US20090302276A1 - Anticorrosive composition - Google Patents
Anticorrosive composition Download PDFInfo
- Publication number
- US20090302276A1 US20090302276A1 US12/480,986 US48098609A US2009302276A1 US 20090302276 A1 US20090302276 A1 US 20090302276A1 US 48098609 A US48098609 A US 48098609A US 2009302276 A1 US2009302276 A1 US 2009302276A1
- Authority
- US
- United States
- Prior art keywords
- molecular weight
- fraction
- molasses
- corrosion
- anticorrosive composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/086—Organic or non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/34—Anti-oxidant compositions; Compositions inhibiting chemical change containing plant or animal materials of unknown composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
- C09K3/185—Thawing materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/54—Compositions for in situ inhibition of corrosion in boreholes or wells
Definitions
- This invention relates in general to corrosion caused by exposure to a corrosive environment and, more specifically, to the use of an anticorrosive agent that has a wide range of applicability in reducing corrosion.
- Corrosion problems caused by exposure to and/or the use of chloride salt has been a longstanding problem in many applications and industries, including deicing and anti-icing for roadways and bridges (often causing rebar corrosion), oil well drilling operations, and other industrial and marine applications carried out in corrosive environments.
- chloride salts are their use in industrial brines.
- a brine can be an aqueous solution of chloride salts alone, or in combination with sodium, potassium, calcium and magnesium cations.
- the present invention relates to the discovery that melanoidins, and higher molecular weight fractions of products containing melanoidins, provide significant corrosive inhibition, which render these melanoidins suitable for use as anticorrosive agents in corrosive environments.
- the melanoidins of the present invention are environmentally friendly and non-toxic, and can be found in animal food and in human foodstuffs.
- these additives can be used (e.g., additives to industrial brines, deicing formulations for roadways and bridges, oil well drilling, and in other industrial and marine applications where corrosion is a problem).
- FIG. 1 illustrates a GPC profile for sucrose.
- FIG. 2 illustrates a GPC profile for a component having a molecular weight of 12,400.
- FIG. 3 illustrates a GPC profile for 79.5 Brix Molasses.
- FIG. 4 illustrates a GPC profile for Fraction A obtained from the alcohol precipitation of the molasses.
- FIG. 5 illustrates a GPC profile for the higher molecular weight fraction (retentate) obtained from the dialysis of Fraction A.
- FIG. 6 illustrates a GPC profile for the lower molecular weight fraction (permeate) obtained from the dialysis of Fraction A.
- FIG. 7 illustrates a GPC profile for the higher molecular weight fraction (retentate) obtained from the ultrafiltration of the molasses.
- the present invention relates to the discovery that melanoidins, and higher molecular weight fractions of products containing melanoidins, provide significant corrosive inhibition, which render these melanoidins suitable for use as anticorrosive agents in corrosive environments.
- Melanoidins are brown-colored polymers formed by the interaction of amino acids and carbohydrates (e.g., mono-, di-, and oligosaccharides). Melanoidins are formed by a reaction between carbohydrates/saccharides and amino acids during aqueous processing at elevated temperatures (e.g., 70 to 120° C.). This is known as the Maillard Reaction which is a complex reaction with a network of consecutive and parallel chemical reactions.
- the molecular weights of melanoidins can vary from about 400 to more than 100,000 depending upon reaction conditions (e.g., temperature, time, pH, water content), the molecular weight of the melanoidins suitable for use in the present invention is above about 10,000, with a preferred range being about 12,400 and higher (i.e., higher molecular weight melanoidins).
- Melanoidins contain groups (e.g., amino, carboxyl) which can chelate ferrous ions.
- ferrous ions are produced at the steel anode. Inhibition of the corrosion process at the anode occurs when chelation/complexation of the ferrous ions occur.
- the type of saccharide is a significant factor in the chelation reaction. For example, glucose is more efficient than the disaccharide lactose in iron binding ability. It has also been shown that glucose/glutamic acid readily complexes with several cations e.g. Mg 2+ , Cu 2+ , Ca 2+ and Zn 2+ . Therefore anodic inhibition will occur.
- the cathode in the corrosion cell requires the presence of oxygen for corrosion to occur. Removing oxygen causes cathodic inhibition.
- Melanoidins from the Maillard Reaction have been shown to have anti-oxidative properties.
- researchers have examined a glucose/glycine model and found anti-oxidation effects.
- Others have used the glucose/glycine model and found that the high molecular weight fraction, with a molecular weight greater than 12,400 was significantly more effective than other fractions.
- Still others have examined Maillard Reaction products from lactose/lysine model systems and concluded that high molecular weight fractions were more colored and had the highest anti-oxidative activity. Therefore cathodic inhibition will occur.
- Molasses derived from sugar cane was selected as the exemplary source for obtaining the higher molecular weight melanoidins of the description of the present invention.
- Melanoidins are present in molasses, which is a product of the manufacture and/or refining of sucrose from mainly sugar cane or sugar beets, although molasses can be obtained from the processing of citrus fruit, starch (from corn or grain sorghum) which is hydrolyzed by enzymes and/or acid, also from hemicellulose extract which is a product of the manufacture of pressed wood.
- melanoidins which may be derived from various agricultural sources (e.g., corn, wheat, barley, rice, sugar beets. and sugar cane, which after processing, yield other products), corn steep liquor (CSL), brewers condensed solubles (BCS), and distillers condensed solubles (DCS).
- CSL corn steep liquor
- BCS condensed solubles
- DCS distillers condensed solubles
- GPC molecular weight
- a mix e.g., 80/20
- molasses e.g., 79.5 Brix Molasses
- chromatographic separation e.g., column chromatography, gel permeation chromatography
- chromatogram profiles were obtained on various diluted samples using gel permeation chromatography (GPC) under the following chromatography conditions: Column (Bio-S-3000), Mobile Phase (Sodium Azide 0.05%), Detector (Refractive Index), Flow Rate (1.0 mL/min), Injection Volume (10.0 ⁇ L), and Run Time (20 minutes).
- GPC gel permeation chromatography
- FIGS. 1 through 7 show GPC profiles for various samples. Each profile shows peaks for the molecular weights of components present in the sample. Peaks do not necessarily represent a single compound, but, particularly at higher molecular weight ranges, may be comprised of multiple components or polymers having heterogeneous composition. Each profile also provides the elapsed time before a particular molecular weight component was released from the column (retention time (RT)). As general rule, the higher the molecular weight of the component, the shorter the retention time. Likewise, the lower the molecular weight of the component, the longer the retention time. Each profile also provides the height and area of the peak representing a particular molecular weight component, which allows for the determination of the weight percent of that particular molecular weight in the sample.
- RT retention time
- FIG. 2 illustrates a GPC profile for a component having a molecular weight of 12,400 having a retention time under those same test conditions of 12.993 minutes. Accordingly, based on those standards and under those same test conditions, for components with molecular weights less than 342, one would expect retention times longer than 15.371 minutes. Similarly, for components with molecular weights greater than 12,400, one would expect retention times shorter than 12.993 minutes.
- Fraction A was a precipitate with the least amount of the alcohol mixture and contained the highest molecular weight components, while fraction E had the greatest amount of the alcohol mixture and was the lowest molecular weight fraction of the molasses. These precipitates could be filtered and dried.
- a 100 ml sample of each fraction (A-E) was then mixed with 400 ml of 30% NaCl to yield an 80/20 mix for corrosion rate testing according to the NACE Standard TM-01-69 Method as modified by the Pacific Northwest Snowfighters (PNS).
- NPS Pacific Northwest Snowfighters
- trans-aconitic acid which comes from sugar cane, is present in the molasses (1.63%), and more specifically, Fraction A (0.88%) and fraction B (0.23%), but is absent from fraction E.
- Aconitic acid is a compound found in sugar processing and is the main organic acid in sugar juice and in raw sugar. Aconitic acid is bound or associated with polysaccharides with a molecular weight of 300,000.
- Corrosion rate testing on the molasses and selected carbohydrates present in the molasses demonstrated that the corrosion inhibition of the molasses is greater than that of its constituent carbohydrates alone. Furthermore, corrosion rate testing demonstrated that higher molecular weight (HMW) Fraction A, which contains 25% of the total solids in the molasses, exhibits similar corrosion inhibition to lower molecular weight (LMW) fraction E, which contains 60% of the total solids in the molasses.
- HMW molecular weight
- LMW lower molecular weight
- the 79.5 Brix molasses was subjected to dialysis at room temperature using a regenerated thin semi-permeable cellulose (RC) Spectrum Laboratories membrane with a defined molecular weight cut-off of 12,400.
- the membrane allows the components having molecular weights below the cut-off to pass through or permeate the membrane (“permeate”), leaving behind the components having molecular weights above the cut-off (and lower molecular weight components closely associated with them) that are stopped or retained by the membrane (“retentate”).
- the brown higher molecular weight fraction (retentate) contained the higher molecular weight components with molecular weights greater than the cellulose membrane cut-off (12,400) as well as lower molecular weight components that are closely associated with the higher molecular weight components stopped or retained by the membrane.
- the brown color and molecular weight data indicates the presence of melanoidins in the higher molecular weight fraction (retentate).
- the yellow lower molecular weight fraction (permeate) contained the lower molecular weight components with molecular weights less than the membrane cut-off (12,400) that passed through or permeated the membrane.
- the yellow color and molecular weight data tends to indicate the absence or limited presence of melanoidins in the lower molecular weight fraction (permeate).
- both the resulting higher molecular weight fraction (retentate) and the lower molecular weight fraction (permeate) contained the relative amounts of components that would be present in a solution of 0.6% molasses (3 g molasses/500 mL distilled water).
- the percent reduction in corrosion for a particular solution is calculated by taking the difference between steel metal loss for that solution and the steel metal loss for the chloride salt solution and dividing that difference by the steel metal loss for the chloride salt solution, and multiplying that ratio by 100.
- the higher molecular weight fraction (retentate) is a far more potent corrosion inhibitor than the molasses or the lower molecular weight fraction (permeate), despite the fact that the solids content of the retentate (63.0 mg/100 mL) is significantly less than the solids content of the molasses (424.2mg/100 mL) and the permeate (not recorded but approximately 360 mg/100 mL).
- the higher molecular weight fraction (retentate) has almost seven times less solids content than the molasses (i.e., only represents approximately 15% of the dry weight molasses or 10% of the liquid molasses), it provides a much greater reduction in corrosion.
- the melanoidins present in the higher molecular weight fraction (retentate) inhibit corrosion by both anodic and cathodic inhibition.
- Fraction A of the 79.5 Brix Molasses was obtained using the alcohol precipitation method described above.
- Fraction A was then subjected to the same dialysis process described above for the molasses using a cellulose membrane with a defined molecular weight cut-off of 12,400.
- the lower molecular weight fraction (permeate) of Fraction A had a bright yellow color and contained the lower molecular weight components with molecular weights less than the membrane cut-off (12,400) that passed through or permeated the membrane.
- the yellow color and molecular weight data tends to indicate the absence or limited presence of melanoidins in the lower molecular weight fraction (permeate) of Fraction A.
- Molasses Fraction A was subjected to hydrolysis using 2M trifluoroacetic acid heated at 120° C. for 2 hours. No increase in carbohydrate peaks was observed. The acid caused a precipitate to form related to the HMW material. The addition of sodium hydroxide to neutralize the acid caused the HMW material to dissolve and again be detected by GPC.
- Ultrafiltration was used to identify the higher molecular weight components in the 79.5 Brix Molasses that are largely responsible for corrosion inhibition.
- Ultrafiltration is a pressure-driven process where a fluid stream is pumped at low pressure and high flow rate across the surface of thin semi-permeable polymeric membranes with a defined molecular weight cutoff.
- ultrafiltration uses a membrane having a defined molecular weight cut-off that allows components having molecular weights below the cut-off to pass through or permeate the membrane (“permeate”), leaving behind the components having molecular weights above the cut-off (and lower molecular weight components closely associated with them) that are stopped or retained by the membrane (“retentate”).
- the ultrafiltration equipment used for the experiment was Quix Stand UltraFiltration System (Amersham Biosciences, GE Healthcare) with a Hollow Fiber Cartridge UFP-10-E-3 MA with a nominal molecular weight cut-off of 10,000 and surface area of 110 cm 2 .
- FIG. 7 illustrates a GPC profile for the higher molecular weight fraction (retentate) obtained from the ultrafiltration of the molasses.
- the GPC profile for the higher molecular weight fraction (retentate) shows a total of ten peaks.
- the GPC profile shows that higher molecular weight components with molecular weights greater than 12,400 make up approximately 6% by weight of the higher molecular weight fraction (retentate), while higher molecular weight components with molecular weights greater than or equal to 10,000 make up approximately 10% of the retentate.
- additional corrosion rate testing was performed using the retentate from the ultrafiltration process to confirm these earlier results.
- the higher molecular weight fraction (retentate) is approximately 17 times more efficient as a corrosion inhibitor than molasses (i.e., 14% improvement on top of a weight difference of 15 times).
- the previously described experiments have shown that it is the higher molecular weight components in the retentate of the molasses (i.e., those components with molecular weights greater than 10,000 or 12,400) that provide the greatest and most unexpected corrosion inhibition. Those components only constitute 6% to 10% of the weight of the retentate.
- those higher molecular weight components are approximately 170 to 280 times more efficient as a corrosion inhibitor than molasses on a weight basis.
- the melanoidins present in the higher molecular weight fraction (retentate) inhibit corrosion by both anodic and cathodic inhibition.
- additives including melanoidins can be used (e.g., additives to industrial brines, deicing formulations for roadways and bridges, oil well drilling, and in other industrial and marine applications where corrosion is a problem).
- Any suitable concentration of the higher molecular weight fraction of the melanoidin-containing product that effectively reduces corrosion in a chloride salt, brine, or a deicing formulation may be used.
- a typical concentration can vary from about 0.03 to 10.0% by weight.
- one embodiment of a deicing formulation using the melanoidins of the present invention is as an additive to a known deicing and anti-icing formulation:
- the basic composition of the known deicing formulation consists of at least the first two of the following three components in aqueous solution depending upon ambient weather conditions, terrain, nature and amount of freezing/snow precipitation, and environmental concerns:
- Inorganic freezing point depressants preferably in the form of chloride salts which include magnesium chloride, calcium chloride and sodium chloride.
- Metal acetates e.g. calcium magnesium acetate, may also be used.
- Thickeners are used in certain applications as the third key component to increase the viscosity of the composition so that the liquid remains in contact with the road surface or with the solid particles in piles of rocksalt/sand, or rocksalt/aggregates, or salt alone, or sand or aggregate.
- Thickeners are mainly cellulose derivatives or high molecular weight carbohydrates. Typical molecular weights for cellulose derivatives are for methyl and hydroxy propyl methyl celluloses from about 60,000 to 120,000 and for hydroxy ethyl celluloses from about 750,000 to 1,000,000. Carbohydrate molecular weights range from about 10,000 to 50,000.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Combustion & Propulsion (AREA)
- Botany (AREA)
- Wood Science & Technology (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/480,986 US20090302276A1 (en) | 2008-06-09 | 2009-06-09 | Anticorrosive composition |
US13/487,915 US8647532B2 (en) | 2008-06-09 | 2012-06-04 | Anticorrosive composition |
US14/176,710 US8951442B2 (en) | 2008-06-09 | 2014-02-10 | Anticorrosive composition |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US5998108P | 2008-06-09 | 2008-06-09 | |
US12/480,986 US20090302276A1 (en) | 2008-06-09 | 2009-06-09 | Anticorrosive composition |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/487,915 Continuation US8647532B2 (en) | 2008-06-09 | 2012-06-04 | Anticorrosive composition |
Publications (1)
Publication Number | Publication Date |
---|---|
US20090302276A1 true US20090302276A1 (en) | 2009-12-10 |
Family
ID=41399467
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/480,986 Abandoned US20090302276A1 (en) | 2008-06-09 | 2009-06-09 | Anticorrosive composition |
US13/487,915 Active US8647532B2 (en) | 2008-06-09 | 2012-06-04 | Anticorrosive composition |
US14/176,710 Expired - Fee Related US8951442B2 (en) | 2008-06-09 | 2014-02-10 | Anticorrosive composition |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/487,915 Active US8647532B2 (en) | 2008-06-09 | 2012-06-04 | Anticorrosive composition |
US14/176,710 Expired - Fee Related US8951442B2 (en) | 2008-06-09 | 2014-02-10 | Anticorrosive composition |
Country Status (4)
Country | Link |
---|---|
US (3) | US20090302276A1 (fr) |
EP (1) | EP2291335B1 (fr) |
CA (1) | CA2725367C (fr) |
WO (1) | WO2009152125A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8795589B1 (en) * | 2011-04-29 | 2014-08-05 | Cortec Corporation | Bio-based volatile corrosion inhibitors |
CN113831682A (zh) * | 2021-09-24 | 2021-12-24 | 鹤山市顺鑫实业有限公司 | 一种耐腐蚀高分子材料及其制备方法 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8873711B2 (en) * | 2012-06-19 | 2014-10-28 | The Boeing Company | Method and system for visualizing effects of corrosion |
US9506879B2 (en) | 2012-06-19 | 2016-11-29 | The Boeing Company | Method and system for non-destructively evaluating a hidden workpiece |
CN105062225A (zh) * | 2015-08-15 | 2015-11-18 | 哈尔滨和谐旺科技开发有限公司 | 一种内墙粉刷材料 |
Citations (86)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2373727A (en) * | 1941-04-10 | 1945-04-17 | Intava Ltd | Compositions for the prevention of the formation or accretion of ice on exposed surfaces |
US2980620A (en) * | 1956-02-28 | 1961-04-18 | Hagan Chemicals & Controls Inc | Method of inhibiting ice melting salts and products for use in ice melting |
US3227654A (en) * | 1962-11-07 | 1966-01-04 | Standard Oil Co | Deicer composition |
US3384590A (en) * | 1964-11-25 | 1968-05-21 | Cargill Inc | Anti-corrosive salt |
US3740336A (en) * | 1970-12-23 | 1973-06-19 | Monsanto Co | Hydrogen embrittlement inhibitors for organic compositions |
US4032090A (en) * | 1975-07-21 | 1977-06-28 | Thornton Trump Walter E | Method for deicing aircraft |
US4425251A (en) * | 1982-04-12 | 1984-01-10 | Gancy A B | Water-activated exothermic chemical formulations |
US4430242A (en) * | 1982-08-02 | 1984-02-07 | Gancy Alan B | Novel road and highway deicer and traction agent, and process for its manufacture |
US4444672A (en) * | 1981-12-21 | 1984-04-24 | Gancy Alan B | Process of making calcium acetate deicing agents and product |
US4501775A (en) * | 1973-07-19 | 1985-02-26 | The Dow Chemical Company | Method for reducing the strength of ice |
US4511485A (en) * | 1981-11-09 | 1985-04-16 | Gancy Alan B | Nonpolluting salts and method of making same |
US4585571A (en) * | 1985-03-15 | 1986-04-29 | Michael A. Bloom | Deicing compositions |
US4594076A (en) * | 1979-09-28 | 1986-06-10 | Union Carbide Corporation | Method and composition for reducing the strength of ice |
US4597884A (en) * | 1984-10-02 | 1986-07-01 | Steve Greenwald | Ice and snow melt |
US4664832A (en) * | 1984-09-28 | 1987-05-12 | State Of South Dakota As Represented By The Department Of Transportation | Deicing chemicals and their preparation from polysaccharide sources |
US4668416A (en) * | 1985-01-14 | 1987-05-26 | Georgia-Pacific Corporation | Corrosion inhibition of road deicing |
US4673519A (en) * | 1985-06-24 | 1987-06-16 | Gancy Alan B | Low-energy process for the manufacture of calcium/magnesium acetate-chloride deicers and freezing point depressants |
US4676918A (en) * | 1985-11-29 | 1987-06-30 | Alkoto Ifjusag Egyesules | Anti-freeze composition suitable for making surfaces free of snow and ice |
US4728393A (en) * | 1985-11-20 | 1988-03-01 | Domtar Inc. | Methods for obtaining deicers from black liquor |
US4746449A (en) * | 1985-11-20 | 1988-05-24 | Domtar Inc. | Deicing product obtained from pulp mill black liquor |
US4803007A (en) * | 1987-10-16 | 1989-02-07 | Garber Frank R | Corrosion inhibitor for salt-based deicing compositions |
US4824588A (en) * | 1987-12-18 | 1989-04-25 | Reed Lignin Inc. | Deicing agent |
US4986925A (en) * | 1989-08-10 | 1991-01-22 | Georgia-Pacific Resins, Inc. | Corrosion inhibitors and deicing agents |
US4990278A (en) * | 1990-01-26 | 1991-02-05 | Reilly Industries, Inc. | Corrosion inhibited deicing composition and method of its use |
US5106517A (en) * | 1990-05-29 | 1992-04-21 | Baker Hughes Incorporated | Drilling fluid with browning reaction anionic carbohydrate |
US5110484A (en) * | 1990-05-29 | 1992-05-05 | Baker Hughes Incorporated | Drilling fluid with stabilized browning reaction anionic carbohydrate |
US5118434A (en) * | 1991-02-26 | 1992-06-02 | The Dow Chemical Company | Deicing fluids |
US5118435A (en) * | 1990-11-19 | 1992-06-02 | Texaco Chemical Company | Anti-icing compositions containing thickener blend having polyacrylic acid and copolymer of acrylic acid and hydrophobic vinyl monomer |
US5127954A (en) * | 1987-12-17 | 1992-07-07 | Domtar Inc. | Corrosion inhibiting systems, products containing residual amounts of such systems, and methods therefor |
US5132035A (en) * | 1989-03-06 | 1992-07-21 | General Atomics International Services Corporation | Deicing compositions comprising calcium magnesium acetate and chelating agent |
US5211868A (en) * | 1990-08-23 | 1993-05-18 | Cargill, Incorporated | Dihydrogen orthophosphate deicing composition |
US5219483A (en) * | 1991-04-02 | 1993-06-15 | General Atomics International Services Corporation | Method to increase the rate of ice melting by cma deicing chemicals with potassium acetate |
US5275752A (en) * | 1992-05-18 | 1994-01-04 | Hansen Charles N | Method and product for inhibiting corrosion due to chlorides |
US5296167A (en) * | 1991-05-13 | 1994-03-22 | Murray W Bruce | Method and composition for inhibiting corrosion by sodium and calcium chloride |
US5316928A (en) * | 1991-05-13 | 1994-05-31 | Regents Of The University Of Minnesota | Direct calcium magnesium acetate production |
US5324442A (en) * | 1992-06-16 | 1994-06-28 | Kansas State University Research Foundation | Fermentation process for the production of calcium magnesium road deicer |
US5386968A (en) * | 1993-10-21 | 1995-02-07 | Texaco Chemical Inc. | Aircraft wing de-icers with improved holdover times |
US5387358A (en) * | 1992-12-17 | 1995-02-07 | Hoechst Aktiengesellschaft | Alkaline earth metal sodium acetate, a process for its preparation and its use |
US5387359A (en) * | 1992-12-17 | 1995-02-07 | Hoechst Aktiengesellschaft | Alkaline earth metal potassium acetate, a process for its preparation and its use |
US5389276A (en) * | 1993-11-15 | 1995-02-14 | Texaco Inc. | Aircraft deicing fluid with thermal and pH-stable wetting agent |
US5419845A (en) * | 1994-03-15 | 1995-05-30 | Basf Corporation | Perfluorinated gemdiphosphonates as corrosion inhibitors for antifreeze coolants and other functional fluids |
US5430185A (en) * | 1989-06-02 | 1995-07-04 | General Atomics International Services Corporation | Process for manufacturing crystalline calcium magnesium acetate |
US5435930A (en) * | 1994-03-28 | 1995-07-25 | General Atomics International Services Corporation | Deicer/anti-icer compositions for aircraft |
US5496482A (en) * | 1991-12-14 | 1996-03-05 | Hoechst Aktiengesellschaft | Process for the preparation of alkali metal acetates |
US5498362A (en) * | 1995-03-21 | 1996-03-12 | Kansas State University Research Foundation | Process for the production of road deicers from water plant residuals |
US5531934A (en) * | 1994-09-12 | 1996-07-02 | Rohm & Haas Company | Method of inhibiting corrosion in aqueous systems using poly(amino acids) |
US5531931A (en) * | 1994-12-30 | 1996-07-02 | Cargill, Incorporated | Corrosion-inhibiting salt deicers |
US5595679A (en) * | 1995-06-13 | 1997-01-21 | Jacam Chemical Partners Ltd. | Corrosion inhibitor |
US5635101A (en) * | 1996-01-22 | 1997-06-03 | Janke George A | Deicing composition and method |
US5705087A (en) * | 1996-05-31 | 1998-01-06 | The United States Of America As Represented By The Secretary Of The Navy | Fuel system icing inhibitor and deicing composition |
US5709813A (en) * | 1996-03-21 | 1998-01-20 | Janke; George A. | Deicing composition and method |
US5709812A (en) * | 1996-04-25 | 1998-01-20 | Janke; George A. | Deicing composition and method |
US5730895A (en) * | 1997-02-13 | 1998-03-24 | Agrinutrients Technology Group, Inc. | Carboxylate coated chloride salt ice melters |
US5747089A (en) * | 1992-12-23 | 1998-05-05 | Danisco Sugar Ab | Method of making molasses product having low hygroscopicity and sufficient non-caking properties |
US5750047A (en) * | 1997-03-13 | 1998-05-12 | The B.F. Goodrich Company | Anti-icing fluids |
US5772912A (en) * | 1995-01-25 | 1998-06-30 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Environmentally friendly anti-icing |
US5876621A (en) * | 1997-09-30 | 1999-03-02 | Sapienza; Richard | Environmentally benign anti-icing or deicing fluids |
US5891225A (en) * | 1998-01-23 | 1999-04-06 | Tetra Technologies Inc | Method for applying halide brines to surfaces |
US5895116A (en) * | 1997-08-25 | 1999-04-20 | W.R. Grace & Co. -Conn. | Mobile admixture product manufacturing and delivery process and system |
US5922241A (en) * | 1997-01-23 | 1999-07-13 | Clariant Gmbh | Corrosion-inhibited deicing composition based on alkali metal and/or alkaline earth metal halides, and method of melting snow and ice on traffic areas using the composition |
US5922240A (en) * | 1995-11-09 | 1999-07-13 | Ice Ban Usa, Inc. | Deicing composition and method |
US6017968A (en) * | 1993-01-29 | 2000-01-25 | Condea Vista Company | Shear thinnable organic compositions thickened with alumina |
US6059989A (en) * | 1996-06-07 | 2000-05-09 | Clariant Gmbh | Deicing composition based on acetates and/or formates, and method for melting snow and ice on traffic areas with the aid of said composition |
US6080330A (en) * | 1999-06-14 | 2000-06-27 | Bloomer; Todd A. | Anti-freezing and deicing composition and method |
US6183664B1 (en) * | 1997-04-24 | 2001-02-06 | Ki-Bum Kim | Deicing and snow-removing composition, method for producing the same, and use thereof |
US6398979B2 (en) * | 2000-02-28 | 2002-06-04 | Cargill, Incorporated | Deicer and pre-wetting agent |
US6416684B1 (en) * | 2001-06-26 | 2002-07-09 | Grain Processing Corp | Anti-freezing and deicing composition and method |
US6506318B1 (en) * | 1997-09-30 | 2003-01-14 | Mli Associates, Llc | Environmentally benign anti-icing or deicing fluids |
US20030015686A1 (en) * | 1998-01-07 | 2003-01-23 | Sears Petroleum & Transport Corp. | Deicing solution |
US20030061962A1 (en) * | 2001-10-03 | 2003-04-03 | Michael Hoerle | Deicer mixing apparatus and method |
US20030071241A1 (en) * | 2001-03-02 | 2003-04-17 | Chon Jung Kyoon | Environmentally safe and low corrosive de-icers and a method of manufacturing same |
US20030070578A1 (en) * | 2001-10-09 | 2003-04-17 | Board Of Control Of Michigan Technological University | Anti-icing coatings and methods |
US20030098438A1 (en) * | 1998-06-29 | 2003-05-29 | Haslin Leonard Arthur | Environmentally friendly compositions having antiicing, deicing or graffiti prevention properties |
US6582622B1 (en) * | 1998-01-07 | 2003-06-24 | Sears Petroleum & Transport Corp. | De-icing solution |
US20030116748A1 (en) * | 1995-01-25 | 2003-06-26 | Haslim Leonard Arthur | Environmentally friendly compositions having anti-icing, deicing or graffiti prevention properties |
US6596188B1 (en) * | 1998-01-07 | 2003-07-22 | Sears Petroleum & Transport Corp. | Deicing solution |
US20040021127A1 (en) * | 2000-02-28 | 2004-02-05 | Koefod Robert Scott | Deicer and pre-wetting agent |
US6891138B2 (en) * | 1997-04-04 | 2005-05-10 | Robert C. Dalton | Electromagnetic susceptors with coatings for artificial dielectric systems and devices |
US7045076B2 (en) * | 1998-01-07 | 2006-05-16 | Sears Petroleum & Transport Corp. & Sears Ecological Applications Co., Llc | Deicing solution |
US20070027283A1 (en) * | 2005-07-26 | 2007-02-01 | Swift Brian L | Binders and materials made therewith |
US7176427B2 (en) * | 1997-04-04 | 2007-02-13 | Dalton Robert C | Electromagnetic susceptors for artificial dielectric systems and devices |
US20070071850A1 (en) * | 2003-09-29 | 2007-03-29 | Richard Van Der Ark | Beverages and foodstuffs resistant to light induced flavour changes, processes for making the same, and compositions for imparting such resistance |
US20080128651A1 (en) * | 2006-12-04 | 2008-06-05 | Ossian, Inc. | Processed raffinate material for enhancing melt value of de-icers |
US20090011125A1 (en) * | 2002-07-10 | 2009-01-08 | Cargill, Incorporated | Deicer mixing method |
US20090026220A1 (en) * | 2007-07-25 | 2009-01-29 | Reynold Ramnarine | Double-action fluid weighing and dispensing process and system |
US20090026411A1 (en) * | 2007-06-23 | 2009-01-29 | Alan David Sheen | De-icing method |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2785127A (en) * | 1953-09-16 | 1957-03-12 | Continental Oil Co | Oil well inhibitor |
DE59105327D1 (de) * | 1991-03-28 | 1995-06-01 | Amino Gmbh | Verfahren zur Herstellung eines Feuchthaltemittels. |
US6395534B1 (en) * | 1999-03-31 | 2002-05-28 | Council Of Scientific And Industrial Research | White rot-lignin-modifying fungus Flavodon flavus and a process for removing dye from dye containing water or soil using the fungus |
US7923437B2 (en) * | 2001-02-16 | 2011-04-12 | Cargill, Incorporated | Water soluble β-glucan, glucosamine, and N-acetylglucosamine compositions and methods for making the same |
