US20090217701A1 - Natural Gas Liquefaction Process for Ling - Google Patents

Natural Gas Liquefaction Process for Ling Download PDF

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Publication number
US20090217701A1
US20090217701A1 US11/922,623 US92262306A US2009217701A1 US 20090217701 A1 US20090217701 A1 US 20090217701A1 US 92262306 A US92262306 A US 92262306A US 2009217701 A1 US2009217701 A1 US 2009217701A1
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United States
Prior art keywords
gas stream
heat exchange
cooled
expanded
refrigerant
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Abandoned
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US11/922,623
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English (en)
Inventor
Moses Minta
Kevin N. Stanley
John B. Stone
Ronald R. Bowen
Linda J. Cote
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Individual
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Individual
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Priority to US11/922,623 priority Critical patent/US20090217701A1/en
Publication of US20090217701A1 publication Critical patent/US20090217701A1/en
Abandoned legal-status Critical Current

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0257—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of nitrogen
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    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022—Hydrocarbons, e.g. natural gas
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    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
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    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/02—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
    • F25J2205/04—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00—Processes characterised by the type or other details of the feed stream
    • F25J2210/06—Splitting of the feed stream, e.g. for treating or cooling in different ways
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00—Processes or apparatus involving steps for the removal of impurities
    • F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
    • F25J2220/62—Separating low boiling components, e.g. He, H2, N2, Air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/08—Cold compressor, i.e. suction of the gas at cryogenic temperature and generally without afterstage-cooler
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/30—Compression of the feed stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/04—Internal refrigeration with work-producing gas expansion loop
    • F25J2270/06—Internal refrigeration with work-producing gas expansion loop with multiple gas expansion loops

Definitions

  • Embodiments of the invention relate to a process for liquefaction of natural gas and other methane-rich gas streams, and more particularly to a process for producing liquefied natural gas (LNG).
  • LNG liquefied natural gas
  • LNG liquefied natural gas
  • the refrigerants used may be a mixture of components such as methane, ethane, propane, butane, and nitrogen in multi-component refrigeration cycles.
  • the refrigerants may also be pure substances such as propane, ethylene, or nitrogen in “cascade cycles.” Substantial volumes of these refrigerants with close control of composition are required. Further, such refrigerants may have to be imported and stored imposing logistics requirements.
  • some of the components of the refrigerant may be prepared, typically by a distillation process integrated with the liquefaction process.
  • the use of gas expanders to provide the feed gas cooling thereby eliminating or reducing the logistical problems of refrigerant handling has been of interest to process engineers.
  • the expander system operates on the principle that the feed gas can be allowed to expand through an expansion turbine, thereby performing work and reducing the temperature of the gas.
  • the low temperature gas is then heat exchanged with the feed gas to provide the refrigeration needed.
  • Supplemental refrigeration is typically needed to fully liquefy the feed gas and this may be provided by a refrigerant system.
  • the power obtained from the expansion is usually used to supply part of the main compression power used in the refrigeration cycle.
  • the typical expander cycle for making LNG operates at the feed gas pressure, typically under about 6,895 kPa (1,000 psia).
  • gas expanders have typically been used to further cool feed gas after it has been pre-cooled to temperatures well below ⁇ 20° C. using an external refrigerant in a closed cycle, for example.
  • a common factor in most proposed expander cycles is the requirement for a second, external refrigeration cycle to pre-cool the gas before the gas enters the expander.
  • Such a combined external refrigeration cycle and expander cycle is sometimes referred to as a “hybrid cycle.” While such refrigerant-based pre-cooling eliminates a major source of inefficiency in the use of expanders, it significantly reduces the benefits of the expander cycle, namely the elimination of external refrigerants. Additional cooling may also be required after the expander cooling and may be provided by another external refrigerant system, such as nitrogen or a cold mixed refrigerant.
  • Embodiments of the present invention provide a process for liquefying natural gas and other methane-rich gas streams to produce liquefied natural gas (LNG) and/or other liquefied methane-rich gases.
  • natural gas as used in this specification, including the appended claims, means a gaseous feed stock suitable for manufacturing LNG.
  • the natural gas could comprise gas obtained from a crude oil well (associated gas) or from a gas well (non-associated gas).
  • the composition of natural gas can vary significantly.
  • natural gas is a methane-rich gas containing methane (C 1 ) as a major component.
  • a first step is carried out in which a first fraction of the feed gas is withdrawn, compressed, cooled and expanded to a lower pressure to cool the withdrawn first fraction.
  • the remaining fraction of the feed stream is cooled by indirect heat exchange with the expanded first fraction in a first heat exchange process.
  • a second step involving a sub-cooling loop, a separate stream comprised of the flash vapor is compressed, cooled and expanded to a lower pressure providing another cold stream. This cold stream is used to cool the remaining feed gas stream in a second indirect heat exchange process, which constitutes the sub-cooling heat exchange process.
  • the expanded stream exiting from the second heat exchange process is used for supplemental cooling in the first indirect heat exchange step.
  • the remaining feed gas is subsequently expanded to a lower pressure, thereby partially liquefying this feed gas stream.
  • the liquefied fraction of this stream is withdrawn from the process as LNG having a temperature corresponding to the bubble point pressure.
  • the vapor fraction of this stream is returned to supplement the cooling provided in the indirect heat exchange steps.
  • the warmed cooling gases from the various sources are compressed and recycled.
  • a process for liquefying a gas stream rich in methane comprising providing a gas stream rich in methane at a pressure less than 1,000 psia; providing a refrigerant at a pressure of less than 1,000 psia; compressing said refrigerant to a pressure greater than or equal to 1500 psia to provide a compressed refrigerant; cooling said compressed refrigerant by indirect heat exchange with a cooling fluid; expanding said compressed refrigerant to further cool said compressed refrigerant, thereby producing an expanded, cooled refrigerant; passing said expanded, cooled refrigerant to a heat exchange area; and passing said gas stream through said heat exchange area to cool at least part of said gas stream by indirect heat exchange with said expanded, cooled refrigerant, thereby forming a cooled gas stream.
  • providing the refrigerant at a pressure of less than 1,000 psia comprises withdrawing a portion of the gas for use as the refrigerant.
  • the portion of the gas stream to be used as the refrigerant is withdrawn from the gas stream before the gas stream is passed to the heat exchange area.
  • the process according to the present invention further comprises providing at least a portion of the refrigeration duty for the heat exchange area using a closed loop charged with flash vapor produced in the process for liquefying the gas stream rich in methane. Additional embodiments according to the present invention will be apparent to those skilled in the art.
  • FIG. 1 is a schematic flow diagram of one embodiment for producing LNG in accordance with the process of this invention.
  • FIG. 2 is a schematic flow diagram of a second embodiment for producing LNG that is similar to the process shown in FIG. 1 , except that the gaseous refrigerant in the compressed, cooled and expanded loop is de-coupled from the feed gas and may therefore have a different composition than the feed gas.
  • FIG. 3 is a schematic flow diagram of a third embodiment for producing LNG in accordance with the process of this invention that uses a plurality of work expansion steps for improved efficiency.
  • FIG. 4 is a schematic flow diagram of a fourth embodiment for producing LNG in accordance with the process of this invention that uses a plurality of work expansion steps similar to FIG. 3 , but also incorporates an additional expansion step as well as compression of the feed gas to improve performance of the expansion steps.
  • FIG. 5 is a schematic flow diagram of a fifth embodiment for producing LNG in accordance with the process of this invention that is similar to the embodiment shown in FIG. 4 , but utilizes an additional side stream and expansion of process gas to provide sub-cooling.
  • FIG. 6 is another embodiment similar to the embodiments shown in FIG. 1 and FIG. 2 in which the refrigerant for the sub-cooling loop is cooled in the sub-cooling heat exchanger prior to expansion.
  • FIG. 7 is another embodiment in which the sub-cooling loop is coupled to the feed gas.
  • FIG. 8 is another embodiment showing an alternative arrangement for the sub-cooling loop.
  • FIG. 9 is a similar embodiment to that of FIG. 8 but using split expanded streams through the sub-cooler wherein an expansion valve, Joules-Thompson valve, or similar expansion device is used for improved efficiency in the sub-cooler.
  • FIG. 10 is another embodiment in which a nitrogen rejection stage has been integrated for situations in which nitrogen rejection may be needed.
  • FIG. 11 is yet another embodiment in which the refrigerant for the sub-cooling loop is derived from the flash vapor from the nitrogen rejection unit and is therefore rich in nitrogen content.
  • Embodiments of the present invention provide a process for natural gas liquefaction using primarily gas expanders and eliminating the need for external refrigerants. That is, in some embodiments disclosed herein, the feed gas itself (e.g., natural gas) is used as the refrigerant in all refrigeration cycles. Such refrigeration cycles do not require supplemental cooling using external refrigerants (i.e., refrigerants other than the feed gas itself or gas that is produced at or near the LNG process plant) as typical proposed gas expander cycles do, yet such refrigeration cycles have a higher efficiency. In one or more embodiments, cooling water or air are the only external sources of cooling fluids and are used for compressor inter-stage or after cooling.
  • FIG. 1 illustrates one embodiment of the present invention in which an expander loop 5 (i.e., an expander cycle) and a sub-cooling loop 6 are used.
  • expander loop 5 and sub-cooling loop 6 are shown with double-width lines in FIG. 1 .
  • loop and cycle are used interchangeably.
  • feed gas stream 10 enters the liquefaction process at a pressure less than about 1200 psia, or less than about 1100 psia, or less than about 1000 psia, or less than about 900 psia, or less than about 800 psia, or less than about 700 psia, or less than about 600 psia.
  • the pressure of feed gas stream 10 will be about 800 psia.
  • Feed gas stream 10 generally comprises natural gas that has been treated to remove contaminants using processes and equipment that are well known in the art.
  • a portion of feed gas stream 10 is withdrawn to form side stream 11 , thus providing, as will be apparent from the following discussion, a refrigerant at a pressure corresponding to the pressure of feed gas stream 10 , namely any of the above pressures, including a pressure of less than about 1000 psia.
  • a portion of the feed gas stream is used as the refrigerant for expander loop 5 .
  • the present method is any of the other embodiments herein described, wherein the portion of the feed gas stream to be used as the refrigerant is withdrawn from the heat exchange area, expanded, and passed back to the heat exchange area to provide at least part of the refrigeration duty for the heat exchange area.
  • Side stream 11 is passed to compression unit 20 where it is compressed to a pressure greater than or equal to about 1500 psia, thus providing compressed refrigerant stream 12 .
  • side stream 11 is compressed to a pressure greater than or equal to about 1600 psia, or greater than or equal to about 1700 psia, or greater than or equal to about 1800 psia, or greater than or equal to about 1900 psia, or greater than or equal to about 2000 psia, or greater than or equal to about 2500 psia, or greater than or equal to about 3000 psia, thus providing compressed refrigerant stream 12 .
  • compression unit means any one type or combination of similar or different types of compression equipment, and may include auxiliary equipment, known in the art for compressing a substance or mixture of substances.
  • a “compression unit” may utilize one or more compression stages.
  • Illustrative compressors may include, but are not limited to, positive displacement types, such as reciprocating and rotary compressors for example, and dynamic types, such as centrifugal and axial flow compressors, for example.
  • compressed refrigerant stream 12 is passed to cooler 30 where it is cooled by indirect heat exchange with a suitable cooling fluid to provide a compressed, cooled refrigerant.
  • cooler 30 is of the type that provides water or air as the cooling fluid, although any type of cooler can be used.
  • the temperature of compressed refrigerant stream 12 as it emerges from cooler 30 depends on the ambient conditions and the cooling medium used and is typically from about 35° F. to about 105° F.
  • Cooled compressed refrigerant stream 12 is then passed to expander 40 where it is expanded and consequently cooled to form expanded refrigerant stream 13 .
  • expander 40 is a work-expansion device, such as gas expander producing work that may be extracted and used for compression.
  • Expanded refrigerant stream 13 is passed to heat exchange area 50 to provide at least part of the refrigeration duty for heat exchange area 50 .
  • heat exchange area means any one type or combination of similar or different types of equipment known in the art for facilitating heat transfer.
  • a “heat exchange area” may be contained within a single piece of equipment, or it may comprise areas contained in a plurality of equipment pieces. Conversely, multiple heat exchange areas may be contained in a single piece of equipment.
  • feed gas stream 10 is sub-cooled by sub-cooling loop 6 (described below) to produce sub-cooled stream 10 a .
  • Sub-cooled stream 10 a is then expanded to a lower pressure in expander 70 , thereby partially liquefying sub-cooled stream 10 a to form a liquid fraction and a remaining vapor fraction.
  • Expander 70 may be any pressure reducing device, including, but not limited to a valve, control valve, Joule Thompson valve, Venturi device, liquid expander, hydraulic turbine, and the like.
  • Partially liquefied sub-cooled stream 10 a is passed to surge tank 80 where the liquefied fraction 15 is withdrawn from the process as LNG having a temperature corresponding to the bubble point pressure.
  • flash vapor stream 16 is used as fuel to power the compressor units and/or as a refrigerant in sub-cooling loop 6 as described below. Prior to being used as fuel, all or a portion of flash vapor stream 16 may optionally be passed from surge tank 80 to heat exchange areas 50 and 55 to supplement the cooling provided in such heat exchange areas.
  • a portion of flash vapor 16 is withdrawn through line 17 to fill sub-cooling loop 6 .
  • a portion of the feed gas from feed gas stream 10 is withdrawn (in the form of flash gas from flash gas stream 16 ) for use as the refrigerant in sub-cooling loop 6 .
  • make-up gas i.e., additional flash vapor from line 17
  • expanded stream 18 is discharged from expander 41 and drawn through heat exchange areas 55 and 50 .
  • Expanded flash vapor stream 18 (the sub-cooling refrigerant stream) is then returned to compression unit 90 where it is re-compressed to a higher pressure and warmed.
  • the re-compressed sub-cooling refrigerant stream is cooled in cooler 31 , which can be of the same type as cooler 30 , although any type of cooler may be used.
  • the re-compressed sub-cooling refrigerant stream is passed to heat exchange area 50 where it is further cooled by indirect heat exchange with expanded refrigerant stream 13 , sub-cooling refrigerant stream 18 , and, optionally, flash vapor stream 16 .
  • the present method is any of the other embodiments disclosed herein further comprising providing cooling using a closed loop (e.g., sub-cooling loop 6 ) charged with flash vapor resulting from the LNG production (e.g., flash vapor 16 ).
  • feed gas stream 10 passes from one heat exchange area to another, the temperature of feed gas stream 10 will be reduced until ultimately a sub-cooled stream is produced.
  • mass flow rate of feed gas stream 10 will be reduced.
  • Other modifications, such as compression, may also be made to feed gas stream 10 . While each such modification to feed gas stream 10 could be considered to produce a new and different stream, for clarity and ease of illustration, the feed gas stream will be referred to as feed gas stream 10 unless otherwise indicated, with the understanding that passage through heat exchange areas, the taking of side streams, and other modifications will produce temperature, pressure, and/or flow rate changes to feed gas stream 10 .
  • FIG. 2 illustrates another embodiment of the present invention that is similar to the embodiment shown in FIG. 1 , except that expander loop 5 has been replaced with expander loop 7 .
  • Expander loop 7 is shown with double-width lines in FIG. 2 for clarity. Expander loop 7 utilizes substantially the same equipment as expander loop 5 (for example, compressor 20 , cooler 30 , and expander 40 , all of which have been described above).
  • the gaseous refrigerant in expander loop 7 however, is de-coupled from the feed gas and may therefore have a different composition than the feed gas. That is, expander loop 7 is essentially a closed loop and is not connected to feed gas stream 10 .
  • the refrigerant for expander loop 7 is therefore not necessarily the feed gas, although it may be.
  • Expander loop 7 may be charged with any suitable refrigerant gas that is produced at or near the LNG process plant in which expander loop 7 is utilized.
  • the refrigerant gas used to charge expander loop 7 could be a feed gas, such as natural gas, that has only been partially treated to remove contaminants.
  • expander loop 7 is a high pressure gas loop.
  • Stream 12 a exits compression unit 20 at a pressure greater than or equal to about 1500 psia, or greater than or equal to about 1600 psia, or greater than or equal to about 1700 psia, or greater than or equal to about 1800 psia, or greater than or equal to about 1900 psia, or greater than or equal to about 2000 psia, or greater than or equal to about 2500 psia, or greater than or equal to about 3000 psia.
  • the temperature of compressed refrigerant stream 12 a as it emerges from cooler 30 depends on the ambient conditions and the cooling medium used and is typically about from about 35° F.
  • expander loops 5 and 7 may be used interchangeably. For example, in an embodiment utilizing expander loop 5 , expander loop 7 may be substituted for expander loop 5 .
  • FIG. 3 shows another embodiment for producing LNG in accordance with the process of the invention.
  • the process illustrated in FIG. 3 utilizes a plurality of work expansion cycles to provide supplemental cooling for the feed gas and other streams.
  • the use of such work expansion cycles results in overall improved efficiency for the liquefaction process.
  • feed gas stream 10 again enters the liquefaction process at the pressures described above.
  • side stream 11 is fed to expander loop 5 in the manner previously described, but it will be apparent that closed expander loop 7 could be utilized in the place of expander loop 5 , in which case side stream 11 would not be necessary.
  • Expander loop 5 operates in the same manner as described above for the embodiment shown in FIG. 1 , except that expanded refrigerant stream 13 is passed through heat exchange area 56 , described in detail below, to provide at least a part of the refrigeration duty for heat exchange area 56 .
  • feed gas stream 10 that is not withdrawn as side stream 11 is passed to heat exchange area 56 where it is cooled, at least in part, by indirect heat exchange with expanded refrigerant stream 13 and other streams described below.
  • feed gas stream 10 is passed through heat exchange areas 57 and 58 where it is further cooled by indirect heat exchange with additional streams described below.
  • first and second work expansion cycles are utilized for improved efficiency as follows: before feed gas stream 10 enters heat exchange area 57 , side stream 11 b is taken from feed gas stream 10 . After feed gas stream 10 exits heat exchange area 57 , but before it enters heat exchange area 58 , side stream 11 c is taken from feed gas stream 10 .
  • side streams 11 b and 11 c are taken from feed gas stream 10 at different stages of feed gas stream cooling. That is, each side stream is withdrawn from the feed gas stream at a different point on the cooling curve of the feed gas such that each successively withdrawn side stream has a lower initial temperature than the previously withdrawn side stream.
  • expanded streams 13 b and 13 c are passed to compression units 61 and 62 , respectively, where they are re-compressed and combined to form stream 14 a .
  • Stream 14 a is cooled by cooler 32 prior to being re-combined with feed gas stream 10 .
  • Cooler 32 can be the same type of cooler or cooler types as coolers 30 and 31 .
  • Expanders 42 and 43 are work expansion devices of the type well know to those of skill in the art. Illustrative, non-limiting examples of suitable work expansion devices include liquid expanders and hydraulic turbines.
  • the feed gas stream is further cooled using a plurality of work expansion devices.
  • each of the work expansion devices expands a portion of the feed gas stream and thereby cools such portion, wherein each of the portions of the feed gas stream expanded in the work expansion devices is withdrawn from the feed gas stream at a different stage of feed gas stream cooling (i.e., at a different feed gas stream temperature).
  • the work expansion devices are utilized by withdrawing one or more side streams from the feed gas stream; passing said one or more side streams to one or more work expansion devices; expanding said one of more side streams to expand and cool said one or more side streams, thereby forming one or more expanded, cooled side streams; passing said one or more expanded, cooled side streams to at least one heat exchange area; passing said gas stream through said at least one heat exchange area; and at least partially cooling said gas stream by indirect heat exchange with said one or more expanded, cooled side streams.
  • feed gas stream 10 after being cooled in heat exchange areas 56 , 57 , and 58 , is then passed to heat exchange area 59 where it is further cooled to produce sub-cooled stream 10 a .
  • the principal function of heat exchange area 59 is to sub-cool feed gas stream 10 .
  • Sub-cooled stream 10 a is then expanded to a lower pressure in expander 85 , thereby partially liquefying sub-cooled stream 10 a to form a liquid fraction and a remaining vapor fraction.
  • Expander 85 may be any pressure reducing device, including, but not limited to a valve, control valve, Joule Thompson valve, Venturi device, liquid expander, hydraulic turbine, and the like.
  • Partially liquefied sub-cooled stream 10 a is passed to surge tank 80 where the liquefied fraction 15 is withdrawn from the process as LNG having a temperature corresponding to the bubble point pressure.
  • the remaining vapor fraction (flash vapor) stream 16 is used as fuel to power the compressor units and/or as a refrigerant in sub-cooling loop 8 in a manner substantially the same as previously described for sub-cooling loop 6 .
  • sub-cooling loop 8 is similar to sub-cooling loop 6 , except that sub-cooling loop 8 supplies cooling to four heat exchange areas (heat exchange areas 56 , 57 , 58 , and 59 ).
  • FIG. 4 illustrates yet another embodiment of the present invention.
  • the embodiment shown in FIG. 4 is substantially the same as the embodiment shown in FIG. 3 , except that compression unit 25 and expander 35 have been added.
  • Expander 35 may be any type of liquid expander or hydraulic turbine. Expander 35 is placed between heat exchange areas 58 and 59 such that feed gas stream 10 flows from heat exchange area 58 into expander 35 where it is expanded, and consequently cooled to produce expanded feed gas stream 10 b . Stream 10 b then is passed to heat exchange area 59 where it is sub-cooled to produce sub-cooled stream 10 c .
  • the overall cooling load on sub-cooling loop 8 is advantageously reduced.
  • the present method is any of the other embodiments disclosed herein further comprising expanding at least a portion of the cooled feed gas stream to produce a cooled, expanded feed gas stream (e.g., stream 10 b ); and further cooling the cooled, expanded feed gas stream by indirect heat exchange with a closed loop (e.g., sub-cooling loop 6 or 8 ) charged with flash vapor resulting from the LNG production (e.g., flash vapor 16 ).
  • a closed loop e.g., sub-cooling loop 6 or 8
  • compression unit 25 is utilized to increase the pressure of feed gas stream 10 prior to entry into the liquefaction process.
  • feed gas stream 10 is passed to compression unit 25 where it is compressed to a pressure above the feed gas supply pressure or, in one or more other embodiments, to a pressure greater than about 1200 psia.
  • feed gas stream 10 is compressed to a pressure greater than or equal to about 1300 psia, or greater than or equal to about 1400 psia, or greater than or equal to about 1500 psia, or greater than or equal to about 1600 psia, or greater than or equal to about 1700 psia, or greater than or equal to about 1800 psia, or greater than or equal to about 1900 psia, or greater than or equal to about 2000 psia, or greater than or equal to about 2500 psia, or greater than or equal to about 3000 psia.
  • feed gas stream 10 is passed to cooler 33 where it is cooled prior to being passed to heat exchange area 56 . It will be appreciated that to the extent compression unit 25 is used to compress feed gas stream 10 (and, hence, side stream 11 ) to a lower pressure than that desired for compressed refrigerant stream 12 , compression unit 20 may be used to boost the pressure.
  • feed gas stream 10 provides three benefits. First, by increasing the pressure of the feed gas stream, the pressures of side streams 11 b and 11 c are also increased, with the result that the cooling performance of work expansion devices 42 and 43 is enhanced. Second, the heat transfer coefficient in the heat exchange areas is improved.
  • the process for producing LNG described herein is carried out according to any of the other embodiments describe herein wherein the feed gas is compressed to the pressures described above prior to entry into a heat exchange area.
  • the present method comprises providing supplemental cooling for the feed gas stream from a plurality of work expansion devices, each of the work expansion devices expanding a portion of the feed gas stream and thereby cooling the portion to form one or more expanded, cooled side streams, wherein each of the portions of the feed gas stream expanded in the work expansion devices is withdrawn from the feed gas stream at a different stage of feed gas stream cooling (i.e., at a different feed gas stream temperature); and cooling said feed gas stream by indirect heat exchange with said one or more expanded, cooled side streams.
  • each of the above-described portions of feed gas has a pressure, prior to expansion, greater than about 1200 psia, or greater than or equal to about 1300 psia, or greater than or equal to about 1400 psia, or greater than or equal to about 1500 psia, or greater than or equal to about 1600 psia, or greater than or equal to about 1700 psia, or greater than or equal to about 1800 psia, or greater than or equal to about 1900 psia, or greater than or equal to about 2000 psia, or greater than or equal to about 2500 psia, or greater than or equal to about 3000 psia.
  • the present method is any of the other embodiments described herein further comprising compressing the feed gas stream to any of the pressures described above to produce a pressurized feed gas stream; feeding the pressurized feed gas stream to a work expansion device, or to a plurality of work expansion devices; expanding the compressed feed gas stream through the work expansion device, or through a plurality of work expansion devices, to provide supplemental cooling for the feed gas stream.
  • a third benefit obtained by compression the feed gas stream as described above is that the cooling capacity of expander 35 is improved, with the result that expander 35 is able to even further reduce the cooling load on sub-cooling loop 8 .
  • compression unit 25 and/or expander 35 could also be advantageously added to other embodiments described herein to provide similar reductions in the cooling load on the sub-cooling loops utilized in those embodiments or other improvements in cooling, and that compression unit 25 and expander 35 may be used independently of each other in any embodiment herein.
  • the cooling capacity of expander 35 (or the work expansion devices 42 and 43 ) will be improved, even without compression of the feed stream, to the extent the feed stream is supplied at a pressure above the bubble point pressure of the LNG.
  • FIG. 5 is a schematic flow diagram of a fifth embodiment for producing LNG in accordance with the process of this invention that is similar to the embodiment shown in FIG. 4 , but utilizes yet another expansion step to provide sub-cooling.
  • sub-cooling loop 8 is not present in the embodiment shown in FIG. 5 .
  • side stream 11 d is taken from stream 10 b and passed to expansion device 105 where it is expanded and consequently cooled to form expanded stream 13 d .
  • Expansion device 105 is a work-producing expander, many types of which are readily available. Illustrative, non-limiting examples of such devices include liquid expanders and hydraulic turbines.
  • Expanded stream 13 d is passed through heat exchange areas 59 , 58 , 57 , and 56 to provide at least part of the refrigeration duty for those heat exchange areas.
  • stream 10 b is also cooled by indirect heat exchange with expanded stream 13 d , as well as by the flash vapor stream 16 .
  • the inventive process further comprises expanding at least a portion of the cooled gas stream (feed gas stream 10 ) in expander 35 before the final heat exchange step (for example, prior to heat exchange area 59 ) to produce an expanded, cooled gas stream (for example, stream 10 b ); passing a portion of said expanded, cooled gas stream to a work-producing expander; further expanding said expanded, cooled gas stream in said work-producing expander; and passing the stream emerging from said work-producing expander (for example, stream 13 d ) to a heat exchange area to further cool said expanded, cooled gas stream by indirect heat exchange in said heat exchange area.
  • expanded stream 13 d is passed to compression unit 95 where it is re-compressed and combined with the streams emerging from compression units 61 and 62 to form part of stream 14 a , which is cooled and then re-cycled to feed stream 10 as before.
  • FIG. 6 A further embodiment shown in FIG. 6 is similar to the embodiment shown in FIG. 1 and described above, except that sub-cooling loop 6 has been modified such that after exiting heat exchange area 50 , the re-compressed and cooled sub-cooling refrigerant stream is further cooled in heat exchange area 55 prior to being expanded through expander 41 .
  • This embodiment is favorable where a cooling fluid is used that does not present much condensation after expander 41 .
  • FIG. 7 depicts another embodiment in which sub-cooling loop 6 a uses a portion of feed gas 10 .
  • the portion of feed gas 10 is re-pressurized in compressor 25 and cooled in cooler 33 from 201, in the same fashion as in FIG. 4 .
  • FIG. 8 is another embodiment similar to FIG. 7 showing an alternative arrangement for the sub-cooling loop 6 .
  • an additional compressor (not shown) may be used to prevent condensation in the sub-cooling loop or to ensure adequate line pressures.
  • FIG. 9 depicts an embodiment for use with certain feed gas 10 compositions and/or pressures.
  • an expansion valve 82 or other expander e.g., a Joules-Thompson valve
  • FIG. 10 represents another embodiment showing the integration of a nitrogen rejection stage using distillation column 81 or equivalent device, for the case where nitrogen rejection is needed, based on feed gas 10 composition. This may be needed to meet the nitrogen specification of product LNG for transmission and end use.
  • FIG. 11 represents another embodiment showing the integration of a nitrogen rejection unit, where the flash vapor from the nitrogen rejection unit is used as refrigerant for the sub-cooling loop.
  • the resulting refrigerant is therefore rich in nitrogen.
  • the volume of flash vapor stream 16 is controlled to match the fuel requirements of the compression units and other equipment.
  • the temperature at state point 207 can be controlled to produce more or less flash vapor (stream 16 ) depending on the fuel requirements. Higher temperatures at state point 207 will result in the production of more flash vapor (and hence more available fuel), and vice-versa.
  • the temperature may be adjusted such that the flash vapor flow rate is higher than the fuel requirement, in which case the excess flow above the fuel flow requirement may be recycled after compression and cooling.

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