US20100155234A1 - Hydrogen-oxygen generating apparatus - Google Patents
Hydrogen-oxygen generating apparatus Download PDFInfo
- Publication number
- US20100155234A1 US20100155234A1 US12/592,637 US59263709A US2010155234A1 US 20100155234 A1 US20100155234 A1 US 20100155234A1 US 59263709 A US59263709 A US 59263709A US 2010155234 A1 US2010155234 A1 US 2010155234A1
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- United States
- Prior art keywords
- electric pole
- electrolyte
- thin walled
- cover
- walled tube
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000001301 oxygen Substances 0.000 title claims abstract description 31
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 31
- 239000003792 electrolyte Substances 0.000 claims abstract description 67
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000009413 insulation Methods 0.000 claims abstract description 11
- 230000000149 penetrating effect Effects 0.000 claims abstract description 10
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 8
- 238000007789 sealing Methods 0.000 claims description 13
- 238000005868 electrolysis reaction Methods 0.000 claims description 12
- 229910052613 tourmaline Inorganic materials 0.000 claims description 9
- 229940070527 tourmaline Drugs 0.000 claims description 9
- 239000011032 tourmaline Substances 0.000 claims description 9
- 239000003054 catalyst Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 6
- 239000002041 carbon nanotube Substances 0.000 claims description 6
- 229910000851 Alloy steel Inorganic materials 0.000 claims description 4
- 238000005516 engineering process Methods 0.000 claims description 4
- 239000007789 gas Substances 0.000 description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- 229910052739 hydrogen Inorganic materials 0.000 description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 229910001882 dioxygen Inorganic materials 0.000 description 5
- 230000005611 electricity Effects 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000005498 polishing Methods 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000006114 decarboxylation reaction Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M25/00—Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture
- F02M25/10—Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture adding acetylene, non-waterborne hydrogen, non-airborne oxygen, or ozone
- F02M25/12—Engine-pertinent apparatus for adding non-fuel substances or small quantities of secondary fuel to combustion-air, main fuel or fuel-air mixture adding acetylene, non-waterborne hydrogen, non-airborne oxygen, or ozone the apparatus having means for generating such gases
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Definitions
- the present disclosure relates to generating apparatuses and, more particularly, to hydrogen-oxygen generating apparatuses.
- Hydrogen-oxygen mixed-gas generating systems are made to produce hydrogen and oxygen from electrolyzed water; to gain hydrogen-oxygen mixed gas, water containing small amount of electrolytes is provided to the storage with positive (+) and negative ( ⁇ ) electrodes and electrolyzed by direct current. Hydrogen and oxygen produced from the process is at ratio of 2:1 and hydrogen is formed as bubbles on the surface of negative ( ⁇ ) electrode and oxygen in bubbles on the positive (+) electrode. The hydrogen and oxygen produced can be mixed and combusted. Also hydrogen-oxygen gas mixture does not produce any pollutants when ignited, making it an important eco-friendly energy source
- a hydrogen-oxygen generating apparatus includes a metal thin walled tube, an insulation tube inside the thin walled tube, multiple 1 st electrolyte plate that has a 1 st small hole placed below a part of a center hole and a first big hole placed above an upper part of the center hole, multiple 2 nd electrolyte plates with small hole placed above an upper part of a center hole and a 2 nd big hole below a lower part of the center hole, a number of rings with a certain thickness between the 1 st electrolyte plate and the 2 nd electrolyte plate, an electrolyte unit including a 1 st electric pole penetrating the 1 st small holes and a 2 nd electric pole penetrating the 2 nd small holes when the 1 st electrolyte plate and the 2 nd electrolyte plate are placed opposed to each other, a front cover with a frontal water flowing pipe at a center and the 1 st electric pole and the 2 nd electric pole piercing
- FIG. 1 is a diagram of a hydrogen-oxygen mixed gas generator according to an embodiment of the present disclosure
- FIG. 2 is an exploded view of the hydrogen-oxygen mixed gas generator according to an embodiment of the present disclosure.
- FIG. 3 is a sectional view of the hydrogen-oxygen mixed gas generator of FIG. 1 , taken along lines
- Embodiments of the present disclosure solve the above-mentioned problems as well as others, to provide an economical hydrogen-oxygen mixed gas generator by expanding the produced amount of hydrogen-oxygen gas mixture compared to the amount of electricity used.
- the hydrogen-oxygen generator produced to solve the above problems contains a caliber, a metal thin walled tube ( 10 ), an insulation tube ( 20 ) inside the thin walled tube ( 10 ), multiple 1 st electrolyte plate ( 31 ) that has the 1 st small hole ( 31 c ) placed at the lower part of the center hole ( 31 a ) and the first big hole ( 31 b ) place on the upper part of the center hole ( 31 a ), multiple 2 nd electrolyte plates ( 32 ) with the small hole ( 32 c ) on the upper part of the center hole ( 32 a ) and the 2 nd big hole ( 32 b ) on the lower part of the center hole ( 32 b ), a number of rings with a certain thickness ( 33 ) between the 1 st electrolyte plate ( 31 ) and the 2 nd electrolyte plate ( 32 ), the electrolyte unit ( 30 ) including the electric pole ( 34 ) penet
- the amount of hydrogen-oxygen mixed gas produced can be increased relative to the amount of electricity used and economical efficiency for the gas can be combusted without adding any additional gas, such as propane gas.
- FIGS. 1-3 The following more detailed descriptions are also based on the attached FIGS. 1-3 .
- the hydrogen-oxygen mixed gas generator is a round metal thin walled tube ( 10 ), multiple the 1 st electrolyte plates ( 31 ) with the 1 st small hole ( 31 c ) and the 1 st big hole ( 31 b ) each on the upper and lower part of the center hole ( 31 a ), multiple 2 nd electrolyte plates( 31 ) with the small hole ( 32 c ) on the upper part of the center hole ( 32 a ) and the 2 nd big hole ( 32 b ) on the lower part of the center hole ( 32 b ), a number of rings with certain thickness ( 33 ) between the 1 st electrolyte plate ( 31 ) and the 2 nd electrolyte plate ( 32 ), electrolyte unit ( 30 ) including the 1 st electric pole ( 34 ) penetrating the small holes ( 31 c ) and the 2 nd electric pole ( 35 ) penetrating the 2 nd small holes ( 32 c
- Front sealing plate ( 46 ) is applied in middle of the front cover ( 10 ) and the thin walled tube ( 40 ) to seal between the front cover ( 40 ) and the thin walled tube ( 10 ) and the rear sealing plate is set up to seal the rear cover ( 50 ) and the thin walled tube ( 10 ).
- the front and rear sealing plates ( 46 ) ( 56 ) and the front and rear covers ( 40 ) ( 50 ) are likely to be made of insulating metal.
- the 1 st thermal conduction plate ( 70 ) is formed between the insulation pipe ( 20 ) and the thin walled tube ( 10 ) to deliver the heat produced while the electrolysis to the thin walled tube ( 10 ) through the insulation pipe ( 20 ) efficiently.
- the 2 nd thermal conduction plate ( 80 ) is formed between the heat radiant plate ( 60 ) and the thin walled tube ( 10 ) to transfer the heat from the thin walled tube ( 10 ) to the heat radiant plate ( 60 ).
- the thin walled tube ( 10 ) can be in any shape; circular, rectangular, hexagonal and so on. It can also be formed by metals such as stainless or alloy steel.
- the thin walled tube ( 10 ) is in a circular shape and has frontal and rear flanges ( 10 a ) ( 10 b ) on both sides.
- This thin walled tube ( 10 ) would be the body of the product.
- the insulation pipe ( 20 ) is favorably composed of materials in which the properties may not be altered during the electrolysis of water, such as Teflon rubber, acetal, or PP, PE substances.
- the 1 st big hole ( 31 b ) and the 1 st small hole ( 31 c ) are formed around the center hole ( 31 a ) at the center of the 1 st electrolyte plate ( 31 ).
- the cylindrical surface area inside the 1 st small hole ( 31 c ) touch the 1 st electric pole ( 34 ) but because the diameter of the 1 st big hole ( 31 b ) is larger than that of the 1 st small hole ( 31 c ), the inner surface are of the 1 st big hole ( 31 b ) does not touch the 1 st electric pole ( 34 ).
- the 2 nd big hole ( 32 b ) and the 2 nd small hole ( 32 c ) are formed around the center hole ( 32 a ) at the center of the 2 nd electrolyte plate ( 32 ).
- the cylindrical surface area inside the 2 nd small hole ( 32 c ) touch the 2 nd electric pole ( 35 ) but because the diameter of the 2 nd big hole ( 32 b ) is larger than that of the 2 nd small hole ( 32 c ), the inner surface are of the 2 nd big hole ( 32 b ) does not touch the 2 nd electric pole ( 35 ).
- the center holes ( 31 a )( 32 a ) on the 1 st electrolyte plate ( 31 ) and the 2 nd electrolyte plate ( 32 ) are shaped as cylinders so water could flow by.
- the ring with a certain thickness ( 33 ) are the rings with the same diameter as the 1,2 nd electrolyte plates ( 31 ) ( 32 ) and separates the 1 st electrolyte plate ( 31 ) and the 2 nd electrolyte plate ( 32 ) so they would not touch each other.
- the 1,2 nd electrolyte plates ( 31 ) ( 32 ) and the ring with a certain thickness have width of 3 mm.
- the 1,2 nd electric poles ( 34 ) ( 35 ) have bolts at the end of each pole.
- the 1 st and the 2 nd electrolyte plates ( 31 )( 32 ) are placed alternatively between the rings ( 33 ) and the 1 st electric pole ( 34 ) 9s connected to the 1 st electrolyte plate ( 31 ) electrically and the 2 nd electric pole ( 35 ) is connected to the 2 nd electrolyte plate ( 32 ).
- a terminal bolt ( 37 ) joining the cluster of bolts ( 34 a )( 35 a ) and the 1,2 nd electric poles ( 34 )( 35 ) can be installed.
- the terminal bolt ( 37 ) is pierced through the 1,2,3,4 th pipes ( 44 )( 45 )( 54 )( 55 ) and is composed of the bolt's ( 37 a ) which connects the 1,2 nd electric poles ( 34 )( 35 ) and the cluster of bolts ( 34 a )( 35 a ) and the bolt's head ( 37 b ) connected to the wire exposed outside the front and rear covers ( 40 )( 50 ) transferring electricity.
- the overall diameter is larger then the 1,2 nd electric poles ( 34 )( 35 ).
- the hydrogen-oxygen mixed gas generator in the example uses low voltage of DC 1-12 V but still dozens of amperes are used.
- the terminal wired to the 1,2 nd electric pole ( 34 )( 35 ) produce massive amount of heat.
- the 1,2 nd electric pole can manage some heat since they are under the water but the terminal above the water can damage the coating of the wires due to lots of heat.
- the terminal bolt ( 37 ) with larger diameter then the 1,2 nd electric poles is used.
- the terminal bolt's ( 37 ) body ( 37 a ) would radiate some heat by sinking into the water in the thin walled tube ( 10 ) decrease the heat produced due to the larger diameter of the bolt's head ( 37 b ) then that of the 1,2 nd electric poles ( 34 )( 35 ).
- the electrolyte plates ( 31 ) should be made from a material that can carry electrolysis effectively.
- One of the materials would be carbon nano-tube alloy steel.
- Carbon nano-tube alloy steel is formed when carbon nano-tube, nickel, and tourmaline powdered and compressed in a form of electrode plate and ignited. Sodium decarboxylation chemical composition may be added and the ignition is carried at 1300° C.
- the electrolyte plates ( 31 ) can also be made from stainless steel which would carry out the electrolysis effectively and also separate the hydrogen-oxygen bubbles when polished by nano-technology the electrolyte plate ( 31 ) is made in metals such as stainless steel or alloy steels.
- Nano-technology means polishing electrolyte plate's ( 31 ) surface by nano units. Polishing by nano technology would minimize the electrode plate's surface friction, making hydrogen or oxygen gas bubbles to separate easily.
- the technical, thermal, electrical, magnetic, and optical properties change when the size of the matter decreases from bulk to nano meter, making electrolysis on water effortless.
- tourmaline catalyst can be attached on the surface of electrolyte plate ( 31 ).
- the tourmaline catalyst would be grinded into micro to nanometer powder, burned in 1300° C. and glued to the electrolyte plate ( 31 ).
- Tourmaline is a mineral under the hexagonal system like crystal; electricity forms by friction, produce massive amount of anion, and catalyzes the electrolysis producing lots of hydrogen and oxygen. Tourmaline becomes a catalyst with many tiny pores that can increase the contact area with electrolyte after being powdered and burned.
- the tourmaline catalyst can promote the electrolysis of electrolytes when attached on the electrolyte plate ( 31 ).
- the front cover ( 40 ) is joined with the frontal flange ( 10 a ) to insulate by the frontal sealing plate ( 46 ) in front of the thin walled tube ( 10 ), bolts (B) and nuts ( ).
- the rear cover ( 50 ) is joined with the rear flange ( 10 b ) to insulate by the rear sealing plate ( 56 ) at the back of the tube ( 10 ), bolts (B), and nuts (N).
- the front and rear water flowing pipes ( 41 )( 51 ) are set up opposite to the center holes ( 31 a )( 32 a ) on the 1,2 nd electrolyte plates ( 31 )( 32 ) so when water is flowing into the front or the rear water flowing pipe ( 41 )( 51 ), the water mixed with the hydrogen-oxygen mixed gas goes out to the other pipe.
- the front sealing plate ( 46 ) includes the front gasket ( 46 a ) between the front cover ( 40 ) and the front flange ( 10 a ) and the front gasket ring ( 46 b ) installed on the front of the front cover ( 40 ) and the back of the front flange ( 10 a ) by the bolts (B) and Nuts (N).
- the rear sealing plate ( 56 ) includes the rear gasket ( 56 a ) between the rear cover ( 50 ) and the rear flange ( 10 b ) and the rear gasket ring ( 56 b ) installed on the front of the rear cover ( 50 ) and the back of the rear flange ( 10 b ) by the bolts (B) and nuts (N).
- the insulating gaskets ( 47 )( 57 ) play insulators disconnecting electricity flowing from the 1,2 nd pipes ( 34 )( 35 ) and seals to prevent a leak as they are connected to the 1,2 nd pipes ( 44 )( 45 ) and the 3,4 th pipes ( 54 )( 55 ).
- the insulating gaskets ( 47 )( 57 ) contain the bodies of the gaskets ( 47 a )( 57 a ) on the 1,2,3,4 th pipes ( 44 )( 45 )( 54 )( 55 ) and gasket flanges ( 47 b )( 57 b ) which has bigger diameter than that of the gaskets ( 47 a )( 57 a ) on the outside of the front and rear covers ( 40 )( 50 ).
- the material can be insulating Teflon.
- the heat radiant plate ( 60 ) is composed of the heat radiant pipe ( 61 ) on the thin walled tube ( 10 ) in between the front and rear covers ( 40 )( 50 ) and the multiple heat radiant pins ( 62 ) placed apart from each other on the heat radiant pipe ( 61 ).
- the heat radiant pipe ( 61 ) and the pins ( 62 ) can be formed by polishing round aluminum or stainless pipes by NC machine, using casting, or sculpturing the heat resistant plastic or ceramics. But in forming the heat radiant plate ( 60 ), the heat radiant pipe ( 61 ) and the pins ( 62 ) can be made separately and connected later on.
- carbon nano-tube or tourmaline catalyst in nanometer size, preferably in 10-60 nanometers, can be applied alone or together.
- the 1 st thermal conduction plate transfers heat produced during the electrolysis to the thin walled tube ( 10 ) through the insulating pipe ( 20 ).
- the 2 nd thermal conduction plate delivers the heat transferred to the thin walled tube ( 10 ) to the heat radiant plate ( 60 ) efficiently.
- the 1,2 nd thermal conduction plates ( 70 )( 80 ) have carbon nano-tube and tourmaline catalysts, preferably in size of 10-6-nanometers, applied.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
- Catalysts (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Abstract
A hydrogen-oxygen generating apparatus includes a metal thin walled tube, an insulation tube inside the thin walled tube, multiple 1st electrolyte plate that has a 1st small hole placed below a part of a center hole and a first big hole placed above an upper part of the center hole, multiple 2nd electrolyte plates with small hole placed above an upper part of a center hole and a 2nd big hole below a lower part of the center hole, a number of rings with a certain thickness between the 1st electrolyte plate and the 2nd electrolyte plate, an electrolyte unit including a 1st electric pole penetrating the 1st small holes and a 2nd electric pole penetrating the 2nd small holes when the 1st electrolyte plate and the 2nd electrolyte plate are placed opposed to each other, a front cover with a frontal water flowing pipe at a center and the 1st electric pole and the 2nd electric pole piercing the cover through 1,2nd pipes up and down the cover in front of the thin walled tube, a rear cover with the 1st electric pole and 2nd electric pole piecing through 3,4th pipes at the upper and lower part of a rear water flowing pipe at a center of the rear cover at the back of the thin walled tube, insulating gaskets on the 1,2nd electric pole connecting the 1,2nd pipes and the 3,4th pipes and a heat radiant plate containing a number of heat radiant pins.
Description
- The present disclosure is based on and claims the benefit of Korean Patent Application No. 10-2008-0121190 filed on Dec. 2, 2008, the entire contents of which are herein incorporated by reference.
- 1. Field of the Disclosure
- The present disclosure relates to generating apparatuses and, more particularly, to hydrogen-oxygen generating apparatuses.
- 2. Background
- Hydrogen-oxygen mixed-gas generating systems are made to produce hydrogen and oxygen from electrolyzed water; to gain hydrogen-oxygen mixed gas, water containing small amount of electrolytes is provided to the storage with positive (+) and negative (−) electrodes and electrolyzed by direct current. Hydrogen and oxygen produced from the process is at ratio of 2:1 and hydrogen is formed as bubbles on the surface of negative (−) electrode and oxygen in bubbles on the positive (+) electrode. The hydrogen and oxygen produced can be mixed and combusted. Also hydrogen-oxygen gas mixture does not produce any pollutants when ignited, making it an important eco-friendly energy source
- However, because the amount of hydrogen-oxygen produced is relatively small compared to the amount of electric current transferred to (−) and (+) electrodes, additional gas, such as propane gas, is added and combusted, resulting in low economical efficiency.
- A hydrogen-oxygen generating apparatus includes a metal thin walled tube, an insulation tube inside the thin walled tube, multiple 1st electrolyte plate that has a 1st small hole placed below a part of a center hole and a first big hole placed above an upper part of the center hole, multiple 2nd electrolyte plates with small hole placed above an upper part of a center hole and a 2nd big hole below a lower part of the center hole, a number of rings with a certain thickness between the 1st electrolyte plate and the 2nd electrolyte plate, an electrolyte unit including a 1st electric pole penetrating the 1st small holes and a 2nd electric pole penetrating the 2nd small holes when the 1st electrolyte plate and the 2nd electrolyte plate are placed opposed to each other, a front cover with a frontal water flowing pipe at a center and the 1st electric pole and the 2nd electric pole piercing the cover through 1,2nd pipes up and down the cover in front of the thin walled tube, a rear cover with the 1st electric pole and 2nd electric pole piecing through 3,4th pipes at the upper and lower part of a rear water flowing pipe at a center of the rear cover at the back of the thin walled tube, insulating gaskets on the 1,2nd electric pole connecting the 1,2nd pipes and the 3,4th pipes and a heat radiant plate containing a number of heat radiant pins.
- A more complete appreciation of the present disclosure and many of the attendant advantages thereof will be readily obtained as the same becomes better understood by reference to the following detailed description when considered in connection with the accompanying drawings, wherein:
-
FIG. 1 is a diagram of a hydrogen-oxygen mixed gas generator according to an embodiment of the present disclosure; -
FIG. 2 is an exploded view of the hydrogen-oxygen mixed gas generator according to an embodiment of the present disclosure; and -
FIG. 3 is a sectional view of the hydrogen-oxygen mixed gas generator ofFIG. 1 , taken along lines - Embodiments of the present disclosure are explained by reference to the accompanying figures. Of course, the figures are examples, and anyone with appropriate knowledge in the field would understand that there can be many variations that may apply.
- Embodiments of the present disclosure solve the above-mentioned problems as well as others, to provide an economical hydrogen-oxygen mixed gas generator by expanding the produced amount of hydrogen-oxygen gas mixture compared to the amount of electricity used.
- Referring to
FIGS. 1-3 , the hydrogen-oxygen generator produced to solve the above problems contains a caliber, a metal thin walled tube (10), an insulation tube (20) inside the thin walled tube (10), multiple 1st electrolyte plate (31) that has the 1st small hole (31 c) placed at the lower part of the center hole (31 a) and the first big hole (31 b) place on the upper part of the center hole (31 a), multiple 2nd electrolyte plates (32) with the small hole (32 c) on the upper part of the center hole (32 a) and the 2nd big hole (32 b) on the lower part of the center hole (32 b), a number of rings with a certain thickness (33) between the 1st electrolyte plate (31) and the 2nd electrolyte plate (32), the electrolyte unit (30) including the electric pole (34) penetrating the 1st small holes (31 c) and the 2nd electric pole (35) penetrating the 2nd small holes (32 c) as the 1st electrolyte plate (31) and the 2nd electrolyte plate (32) are place opposed to each other, the front cover (40) with the frontal water flowing pipe (41) at the center and the 1st electric pole (34) and the 2nd electric pole (35) piercing the cover through the 1,2nd pipes (44)(45) up and down the cover in front of the thin walled tube (10), the rear cover (50) with the 1st electric pole (34) and 2nd electric pole (35) piecing through the 3,4th pipes (54)(55) at the upper and lower part of the rear water flowing pipe (51) at the center of the rear cover (50) at the back of the thin walled tube (10), insulating gaskets (47)(57) on the 1,2nd electric pole (34)(35) connecting the 1,2nd pipes (44)(45) and the 3,4rh pipes (54)(55), and the heat radiant plate (60) containing a number of heat radiant pins (62). - According to the developed hydrogen-oxygen mixed gas generator the amount of hydrogen-oxygen mixed gas produced can be increased relative to the amount of electricity used and economical efficiency for the gas can be combusted without adding any additional gas, such as propane gas.
- Also, hydrogen and oxygen formed in bubble forms can be easily removed from the electrodes. As a result, the surface area of the electrodes is enlarged, amplifying the electrolysis efficiency.
- The following more detailed descriptions are also based on the attached
FIGS. 1-3 . - The hydrogen-oxygen mixed gas generator according to an embodiment of the present disclosure is a round metal thin walled tube (10), multiple the 1st electrolyte plates (31) with the 1st small hole (31 c) and the 1st big hole (31 b) each on the upper and lower part of the center hole (31 a), multiple 2nd electrolyte plates(31) with the small hole (32 c) on the upper part of the center hole (32 a) and the 2nd big hole (32 b) on the lower part of the center hole (32 b), a number of rings with certain thickness (33) between the 1st electrolyte plate (31) and the 2nd electrolyte plate (32), electrolyte unit (30) including the 1st electric pole (34) penetrating the small holes (31 c) and the 2nd electric pole (35) penetrating the 2nd small holes (32 c) as the 1st electrolyte plate (31) and the 2nd electrolyte plate (32) are place opposed to each other, the front cover (40) with the frontal water flowing pipe (41) at the center and the 1st electric pole (34) and the 2nd electric pole (35) piercing the cover through the 1,2nd pipes (44)(45) up and down the cover in front of the thin walled tube (10), the rear cover (50) with the 1st electric pole (34) and 2nd electric pole (35) piecing through the 3,4th pipes (54)(55) at the upper and lower part of the rear water flowing pipe (51) at the center of the rear cover (50) at the back of the thin walled tube (10), insulating gaskets (47)(57) on the 1,2nd electric pole (34)(35) connecting the 1,2nd pipes (44)(45) and the 3,4rh pipes (54)(55), and the heat radiant plate (60) containing a number of heat radiant pins (62).
- Front sealing plate (46) is applied in middle of the front cover (10) and the thin walled tube (40) to seal between the front cover (40) and the thin walled tube (10) and the rear sealing plate is set up to seal the rear cover (50) and the thin walled tube (10). The front and rear sealing plates (46) (56) and the front and rear covers (40) (50) are likely to be made of insulating metal.
- The 1st thermal conduction plate (70) is formed between the insulation pipe (20) and the thin walled tube (10) to deliver the heat produced while the electrolysis to the thin walled tube (10) through the insulation pipe (20) efficiently. Also the 2nd thermal conduction plate (80) is formed between the heat radiant plate (60) and the thin walled tube (10) to transfer the heat from the thin walled tube (10) to the heat radiant plate (60). The thin walled tube (10) can be in any shape; circular, rectangular, hexagonal and so on. It can also be formed by metals such as stainless or alloy steel. In the invention explained above, the thin walled tube (10) is in a circular shape and has frontal and rear flanges (10 a) (10 b) on both sides. This thin walled tube (10) would be the body of the product.
- The insulation pipe (20), adhered inside the thin walled tube (10), insulates the insulation pipe (20) and the electrolyte plate (30). The insulation pipe (20) is favorably composed of materials in which the properties may not be altered during the electrolysis of water, such as Teflon rubber, acetal, or PP, PE substances.
- As drawn, the 1st big hole (31 b) and the 1st small hole (31 c) are formed around the center hole (31 a) at the center of the 1st electrolyte plate (31). At this point, the cylindrical surface area inside the 1st small hole (31 c) touch the 1st electric pole (34) but because the diameter of the 1st big hole (31 b) is larger than that of the 1st small hole (31 c), the inner surface are of the 1st big hole (31 b) does not touch the 1st electric pole (34). Also, the 2nd big hole (32 b) and the 2nd small hole (32 c) are formed around the center hole (32 a) at the center of the 2nd electrolyte plate (32). At this point, the cylindrical surface area inside the 2nd small hole (32 c) touch the 2nd electric pole (35) but because the diameter of the 2nd big hole (32 b) is larger than that of the 2nd small hole (32 c), the inner surface are of the 2nd big hole (32 b) does not touch the 2nd electric pole (35). The center holes (31 a)(32 a) on the 1st electrolyte plate (31) and the 2nd electrolyte plate (32) are shaped as cylinders so water could flow by.
- The ring with a certain thickness (33) are the rings with the same diameter as the 1,2nd electrolyte plates (31) (32) and separates the 1st electrolyte plate (31) and the 2nd electrolyte plate (32) so they would not touch each other. In the example, the 1,2nd electrolyte plates (31) (32) and the ring with a certain thickness have width of 3 mm.
- The 1,2nd electric poles (34) (35) have bolts at the end of each pole.
- According to the structure described, the 1st and the 2nd electrolyte plates (31)(32) are placed alternatively between the rings (33) and the 1st electric pole (34) 9s connected to the 1st electrolyte plate (31) electrically and the 2nd electric pole (35) is connected to the 2nd electrolyte plate (32).
- On the 1,2nd pipes (44)(45) of the front cover (40) and the 3,4th pipes (54)(55) on the rear cover (50), a terminal bolt (37) joining the cluster of bolts (34 a)(35 a) and the 1,2nd electric poles (34)(35) can be installed. The terminal bolt (37) is pierced through the 1,2,3,4th pipes (44)(45)(54)(55) and is composed of the bolt's (37 a) which connects the 1,2nd electric poles (34)(35) and the cluster of bolts (34 a)(35 a) and the bolt's head (37 b) connected to the wire exposed outside the front and rear covers (40)(50) transferring electricity. The overall diameter is larger then the 1,2nd electric poles (34)(35).
- The hydrogen-oxygen mixed gas generator in the example uses low voltage of DC 1-12 V but still dozens of amperes are used. As a result, the terminal wired to the 1,2nd electric pole (34)(35) produce massive amount of heat. The 1,2nd electric pole can manage some heat since they are under the water but the terminal above the water can damage the coating of the wires due to lots of heat. To prevent it, the terminal bolt (37) with larger diameter then the 1,2nd electric poles is used. The terminal bolt's (37) body (37 a) would radiate some heat by sinking into the water in the thin walled tube (10) decrease the heat produced due to the larger diameter of the bolt's head (37 b) then that of the 1,2nd electric poles (34)(35).
- The electrolyte plates (31) should be made from a material that can carry electrolysis effectively. One of the materials would be carbon nano-tube alloy steel. Carbon nano-tube alloy steel is formed when carbon nano-tube, nickel, and tourmaline powdered and compressed in a form of electrode plate and ignited. Sodium decarboxylation chemical composition may be added and the ignition is carried at 1300° C.
- The electrolyte plates (31) can also be made from stainless steel which would carry out the electrolysis effectively and also separate the hydrogen-oxygen bubbles when polished by nano-technology the electrolyte plate (31) is made in metals such as stainless steel or alloy steels.
- Nano-technology means polishing electrolyte plate's (31) surface by nano units. Polishing by nano technology would minimize the electrode plate's surface friction, making hydrogen or oxygen gas bubbles to separate easily. The technical, thermal, electrical, magnetic, and optical properties change when the size of the matter decreases from bulk to nano meter, making electrolysis on water effortless.
- On the surface of electrolyte plate (31), tourmaline catalyst can be attached. The tourmaline catalyst would be grinded into micro to nanometer powder, burned in 1300° C. and glued to the electrolyte plate (31). Tourmaline is a mineral under the hexagonal system like crystal; electricity forms by friction, produce massive amount of anion, and catalyzes the electrolysis producing lots of hydrogen and oxygen. Tourmaline becomes a catalyst with many tiny pores that can increase the contact area with electrolyte after being powdered and burned. The tourmaline catalyst can promote the electrolysis of electrolytes when attached on the electrolyte plate (31).
- The front cover (40) is joined with the frontal flange (10 a) to insulate by the frontal sealing plate (46) in front of the thin walled tube (10), bolts (B) and nuts ( ). Also, the rear cover (50) is joined with the rear flange (10 b) to insulate by the rear sealing plate (56) at the back of the tube (10), bolts (B), and nuts (N). The front and rear water flowing pipes (41)(51) are set up opposite to the center holes (31 a)(32 a) on the 1,2nd electrolyte plates (31)(32) so when water is flowing into the front or the rear water flowing pipe (41)(51), the water mixed with the hydrogen-oxygen mixed gas goes out to the other pipe.
- As drawn in the diagram 2 and 3, the front sealing plate (46) includes the front gasket (46 a) between the front cover (40) and the front flange (10 a) and the front gasket ring (46 b) installed on the front of the front cover (40) and the back of the front flange (10 a) by the bolts (B) and Nuts (N).
- As drawn in the diagram 2 and 3, the rear sealing plate (56) includes the rear gasket (56 a) between the rear cover (50) and the rear flange (10 b) and the rear gasket ring (56 b) installed on the front of the rear cover (50) and the back of the rear flange (10 b) by the bolts (B) and nuts (N).
- The insulating gaskets (47)(57) play insulators disconnecting electricity flowing from the 1,2nd pipes (34)(35) and seals to prevent a leak as they are connected to the 1,2nd pipes (44)(45) and the 3,4th pipes (54)(55). The insulating gaskets (47)(57) contain the bodies of the gaskets (47 a)(57 a) on the 1,2,3,4th pipes (44)(45)(54)(55) and gasket flanges (47 b)(57 b) which has bigger diameter than that of the gaskets (47 a)(57 a) on the outside of the front and rear covers (40)(50). The material can be insulating Teflon.
- The heat radiant plate (60) is composed of the heat radiant pipe (61) on the thin walled tube (10) in between the front and rear covers (40)(50) and the multiple heat radiant pins (62) placed apart from each other on the heat radiant pipe (61). The heat radiant pipe (61) and the pins (62) can be formed by polishing round aluminum or stainless pipes by NC machine, using casting, or sculpturing the heat resistant plastic or ceramics. But in forming the heat radiant plate (60), the heat radiant pipe (61) and the pins (62) can be made separately and connected later on. Furthermore, to increase the heat resistance on the heat radiant plate (60), carbon nano-tube or tourmaline catalyst in nanometer size, preferably in 10-60 nanometers, can be applied alone or together.
- The 1st thermal conduction plate transfers heat produced during the electrolysis to the thin walled tube (10) through the insulating pipe (20). The 2nd thermal conduction plate delivers the heat transferred to the thin walled tube (10) to the heat radiant plate (60) efficiently. To accomplish the goals, the 1,2nd thermal conduction plates (70)(80) have carbon nano-tube and tourmaline catalysts, preferably in size of 10-6-nanometers, applied.
- According to the structure described, if electric current is provided to the 1,2nd electric poles (35)(45) when water is flowing in either front or rear water flowing pipes (41)(51), − and + electric charge is formed on the surfaces of the 1,2nd electrolyte plates (31)(32), and the magnetic field is created between the 1,2nd electrolyte plates (31)(32). The electric space, where electrolysis is carried, becomes the place where magnetic field is formed and the total electric space expands according to the number of the 1,2nd electrolyte plates (31)(32) so the electrolysis becomes active, producing lots of hydrogen and oxygen gas. The hydrogen-oxygen gas produced goes out through one of the front or the rear water flowing pipes after mixed together.
- The present disclosure is described herein by reference to specific examples. Of course, it should be kept in mind that these are only specific possibilities and anyone with sufficient knowledge in the field would understand that variations can be applied.
- The following list identifies various elements depicted in the Figures:
- 10—thin walled tube
- 10 a,10 b—front and rear flange
- 20—insulation pipe
- 30—electrolyte unit
- 31—the 1st electrolyte plate
- 31 a—center hole
- 31 b—the 1st big hole
- 31 c—the 1st small hole
- 32—the 2nd electrolyte plate
- 32 a—center hole
- 32 b—the 2nd big hole
- 32 c—the 2nd small hole
- 33—ring with a certain thickness
- 34,35—the 1,2nd electric poles
- 34 a,35 a—cluster of bolts
- 37—terminal bolts
- 37 a—bolt's body
- 37 b—bolt's head
- 40—front cover
- 41—front water flowing pipe
- 44,45—the 1,2nd pipe
- 46—front sealing plate
- 46 a—front gasket
- 46 b—front gasket ring
- 56—rear sealing plate
- 56 a—rear gasket
- 56 b—rear gasket ring
- 47,57—insulation gasket
- 47 a,47 b—body of gasket
- 57 a,57 b—gasket flange
- 50—rear cover
- 51—rear water flowing pipe
- 54,55—the 3,4th pipes
- 60—heat radiant plate
- 61—heat radiant pipe
- 62—heat radiant pin
- 70—the 1st thermal conduction plate
- 80—the 2nd thermal conduction plate
Claims (6)
1. A hydrogen-oxygen generating apparatus comprises:
a metal thin walled tube;
an insulation tube inside the thin walled tube;
multiple 1st electrolyte plate that has a 1st small hole placed below a part of a center hole and a first big hole placed above an upper part of the center hole;
multiple 2nd electrolyte plates with small hole placed above an upper part of a center hole and a 2nd big hole below a lower part of the center hole;
a number of rings with a certain thickness between the 1st electrolyte plate and the 2nd electrolyte plate;
an electrolyte unit including a 1st electric pole penetrating the 1st small holes and a 2nd electric pole penetrating the 2nd small holes when the 1st electrolyte plate and the 2nd electrolyte plate are placed opposed to each other;
a front cover with a frontal water flowing pipe at a center and the 1st electric pole and the 2nd electric pole piercing the cover through 1,2nd pipes up and down the cover in front of the thin walled tube;
a rear cover with the 1st electric pole and 2nd electric pole piecing through 3,4th pipes at the upper and lower part of a rear water flowing pipe at a center of the rear cover at the back of the thin walled tube;
insulating gaskets on the 1,2nd electric pole connecting the 1,2nd pipes and the 3,4th pipes; and
a heat radiant plate containing a number of heat radiant pins.
2. The hydrogen-oxygen generating apparatus according to claim 1 , further comprising:
a front sealing plate applied in middle of the front cover and the thin walled tube to seal between the front cover and the thin walled tube; and
a rear sealing plate applied in middle of the rear cover and the thin walled tube to seal the rear cover and the thin walled tube.
3. The hydrogen-oxygen generating apparatus according to claim 2 , wherein the front sealing plate includes the front gasket between the front cover and a front flange and the front gasket ring installed on the front of the front cover and the back of the front flange by bolts and Nuts and wherein the rear sealing plate includes the rear gasket between the rear cover and a rear flange and the rear gasket ring installed on the front of the rear cover and the back of the rear flange by bolts and nuts.
4. The hydrogen-oxygen generating apparatus according to claim 1 , wherein the the electrolyte plates are made from carbon nano-tube alloy steel.
5. The hydrogen-oxygen generating apparatus according to claim 1 , wherein a surface of the electrolyte plates is polished by nano-technology to carry out the electrolysis effectively and also to separate the hydrogen-oxygen bubbles.
6. The hydrogen-oxygen generating apparatus according to claim 1 , wherein on a surface of electrolyte plate, tourmaline catalyst is attached.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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KR1020080121190A KR100894288B1 (en) | 2008-12-02 | 2008-12-02 | A hydrogen-oxygen generating apparatus |
KR10-2008-0121190 | 2008-12-02 |
Publications (1)
Publication Number | Publication Date |
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US20100155234A1 true US20100155234A1 (en) | 2010-06-24 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US12/592,637 Abandoned US20100155234A1 (en) | 2008-12-02 | 2009-11-30 | Hydrogen-oxygen generating apparatus |
Country Status (8)
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US (1) | US20100155234A1 (en) |
EP (1) | EP2199431A1 (en) |
JP (1) | JP2010133026A (en) |
KR (1) | KR100894288B1 (en) |
CN (1) | CN101748421A (en) |
AU (1) | AU2009243469A1 (en) |
BR (1) | BRPI0905352A2 (en) |
TW (1) | TW201030186A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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US20110024695A1 (en) * | 2009-02-18 | 2011-02-03 | Boo-Sung Hwang | Hydrogen-oxygen generating electrode Plate and method for manufacturing the same |
WO2012144961A1 (en) * | 2011-04-21 | 2012-10-26 | Katanyoophatai Co., Ltd. | Catalytic converter for hydrogen powered engine |
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US8591707B2 (en) * | 2011-05-03 | 2013-11-26 | Hydroripp, LLC | Hydrogen gas generator |
KR101344047B1 (en) | 2013-03-20 | 2013-12-24 | 유병인 | Hydrogen-oxygen mixing gas generator and system for generating hydrogen-oxygen mixing gas using the same |
US9939866B2 (en) | 2014-05-22 | 2018-04-10 | Uripp Llc | Operating system control for power source |
JP6586231B2 (en) | 2016-06-07 | 2019-10-02 | 富士フイルム株式会社 | Photocatalytic electrode, artificial photosynthesis module, and artificial photosynthesis device |
CN106090910B (en) * | 2016-08-15 | 2017-11-24 | 衢州昀睿工业设计有限公司 | A kind of aqueous medium gasification combustion system |
CN109869717B (en) * | 2019-01-29 | 2020-05-19 | 武汉船用电力推进装置研究所(中国船舶重工集团公司第七一二研究所) | Self-heating hydrogen-oxygen catalytic combustor and self-heating starting method |
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Also Published As
Publication number | Publication date |
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EP2199431A1 (en) | 2010-06-23 |
KR100894288B1 (en) | 2009-04-21 |
JP2010133026A (en) | 2010-06-17 |
CN101748421A (en) | 2010-06-23 |
BRPI0905352A2 (en) | 2015-10-27 |
AU2009243469A1 (en) | 2010-06-17 |
TW201030186A (en) | 2010-08-16 |
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