US6641753B1 (en) | 2002-07-22 | 2003-11-04 | Todd A. Bloomer | Anti-icing and deicing compositions and method |
-
2009
- 2009-06-09 EP EP09763416.6A patent/EP2291335B1/fr not_active Not-in-force
- 2009-06-09 CA CA2725367A patent/CA2725367C/fr active Active
- 2009-06-09 US US12/480,986 patent/US20090302276A1/en not_active Abandoned
- 2009-06-09 WO PCT/US2009/046698 patent/WO2009152125A1/fr active Application Filing
-
2012
- 2012-06-04 US US13/487,915 patent/US8647532B2/en active Active
-
2014
- 2014-02-10 US US14/176,710 patent/US8951442B2/en not_active Expired - Fee Related
Patent Citations (99)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2373727A (en) * | 1941-04-10 | 1945-04-17 | Intava Ltd | Compositions for the prevention of the formation or accretion of ice on exposed surfaces |
US2980620A (en) * | 1956-02-28 | 1961-04-18 | Hagan Chemicals & Controls Inc | Method of inhibiting ice melting salts and products for use in ice melting |
US3227654A (en) * | 1962-11-07 | 1966-01-04 | Standard Oil Co | Deicer composition |
US3384590A (en) * | 1964-11-25 | 1968-05-21 | Cargill Inc | Anti-corrosive salt |
US3740336A (en) * | 1970-12-23 | 1973-06-19 | Monsanto Co | Hydrogen embrittlement inhibitors for organic compositions |
US4501775A (en) * | 1973-07-19 | 1985-02-26 | The Dow Chemical Company | Method for reducing the strength of ice |
US4032090A (en) * | 1975-07-21 | 1977-06-28 | Thornton Trump Walter E | Method for deicing aircraft |
US4594076A (en) * | 1979-09-28 | 1986-06-10 | Union Carbide Corporation | Method and composition for reducing the strength of ice |
US4511485A (en) * | 1981-11-09 | 1985-04-16 | Gancy Alan B | Nonpolluting salts and method of making same |
US4444672A (en) * | 1981-12-21 | 1984-04-24 | Gancy Alan B | Process of making calcium acetate deicing agents and product |
US4425251A (en) * | 1982-04-12 | 1984-01-10 | Gancy A B | Water-activated exothermic chemical formulations |
US4430242A (en) * | 1982-08-02 | 1984-02-07 | Gancy Alan B | Novel road and highway deicer and traction agent, and process for its manufacture |
US4664832A (en) * | 1984-09-28 | 1987-05-12 | State Of South Dakota As Represented By The Department Of Transportation | Deicing chemicals and their preparation from polysaccharide sources |
US4597884A (en) * | 1984-10-02 | 1986-07-01 | Steve Greenwald | Ice and snow melt |
US4668416A (en) * | 1985-01-14 | 1987-05-26 | Georgia-Pacific Corporation | Corrosion inhibition of road deicing |
US4585571A (en) * | 1985-03-15 | 1986-04-29 | Michael A. Bloom | Deicing compositions |
US4673519A (en) * | 1985-06-24 | 1987-06-16 | Gancy Alan B | Low-energy process for the manufacture of calcium/magnesium acetate-chloride deicers and freezing point depressants |
US4728393A (en) * | 1985-11-20 | 1988-03-01 | Domtar Inc. | Methods for obtaining deicers from black liquor |
US4746449A (en) * | 1985-11-20 | 1988-05-24 | Domtar Inc. | Deicing product obtained from pulp mill black liquor |
US4676918A (en) * | 1985-11-29 | 1987-06-30 | Alkoto Ifjusag Egyesules | Anti-freeze composition suitable for making surfaces free of snow and ice |
US4803007A (en) * | 1987-10-16 | 1989-02-07 | Garber Frank R | Corrosion inhibitor for salt-based deicing compositions |
US5127954A (en) * | 1987-12-17 | 1992-07-07 | Domtar Inc. | Corrosion inhibiting systems, products containing residual amounts of such systems, and methods therefor |
US4824588A (en) * | 1987-12-18 | 1989-04-25 | Reed Lignin Inc. | Deicing agent |
US5132035A (en) * | 1989-03-06 | 1992-07-21 | General Atomics International Services Corporation | Deicing compositions comprising calcium magnesium acetate and chelating agent |
US5430185A (en) * | 1989-06-02 | 1995-07-04 | General Atomics International Services Corporation | Process for manufacturing crystalline calcium magnesium acetate |
US4986925A (en) * | 1989-08-10 | 1991-01-22 | Georgia-Pacific Resins, Inc. | Corrosion inhibitors and deicing agents |
US4990278A (en) * | 1990-01-26 | 1991-02-05 | Reilly Industries, Inc. | Corrosion inhibited deicing composition and method of its use |
US5106517A (en) * | 1990-05-29 | 1992-04-21 | Baker Hughes Incorporated | Drilling fluid with browning reaction anionic carbohydrate |
US5110484A (en) * | 1990-05-29 | 1992-05-05 | Baker Hughes Incorporated | Drilling fluid with stabilized browning reaction anionic carbohydrate |
US5211868A (en) * | 1990-08-23 | 1993-05-18 | Cargill, Incorporated | Dihydrogen orthophosphate deicing composition |
US5118435A (en) * | 1990-11-19 | 1992-06-02 | Texaco Chemical Company | Anti-icing compositions containing thickener blend having polyacrylic acid and copolymer of acrylic acid and hydrophobic vinyl monomer |
US5118434A (en) * | 1991-02-26 | 1992-06-02 | The Dow Chemical Company | Deicing fluids |
US5219483A (en) * | 1991-04-02 | 1993-06-15 | General Atomics International Services Corporation | Method to increase the rate of ice melting by cma deicing chemicals with potassium acetate |
US5296167A (en) * | 1991-05-13 | 1994-03-22 | Murray W Bruce | Method and composition for inhibiting corrosion by sodium and calcium chloride |
US5316928A (en) * | 1991-05-13 | 1994-05-31 | Regents Of The University Of Minnesota | Direct calcium magnesium acetate production |
US5496482A (en) * | 1991-12-14 | 1996-03-05 | Hoechst Aktiengesellschaft | Process for the preparation of alkali metal acetates |
US5275752A (en) * | 1992-05-18 | 1994-01-04 | Hansen Charles N | Method and product for inhibiting corrosion due to chlorides |
US5324442A (en) * | 1992-06-16 | 1994-06-28 | Kansas State University Research Foundation | Fermentation process for the production of calcium magnesium road deicer |
US5387358A (en) * | 1992-12-17 | 1995-02-07 | Hoechst Aktiengesellschaft | Alkaline earth metal sodium acetate, a process for its preparation and its use |
US5387359A (en) * | 1992-12-17 | 1995-02-07 | Hoechst Aktiengesellschaft | Alkaline earth metal potassium acetate, a process for its preparation and its use |
US5747089A (en) * | 1992-12-23 | 1998-05-05 | Danisco Sugar Ab | Method of making molasses product having low hygroscopicity and sufficient non-caking properties |
US6017968A (en) * | 1993-01-29 | 2000-01-25 | Condea Vista Company | Shear thinnable organic compositions thickened with alumina |
US5386968A (en) * | 1993-10-21 | 1995-02-07 | Texaco Chemical Inc. | Aircraft wing de-icers with improved holdover times |
US5389276A (en) * | 1993-11-15 | 1995-02-14 | Texaco Inc. | Aircraft deicing fluid with thermal and pH-stable wetting agent |
US5419845A (en) * | 1994-03-15 | 1995-05-30 | Basf Corporation | Perfluorinated gemdiphosphonates as corrosion inhibitors for antifreeze coolants and other functional fluids |
US5435930A (en) * | 1994-03-28 | 1995-07-25 | General Atomics International Services Corporation | Deicer/anti-icer compositions for aircraft |
US5531934A (en) * | 1994-09-12 | 1996-07-02 | Rohm & Haas Company | Method of inhibiting corrosion in aqueous systems using poly(amino acids) |
US5531931A (en) * | 1994-12-30 | 1996-07-02 | Cargill, Incorporated | Corrosion-inhibiting salt deicers |
US20030116748A1 (en) * | 1995-01-25 | 2003-06-26 | Haslim Leonard Arthur | Environmentally friendly compositions having anti-icing, deicing or graffiti prevention properties |
US5772912A (en) * | 1995-01-25 | 1998-06-30 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Environmentally friendly anti-icing |
US5498362A (en) * | 1995-03-21 | 1996-03-12 | Kansas State University Research Foundation | Process for the production of road deicers from water plant residuals |
US5595679A (en) * | 1995-06-13 | 1997-01-21 | Jacam Chemical Partners Ltd. | Corrosion inhibitor |
US5922240A (en) * | 1995-11-09 | 1999-07-13 | Ice Ban Usa, Inc. | Deicing composition and method |
US5635101A (en) * | 1996-01-22 | 1997-06-03 | Janke George A | Deicing composition and method |
US5709813A (en) * | 1996-03-21 | 1998-01-20 | Janke; George A. | Deicing composition and method |
US5919394A (en) * | 1996-04-25 | 1999-07-06 | Ice Ban Usa, Inc. | Deicing composition and method |
US5709812A (en) * | 1996-04-25 | 1998-01-20 | Janke; George A. | Deicing composition and method |
US5705087A (en) * | 1996-05-31 | 1998-01-06 | The United States Of America As Represented By The Secretary Of The Navy | Fuel system icing inhibitor and deicing composition |
US6059989A (en) * | 1996-06-07 | 2000-05-09 | Clariant Gmbh | Deicing composition based on acetates and/or formates, and method for melting snow and ice on traffic areas with the aid of said composition |
US5922241A (en) * | 1997-01-23 | 1999-07-13 | Clariant Gmbh | Corrosion-inhibited deicing composition based on alkali metal and/or alkaline earth metal halides, and method of melting snow and ice on traffic areas using the composition |
US5730895A (en) * | 1997-02-13 | 1998-03-24 | Agrinutrients Technology Group, Inc. | Carboxylate coated chloride salt ice melters |
US5750047A (en) * | 1997-03-13 | 1998-05-12 | The B.F. Goodrich Company | Anti-icing fluids |
US7176427B2 (en) * | 1997-04-04 | 2007-02-13 | Dalton Robert C | Electromagnetic susceptors for artificial dielectric systems and devices |
US6891138B2 (en) * | 1997-04-04 | 2005-05-10 | Robert C. Dalton | Electromagnetic susceptors with coatings for artificial dielectric systems and devices |
US6183664B1 (en) * | 1997-04-24 | 2001-02-06 | Ki-Bum Kim | Deicing and snow-removing composition, method for producing the same, and use thereof |
US6224250B1 (en) * | 1997-08-25 | 2001-05-01 | W. R. Grace & Co.-Conn. | Mobile cement additive and concrete admixture manufacturing process and system |
US5895116A (en) * | 1997-08-25 | 1999-04-20 | W.R. Grace & Co. -Conn. | Mobile admixture product manufacturing and delivery process and system |
US6544434B2 (en) * | 1997-09-30 | 2003-04-08 | Metss Corporation | Environmentally benign anti-icing or deicing fluids |
US20020063236A1 (en) * | 1997-09-30 | 2002-05-30 | Richard Sapienza | Environmentally benign anti-icing or deicing fluids |
US20030136940A1 (en) * | 1997-09-30 | 2003-07-24 | Richard Sapienza | Environmentally benign anti-icing or deicing fluids |
US6506318B1 (en) * | 1997-09-30 | 2003-01-14 | Mli Associates, Llc | Environmentally benign anti-icing or deicing fluids |
US5876621A (en) * | 1997-09-30 | 1999-03-02 | Sapienza; Richard | Environmentally benign anti-icing or deicing fluids |
US7045076B2 (en) * | 1998-01-07 | 2006-05-16 | Sears Petroleum & Transport Corp. & Sears Ecological Applications Co., Llc | Deicing solution |
US20080054219A1 (en) * | 1998-01-07 | 2008-03-06 | Sears Petroleum & Transport Corporation | Deicing solution |
US7014789B2 (en) * | 1998-01-07 | 2006-03-21 | Sears Petroleum & Transport Corp | Deicing solution |
US6905631B2 (en) * | 1998-01-07 | 2005-06-14 | Sear Petroleum & Transport Corp. | De-icing solution |
US6582622B1 (en) * | 1998-01-07 | 2003-06-24 | Sears Petroleum & Transport Corp. | De-icing solution |
US20030015686A1 (en) * | 1998-01-07 | 2003-01-23 | Sears Petroleum & Transport Corp. | Deicing solution |
US6596188B1 (en) * | 1998-01-07 | 2003-07-22 | Sears Petroleum & Transport Corp. | Deicing solution |
US7208101B2 (en) * | 1998-01-07 | 2007-04-24 | Sears Petroleum & Transport Corp. | Deicing solution |
US5891225A (en) * | 1998-01-23 | 1999-04-06 | Tetra Technologies Inc | Method for applying halide brines to surfaces |
US20030098438A1 (en) * | 1998-06-29 | 2003-05-29 | Haslin Leonard Arthur | Environmentally friendly compositions having antiicing, deicing or graffiti prevention properties |
US6080330A (en) * | 1999-06-14 | 2000-06-27 | Bloomer; Todd A. | Anti-freezing and deicing composition and method |
US20040021127A1 (en) * | 2000-02-28 | 2004-02-05 | Koefod Robert Scott | Deicer and pre-wetting agent |
US20070040149A1 (en) * | 2000-02-28 | 2007-02-22 | Sears Petroleum & Transport Corporation | Deicer and pre-wetting agent |
US20050017215A1 (en) * | 2000-02-28 | 2005-01-27 | Cargill, Incorporated | Deicer and pre-wetting agent |
US6398979B2 (en) * | 2000-02-28 | 2002-06-04 | Cargill, Incorporated | Deicer and pre-wetting agent |
US20030071241A1 (en) * | 2001-03-02 | 2003-04-17 | Chon Jung Kyoon | Environmentally safe and low corrosive de-icers and a method of manufacturing same |
US6416684B1 (en) * | 2001-06-26 | 2002-07-09 | Grain Processing Corp | Anti-freezing and deicing composition and method |
US20030061962A1 (en) * | 2001-10-03 | 2003-04-03 | Michael Hoerle | Deicer mixing apparatus and method |
US20030070578A1 (en) * | 2001-10-09 | 2003-04-17 | Board Of Control Of Michigan Technological University | Anti-icing coatings and methods |
US20090011125A1 (en) * | 2002-07-10 | 2009-01-08 | Cargill, Incorporated | Deicer mixing method |
US20070071850A1 (en) * | 2003-09-29 | 2007-03-29 | Richard Van Der Ark | Beverages and foodstuffs resistant to light induced flavour changes, processes for making the same, and compositions for imparting such resistance |
US20070123679A1 (en) * | 2005-07-26 | 2007-05-31 | Swift Brian L | Binders and materials made therewith |
US20070027283A1 (en) * | 2005-07-26 | 2007-02-01 | Swift Brian L | Binders and materials made therewith |
US20080128651A1 (en) * | 2006-12-04 | 2008-06-05 | Ossian, Inc. | Processed raffinate material for enhancing melt value of de-icers |
US7473379B2 (en) * | 2006-12-04 | 2009-01-06 | Ossian, Inc. | Processed raffinate material for enhancing melt value of de-icers |
US20090026411A1 (en) * | 2007-06-23 | 2009-01-29 | Alan David Sheen | De-icing method |
US20090026220A1 (en) * | 2007-07-25 | 2009-01-29 | Reynold Ramnarine | Double-action fluid weighing and dispensing process and system |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8795589B1 (en) * | 2011-04-29 | 2014-08-05 | Cortec Corporation | Bio-based volatile corrosion inhibitors |
CN113831682A (zh) * | 2021-09-24 | 2021-12-24 | 鹤山市顺鑫实业有限公司 | 一种耐腐蚀高分子材料及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
US8951442B2 (en) | 2015-02-10 |
EP2291335B1 (fr) | 2017-02-01 |
US8647532B2 (en) | 2014-02-11 |
EP2291335A1 (fr) | 2011-03-09 |
CA2725367C (fr) | 2018-01-23 |
CA2725367A1 (fr) | 2009-12-17 |
WO2009152125A1 (fr) | 2009-12-17 |
EP2291335A4 (fr) | 2011-12-14 |
US20140155304A1 (en) | 2014-06-05 |
US20120240819A1 (en) | 2012-09-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US8951442B2 (en) | Anticorrosive composition | |
US6440325B1 (en) | De-icing solution | |
US7208101B2 (en) | Deicing solution | |
US8226846B2 (en) | Deicing solution | |
US6299793B1 (en) | Deicing solution | |
Panagiotopoulos et al. | Analytical methods for the determination of sugars in marine samples: A historical perspective and future directions | |
US6596188B1 (en) | Deicing solution | |
US6599440B2 (en) | Deicing solution | |
Fernández-Bolaños et al. | Total recovery of the waste of two-phase olive oil processing: isolation of added-value compounds | |
Raja et al. | Polysaccharides from Moringa oleifera gum: structural elements, interaction with β-lactoglobulin and antioxidative activity | |
US20160002358A1 (en) | Biomass processing using ionic liquids | |
Petanovska-Ilievska et al. | Development of reverse-phase high-performance liquid chromatography method for simultaneous determination of sodium benzoate and potassium sorbate in beverages | |
Hokputsa et al. | A physico-chemical comparative study on extracellular carbohydrate polymers from five desert algae | |
US20180030554A1 (en) | Biomass processing using ionic liquids | |
Martínez et al. | New structural features of Acacia tortuosa gum exudate | |
Nagel et al. | The arabinogalactan of dried mango exudate and its co-extraction during pectin recovery from mango peel | |
López-Barajas et al. | Improved size-exclusion high-performance liquid chromatographic method for the simple analysis of grape juice and wine polysaccharides | |
Kemmei et al. | Simultaneous and sensitive analysis of aliphatic carboxylic acids by ion-chromatography using on-line complexation with copper (II) ion | |
Lance et al. | THE DETERMINATION OF α‐AND β‐ACIDS IN HOPS AND HOP PRODUCTS USING HPLC | |
De Pinto et al. | Structural elucidation of proteic fraction isolated from Acacia glomerosa gum | |
Panagiotopoulos et al. | Spectrophotometric and chromatographic analysis of carbohydrates in marine samples | |
Parish | The amino‐acids of sugar cane. I.—The amino‐acids of cane‐juice and the effect of nitrogenous fertilisation on the levels of these substances | |
Brown | Nitrogenous Compounds in Sugar Beet Juices | |
Takagi et al. | High performance liquid chromatographic separation of malto-oligosaccharides as quinoxaline derivatives for measurement of degree of polymerization | |
Chew et al. | Tunable durian seed gum-derived eutectogel as a novel coating material: Rheological, thermal, textural and barrier properties for enhanced food preservation |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: SEARS ECOLOGICAL APPLICATIONS CO. LLC AND SEARS PE Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:HARTLEY, ROBERT A.;WOOD, DAVID H.;REEL/FRAME:022799/0274 Effective date: 20090608 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |