US20110008692A1 - Fuel Cell System - Google Patents

Fuel Cell System Download PDF

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Publication number
US20110008692A1
US20110008692A1 US12/933,054 US93305409A US2011008692A1 US 20110008692 A1 US20110008692 A1 US 20110008692A1 US 93305409 A US93305409 A US 93305409A US 2011008692 A1 US2011008692 A1 US 2011008692A1
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US
United States
Prior art keywords
gas
supplied
jet pump
anode
hydrogen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US12/933,054
Inventor
Andreas Knoop
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mercedes Benz Group AG
Original Assignee
Daimler AG
Ford Global Technologies LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Assigned to FORD GLOBAL TECHNOLOGIES, LLC, DAIMLER AG reassignment FORD GLOBAL TECHNOLOGIES, LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KNOOP, ANDREAS
Publication of US20110008692A1 publication Critical patent/US20110008692A1/en
Assigned to DAIMLER AG reassignment DAIMLER AG ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: FORD GLOBAL TECHNOLOGIES LLC
Abandoned legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04097Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with recycling of the reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Definitions

  • the invention relates to a fuel cell system in which anode exhaust gas is recirculated to the anode inlet.
  • This fuel cell system comprises an anode circuit having a gas jet pump with two inlets and one outlet, for conveying surplus hydrogen from the anode outlet to the anode inlet.
  • a “motive jet” under elevated pressure is introduced at one inlet, and passes through the gas jet pump to its outlet.
  • a further inlet of the gas jet pump is arranged such that the motive jet flowing through the gas jet pump produces a low pressure at the further inlet, and is thereby able to draw in gas via the further inlet and entrain it as far as the outlet.
  • the fuel cell system in which a part of the anode waste gas is supplied to a compressor, which comprises it and supplies it to the motive jet side of a gas jet pump.
  • a compressor which comprises it and supplies it to the motive jet side of a gas jet pump.
  • Another embodiment of the invention has two gas jet pumps, to one of which the compressed waste is supplied, with hydrogen from the tank being supplied to the other.
  • Each gas jet pump then has a part of the uncompressed waste gas supplied to it as gas to be drawn in. With this embodiment too it is ensured that the fuel cell system functions under low loads.
  • all the gas jet pumps in this embodiment need to have a nonreturn valve on the anode inlet side.
  • FIG. 1 is a schematic representation of a first embodiment of the invention
  • FIG. 2 is a schematic representation of a second embodiment of the invention.
  • FIG. 3 is a schematic representation of a third embodiment of the invention.
  • FIG. 4 is a schematic representation of a modification of the third embodiment of the invention.
  • a fuel cell 10 comprises an anode 12 , which has an anode inlet 14 , via which hydrogen is supplied.
  • the majority of the hydrogen comes from a tank 16 .
  • a valve 18 and a gas jet pump 20 Arranged downstream of the tank 16 are a valve 18 and a gas jet pump 20 .
  • the hydrogen jet coming from the tank 16 functions as the motive jet for the gas jet pump 20 , this being supplied to a motive jet inlet (normally a nozzle) 22 of the gas jet pump 20 , and exiting at an outlet 24 .
  • a motive jet inlet normally a nozzle
  • further gas may be drawn in via a further inlet 26 of the gas jet pump 20 .
  • the waste gas emerging from the anode 12 via an anode outlet 28 is supplied in part to the further inlet 26 .
  • the system is less dependent on the quantity of hydrogen supplied via the valve 18 and consequently operates better in particular under low fuel cell loads than if the branch with the compressor 32 is omitted.
  • the precompressed waste gas is supplied directly from the compressor to the gas jet pump 20 , the latter then having two inlet nozzles, namely a first inlet nozzle 22 , via which the hydrogen is supplied from the valve 18 , and a second inlet nozzle 36 , via which precisely the compressed waste gas is supplied. (See FIG. 2 .)
  • the invention also works if the hydrogen from the tank 16 and the compressed waste gas are supplied to different gas jet pumps 20 and 38 respectively. Different parts of the waste gas from the anode 12 are supplied to each gas jet pump 20 and 38 , the two gas jet pumps 20 and 38 operating mutually independently. (See FIG. 3 .) In the latter embodiment, the compressor 32 must in any case always be running, so that gas does not pass through the gas jet pump 38 in the opposite direction from normal, due to certain pressure differences. This may be prevented if, as shown in FIG. 4 , the two gas jet pumps 20 and 38 each comprise a nonreturn valve 40 and 42 respectively.
  • the compressor 32 serves in particular to recirculate a sufficient stream of waste gas when the fuel cell 10 is under low loads.
  • the quantity of waste gas compressed by the compressor 32 may here be relatively small.
  • the compressor 32 does not therefore need to be of a high power and may for example be operated with a 12 V voltage. It is significantly less expensive to provide the compressor 32 than a blower, as is occasionally used in the anode circuit in the prior art.

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  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

The potential energy from a hydrogen tank is used in a gas jet pump, which draws in anode waste gas via an inlet and recirculates it to an anode inlet. To ensure that this system operates effectively even under low loads, a part of the waste gas is supplied to a compressor, and the compressed waste gas is supplied to the motive jet inlet of a gas jet pump, which may be the same one to which the hydrogen from the tank is also supplied. Different gas jet pumps may also be used, for the hydrogen from the tank on the one hand, and the compressed waste gas on the other hand.

Description

    BACKGROUND AND SUMMARY OF THE INVENTION
  • This application is a national stage of PCT International Application No. PCT/EP2009/001494, filed Mar. 3, 2009, which claims priority under 35 U.S.C. §119 to German Patent Application No. 10 2008 014 783.4, filed Mar. 18, 2008, the entire disclosure of which is herein expressly incorporated by reference.
  • The invention relates to a fuel cell system in which anode exhaust gas is recirculated to the anode inlet.
  • This fuel cell system comprises an anode circuit having a gas jet pump with two inlets and one outlet, for conveying surplus hydrogen from the anode outlet to the anode inlet. A “motive jet” under elevated pressure is introduced at one inlet, and passes through the gas jet pump to its outlet. A further inlet of the gas jet pump is arranged such that the motive jet flowing through the gas jet pump produces a low pressure at the further inlet, and is thereby able to draw in gas via the further inlet and entrain it as far as the outlet.
  • It is known in particular from fuel cell systems to utilize the high pressure which hydrogen is conventionally under in a hydrogen tank to form a motive jet for a gas jet pump. The gas jet pump is thus arranged between the hydrogen tank and the anode inlet. As a result, the quantity of anode waste gas that is drawn in via the further inlet of the gas jet pump is directly dependent on the quantity of hydrogen gas supplied from the tank and forming the motive jet, which in turn depends on the fuel cell system load.
  • This known arrangement is problematic under low load. In particular, it would then be desirable for somewhat more anode waste gas to be recirculated than is possible with the gas jet pump. Satisfactory recirculation under low loads has heretofore been made possible, if need be, by using a blower. However, a blower is a complex and expensive component, which is susceptible to failure in particular at cold temperatures due to icing.
  • It is therefore an object of the present invention to provide a fuel cell system which operates reliably, even under low loads, and is nonetheless inexpensive.
  • This and other objects and advantages are achieved by the fuel cell system according to the invention, in which a part of the anode waste gas is supplied to a compressor, which comprises it and supplies it to the motive jet side of a gas jet pump. In this way it is ensured that a sufficient quantity of gas in particular a quantity sufficient for low loads, is always available on the motive jet side. In practice only very small quantities of anode waste gas need to be compressed, such that the power of the compressor may be so low that it can be operated with a 12 volt power supply. Expenditure is therefore low, while the solution is nevertheless effective.
  • It is advantageous, first of all, for hydrogen from a tank also to be supplied to the same gas jet pump to which the compressed waste gas is supplied, as in the prior art. This may be achieved by bringing the compressed waste gas and the hydrogen from the tank together upstream of the gas jet pump. It needs to be ensured that the compressed waste gas and the hydrogen are at roughly the same pressure. The compressed waste gas and the hydrogen may however also be supplied directly to the gas jet pump independently of one another, using different inlet nozzles.
  • Another embodiment of the invention has two gas jet pumps, to one of which the compressed waste is supplied, with hydrogen from the tank being supplied to the other. Each gas jet pump then has a part of the uncompressed waste gas supplied to it as gas to be drawn in. With this embodiment too it is ensured that the fuel cell system functions under low loads.
  • To prevent flow in undesired directions, all the gas jet pumps in this embodiment need to have a nonreturn valve on the anode inlet side.
