US20100212354A1 - Method of disposing of carbon dioxide - Google Patents
Method of disposing of carbon dioxide Download PDFInfo
- Publication number
- US20100212354A1 US20100212354A1 US12/666,664 US66666408A US2010212354A1 US 20100212354 A1 US20100212354 A1 US 20100212354A1 US 66666408 A US66666408 A US 66666408A US 2010212354 A1 US2010212354 A1 US 2010212354A1
- Authority
- US
- United States
- Prior art keywords
- carbon dioxide
- containing fraction
- liquefaction
- disposing
- fractionation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 108
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 54
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims abstract description 33
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000005194 fractionation Methods 0.000 claims abstract description 12
- 239000003345 natural gas Substances 0.000 claims abstract description 10
- 238000000746 purification Methods 0.000 claims abstract description 10
- 239000003507 refrigerant Substances 0.000 claims abstract description 10
- 230000009919 sequestration Effects 0.000 claims description 10
- 239000012530 fluid Substances 0.000 claims description 2
- 230000014759 maintenance of location Effects 0.000 claims 1
- 239000007789 gas Substances 0.000 description 7
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
- F25J3/0238—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 2 carbon atoms or more
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0045—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by vaporising a liquid return stream
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
- F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/006—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
- F25J1/0095—Oxides of carbon, e.g. CO2
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0244—Operation; Control and regulation; Instrumentation
- F25J1/0245—Different modes, i.e. 'runs', of operation; Process control
- F25J1/0249—Controlling refrigerant inventory, i.e. composition or quantity
- F25J1/025—Details related to the refrigerant production or treatment, e.g. make-up supply from feed gas itself
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
- F25J1/0275—Construction and layout of liquefaction equipments, e.g. valves, machines adapted for special use of the liquefaction unit, e.g. portable or transportable devices
- F25J1/0277—Offshore use, e.g. during shipping
- F25J1/0278—Unit being stationary, e.g. on floating barge or fixed platform
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
- F25J3/0209—Natural gas or substitute natural gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
- F25J3/0233—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2220/00—Processes or apparatus involving steps for the removal of impurities
- F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
- F25J2220/66—Separating acid gases, e.g. CO2, SO2, H2S or RSH
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2260/00—Coupling of processes or apparatus to other units; Integrated schemes
- F25J2260/80—Integration in an installation using carbon dioxide, e.g. for EOR, sequestration, refrigeration etc.
Definitions
- the invention relates to a method and also an arrangement for disposing of one of more carbon dioxide-containing fractions which occur at one or more sites of a fractionation and/or liquefaction process such as, for example, a natural gas liquefaction process.
- carbon dioxide sources are, for example, the residual gas originating from acid gas removal or amine scrubbing and also the exhaust gas streams of gas turbines and steam generators.
- the abovementioned carbon dioxide-containing fractions have been to date released essentially untreated to the atmosphere. The reason for this is to be seen in the fact that although limiting values are prescribed for hydrocarbons and sulphur compounds by the German TA Lucas [German Instructions on Air Pollution], they are not for carbon dioxide; emission thereof is therefore still permitted without restrictions. In view of current discussions with respect to the carbon dioxide problem, such a procedure can now be considered outmoded.
- carbon dioxide is used as refrigerant.
- pure carbon dioxide refrigerant cycles are suitable for precooling the natural gas to be liquefied; such a natural gas liquefaction method is disclosed, for example, in U.S. Pat. No. 6,722,157. Provision and, in particular, disposal of the carbon dioxide necessary for these (precooling) refrigerant cycles, however, have not to date been given sufficient attention.
- a method of disposing of one or more carbon dioxide-containing fractions which is characterized in that the carbon dioxide-containing fraction(s) is or are subjected to a purification and/or liquefaction and subsequently sequestered.
- the arrangement of the invention for disposing of one or more carbon dioxide-containing fractions is characterized by at least one purification unit and/or at least one liquefaction unit to which is or are fed the carbon dioxide-containing fraction(s), and also by means for feeding the purified and/or liquefied carbon dioxide-containing fraction(s) to a sequestration.
- the black boxes A, A′ and A′′ shown in the FIGURE represent a plurality of “carbon dioxide sources” such as, for example, one or more amine scrubbers (A), one or more gas turbines (A′) and also one or more steam generators (A′′), as are generally provided in the context of fractionation and/or liquefaction processes.
- carbon dioxide sources such as, for example, one or more amine scrubbers (A), one or more gas turbines (A′) and also one or more steam generators (A′′), as are generally provided in the context of fractionation and/or liquefaction processes.
- the carbon dioxide-containing gas or exhaust gas occurring in these “carbon dioxide sources” is taken off for lines 1 , 2 and 3 , combined and fed via a shared line 4 to a purification unit B.
- This purification unit B is preferably constructed as a purification unit operating by absorption, adsorption and/or permeation.
- the purification unit B comprises, where this is necessary in individual cases, a drying unit for the carbon dioxide-containing fraction which is fed.
- the carbon dioxide-containing fraction taken off from the purification unit B via line 5 preferably has a carbon dioxide content of greater than 90% by volume.
- This fraction is then compressed to the extent that, in the downstream liquefaction unit C, liquefaction of the carbon dioxide-containing fraction can proceed against a suitable medium, such as, for example, cooling water, air or another suitable fluid.
- a suitable medium such as, for example, cooling water, air or another suitable fluid.
- the liquefied carbon dioxide-containing fraction can then according to the invention be used in whole or at least in part as refrigerant, for example for precooling in the context of a natural gas liquefaction process, or for cooling in the removal of lighter hydrocarbons, such as C 2+ or C 3+ hydrocarbons, from natural gas.
- This (pre)cooling is intended to be shown by black box D to which the carbon dioxide-containing fraction is fed via line 6 .
- the carbon dioxide-containing fraction used as refrigerant (black box D) and “exhausted” is fed via line 7 back to the liquefaction unit C and in this is optionally reliquefied.
- the fraction of liquefied carbon dioxide-containing fraction which is intended to be fed to a sequestration is pumped to the desired sequestration pressure by means of a single-stage or multistage pump unit 9 .
- This sequestration pressure is preferably above 100 bar.
- the carbon dioxide-containing fraction is fed via line 8 to a suitable sequestration E such as, for example, a subterraneous store or cavern.
- the method according to the invention and also the arrangement according to the invention for disposing of one or more carbon dioxide-containing fractions is suitable, in particular, for floating natural gas production plants since, in these, owing to the safety risks associated with certain hydrocarbon mixtures, carbon dioxide is preferred as refrigerant for the precooling.
- the invention is always used when, firstly, within the fractionation process and/or liquefaction process, a plurality of carbon dioxide-containing fractions occur, and secondly, liquid carbon dioxide or a liquefied carbon dioxide-containing fraction is desired or necessary as refrigerant.
Abstract
A process and also an arrangement for disposing of one of more carbon dioxide-containing fractions which occur at one or more sites of a fractionation and/or liquefaction process such as, for example, a natural gas liquefaction process. The carbon dioxide-containing fraction(s) is or are subjected to a purification (B) and/or liquefaction (C) and subsequently sequestered (D). Preferably, use is made of at least one substream (6) of the liquefied carbon dioxide-containing fraction(s) as refrigerant (D) within the fractionation and/or liquefaction process.
Description
- The invention relates to a method and also an arrangement for disposing of one of more carbon dioxide-containing fractions which occur at one or more sites of a fractionation and/or liquefaction process such as, for example, a natural gas liquefaction process.
- In the context of fractionation and/or liquefaction processes such as, for example, natural gas fractionation and/or liquefaction processes, generally one or more carbon dioxide-containing fractions occurs or occur. Such “carbon dioxide sources” are, for example, the residual gas originating from acid gas removal or amine scrubbing and also the exhaust gas streams of gas turbines and steam generators. The abovementioned carbon dioxide-containing fractions have been to date released essentially untreated to the atmosphere. The reason for this is to be seen in the fact that although limiting values are prescribed for hydrocarbons and sulphur compounds by the German TA Luft [German Instructions on Air Pollution], they are not for carbon dioxide; emission thereof is therefore still permitted without restrictions. In view of current discussions with respect to the carbon dioxide problem, such a procedure can now be considered outmoded.
- In a multiplicity of liquefaction and/or fractionation processes, carbon dioxide is used as refrigerant. In particular in natural gas liquefaction processes, pure carbon dioxide refrigerant cycles are suitable for precooling the natural gas to be liquefied; such a natural gas liquefaction method is disclosed, for example, in U.S. Pat. No. 6,722,157. Provision and, in particular, disposal of the carbon dioxide necessary for these (precooling) refrigerant cycles, however, have not to date been given sufficient attention.
- It is an object of the present invention to specify a method of the type in question and also an arrangement of the type in question for disposing of one or more carbon dioxide-containing fractions which avoid the above-described disadvantages.
- To achieve this object, a method of disposing of one or more carbon dioxide-containing fractions is proposed which is characterized in that the carbon dioxide-containing fraction(s) is or are subjected to a purification and/or liquefaction and subsequently sequestered.
- The arrangement of the invention for disposing of one or more carbon dioxide-containing fractions is characterized by at least one purification unit and/or at least one liquefaction unit to which is or are fed the carbon dioxide-containing fraction(s), and also by means for feeding the purified and/or liquefied carbon dioxide-containing fraction(s) to a sequestration.
- Further advantageous embodiments of the method of the invention and also of the arrangement of the invention for disposing of one or more carbon dioxide-containing fractions which are subject matters of the dependent claims are characterized in that
- at least one substream of the liquefied carbon dioxide-containing fraction(s) is used as refrigerant within the fractionation and/or liquefaction process,
- the liquefied carbon dioxide-containing fraction(s), before sequestration thereof, is or are pumped to a pressure of at least 100 bar and
- the carbon dioxide-containing fraction(s) has or have a carbon dioxide content of at least 90% by volume.
- The method according to the invention and the arrangement according to the invention for disposing of one or more carbon dioxide-containing fractions expansion turbine, and also other embodiments of the same may be described in more detail hereinafter with reference to the exemplary embodiment shown in the FIGURE.
- The black boxes A, A′ and A″ shown in the FIGURE represent a plurality of “carbon dioxide sources” such as, for example, one or more amine scrubbers (A), one or more gas turbines (A′) and also one or more steam generators (A″), as are generally provided in the context of fractionation and/or liquefaction processes.
- The carbon dioxide-containing gas or exhaust gas occurring in these “carbon dioxide sources” is taken off for
lines line 4 to a purification unit B. This purification unit B is preferably constructed as a purification unit operating by absorption, adsorption and/or permeation. The purification unit B comprises, where this is necessary in individual cases, a drying unit for the carbon dioxide-containing fraction which is fed. The carbon dioxide-containing fraction taken off from the purification unit B vialine 5 preferably has a carbon dioxide content of greater than 90% by volume. - This fraction is then compressed to the extent that, in the downstream liquefaction unit C, liquefaction of the carbon dioxide-containing fraction can proceed against a suitable medium, such as, for example, cooling water, air or another suitable fluid.
- The liquefied carbon dioxide-containing fraction can then according to the invention be used in whole or at least in part as refrigerant, for example for precooling in the context of a natural gas liquefaction process, or for cooling in the removal of lighter hydrocarbons, such as C2+ or C3+ hydrocarbons, from natural gas. This (pre)cooling is intended to be shown by black box D to which the carbon dioxide-containing fraction is fed via
line 6. - The carbon dioxide-containing fraction used as refrigerant (black box D) and “exhausted” is fed via
line 7 back to the liquefaction unit C and in this is optionally reliquefied. - The fraction of liquefied carbon dioxide-containing fraction which is intended to be fed to a sequestration is pumped to the desired sequestration pressure by means of a single-stage or
multistage pump unit 9. This sequestration pressure is preferably above 100 bar. The carbon dioxide-containing fraction is fed vialine 8 to a suitable sequestration E such as, for example, a subterraneous store or cavern. - The method according to the invention and also the arrangement according to the invention for disposing of one or more carbon dioxide-containing fractions is suitable, in particular, for floating natural gas production plants since, in these, owing to the safety risks associated with certain hydrocarbon mixtures, carbon dioxide is preferred as refrigerant for the precooling. Advantageously, the invention is always used when, firstly, within the fractionation process and/or liquefaction process, a plurality of carbon dioxide-containing fractions occur, and secondly, liquid carbon dioxide or a liquefied carbon dioxide-containing fraction is desired or necessary as refrigerant.
Claims (8)
1. A method of disposing of one or more carbon dioxide-containing fractions which occur at one or more sites of a fractionation and/or liquefaction process, such method comprising subjecting the carbon dioxide-containing fraction(s) a purification (B) and/or liquefaction (C) and subsequently sequestering resultant carbon dioxide-containing fraction (D).
2. A method according to claim 1 , comprising passing at least one substream (6) of the liquefied carbon dioxide-containing fraction(s) as refrigerant (D) within the fractionation and/or liquefaction process.
3. A method according to claim 1 , wherein the liquefied carbon dioxide-containing fraction(s), before sequestration (D) thereof, is or are pumped (9) to a pressure of at least 100 bar.
4. A method according to claim 1 , wherein, the carbon dioxide-containing fraction(s) has or have a carbon dioxide content of at least 90% by volume.
5. An arrangement of apparatus for disposing of one or more carbon dioxide-containing fractions which occur at one or more sites of a fractionation and/or liquefaction plants, comprising at least one purification unit (B) and/or at least one liquefaction unit (C) which is or are connected in fluid communication to means for feeding the carbon dioxide-containing fraction(s), and means for feeding resultant purified and/or liquefied carbon dioxide-containing fraction(s) to means for sequestration (D).
6. An arrangement according to claim 5 , wherein the means for feeding the purified and/or liquefied carbon dioxide-containing fraction(s) to a sequestration (D) comprises at least one pressure-boosting unit (9).
7. An arrangement according to claim 6 , wherein the pressure-boosting unit (9) has means to increase the pressure of the carbon dioxide-containing fraction(s) fed to the means for sequestration (D) to at least 100 bar.
8. A method according to claim 1 , wherein said sites include a natural gas liquefaction process.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102007029434.6 | 2007-06-26 | ||
DE102007029434A DE102007029434A1 (en) | 2007-06-26 | 2007-06-26 | Process for the disposal of carbon dioxide |
PCT/EP2008/004505 WO2009000393A2 (en) | 2007-06-26 | 2008-06-05 | Method for the removal of carbon dioxide |
Publications (1)
Publication Number | Publication Date |
---|---|
US20100212354A1 true US20100212354A1 (en) | 2010-08-26 |
Family
ID=40075875
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/666,664 Abandoned US20100212354A1 (en) | 2007-06-26 | 2008-06-05 | Method of disposing of carbon dioxide |
Country Status (9)
Country | Link |
---|---|
US (1) | US20100212354A1 (en) |
CN (1) | CN101874187A (en) |
AU (1) | AU2008267511A1 (en) |
DE (1) | DE102007029434A1 (en) |
MX (1) | MX2009013404A (en) |
MY (1) | MY177037A (en) |
NO (1) | NO20100108L (en) |
RU (1) | RU2482407C2 (en) |
WO (1) | WO2009000393A2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120174621A1 (en) * | 2011-01-06 | 2012-07-12 | General Electric Company | Carbon dioxide liquefaction system |
DE102013011640A1 (en) * | 2013-07-11 | 2015-01-29 | Linde Aktiengesellschaft | Process for separating sour gases from natural gas |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3962881A (en) * | 1974-02-19 | 1976-06-15 | Airco, Inc. | Liquefaction of a vapor utilizing refrigeration of LNG |
US20020144506A1 (en) * | 1995-06-07 | 2002-10-10 | Fermin Viteri | Hydrocarbon combustion power generation system with CO2 sequestration |
US20080307966A1 (en) * | 2007-02-12 | 2008-12-18 | Donald Leo Stinson | System for Separating Carbon Dioxide from a Produced Gas with a Methanol Removal System |
US20100006803A1 (en) * | 2008-07-10 | 2010-01-14 | Jose Luis Bravo | Method of treating a high-pressure hydrocarbon stream having a high carbon dioxide content to yield a high purity hydrocarbon gas stream and a sequestration ready carbon dioxide gas stream |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5973416A (en) * | 1982-10-15 | 1984-04-25 | Ishikawajima Harima Heavy Ind Co Ltd | Preparation of liquefied carbonic acid from waste combustion gas of liquefied natural gas |
SU1366821A1 (en) * | 1984-06-28 | 1988-01-15 | Специализированное Управление "Узоргэнергогаз" | Method of removing acid components from natural gas |
CN1035478A (en) * | 1989-03-16 | 1989-09-13 | 于洪喜 | Productive technology of carbon dioxide |
JPH0663699B2 (en) * | 1990-06-14 | 1994-08-22 | 財団法人電力中央研究所 | Recovery method of carbon dioxide emitted from liquefied natural gas-fired power plant |
US5681360A (en) * | 1995-01-11 | 1997-10-28 | Acrion Technologies, Inc. | Landfill gas recovery |
US6070431A (en) * | 1999-02-02 | 2000-06-06 | Praxair Technology, Inc. | Distillation system for producing carbon dioxide |
JP4138399B2 (en) * | 2002-08-21 | 2008-08-27 | 三菱重工業株式会社 | Method for producing liquefied natural gas |
CN2606739Y (en) * | 2003-03-14 | 2004-03-17 | 大连理工大学 | CO2 purifying device by adsorptive fine disstillation |
US6722157B1 (en) | 2003-03-20 | 2004-04-20 | Conocophillips Company | Non-volatile natural gas liquefaction system |
US7076969B2 (en) * | 2004-01-19 | 2006-07-18 | Air Products And Chemicals, Inc. | System for supply and delivery of high purity and ultrahigh purity carbon dioxide |
-
2007
- 2007-06-26 DE DE102007029434A patent/DE102007029434A1/en not_active Withdrawn
-
2008
- 2008-06-05 CN CN200880021862A patent/CN101874187A/en active Pending
- 2008-06-05 MY MYPI20095486A patent/MY177037A/en unknown
- 2008-06-05 AU AU2008267511A patent/AU2008267511A1/en not_active Abandoned
- 2008-06-05 MX MX2009013404A patent/MX2009013404A/en unknown
- 2008-06-05 RU RU2010102252/06A patent/RU2482407C2/en active
- 2008-06-05 WO PCT/EP2008/004505 patent/WO2009000393A2/en active Application Filing
- 2008-06-05 US US12/666,664 patent/US20100212354A1/en not_active Abandoned
-
2010
- 2010-01-21 NO NO20100108A patent/NO20100108L/en not_active Application Discontinuation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3962881A (en) * | 1974-02-19 | 1976-06-15 | Airco, Inc. | Liquefaction of a vapor utilizing refrigeration of LNG |
US20020144506A1 (en) * | 1995-06-07 | 2002-10-10 | Fermin Viteri | Hydrocarbon combustion power generation system with CO2 sequestration |
US20080307966A1 (en) * | 2007-02-12 | 2008-12-18 | Donald Leo Stinson | System for Separating Carbon Dioxide from a Produced Gas with a Methanol Removal System |
US20100006803A1 (en) * | 2008-07-10 | 2010-01-14 | Jose Luis Bravo | Method of treating a high-pressure hydrocarbon stream having a high carbon dioxide content to yield a high purity hydrocarbon gas stream and a sequestration ready carbon dioxide gas stream |
Also Published As
Publication number | Publication date |
---|---|
RU2010102252A (en) | 2011-08-10 |
MY177037A (en) | 2020-09-02 |
DE102007029434A1 (en) | 2009-01-02 |
WO2009000393A2 (en) | 2008-12-31 |
NO20100108L (en) | 2010-01-22 |
WO2009000393A3 (en) | 2014-02-20 |
RU2482407C2 (en) | 2013-05-20 |
AU2008267511A1 (en) | 2008-12-31 |
CN101874187A (en) | 2010-10-27 |
MX2009013404A (en) | 2010-01-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US7731779B2 (en) | Method for processing landfill and other stranded gas containing commercial quantities of methane and contaminated by carbon dioxide, nitrogen and oxygen into a pipeline or vehicle quality natural gas product | |
US7442231B2 (en) | Electricity generation system | |
US20220065161A1 (en) | Liquid natural gas processing with hydrogen production | |
US9114351B2 (en) | Configurations and methods for high pressure acid gas removal | |
US20070068386A1 (en) | Landfill gas upgrading process | |
US20110185896A1 (en) | Gas purification processes | |
US20220065526A1 (en) | Liquid natural gas processing with hydrogen production | |
EP1391669A3 (en) | Plant and method for producing liquefied natural gas and recovering carbon dioxide contained in natural gas and in a combustion exhaust gas | |
US20210172677A1 (en) | Cryogenic process for removing nitrogen from a discharge gas | |
US20220065529A1 (en) | Devices, systems, facilities, and processes for liquefied natural gas production | |
US11806664B2 (en) | Devices, systems, facilities, and processes of liquid natural gas processing for power generation | |
CN112304028A (en) | Method for obtaining carbon dioxide from furnace combustion fumes | |
US20100212354A1 (en) | Method of disposing of carbon dioxide | |
US20160265842A1 (en) | Light gas separation process and system | |
US11291946B2 (en) | Method for distilling a gas stream containing oxygen | |
US20130025866A1 (en) | Integrated process utilizing nitrogen and carbon dioxide streams for enhanced oil recovery | |
JP4050543B2 (en) | Method for supplying impure nitrogen to a combustion chamber of a gas turbine coupled to an air distillation unit and corresponding power plant | |
Lockwood et al. | Oxy-combustion CPU–From pilots towards industrial-scale demonstration | |
KR102372751B1 (en) | The System and Method for Carbon Dioxide Separation from Natural Gas before Gas Liquefaction Process on LNG-FPSO | |
Tierling et al. | Considerations for the use of carbon dioxide removal membranes in an offshore environment | |
US20210087123A1 (en) | Method for limiting the concentration of oxygen contained in a biomethane stream | |
JPH04240101A (en) | Production of carbon dioxide in equipment for producing hydrogen from methanol | |
KR102372754B1 (en) | The Method for Carbon Dioxide Removal from Natural Gas | |
TW201323062A (en) | Flue gas recirculation with CO2 enrichment membrane |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: LINDE AKTIENGESELLSCHAFT, GERMANY Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:BAUER, HEINZ;REEL/FRAME:024335/0355 Effective date: 20100427 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |