US20070218252A1 - Flooring element - Google Patents

Flooring element Download PDF

Info

Publication number
US20070218252A1
US20070218252A1 US11/682,504 US68250407A US2007218252A1 US 20070218252 A1 US20070218252 A1 US 20070218252A1 US 68250407 A US68250407 A US 68250407A US 2007218252 A1 US2007218252 A1 US 2007218252A1
Authority
US
United States
Prior art keywords
mixture
mold
particles
layer
abrasion resistant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/682,504
Inventor
Malcolm Roger Curzon Donald
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MRB HOLDINGS CORP
Original Assignee
VISUL Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by VISUL Corp filed Critical VISUL Corp
Assigned to ESF CORPORATION reassignment ESF CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: DONALD, MALCOLM ROGER CURZON
Assigned to VISUL CORPORATION reassignment VISUL CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ESF CORPORATION
Publication of US20070218252A1 publication Critical patent/US20070218252A1/en
Assigned to MRF HOLDINGS CORPORATION reassignment MRF HOLDINGS CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: VISUL CORPORATION
Assigned to MRB HOLDINGS CORPORATION reassignment MRB HOLDINGS CORPORATION CORRECTIVE ASSIGNMENT TO CORRECT THE COVER SHEET DATA FOR ASSIGNEE NAME FROM "MRF HOLDINGS CORPORATION" TO "MRB HOLDINGS CORPORATION" PREVIOUSLY RECORDED ON REEL 019913 FRAME 0091. ASSIGNOR)S) HEREBY CONFIRMS THE TRANSFER FROM VISUL CORPORATION TO MRB HOLDINGS CORPORATION. Assignors: VISUAL CORPORATION
Priority to US13/081,877 priority Critical patent/US8557152B2/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • B29C39/003Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor characterised by the choice of material
    • B29C39/006Monomers or prepolymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • B29C39/02Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • B29C39/02Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles
    • B29C39/021Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles by casting in several steps
    • B29C39/025Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor for making articles of definite length, i.e. discrete articles by casting in several steps for making multilayered articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • B29C39/22Component parts, details or accessories; Auxiliary operations
    • B29C39/42Casting under special conditions, e.g. vacuum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/58Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres
    • B29C70/64Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres the filler influencing the surface characteristics of the material, e.g. by concentrating near the surface or by incorporating in the surface by force
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C11/00Details of pavings
    • E01C11/24Methods or arrangements for preventing slipperiness or protecting against influences of the weather
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C5/00Pavings made of prefabricated single units
    • E01C5/20Pavings made of prefabricated single units made of units of plastics, e.g. concrete with plastics, linoleum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2791/00Shaping characteristics in general
    • B29C2791/004Shaping under special conditions
    • B29C2791/008Using vibrations during moulding
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372Particulate matter
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness

Definitions

  • This invention pertains to floor tiling, in general, and to tactile floor tiling, in particular.
  • Tactile floorings have an uneven surface so that they can provide information about the surroundings to those walking on them, e.g., blind and partially-sighted people.
  • tactile tiling for example, tiles with ‘blisters’ arranged on a square pattern are used on pavements at the edges of pedestrian crossings, tiles with a triangular pattern are used near the edges of railway platforms, and tiles with regularly spaced parallel ridges are used at the tops and bottoms of stairs.
  • the ‘blisters’ are about 25 mm in diameter, about 5 mm high, and spaced 67 mm apart.
  • Such tiling is highly beneficial to blind people because the blisters can be detected by both a stick sweeping the ground in front of them and through the soles of their shoes.
  • Tactile tiles may be provided in a contrasting color to that of the rest of the flooring so that sighted caregivers for blind persons and partially sighted people may be further warned of the impending hazard.
  • Tactile tiling is used both outside, e.g., in the street and public spaces, and inside, e.g., in public access areas, shopping malls, and locations particularly frequented by blind people.
  • the tiles are often cast from concrete or similar materials, but for inside use, they are usually made from polymeric materials, sometimes incorporating a degree of cushioning.
  • FIG. 1 shows a current design of polymeric tile and some problems associated with it.
  • Tile 1 consists of regularly spaced blisters 2 on a substrate 3 .
  • the upper face has a hard-wearing surface 4 .
  • tile 1 Because of the shape and pattern of the blisters 2 , tile 1 has to be cast upside down, i.e., with the blisters at the bottom of the mold, and so, lower surface 5 is the top surface in the mold.
  • the mixture from which the tile is cast contains resin, hardener, and a filler, such as sand or grit particles.
  • apparatus for and methods of making a flooring element include providing a mixture of a cross-linkable, polymerizable resin and a hardener filled with abrasion resistant particles characterized in that the abrasion-resistant particles are concentrated in the upper layer of the flooring element to give a high friction, wear resistant surface and further characterized in that a layer of abrasion resistant particles is incorporated into the base surface of the element prior to polymerization so that, after polymerization, it forms a rough backing layer integral with the flooring element, ideal for the adhesion of the element to the foundation plane to which the flooring element is to be bonded with an appropriate adhesive.
  • the flooring element is cast upside down in a mold.
  • the mold is filled with the polymerizable mixture, which is pressed into the mold.
  • the mold is vibrated to ensure complete filling and removal of air bubbles in the polymerizable mixture.
  • the vibration of the mold causes segregation of the various fillers within the resin mixture before polymerization occurs.
  • the segregation process produces a layer of abrasion resistant particles at or near the base of the mold, which becomes the wearing surface of the flooring element.
  • resilient, such as rubber, particles are included in the polymerizable mixture.
  • the resilient particles are concentrated in the upper layer of the mold, which becomes a resilient substrate of the flooring element.
  • the mold is provided with parts such that, after casting, polymerization, and removal from the mold, said parts creating areas of the flooring element which project above the plane of the wearing surface.
  • the projecting areas have the form of partial spheres.
  • the projecting areas have the form of a ridge.
  • the projecting areas have the form of parallel ridges with a groove between adjacent ridges.
  • the parts of the mold are pre-filled with a resin mixture containing a high concentration of the abrasion resistant particles before the other resin-filled mixture(s) is/are added to the mold.
  • the pre-filling resin mixture contains a photo-luminescent additive.
  • pre-manufactured items are located in the parts of the mold before the other resin-filled mixture(s) is/are added to the mold so that, after polymerization, the pre-manufactured items are bonded to the rest of the polymerized matrix.
  • the viscosity of the polymerizable mixture is adjustable so that, during vibration prior to polymerization, adequate segregation occurs due to density differences with air bubbles rising and abrasion-resistant particles sinking.
  • the viscosity of the polymerizable mixture is adjusted by controlling one or more of the temperature, proportion of resin to hardener, and/or quantity of filler(s).
  • FIG. 1 is a side elevation of a prior art type of tactile floor tile
  • FIG. 2 is a part sectional elevation of a first embodiment showing the polymerizable mixtures in a mold
  • FIG. 3 is a part sectional elevation of the filled mold, shown in FIG. 2 , after vibration and addition of the rough backing member;
  • FIG. 4 is a part sectional elevation of a second embodiment showing the polymerizable mixture filling the mold
  • FIG. 5 is a part sectional elevation of the mold, shown in FIG. 4 after vibration and addition of the rough backing member;
  • FIG. 6 is a part sectional elevation of a mold, the blister of which has been pre-filled with a resin mixture containing a high concentration of the abrasion resistant particles before the other resin-filled mixture(s) is/are added to the mold and after the settling and segregation caused by the vibrating of the mold and its contents;
  • FIG. 7 is a part sectional elevation of the floor tile, shown in FIG. 6 , after polymerization;
  • FIG. 8 is a part sectional elevation of a mold, into which an optical element has been placed before filling with the resin mixture(s) and after vibrating the mold and its contents to settle the resin mixture around the optical element and cause segregation of the fillers within the mixture(s);
  • FIG. 9 is a part sectional elevation of the floor tile shown in FIG. 8 , after polymerization;
  • FIG. 10 is a part sectional elevation of a mold having parts to form ridges in the floor tile and which parts have been pre-filled with a resin mixture containing a high concentration of the abrasion resistant particles before the other resin-filled mixture(s) is/are added to the mold and after the settling and segregation caused by the vibrating of the mold and its contents;
  • FIG. 11 is a part sectional elevation of a floor tile, such as one cast in the mold shown in FIG. 10 and showing one embodiment of the incorporation of a photo-luminescent strip;
  • FIG. 12 is a flow diagram of one embodiment of the method.
  • the first embodiment provides for the resin hardener mixture to be added to mold 10 in two separate stages.
  • the resin and hardener are mixed with a silica sand and bauxite filler to form a uniform mixture and placed as a first layer 19 in mold 10 .
  • Mold 10 is provided with concave projections 11 so that the mixture 19 therein has convex blisters 2 after polymerization.
  • first layer 19 is squeezed into the corners and blisters 11 and roughly leveled to give a surface 16 , only partly filling mold 10 .
  • a further batch of the same resin and hardener formulation is prepared, this time with a filler of resilient, or rubber, particles 15 .
  • a uniform mixture is produced and added as a second layer 20 to mold 10 on top of surface 16 of first layer 19 so that the mold is now full.
  • the particles of sand and bauxite filler 14 and the resilient particle filler 15 are uniformly distributed throughout resin mixture 13 in their respective layers 19 and 20 .
  • Mold 10 is now vibrated, primarily to settle the mixture in the mold and blisters 11 and to allow trapped air bubbles (not shown) to rise and leave the mold through surface 17 .
  • a secondary effect of the vibration is to cause the denser sand and bauxite particles to sink, thus collecting 14 A near the bottom of mold 10 , 11 . This increases the wear resistance of the surface of the tile after polymerization.
  • Another effect of the vibration is to meld the two layers of polymer mixture together in the region of the boundary 16 , which is now shown dashed 16 A to indicate this local mixing of the two layers 19 , 20 .
  • This process also causes some rubber particles 15 to be incorporated into the first layer 19 , as shown.
  • the resin surface 17 is leveled off with mold lip 12 . As the same resin and hardener is used for both layers, melding of the two layers occurs naturally.
  • the resin mixture has just started to polymerize and surface 17 is tacky.
  • a layer 18 of silica sand is placed on surface 17 so that the particles partly sink into tacky surface 17 .
  • gentle pressure may be applied, e.g., with a roller, a flat board or builder's float.
  • the mold is now placed in an oven and, in one embodiment, allowed to polymerize for three hours at 35° C. After this the tiles are removed from the molds, stacked horizontally on flat boards, and kept for 24 hours at ambient temperature. This allows them to cool naturally and the polymerization process to continue, essentially to completion. The tiles are then trimmed to size to remove any edge imperfections and packed into boxes for distribution. As previously, the boxes are kept horizontal and flat though any further polymerizing set is unlikely.
  • the formulation is:
  • Hardener e.g., Nufins Casting Resin Hardener
  • the resin is mixed at the rate of between 2.5 to 4.0 parts per 1.0 part of hardener, by weight.
  • Bauxite filler passing a 0.5 to 1.0 mm mesh screen, 10 wt. %
  • the filler mixture is gradually added to the resin mixture above until a rate of 65 to 72 wt. % is achieved, i.e., 35 to 28 wt. % resin. 1 to 2 wt. % pigment may be added in lieu of an equivalent quantity of filler. Mixing under a vacuum is not essential.
  • Equal parts of rubber particles passing a 40 mesh screen and a 26 mesh screen, are mixed together and added progressively to the above resin mixture until a rate of 10 wt. % to 90 wt. % resin is achieved.
  • a rate of 10 wt. % to 90 wt. % resin is achieved.
  • the rubber particles do not pack well, there is a much greater volume of rubber than resin and the rubber particles float on the resin.
  • mixing involves thoroughly wetting the particles and kneading the whole to distribute the particles evenly.
  • silica sand particles are sprinkled on to the tacky polymer surface to give a uniform covering. Normally, the particles partly sink into the polymer matrix and bond with the matrix. However, gentle pressure is applied, if required. Before removal from the molds and, after polymerization, the tiles are inverted and brushed gently to remove unbonded particles
  • an ultra-violet fight stabilizing agent is added, along with the fillers, to the first layer only. (The agent is very expensive and not required in the second layer.)
  • the second embodiment provides for the resin hardener mixture to be added to mold 10 in a single stage.
  • the resin and hardener are mixed as before and the silica sand, bauxite, and rubber filler added to form a single uniform mixture. From a practical point of view, it is desirable to add the less dense rubber particles first because they float and it is easier to disperse the rubber particles into a free flowing liquid than after the silica sand and bauxite mixture have been added.
  • the mixture is pressed and squeezed into the corners and blisters 11 , filled 17 to the brim, and vibrated to allow buoyant air bubbles (not shown) to rise to the surface and to allow the mixture to fill the mold 10 , 11 completely with surface 17 aligning with lip 12 .
  • the silica sand (density 7.5-2.1) and bauxite (density 3.9) particles settle 14 A to the lower part of mold 10 , 11 , through the resin (density c. 0.9) to give a denser packing 14 A at the base of the mold, and especially in the blisters, to give greater wear resistance to the tile after polymerization.
  • the denser bauxite particles settle more quickly during the vibration period and so enhance the wear resistance of the surface.
  • the rubber particles (density c. 0.9) remain distributed uniformly throughout the single layer 21 .
  • silica sand particles 18 are added to the tacky surface 17 and become an integral part of layer 17 . This is shown in FIGS. 3 and 5 with the cross symbols representing these particles passing through the surface 17 into the resin mixture 20 and 21 respectively.
  • the formulation is:
  • Resin Mixture As described above.
  • Rubber particles as described above, 3 to 10 wt %