  • Other objects, advantages and novel features of the present invention will become apparent from the following detailed description of the invention when considered in conjunction with the accompanying drawings.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a schematic representation of a first embodiment of the invention;
  • FIG. 2 is a schematic representation of a second embodiment of the invention;
  • FIG. 3 is a schematic representation of a third embodiment of the invention; and
  • FIG. 4 is a schematic representation of a modification of the third embodiment of the invention.
  • DETAILED DESCRIPTION OF THE DRAWINGS
  • As shown in the Figures, a fuel cell 10 comprises an anode 12, which has an anode inlet 14, via which hydrogen is supplied. The majority of the hydrogen comes from a tank 16. Arranged downstream of the tank 16 are a valve 18 and a gas jet pump 20. The hydrogen jet coming from the tank 16 functions as the motive jet for the gas jet pump 20, this being supplied to a motive jet inlet (normally a nozzle) 22 of the gas jet pump 20, and exiting at an outlet 24. As a result of the low pressure generated by the motive jet, further gas may be drawn in via a further inlet 26 of the gas jet pump 20. In the present case, the waste gas emerging from the anode 12 via an anode outlet 28 is supplied in part to the further inlet 26. According to the invention, provision is then made for a further part of the waste gas to be supplied from a branch point 30, which also leads to the further inlet 26, to a compressor 32, there to be compressed to the pressure of the hydrogen coming from the tank 16 downstream of the valve 18 and also to be introduced into the hydrogen stream downstream of the valve 18 at a point 34 which lies upstream of the inlet nozzle 22 in the first embodiment according to FIG. 1. Because a proportion of the waste gas emerging from the anode outlet 28 is always used in any case to form the motive jet, the system is less dependent on the quantity of hydrogen supplied via the valve 18 and consequently operates better in particular under low fuel cell loads than if the branch with the compressor 32 is omitted.
  • In a modification of the embodiment of FIG. 1, the precompressed waste gas is supplied directly from the compressor to the gas jet pump 20, the latter then having two inlet nozzles, namely a first inlet nozzle 22, via which the hydrogen is supplied from the valve 18, and a second inlet nozzle 36, via which precisely the compressed waste gas is supplied. (See FIG. 2.)
  • The invention also works if the hydrogen from the tank 16 and the compressed waste gas are supplied to different gas jet pumps 20 and 38 respectively. Different parts of the waste gas from the anode 12 are supplied to each gas jet pump 20 and 38, the two gas jet pumps 20 and 38 operating mutually independently. (See FIG. 3.) In the latter embodiment, the compressor 32 must in any case always be running, so that gas does not pass through the gas jet pump 38 in the opposite direction from normal, due to certain pressure differences. This may be prevented if, as shown in FIG. 4, the two gas jet pumps 20 and 38 each comprise a nonreturn valve 40 and 42 respectively.
  • In accordance with the stated object, the compressor 32 serves in particular to recirculate a sufficient stream of waste gas when the fuel cell 10 is under low loads. The quantity of waste gas compressed by the compressor 32 may here be relatively small. The compressor 32 does not therefore need to be of a high power and may for example be operated with a 12 V voltage. It is significantly less expensive to provide the compressor 32 than a blower, as is occasionally used in the anode circuit in the prior art.
  • The foregoing disclosure has been set forth merely to illustrate the invention and is not intended to be limiting. Since modifications of the disclosed embodiments incorporating the spirit and substance of the invention may occur to persons skilled in the art, the invention should be construed to include everything within the scope of the appended claims and equivalents thereof.
  • LIST OF REFERENCE SIGNS
      • 10 Fuel cell
      • 12 Anode
      • 14 Anode inlet
      • 16 Tank
      • 18 Valve
      • 20 Gas jet pump
      • 22 Inlet nozzle
      • 24 Outlet of the gas jet pump 20
      • 26 Inlet of the gas jet pump 20
      • 28 Anode outlet
      • 30 Branch point
      • 32 Compressor
      • 38 Gas jet pump
      • 40 Nonreturn valve
      • 42 Nonreturn valve

Claims (7)

1.-6. (canceled)
7. A fuel cell system having at least one fuel cell with an anode; wherein:
hydrogen is supplied to the anode via an anode inlet;
waste gas from the anode is conveyable via an anode outlet, back to the anode inlet in a circuit that includes at least one gas jet pump;
a part of the waste gas is supplied to the at least one gas jet pump, as gas to be drawn in;
an outlet of the at least one gas jet pump is connected to the anode inlet;
a further part of the waste gas is supplied to a compressor; and
waste gas compressed by the compressor is supplied to a motive jet side of the gas jet pump.
8. The fuel cell system as claimed in claim 7, wherein hydrogen from a tank is also supplied to the same gas jet pump to which the compressed waste gas is supplied.
9. The fuel cell system as claimed in claim 8, wherein the compressed waste gas and the hydrogen from the tank are brought together upstream of the gas jet pump.
10. The fuel cell system as claimed in claim 8, wherein the compressed waste gas and the hydrogen are supplied to different inlet nozzles of the gas jet pump.
11. The fuel cell system as claimed in claim 7, wherein the hydrogen from the tank is supplied to a gas jet pump other than the gas jet pump to which the compressed waste gas is supplied.
12. The fuel cell system as claimed in claim 10, wherein each of the gas jet pumps has a nonreturn valve on the side of the anode inlet.
US12/933,054 2008-03-18 2009-03-03 Fuel Cell System Abandoned US20110008692A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102008014783.4 2008-03-18
DE102008014783 2008-03-18
PCT/EP2009/001484 WO2009115184A1 (en) 2008-03-18 2009-03-03 Fuel cell system

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/001484 A-371-Of-International WO2009115184A1 (en) 2008-03-18 2009-03-03 Fuel cell system

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US14/072,135 Continuation US8920988B2 (en) 2008-03-18 2013-11-05 Fuel cell system

Publications (1)

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US20110008692A1 true US20110008692A1 (en) 2011-01-13

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US12/933,054 Abandoned US20110008692A1 (en) 2008-03-18 2009-03-03 Fuel Cell System
US14/072,135 Active US8920988B2 (en) 2008-03-18 2013-11-05 Fuel cell system

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Application Number Title Priority Date Filing Date
US14/072,135 Active US8920988B2 (en) 2008-03-18 2013-11-05 Fuel cell system

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US (2) US20110008692A1 (en)
EP (1) EP2253040B1 (en)
JP (1) JP5378498B2 (en)
CN (1) CN101978541B (en)
WO (1) WO2009115184A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102014219836A1 (en) * 2014-09-30 2016-05-25 Volkswagen Aktiengesellschaft Fuel cell arrangement with jet pump in exhaust path and motor vehicle with fuel cell assembly
US10511035B2 (en) * 2013-09-23 2019-12-17 Convion Oy Recirculation arrangement and method for a high temperature cell system

Families Citing this family (4)

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US9224151B2 (en) 2008-06-18 2015-12-29 Microsoft Technology Licensing, L.L.C. Presenting advertisements based on web-page interaction
DE102019108158A1 (en) * 2019-03-29 2020-10-01 Airbus Operations Gmbh Fuel extraction system, fuel tank device with fuel extraction system and fuel cell system with fuel extraction system
DE102021126289A1 (en) 2021-10-11 2023-04-13 Ekpo Fuel Cell Technologies Gmbh fuel cell device
CA3239664A1 (en) * 2021-12-02 2023-06-08 Casy Cloudless BROWN Fuel cell system including ejector

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US20030148167A1 (en) * 2001-11-09 2003-08-07 Honda Giken Kogyo Kabushiki Kaisha Fuel circuit of the fuel cell system
US20050100777A1 (en) * 2003-11-12 2005-05-12 Victor Gurin Fuel cell with integrated feedback control
US6902840B2 (en) * 2002-07-02 2005-06-07 Fuelcell Energy, Inc. Fuel cell system with mixer/eductor
US20060251935A1 (en) * 2001-08-31 2006-11-09 Barrett Scott N Fuel cell system and method for recycling exhaust
US20070190389A1 (en) * 2006-01-25 2007-08-16 Daimlerchrysler Ag Fuel cell system having a fuel cell, a hydrogen storage tank, and an anode circuit

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JP3729150B2 (en) * 2002-04-24 2005-12-21 日産自動車株式会社 Fuel circulation system for ejector and fuel cell system
JP3951885B2 (en) * 2002-10-22 2007-08-01 日産自動車株式会社 Fuel cell system
JP3939640B2 (en) * 2002-12-24 2007-07-04 本田技研工業株式会社 Reactive gas circulation fuel cell system
JP2005108698A (en) * 2003-09-30 2005-04-21 Nissan Motor Co Ltd Fuel cell system
US20100143809A1 (en) * 2005-12-30 2010-06-10 Perry Michael L Air Bleed Through Fuel Cell Fuel Recycle Loop
US8029939B2 (en) * 2007-01-25 2011-10-04 GM Global Technology Operations LLC Fuel cell ejector with integrated check valve

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Publication number Priority date Publication date Assignee Title
US20060251935A1 (en) * 2001-08-31 2006-11-09 Barrett Scott N Fuel cell system and method for recycling exhaust
US20030148167A1 (en) * 2001-11-09 2003-08-07 Honda Giken Kogyo Kabushiki Kaisha Fuel circuit of the fuel cell system
US6902840B2 (en) * 2002-07-02 2005-06-07 Fuelcell Energy, Inc. Fuel cell system with mixer/eductor
US20050100777A1 (en) * 2003-11-12 2005-05-12 Victor Gurin Fuel cell with integrated feedback control
US20070190389A1 (en) * 2006-01-25 2007-08-16 Daimlerchrysler Ag Fuel cell system having a fuel cell, a hydrogen storage tank, and an anode circuit

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10511035B2 (en) * 2013-09-23 2019-12-17 Convion Oy Recirculation arrangement and method for a high temperature cell system
DE102014219836A1 (en) * 2014-09-30 2016-05-25 Volkswagen Aktiengesellschaft Fuel cell arrangement with jet pump in exhaust path and motor vehicle with fuel cell assembly
US10535886B2 (en) 2014-09-30 2020-01-14 Audi Aktiengesellschaft Fuel cell assembly with jet pump in the exhaust path, and motor vehicle with fuel cell assembly

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Publication number Publication date
CN101978541A (en) 2011-02-16
JP5378498B2 (en) 2013-12-25
US20140087278A1 (en) 2014-03-27
EP2253040B1 (en) 2016-08-17
EP2253040A1 (en) 2010-11-24
JP2011514643A (en) 2011-05-06
WO2009115184A1 (en) 2009-09-24
US8920988B2 (en) 2014-12-30
CN101978541B (en) 2015-08-19

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Owner name: DAIMLER AG, GERMANY

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