US20100018668A1 - Co2 based district energy system - Google Patents

Co2 based district energy system Download PDF

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Publication number
US20100018668A1
US20100018668A1 US12/526,877 US52687708A US2010018668A1 US 20100018668 A1 US20100018668 A1 US 20100018668A1 US 52687708 A US52687708 A US 52687708A US 2010018668 A1 US2010018668 A1 US 2010018668A1
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United States
Prior art keywords
energy system
pipe
end user
district
district energy
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Abandoned
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US12/526,877
Inventor
Daniel Favrat
Céline Weber
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Ecole Polytechnique Federale de Lausanne EPFL
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Ecole Polytechnique Federale de Lausanne EPFL
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Priority to US12/526,877 priority Critical patent/US20100018668A1/en
Assigned to ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL) reassignment ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL) ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: FAVRAT, DANIEL, WEBER, CELINE
Publication of US20100018668A1 publication Critical patent/US20100018668A1/en
Abandoned legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D7/00Central heating systems employing heat-transfer fluids not covered by groups F24D1/00 - F24D5/00, e.g. oil, salt or gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D10/00District heating systems
    • F24D10/003Domestic delivery stations having a heat exchanger
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D12/00Other central heating systems
    • F24D12/02Other central heating systems having more than one heat source
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D2200/00Heat sources or energy sources
    • F24D2200/12Heat pump
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24HEATING; RANGES; VENTILATING
    • F24DDOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
    • F24D2200/00Heat sources or energy sources
    • F24D2200/13Heat from a district heating network
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/17District heating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/14Combined heat and power generation [CHP]

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Other Air-Conditioning Systems (AREA)
  • Pipeline Systems (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

District energy system comprising a pipe system, end user's locations, and an optional plant for transferring an energy transfer medium between said end user's locations and/or between said optional plant and said end user's locations, characterized by the fact that said energy transfer medium is CO2.

Description

    FIELD OF INVENTION
  • The present invention relates to district energy systems which are converting energy and delivering energy services (e.g. heating, hot water, cooling and electricity) to buildings at various locations, using renewable energy sources, as well as waste heat, and making use of synergies between buildings.
  • STATE OF THE ART
  • District energy systems produce steam, hot water or chilled water at a central plant and then pipe that water out to buildings in the district for space heating, domestic hot water heating and air conditioning. Individual buildings don't need their own boilers or furnaces, chillers or air conditioners. A district energy system does that work for them.
  • GENERAL DESCRIPTION OF THE INVENTION
  • One object of the present invention is to offer a valuable alternative to existing district energy systems.
  • Another object is to reduce the space required to implement the pipes in the ground or in underground channels.
  • Another object is to solve the safety issues linked with possible leakage problems when implementing water pipes in underground channels including electrical or telecommunication wires.
  • Another object is to enhance the energetic and exergetic efficiencies of district energy systems.
  • Another object is make use of the latent heat of the transfer medium instead of the specific heat.
  • Another object is to have a CO2 “reservoir” from which CO2 can be extracted (fire extinction) or stored (fuel cell).
  • The above objects are solved in accordance with the invention by a district energy system characterized by the use of CO2 as energy transfer medium.
  • Preferred embodiments of the invention are defined in the claims.
  • The present invention offers several advantages, in particular:
      • a) Unlike conventional district heating/cooling systems, the thermodynamic state of the working fluid, CO2, is not defined only at a central heating/cooling plant, but also directly at the customer's place when requested with decentralized compressor units, heat pumps, expansion valves, condensers and evporators. The thermodynamic state of the CO2 can thus be directly adjusted following the specific requirements of each building, thereby minimizing energy losses.
      • b) Unlike conventional district heating/cooling systems having one working fluid for the heat-pump for instance at the central heating/cooling plant, and another working fluid in the pipes of the network, in the case described here there is only one working fluid for the whole system, thus minimizing energy losses in additional heat-exchangers.
      • c) When combining different modes at the customer's place (see below), because of the internal recirculation of the CO2 at the customer's place, a direct energy transfer takes place between the heating and the air-conditioning requirements (or vice-versa), so that the CO2 that is being pumped between the heating/cooling plant and the customer is kept to a minimum.
      • d) Only two pipes are required to meet all the different possible energy service requirements, when in conventional systems four (or at best three) pipes are required to provide the same services.
      • e) The network can be used for districts or cities, but also in industrial plants.
    DETAILED DESCRIPTION OF THE INVENTION
  • The invention will be better understood below with a detailed description illustrated by a FIGURE which schematically represents a district heating/cooling energy system according to the invention.
  • The network comprises two main pipes: one main pipe containing liquid CO2 (upper pipe in the FIGURE) and one main pipe containing gaseous CO2 (bottom pipe in the FIGURE). Both pipes are preferably at a similar pressure, advantageously however with a slightly higher pressure in the liquid pipe to avoid the need of a pump when liquid is evaporated for air-conditioning and the vapor directly fed back to the gaseous line. One preferred pressure level is a pressure corresponding to a saturation temperature of CO2 of 18° C. Lower temperatures, of 15° C. or 16° for instance, may be chosen.
  • At the district heating/cooling plant the pipes are connected to a heat-exchanger working either as evaporator in heating mode (winter) or as condenser in cooling mode (summer). A set of valves at the central plant couple the evaporator with an expansion valve and a compressor in the heating mode and the condenser with a pump in the cooling mode. When dealing with a district located near a lake, a river, or a waste water treatment facility, the available water can serve as heat source (heating mode) or heat sink (cooling mode). However, any other heat source such as solar energy, geothermal energy, seasonal heat storage, waste incineration . . . could also be used, directly in the heating mode, or over an absorption chiller in the cooling mode. To compensate pressure losses in the pipes and avoid parasitic boiling, intermediate small circulation pumps may be implemented along the network.
  • Unlike conventional district heating/cooling systems having dedicated supply and return pipes, with the system described here the direction of the flow in the pipes depends on the ratio of the heating (and/or hot water) and cooling (and/or freezing) requirements. If the total heating (and/or hot water) requirements in the district exceed the total cooling (and/or freezing) requirements, the gaseous pipe is the supply pipe and the liquid pipe the return pipe. In this case, the CO2 is evaporated at the central plant and pumped to the customers. On the other hand, if the total cooling (and/or freezing) requirements in the district exceed the total heating (and/or hot water) requirements, the liquid pipe becomes the supply pipe and the gaseous pipe the return pipe. In this case, the CO2 is condensed at the central plant before being pumped to the customers.
  • At the user's location, following processes can take place: heating, hot water preparation, air-conditioning and refrigeration. Besides, assuming that another heat source is available at some location along the network (heat from a chemical industry for instance), the CO2 network can operate as a heat sink for an ORC. In case geothermal collectors are available or possible (under green areas for example), gaseous CO2 can be generated in winter by means of a heat pump, and CO2 liquefaction could take place in summer, when the air-conditioning requirements are predominant. Finally, if unglazed solar roofs are installed, CO2 could be circulated through the solar panels in winter for instance, if the sun is shining, in order to generate additional gaseous CO2 to meet the heating and hot water requirements. In summer, at night, CO2 can be liquefied if the atmospheric temperature is below 18° C. In order to compare this CO2 system with the conventional district energy systems operating with water, the heating, hot water and cooling processes are explained below. The “liquid” and “gas” pipes in the FIGURE always refer to the pipes connecting the end user with the heating/cooling plant.
  • 1. Heating and Hot Water (Open CO2 Heat Pump)
  • In the heating mode, the gaseous CO2 is compressed according to the specific needs (temperature level) of the building. It then passes through the heat-exchanger where it releases its energy to the building heating network, before being circulated through an expansion turbine (if any mechanical energy can be recovered), an expansion valve and a separator. The liquid phase is sent to the liquid CO2 pipe. The gaseous phase is directly recirculated to the compressor. If the heating requirements decrease, thus diminishing the needs for CO2 in the gaseous phase, the gaseous CO2 can be circulated directly from the separator back to the gaseous CO2 pipe. This mode is specially advantageous for the hot water preparation.
  • 2. Heating and Hot Water with a Closed Loop Heat Pump
  • A conventional heat pump can be used as superposed cycle in particular when the heating temperature glide is small and disadvantageous for a supercritical CO2 cycle.
  • 3. Air Conditioning
  • In the air conditioning mode, liquid CO2 is circulated from the liquid pipe, via the heat-exchanger where it is evaporated with the heat coming from the building, to the gaseous pipe. Due to the slight over-pressure in the liquid pipe compared to the gaseous pipe, no pump is required in the cooling mode.
  • 4. Refrigeration
  • In the refrigeration mode, liquid CO2 is circulated over an expansion valve to the heat-exchanger where it serves as heat-sink to the refrigeration network of the building (for industrial refrigeration for instance). The expansion valve can be regulated so as to meet the exact refrigeration temperature required by the building. After the heat-exchanger, the CO2 is compressed and sent back to the gaseous line.
  • 5. Electricity Generation
  • If a heat-source with a high enough temperature is available somewhere along the CO2 network, the network can operate as a heat-sink for an ORC (conventional or supercritical) and thereby generate some electricity.
  • 6. Geothermy
  • In cities and districts with big green parks, geothermal probes can be dug into the soil. In winter, geothermal heat could be used to evaporate liquid CO2 using a heat-pump, and therefore help providing the required CO2 for heating and hot water purposes. On the other hand, in summer, gaseous CO2 can be liquified (mainly in the nighttime) in order to have enough liquid CO2 for the air-conditioning during the day. Geothermal energy can also be gained by means of geothermal structures implemented in the foundations of large multi-storey car parks.
  • 7. Unglazed Solar Collectors
  • Unglazed solar collectors mounted on the roof of buildings can help generate gaseous CO2. During the nighttime, especially in summer, if the atmospheric temperature is below 18° C., the existing heat-exchanger can be used to liquefy gaseous CO2 for the daytime air-conditioning.
  • 8. Fire Extinction
  • The CO2 contained in the network can be used for fire extinction purposes if needed.
  • 9. CO2 Collection
  • The network can be used to collect and transport CO2 from fuel cell or other decentralized cogeneration units.
  • 10. Combination
  • The operating modes described above can also be combined. For instance the heating and air-conditioning modes can be combined at the customer's place. When both heating and air-conditioning are required in the same building, this system directly transfers the energy from the evaporator (air-conditioning) to the heat-exchanger (heating and/or hot water) or vice-versa via the CO2. When one of the two energy requirements exceeds the other, the CO2 that cannot be reused internally at the customer's place is circulated via the heating/cooling plant.
  • In the heating mode, the gaseous CO2 is compressed according to the specific needs (temperature level) of the building, as described above (point 1). After having passed through the heat-exchanger, expansion turbine, expansion valve and separator, the liquid can be circulated directly to the evaporator together with any additional liquid CO2 from the pipe of the network, if cooling is required in the building. The vapor on the other hand either flows back to the compressor, or, if the heating (and/or hot water) requirements decrease, to the gaseous pipe. Likewise, the CO2 evaporated in the evaporator (cooling mode) can be circulated to the compressor for heating (and/or hot water) requirements, via a separator to insure the vapor quality, or back to the gaseous pipe.

Claims (10)

1. District energy system comprising a pipe system, end user's locations and an optional plant for transferring an energy transfer medium between said end user's locations and/or between said optional plant and said end user's locations, characterized by the fact that said energy transfer medium is CO2.
2. District energy system according to claim 1 comprising two main pipes extending between said end user's locations and/or between said optional plant and said end user's locations, the first main pipe containing CO2 in liquid state and the second main pipe containing CO2 in gaseous state.
3. District energy system according to claim 1 including at least one energy transformer, said transformer having one inlet communicating with one of said two main pipes and one outlet communication with the other one of said two main pipes.
4. District energy system according to claim 1 wherein at least one end user location comprise one or several outlets, e.g. valves, which are adapted for fire extinguishing.
5. District energy system according to claim 1 wherein at least one end user location comprise one or several inlets which are adapted for bringing external CO2 into said district energy system.
6. District energy system according to claim 1 wherein the pressure level in both main pipes is very similar, the pressure in the first main pipe being slightly higher than the pressure in the second main pipe.
7. District energy system according to claim 1 wherein the pressure level in both main pipes is the pressure corresponding to a CO2 saturation temperature in the range of 15° C. to 18° C.
8. District energy system according to claim 1 wherein one of said two main pipes is a supply pipe and the other of said two main pipes is a return pipe.
9. Use of a district energy system as defined in claim 8 characterized by the fact that, when the heating requirements are higher than the cooling requirements (e.g. in winter), said second main pipe is used as supply pipe and when the cooling requirements are higher than the heating requirements (e.g. in summer), said first main pipe is used as supply pipe.
10. Use of a district energy system according to claim 9 including at least one heat-exchanger for providing heating or hot water wherein gaseous CO2 follows a circuit in which it is successively compressed and passed through said heat-exchanger, an expansion valve and a separator, the resulting CO2 liquid phase being sent to said first main pipe and the remaining gaseous CO2 being redirected in said circuit.
US12/526,877 2007-02-19 2008-02-16 Co2 based district energy system Abandoned US20100018668A1 (en)

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PCT/IB2008/050573 WO2008102292A2 (en) 2007-02-19 2008-02-16 Co2 based district energy system
US12/526,877 US20100018668A1 (en) 2007-02-19 2008-02-16 Co2 based district energy system

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* Cited by examiner, † Cited by third party
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WO2013115286A1 (en) * 2012-01-31 2013-08-08 株式会社日立製作所 Device for controlling regional heat energy supply network
WO2013144473A1 (en) * 2012-03-28 2013-10-03 IFP Energies Nouvelles Method for pooling heat energy, and loop system for heat exchange between industrial and commercial sites
US20130298593A1 (en) * 2012-05-11 2013-11-14 Hill Phoenix, Inc. Co2 refrigeration system with integrated air conditioning module
KR101531159B1 (en) * 2014-07-04 2015-06-25 한국에너지기술연구원 CO2 based district energy system with low operating pressure
US20170030590A1 (en) * 2014-04-22 2017-02-02 Vito Broad band district heating and cooling system
JP2018533715A (en) * 2015-11-04 2018-11-15 エー.オン、スベリゲ、アクチボラグE.ON Sverige Aktiebolag Regional heat energy distribution system
JP2018536829A (en) * 2015-11-04 2018-12-13 エー.オン、スベリゲ、アクチボラグE.ON Sverige Aktiebolag Local thermal energy consumer assembly and local thermal energy generator assembly for a district thermal energy distribution system
US10859275B2 (en) * 2007-01-26 2020-12-08 Thermodynamic Process Control, Llc Modulation control of hydronic systems
CN112378125A (en) * 2020-11-16 2021-02-19 浙江省海洋科学院 Heat pump type seawater treatment system
US20230029186A1 (en) * 2019-10-25 2023-01-26 M.E.D. Energy Inc. Method for thermal energy transmission using water and carbon dioxide
US20230039702A1 (en) * 2020-01-10 2023-02-09 Exergo Sa Methods and Systems for District Energy CO2 Support
US11578882B2 (en) * 2016-07-07 2023-02-14 E. ON Sverige AB Combined heating and cooling system
US11698207B2 (en) 2018-07-31 2023-07-11 His Majesty The King In Right Of Canada, As Represented By The Minister Of Natural Resources Single-pipe thermal energy system
WO2024038368A1 (en) * 2022-08-15 2024-02-22 Exergo Sa Three-pipe thermal network

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FR2928444A1 (en) * 2007-09-20 2009-09-11 Jean Samuel Gotlibowicz Energy i.e. fossil energy, recycling permitting device for transferring energy to e.g. residential building, has cold or heat liquid source provided with pumps, and evaporators reheating loop, where producers and users are connected on loop
EP2182296A3 (en) * 2008-10-28 2014-02-19 Oilon Scancool Oy District heating arrangement and method
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KR101549657B1 (en) * 2013-11-08 2015-09-03 한국에너지기술연구원 System and method for controlling of heat exchange between district heating networks
GB2522025B (en) * 2014-01-09 2016-07-20 Greenfield Master Ipco Ltd Thermal Energy Network
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CH712646B1 (en) * 2016-07-04 2023-02-28 Geinoz Francois Ignace Network thermal energy distribution device to supply an urban and/or industrial site.
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EP3273169A1 (en) 2016-07-19 2018-01-24 E.ON Sverige AB Heat transfer system
CH712934B1 (en) * 2016-09-16 2023-02-28 Geinoz Francois Ignace Urban heat exchange network.
EP3296647A1 (en) * 2016-09-20 2018-03-21 E.ON Sverige AB Energy distributing system
EP3399246A1 (en) * 2017-05-02 2018-11-07 E.ON Sverige AB District energy distributing system and method of providing mechanical work and heating heat transfer fluid of a district thermal energy circuit
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Cited By (21)

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Publication number Priority date Publication date Assignee Title
US10859275B2 (en) * 2007-01-26 2020-12-08 Thermodynamic Process Control, Llc Modulation control of hydronic systems
JP2013155988A (en) * 2012-01-31 2013-08-15 Hitachi Ltd Control device of district heat energy supply network
WO2013115286A1 (en) * 2012-01-31 2013-08-08 株式会社日立製作所 Device for controlling regional heat energy supply network
WO2013144473A1 (en) * 2012-03-28 2013-10-03 IFP Energies Nouvelles Method for pooling heat energy, and loop system for heat exchange between industrial and commercial sites
FR2988814A1 (en) * 2012-03-28 2013-10-04 IFP Energies Nouvelles METHOD OF MUTUALIZING THERMAL ENERGY AND THERMAL EXCHANGE LOOP SYSTEM BETWEEN INDUSTRIAL AND TERTIARY SITES
US20130298593A1 (en) * 2012-05-11 2013-11-14 Hill Phoenix, Inc. Co2 refrigeration system with integrated air conditioning module
US9689590B2 (en) * 2012-05-11 2017-06-27 Hill Phoenix, Inc. CO2 refrigeration system with integrated air conditioning module
US20170030590A1 (en) * 2014-04-22 2017-02-02 Vito Broad band district heating and cooling system
US10883728B2 (en) * 2014-04-22 2021-01-05 Vito Broad band district heating and cooling system
KR101531159B1 (en) * 2014-07-04 2015-06-25 한국에너지기술연구원 CO2 based district energy system with low operating pressure
JP2018536829A (en) * 2015-11-04 2018-12-13 エー.オン、スベリゲ、アクチボラグE.ON Sverige Aktiebolag Local thermal energy consumer assembly and local thermal energy generator assembly for a district thermal energy distribution system
JP2018533715A (en) * 2015-11-04 2018-11-15 エー.オン、スベリゲ、アクチボラグE.ON Sverige Aktiebolag Regional heat energy distribution system
US11578882B2 (en) * 2016-07-07 2023-02-14 E. ON Sverige AB Combined heating and cooling system
CN116221802A (en) * 2016-07-07 2023-06-06 瑞典意昂公司 Combined heating and cooling system
US11698207B2 (en) 2018-07-31 2023-07-11 His Majesty The King In Right Of Canada, As Represented By The Minister Of Natural Resources Single-pipe thermal energy system
US20230029186A1 (en) * 2019-10-25 2023-01-26 M.E.D. Energy Inc. Method for thermal energy transmission using water and carbon dioxide
US11719469B2 (en) * 2019-10-25 2023-08-08 M.E.D. Energy Inc. Method for thermal energy transmission using water and carbon dioxide
US20230039702A1 (en) * 2020-01-10 2023-02-09 Exergo Sa Methods and Systems for District Energy CO2 Support
US11965659B2 (en) * 2020-01-10 2024-04-23 Exergo Sa Methods and systems for district energy CO2 support
CN112378125A (en) * 2020-11-16 2021-02-19 浙江省海洋科学院 Heat pump type seawater treatment system
WO2024038368A1 (en) * 2022-08-15 2024-02-22 Exergo Sa Three-pipe thermal network

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EP2122257B1 (en) 2017-04-26
WO2008102292A2 (en) 2008-08-28
EP2122257A2 (en) 2009-11-25
WO2008102292A3 (en) 2008-11-27

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