for a Rankine engine with efficient heat exchange system according to the present invention. - Similar reference characters denote corresponding features consistently throughout the attached drawings.
- As shown if
FIGS. 1 , 2A and 2B, the present invention relates to a Rankine engine with efficient heat exchange system having a quickly rechargeable thermal energy bank with a slurry S circulating through an energystorage heat exchanger 60, wherein the slurry S can be rapidly heated by electromagnetic energy in the form of microwave heating. The microwave energy may be supplied to the system via a network of waveguide/heatexchange gasifier tubes 200 andwaveguide interconnections - The microwave source may include, but is not limited to, at least one
magnetron tube 55 that can be coupled to the waveguide network atwaveguide interconnection 205 a. Themagnetron 55 can be charged by time/distance of operation desired, i.e., a commuter trip may be estimated for travel time or calculated by GPS for distance. Under computer control, a high pressure fed-finely atomized working fluid dispersed tangentially into a favorable low pressure environment created and enhanced through velocity/pressure trade-off enabling geometry heat exchanging gasifier tubes ensuring a minimum amount of stored thermal energy be drawn from the system under normal operation regime to achieve the trip with safety reserve. Since the magnetron(s) 55 may be a part of theonboard system 50, thermal recharging stations could be located conveniently at place of employment or popular destinations, enroute smart-rail recharging, as well as regenerative braking in a feedback loop. The ability of themagnetron 55 to deliver the energy quickly precludes time and energy consuming recharging periods. - The thermal energy storage of a slurry S in
heat exchanger 60 can sustain operation of a Rankinecycle engine 108 to operate a vehicle for extended periods of time without a constant or direct connection to an electrical power grid, while retaining the potential to be quickly and conveniently recharged enroute if necessary. - The slurry S is an engineered slurry comprising, for example, highly refined micro-powdered stainless steel and finely powdered ceramic materials in a viscous or semi-viscous mixture combined with silicone-based oils or in combination with other suitable materials of high heat capacity such as clays or salts which may repeatedly absorb, retain, and disperse the waveguide supplied microwave energy. Heat retentive viscous fluid, of high heat capacity, such as a silicone based oils, or aforementioned engineered slurry is capable of functioning as the thermal energy supply fluid in the hot side of the
heat exchanger 60. Some degree of viscosity is preferred in the engineered slurry S so that the slurry S can be slowly pumped through or directly heated by the permeable matrix containing the waveguide connections in order to bring it up to (and maintain for extended periods) the maximum possible storage of heat energy (without significant outgassing). The viscous nature of the slurry is ideal for maximum heat transfer to the working fluid, while limiting deleterious oxidation events to the primary matrix. Liquid ceramics, liquefied metals, clays, or salts may be used in place of silicone oils as the optimum engineered thermal energy retention fluid. The stored thermal energy produces the last percentage of conversion of the pre-heated engine working fluid (preheated by first circulating, viapreheat line 105 b, proximate the slurry in heat exchanger 60) to the working gas as produced in the changingcross-section tubes 95 ofheat exchanger 60. The cross-sectional geometric change is intended to facilitate the vapor phase transformation through localized reduction of withdrawn thermal energy requirements from the thermal reservoir. - Insulation is provided in order to maintain the slurry S at sufficient temperature to effect the conversion, and can comprise a plurality of layers of zirconium applied by plasma-spray process, over which several inches of ceramic-based insulation could be applied. Vacuum chambers, other thermal barriers, etc., may be introduced into the layers of insulation in order to reduce radiated heat from the entire device to a negligible level.
- Preferably the
heat exchanger 60, includinggasifier tubes 95, is constructed primarily of an austenitic nickel-base superalloy, such as Inconel®, or other typically high temperature-resistant material, high-nickel content, superhigh performance alloy, such as Hastelloy® or the like, capable of withstanding the long duration elevated temperatures of the slurry S. The heat exchanger operates to draw thermal energy from the heated slurry S, which may either thermosiphoned or, alternatively, may be mechanically pumped across a plurality ofshaped diffuser tubes 95. The advantage of the powdered metal, or permeable powdered metal/ceramic matrix coincident to the slurry S is the ability to be heated almost instantly to extreme temperatures by the supplied microwave energy. Powdered materials absorb microwave energy readily, as they display huge cumulative surface area and low coefficients of reflectivity. The engineering of a strategically positioned permanently permeable matrix composed of a mixture of compressed powdered materials, both ceramic and metal based, provide sufficient waveguide conductivity to repeatedly heat within a near percentage of solidification/coalescence, while retaining capability of efficient heat transfer to slowly circulating heat retentive slurry. - The quantity of slurry S in the base of the
heat exchanger 60 is sufficient to ensure adequate thermal energy transfer in order to operate theengine 108, which is capable of operating via a high pressure micro-atomized steam working medium. The slurry S may be heated by plugging the system into standard AC power for a predetermined heat-charging duration, or, alternatively, by utilizing an enroute rail charging system while the vehicle is on the road. - As shown in
FIG. 3 , the Rankine engine with efficient heat exchange system comprises on-board microwave generator 55 (OBMWG) connected to the heat exchanger viawaveguide interconnection 205 a. Hightemperature slurry pump 65 slowly pumps the slurry S viaslurry supply line 70 through “hot” side ofheat exchanger 60. The slurry S recirculates back to theslurry pump 65 viaslurry return line 75. In actual practice, the slurry reservoir and the heat exchanger can be most efficiently constructed and thermally insulated as a single integral unit. - As shown in
FIGS. 2A-2B , the waveguide interconnection 205A in theheat exchanger 60 joins an enclosed, circular, heat transfer/waveguide continuation tube 200 that is disposed concentrically within the internally hourglass shapedgasifier tube 95.Tube 200 acts as a central conductor of thermal energy, an axis about which the finely atomized working fluid is dispersed. Atomized working fluid is thusly exposed to the maximum possible area of heat exchanger wall surface area to promote efficient heat transfer. - There may be plurality of
such gasifier tubes 95 disposed adjacent to each other within theheat exchanger 60. Thegasifier tube 95 is configured so that the engine-driving work fluid is kept isolated from the slurry S. The workingfluid powering engine 108 may be a variety of formulation, including, but not limited to, pure water, a recapturable refrigerant, such as ammonia or Puron and the like. - Disposed inside the central heat absorption/
transfer tube 200 is a continuation of the waveguide charged permeable powdered metal andceramic matrix member 202. As shown in the section drawing ofFIG. 2A , the central conductor of theheat rejection tube 200 interconnects the two wall-adjacent portions of thetube 200 in the section drawing. In actual practice, thematrix 202 extends about the entire circumference of the changing cross-section gasifier tube. Preferably,member 202 is capable of high electromagnetic energy absorption, while encountering minimum reflection from the waveguide charged bymagnetron 55.Members 202 may also remain capable of repeated extreme thermal cycling without significant degradation of material properties, such as permanent permeability, in order to act as an efficient conduit for thermal energy introduced into the entire slurry S. - Microwave energy conducted through the
absorption tube 200, effects a conversion of EM energy into thermal energy, rapidly heating anything in contact with, or inside, thetube 200. Thetube 95 has a plurality of perforations or slottedopening 97 through itsouter walls 232. The slottedopenings 97 allow slurry S circulating thought theheat exchanger 60 to enter, remain, and gradually flow within the central heat absorption/transfer tube 200. Since the slurry S has a directional flow (imparted by slurry pump 65) from the integral slurry reservoir through the heat exchangergasifier tube section 60 to the opposite end of theheat exchanger 60, slurry S circulates throughouttube 200 and will flow directionally throughabsorption tube 200 until it can escape back to the common reservoir of heated slurry through the slottedopenings 97 on the opposite side. This slow directional flow of high heat capacity slurry in constant contact with the walls of the gasifier enables the maximum amount of thermal energy dispersal into the regime of the highly atomized working fluid. Slurry S that flows through theheat absorption tube 200 in this manner may be initially heated and then remain heated for extended periods to temperatures between 1100 C to 1300 C (the maximum temperature remaining below sintering threshold, whereupon the slurry charging matrix may coalesce into a solid, losing some degree of it's desired permeability, E-M energy absorption capability, and further, the ability to transfer heat to the slurry). Inconel 718 or higher temperature capable grade superalloy is the preferred material forgasifier tube 95 construction, as it maintains sufficient structural integrity to house the powdered metal and ceramic matrix at or near sintering temperatures, while repeatedly performing it's role as a structured enclosure of geometry as a gasifier. - Microwave radiation has proven to be highly efficient at heating powdered metals. Thus, the powdered metal suspended in silicone oils offers the ability to flow through a heat exchanger and transfer heat energy to the diffuser tube, while minimizing outgassing, and can be maintained in a vacuum to improve retention of thermal energy, while limiting oxidation. It is contemplated that the slurry S can retain these temperatures for a considerable duration once the microwave energy is removed from the waveguide.
- Referring again to
FIG. 3 , working fluid originates inreservoir 80, which is connected to the working fluid supplyhigh pressure pump 85, which, in turn, has an output connected to theheat exchanger 60. As shown inFIG. 2B ,high pressure pump 85 has a manifolded output, which connects to a pair ofatomizer nozzles sidewalls 232 of each one of thegasifier tubes 95. The pump connection placesatomizer nozzles pressure regulator 215 having return line 216, and back toreservoir 80. The output line ofatomizer 210 b inFIG. 2A can be connected to a manifold capable of feeding the high pressure working fluid to remaining pairs ofatomizers gasifier tubes 95, which comprise the working fluid portion of theheat exchanger 60. - As shown in
FIGS. 2A-2B , theatomizers sidewalls 232 above the lower conic section of thegasifier tube 95. Theatomizers gasifier tube 95 at or below the geometric transition of thegasifier tube 95, the location depending primarily on region of pressure gradient advantage. Moreover, the nozzle orientations ofatomizers atomizers coincident conductor tube 200, to maximize the time in contact with the highest temperature regime of the gasifier tube. - During motor (non-charging) operations of the
device 50, the combination of the high thermal energy of slowly circulating slurry S ingasifier tube 200 and pressure differential created byBernoulli tube 95 acting upon the spray mist of working fluid ejected from theatomizers gasifier tubes 95 by a computer controlled ingress/egress output manifold that takes working gas from the dome of the heat exchanger and feeds a high pressuresteam output line 100. In this way, the working gas can be momentarily stored during periods of deceleration or braking of the vehicle, and a recirculation valve may be employed to reheat or superheat unused or underutilized output working gas. The high pressure steam inoutput line 100 is ultimately fed to theengine 108. While theengine 108 can be a variety of designs, including but not limited to, a turbine engine or the like, preferably, theengine 108, as shown inFIG. 1 , has a closed, triple-expansion, reciprocating configuration utilizing a Rankine cycle to do work based on adiabatic expansion of the working medium in theengine 108. - The system in
engine 108 may be open if water is used as the working fluid, or completely closed (sealed) if a suitable convertible fluid is used that can be recaptured indefinitely (Freon/Puron). As shown inFIG. 1 , theengine 108 is a V-8 configuration, having opposingcylinder head 112 and opposing cylinder bores disposed therein (and within the cylinder block of engine 108). Designated as C1, C2, and C3. Cylinders C1 have a low volume, high pressure bore, Cylinders C2 have a medium volume, medium pressure bore, and Cylinders C3 have a high volume, low pressure bore. Thus, the configuration offers increasing bore and/or stroke in opposed pairs. The high pressuresteam output line 100 connects to the first set of bores C1. The C1 (high pressure) bores may incorporate additional waveguide-fed matrix and slurry locations integral to their chamber heads in order to effect/promote and sustain superheat status of certain eligible working fluid(s) in closest mechanical proximity to the expansion phase. - As shown in
FIG. 1 , the C1 bores have insulated steam outlet ports connecting to the C2 bores, and the C2 bores have steam outlet ports connecting to the C3 bores. Under electromechanical and/or computer control (e.g., computer and electronically controlled square-wave pulse-activated high degree-of-atomization nozzles, in combination with mechanically controlled cam-action poppet valves), when pistons P in the C1 bores have completed a power stroke, intermediate pressure steam is permitted to escape via steam outlet to drive pistons P in the C2 bores. Subsequently, when the pistons P in the C2 bores have completed their power stroke, lower pressure steam is permitted to escape via steam outlet to drive pistons P in the C3 bores, and when pistons P in the C3 bores have finished their power stroke, the low pressure work medium is exhausted to returnline 105 a. Basic aspects of thetriple expansion engine 108 have long been understood by those of ordinary skill in the art. - As is known by one of ordinary skill in the art, the reciprocating motion of the pistons P is transmitted to a crankshaft, which ultimately powers differential 310 for rotational motion of the vehicle wheels. The precisely controlled timing of steam power through
reciprocating engine 108 is accomplished by a set of electrical solenoid or variable timing camshaft actuatedpoppet valves 92 connected tocomputer 40 via control lines 91. Common, split, or multiple camshafts can control the entire poppet valve inlet and egress system, which may incorporate methods of variable timing of poppet valve events to achieve localized performance enhancements, such as may be offered by these variations. - As shown in
FIG. 3 , thereturn line 105 a is routed back to theheat exchanger 60 where the medium can be preheated for another cycle of flow through theheat exchanger 60. The preheated working medium is then routed vialine 105 b tocondenser 110. Output ofcondenser 110 is routed via continuation ofline 105 b back to thereservoir 80. Thecontrol computer 40 has a control connection to theheat exchanger 60 in order to precisely control atomization flow (typically square wave pulse width) provided to theatomizers heat exchanger 60. - The
atomizers computer 40 so that only the minimum necessary amount of working gas is produced based on real-time evaluation of current need (throttle position versus load calculation). Producing the gas near-instantaneously on a need-only basis allows for significantly reduced consumption of the thermal energy stored in the slurry.Computer 40 can accept inputs from a variety of sensors disposed in the system in order to make the executive command decisions required to achieve the objective of the on-demand vapor/steam supply. - Preferably,
computer 40 is a digital convertible fluid injection (DCVI), and is capable of accurately addressing the pulse width of theliquid atomization nozzles heat exchanger 60, as well as the pulse width of the solenoid operatedpoppet valves 92 in the inlet ofengine 108. For example,computer 90 can take a reading of the exhaust gas pressure and temperature, and loop it back to the gas-producing nozzle pulse width. Hence, the device is both load and demand (acceleration or deceleration) sensitive to real time. - Sensors could be added to read inlet (liquid) feed temperature and pressure (from feed pump), working gas temperature and pressure in the plenum/dome, load encountered, condition desired (accelerate/decelerate/stop/reverse), mean effective pressure in any of the cylinders (high/medium/low pressure) to vary the timing of poppet valve events through such mechanism as described (mechanical systems: multiple cam/articulating rocker arm stanchions/lobe advance or retard mechanism. Digitally controlled electrical systems may include solenoid-activated poppet valves). Precise event timing control (DCVI computerized nozzles, as well as poppet valve events) is desirable as the slurry S gradually and continuously loses temperature to the working fluid as the working fluid transitions to working gas. The longest range is available when only the precise and minimum amount of gas is produced to meet the load and condition requirements.
- As shown in
FIG. 4 , in the case of enroute recharging, a buriedsmart rail conductor 405 that is basically flush with a road surface R may be utilized, either by direct contact (brush/roller) or by inductive coupling, to provide the electrical energy necessary to operate themicrowave generator 55 or charge a supercapacitor to fire themagnetron 55 when desired board the vehicle V. The rail is segmented by insulation and can powered by any existing power grid from which (preferably) rectified DC current can be obtained. Each segment can be fed by a solid state, e.g., transistor or SCR circuit, whereby the high current only flows to the particular segment when the associated gating circuit is energized. - The gate of each semiconductor can be actuated by an inductively coupled or otherwise induced discrete signal from the vehicle V directly above it, thereby allowing the
smart rail 405 to remain safe from lethal contact with accidentally contact by humans, animals, or the like.Segments 405 may be of a length only sufficient for a conducting condition while the vehicle V needing the recharge is directly above it, thereby shielding therail 405 from accidental contact. As such,rail segments 405 conduct only in response to an induced signal from above, which can come from several sources, such as acoil 410 inducting the trigger (gating) current, or an ultrasound device, or a laser signal, or any other device that can perform the task of momentarily (locally) charging the gate of a main power transistor or SCR, which connects the high current power grid to thesegmented rail 405, forcing it to conduct. Once the vehicle V has passed beyond a particular energized one of thesegments 405, thesmart rail 405 returns to a nonconducting and thoroughly (safe) condition. - The
smart rail 405 may be accessed to charge the on-boardmicrowave generator OBMWG 55 directly, or to charge a supercapacitor that can store the charge and supply it to theOBMWG 55 whenever desired or necessary. - The signal that suggests the
smart rail conductor 405 may eventually be capable of discrete operation, whereby the information of which distinct vehicle V is drawing power from the rail can be recorded and used for energy billing purposes. Thesmart rail system 405 allows a commuter the ability to access thesmart rail 405 if in need of a recharge (and have the energy transfer recorded), or pass over it with no energy transfer. - The
smart rail 405 may be an ideal enroute recharging mechanism for a variety of vehicles utilizing some form of electrical or chemical energy as a means of propulsion, and may be incorporated into existing highways while remaining unobtrusive, safe, and non-interfering with the operation of existing technology vehicles. - With respect to utilizing the inventive Rankine engine in the context of an electrical grid co-generation facility, a need has been articulated for electrical energy storage for the power grid, such as to release stored excess energy produced in off hours and employ it conveniently during peak periods of usage, thus alleviating said peaks and brownouts. Additionally, electricity produced from wind, solar, optical, geothermal or tidal sources may fluctuate in intensity, and hence a storage system for power grid energy would be advantageous to reduce or eliminate these power production fluctuations.
- The inventive Microwave-
Rankine cycle engine 108 could be used to store the energy into a form of thermal energy, and release it upon demand via a conventional or novel Rankine cycle expander. The microwave-Rankine cycle has been recently described as a “capacitive” function if described in the formally descriptive terms of Classical Circuit Theory, it has acavity magnetron 55 coupled permanently to what is called a permanently permeable matrix (PPM) consisting of a porous powdered semi-sintered (necking only) superalloy of relatively small gradient size, typically Inconel®, sandwiched and again sintered between even more highly porous superalloy foam matrix material or highly porous sinterment of larger gradient powder, which may include powdered ceramics as well as sacrificial constituents such as lithium stearate that may be subsequently leeched out after sintering to precisely control the porosity of the sinterment. Thus, the PPM begins at or even more precisely within the mouth of the waveguide, may have a surface of specialized geometry (tetrahedral) tuned by height to some multiple or heterodyne of the microwave frequency to assist electromagnetic energy to efficiently enter the PPM and propagate instantly to a heat retentive slurry co-located within a resonant cavity formed around an efficient heat exchange mechanism. - The porous powdered material is typically introduced into the end of the waveguide, typically as a multiple tetrahegonal or pyramid shape, with the walls matching the wavelength, or some multiple of the wavelength, of the microwave generator, usually (but of course not limited to) S Band 2.45 gig or L band 915 mhz.; both would be most commonly applicable. The PPM at the waveguide is of a fine gradient, sintered to sphere-to-sphere necking but not to complete coalescence, creating an engineered level, degree, or percentage of porosity. In the case of microwave energy absorption, the key aspect is cumulative surface area, thus the smaller the spherical size of the powder, the more surface area per cubic inch of material. This finer grade of PPM extends from the mouth of the waveguide into the resonant cavity, where it is sandwiched via further sintering operations to what is referred to as metal foam, which can be as great as 85-95% porous. The powdered superalloy is typically in the 40-45% porous range where it exits the waveguide.
- The magnetron is always kept in tune with the load via automated stub tuning, tuning stubs changing length in response to the VSWR curve caused by warming of the slurry, which is actively monitored and fed back into the tuning stub actuation mechanism consisting of rack/pinion driving miniature electric motors under computer algorithmic control.
- PPM with co-located slurry thus becomes a permanently tuned antenna or more precisely, a dummy load for the magnetron, thus relieving the slowly ramping coupling curve associated with using microwave energy to heat a bath of molten salt or saltpetre (the default thermal storage media). In applications where PPM is not present as the third element of the device, coupling between microwave energy and salt is temperature dependent, coupling is slow to initiate until such time as the salt has warmed considerably, at which point coupling increases along a curve. This is highly disadvantageous to the mechanism as a whole, where immediate coupling is desirable. The PPM acts as the primary agent of relatively instantaneous microwave energy-to-slurry coupling, in concert with the computerized stub tuning continually maintaining the VSWR at low levels.
- Initial research (discovery) has been done to potentially improve the thermal diffusivity of various media in order to outperform default molten salt/saltpetre, by increasing the likelihood of frequency of electron collisions, particularly outer valance electrons, through the theoretical mechanism of the outward facing quark charge, as conjectured herein, affecting the probability of electron location.
- This theoretical “discovery” regarding the mention of “outward facing quark charge” in the text above, is with respect to engineered industrial chemistry of advanced thermal diffusivity characteristics. Taking into account Heisenberg's uncertainty dilemma, a means of resolving some measure of uncertainty is propose by considering the charges of the three quark model that make up the particle's protons and neutrons.
- The standard model states that, among numerous characteristics, these UP and DOWN quarks have charges of +⅔ and −⅓ respectively, with protons consisting of two UP and one DOWN quark, while neutrons consist of one UP and two DOWN quarks. By simple addition the charge of a proton is +1 (matching the atom's electrons-i charge on a one-to-one ratio), and a charge of zero in the neutron.
- However, it should be considered that these fractions in thirds are repeating endlessly. Hence in real terms it may be considered that energy levels may indeed force the issue one way or the other, in decimal terms to resolve the fractions up or down on (at least) their last decimal place. That being postulated, it is straightforward to postulate that the quark-to-quark charge may decide to rebalance itself electrically, by means of free rotation of the three quark model internal to the particles proton and neutron, whose position does not change. Given that the three quark make-up is considered to be free to rotate, than a rebalance between quarks can always be maintained simply by rotation relative to each other. If that can be postulated to occur, then the result is that the quarks facing outside the nucleus are now of different charge, if an UP quark in the Proton is now more attracted to a DOWN quark in the neutron, and the three quark models in each particle are free to rotate to rebalance themselves, than the outward facing quark charges are now different than they were, thus effecting the electron location.
- Thus, it is logical to consider that freely rotating/rebalancing three quark models internal to protons and neutrons thus face outward of the nucleus differing charges based on the degree of rotation of the quarks, and these outward facing quark charges may logically directly affect the electron location probability. As to whether or not this mechanism is truly at work, it still gives one a tool to begin designing quantum mechanically engineered compounds. For example, in the case of thermal diffusivity studies on the Sodium atom electron collisions are the chief source of the element Sodium to retain heat for long periods of time. If one can further understand the electron location probability through the simple mechanism of outward facing quark charge, one may be able to design industrial chemistry to take advantage of these perhaps enhanced levels of probability, thus engineering more collisions of electrons, and improving thermal diffusivity above the default media of molten salt or saltpetre.
- At certain precise energy levels it may prove possible to definitely increase this likelihood of electron collisions, by forcing electrons into higher likelihood of position probability, thus increasing or engineering the “opportunity for collisions” and thus theoretically increasing the thermal diffusivity of the slurry material.
- Magnetrons and PPM might be divided into segmented ceramic tubes, highly insulated with Aerogel style insulation, feeding a common (at some level) thermal reservoir of some magnitude of volume, this arrangement allows the thermal storage to be segregated by input power, the attempt is to get the slurry up to temperature rapidly (1300-1450 F) using the stub tuned matching networks, then adding magnetrons and PPM incrementally (in segregated ceramic tubes) to bring additional molten salt or quantum modified HTD (high thermal diffusivity) slurry up to temperature, until such time as the entire reservoir may be held at highly elevated temperature. This segregation allows various levels of energy storage, like a multi-cell battery, each PPM tube or cell contributing to the overall, but not creating a situation where the entire slurry cell is always common, whereby relatively low input energy creates a relatively useless (thermally diluted) large volume of low temperature slurry.
- Heated slurry then can be readily used to perform work, particularly in the form of Rankine cycle expansion, as has been described in co-pending U.S. patent application Ser. No. 12/149,670 incorporated by reference in its entirety herein. Multiple expansion Rankine reciprocating with optional pressure exchange for auto/truck/aircraft), emulated turbine devices driving superconducting alternators (ideally), however, obviously the slurry can power (through heat exchangers providing gasification of a working fluid) conventional Rankine expanders like bladed turbines driving conventional generators.
- The emulated turbine is a device based upon the novel three element pressure exchanger with airfoil blades transposed along their chord lines, forming continuously devolving but relatively finite volume chambers, instead of the high-gas-throughput inherent to the conventional bladed multi-stage turbine. The conventional bladed turbine, a takeoff of the water wheel, is highly wasteful of working gas, in either Brayton or Rankine cycles. Reciprocating devices have reversals in motion and higher internal friction, although they are somewhat more economical of working gas, particularly when insulated with zirconia plasma-applied thermal barrier coatings on all exposed surfaces, piston tops, valve heads, cylinder walls, and inside ports. The drawbacks to reciprocals are the inherent exponential volume increase as pistons move downwards in individual cylinders, high friction due primarily to piston rings but include valve springs and lubrication induced viscous drag among others.
- Emulated turbines can offer the same thermal barrier application possibilities, while keeping the controlled expanding volume of the contra-rotating formed chambers to a more manageable condition, this can be accomplished through a multi-axis (linear) movement of the already contra rotating concentric drums that continually form and reform the devolving chambers. Devolving chambers can thus be fed working gas segmentally, depending on precise torque requirements, this allows the chambers to remain at peak thermal insulative capacity, unlike a bladed turbine wherein any lessening of volume or temperature of impinging gas lowers the temperature (and thus efficiency) of the turbine substantially. These drawbacks make the bladed turbine most efficient only at high and steady maintained torque producing output, they do not throttle efficiently, and are not thermally efficient at less than ideal torque outputs. The individualized constantly devolving chambers of the emulated turbine can be segregated as to input of working gas, and thus the efficiency remains high at all levels of torque output.
- Working gas is produced in the heat exchange portion of the large thermal (slurry) reservoir. Recall that slurry is co-located with PPM, the porous PPM is inundated in slurry, and heats slurry quickly through rather instantaneous coupling to the microwave generator (cavity magnetrons) Slurry surrounds gasifier tubes, which are geometrically advantageous (for improved gasification) of a Rankine working fluid, of which water can be readily used in power grid storage/production.
- The document herein thoroughly describes an exemplary Rankine multi-expansion reciprocating expander side portion of the device, in which case the gasifier tubes can be integral to the expander, allowing short path recirculation, multi-path superheating, stage-to-stage re-pass through the heat exchanger, and pressure exchange from high (HP) to low (LP) stages using conventional (straight longitudinal semi-circular concave multiple channel on rotating drum with valved/ported stationary end plates) or the novel three element pressure exchanger with stator section.
- Moreover, disclosed herein is a direct working gas producing magnetron, formed with a lens mechanism that allows microwave energy heated (to incandescence) fine metal powder, continuously circulating through the lens, this powder is mixed with finely atomized working fluid within the lens, where it transfers heat directly to atomized working fluid, then is returned endlessly to the powder reservoir via electromagnetic deflection. Microwave energy is readily absorbed by small gradient powder, due to its relatively huge combined surface area, whereas microwave energy heats water directly by bipolar stimulation, this effect is highly inefficient in the production of large quantities of superheated working gas. The heated powder, superalloy or ceramic material transfers heat instantly to highly atomized fluid within the lens, which is formed adjacent to the magnetron, or indeed integral to the magnetron. Thus both dipolar heating as well as direct conductive heating from incandescent powder occur simultaneously within the lens. Atomization can be improved with piezo-electric diaphragm injector nozzles that break up already fine working fluid spray into pure fog, these special ultrasonically atomizing injector nozzles would be highly advantageous in various applications, not strictly Rankine cycle applications.
- The direct gas producing magnetron, with mixing lens, is convenient to maintain operating temperature and lower torque rotation of the Rankine expander, particularly an expander as described whereby the input gas can be effectively throttled, i.e. where the expansion events are discernable one from another, either in individual cylinders, or devolving chambers, more so perhaps than in standard issue turbines that require such massive volumes of working gas. These gas producing lensed magnetrons could be coupled to individual inlets of reciprocating devices or discretionary chambers of an emulated turbine device, thus keeping rotation of the expander underway. At all times, the current supplied to the rotating field of the alternator would be coupled to the available torque production of the lensed magnetrons, when overpeak power exists, and when underpeak conditions come into play the thermal batch of salt as described earlier is added to the total working gas production mix through the novel three element heat exchange mechanism, i.e., magnetron, PPM, heated slurry, working gas production system, as described herein and in co-pending U.S. patent application Ser. No. 12/149,670.
- The uniqueness of this system is thus based on custom versions of microwave producing devices which include the inventive magnetron-to-PPM stuffed waveguide that instantly couples microwave energy to a permanently permeable porous matrix that is imbedded in the heat retentive slurry, be it saltpetre or novel advanced quantum mechanically defined chemistry of higher thermal diffusivity, or more simply quantum mechanically engineered industrial chemistry. The automated stub tuning keeps the VSWR low across the spectrum of potential slurry condition, from nearly solidified to 1450 F (for molten salt). The direct gas producing magnetron with lens as described herein can also be employed to maintain a liquid condition of the molten salt (keeping it above solidification temperature). This would be readily accomplished by directing the gas through heat exchange tubing through the energy storing vat of slurry on its way to the expander where it maintains temperature and some measure of rotation of the expander/alternator (generator). The aim here is to maintain the slurry within a range of temperature that equates to manageable VSWR range, a range that be accommodated by the automated stub tuning. Thus, when over-peak power is available from the power grid, the device is immediately ready for energy storage, the slurry is liquid, and the expander is turning over and at sufficient temperature to ensure proper sealing and adequate internal lubrication.
- With respect to
magnetron tube 55, the goal of using a direct gasification magnetron is to create a vortex of incandescent powder mixed homogeneously with finely atomized vapor admitted through high pressure atomizing nozzles. The powder, typically a superalloy with sufficient ferritic component to be influenced by magnetic fields, absorbs microwave energy directly due to its relatively huge combined surface area, and transfers heat efficiently to the atomized working fluid. The working fluid can even be further atomized in a combination type nozzle, such as one that combines a piezo-electric disperser element along with the multiple tiny exit passages in the nozzle tip. - The lens can be formed as a helix, with powder fed from a reservoir into a blower arrangement consisting of compressed gas or air, the powder can be fed by gravity, pressure, or picked up via suction like the wide variety of existing media spraying apparatus. Fed into the helical vortexer under considerable pressure, the vortexer forms a resonant cavity that transfers microwave energy to the powder/atomized working fluid combination, instantly gasifying the fluid within the short area of the lens. The lens exit might be a charged screen matrix, which readily passes the superheated gas while redirecting the powder back to its reservoir. The possible helical arrangement of the vortexer might be useful to helping to aim the powder in an advantageous direction along with the electromagnetic steering of powder, which might be accomplished via electromagnetic coil or even as part of a high voltage flyback transformer arrangement to facilitate powder/particle steering out of the produced gas stream and back to its reservoir from where it is endlessly recycled.
- The helical nature of this resonant cavity may be as simple as winding a hollow tube of some diameter into a tight helix, i.e., no space between the windings, and then boring the center of the tube out to reveal a helical track within which the pressurized powder rotates along as if within a hollow screw thread. This vortexing activity prolongs the time that the powder is exposed to the microwave energy, and absorbs this energy instantly, typically more rapidly than the atomized working fluid alone can absorb this energy through traditional dipolar means. One powder reservoir can be situated so as to feed a multiplicity of gasifying magnetrons, this is advantageous when these direct gas producing magnetrons are disposed about an expander operating typically on the Rankine cycle.
- Resonant cavities like the vortexing lens are of course determined by length and diameter/volume as some function of wavelength, and some multiple or heterodyne of said wavelength. The exit screening of the cavity might incorporate sufficient electromagnetic charge as to render it relatively opaque to microwave energy escape, this lens exit can be so construed as to form a constricted outlet that only higher pressure fully superheated gas may force its exit from the lens through this constriction, the constriction may be as simple as a spring loaded poppet or ball seated on a cone. In cases where it might occur that microwave energy wishes to escape this resonant cavity through its only permissible exit, the poppet arrangement can be so constructed as to the poppet body having vanes instead or pointed nose or round. The vanes can extend fully into mirrored hollow vanes in the poppet valve body, thus forming a labyrinth that may be impervious to microwave energy escape but able to pass high pressure working gas. Gas would escape through the labyrinth so formed, when the vaned poppet is lifted from its seat, but while the vanes are still engaged with the mirrored hollow vanes forming the labyrinth. Thus what is disclosed is a labyrinthian exit structure for a pressurized resonant cavity in which high pressure superheated gas may be readily produced via microwave energy.
- Properly designed, the labyrinthian vaned poppet and mirrored labyrinthian seat may allow the powder to escape through the labyrinthian arrangement clearance so disposed radially about the poppet in multiplicity, while effectively trapping the microwave energy within the resonant cavity. Thus the exit lens of the direct gas producing magnetron is formed so as to promote mixing of gas and charged powder, perhaps via a helical arrangement such as a hollow screw thread. This helical chamber be constructed to the dimensions necessary to act as resonant cavity of proper volume to minimize VSWR. Charged powder acts to transfer heat directly to highly atomized gas from high pressure atomizing nozzle, including the option of piezo-electric ultrasonic dispersion of working vapor. Powder runs in an endless cycle from reservoir to lens and back. Powder is directed out of the produced gas stream via electromagnetic field and labyrinthian poppet. Labyrinthian poppet assembly is opaque to microwave energy while passing both superheated working gas and powder back to its reservoir.
- It is to be understood that the present invention is not limited to the embodiments described above, but encompasses any and all embodiments within the scope of the following claims.
Claims (29)
1. A Rankine engine with efficient heat exchange system, comprising:
a vapor phase change engine connected to electrical production means;
an energy storage heat exchanger;
an energy source proximate the heat exchanger, wherein the energy source includes a waveguide network connected to the energy source;
a high operating temperature slurry capable of rapid heating under electromagnetic microwave energy exposure and being capable of retaining the high temperature for a substantial duration, whereby the waveguide network guides energy from the energy source to the slurry;
means for circulating the slurry in a closed loop within the heat exchanger;
a working fluid;
means for circulating the working fluid through the heat exchanger to pick up sufficient heat content from the slurry in order to change phase to a high pressure vapor/steam; and
means for directing the high pressure vapor/steam to an inlet of the engine in order to operate the engine;
whereby electricity can be produced under vapor/steam power from stored heat energy in the slurry until the slurry temperature cools down to a temperature ineffective to cause the work fluid to vaporize.
2. A Rankine engine with efficient heat exchange system, comprising:
a vapor phase change engine mechanically coupled to an electrical generator that supplies power to a power grid;
an energy storage heat exchanger operably connected to the vapor phase change engine 1 the heat exchanger including a permeable powdered metal-ceramic matrix disposed within the heat exchanger;
an energy source proximate the heat exchanger, wherein the energy source includes a waveguide network connected to the energy source
a high operating temperature slurry capable of rapid heating under electromagnetic microwave energy exposure and being capable of retaining the high temperature for a substantial duration, whereby the waveguide network guides energy from the energy source to the slurry and the matrix is coincident to the slurry, the matrix accelerating the heating of the slurry when the energy is applied;
a slurry pump circulating the slurry in a closed loop within the heat exchanger;
a working fluid;
a working fluid pump circulating the working fluid through the heat exchanger to pick up sufficient heat content from the slurry in order to change phase to a high pressure vapor/steam; and
a high pressure steam output line directing the high pressure vapor/steam to an inlet of the engine in order to operate the engine;
whereby the generator can be actuated under vapor/steam power from stored heat energy in the slurry until the slurry temperature cools down to a temperature ineffective to cause the work fluid to vaporize.
3. The Rankine engine according to claim 2 , wherein the electromagnetic energy exposure comprises:
a microwave energy source proximate the heat exchanger.
4. The Rankine engine according to claim 2 , further comprising:
manifolded high pressure output lines extending from the working fluid pump; and
a plurality of gasifier tubes proximate the heat exchanger, the gasifier tubes receiving high pressure fluid from the manifolded high pressure output lines, the gasifier tubes outputting a rapid phase change of the working fluid from liquid to the high pressure vapor steam/vapor.
5. The Rankine engine according to claim 4 , further comprising:
output manifolds disposed on the gasifier tubes; and
a computer operably connected to the gasifier output manifolds, the computer modulating the high pressure vapor steam/vapor to the engine inlet.
6. The Rankine engine according to claim 4 , further comprising atomizers disposed within the gasifiers, the atomizers atomizing high pressure fluid at the inputs to the gasifiers.
7. The Rankine engine according to claim 6 , further comprising a plurality of waveguide continuation tubes disposed within the gasifier tubes, the continuation tubes centrally conducting thermal energy about an axis through which atomized working fluid is dispersed by the atomizers, wherein atomized working fluid is exposed to the maximum possible area of heat exchanger wall surface area to promote efficient heat transfer to the working fluid.
8. The Rankine engine according to claim 4 , wherein the gasifier tubes are disposed in a housing of the heat exchanger.
9. The Rankine engine according to claim 4 , wherein the gasifier tubes are made from a high grade, high temperature capable superalloy, the gasifier tubes maintaining structural integrity at sintering temperatures.
10. The Rankine engine according to claim 7 , wherein a first atomizer within a gasifier tube is disposed in a non coplanar manner with respect to a second atomizer disposed in the same gasifier tube, the non-coplanar atomizers facilitating a spiraling action of working fluid finely atomized spray/steam around the central coincident conductor tube, thereby maximizing the time in contact with a highest temperature regime of the gasifier tube.
11. The Rankine engine according to claim 2 , wherein the engine has a closed, triple-expansion, reciprocating configuration utilizing the Rankine cycle to do work based on adiabatic expansion of the working medium in the engine.
12. The Rankine engine according to claim 2 , further comprising an engine control computer, the engine control computer controlling a set of inlet and outlet valves of the engine, thereby precisely controlling timing of steam power through the engine.
13. The Rankine engine according to claim 12 , further comprising a control line forming an interconnection between the engine control computer and the atomizers, the engine control computer controlling the atomizers via the interconnection, wherein only the minimum necessary amount of working gas is produced based on real-time evaluation of current throttle position versus a load calculation computed by the engine control computer.
14. The Rankine engine according to claim 1 , wherein the electromagnetic energy source is microwave.
15. The Rankine engine according to claim 1 , further comprising a permeable powdered metal/ceramic matrix disposed within the heat exchanger and coincident to the slurry, the matrix accelerating the heating of the slurry when the electromagnetic energy is applied.
16. The Rankine engine according to claim 2 , wherein the electromagnetic energy source is microwave.
17. The Rankine engine according to claim 3 , further comprising:
a resonant cavity formed around said heat exchanger; and
said slurry being co-located within said resonant cavity.
18. The Rankine engine according to claim 17 further comprising:
a permeable powdered metal/ceramic matrix (PPM) disposed within the heat exchanger and coincident to the slurry, the matrix accelerating the heating of the slurry when the microwave energy is applied, said PPM having a tetrahedral geometry tuned by height to a multiple or heterodyne of a frequency of said microwave energy source.
19. The Rankine engine according to claim 18 wherein said PPM has a high surface area to volume ratio so that a high end porosity of said PPM is as high as approximately ninety five percent at an entry point of said waveguide network.
20. The Rankine engine according to claim 19 wherein said microwave energy source includes means for tuning said microwave energy source responsive to a voltage standing wave ratio caused by warming of said slurry.
21. The Rankine engine according to claim 20 further comprising:
means for dividing a plurality of said microwave energy source and said PPM into segmented ceramic tubes feeding a common thermal reservoir; and
means for incrementally adding power from said plurality of said microwave energy source to bring said slurry up to a predefined operating temperature.
22. The Rankine engine according to claim 20 further comprising means for emulating a turbine device driven by said Rankine engine.
23. The Rankine engine according to claim 20 wherein said microwave energy source is a magnetron.
24. The Rankine engine according to claim 23 further comprising:
means for electromagnetic deflection of said working fluid;
means for heating said PPM to incandescence wherein said PPM is mixed with finely atomized working fluid thereby transferring heat directly to atomized working fluid and returning said working fluid endlessly to a reservoir via said means for electromagnetic deflection.
25. The Rankine engine according to claim 24 further comprising:
a resonant cavity formed by said means for heating said PPM to incandescence; and
means for trapping said microwave energy inside said resonant cavity while still allowing said PPM to flow through said cavity.
26. The Rankine engine according to claim 23 further comprising:
means for adding energy to said slurry when supply of said power grid exceeds demand required of said power grid; and
means for rapidly actuating said electric generator to provide electrical power to said power grid when demand required of said power grid exceeds supply of said power grid.
27. The Rankine engine according to claim 23 , further comprising:
manifolded high pressure output lines extending from the working fluid pump; and
a plurality of gasifier tubes proximate the heat exchanger, the gasifier tubes receiving high pressure fluid from the manifolded high pressure output lines, the gasifier tubes outputting a rapid phase change of the working fluid from liquid to the high pressure vapor steam/vapor.
28. The Rankine engine according to claim 27 , further comprising atomizers disposed within the gasifiers, the atomizers atomizing high pressure fluid at the inputs to the gasifiers.
29. The Rankine engine according to claim 28 , wherein said gasifiers further comprise nozzles that combine piezo-electric disperser elements along with multiple tiny exit passages in tips of said nozzles.
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US13/087,318 US20110192164A1 (en) | 2008-05-06 | 2011-04-14 | Rankine engine with efficient heat exchange system |
US13/440,788 US9222371B2 (en) | 2007-06-08 | 2012-04-05 | Efficient heat exchange system for storing energy |
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US12/149,670 US7926274B2 (en) | 2007-06-08 | 2008-05-06 | Rankine engine with efficient heat exchange system |
US13/087,318 US20110192164A1 (en) | 2008-05-06 | 2011-04-14 | Rankine engine with efficient heat exchange system |
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