US20090317717A1 - Electrode Assembly Having Tab-Lead Joint Portion of Minimized Resistance Difference Between Electrodes and Electrochemical Cell Containing The Same - Google Patents

Electrode Assembly Having Tab-Lead Joint Portion of Minimized Resistance Difference Between Electrodes and Electrochemical Cell Containing The Same Download PDF

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US20090317717A1
US20090317717A1 US12/309,549 US30954907A US2009317717A1 US 20090317717 A1 US20090317717 A1 US 20090317717A1 US 30954907 A US30954907 A US 30954907A US 2009317717 A1 US2009317717 A1 US 2009317717A1
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electrode
tabs
lead
electrode assembly
cathode
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Ji Heon Ryu
Jeong Hee Choi
Kwangho Yoo
Youngjoon Shin
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LG Chem Ltd
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LG Chem Ltd
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Assigned to LG CHEM, LTD. reassignment LG CHEM, LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CHOI, JEONG HEE, RYU, JI HEON, SHIN, YOUNGJOON, YOO, KWANGHO
Publication of US20090317717A1 publication Critical patent/US20090317717A1/en
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/04—Hybrid capacitors
    • H01G11/06—Hybrid capacitors with one of the electrodes allowing ions to be reversibly doped thereinto, e.g. lithium ion capacitors [LIC]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/531—Electrode connections inside a battery casing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/22—Electrodes
    • H01G11/26—Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES OR LIGHT-SENSITIVE DEVICES, OF THE ELECTROLYTIC TYPE
    • H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
    • H01G11/66—Current collectors
    • H01G11/72—Current collectors specially adapted for integration in multiple or stacked hybrid or EDL capacitors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/04—Construction or manufacture in general
    • H01M10/0413—Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/04—Construction or manufacture in general
    • H01M10/0459—Cells or batteries with folded separator between plate-like electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H01M10/0583—Construction or manufacture of accumulators with folded construction elements except wound ones, i.e. folded positive or negative electrodes or separators, e.g. with "Z"-shaped electrodes or separators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/116—Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
    • H01M50/117—Inorganic material
    • H01M50/119—Metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/116—Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
    • H01M50/121—Organic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/116—Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
    • H01M50/124—Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/531—Electrode connections inside a battery casing
    • H01M50/533—Electrode connections inside a battery casing characterised by the shape of the leads or tabs
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/531—Electrode connections inside a battery casing
    • H01M50/534—Electrode connections inside a battery casing characterised by the material of the leads or tabs
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/531—Electrode connections inside a battery casing
    • H01M50/536—Electrode connections inside a battery casing characterised by the method of fixing the leads to the electrodes, e.g. by welding
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50—Current conducting connections for cells or batteries
    • H01M50/531—Electrode connections inside a battery casing
    • H01M50/54—Connection of several leads or tabs of plate-like electrode stacks, e.g. electrode pole straps or bridges
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/10—Batteries in stationary systems, e.g. emergency power source in plant
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2220/00—Batteries for particular applications
    • H01M2220/30—Batteries in portable systems, e.g. mobile phone, laptop
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Connection Of Batteries Or Terminals (AREA)
  • Secondary Cells (AREA)
  • Electric Double-Layer Capacitors Or The Like (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Battery Mounting, Suspending (AREA)

Abstract

Disclosed herein is a stacking or stacking/folding type electrode assembly of a cathode/separator/anode structure, wherein the electrode assembly is constructed in a structure in which tabs (electrode tabs), having no active material applied thereto, protrude from electrode plates constituting the electrode assembly, the electrode tabs are electrically connected to an electrode lead, and the pluralities of electrode tabs are joined to the top and the bottom of the electrode lead at an electrode lead-electrode tabs joint portion such that the resistance difference between electrodes at the electrode lead-electrode tabs joint portion is minimized. Also disclosed is an electrochemical cell including the electrode assembly.

Description

    FIELD OF THE INVENTION
  • The present invention relates to an electrode assembly having a tab-lead joint portion of minimized resistance difference between electrodes, and, more particularly, to a stacking or stacking/folding type electrode assembly of a cathode/separator/anode structure, wherein the electrode assembly is constructed in a structure in which tabs (electrode tabs), having no active material applied thereto, protrude from electrode plates constituting the electrode assembly, the electrode tabs are electrically connected to an electrode lead, and the pluralities of electrode tabs are joined to the top and the bottom of the electrode lead at an electrode lead-electrode tabs joint portion such that the resistance difference between electrodes at the electrode lead-electrode tabs joint portion is minimized.
    • BACKGROUND OF THE INVENTION
  • As mobile devices have been increasingly developed, and the demand for such mobile devices has increased, the demand for batteries has also sharply increased as an energy source for the mobile devices. Also, much research on batteries satisfying various needs has been carried out.
  • In terms of the shape of batteries, the demand for prismatic secondary batteries or pouch-shaped secondary batteries, which are thin enough to be applied to products, such as mobile phones, is very high. In terms of the material for batteries, on the other hand, the demand for lithium secondary batteries, such as lithium ion batteries and lithium ion polymer batteries, having high energy density, high discharge voltage, and high output stability, is very high.
  • Furthermore, secondary batteries may be classified based on the construction of an electrode assembly having a cathode/separator/anode structure. For example, the electrode assembly may be constructed in a jelly-roll (winding) type structure in which long-sheet type cathodes and long-sheet type anodes are wound while separators are disposed respectively between the cathodes and the anodes, a stacking type structure in which pluralities of cathodes and anodes having a predetermined size are successively stacked while separators are disposed respectively between the cathodes and the anodes, or a stacking/folding type structure in which pluralities of cathodes and anodes having a predetermined size are successively stacked while separators are disposed respectively between the cathodes and the anodes to constitute a bi-cell or a full-cell, and then the bi-cell or the field-cell is wound.
  • FIG. 1 is a side view typically illustrating the general structure of a conventional representative stacking type electrode assembly.
  • Referring to FIG. 1, the stacking type electrode assembly 10 is constructed in a structure in which cathodes 20, each of which has a cathode active material 22 applied to the opposite major surfaces of a cathode current collector 21, and anodes 30, each of which has an anode active material 32 applied to the opposite major surfaces of an anode current collector 31, are sequentially stacked while separators 70 are disposed respectively between the cathodes 20 and the anodes 30.
  • From one-side ends of the cathode current collectors 21 and the anode current collectors 31 protrude pluralities of cathode tabs 41 and anode tabs 51, to which an active material is not applied, such that the cathode tabs 41 and the anode tabs 51 are electrically connected to a cathode lead 60 and an anode lead (not shown) constituting electrode terminals of a battery. The cathode tabs 41 and the anode tabs 51 are joined in a concentrated state, and are then connected to the cathode lead 60 and the anode lead, respectively. This structure is more clearly illustrated in FIGS. 2 and 3, which are partially enlarged views typically illustrating the joint portion between the cathode tabs and the cathode lead. FIGS. 2 and 3 illustrate only the joint portion between the cathode tabs and the cathode lead for convenience of description, although this structure is also applied to the joint portion between the anode tabs and the anode lead.
  • Referring to these drawings, the cathode tabs 40 are brought into tight contact with each other in the direction indicated by an arrow, and are connected to the cathode lead 60. The cathode lead 60 is normally joined to the cathode tabs by welding. The cathode lead 60 may be joined to the cathode tabs while the cathode lead 60 is located at the top of the uppermost cathode tab 41, as shown in FIG. 2. Alternatively, the cathode lead 60 may be joined to the cathode tabs while the cathode lead 60 is located at the bottom of the lowermost cathode tab 42, as shown in FIG. 3.
  • Due to this joint structure, however, the resistance difference between the electrodes with respect to each electrode lead may occur in the electrode assembly. Specifically, the electrode resistance of the electrode tab at the shortest distance from the electrode lead is different from that of the electrode tab at the longest distance from the electrode lead. In a middle- or large-sized battery pack including the electrode assembly with the above-stated construction, large-capacity electricity is charged and discharged. Consequently, the electrodes may be nonuniformly operated or deteriorated, due to the resistance difference between the electrodes, which may reduce the life span of the battery.
  • Also, when the electrode tabs are joined to the electrode lead in the above-described structure, a welding process for the joining the electrode tabs and the electrode lead is performed only in one direction, with the result that the joint force between the electrode tabs and the electrode lead may be lowered.
  • Consequently, there is a high necessity for an electrode assembly having an improved structure in which the joint force between the electrode tabs and the electrode lead is increased while the resistance difference between the electrodes is minimized.
    • SUMMARY OF THE INVENTION
  • Therefore, the present invention has been made to solve the above problems, and other technical problems that have yet to be resolved.
  • Specifically, it is an object of the present invention to provide an electrode assembly having a structure in which the resistance difference between electrodes is minimized.
  • It is another object of the present invention to provide an electrode assembly having a structure in which the joint force between electrode tabs and each electrode lead is increased, whereby high reliability is secured.
  • It is a further object of the present invention to provide an electrochemical cell including the electrode assembly.
    • BRIEF DESCRIPTION OF THE DRAWINGS
  • The above and other objects, features and other advantages of the present invention will be more clearly understood from the following detailed description taken in conjunction with the accompanying drawings, in which:
  • FIG. 1 is a typical view illustrating the general structure of a conventional stacking type electrode assembly;
  • FIGS. 2 and 3 are partially enlarged views illustrating the connection between cathode tabs, joined to each other in a concentrated state, and a cathode lead of the electrode assembly shown in FIG. 1; and
  • FIG. 4 is a partially enlarged view illustrating the connection between cathode tabs, joined to each other in a concentrated state, and a cathode lead of an electrode assembly according to a preferred embodiment of the present invention.
    •  DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS
  • In accordance with one aspect of the present invention, the above and other objects can be accomplished by the provision of a stacking or stacking/folding type electrode assembly of a cathode/separator/anode structure, wherein the electrode assembly is constructed in a structure in which tabs (electrode tabs), having no active material applied thereto, protrude from electrode plates constituting the electrode assembly, the electrode tabs are electrically connected to an electrode lead, and pluralities of electrode tabs are joined to the top and the bottom of the electrode lead at an electrode lead-electrode tabs joint portion such that the resistance difference between electrodes at the electrode lead-electrode tabs joint portion is minimized.
  • In a preferred embodiment, the number of the electrode tabs joined to the top of the electrode lead is approximately equal to that of the electrode tabs joined to the bottom of the electrode lead such that the electrode tabs are joined to the electrode lead approximately in a symmetrical fashion. Specifically, when a total of A electrode tabs are joined to the top of the electrode lead, the same number of electrode tabs, i.e., a total of A electrode tabs, or the similar number of electrode tabs, i.e., a total of A′ electrode tabs, may be joined to the bottom of the electrode lead.
  • This structure will be described in more detail with reference to FIG. 4. Referring to FIG. 4, electrode tabs 200 are joined to the electrode lead 100 while three electrode tabs 210 are located at the top 110 of the electrode lead 100, and three electrode tabs 220 are located at the bottom 120 of the electrode lead 100. Consequently, the electrode tabs 200 are disposed at the electrode lead 100, at a joint region A, in a symmetrical structure in which the electrode tabs 200 are disposed symmetrically at the top 110 and the bottom 120 of the electrode lead 100.
  • The electrode tabs 200 are brought into tight contact with each other in the direction indicated by an arrow, while the electrode lead 100 is disposed between the electrode tabs 200, and then the electrode lead 100 is joined to the electrode tabs 200 by welding. According to circumstances, the electrode lead 100 may be inserted between the electrode tabs 200, while the electrode tabs are in tight contact with each other, and then the electrode lead 100 may be joined to the electrode tabs 200 by welding.
  • According to the present invention, the electrode lead is not particularly restricted so long as the electrode lead is made of a material that can be electrically connected to the electrode tabs. Preferably, the electrode lead is made of a metal plate. The metal plate may be selected from a group consisting of an aluminum plate, a copper plate, a nickel plate, a copper plate coated with nickel, and a SUS plate.
  • Also, the electrode lead is not particularly restricted so long as the electrode lead is constructed in a structure in which the electrode lead is easily connected to the electrode tabs. For example, the electrode lead may be formed in the shape of a straight line in vertical section. The electrode lead may be connected to the electrode tabs in various manners. Preferably, the electrode lead is more stably connected to the electrode tabs by welding. The welding may include ultrasonic welding, laser welding, and resistance welding.
  • In accordance with another aspect of the present invention, there is provided an electrochemical cell including the electrode assembly with the above-stated construction.
  • The electrochemical cell is one that provides electricity through an electrochemical reaction. For example, the electrochemical cell may be an electrochemical secondary battery or an electrochemical capacitor. Especially, the electrochemical cell is preferably applied to a lithium secondary battery.
  • The secondary battery includes an electrode assembly that can be charged and discharged. Preferably, the secondary battery is constructed in a structure in which an electrode assembly is mounted in a battery case made of a laminate sheet including a metal layer and a resin layer in a sealed state. The secondary battery with the above-described structure may be referred to as a pouch-shaped secondary battery.
  • Also, the secondary battery is preferably used as a unit cell for high-output, large-capacity battery packs.
  • Hereinafter, examples of the present invention will be described in more detail. It should be noted, however, that the scope of the present invention is not limited by the illustrated examples.
    • EXAMPLE 1
  • A cathode active material containing lithium and an anode active material containing graphite were applied to opposite major surfaces of an aluminum foil and a copper foil, respectively, and then the aluminum foil and the copper foil were cut to manufacture cathode plates and anode plates, having electrode tabs to which the active materials were not applied. Subsequently, the cathode plates and the anode plates were sequentially stacked while separators were disposed respectively between the cathode plates and the anode plates. After that, a cathode lead was welded to the cathode tabs, while the cathode lead was disposed between the cathode tabs, and an anode lead was welded to the anode tabs, while the anode lead was disposed between the anode tabs, as shown in FIG. 4, to manufacture an electrode assembly.
    • COMPARATIVE EXAMPLE 1
  • An electrode assembly was manufactured in the same method as Example 1 except that the cathode lead was welded to the cathode tabs, while the cathode lead was located at the bottom of the lowermost cathode tab, and the anode lead was welded to the anode tabs, while the anode lead was located at the bottom of the lowermost anode tab, as shown in FIG. 3.
    • EXPERIMENTAL EXAMPLE 1
  • Resistance measurement experiments were carried out on 20 electrode assemblies manufactured respectively according to Example 1 and Comparative example 1. The experiment results are indicated in Table 1 below. The experiments were repeatedly carried out on the respective 20 electrode assemblies. The resistance at the joint portion between the cathode tabs and the cathode lead was measured using an Agilent milli-ohmmeter. The measured experiment values are indicated in Table 1 below as an average resistance value.
  • Group A of Table 1 below indicates the cathode tabs located at the upper part of the electrode assembly. For Example 1, Group A indicates the cathode tabs located at the top of the cathode lead. For Comparative example 1, Group A indicates the cathode tabs at long distances from the cathode lead. Group B of Table 1 below indicates the cathode tabs located at the lower part of the electrode assembly. For Example 1, Group B indicates the cathode tabs located at the bottom of the cathode lead. For Comparative example 1, Group B indicates the cathode tabs at short distances from the cathode lead.
  • TABLE 1
    Average Average Average
    resistance of A- resistance of B- resistance
    group cathode group cathode difference between
    tabs (mΩ) tabs (mΩ) electrodes
    Example 1 5.32 5.31 0.01
    Comparative 5.37 5.32 0.05
    example 1
  • As can be seen from Table 1 above, the resistance of the cathode tabs located at the top of the cathode lead was approximately equal to that of the cathode tabs located at the bottom of the cathode lead in the electrode assembly manufactured according to Example 1. Specifically, the resistance difference did not occur at all the cathodes. In the electrode assembly manufactured according to Comparative example 1, on the other hand, the resistance difference occurred between the cathode tabs at short distances from the cathode lead and the cathode tabs at long distances from the cathode lead. Even though the resistance difference is slight, the resistance difference causes the operational nonuniformity between the electrodes during the repetitive charge and discharge of the electrode assembly or in a high-output, large-capacity battery pack having a large amount of electric current. Especially, the resistance difference causes rapid deterioration of specific electrodes, during the long-term use of the electrode assembly, with the result that the life span of a battery is reduced.
    • INDUSTRIAL APPLICABILITY
  • As apparent from the above description, the electrode assembly according to the present invention has the following effects. The electrode assembly is constructed in a structure in which the resistance difference between electrodes is minimized. Furthermore, the electrode assembly is constructed in a structure in which the joint force between electrode tabs and each electrode lead is increased, whereby high reliability is secured.
  • Although the preferred embodiment of the present invention has been disclosed for illustrative purposes, those skilled in the art will appreciate that various modifications, additions and substitutions are possible, without departing from the scope and spirit of the invention as disclosed in the accompanying claims.

Claims (9)

1. A stacking or stacking/folding type electrode assembly of a cathode/separator/anode structure, wherein the electrode assembly is constructed in a structure in which tabs (electrode tabs), having no active material applied thereto, protrude from electrode plates constituting the electrode assembly, the electrode tabs are electrically connected to an electrode lead, and the pluralities of electrode tabs are joined to the top and the bottom of the electrode lead at an electrode lead-electrode tabs joint portion such that the resistance difference between electrodes at the electrode lead-electrode tabs joint portion is minimized.
2. The electrode assembly according to claim 1, wherein the number of the electrode tabs joined to the top of the electrode lead is approximately equal to that of the electrode tabs joined to the bottom of the electrode lead.
3. The electrode assembly according to claim 1, wherein the electrode lead is made of a metal plate.
4. The electrode assembly according to claim 3, wherein the metal plate is selected from a group consisting of an aluminum plate, a copper plate, a nickel plate, a copper plate coated with nickel, and a SUS plate.
5. The electrode assembly according to claim 1, wherein the electrode lead is formed in the shape of a straight line in vertical section, and the electrode lead is joined to the electrode tabs by welding.
6. An electrochemical cell including an electrode assembly according to claim 1.
7. The electrochemical cell according to claim 6, wherein the electrochemical cell is a secondary battery or a capacitor.
8. The electrochemical cell according to claim 7, wherein the secondary battery is constructed in a structure in which an electrode assembly is mounted in a battery case made of a laminate sheet including a metal layer and a resin layer in a sealed state.
9. The electrochemical cell according to claim 8, wherein the secondary battery is a unit cell for high-output, large-capacity battery packs.
US12/309,549 2006-07-24 2007-07-21 Electrode Assembly Having Tab-Lead Joint Portion of Minimized Resistance Difference Between Electrodes and Electrochemical Cell Containing The Same Abandoned US20090317717A1 (en)

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Application Number Priority Date Filing Date Title
KR1020060068825A KR100888284B1 (en) 2006-07-24 2006-07-24 Electrode Assembly Having Tap-Lead Joint Portion of Minimized Resistance Difference between Electrodes and Electrochemical Cell Containing the Same
KR10-2006-0068825 2006-07-24
PCT/KR2007/003530 WO2008013381A1 (en) 2006-07-24 2007-07-21 Electrode assembly having tab-lead joint portion of minimized resistance difference between electrodes and electrochemical cell containing the same

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CN101496217A (en) 2009-07-29
CN102593407B (en) 2016-03-30

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