US20070089860A1 - Heat pipe with sintered powder wick - Google Patents

Heat pipe with sintered powder wick Download PDF

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Publication number
US20070089860A1
US20070089860A1 US11/478,392 US47839206A US2007089860A1 US 20070089860 A1 US20070089860 A1 US 20070089860A1 US 47839206 A US47839206 A US 47839206A US 2007089860 A1 US2007089860 A1 US 2007089860A1
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Prior art keywords
metal powder
spherical metal
heat pipe
powder
casing
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US11/478,392
Inventor
Chuen-Shu Hou
Tay-Jian Liu
Chao-Nien Tung
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Foxconn Technology Co Ltd
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Foxconn Technology Co Ltd
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Assigned to FOXCONN TECHNOLOGY CO., LTD. reassignment FOXCONN TECHNOLOGY CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: HOU, CHUEN-SHU, LIU, TAY-JIAN, TUNG, CHAO-NIEN
Publication of US20070089860A1 publication Critical patent/US20070089860A1/en
Abandoned legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D15/00Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies
    • F28D15/02Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes
    • F28D15/04Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with tubes having a capillary structure
    • F28D15/046Heat-exchange apparatus with the intermediate heat-transfer medium in closed tubes passing into or through the conduit walls ; Heat-exchange apparatus employing intermediate heat-transfer medium or bodies in which the medium condenses and evaporates, e.g. heat pipes with tubes having a capillary structure characterised by the material or the construction of the capillary structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/05Metallic powder characterised by the size or surface area of the particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/10Sintering only
    • B22F3/11Making porous workpieces or articles
    • B22F3/1103Making porous workpieces or articles with particular physical characteristics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/4935Heat exchanger or boiler making
    • Y10T29/49353Heat pipe device making

Definitions

  • the present invention relates generally to heat pipes as heat transfer/dissipating device, and more particularly to a heat pipe with a sintered powder wick.
  • Heat pipes have excellent heat transfer properties and therefore are an effective means for transfer or dissipation of heat from heat sources. Heat pipes are widely used for removing heat from heat-generating components such as computer central processing units (CPUs).
  • a heat pipe is usually a vacuum tube containing a working fluid therein, which is employed to carry thermal energy from one section of the heat pipe (typically referred to as the “evaporating section”) to another section thereof (typically referred to as the “condensing section”) via phase transitions between a liquid state and a vapor state of the working fluid.
  • the tube is made of a highly thermally conductive material such as copper or aluminum.
  • a wick structure is provided inside the heat pipe, lining an inner wall of the tube, for drawing the working fluid back to the evaporating section after it has condensed in the condensing section.
  • the working fluid contained in the evaporating section can absorb heat generated by the heat-generating component and turn into vapor. Due to the difference in vapor pressure between the two sections of the heat pipe, the vapor moves towards the condensing section where the vapor is condensed into liquid, releasing the heat into ambient environment in the process; the heat is then dispersed by, for example, fins thermally contacting the condensing section. Due to the difference of capillary pressure in the wick structure between the two sections, the condensed liquid is then drawn back by the wick structure to the evaporating section where it is again available for evaporation.
  • FIG. 3 illustrates a wick structure in accordance with related art, provided for a heat pipe and mainly composed of water atomized irregular copper powder 100 with low apparent density.
  • the powder 100 has irregular shape particle and the apparent density ranges from 2.5 g/cm 3 to 3.3 g/cm 3 , thereby forming a plurality of micro pores 110 in the powder.
  • FIG. 4 shows a microstructure of a wick structure formed by sintering the powder particles 100 having a relatively high green density and sintered at a relatively low temperature.
  • FIG. 5 shows a microstructure of a wick structure formed by sintering the powder particles 100 having a relatively low green density and sintered at a relatively high temperature.
  • most of the micro pores 110 of the FIG. 4 is not eliminated.
  • the micro pores 110 can be eliminated only at the relatively high temperature (see FIG. 5 ).
  • the conventional water atomized irregular copper powder 100 is sintered at the high temperature, not only the number of the micro pores 110 is reduced but also a total porosity of the sintered wick structure is reduced. The reduction of the total porosity of the sintered structure adversely affects the performance of the heat pipe.
  • a heat pipe in accordance with an embodiment of the present invention includes a casing and a sintered powder wick arranged at an inner surface of the casing.
  • the sintered powder wick is made of spherical metal powder, the spherical metal powder having an apparent density ranging from 3.3 g/cm 3 to 4.8 g/cm 3 to reduce micro pores of the sintered powder wick and improve ability of heat transfer of the heat pipe.
  • the present invention in another aspect, relates to a method for manufacturing a sintered heat pipe.
  • the preferred method includes steps of (1) providing a hollow casing; (2) inserting a mandrel into the casing; (3) filling spherical metal powder into a space between the mandrel and the inner surface of the casing, wherein an apparent density of the spherical metal powder ranges from 3.3 g/cm 3 to 4.8 g/cm 3 ; and (4) conducting sintering process to the casing and the filled spherical metal powder, whereby a sintered wick structure made of the spherical metal powder is formed inside the casing.
  • FIG. 1 is a microstructure of powder particles of a heat pipe in accordance with a preferred embodiment of the present invention
  • FIG. 2 is a graph of a permeation rate distribution of different types of powder, wherein the permeation rate is changed with time;
  • FIG. 3 is a scanning electron micrograph of a wick structure formed by sintering a water atomized irregular copper powder
  • FIG. 4 is a scanning electron micrograph of a wick structure formed by sintering the water atomized irregular copper powder having a relatively high green density and sintered at a relatively low temperature;
  • FIG. 5 a scanning electron micrograph of a wick structure formed by sintering the water atomized irregular copper powder having a relatively low green density and sintered at a relatively high temperature.
  • a heat pipe in accordance with an embodiment of the present invention includes a casing, a sintered powder wick structure arranged at an inner surface of the casing and working fluid filled with the casing.
  • a method of manufacturing the heat pipe comprises following steps: (1) inserting a mandrel into the casing; (2) filling spherical metal powder 300 such as copper or aluminum powder into a space between the mandrel and the inner surface of the casing, wherein an apparent density of the spherical metal powder 300 ranges from 3.3 g/cm 3 to 4.8 g/cm 3 ; (3) heating the filled spherical metal powder 300 together with the casing at a high temperature, whereby the filled spherical metal powder 300 is sintered and diffusion bonded to the inner surface of the casing and particles of the powder after the sintering have approximately the same diameters to enhance the performance of the heat pipe.
  • the spherical metal powder 300 having high apparent density is manufactured by mechanical method, such as cutting, crushing, chipping, etc.
  • Particle diameter of the spherical metal powder 300 ranges from 80 ⁇ m to 300 ⁇ m, wherein 100 ⁇ m ⁇ 250 ⁇ m is preferable.
  • Fine powder having a diameter smaller than that of the spherical metal powder and acting as an additive is added to the spherical metal powder 300 to improve the sintering strength of the wick structure.
  • the fine powder has a weight which is 1 ⁇ 10% of a weight of the metal powder 300 .
  • FIG. 1 shows, in an enlarged scale, a structure of particles of the spherical metal powder 300 formed in accordance with an alternative method of the present invention, rather than the afore-mentioned mechanical method such as cutting, crushing, chipping, etc.
  • each particle of the spherical metal powder 300 consists of superfine powder 200 having a particle diameter below 10 ⁇ m.
  • the superfine powder 200 is processed by controlling parameters of a pressure granulator or centrifugal granulator, to thereby obtain the spherical metal powder 300 with high consistency.
  • a particle diameter of the spherical metal powder 300 formed according to this method ranges from 30 ⁇ m to 300 ⁇ m.
  • the super fine powder 200 is pre-sintered at a suitable temperature, for example, about 600 ⁇ 800 degrees Celsius, whereby densification temperature of the spherical metal powder 300 is dropped significantly. At the same time, number of micro pores in the spherical metal powder 300 is reduced and flowability of the spherical metal powder 300 is increased to prevent a bridging effect of the spherical metal powder 300 during the filling of the spherical metal powder 300 into the casing.
  • a suitable temperature for example, about 600 ⁇ 800 degrees Celsius
  • FIG. 2 shows a permeation rate distribution of three different types of powder with a porosity of 47%.
  • the three different types of powder comprises the spherical metal powder 300 , water atomized irregular copper powder and penniform electrolyte power. It is obviousness that the spherical metal powder 300 has a superior permeation rate to another two types of powder.
  • the present invention provides the spherical metal powder 300 for forming the sintered wick structure of the heat pipe having various advantages over the heat pipe having water atomized irregular copper powder in accordance with the related art. For example, one advantage is capable of improving ability of heat transfer by using of the spherical metal powder 300 having high apparent density. Another advantage is to reduce micro pores of the spherical metal powder 300 by pre-sintered processing. In addition, the flowability of the spherical metal powder 300 is better than the water atomized irregular copper powder 100 .

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Powder Metallurgy (AREA)
  • Materials For Medical Uses (AREA)

Abstract

A heat pipe includes a casing and a sintered powder wick arranged at an inner surface of the casing. The sintered powder wick is made of spherical metal powder (300), the spherical metal powder having an apparent density ranging from 3.3 g/cm3 to 4.8 g/cm3 to reduce micro pores of the sintered powder wick and improve ability of heat transfer of the heat pipe.

Description

    BACKGROUND
  • 1. Field
  • The present invention relates generally to heat pipes as heat transfer/dissipating device, and more particularly to a heat pipe with a sintered powder wick.
  • 2. Description of related art
  • Heat pipes have excellent heat transfer properties and therefore are an effective means for transfer or dissipation of heat from heat sources. Heat pipes are widely used for removing heat from heat-generating components such as computer central processing units (CPUs). A heat pipe is usually a vacuum tube containing a working fluid therein, which is employed to carry thermal energy from one section of the heat pipe (typically referred to as the “evaporating section”) to another section thereof (typically referred to as the “condensing section”) via phase transitions between a liquid state and a vapor state of the working fluid. The tube is made of a highly thermally conductive material such as copper or aluminum. Preferably, a wick structure is provided inside the heat pipe, lining an inner wall of the tube, for drawing the working fluid back to the evaporating section after it has condensed in the condensing section. Specifically, as the evaporating section of the heat pipe is maintained in thermal contact with a heat-generating component, the working fluid contained in the evaporating section can absorb heat generated by the heat-generating component and turn into vapor. Due to the difference in vapor pressure between the two sections of the heat pipe, the vapor moves towards the condensing section where the vapor is condensed into liquid, releasing the heat into ambient environment in the process; the heat is then dispersed by, for example, fins thermally contacting the condensing section. Due to the difference of capillary pressure in the wick structure between the two sections, the condensed liquid is then drawn back by the wick structure to the evaporating section where it is again available for evaporation.
  • FIG. 3 illustrates a wick structure in accordance with related art, provided for a heat pipe and mainly composed of water atomized irregular copper powder 100 with low apparent density. The powder 100 has irregular shape particle and the apparent density ranges from 2.5 g/cm3 to 3.3 g/cm3, thereby forming a plurality of micro pores 110 in the powder. Capillary pressure is related to interfacial tension, pore size and contact angle by the following equation:
    (Pc)=(2×σ×cos θ)/r
    where
    • Pc=capillary pressure;
    • s=interfacial tension;
    • r=radius of pore;
    • θ=contact angle.
  • It can be seen from the above equation that the smaller the effective pores 110 sizes the higher the capillary pressure. A flow resistance to working liquid also increases due to a decrease in pores 110 sizes of the wick structure. The working fluid and non-condensation gas in the heat pipe is prone to adhere into the pores 110 having higher capillary pressure and is prevented flowing out of the pores 110 of the wick structure, thereby causing a lack of the working fluid available for heat transfer and reducing the heat transfer performance of the heat pipe. Therefore, the powder 100 is often sintered at a predetermined temperature to eliminate the micro pores 110 of the wick structure. FIG. 4 shows a microstructure of a wick structure formed by sintering the powder particles 100 having a relatively high green density and sintered at a relatively low temperature. FIG. 5 shows a microstructure of a wick structure formed by sintering the powder particles 100 having a relatively low green density and sintered at a relatively high temperature. Compared with the FIG. 5, most of the micro pores 110 of the FIG. 4 is not eliminated. The micro pores 110 can be eliminated only at the relatively high temperature (see FIG. 5). However, when the conventional water atomized irregular copper powder 100 is sintered at the high temperature, not only the number of the micro pores 110 is reduced but also a total porosity of the sintered wick structure is reduced. The reduction of the total porosity of the sintered structure adversely affects the performance of the heat pipe.
  • Therefore, there is a need for a heat pipe with a sintered powder wick which can solve the above problems.
  • SUMMARY OF THE INVENTION
  • A heat pipe in accordance with an embodiment of the present invention includes a casing and a sintered powder wick arranged at an inner surface of the casing. The sintered powder wick is made of spherical metal powder, the spherical metal powder having an apparent density ranging from 3.3 g/cm3 to 4.8 g/cm3 to reduce micro pores of the sintered powder wick and improve ability of heat transfer of the heat pipe.
  • The present invention in another aspect, relates to a method for manufacturing a sintered heat pipe. The preferred method includes steps of (1) providing a hollow casing; (2) inserting a mandrel into the casing; (3) filling spherical metal powder into a space between the mandrel and the inner surface of the casing, wherein an apparent density of the spherical metal powder ranges from 3.3 g/cm3 to 4.8 g/cm3; and (4) conducting sintering process to the casing and the filled spherical metal powder, whereby a sintered wick structure made of the spherical metal powder is formed inside the casing.
  • Other advantages and novel features of the present invention will become more apparent from the following detailed description of the embodiment when taken in conjunction with the accompanying drawings, in which:
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • Many aspects of the present device can be better understood with reference to the following drawings. The components in the drawings are not necessarily drawn to scale, the emphasis instead being placed upon clearly illustrating the principles of the present device. Moreover, in the drawings, like reference numerals designate corresponding parts throughout the several views.
  • FIG. 1 is a microstructure of powder particles of a heat pipe in accordance with a preferred embodiment of the present invention;
  • FIG. 2 is a graph of a permeation rate distribution of different types of powder, wherein the permeation rate is changed with time;
  • FIG. 3 is a scanning electron micrograph of a wick structure formed by sintering a water atomized irregular copper powder;
  • FIG. 4 is a scanning electron micrograph of a wick structure formed by sintering the water atomized irregular copper powder having a relatively high green density and sintered at a relatively low temperature; and
  • FIG. 5 a scanning electron micrograph of a wick structure formed by sintering the water atomized irregular copper powder having a relatively low green density and sintered at a relatively high temperature.
  • DETAILED DESCRIPTION OF THE INVENTION
  • A heat pipe in accordance with an embodiment of the present invention includes a casing, a sintered powder wick structure arranged at an inner surface of the casing and working fluid filled with the casing. A method of manufacturing the heat pipe comprises following steps: (1) inserting a mandrel into the casing; (2) filling spherical metal powder 300 such as copper or aluminum powder into a space between the mandrel and the inner surface of the casing, wherein an apparent density of the spherical metal powder 300 ranges from 3.3 g/cm3 to 4.8 g/cm3; (3) heating the filled spherical metal powder 300 together with the casing at a high temperature, whereby the filled spherical metal powder 300 is sintered and diffusion bonded to the inner surface of the casing and particles of the powder after the sintering have approximately the same diameters to enhance the performance of the heat pipe.
  • In this embodiment, the spherical metal powder 300 having high apparent density is manufactured by mechanical method, such as cutting, crushing, chipping, etc. Particle diameter of the spherical metal powder 300 ranges from 80 μm to 300 μm, wherein 100 μm˜250 μm is preferable. Fine powder having a diameter smaller than that of the spherical metal powder and acting as an additive is added to the spherical metal powder 300 to improve the sintering strength of the wick structure. The fine powder has a weight which is 1˜10% of a weight of the metal powder 300.
  • FIG. 1 shows, in an enlarged scale, a structure of particles of the spherical metal powder 300 formed in accordance with an alternative method of the present invention, rather than the afore-mentioned mechanical method such as cutting, crushing, chipping, etc. According to this alternative method, each particle of the spherical metal powder 300 consists of superfine powder 200 having a particle diameter below 10 μm. The superfine powder 200 is processed by controlling parameters of a pressure granulator or centrifugal granulator, to thereby obtain the spherical metal powder 300 with high consistency. A particle diameter of the spherical metal powder 300 formed according to this method ranges from 30 μm to 300 μm. The super fine powder 200 is pre-sintered at a suitable temperature, for example, about 600˜800 degrees Celsius, whereby densification temperature of the spherical metal powder 300 is dropped significantly. At the same time, number of micro pores in the spherical metal powder 300 is reduced and flowability of the spherical metal powder 300 is increased to prevent a bridging effect of the spherical metal powder 300 during the filling of the spherical metal powder 300 into the casing.
  • FIG. 2 shows a permeation rate distribution of three different types of powder with a porosity of 47%. The three different types of powder comprises the spherical metal powder 300, water atomized irregular copper powder and penniform electrolyte power. It is obviousness that the spherical metal powder 300 has a superior permeation rate to another two types of powder.
  • The present invention provides the spherical metal powder 300 for forming the sintered wick structure of the heat pipe having various advantages over the heat pipe having water atomized irregular copper powder in accordance with the related art. For example, one advantage is capable of improving ability of heat transfer by using of the spherical metal powder 300 having high apparent density. Another advantage is to reduce micro pores of the spherical metal powder 300 by pre-sintered processing. In addition, the flowability of the spherical metal powder 300 is better than the water atomized irregular copper powder 100.
  • It is to be understood, however, that even though numerous characteristics and advantages of the present invention have been set forth in the foregoing description, together with details of the structure and function of the invention, the disclosure is illustrative only, and changes may be made in detail, especially in matters of shape, size, and arrangement of parts within the principles of the invention to the full extent indicated by the broad general meaning of the terms in which the appended claims are expressed.

Claims (15)

1. A heat pipe comprising:
a casing;
working fluid received in the casing; and
a wick structure sintered at an inner surface of the casing, the wick structure comprising spherical metal powder, the spherical metal powder having an apparent density ranging from 3.3 g/cm3 to 4.8 g/cm3.
2. The heat pipe of claim 1, wherein fine powder acting as an additive is added to the spherical metal powder to improve the strength of the wick structure, wherein the fine powder have a particle size smaller than that of the spherical metal powder.
3. The heat pipe of claim 2, wherein a weight of the fine powder is 1˜10% of a weight of the metal powder.
4. The heat pipe of claim 1, wherein a particle diameter of the spherical metal powder ranges from 80 μm to 300 μm.
5. The heat pipe of claim 4, wherein the particle diameter of the spherical metal powder ranges from 100 μm to 250 μm.
6. The heat pipe of claim 1, wherein a particle diameter of the spherical metal powder ranges from 30 μm to 300 μm.
7. The heat pipe of claim 1, wherein the spherical metal powder is made from superfine powder having a particle diameter below 10 μm.
8. A method for manufacturing a heat pipe comprising steps of:
providing a hollow casing;
inserting a mandrel into the casing;
filling spherical metal powder into a space between the mandrel and the inner surface of the casing, wherein an apparent density of the spherical metal powder ranges from 3.3 g/cm3 to 4.8 g/cm3; and
conducting sintering process to the casing and the filled spherical metal powder, whereby a sintered wick structure made of the spherical metal powder is formed inside the casing.
9. The method for manufacturing a heat pipe as in claim 8, wherein each of the spherical metal powder consists of superfine powder having a particle diameter below 10 μm and sintered at 600˜800 degrees Celsius.
10. The method for manufacturing a heat pipe as in claim 8, wherein fine powder acting as an addictive supplement is added to the spherical metal powder to improve the strength of the wick structure, the fin powder having a particle diameter smaller than that of the spherical metal powder.
11. The method for manufacturing a heat pipe as in claim 10, wherein a weight of the fine powder is 1˜10% of a weight of the metal powder.
12. The method for manufacturing a heat pipe as in claim 8, wherein a particle diameter of the spherical metal powder ranges from 80 μm to 300 μm.
13. The method for manufacturing a heat pipe as in claim 8, wherein the particle diameter of the spherical metal powder ranges from 100 μm to 250 μm.
14. The method for manufacturing a heat pipe as in claim 8, wherein a particle diameter of the spherical metal powder ranges from 30 μm to 300 μm.
15. The method for manufacturing a heat pipe as claim 8, wherein the spherical metal powder is made from superfine powder having a particle diameter below 10 μm.
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US20130168052A1 (en) * 2011-12-30 2013-07-04 Celsia Technologies Taiwan, Inc. Heat pipe and composition of capillary wick thereof
US20170153072A1 (en) * 2014-07-02 2017-06-01 Mitsubishi Materials Corporation Porous aluminum heat exchanger
US10639712B2 (en) 2018-06-19 2020-05-05 Amastan Technologies Inc. Process for producing spheroidized powder from feedstock materials
CN111912275A (en) * 2020-06-28 2020-11-10 武汉理工大学 Gradient ordered pore porous capillary core ultrathin heat pipe and manufacturing method thereof
US10981230B2 (en) 2014-05-30 2021-04-20 Mitsubishi Materials Corporation Porous aluminum complex and method of producing porous aluminum complex
US10987735B2 (en) 2015-12-16 2021-04-27 6K Inc. Spheroidal titanium metallic powders with custom microstructures
US11148202B2 (en) 2015-12-16 2021-10-19 6K Inc. Spheroidal dehydrogenated metals and metal alloy particles
US11311938B2 (en) 2019-04-30 2022-04-26 6K Inc. Mechanically alloyed powder feedstock
US11590568B2 (en) 2019-12-19 2023-02-28 6K Inc. Process for producing spheroidized powder from feedstock materials
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US11717886B2 (en) 2019-11-18 2023-08-08 6K Inc. Unique feedstocks for spherical powders and methods of manufacturing
US11855278B2 (en) 2020-06-25 2023-12-26 6K, Inc. Microcomposite alloy structure
US11919071B2 (en) 2020-10-30 2024-03-05 6K Inc. Systems and methods for synthesis of spheroidized metal powders
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TWI477730B (en) * 2011-10-28 2015-03-21 Celsia Technologies Taiwan Inc Heat pipe and the composition of the capillary wick thereof

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