  • the rubber and inorganic fillers are added progressively to the resin mixture, as described above, until a rate of 62 to 75 wt. % is achieved, i.e., 38 to 25 wt. % resin. 1 to 2 wt. % pigment may be added in lieu of an equivalent quantity of filler. Again, mixing under a vacuum is not essential, but the mixing process is maintained for an adequate time to ensure homogeneity.
  • the vibration process leads to segregation 14 A of the denser inorganic fillers relative to the rest of the mixture 19 , 20 and 21 .
  • the parameter affecting this segregation process is the viscosity of the bulk mixture, after adding the fillers. Raising the temperature of the resin and hardener reduces the viscosity, as does adding less of the fillers.
  • to maximize wear resistance requires a large amount of the inorganic filler and that the filler be located at, or close to, the surface of the tile, (i.e., 4 in FIG. 1 ).
  • to maximize cushioning requires the maximum quantity of rubber particles.
  • the resin, hardener, and fillers are stored in a temperature-controlled room at 20° C., together with the mixer and vibrator.
  • the whole manufacturing process is conducted in a constant temperature environment.
  • FIGS. 2 and 3 The principle of two layered manufacture has been explained ( FIGS. 2 and 3 ) and, in other embodiments, the number of layers is increased to three layers.
  • a resin/hardener mixture is prepared as usual but loaded with a higher than normal concentration of sand/bauxite filler and the resulting mixture 22 placed in the blisters 11 ( FIG. 6 ) or ridge-forming channels LLA ( FIG. 10 ).
  • An injection means such as a mastic gun (not shown), is used to place the required quantity of mix 22 in place.
  • the effects of the vibration melds the adjacent layers together at their boundary layers.
  • highly wear-resistant blisters 22 A FIG. 7
  • ridges 28 FIG. 11
  • Another embodiment is to incorporate illumination into the tiling. This is done by placing pre-formed glass “cats' eyes” 24 ( FIG. 8 ) into blisters before adding resin 21 A.
  • a blob of adhesive 27 e.g., a blob of grease or a weak adhesive (such as used on memo-attachment notes) is used to hold the cat's eye 24 in place so that the resin mixture 21 A can fill gap 25 during the vibration and thus hold the cat's eye 24 firmly after polymerization ( FIG. 9 ).
  • incident light is refracted into cat's eye 24 , reflected from rear surface 24 A and re-emitted 26 A, 26 B.
  • the lip 25 grips cat's eye 24 , as well as via the adhesion of the resin mix 21 A to the surface 24 A.
  • the cats' eyes 24 are pure glass elements or cast from a glass particle/resin mixture.
  • the glass may be plain or colored, as desired. The effect is enhanced if the tiles are illuminated by low-level, glancing lighting.
  • a still another embodiment is to incorporate a photo-luminescence substance into a concentrated filler 22 , as shown by numeral 23 ( FIGS. 8 and 10 ).
  • a photo-luminescent substance absorbs incident light and emits it after dark or if the lights failed, e.g., during a fire emergency.
  • a photo-luminescent mixture is used for one ridge 23 located between two highly wear-resistant ridges 22 to give added protection.
  • FIG. 8 and 10 a photo-luminescent mixture is used for one ridge 23 located between two highly wear-resistant ridges 22 to give added protection.
  • either a pre-formed photo-luminescent strip 23 A is incorporated into ridge 22 , e.g., using the same method as for cats' eye 24 , or a separate photo-luminescent liquid-resin mixture is injected into the appropriate channel 1 A, before resin mixtures 22 , 21 A are added.
  • Flooring elements made according to the method are an improvement over present tactile floor tile technology by optimizing the resin system and the actual location of the wear resistant and cushioning components within the tile itself.
  • the skilled person will appreciate the variations of the method of the teaching, all of which are implicit in the disclosure.
  • FIG. 12 illustrates a flow diagram of various embodiments of the method of making a flooring element tile 1 .
  • the first step 102 is to prepare a mixture of resin and hardener, followed by the step 104 of adding the filler, which is an abrasion resistant material. This combination is then added to the mold 106 as a first layer.
  • This combination is then added to the mold 122 as a second layer, after the first layer has been added to the mold 106 .
  • next step 108 is to vibrate the mold, followed by the steps 110 , 112 of leveling the top and adding particles to the top surface.
  • the next step 114 is to polymerize the tile in the mold.
  • the next step 116 is to remove the tile from the mold and temporarily store the tile flat while the tile completes curing.
  • mixture is prepared 102 , and the filler is added 104 , with the filler including both abrasion resistant material and resilient material.
  • the mold is then filled 106 with only a single layer and steps 118 , 120 , 122 for a second layer are not performed.
  • the step 124 of adding an item to the mold is performed before the first layer is added 106 to the mold.
  • the item includes pre-formed reflective items, cats' eyes 24 , and/or pre-formed photo-luminescent strip 23 A.
  • a third layer is added to the mold.
  • the flooring element is cast into a mold in two layers, the first layer comprising a mixture of a cross-linkable, polymerizable resin and a hardener filled with abrasion resistant particles and placed in the mold 106 first to form a wear-resistant surface layer and a second layer comprising a mixture of a cross-linkable, polymerizable resin and a hardener filled with rubber particles and placed in the mold 122 on top of the first layer to form a resilient substrate and a layer of abrasion resistant particles is incorporated into the base surface of the element, prior to polymerization so that, after polymerization 114 , it forms a rough backing layer integral with the flooring element, ideal for the adhesion of the element to the foundation plane to which the flooring element is to be bonded with an appropriate adhesive.
  • the mixture forming the first layer of the flooring element includes a component to stabilize the polymerized element against the effects of ultra violet light.
  • the vibration of the mold causes intermixing of the first and second resin, hardener and filler layers, so that the two layers polymerize together to form effectively a single layer with different concentrations of fillers in different parts of said single layer.
  • the flooring element is cast from a single mixture of a cross-linkable, polymerizable resin and a hardener filled with both abrasion-resistant particles and rubber particles, placed in a mold and the mold and its contents vibrated for a period of time sufficient to allow air bubbles to rise out of the mixture and for the denser abrasion-resistant particles to sink towards the bottom of the mold to form a wear resistant surface layer to the element with most of the rubber particles remaining in the bulk of the mixture to form a resilient substrate and a layer of abrasion resistant particles is incorporated into the base surface of the element, prior to polymerization, so that, after polymerization, it forms a rough backing layer integral with the flooring element, ideal for the adhesion of the element to the foundation plane to which the flooring element is to be bonded with an appropriate adhesive.
  • a resin and hardener mixture is prepared and abrasion-resistant and rubber particle fillers are progressively added to the mixture, with thorough mixing between each addition.
  • a mold is filled with the mixture, which is gently pressed into place.
  • the mold, with its mixture, is then vibrated for a period of time during which any air bubbles rise to the surface and the denser fraction of the fillers sinks towards the bottom of the mold.
  • the upper surface of the mixture is leveled off with the top of the mold and silica sand particles are sprinkled onto the tacky surface of the mixture, where the particles partly sink into the resin mixture.
  • gentle pressure may be applied to the silica particles, if they do not sink sufficiently into the resin mixture.
  • the tile After polymerization in an oven, when the silica sand particles on the surface of the mixture become firmly bonded to the polymer matrix, the tile is removed from the mold and placed on a flat, level surface for a further period of time, at ambient temperature, to allow the polymerization to proceed to completion.
  • the tiles, thus prepared, are then ready to be supplied for use.
  • Particular advantages of the tile are that it is flexible and so may be fitted on slightly uneven surfaces.
  • the rough surface of the silica particle backing is ideal for adhesive bonding to the floor foundation and the concentration of abrasion-resistant particles gives a hard-wearing surface
  • the tiles are to be used outside, stabilization against UV light is desirable, as the stabilizing agent is very expensive, it is desirable to concentrate it in the surface layer of the tile.
  • This is done by preparing the resin mixture in two parts. In the first part, only the abrasion-resistant particles and NV agent are used as fillers and this mixture is placed in the mold first and pressed down to give a first layer. In the second part, only rubber particle filler is used and this mixture added to the mold as a second layer. The effect of the vibration is both to cause the abrasion-resistant particle to sink, as before, but also to cause mixing between the two layers and give an essentially uniform matrix for polymerization.
  • partial spherical depressions are provided in the base so that flooring tiles made from the mold have raised ‘blisters’, which blind and partially sighted people can detect, either with a stick or through the soles of their feet.
  • parallel channels are provided in the base so that the tiles have raised parallel ridges, separated by grooves.
  • a resin/hardener mixture with a high concentration of abrasion resistant particles is used to fill the depressions before the normal resin mixture(s) is/are added.
  • the vibration causes a degree of mixing at the interface between any two adjacent mixture layers so that there are no plane(s) of weakness between the adjacent layers.
  • pre-formed reflective items are placed in all or some of the depressions to catch and reflect incident light, as “cats' eyes” do on roads. This further emphasizes the presence of the tiling (and the hazard to which it refers). The effect is enhanced if the tile is illuminated by low level, glancing light.
  • the tiles 1 have an upper surface that includes abrasion resistant material and the bottom of the tiles 1 include a surface that is rough and suitable for adhesively attaching to a substrate.
  • the tiles 1 also include, in one embodiment, a resilient filler disposed between the upper and bottom surfaces of the tile 1 so as to provide a cushioning effect for the tile 1 .
  • the method includes providing a mixture of a cross-linkable, polymerizable resin and a hardener filled with abrasion resistant particles characterized in that the abrasion-resistant particles are concentrated in the upper layer of the flooring element to give a high friction, wear resistant surface and further characterized in that a layer of abrasion resistant particles is incorporated into the base surface of the element, prior to polymerization so that, after polymerization, it forms a rough backing layer integral with the flooring element, ideal for the adhesion of the element to the foundation plane to which the flooring element is to be bonded with an appropriate adhesive.
  • rubber particles are also included in the resin-filler mixture to provide cushioning in the substrate of the tile.
  • the resin-filler mixture is applied to the mold either in a single layer or in multiple layers.
  • a feature of the method is that the viscosity of the resin mixture is carefully controlled so that, during the period of vibration to settle the mixture fully into the mold, segregation of the filler(s) occurs within the resin mixture.
  • the denser abrasion resistant particles sink through the resin mixture towards the base of the mold, which is the wearing surface of the tile, after polymerization and removal from the mold.
  • the mold may be provided with parts to create areas of the tile, which project above the plane of the surface of the tile. Means to increase the wear resistance of the projecting areas and to incorporate means of illuminating parts of the tiles are taught.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Floor Finish (AREA)

Abstract

An apparatus for and a method of making a flooring element. The flooring element is a tile formed of a polymer with embedded filler material. The filler material includes abrasive particles adjacent the top surface and a resilient or rubber-like material. The bottom surface of the tile includes a plurality of particles embedded in and extending from the bottom, which enables the tile to be securely adhered to a substrate. One embodiment of a method of making the tile includes adding a first layer containing a filler material to a mold, vibrating the mold to cause the heavier filler material to sink, applying a plurality of particles to the top of the polymer mixture in the mold, and polymerizing the mixture in the mold. In another embodiment, a second layer including resilient particles is added to the mold above the first layer before the mold is vibrated.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • This application claims the benefit of Application Number 0605413.4, filed Mar. 17, 2006, in the United Kingdom, hereby incorporated by reference. STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT
  • Not Applicable
  • BACKGROUND OF THE INVENTION
  • 1. Field of Invention
  • This invention pertains to floor tiling, in general, and to tactile floor tiling, in particular. Tactile floorings have an uneven surface so that they can provide information about the surroundings to those walking on them, e.g., blind and partially-sighted people.
  • 2. Description of the Related Art
  • There is an international standard for the designs and uses of tactile tiling, for example, tiles with ‘blisters’ arranged on a square pattern are used on pavements at the edges of pedestrian crossings, tiles with a triangular pattern are used near the edges of railway platforms, and tiles with regularly spaced parallel ridges are used at the tops and bottoms of stairs. In this context, the ‘blisters’ are about 25 mm in diameter, about 5 mm high, and spaced 67 mm apart. Such tiling is highly beneficial to blind people because the blisters can be detected by both a stick sweeping the ground in front of them and through the soles of their shoes. Tactile tiles may be provided in a contrasting color to that of the rest of the flooring so that sighted caregivers for blind persons and partially sighted people may be further warned of the impending hazard.
  • Tactile tiling is used both outside, e.g., in the street and public spaces, and inside, e.g., in public access areas, shopping malls, and locations particularly frequented by blind people. For outside use, the tiles are often cast from concrete or similar materials, but for inside use, they are usually made from polymeric materials, sometimes incorporating a degree of cushioning.
  • FIG. 1 shows a current design of polymeric tile and some problems associated with it. Tile 1 consists of regularly spaced blisters 2 on a substrate 3. The upper face has a hard-wearing surface 4. Because of the shape and pattern of the blisters 2, tile 1 has to be cast upside down, i.e., with the blisters at the bottom of the mold, and so, lower surface 5 is the top surface in the mold. The mixture from which the tile is cast contains resin, hardener, and a filler, such as sand or grit particles.
  • In the manufacturing process it is normal to fill the mold and then vibrate it to release trapped air bubbles and settle the mixture fully down into the mold. This vibrating process also causes the filler particles to settle in the resin mixture and leave a smooth surface at the top of the mold. Thus, after polymerization and removal from the mold, this smooth surface becomes lower surface 5 of tile 1. When the flooring is fitted, it is normal to bond tiles 1 adhesively to a wood or concrete foundation. A smooth surface 5 is not ideal for adhesive bonding. It is possible to roughen surface 5, e.g., with sandpaper, but this is not really practicable when working to deadlines. The result is that, in use, tiles frequently become wholly, or partly, unbonded and detached from the foundation.
  • Another problem that arises, occurs because the polymerization process continues after the tiles have been removed from the mold. If tiles 1 are not stored perfectly flat, e.g., they are placed on a slightly uneven surface or, perhaps, overlapping the edge of a pallet, it is possible that a ‘kink’, resulting in a ‘permanent set’, may occur. This is illustrated as displacement 6 in FIG. 1. Though the tile 1 may be ‘bent straight’ by the person laying the floor and then adhesively bonded to the substrate, the distortion 6 remains as an internal tensile stress. It is known that adhesive bonds are weak in tension and, especially when the adhesive is bonded to a smooth surface 5, failure of the bond is a high probability. Adhesive failure, whether due to the smooth surface 5, or exacerbated by a kink 6, is a common problem with the fixing of this form of tile.
  • There is thus a need for a form of tiling with a hard wearing surface and cushioned substrate, which can be bonded firmly to the flooring foundation and remains firmly bonded for the lifetime of the tile.
  • BRIEF SUMMARY OF THE INVENTION
  • According to various embodiments, apparatus for and methods of making a flooring element are provided. The methods include providing a mixture of a cross-linkable, polymerizable resin and a hardener filled with abrasion resistant particles characterized in that the abrasion-resistant particles are concentrated in the upper layer of the flooring element to give a high friction, wear resistant surface and further characterized in that a layer of abrasion resistant particles is incorporated into the base surface of the element prior to polymerization so that, after polymerization, it forms a rough backing layer integral with the flooring element, ideal for the adhesion of the element to the foundation plane to which the flooring element is to be bonded with an appropriate adhesive.
  • According to a first variation, the flooring element is cast upside down in a mold.
  • According to a second variation, the mold is filled with the polymerizable mixture, which is pressed into the mold.
  • According to a third variation, the mold is vibrated to ensure complete filling and removal of air bubbles in the polymerizable mixture.
  • According to a fourth variation, the vibration of the mold causes segregation of the various fillers within the resin mixture before polymerization occurs.
  • According to a fifth variation, the segregation process produces a layer of abrasion resistant particles at or near the base of the mold, which becomes the wearing surface of the flooring element.
  • According to a sixth variation, resilient, such as rubber, particles are included in the polymerizable mixture.
  • According to a seventh variation, the resilient particles are concentrated in the upper layer of the mold, which becomes a resilient substrate of the flooring element.
  • According to an eighth variation, the mold is provided with parts such that, after casting, polymerization, and removal from the mold, said parts creating areas of the flooring element which project above the plane of the wearing surface.
  • According to a ninth variation, the projecting areas have the form of partial spheres.
  • According to a tenth variation, the projecting areas have the form of a ridge.
  • According to an eleventh variation, the projecting areas have the form of parallel ridges with a groove between adjacent ridges.
  • According to a twelfth variation, the parts of the mold are pre-filled with a resin mixture containing a high concentration of the abrasion resistant particles before the other resin-filled mixture(s) is/are added to the mold.
  • According to a thirteenth variation, the pre-filling resin mixture contains a photo-luminescent additive.
  • According to a fourteenth variation, pre-manufactured items are located in the parts of the mold before the other resin-filled mixture(s) is/are added to the mold so that, after polymerization, the pre-manufactured items are bonded to the rest of the polymerized matrix.
  • According to a fifteenth variation, the viscosity of the polymerizable mixture is adjustable so that, during vibration prior to polymerization, adequate segregation occurs due to density differences with air bubbles rising and abrasion-resistant particles sinking.
  • According to a sixteenth variation of the method, the viscosity of the polymerizable mixture is adjusted by controlling one or more of the temperature, proportion of resin to hardener, and/or quantity of filler(s).
  • BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
  • The above-mentioned features of the invention will become more clearly understood from the following detailed description of the invention read together with the drawings in which:
  • FIG. 1 is a side elevation of a prior art type of tactile floor tile;
  • FIG. 2 is a part sectional elevation of a first embodiment showing the polymerizable mixtures in a mold;
  • FIG. 3 is a part sectional elevation of the filled mold, shown in FIG. 2, after vibration and addition of the rough backing member;
  • FIG. 4 is a part sectional elevation of a second embodiment showing the polymerizable mixture filling the mold;
  • FIG. 5 is a part sectional elevation of the mold, shown in FIG. 4 after vibration and addition of the rough backing member;
  • FIG. 6 is a part sectional elevation of a mold, the blister of which has been pre-filled with a resin mixture containing a high concentration of the abrasion resistant particles before the other resin-filled mixture(s) is/are added to the mold and after the settling and segregation caused by the vibrating of the mold and its contents;
  • FIG. 7 is a part sectional elevation of the floor tile, shown in FIG. 6, after polymerization;
  • FIG. 8 is a part sectional elevation of a mold, into which an optical element has been placed before filling with the resin mixture(s) and after vibrating the mold and its contents to settle the resin mixture around the optical element and cause segregation of the fillers within the mixture(s);
  • FIG. 9 is a part sectional elevation of the floor tile shown in FIG. 8, after polymerization;
  • FIG. 10 is a part sectional elevation of a mold having parts to form ridges in the floor tile and which parts have been pre-filled with a resin mixture containing a high concentration of the abrasion resistant particles before the other resin-filled mixture(s) is/are added to the mold and after the settling and segregation caused by the vibrating of the mold and its contents;
  • FIG. 11 is a part sectional elevation of a floor tile, such as one cast in the mold shown in FIG. 10 and showing one embodiment of the incorporation of a photo-luminescent strip; and
  • FIG. 12 is a flow diagram of one embodiment of the method.
  • DETAILED DESCRIPTION OF THE INVENTION
  • In the following description, the same reference number is used for the same component or for different components fulfilling an identical function.
  • Referring to FIGS. 2 and 3, the first embodiment provides for the resin hardener mixture to be added to mold 10 in two separate stages. In the first stage the resin and hardener are mixed with a silica sand and bauxite filler to form a uniform mixture and placed as a first layer 19 in mold 10. Mold 10 is provided with concave projections 11 so that the mixture 19 therein has convex blisters 2 after polymerization. As shown, first layer 19 is squeezed into the corners and blisters 11 and roughly leveled to give a surface 16, only partly filling mold 10.
  • In the second stage, a further batch of the same resin and hardener formulation is prepared, this time with a filler of resilient, or rubber, particles 15. As before, a uniform mixture is produced and added as a second layer 20 to mold 10 on top of surface 16 of first layer 19 so that the mold is now full. As shown in FIG. 2 the particles of sand and bauxite filler 14 and the resilient particle filler 15 are uniformly distributed throughout resin mixture 13 in their respective layers 19 and 20.
  • Mold 10 is now vibrated, primarily to settle the mixture in the mold and blisters 11 and to allow trapped air bubbles (not shown) to rise and leave the mold through surface 17. A secondary effect of the vibration is to cause the denser sand and bauxite particles to sink, thus collecting 14A near the bottom of mold 10, 11. This increases the wear resistance of the surface of the tile after polymerization.
  • Another effect of the vibration is to meld the two layers of polymer mixture together in the region of the boundary 16, which is now shown dashed 16A to indicate this local mixing of the two layers 19, 20. This process also causes some rubber particles 15 to be incorporated into the first layer 19, as shown. After vibrating, the resin surface 17 is leveled off with mold lip 12. As the same resin and hardener is used for both layers, melding of the two layers occurs naturally.
  • At this point in the process, the resin mixture has just started to polymerize and surface 17 is tacky. With the surface in this condition, a layer 18 of silica sand is placed on surface 17 so that the particles partly sink into tacky surface 17. If the silica particles do not sink sufficiently into the surface of the tacky resin, gentle pressure may be applied, e.g., with a roller, a flat board or builder's float. The mold is now placed in an oven and, in one embodiment, allowed to polymerize for three hours at 35° C. After this the tiles are removed from the molds, stacked horizontally on flat boards, and kept for 24 hours at ambient temperature. This allows them to cool naturally and the polymerization process to continue, essentially to completion. The tiles are then trimmed to size to remove any edge imperfections and packed into boxes for distribution. As previously, the boxes are kept horizontal and flat though any further polymerizing set is unlikely.
  • In one application of the first embodiment of the process, the formulation is:
  • Resin Mixture
  • Resin, e.g., Nufins P U Casting Resin
  • Hardener, e.g., Nufins Casting Resin Hardener
  • The resin is mixed at the rate of between 2.5 to 4.0 parts per 1.0 part of hardener, by weight.
  • First Layer
  • Silica sand filler, passing a 0.5 to 1.0 mm mesh screen, 90 wt. %
  • Bauxite filler, passing a 0.5 to 1.0 mm mesh screen, 10 wt. %
  • The filler mixture is gradually added to the resin mixture above until a rate of 65 to 72 wt. % is achieved, i.e., 35 to 28 wt. % resin. 1 to 2 wt. % pigment may be added in lieu of an equivalent quantity of filler. Mixing under a vacuum is not essential.
  • Second Layer
  • Equal parts of rubber particles, passing a 40 mesh screen and a 26 mesh screen, are mixed together and added progressively to the above resin mixture until a rate of 10 wt. % to 90 wt. % resin is achieved. As the rubber particles do not pack well, there is a much greater volume of rubber than resin and the rubber particles float on the resin. Thus, mixing involves thoroughly wetting the particles and kneading the whole to distribute the particles evenly.
  • Vibration: 15 to 60 seconds, depending on the viscosity of the resin/hardener mixture
  • Backing Layer
  • 0.2 to 0.7 mm silica sand particles are sprinkled on to the tacky polymer surface to give a uniform covering. Normally, the particles partly sink into the polymer matrix and bond with the matrix. However, gentle pressure is applied, if required. Before removal from the molds and, after polymerization, the tiles are inverted and brushed gently to remove unbonded particles
  • Polymerization
  • 3 hours at 35° C. in an oven, followed by removal from the molds and 24 hours at room temperature, with each tile horizontally on a flat board. The resin system taught is fully cross-linked throughout the matrix but is also thermoplastic, which assists the fitters when laying the tiles.
  • In the embodiment where the tiles are for outdoor applications, an ultra-violet fight stabilizing agent is added, along with the fillers, to the first layer only. (The agent is very expensive and not required in the second layer.)
  • Referring to FIGS. 4 and 5, the second embodiment provides for the resin hardener mixture to be added to mold 10 in a single stage. The resin and hardener are mixed as before and the silica sand, bauxite, and rubber filler added to form a single uniform mixture. From a practical point of view, it is desirable to add the less dense rubber particles first because they float and it is easier to disperse the rubber particles into a free flowing liquid than after the silica sand and bauxite mixture have been added.
  • As before, the mixture is pressed and squeezed into the corners and blisters 11, filled 17 to the brim, and vibrated to allow buoyant air bubbles (not shown) to rise to the surface and to allow the mixture to fill the mold 10, 11 completely with surface 17 aligning with lip 12. During the vibration, as explained previously, the silica sand (density 7.5-2.1) and bauxite (density 3.9) particles settle 14A to the lower part of mold 10, 11, through the resin (density c. 0.9) to give a denser packing 14A at the base of the mold, and especially in the blisters, to give greater wear resistance to the tile after polymerization. Though more expensive, the denser bauxite particles settle more quickly during the vibration period and so enhance the wear resistance of the surface. In this case, the rubber particles (density c. 0.9) remain distributed uniformly throughout the single layer 21.
  • Close examination of the tile after polymerisation shows that the sand and bauxite particles are often surrounded by a layer of the smaller rubber particles, which provides an excellent bond for the sand and bauxite, i.e., it promotes the wear resistance of the tile surface 4.
  • As before, silica sand particles 18 are added to the tacky surface 17 and become an integral part of layer 17. This is shown in FIGS. 3 and 5 with the cross symbols representing these particles passing through the surface 17 into the resin mixture 20 and 21 respectively.
  • In an application of the second embodiment of the process, the formulation is:
  • Resin Mixture: As described above.
  • Fillers
  • Silica sand and bauxite filler mixture as above, 60 to 70 wt. %
  • Rubber particles, as described above, 3 to 10 wt %
  • The rubber and inorganic fillers are added progressively to the resin mixture, as described above, until a rate of 62 to 75 wt. % is achieved, i.e., 38 to 25 wt. % resin. 1 to 2 wt. % pigment may be added in lieu of an equivalent quantity of filler. Again, mixing under a vacuum is not essential, but the mixing process is maintained for an adequate time to ensure homogeneity.
  • Vibration, Backing layer, and Polymerization: As described above.
  • As shown in FIGS. 3 and 5, it is a feature of the method that the vibration process leads to segregation 14A of the denser inorganic fillers relative to the rest of the mixture 19, 20 and 21. The parameter affecting this segregation process is the viscosity of the bulk mixture, after adding the fillers. Raising the temperature of the resin and hardener reduces the viscosity, as does adding less of the fillers. However, to maximize wear resistance requires a large amount of the inorganic filler and that the filler be located at, or close to, the surface of the tile, (i.e., 4 in FIG. 1). Similarly, to maximize cushioning requires the maximum quantity of rubber particles. Thus, there are conflicting requirements and the formulation range given allows the skilled person to select an appropriate balance for any particular application.
  • Increasing the ratio of resin to hardener, i.e., reducing the amount of hardener for a given quantity of resin, slows down the rate of polymerization. As the polymerization increases the viscosity, reducing the rate of polymerization allows the segregating effect of the vibration to become relatively more pronounced. This feature is implicit in the recommended resin mixture rate of between 2.5 to 4.0 parts per 1.0 part of hardener, by weight.
  • In one embodiment of the method, the resin, hardener, and fillers are stored in a temperature-controlled room at 20° C., together with the mixer and vibrator. Thus, the whole manufacturing process is conducted in a constant temperature environment.
  • It is also noted that, in the single layer mixture 21, some of the inorganic particles e g. those numbered 14 in FIG. 4 have a greater distance to settle to reach zone 14A, than ones in the lower part of mold 10. Thus, for the single layer application 21 (FIGS. 4 and 5), either a lower viscosity and/or a longer vibration time is required. However, the polymerization process is continuing all the time and vibration generates heat in the mixture, which accelerates the polymerization. This emphasizes the importance of the initial viscosity of the resin-hardener mixture. Typical vibration times are 15-60 seconds for both the two layer system (FIGS. 2 and 3) and the single layer system (FIGS. 4 and 5).
  • Having explained the method and its application to the manufacture of flooring tiles, specific developments of the principle will now be taught.
  • The principle of two layered manufacture has been explained (FIGS. 2 and 3) and, in other embodiments, the number of layers is increased to three layers. In such a case, a resin/hardener mixture is prepared as usual but loaded with a higher than normal concentration of sand/bauxite filler and the resulting mixture 22 placed in the blisters 11 (FIG. 6) or ridge-forming channels LLA (FIG. 10). An injection means, such as a mastic gun (not shown), is used to place the required quantity of mix 22 in place. After filling molds 10 or LOA with one or two additional layers, as taught above, the effects of the vibration melds the adjacent layers together at their boundary layers. After polymerization, highly wear-resistant blisters 22A (FIG. 7) or ridges 28 (FIG. 11) are created.
  • Another embodiment is to incorporate illumination into the tiling. This is done by placing pre-formed glass “cats' eyes” 24 (FIG. 8) into blisters before adding resin 21A. In this embodiment, a blob of adhesive 27, e.g., a blob of grease or a weak adhesive (such as used on memo-attachment notes) is used to hold the cat's eye 24 in place so that the resin mixture 21A can fill gap 25 during the vibration and thus hold the cat's eye 24 firmly after polymerization (FIG. 9). As shown 26A, 26B, incident light is refracted into cat's eye 24, reflected from rear surface 24A and re-emitted 26A, 26B. As shown, the lip 25 grips cat's eye 24, as well as via the adhesion of the resin mix 21A to the surface 24A. In various embodiments, the cats' eyes 24 are pure glass elements or cast from a glass particle/resin mixture. The glass may be plain or colored, as desired. The effect is enhanced if the tiles are illuminated by low-level, glancing lighting.
  • A still another embodiment is to incorporate a photo-luminescence substance into a concentrated filler 22, as shown by numeral 23 (FIGS. 8 and 10). Such a substance absorbs incident light and emits it after dark or if the lights failed, e.g., during a fire emergency. In FIG. 10, a photo-luminescent mixture is used for one ridge 23 located between two highly wear-resistant ridges 22 to give added protection. In FIG. 11, either a pre-formed photo-luminescent strip 23A is incorporated into ridge 22, e.g., using the same method as for cats' eye 24, or a separate photo-luminescent liquid-resin mixture is injected into the appropriate channel 1A, before resin mixtures 22, 21A are added.
  • Flooring elements made according to the method are an improvement over present tactile floor tile technology by optimizing the resin system and the actual location of the wear resistant and cushioning components within the tile itself. The skilled person will appreciate the variations of the method of the teaching, all of which are implicit in the disclosure.
  • FIG. 12 illustrates a flow diagram of various embodiments of the method of making a flooring element tile 1. In the first embodiment, the first step 102 is to prepare a mixture of resin and hardener, followed by the step 104 of adding the filler, which is an abrasion resistant material. This combination is then added to the mold 106 as a first layer. Along a parallel path, a step 118 of preparing a mixture of resin and hardener, followed by the step 104 of adding the filler, which is a resilient material, such as rubber or a rubber-like material. This combination is then added to the mold 122 as a second layer, after the first layer has been added to the mold 106. After the mold is filled, the next step 108 is to vibrate the mold, followed by the steps 110, 112 of leveling the top and adding particles to the top surface. The next step 114 is to polymerize the tile in the mold. After polymerization, the next step 116 is to remove the tile from the mold and temporarily store the tile flat while the tile completes curing.
  • In a second embodiment, mixture is prepared 102, and the filler is added 104, with the filler including both abrasion resistant material and resilient material. The mold is then filled 106 with only a single layer and steps 118, 120, 122 for a second layer are not performed.
  • In a third embodiment, before the first layer is added 106 to the mold, the step 124 of adding an item to the mold is performed. The item includes pre-formed reflective items, cats' eyes 24, and/or pre-formed photo-luminescent strip 23A. In other embodiments, a third layer is added to the mold.
  • According to a first embodiment of the method, the flooring element is cast into a mold in two layers, the first layer comprising a mixture of a cross-linkable, polymerizable resin and a hardener filled with abrasion resistant particles and placed in the mold 106 first to form a wear-resistant surface layer and a second layer comprising a mixture of a cross-linkable, polymerizable resin and a hardener filled with rubber particles and placed in the mold 122 on top of the first layer to form a resilient substrate and a layer of abrasion resistant particles is incorporated into the base surface of the element, prior to polymerization so that, after polymerization 114, it forms a rough backing layer integral with the flooring element, ideal for the adhesion of the element to the foundation plane to which the flooring element is to be bonded with an appropriate adhesive.
  • According to first variation of the first embodiment of the method, the mixture forming the first layer of the flooring element includes a component to stabilize the polymerized element against the effects of ultra violet light.
  • According to second variation of the first embodiment of the method, the vibration of the mold causes intermixing of the first and second resin, hardener and filler layers, so that the two layers polymerize together to form effectively a single layer with different concentrations of fillers in different parts of said single layer.
  • According to a second embodiment of the method, the flooring element is cast from a single mixture of a cross-linkable, polymerizable resin and a hardener filled with both abrasion-resistant particles and rubber particles, placed in a mold and the mold and its contents vibrated for a period of time sufficient to allow air bubbles to rise out of the mixture and for the denser abrasion-resistant particles to sink towards the bottom of the mold to form a wear resistant surface layer to the element with most of the rubber particles remaining in the bulk of the mixture to form a resilient substrate and a layer of abrasion resistant particles is incorporated into the base surface of the element, prior to polymerization, so that, after polymerization, it forms a rough backing layer integral with the flooring element, ideal for the adhesion of the element to the foundation plane to which the flooring element is to be bonded with an appropriate adhesive.
  • In one such embodiment of the method to produce a floor tile, a resin and hardener mixture is prepared and abrasion-resistant and rubber particle fillers are progressively added to the mixture, with thorough mixing between each addition. When the full quantity of fillers has been added, a mold is filled with the mixture, which is gently pressed into place. The mold, with its mixture, is then vibrated for a period of time during which any air bubbles rise to the surface and the denser fraction of the fillers sinks towards the bottom of the mold. This segregation of the denser, abrasion-resistant fillers to the bottom of the mixture in the mold, which becomes the hard-wearing surface of the flooring element, is a feature.
  • After the mold has been vibrated for the required period of time, the upper surface of the mixture is leveled off with the top of the mold and silica sand particles are sprinkled onto the tacky surface of the mixture, where the particles partly sink into the resin mixture. Gentle pressure may be applied to the silica particles, if they do not sink sufficiently into the resin mixture.
  • After polymerization in an oven, when the silica sand particles on the surface of the mixture become firmly bonded to the polymer matrix, the tile is removed from the mold and placed on a flat, level surface for a further period of time, at ambient temperature, to allow the polymerization to proceed to completion. The tiles, thus prepared, are then ready to be supplied for use. Particular advantages of the tile are that it is flexible and so may be fitted on slightly uneven surfaces. The rough surface of the silica particle backing is ideal for adhesive bonding to the floor foundation and the concentration of abrasion-resistant particles gives a hard-wearing surface,
  • If the tiles are to be used outside, stabilization against UV light is desirable, as the stabilizing agent is very expensive, it is desirable to concentrate it in the surface layer of the tile. This is done by preparing the resin mixture in two parts. In the first part, only the abrasion-resistant particles and NV agent are used as fillers and this mixture is placed in the mold first and pressed down to give a first layer. In the second part, only rubber particle filler is used and this mixture added to the mold as a second layer. The effect of the vibration is both to cause the abrasion-resistant particle to sink, as before, but also to cause mixing between the two layers and give an essentially uniform matrix for polymerization.
  • In one embodiment of a mold, partial spherical depressions are provided in the base so that flooring tiles made from the mold have raised ‘blisters’, which blind and partially sighted people can detect, either with a stick or through the soles of their feet. In another embodiment of a mold, parallel channels are provided in the base so that the tiles have raised parallel ridges, separated by grooves.
  • In one application of the molds of these designs, a resin/hardener mixture with a high concentration of abrasion resistant particles is used to fill the depressions before the normal resin mixture(s) is/are added. The vibration causes a degree of mixing at the interface between any two adjacent mixture layers so that there are no plane(s) of weakness between the adjacent layers. An advantage of this is that the raised parts, which are most prone to wear, are also the most wear-resistant. If a photo-luminescent additive is incorporated into the mix for the raised parts, it absorbs light and re-emits it, e.g., after dusk or during a fire alert.
  • In a further embodiment, pre-formed reflective items are placed in all or some of the depressions to catch and reflect incident light, as “cats' eyes” do on roads. This further emphasizes the presence of the tiling (and the hazard to which it refers). The effect is enhanced if the tile is illuminated by low level, glancing light.
  • From the foregoing description, it will be recognized by those skilled in the art that an apparatus for tactile flooring elements and a method of making tactile flooring elements such as tiles has been provided. The tiles 1 have an upper surface that includes abrasion resistant material and the bottom of the tiles 1 include a surface that is rough and suitable for adhesively attaching to a substrate. The tiles 1 also include, in one embodiment, a resilient filler disposed between the upper and bottom surfaces of the tile 1 so as to provide a cushioning effect for the tile 1.
  • The method includes providing a mixture of a cross-linkable, polymerizable resin and a hardener filled with abrasion resistant particles characterized in that the abrasion-resistant particles are concentrated in the upper layer of the flooring element to give a high friction, wear resistant surface and further characterized in that a layer of abrasion resistant particles is incorporated into the base surface of the element, prior to polymerization so that, after polymerization, it forms a rough backing layer integral with the flooring element, ideal for the adhesion of the element to the foundation plane to which the flooring element is to be bonded with an appropriate adhesive.
  • In one embodiment, rubber particles are also included in the resin-filler mixture to provide cushioning in the substrate of the tile. The resin-filler mixture is applied to the mold either in a single layer or in multiple layers.
  • A feature of the method is that the viscosity of the resin mixture is carefully controlled so that, during the period of vibration to settle the mixture fully into the mold, segregation of the filler(s) occurs within the resin mixture. The denser abrasion resistant particles sink through the resin mixture towards the base of the mold, which is the wearing surface of the tile, after polymerization and removal from the mold. The mold may be provided with parts to create areas of the tile, which project above the plane of the surface of the tile. Means to increase the wear resistance of the projecting areas and to incorporate means of illuminating parts of the tiles are taught.
  • While the present invention has been illustrated by description of several embodiments and while the illustrative embodiments have been described in considerable detail, it is not the intention of the applicant to restrict or in any way limit the scope of the appended claims to such detail. Additional advantages and modifications will readily appear to those skilled in the art. The invention in its broader aspects is therefore not limited to the specific details, representative apparatus and methods, and illustrative examples shown and described. Accordingly, departures may be made from such details without departing from the spirit or scope of applicant's general inventive concept.

Claims (38)

1. A flooring element comprising:
a tile having a top surface and a bottom surface, said bottom surface being substantially planar, said tile formed as a single piece of a polymer having a first concentration of a plurality of first particles and a second concentration of said plurality of first particles, said plurality of first particles including a plurality of abrasion resistant particles, said first concentration greater than said second concentration, said first concentration proximate said top surface of said tile and said second concentration proximate said bottom surface; and
a plurality of second particles embedded in and extending from said bottom surface of said tile.
2. The flooring element of claim 1 wherein said tile includes a plurality of resilient material pieces embedded in said polymer.
3. The flooring element of claim 1 wherein selected portions of said top surface of said tile includes a photo-luminescent material.
4. The flooring element of claim 1 wherein said top surface of said tile includes a plurality of protrusions extending away from said bottom surface, said plurality of protrusions selected from a group including a plurality of blisters integral with said tile, a plurality of pre-formed reflective items embedded in said polymer, and a plurality of ridges integral with said tile.
5. The flooring element of claim 1 wherein said top surface of said tile includes a component to stabilize said top surface against ultra-violet light.
6. A flooring element comprising:
a mixture of a polymerizable resin, a hardener, and a filler material, said filler material including abrasion resistant particles, said flooring element having a thickness defining at least a first and a second region, wherein said first region has a concentration of said abrasion resistant particles that is greater than that of said second region.
7. The flooring element of claim 6 further including an upper surface and a lower surface, and wherein said first region is provided at the upper surface.
8. The flooring element of claim 7 further including a third region provided at said lower surface, wherein said third region has a concentration of said abrasion resistant particles that is greater than that of said second region.
9. The flooring element of claim 6 wherein said flooring element is a tactile tile.
10. The flooring element of claim 6 wherein said filler material comprises a first set of abrasion resistant particles and a second set of abrasion resistant particles, the first set of abrasion resistant particles having a density that is higher than that of the second set.
11. The flooring element of claim 10 wherein said first set of abrasion resistant particles includes one or both of sand and bauxite.
12. The flooring element of claim 10 wherein said second set of abrasion resistant particles includes a resilient material.
13. The flooring element of claim 6 wherein said mixture includes a photo-luminescent additive.
14. The flooring element of claim 6 wherein said mixture includes a component to stabilize said first region against the effects of ultra violet light.
15. A method of making a flooring element including a mixture of a polymerizable resin, a hardener and a filler material, the filler material including abrasion resistant particles, the method comprising the steps of:
a) providing a first layer of a mixture in a mold prior to polymerization of the mixture;
b) treating said mixture so that there is movement of the abrasion resistant particles to define at least a first and a second region of said mixture, wherein said first region has a concentration of abrasion resistant particles which is greater than that of said second region; and
c) polymerizing said first layer.
16. The method of claim 15 wherein said step b) of treating said mixture includes vibrating said mixture.
17. The method of claim 15 wherein the filler material includes a first set of abrasion resistant particles having a density that is higher than the density of at least the polymerizable resin such that said first set of abrasion resistant particles moves to a lower portion of a volume of said mixture during treatment of said mixture to define said first region.
18. The method of claim 17 wherein said first set of abrasion resistant particles includes one or both of sand and bauxite.
19. The method of claim 17 wherein the flooring element is formed upside down in the mold such that said first region is adjacent an upper surface of the flooring element, said upper surface configured to be tread upon.
20. The method of claim 19 further including the step of adding a third set of abrasion resistant particles to said mold during polymerization to define a third region of said mixture, said third region having a concentration of said abrasion resistant particles that is greater than that of said second region.
21. The method of claim 17 wherein the filler material includes a second set of abrasion resistant particles, said first set having a density that is higher than that of said second set.
22. The method of claim 21 further including the step of providing a second layer of said mixture in the mold prior to step c) of polymerizing said mixture, said second layer including said second set of abrasion resistant particles, said step c) of polymerizing including polymerizing said second layer.
23. The method of claim 22 further including the step of vibrating said mold to cause intermixing of the first and second layers.
24. The method of claim 21 wherein said second set of abrasion resistant particles includes a resilient material.
25. The method of claim 15 further including the step of providing at least one cavity at the mold to create at least one protrusion of the flooring element.
26. The method of claim 15 further including the step of pressing said mixture within said mold.
27. The method of claim 15 further including the step of adding a photo-luminescent additive to said mixture.
28. The method of claim 15 wherein the viscosity of said mixture is adjusted.
29. The method of claim 15 further including the step of adding to said mixture a component to stabilize said first layer against the effects of ultra violet light.
30. A method of making a flooring element, said method comprising the steps of:
a) adding a first layer to a mold, said first layer including a resin, a hardener, and a plurality of first particles, said mold having a shallow and substantially planar cavity configured to receive said first layer, said mold having a bottom that corresponds to a top of said flooring element, said plurality of first particles including abrasion resistant material;
b) vibrating said mold until a substantial portion of said plurality of first particles are located adjacent said bottom of said mold;
c) adding a plurality of second particles to a top surface of a mixture in said mold, said mixture including said first layer, said plurality of second particles being partially embedded in said top surface and extending from said top surface; and
d) polymerizing said mixture in said mold.
31. The method of claim 30 further including, after said step d) of polymerizing, a step e) of removing said mixture from said mold and a step f) of storing said mixture on a flat horizontal surface for a specified time.
32. The method of claim 30 wherein said first layer includes a plurality of resilient particles.
33. The method of claim 30 further including a step al) of adding a second layer to said mold after said step a), said second layer including a resin, a hardener, and a plurality of resilient particles, said mixture including said second layer.
34. The method of claim 30 further including a step of adjusting a viscosity of said first layer before said step b) of vibrating.
35. The method of claim 30 further including, before said step a) of adding said first layer, a step of adding a pre-formed reflective item to said mold.
36. The method of claim 30 further including a step of adjusting a viscosity of said first layer before said step b) of vibrating, said viscosity adjusted by controlling one or both of a temperature of said first layer and a ration of said resin to said hardener.
37. The method of claim 30 wherein said mold includes a bottom having a plurality of depressions configured to form a plurality of features selected from a plurality of blisters and a plurality of ridges.
38. The method of claim 30 wherein said first layer includes one or both of a photo-luminescent material and a component to stabilize said top surface against ultra-violet light.
US11/682,504 2006-03-17 2007-03-06 Flooring element Abandoned US20070218252A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US13/081,877 US8557152B2 (en) 2006-03-17 2011-04-07 Flooring element

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0605413.4 2006-03-17
GB0605413A GB2436082B (en) 2006-03-17 2006-03-17 Tactile tiling

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US13/081,877 Division US8557152B2 (en) 2006-03-17 2011-04-07 Flooring element

Publications (1)

Publication Number Publication Date
US20070218252A1 true US20070218252A1 (en) 2007-09-20

Family

ID=36292967

Family Applications (2)

Application Number Title Priority Date Filing Date
US11/682,504 Abandoned US20070218252A1 (en) 2006-03-17 2007-03-06 Flooring element
US13/081,877 Active 2027-10-11 US8557152B2 (en) 2006-03-17 2011-04-07 Flooring element

Family Applications After (1)

Application Number Title Priority Date Filing Date
US13/081,877 Active 2027-10-11 US8557152B2 (en) 2006-03-17 2011-04-07 Flooring element

Country Status (2)

Country Link
US (2) US20070218252A1 (en)
GB (1) GB2436082B (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140331585A1 (en) * 2011-10-05 2014-11-13 Maax Bath, Inc. Decorative panel and method for manufacturing the same
US20140352248A1 (en) * 2010-01-11 2014-12-04 Valinge Innovation Ab Floor covering with interlocking design
US20150151456A1 (en) * 2012-05-24 2015-06-04 Glasseco Llc Method of manufacturing a surface apparatus and apparatus therefore
US20150233127A1 (en) * 2012-10-05 2015-08-20 Kronoplus Technical Ag Floor panel for outdoors
US9314936B2 (en) 2011-08-29 2016-04-19 Valinge Flooring Technology Ab Mechanical locking system for floor panels
US10047527B2 (en) 2009-09-04 2018-08-14 Valinge Innovation Ab Resilient floor
CN108505727A (en) * 2018-06-26 2018-09-07 湖州悦锦阁木业有限公司 The timber floor of antidetonation
US10287777B2 (en) 2016-09-30 2019-05-14 Valinge Innovation Ab Set of panels
US10301830B2 (en) 2013-03-25 2019-05-28 Valinge Innovation Ab Floorboards provided with a mechanical locking system
US10316526B2 (en) 2014-08-29 2019-06-11 Valinge Innovation Ab Vertical joint system for a surface covering panel
US10598382B2 (en) 2014-11-07 2020-03-24 United Technologies Corporation Impingement film-cooled floatwall with backside feature
US10808410B2 (en) 2018-01-09 2020-10-20 Valinge Innovation Ab Set of panels
US10837181B2 (en) 2015-12-17 2020-11-17 Valinge Innovation Ab Method for producing a mechanical locking system for panels
US11725395B2 (en) 2009-09-04 2023-08-15 Välinge Innovation AB Resilient floor

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITVR20090174A1 (en) * 2009-10-23 2011-04-24 Cremar S P A BUILDING ELEMENT IN STONE MATERIAL AND PROCEDURE FOR ITS REALIZATION
GB2529380B (en) * 2014-06-08 2018-04-25 Pipex Structural Composites Ltd Improvements in or relating to railway platforms
US20180353802A1 (en) * 2015-09-16 2018-12-13 Grounding Inc. Sporting towel mat for use on a support surface
TWI611827B (en) * 2015-09-16 2018-01-21 Grounding Inc Sports towel with continuous slip strip
US10697186B1 (en) * 2018-07-11 2020-06-30 Errol L. McLaren Non-slip shower tile
GB202113743D0 (en) * 2021-09-24 2021-11-10 Wagstaff David Anthony Improved flooring substrate
EP4303256A1 (en) * 2022-07-07 2024-01-10 ACS International Products, L.P. Composite material with coating layer

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3097080A (en) * 1959-06-29 1963-07-09 Arthur R Weir Artificial stone facing plaque
US3344011A (en) * 1964-11-02 1967-09-26 Goozner Murray Terrazzo tile
US3419454A (en) * 1964-08-14 1968-12-31 Hoffman Alfred Method of making and reinforcing decorative polyester resin products
US4501783A (en) * 1982-07-06 1985-02-26 Toyo Linoleum Company, Limited Non-slip floor material
US4715743A (en) * 1986-06-13 1987-12-29 Schmanski Donald W Mobility guide tile for visually handicapped
US4944998A (en) * 1987-07-29 1990-07-31 Armstrong World Industries, Inc. Charge dissipative floor tiles
US20030215596A1 (en) * 2002-05-16 2003-11-20 Robert Nolt Photoluminescent floor tile
US20040211130A1 (en) * 2003-04-24 2004-10-28 Horstman R. Ted High traction flooring laminate
US7141618B2 (en) * 2002-06-03 2006-11-28 Ppg Industries Ohio, Inc. Coating compositions with modified particles and methods of using the same

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242242A (en) * 1962-11-29 1966-03-22 Douglas P Bournique Method for the production of decorative wall and flooring tile
FR2190137A5 (en) * 1972-06-19 1974-01-25 Cambon Christia Non-slip flagstone of cement and marble - on a concrete substrate
DE3373465D1 (en) * 1982-12-16 1987-10-15 Dynamit Nobel Ag Water-containing hardenable shaped masses based on inorganic components, and method of producing shaped bodies
FR2590203A1 (en) * 1985-11-15 1987-05-22 Sinclair Francis Synthetic-resin coatings having an abrasion-resistant hard surface for buildings and for industry
US5637236A (en) * 1991-05-15 1997-06-10 Lowe; Michael Method for producing a wall, roadway, sidewalk or floor of cementitious material
JP2731790B2 (en) * 1991-11-20 1998-03-25 東リ株式会社 Floor tile
JP3015628B2 (en) * 1993-06-30 2000-03-06 日本プレストン株式会社 Transfer type decorative sheet and manufacturing method thereof
US6061940A (en) * 1996-06-14 2000-05-16 Rice; Lawrence William Road utility marker

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3097080A (en) * 1959-06-29 1963-07-09 Arthur R Weir Artificial stone facing plaque
US3419454A (en) * 1964-08-14 1968-12-31 Hoffman Alfred Method of making and reinforcing decorative polyester resin products
US3344011A (en) * 1964-11-02 1967-09-26 Goozner Murray Terrazzo tile
US4501783A (en) * 1982-07-06 1985-02-26 Toyo Linoleum Company, Limited Non-slip floor material
US4715743A (en) * 1986-06-13 1987-12-29 Schmanski Donald W Mobility guide tile for visually handicapped
US4944998A (en) * 1987-07-29 1990-07-31 Armstrong World Industries, Inc. Charge dissipative floor tiles
US20030215596A1 (en) * 2002-05-16 2003-11-20 Robert Nolt Photoluminescent floor tile
US7141618B2 (en) * 2002-06-03 2006-11-28 Ppg Industries Ohio, Inc. Coating compositions with modified particles and methods of using the same
US20040211130A1 (en) * 2003-04-24 2004-10-28 Horstman R. Ted High traction flooring laminate
US7029744B2 (en) * 2003-04-24 2006-04-18 Ultimate Systems, Ltd. High traction flooring laminate

Cited By (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10047527B2 (en) 2009-09-04 2018-08-14 Valinge Innovation Ab Resilient floor
US11725395B2 (en) 2009-09-04 2023-08-15 Välinge Innovation AB Resilient floor
US11306486B2 (en) 2009-09-04 2022-04-19 Valinge Innovation Ab Resilient floor
US10526793B2 (en) 2009-09-04 2020-01-07 Valinge Innovation Ab Resilient floor
US20140352248A1 (en) * 2010-01-11 2014-12-04 Valinge Innovation Ab Floor covering with interlocking design
US11795701B2 (en) 2010-01-11 2023-10-24 Välinge Innovation AB Floor covering with interlocking design
US11359387B2 (en) 2010-01-11 2022-06-14 Valinge Innovation Ab Floor covering with interlocking design
US9695601B2 (en) * 2010-01-11 2017-07-04 Valinge Innovation Ab Floor covering with interlocking design
US10704269B2 (en) 2010-01-11 2020-07-07 Valinge Innovation Ab Floor covering with interlocking design
US9758972B2 (en) 2011-08-29 2017-09-12 Ceraloc Innovation Ab Mechanical locking system for floor panels
US9714515B2 (en) 2011-08-29 2017-07-25 Ceraloc Innovation Ab Mechanical locking system for floor panels
US9314936B2 (en) 2011-08-29 2016-04-19 Valinge Flooring Technology Ab Mechanical locking system for floor panels
US9518392B2 (en) * 2011-10-05 2016-12-13 Maax Bath Inc. Decorative panel and method for manufacturing the same
US20140331585A1 (en) * 2011-10-05 2014-11-13 Maax Bath, Inc. Decorative panel and method for manufacturing the same
US20150151456A1 (en) * 2012-05-24 2015-06-04 Glasseco Llc Method of manufacturing a surface apparatus and apparatus therefore
US20150233127A1 (en) * 2012-10-05 2015-08-20 Kronoplus Technical Ag Floor panel for outdoors
US9828777B2 (en) * 2012-10-05 2017-11-28 Kronoplus Technical Ag Floor panel for outdoors
US11898356B2 (en) 2013-03-25 2024-02-13 Välinge Innovation AB Floorboards provided with a mechanical locking system
US10301830B2 (en) 2013-03-25 2019-05-28 Valinge Innovation Ab Floorboards provided with a mechanical locking system
US10407919B2 (en) 2013-03-25 2019-09-10 Valinge Innovation Ab Floorboards provided with a mechanical locking system
US11421426B2 (en) 2013-03-25 2022-08-23 Valinge Innovation Ab Floorboards provided with a mechanical locking system
US10844612B2 (en) 2013-03-25 2020-11-24 Valinge Innovation Ab Floorboards provided with a mechanical locking system
US11661749B2 (en) 2014-08-29 2023-05-30 Valinge Innovation Ab Vertical joint system for a surface covering panel
US10865571B2 (en) 2014-08-29 2020-12-15 Valinge Innovation Ab Vertical joint system for a surface covering panel
US10982449B2 (en) 2014-08-29 2021-04-20 Valinge Innovation Ab Vertical joint system for a surface covering panel
US10316526B2 (en) 2014-08-29 2019-06-11 Valinge Innovation Ab Vertical joint system for a surface covering panel
US10598382B2 (en) 2014-11-07 2020-03-24 United Technologies Corporation Impingement film-cooled floatwall with backside feature
US10837181B2 (en) 2015-12-17 2020-11-17 Valinge Innovation Ab Method for producing a mechanical locking system for panels
US10851549B2 (en) 2016-09-30 2020-12-01 Valinge Innovation Ab Set of panels
US10287777B2 (en) 2016-09-30 2019-05-14 Valinge Innovation Ab Set of panels
US11814850B2 (en) 2016-09-30 2023-11-14 Välinge Innovation AB Set of panels
US10808410B2 (en) 2018-01-09 2020-10-20 Valinge Innovation Ab Set of panels
US11808045B2 (en) 2018-01-09 2023-11-07 Välinge Innovation AB Set of panels
CN108505727A (en) * 2018-06-26 2018-09-07 湖州悦锦阁木业有限公司 The timber floor of antidetonation

Also Published As

Publication number Publication date
GB0605413D0 (en) 2006-04-26
US8557152B2 (en) 2013-10-15
GB2436082B (en) 2011-02-23
US20110179746A1 (en) 2011-07-28
GB2436082A (en) 2007-09-19

Similar Documents

Publication Publication Date Title
US8557152B2 (en) Flooring element
US7291288B2 (en) Artificial stone and formation therefor
US20030087074A1 (en) Artificial stone and formation therefor
US7388063B2 (en) Repair kit
ES2275488T3 (en) MATERIAL FOR PAVEMENT OF PLASTIC FLOORS RESISTANT TO SPOTS AND ANTI-SLIP.
CA2666617C (en) Method of forming detectable warnings on surfaces and products thereof
US9163364B2 (en) Materials
JP2000320122A (en) Sheet shape floor mat and manufacture thereof
JP4865612B2 (en) Elastic tile
KR200410601Y1 (en) A packing lawn is elasticity
KR20140043212A (en) Grain stone tile or of the ground block and manufacturing method thereof and construction working method
KR101209399B1 (en) Floor projection screen and manufacturing method
KR101464316B1 (en) A hign-intense guide block and manufacturing method of the same for visually handicapped person
KR101145816B1 (en) Retroreflection Type Rugged Pavement and Method for Consructing the Same
KR20150125534A (en) construction method for elastic pavement with luminescence specific
KR100300489B1 (en) The processing method of guide block using polymer concrete
KR101032041B1 (en) Road paving materials using bottom ash
KR101670998B1 (en) Paint Composition of lane painting with non-slip and painting process using thereof
JPH07125116A (en) Uneven-surfaced sheet and its manufacture
JPS61176708A (en) Light reflective slip preventing paving body
KR101413562B1 (en) physical training facilities
AU784970B2 (en) Artificial stone and formation therefor
JP2022040617A (en) Stair repair material and stair repair method using the same
JP2002103523A (en) Non-slip rubber panel and method for manufacturing the same
JP2011140871A (en) Braille paving tile for visually handicapped person

Legal Events

Date Code Title Description
AS Assignment

Owner name: ESF CORPORATION, TENNESSEE

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:DONALD, MALCOLM ROGER CURZON;REEL/FRAME:019316/0695

Effective date: 20070516

Owner name: VISUL CORPORATION, TENNESSEE

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:ESF CORPORATION;REEL/FRAME:019316/0697

Effective date: 20070518

AS Assignment

Owner name: MRF HOLDINGS CORPORATION, TENNESSEE

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:VISUL CORPORATION;REEL/FRAME:019913/0091

Effective date: 20071002

AS Assignment

Owner name: MRB HOLDINGS CORPORATION, TENNESSEE

Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE COVER SHEET DATA FOR ASSIGNEE NAME FROM "MRF HOLDINGS CORPORATION" TO "MRB HOLDINGS CORPORATION" PREVIOUSLY RECORDED ON REEL 019913 FRAME 0091;ASSIGNOR:VISUAL CORPORATION;REEL/FRAME:019966/0004

Effective date: 20071002

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION