US20070084772A1 - Controlled dosing of chlorine dioxide or other sanitizing agents into pressurized water systems - Google Patents
Controlled dosing of chlorine dioxide or other sanitizing agents into pressurized water systems Download PDFInfo
- Publication number
- US20070084772A1 US20070084772A1 US11/468,563 US46856306A US2007084772A1 US 20070084772 A1 US20070084772 A1 US 20070084772A1 US 46856306 A US46856306 A US 46856306A US 2007084772 A1 US2007084772 A1 US 2007084772A1
- Authority
- US
- United States
- Prior art keywords
- fluid
- sanitizing
- water
- chamber
- chlorine dioxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Images
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/20—Gaseous substances, e.g. vapours
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/26—Accessories or devices or components used for biocidal treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D37/00—Processes of filtration
- B01D37/02—Precoating the filter medium; Addition of filter aids to the liquid being filtered
- B01D37/025—Precoating the filter medium; Addition of filter aids to the liquid being filtered additives incorporated in the filter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F21/00—Dissolving
- B01F21/20—Dissolving using flow mixing
- B01F21/22—Dissolving using flow mixing using additional holders in conduits, containers or pools for keeping the solid material in place, e.g. supports or receptacles
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
- C02F1/685—Devices for dosing the additives
- C02F1/688—Devices in which the water progressively dissolves a solid compound
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/76—Treatment of water, waste water, or sewage by oxidation with halogens or compounds of halogens
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/02—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
- A61L2/022—Filtration
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
- A61L2202/10—Apparatus features
- A61L2202/12—Apparatus for isolating biocidal substances from the environment
- A61L2202/122—Chambers for sterilisation
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
- A61L2202/10—Apparatus features
- A61L2202/14—Means for controlling sterilisation processes, data processing, presentation and storage means, e.g. sensors, controllers, programs
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/002—Construction details of the apparatus
- C02F2201/003—Coaxial constructions, e.g. a cartridge located coaxially within another
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/002—Construction details of the apparatus
- C02F2201/006—Cartridges
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/02—Odour removal or prevention of malodour
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2303/00—Specific treatment goals
- C02F2303/04—Disinfection
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2307/00—Location of water treatment or water treatment device
- C02F2307/02—Location of water treatment or water treatment device as part of a bottle
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/4891—With holder for solid, flaky or pulverized material to be dissolved or entrained
Definitions
- the subject invention relates to a system and method of water treatment, and more particularly, to systems and methods of delivering controlled doses of chlorine dioxide or other sanitizing agents into a pressurized water system.
- Potable water contains various levels of background contaminants such as HPC, pathogenic bacteria and algae, even after municipal treatment. In most instances, chlorine is used to reduce the concentration of such background contaminants. Chlorine and chlorine compounds used for sanitization or disinfection are often removed from water supplies prior to use in drinking water systems, food service beverage systems and ice dispensing equipment. The reasons for removal vary depending on the application or system. For example, the presence of chlorine in the water supply to certain beverage systems may negatively impact a particular quality of the beverage product, such as its taste.
- Chlorine dioxide or other sanitizing agents have also been found to be highly effective as a sanitizer for use in potable water lines.
- Prior treatment procedures employed a highly concentrated solution of chlorine dioxide or other sanitizing agents, which is formed independently in a remote container and then pumped into the system lines. This solution is allowed to remain in the system lines for extended periods of time while the pressure in the water line is shut off.
- the flushing process itself often significantly extends the system downtime of the prior treatment procedures because of a residue left in the system lines by the prolonged static exposure to the chlorine or other sanitizing agents solution. This residue is often difficult to remove, and even low levels of such residue may be considered toxic or noxious, thus requiring the repeated flushing of the system.
- the present invention provides new and useful systems and methods for delivering controlled doses of chlorine dioxide or other sanitizing agents into a pressurized potable water system which overcomes the problems associated with the prior art.
- a medium having a support structure with an inlet configured for receiving a fluid, an outlet configured for delivering a fluid and a body configured for circulating a fluid therein such as a replaceable filter cartridge, which includes a sanitizing agent containing one or more reactants that are chemically configured for releasing a compound having sanitizing properties, such as chlorine dioxide, in a controlled dose upon being wetted by the fluid and positioned within the medium to be exposed to the fluid circulating therein.
- the sanitizing agent releases chlorine dioxide or other sanitizing agents in specific amounts, at a specific and controlled constant rate, to sanitize, deodorize, and disinfect equipment pipes connected to the medium outlet.
- the rate of chlorine dioxide or other sanitizing agents release would be set to dilute in water with a constant flow rate for a duration equivalent to perform the desired task, such as sanitize, deodorize, or disinfect water lines and equipment wetted parts.
- the preferred mediums to be used in accordance with the present invention include systems or disposable cartridges.
- the present invention is directed to a system for delivering a sanitizing agent to a fluid, which includes a substantially hollow vessel and a sanitizing agent having one or more reactants which are chemically configured to release a compound having sanitizing properties upon exposure to the fluid.
- the hollow vessel includes an inlet passage configured for receiving fluid flow, an outlet passage configured for fluid egress, and an interior chamber configured for receiving fluid from the inlet passage and providing temporary confinement of the fluid therein prior to egress from the outlet passage.
- the sanitizing agent is disposed in the chamber and the confinement of water therein may be provided by an independent valve.
- the present invention is also directed to a filter cartridge that includes a hollow housing with a filter media chamber defined therein and a sanitizing agent disposed in the filter media chamber.
- the sanitizing agent preferably includes one or more reactants which are chemically configured to release a compound having sanitizing properties upon exposure to the fluid in the filter media chamber.
- inlet passage in the housing configured to provide fluid communication with the chamber and an outlet passage in the housing configured to provide fluid communication with the chamber.
- the fluid is directed to the inlet passage and flows through the filter media chamber, exiting the outlet passage with chlorine dioxide or other sanitizing agents from a portion of fluid included therewith having been exposed to the sanitizing agent in the filter media chamber.
- the fluid is water and the compound is chlorine dioxide or other sanitizing agents
- the one or more reactants can include a chlorite and the release of chlorine dioxide or other sanitizing agents is initiated by contact with the water.
- the chlorite may be an aqueous soluble chlorite selected from the group consisting of sodium chlorite and potassium chlorite and mixtures thereof.
- the one or more reactants include an aqueous soluble chlorite and an aqueous soluble acid.
- the aqueous soluble acid is selected from the group consisting of phosphoric acid, fumaric acid, glycolic acid, acetic acid, ascorbic acid, oxalic acid, maleic acid, lactic acid, tartaric acid, citric acid and mixtures thereof.
- system or filter cartridge of the present invention may also include a filtration media disposed in the chamber along with the sanitizing agent.
- the filtration media may be configured to provide chemical or mechanical filtration depending on the application.
- the filtration media and sanitizing agent are disposed in the chamber and configured so that fluid entering the chamber is first exposed to the filtration media prior to being exposed to the sanitizing agent and exiting the outlet.
- a solution may be disposed in the chamber that includes a second compound having sanitizing properties, such as chlorine. This solution is then mixed with fluid flowing in the chamber and exits through the outlet passage.
- a second compound having sanitizing properties such as chlorine
- a substantially hollow neck is mated with the chamber.
- the neck has an inlet port in fluid communication with an inlet passage that is configured to be in fluid communication with the chamber, and an outlet port in fluid communication with an outlet passage that is also configured to be in fluid communication with the chamber.
- the inlet passage and outlet passage are both disposed in the neck and configured to provide dual fluid flow within the neck and independent fluid communication with the chamber.
- the aforementioned embodiment may further include a tubular member disposed axially in the neck and having a portion with a porous periphery extending into the chamber.
- the tubular member defines an inner axial passage therein and a radially outer axial passage bounded by the periphery of the tubular member and inner surface of the neck.
- the outer axial passage and the inner axial passage can provide the inlet and outlet passages, respectively.
- a filtration media may be disposed along the porous periphery of the portion of the tubular member extending into the filter media chamber and the sanitizing agent can be disposed within the inner axial passage of the portion of the tubular member extending into the chamber.
- the sanitizing agent is separated from the filtration media by an inert porous divider.
- a second outlet port may be added to the housing or vessel at a position where it will be in fluid communication with the chamber, and adjacent relative to the position of the sanitizing agent within the chamber, so that a majority or substantially all of the fluid exposed to the sanitizing agent exits this second outlet.
- FIG. 1 is a representative illustration of a system for providing controlled dosing of chlorine dioxide or other sanitizing agents to sanitize and clean equipment pipes or lines constructed in accordance with a preferred embodiment of the present invention, which depicts the system including a dry sanitizing agent, which releases chlorine dioxide or other sanitizing agents upon wetting with water, and a liquid sanitizing agent and a filter head for connecting the system with the equipment;
- FIG. 2 is a representative illustration of a filter cartridge for providing controlled dosing of chlorine dioxide or other sanitizing agents to sanitize and clean equipment pipes or lines constructed in accordance with a preferred embodiment of the present invention, including a dry sanitizing agent, which releases chlorine dioxide or other sanitizing agents upon wetting with water, a filtration media, a first outlet for water exposed to the filtration media, and a second outlet for providing water exposed to the sanitizing agent; and
- FIG. 3 is a representative illustration of a filter cartridge for providing controlled dosing of chlorine dioxide or other sanitizing agents to sanitize and clean equipment pipes or lines constructed in accordance with a preferred embodiment of the present invention, including a dry sanitizing agent, which releases chlorine dioxide or other sanitizing agents upon wetting with water and a filtration media, wherein the outlet stream from the filter cartridge contains a blend of water exposed to the filtration media and water exposed to the sanitizing agent.
- the present invention provides vehicles, such as replaceable filter cartridges, for delivering chlorine dioxide or other sanitizing agents to a water system in a variety of controlled doses periodically by exposure of the water in the system to sanitizing or cleaning agents.
- These agents may include stable dry chemicals such as, but not limited to, those which are disclosed in the herein incorporated Published International Patent Application No. 01/60750A3 (PCT/US01/05002), capable of generating chlorine dioxide or other sanitizing agents when wetted.
- the agent or agents release a specific amount of chlorine dioxide or other sanitizing agents, at a specific and controlled constant rate.
- the rate of chlorine dioxide or other sanitizing agents release would be set to dilute in water with a constant flow rate for a duration equivalent to clean (sanitize) water lines and equipment wetted parts.
- FIG. 1 a representative depiction of a stand-alone type system for providing controlled dosing of sanitizer/cleaner into pressurized water systems which is constructed in accordance with a preferred embodiment of the subject invention and designated generally by reference numeral 10 .
- System 10 includes a pressure vessel 12 having a first end 14 and a second end 16 defining a hollowed out, generally cylindrical chamber 18 therein.
- First end 14 has a neck 20 which has an inlet port 22 in fluid communication with an inlet passage for directing fluid flow into chamber 18 according to arrow 24 (hereinafter referred to as “inlet passage 24 ”).
- Neck 20 also includes an outlet port 26 in fluid communication with an outlet tube 28 which extends axially into chamber 18 .
- neck 20 also includes an optional bypass passage which provides fluid communication between inlet passage 24 and outlet port 26 in accordance with arrow 30 (hereinafter referred to as “bypass passage 30 ”).
- Chamber 18 includes an unfilled region 32 adjacent first end 14 , a first treatment region 34 containing a dry sanitizing agent 36 with controlled reaction dissolution and a second treatment region 38 containing a concentrated sanitizing liquid 40 adjacent second end 16 .
- First treatment region 34 and second treatment region 38 are separated from each other by a porous inert divider 42 .
- Sanitizing liquid 40 is preferably chlorine and may also include a dye indicator for facilitating awareness of its exhaustion.
- System 10 is attachable to the water supply line (not shown) to a master system (not shown), such as a beverage preparation device or ice making machine, via a filter head 44 having a first line 46 for receiving fluid from a supply line (not shown), a second line 48 for providing fluid to the master system and a treatment device port 50 .
- Filter head 44 may be constructed with or retrofitted onto the supply line or any other lines in the master system.
- System 10 may also be connected to the master system in other ways, such as by a permanent connection having flow control valves.
- Treatment device port 50 separates first line 46 and second line 48 and to provide a space in which neck 20 of system 10 may be inserted.
- Filter head 44 may also include a line pressure bypass with constant flow rate. The flow rate may vary depending on the application but typically ranges from about 0.25 gallons per minute to about 5.0 gallons per minute.
- the outer periphery of neck 20 and the inner surface of treatment device port 50 are configured to be engaged by corresponding cooperative structures defined respectively thereon.
- the cooperative structures may consist of a proprietary interconnection
- neck 20 and treatment device port 50 be sealingly engaged (e.g., using water resistant sealing rings fabricated of an elastomeric material) to maintain the integrity of fluid communication between the first line 46 and inlet port 22 , and between outlet port 26 and second line 48 , respectively.
- bypass passage 30 is configured to direct the water flowing therein through outlet port 26 sans treatment, to be diluted with the treated water also exiting from outlet port 26 .
- the water flowing through inlet passage 24 pours into unfilled region 32 of chamber 18 creating turbulence as indicated by arrows 52 which facilitates better mixing of the untreated water and greater contact with the sanitizers in treatment regions 34 and 38 within chamber 18 .
- the pressure of the incoming flow forces water within unfilled region 32 through first treatment region 34 , porous divider 42 , and second treatment region 38 before exiting chamber 18 via outlet tube 28 .
- the flow from outlet tube 28 mixes with untreated water flowing from outlet 26 via bypass passage 30 (if included) before being directed to the master system via second line 48 in filter head 44 .
- the water flowing to the master system contains about 0.1 parts per million of sanitizer to about 10 parts per million of sanitizer after passage through system 10 .
- FIG. 2 Another preferred embodiment of the present invention is represented by the depiction in FIG. 2 of a filter cartridge having a separate sanitizer stream for providing controlled dosing of sanitizer/cleaner into pressurized water systems, which is constructed in accordance with the subject invention and designated generally by reference numeral 110 .
- System 110 includes a filter cartridge housing 112 having a first end 114 and a second end 116 defining a hollowed out, generally cylindrical chamber 118 therein.
- First end 114 has a neck 120 which has an inlet port 122 in fluid communication with an inlet passage for directing fluid flow into chamber 118 according to arrow 124 (hereinafter referred to as “inlet passage 124 ”).
- Neck 120 also includes an outlet port 126 in fluid communication with an outlet tube 128 extending axially into chamber 118 .
- filter cartridge housing 112 also includes a separate sanitizer line 154 that draws fluid from chamber 118 adjacent to second end 116 of filter cartridge housing 112 .
- Chamber 118 includes an axially disposed, radially porous center core 156 and radially outer first treatment region 134 containing a filtration media 158 adjacent first end 114 , which may be mechanical or chemical in nature (e.g., a peat block, screen, activated carbon block, sediment block, granular media, etc.), and which substantially surrounds center core 156 .
- Center core 156 includes a first open axial end 160 adjacent to first end 114 of filter cartridge housing 112 and a second open axial end 162 adjacent to second end 116 of filter cartridge housing 112 .
- the second open end 162 of center core 156 is adjacent to a second treatment region 138 containing a dry sanitizing agent 136 with controlled reaction dissolution.
- First treatment region 134 and second treatment region 138 are separated by a porous inert divider 142 .
- filtration media 158 is configured and dimensioned to fit within filter cartridge housing 112 to define an unfilled annular region 132 between the inner circumferential surface of chamber 118 and the outer periphery of filtration media 158 for fluid flow therebetween, as illustrated by arrows 164 .
- Filter cartridge 110 is attachable to a supply line (not shown), preferably located within the housing of a master system (not shown), such as a beverage preparation device or ice making machine. This may be accomplished via a filter head (not shown) as in the previous embodiment or other connection having a port configured to engage neck 120 .
- water pumped through the supply line enters inlet port 122 and flows into chamber 118 through inlet passage 124 in neck 120 of filter cartridge housing 112 .
- the water flows through the unfilled annular region 132 and is pushed radially inward by the fluid pressure created in cartridge housing 112 .
- the water is forced through filtration media 158 and into center core 156 .
- a portion of the water flow in center core 156 is directed towards first end 114 and into outlet tube 128 , eventually exiting filter cartridge housing 112 through outlet port 126 , as illustrated by arrows 166 .
- the majority of the water flow follows the path shown by arrows 166 .
- This flow of treated water exits center core 156 from second open end 162 and enters into second treatment region 138 through porous inert divider 142 , as illustrated by arrow 170 .
- the water exposed to dry sanitizing agent 136 may be controlled by a control valve 172 in sanitizer line 154 .
- FIG. 3 Another preferred embodiment of the present invention is represented by the depiction in FIG. 3 of a filter cartridge having an encapsulated sanitizing agent for providing controlled dosing of sanitizer/cleaner into pressurized water systems, which is constructed in accordance with the subject invention and designated generally by reference numeral 210 .
- System 210 includes a filter cartridge housing 212 having a first end 214 and a second end 216 defining a hollowed out, generally cylindrical chamber 218 therein.
- First end 214 has a neck 220 which has an inlet port 222 in fluid communication with an inlet passage for directing fluid flow into chamber 218 according to arrow 224 (hereinafter referred to as “inlet passage 224 ”).
- Neck 220 also includes an outlet port 226 in fluid communication with an outlet tube 228 extending axially into chamber 218 .
- Chamber 218 includes an axially disposed, radially porous center core 256 and radially outer first treatment region 234 containing a filtration media 258 that extends axially substantially from first end 214 to second end 216 and substantially surrounds center core 256 .
- Filtration media 258 is configured and dimensioned to provide an unfilled annular region 232 between the inner circumferential surface of chamber 218 and the outer periphery of filtration media 258 for fluid flow therebetween, as illustrated by arrows 264 .
- Filtration media 258 may be mechanical or chemical in nature (e.g., a peat block, screen, activated carbon block, sediment block, granular media, etc.).
- Center core 256 includes an open axial end 260 adjacent to first end 214 of filter cartridge housing 212 and a second treatment region 238 containing a dry sanitizing agent 236 with controlled reaction dissolution adjacent to second end 216 of filter cartridge housing 212 .
- An axially disposed porous inert divider 242 separates second treatment region 238 from the remaining portion of center core 256 .
- Filter cartridge 210 is attachable to a supply line (not shown), preferably located within the housing of a master system (not shown), such as a beverage preparation device or ice making machine. This may be accomplished via a filter head (not shown) as in the previous embodiments or other connection having a port configured to engage neck 220 .
- water is pumped through supply line and flows from inlet port 222 to chamber 218 through inlet passage 224 in neck 220 of filter cartridge housing 212 .
- the water flows through the unfilled annular region 232 and is pushed radially inward by fluid pressure.
- Water is forced through filtration media 258 and into center core 256 , where it makes its way into outlet tube 228 and exits cartridge housing 212 through outlet port 226 , as illustrated by arrows 266 .
- a portion of the water flow forced through filtration media 258 also enters second treatment region 238 and contacts dry sanitizing agent 236 , as illustrated by arrow 268 .
- the water exposed to dry sanitizing agent 236 flows through porous inert divider 242 , as shown by arrows 270 , where it mixes with water which has not been treated by dry sanitizing agent 236 before exiting filter cartridge housing 212 , as described above.
- predetermined amounts of dry sanitizing agent 236 is encapsulated in a sanitary cartridge such as cartridge 110 and 210 , in a way, that would allow the full flow of fluid therethrough.
- a suitable encapsulated sanitary cartridge configuration is manufactured by Cuno Incorporated of Meriden, Conn., and sold under the tradename SQC® series drinking water system.
- System 10 and cartridges 110 and 210 may have a variety of end connector configurations to fit existing filter systems for periodic insertion and activation, as well as proprietary interconnects.
- a system or cartridge constructed in accordance with the present invention can also be incorporated into master system downstream of any absorbent media and can be removed or left in place until replaced for another treatment depending upon the filter head configuration.
- a system or cartridge of the present invention can be a standard component, which would be either supplied as part of a new installation, as a retrofit or as a replacement medium for chlorine dioxide or other sanitizing agents dosing.
- Various doses of chlorine dioxide or other sanitizing agents may be administered via the systems and cartridges of the present invention.
- the periodic high dosing of chlorine dioxide or other sanitizing agents may be accomplished by utilizing predetermined amounts of a sanitizing agent that also allows full flow through the cartridge.
- water can be introduced into a system or cartridge of the present invention is filled with the outlet port restricted. Once wetted the agent would generate chlorine dioxide or other sanitizing agents within the cartridge for a predetermined period of time, until a high level (e.g. 50 parts per million to 100 parts per million) is dissolved into the water in the system or cartridge chamber.
- the outlet port may be opened when ready and the chlorine dioxide or other sanitizing agents rich water can be forced by water pressure downstream into the water lines and equipment wetted parts, thereby stripping biofilm therefrom.
- the concentrated solution may be allowed to reach all exit ports of the downstream equipment. Thereafter, the outlet line of the master system can be shut off.
- the chlorine dioxide or other sanitizing agents rich solution may be held for a predetermined amount of time (e.g., from twenty minutes to several hours) to facilitate the stripping of biofilm build-up in the master system lines and sanitize the water and wetted equipment parts.
- the master system can then be flushed for a prescribed amount of time so as to clear the water lines and cartridge of any remaining chlorine dioxide or other sanitizing agents residue.
- One of the advantages of using chlorine dioxide or other sanitizing agents is its powerful oxidation capabilities and the ease by which residue is flushed out of the system.
- the rate of chlorine dioxide or other sanitizing agents generation is rapid, but its release from the cartridge or stand alone system can be set to dilute in water with a constant flow rate, preferably between 50 parts per million and 100 parts per million, for a duration equivalent to fill water lines and equipment wetted parts.
- Low doses of chlorine dioxide or other sanitizing agents can also be delivered into the water system periodically by exposure of the water in the system to sanitizing or cleaning agents contained in a system or cartridge constructed in accordance with the present invention.
- a low-level chlorine dioxide or other sanitizing agents dosing agent may be incorporated into a cartridge, such as cartridge 210 , which are constructed in accordance with the present invention, along with other reduction, removal or absorptive capabilities, or combinations thereof.
- the agent can generate chlorine dioxide or other sanitizing agents at a low controlled rate for a short duration.
- the chlorine dioxide or other sanitizing agents generation occurs at a location that is downstream of any absorbent media within the same cartridge.
- chlorine dioxide or other sanitizing agents generation begins.
- the absorbent and reduction media would perform as normal for their prescribed life (e.g., 3 months, 6 months or 1 year), while the chlorine dioxide or other sanitizing agents generation would end within the first few minutes of use (e.g., from about 5 to about 20 minutes).
- the net result would be the periodic sanitization of water lines and equipment wetted parts with the convenience of a standard cartridge replacement.
- a system or cartridge constructed in accordance with the present invention provides for the safe transportation and handling of chlorine dioxide or other sanitizing agents producing agents, controlled low level dosing rate in a dynamic flowing condition, controlled dosing duration, and system or cartridge formats and head assemblies which can introduce chlorine dioxide or other sanitizing agents into a pressurized water line.
- a filter cartridge may be constructed having a sanitizing agent in accordance with the present invention and with a bypass feature such as, but not limited to, those filter cartridges which are disclosed in the herein incorporated, copending and commonly owned U.S. patent application Ser. No. 10/337,832filed on Jan. 7, 2003.
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Water Treatment By Sorption (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
Abstract
A medium having a support structure configured for circulation of a fluid therein, such as a replaceable filter cartridge, including a sanitizing agent which contains one or more reactants that are chemically configured for delivering chlorine dioxide or other sanitizing agents in a controlled dose to sanitize, deodorize, and disinfect upon being wetted by the fluid and positioned in the medium support structure to be exposed to the fluid circulating therein.
Description
- The subject application is a continuation of U.S. patent application Ser. No. 11/096,537, filed Apr. 1, 2005, which is a continuation of U.S. patent application Ser. No. 10/392,670, filed Mar. 18, 2003, now U.S. Pat. No. 6,913,691; which claims the benefit of priority to U.S. Provisional Patent Application No. 60/366,144, filed Mar. 20, 2002, the disclosure of each is herein incorporated by reference to the extent not inconsistent with the present disclosure.
- The subject invention relates to a system and method of water treatment, and more particularly, to systems and methods of delivering controlled doses of chlorine dioxide or other sanitizing agents into a pressurized water system.
- Potable water contains various levels of background contaminants such as HPC, pathogenic bacteria and algae, even after municipal treatment. In most instances, chlorine is used to reduce the concentration of such background contaminants. Chlorine and chlorine compounds used for sanitization or disinfection are often removed from water supplies prior to use in drinking water systems, food service beverage systems and ice dispensing equipment. The reasons for removal vary depending on the application or system. For example, the presence of chlorine in the water supply to certain beverage systems may negatively impact a particular quality of the beverage product, such as its taste.
- There are also a significant amount of downstream potable water systems that do not use disinfection chemicals. This results in increased levels of microorganisms and biofilm build-up. The build-up increases within dechlorination filters, resin beds, and other finely divided media filters during periods of stagnation. The build-up can be released downstream at high levels causing health concerns, as well as severe off-tastes and odors. Over a prolonged period of time biofilm coats water lines and wetted parts of dispensing equipment, thus compounding the problem.
- The concern generated by known high levels of microorganism build-up has caused many in the food service and drinking water industry to periodically sanitize water lines, often reaching the threshold allowable by state or local regulations. Many of the sanitization procedures currently available are difficult to administer, costly, service intensive and use highly toxic chemicals. Some of the chemicals typically used in these procedures include peroxide, chlorine derivatives, muric acid and citric acid. Although the desired sanitizing effect may be achieved by these procedures, they are seldom implemented due to the aforementioned problems.
- Chlorine dioxide or other sanitizing agents have also been found to be highly effective as a sanitizer for use in potable water lines. Prior treatment procedures employed a highly concentrated solution of chlorine dioxide or other sanitizing agents, which is formed independently in a remote container and then pumped into the system lines. This solution is allowed to remain in the system lines for extended periods of time while the pressure in the water line is shut off.
- One of the primary disadvantages of using chlorine dioxide or other sanitizing agents as a sanitizer according to prior treatment procedures is the economic cost associated with the resulting system downtime since the system being sanitized is unusable during the treatment. Also, due to the toxic nature of the chlorine dioxide or other sanitizing agents solution, a specially trained service technician is often required to remain on-site until the solution is completely flushed out, thus further adding to the financial burden associated with these prior treatment procedures.
- The flushing process itself often significantly extends the system downtime of the prior treatment procedures because of a residue left in the system lines by the prolonged static exposure to the chlorine or other sanitizing agents solution. This residue is often difficult to remove, and even low levels of such residue may be considered toxic or noxious, thus requiring the repeated flushing of the system.
- It would be beneficial therefore, to provide a system and method for delivering controlled doses of chlorine dioxide or other sanitizing agents into a pressurized water system, which overcomes the deficiencies of the prior art.
- The present invention provides new and useful systems and methods for delivering controlled doses of chlorine dioxide or other sanitizing agents into a pressurized potable water system which overcomes the problems associated with the prior art.
- A medium having a support structure with an inlet configured for receiving a fluid, an outlet configured for delivering a fluid and a body configured for circulating a fluid therein, such as a replaceable filter cartridge, which includes a sanitizing agent containing one or more reactants that are chemically configured for releasing a compound having sanitizing properties, such as chlorine dioxide, in a controlled dose upon being wetted by the fluid and positioned within the medium to be exposed to the fluid circulating therein.
- Preferably, the sanitizing agent releases chlorine dioxide or other sanitizing agents in specific amounts, at a specific and controlled constant rate, to sanitize, deodorize, and disinfect equipment pipes connected to the medium outlet. The rate of chlorine dioxide or other sanitizing agents release would be set to dilute in water with a constant flow rate for a duration equivalent to perform the desired task, such as sanitize, deodorize, or disinfect water lines and equipment wetted parts.
- The preferred mediums to be used in accordance with the present invention include systems or disposable cartridges. In particular, the present invention, is directed to a system for delivering a sanitizing agent to a fluid, which includes a substantially hollow vessel and a sanitizing agent having one or more reactants which are chemically configured to release a compound having sanitizing properties upon exposure to the fluid. The hollow vessel includes an inlet passage configured for receiving fluid flow, an outlet passage configured for fluid egress, and an interior chamber configured for receiving fluid from the inlet passage and providing temporary confinement of the fluid therein prior to egress from the outlet passage. The sanitizing agent is disposed in the chamber and the confinement of water therein may be provided by an independent valve.
- The present invention is also directed to a filter cartridge that includes a hollow housing with a filter media chamber defined therein and a sanitizing agent disposed in the filter media chamber. The sanitizing agent preferably includes one or more reactants which are chemically configured to release a compound having sanitizing properties upon exposure to the fluid in the filter media chamber.
- There can be inlet passage in the housing configured to provide fluid communication with the chamber and an outlet passage in the housing configured to provide fluid communication with the chamber. The fluid is directed to the inlet passage and flows through the filter media chamber, exiting the outlet passage with chlorine dioxide or other sanitizing agents from a portion of fluid included therewith having been exposed to the sanitizing agent in the filter media chamber.
- Preferably, the fluid is water and the compound is chlorine dioxide or other sanitizing agents, in which case, the one or more reactants can include a chlorite and the release of chlorine dioxide or other sanitizing agents is initiated by contact with the water. The chlorite may be an aqueous soluble chlorite selected from the group consisting of sodium chlorite and potassium chlorite and mixtures thereof. Preferably, the one or more reactants include an aqueous soluble chlorite and an aqueous soluble acid. Preferably, the aqueous soluble acid is selected from the group consisting of phosphoric acid, fumaric acid, glycolic acid, acetic acid, ascorbic acid, oxalic acid, maleic acid, lactic acid, tartaric acid, citric acid and mixtures thereof.
- In addition, the system or filter cartridge of the present invention may also include a filtration media disposed in the chamber along with the sanitizing agent. The filtration media may be configured to provide chemical or mechanical filtration depending on the application. Preferably, the filtration media and sanitizing agent are disposed in the chamber and configured so that fluid entering the chamber is first exposed to the filtration media prior to being exposed to the sanitizing agent and exiting the outlet.
- In another embodiment which can be implemented in any medium (e.g., cartridge or system) constructed in accordance with the present invention, a solution may be disposed in the chamber that includes a second compound having sanitizing properties, such as chlorine. This solution is then mixed with fluid flowing in the chamber and exits through the outlet passage.
- In yet another embodiment which can be implemented in any medium constructed in accordance with the present invention, a substantially hollow neck is mated with the chamber. The neck has an inlet port in fluid communication with an inlet passage that is configured to be in fluid communication with the chamber, and an outlet port in fluid communication with an outlet passage that is also configured to be in fluid communication with the chamber. The inlet passage and outlet passage are both disposed in the neck and configured to provide dual fluid flow within the neck and independent fluid communication with the chamber.
- The aforementioned embodiment may further include a tubular member disposed axially in the neck and having a portion with a porous periphery extending into the chamber. The tubular member defines an inner axial passage therein and a radially outer axial passage bounded by the periphery of the tubular member and inner surface of the neck. Thus, the outer axial passage and the inner axial passage can provide the inlet and outlet passages, respectively. A filtration media may be disposed along the porous periphery of the portion of the tubular member extending into the filter media chamber and the sanitizing agent can be disposed within the inner axial passage of the portion of the tubular member extending into the chamber. Preferably, the sanitizing agent is separated from the filtration media by an inert porous divider.
- In yet another embodiment which can be implemented in any medium constructed in accordance with the present invention, a second outlet port may be added to the housing or vessel at a position where it will be in fluid communication with the chamber, and adjacent relative to the position of the sanitizing agent within the chamber, so that a majority or substantially all of the fluid exposed to the sanitizing agent exits this second outlet.
- Further features of the subject invention will become more apparent from the detailed description of the present invention that follows taken in conjunction with the drawings.
- So that those having ordinary skill in the art to which the present application appertains will more readily understand how to make and use the same, reference may be had to the drawings wherein:
-
FIG. 1 is a representative illustration of a system for providing controlled dosing of chlorine dioxide or other sanitizing agents to sanitize and clean equipment pipes or lines constructed in accordance with a preferred embodiment of the present invention, which depicts the system including a dry sanitizing agent, which releases chlorine dioxide or other sanitizing agents upon wetting with water, and a liquid sanitizing agent and a filter head for connecting the system with the equipment; -
FIG. 2 is a representative illustration of a filter cartridge for providing controlled dosing of chlorine dioxide or other sanitizing agents to sanitize and clean equipment pipes or lines constructed in accordance with a preferred embodiment of the present invention, including a dry sanitizing agent, which releases chlorine dioxide or other sanitizing agents upon wetting with water, a filtration media, a first outlet for water exposed to the filtration media, and a second outlet for providing water exposed to the sanitizing agent; and -
FIG. 3 is a representative illustration of a filter cartridge for providing controlled dosing of chlorine dioxide or other sanitizing agents to sanitize and clean equipment pipes or lines constructed in accordance with a preferred embodiment of the present invention, including a dry sanitizing agent, which releases chlorine dioxide or other sanitizing agents upon wetting with water and a filtration media, wherein the outlet stream from the filter cartridge contains a blend of water exposed to the filtration media and water exposed to the sanitizing agent. - These and other features of the subject invention will become more readily apparent to those having ordinary skill in the art from the following description of the preferred embodiment.
- In the following detailed description of the present invention, references are made to the accompanying drawings, which form a part hereof, and in which is shown by way of illustration specific embodiments in which the invention may be practiced. These embodiments are described in sufficient detail to enable those skilled in the art to practice the invention, and it is to be understood that other embodiments may be utilized and that structural changes may be made without departing from the spirit and scope of the present invention. The following detailed description is, therefore, not to be taken in a limiting sense, and the scope of the present invention is defined by the appended claims and equivalents thereof.
- The present invention provides vehicles, such as replaceable filter cartridges, for delivering chlorine dioxide or other sanitizing agents to a water system in a variety of controlled doses periodically by exposure of the water in the system to sanitizing or cleaning agents. These agents may include stable dry chemicals such as, but not limited to, those which are disclosed in the herein incorporated Published International Patent Application No. 01/60750A3 (PCT/US01/05002), capable of generating chlorine dioxide or other sanitizing agents when wetted. Preferably, the agent or agents release a specific amount of chlorine dioxide or other sanitizing agents, at a specific and controlled constant rate. The rate of chlorine dioxide or other sanitizing agents release would be set to dilute in water with a constant flow rate for a duration equivalent to clean (sanitize) water lines and equipment wetted parts.
- Referring now to the drawings wherein like reference numerals identify similar structural features of the invention, there is illustrated in
FIG. 1 , a representative depiction of a stand-alone type system for providing controlled dosing of sanitizer/cleaner into pressurized water systems which is constructed in accordance with a preferred embodiment of the subject invention and designated generally byreference numeral 10. -
System 10 includes apressure vessel 12 having afirst end 14 and asecond end 16 defining a hollowed out, generallycylindrical chamber 18 therein.First end 14 has aneck 20 which has aninlet port 22 in fluid communication with an inlet passage for directing fluid flow intochamber 18 according to arrow 24 (hereinafter referred to as “inlet passage 24”).Neck 20 also includes anoutlet port 26 in fluid communication with anoutlet tube 28 which extends axially intochamber 18. In this embodiment,neck 20 also includes an optional bypass passage which provides fluid communication betweeninlet passage 24 andoutlet port 26 in accordance with arrow 30 (hereinafter referred to as “bypass passage 30”).Chamber 18 includes anunfilled region 32 adjacentfirst end 14, afirst treatment region 34 containing adry sanitizing agent 36 with controlled reaction dissolution and asecond treatment region 38 containing a concentrated sanitizingliquid 40 adjacentsecond end 16.First treatment region 34 andsecond treatment region 38 are separated from each other by a porousinert divider 42. Sanitizingliquid 40 is preferably chlorine and may also include a dye indicator for facilitating awareness of its exhaustion. -
System 10 is attachable to the water supply line (not shown) to a master system (not shown), such as a beverage preparation device or ice making machine, via afilter head 44 having afirst line 46 for receiving fluid from a supply line (not shown), asecond line 48 for providing fluid to the master system and atreatment device port 50.Filter head 44 may be constructed with or retrofitted onto the supply line or any other lines in the master system.System 10 may also be connected to the master system in other ways, such as by a permanent connection having flow control valves.Treatment device port 50 separatesfirst line 46 andsecond line 48 and to provide a space in whichneck 20 ofsystem 10 may be inserted.Filter head 44 may also include a line pressure bypass with constant flow rate. The flow rate may vary depending on the application but typically ranges from about 0.25 gallons per minute to about 5.0 gallons per minute. - Preferably, the outer periphery of
neck 20 and the inner surface oftreatment device port 50 are configured to be engaged by corresponding cooperative structures defined respectively thereon. The cooperative structures may consist of a proprietary interconnection Also, it is preferable thatneck 20 andtreatment device port 50 be sealingly engaged (e.g., using water resistant sealing rings fabricated of an elastomeric material) to maintain the integrity of fluid communication between thefirst line 46 andinlet port 22, and betweenoutlet port 26 andsecond line 48, respectively. - Once
system 10 is installed in filter head 44 (i.e.,neck 20 is engaged with treatment device port 50), water is provided tofirst line 46 and allowed to enterinlet port 22. A portion of the water flow enteringinlet port 22 will travel throughinlet passage 24 intochamber 18 while the remaining portion of water flow will travel throughbypass passage 30.Bypass passage 30 is configured to direct the water flowing therein throughoutlet port 26 sans treatment, to be diluted with the treated water also exiting fromoutlet port 26. The water flowing throughinlet passage 24 pours intounfilled region 32 ofchamber 18 creating turbulence as indicated byarrows 52 which facilitates better mixing of the untreated water and greater contact with the sanitizers intreatment regions chamber 18. - The pressure of the incoming flow forces water within
unfilled region 32 throughfirst treatment region 34,porous divider 42, andsecond treatment region 38 before exitingchamber 18 viaoutlet tube 28. As the water passes throughtreatment regions agent 36 and concentrated sanitizingliquid 40. The flow fromoutlet tube 28 mixes with untreated water flowing fromoutlet 26 via bypass passage 30 (if included) before being directed to the master system viasecond line 48 infilter head 44. Preferably, for this embodiment, the water flowing to the master system contains about 0.1 parts per million of sanitizer to about 10 parts per million of sanitizer after passage throughsystem 10. - Another preferred embodiment of the present invention is represented by the depiction in
FIG. 2 of a filter cartridge having a separate sanitizer stream for providing controlled dosing of sanitizer/cleaner into pressurized water systems, which is constructed in accordance with the subject invention and designated generally byreference numeral 110. -
System 110 includes afilter cartridge housing 112 having afirst end 114 and asecond end 116 defining a hollowed out, generallycylindrical chamber 118 therein.First end 114 has aneck 120 which has aninlet port 122 in fluid communication with an inlet passage for directing fluid flow intochamber 118 according to arrow 124 (hereinafter referred to as “inlet passage 124”).Neck 120 also includes anoutlet port 126 in fluid communication with anoutlet tube 128 extending axially intochamber 118. In this embodiment,filter cartridge housing 112 also includes aseparate sanitizer line 154 that draws fluid fromchamber 118 adjacent tosecond end 116 offilter cartridge housing 112. -
Chamber 118 includes an axially disposed, radiallyporous center core 156 and radially outerfirst treatment region 134 containing afiltration media 158 adjacentfirst end 114, which may be mechanical or chemical in nature (e.g., a peat block, screen, activated carbon block, sediment block, granular media, etc.), and which substantially surroundscenter core 156.Center core 156 includes a first openaxial end 160 adjacent tofirst end 114 offilter cartridge housing 112 and a second openaxial end 162 adjacent tosecond end 116 offilter cartridge housing 112. - The second
open end 162 ofcenter core 156 is adjacent to asecond treatment region 138 containing adry sanitizing agent 136 with controlled reaction dissolution.First treatment region 134 andsecond treatment region 138 are separated by a porousinert divider 142. In addition,filtration media 158 is configured and dimensioned to fit withinfilter cartridge housing 112 to define an unfilledannular region 132 between the inner circumferential surface ofchamber 118 and the outer periphery offiltration media 158 for fluid flow therebetween, as illustrated byarrows 164. -
Filter cartridge 110 is attachable to a supply line (not shown), preferably located within the housing of a master system (not shown), such as a beverage preparation device or ice making machine. This may be accomplished via a filter head (not shown) as in the previous embodiment or other connection having a port configured to engageneck 120. - When
system 110 is in use, water pumped through the supply line entersinlet port 122 and flows intochamber 118 throughinlet passage 124 inneck 120 offilter cartridge housing 112. As illustrated byarrows 164, the water flows through the unfilledannular region 132 and is pushed radially inward by the fluid pressure created incartridge housing 112. The water is forced throughfiltration media 158 and intocenter core 156. A portion of the water flow incenter core 156 is directed towardsfirst end 114 and intooutlet tube 128, eventually exitingfilter cartridge housing 112 throughoutlet port 126, as illustrated byarrows 166. Preferably, the majority of the water flow follows the path shown byarrows 166. - A portion of the water entering unfilled
annular region 132 flows axially towardsecond end 116 inchamber 118 and intosecond treatment region 138 through porousinert divider 142 without passing throughfiltration media 158, as illustrated byarrow 168. A portion of the water flow incenter core 156 which has passed throughfiltration media 158 is directed by pressure, or lack thereof, towardsecond end 116. This flow of treated waterexits center core 156 from secondopen end 162 and enters intosecond treatment region 138 through porousinert divider 142, as illustrated byarrow 170. Water flowing withinsecond treatment region 138 contactsdry sanitizing agent 136 and then exitsfilter cartridge housing 112 throughseparate sanitizer line 154. The water exposed todry sanitizing agent 136 may be controlled by acontrol valve 172 insanitizer line 154. - Another preferred embodiment of the present invention is represented by the depiction in
FIG. 3 of a filter cartridge having an encapsulated sanitizing agent for providing controlled dosing of sanitizer/cleaner into pressurized water systems, which is constructed in accordance with the subject invention and designated generally byreference numeral 210. -
System 210 includes afilter cartridge housing 212 having afirst end 214 and asecond end 216 defining a hollowed out, generallycylindrical chamber 218 therein.First end 214 has aneck 220 which has aninlet port 222 in fluid communication with an inlet passage for directing fluid flow intochamber 218 according to arrow 224 (hereinafter referred to as “inlet passage 224”).Neck 220 also includes anoutlet port 226 in fluid communication with anoutlet tube 228 extending axially intochamber 218. -
Chamber 218 includes an axially disposed, radiallyporous center core 256 and radially outerfirst treatment region 234 containing afiltration media 258 that extends axially substantially fromfirst end 214 tosecond end 216 and substantially surroundscenter core 256.Filtration media 258 is configured and dimensioned to provide an unfilledannular region 232 between the inner circumferential surface ofchamber 218 and the outer periphery offiltration media 258 for fluid flow therebetween, as illustrated byarrows 264. -
Filtration media 258 may be mechanical or chemical in nature (e.g., a peat block, screen, activated carbon block, sediment block, granular media, etc.). -
Center core 256 includes an openaxial end 260 adjacent tofirst end 214 offilter cartridge housing 212 and asecond treatment region 238 containing adry sanitizing agent 236 with controlled reaction dissolution adjacent tosecond end 216 offilter cartridge housing 212. An axially disposed porousinert divider 242 separatessecond treatment region 238 from the remaining portion ofcenter core 256. -
Filter cartridge 210 is attachable to a supply line (not shown), preferably located within the housing of a master system (not shown), such as a beverage preparation device or ice making machine. This may be accomplished via a filter head (not shown) as in the previous embodiments or other connection having a port configured to engageneck 220. - In use, water is pumped through supply line and flows from
inlet port 222 tochamber 218 throughinlet passage 224 inneck 220 offilter cartridge housing 212. As illustrated byarrows 264, the water flows through the unfilledannular region 232 and is pushed radially inward by fluid pressure. Water is forced throughfiltration media 258 and intocenter core 256, where it makes its way intooutlet tube 228 and exitscartridge housing 212 throughoutlet port 226, as illustrated byarrows 266. - A portion of the water flow forced through
filtration media 258 also enterssecond treatment region 238 and contactsdry sanitizing agent 236, as illustrated byarrow 268. The water exposed todry sanitizing agent 236 flows through porousinert divider 242, as shown byarrows 270, where it mixes with water which has not been treated bydry sanitizing agent 236 before exitingfilter cartridge housing 212, as described above. - Preferably, predetermined amounts of
dry sanitizing agent 236 is encapsulated in a sanitary cartridge such ascartridge -
System 10 andcartridges - Various doses of chlorine dioxide or other sanitizing agents may be administered via the systems and cartridges of the present invention. For example, the periodic high dosing of chlorine dioxide or other sanitizing agents may be accomplished by utilizing predetermined amounts of a sanitizing agent that also allows full flow through the cartridge. Once installed, water can be introduced into a system or cartridge of the present invention is filled with the outlet port restricted. Once wetted the agent would generate chlorine dioxide or other sanitizing agents within the cartridge for a predetermined period of time, until a high level (e.g. 50 parts per million to 100 parts per million) is dissolved into the water in the system or cartridge chamber. The outlet port may be opened when ready and the chlorine dioxide or other sanitizing agents rich water can be forced by water pressure downstream into the water lines and equipment wetted parts, thereby stripping biofilm therefrom.
- The concentrated solution may be allowed to reach all exit ports of the downstream equipment. Thereafter, the outlet line of the master system can be shut off. The chlorine dioxide or other sanitizing agents rich solution may be held for a predetermined amount of time (e.g., from twenty minutes to several hours) to facilitate the stripping of biofilm build-up in the master system lines and sanitize the water and wetted equipment parts. The master system can then be flushed for a prescribed amount of time so as to clear the water lines and cartridge of any remaining chlorine dioxide or other sanitizing agents residue. One of the advantages of using chlorine dioxide or other sanitizing agents is its powerful oxidation capabilities and the ease by which residue is flushed out of the system.
- For high dosing as described above, the rate of chlorine dioxide or other sanitizing agents generation is rapid, but its release from the cartridge or stand alone system can be set to dilute in water with a constant flow rate, preferably between 50 parts per million and 100 parts per million, for a duration equivalent to fill water lines and equipment wetted parts.
- Low doses of chlorine dioxide or other sanitizing agents (i.e., about 0.1 parts per million to about 0.5 parts per million) can also be delivered into the water system periodically by exposure of the water in the system to sanitizing or cleaning agents contained in a system or cartridge constructed in accordance with the present invention. For example, a low-level chlorine dioxide or other sanitizing agents dosing agent may be incorporated into a cartridge, such as
cartridge 210, which are constructed in accordance with the present invention, along with other reduction, removal or absorptive capabilities, or combinations thereof. Upon installation, the agent can generate chlorine dioxide or other sanitizing agents at a low controlled rate for a short duration. Preferably, the chlorine dioxide or other sanitizing agents generation occurs at a location that is downstream of any absorbent media within the same cartridge. As water enters the filter cartridge, chlorine dioxide or other sanitizing agents generation begins. The absorbent and reduction media would perform as normal for their prescribed life (e.g., 3 months, 6 months or 1 year), while the chlorine dioxide or other sanitizing agents generation would end within the first few minutes of use (e.g., from about 5 to about 20 minutes). The net result would be the periodic sanitization of water lines and equipment wetted parts with the convenience of a standard cartridge replacement. - In addition, a system or cartridge constructed in accordance with the present invention provides for the safe transportation and handling of chlorine dioxide or other sanitizing agents producing agents, controlled low level dosing rate in a dynamic flowing condition, controlled dosing duration, and system or cartridge formats and head assemblies which can introduce chlorine dioxide or other sanitizing agents into a pressurized water line.
- While the present invention has been described with respect to preferred embodiments, those skilled in the art will readily appreciate that various changes and/or modifications can be made to the present invention without departing from the spirit or scope of the invention. For example, a filter cartridge may be constructed having a sanitizing agent in accordance with the present invention and with a bypass feature such as, but not limited to, those filter cartridges which are disclosed in the herein incorporated, copending and commonly owned U.S. patent application Ser. No. 10/337,832filed on Jan. 7, 2003.
Claims (6)
1. A system for delivering controlled doses of a sanitizing agent to a fluid, comprising:
a disposable substantially hollow pressure vessel having an inlet passage configured for receiving fluid flow, an outlet passage configured for fluid egress, and an interior chamber configured for receiving fluid from the inlet passage and providing temporary confinement of the fluid therein prior to egress from the outlet passage;
one or more reactants operatively disposed in the chamber which form a sanitizing solution upon contact with the fluid as it enters the chamber, wherein further mixing of the fluid and the solution occurs within the chamber prior to egress through the outlet passage.
2. The system of claim 1 , wherein the reactants form a solution of chlorine dioxide in water.
3. The system of claim 1 , wherein the system provides the sanitizing solution to equipment lines or pipes.
4. The system of claim 1 , wherein the disposable substantially hollow pressure vessel is replaced after each sanitizing operation.
5. A The system of claim 1 , wherein the disposable substantially hollow pressure vessel also contains filtration media.
6. The system of claim 1 , wherein the sanitizing solution also has a dye indicator for facilitating awareness of the presence of the sanitizing agent in the fluid and the subsequent exhaustion thereof from the fluid.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/468,563 US20070084772A1 (en) | 2002-03-20 | 2006-08-30 | Controlled dosing of chlorine dioxide or other sanitizing agents into pressurized water systems |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US36614402P | 2002-03-20 | 2002-03-20 | |
US10/392,670 US6913691B2 (en) | 2002-03-20 | 2003-03-18 | Controlled dosing of chlorine dioxide or other sanitizing agents into pressurized water systems |
US11/096,537 US7112276B2 (en) | 2002-03-20 | 2005-04-01 | Controlled dosing of chlorine dioxide of other sanitizing agents into pressurized water systems |
US11/468,563 US20070084772A1 (en) | 2002-03-20 | 2006-08-30 | Controlled dosing of chlorine dioxide or other sanitizing agents into pressurized water systems |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/096,537 Continuation US7112276B2 (en) | 2002-03-20 | 2005-04-01 | Controlled dosing of chlorine dioxide of other sanitizing agents into pressurized water systems |
Publications (1)
Publication Number | Publication Date |
---|---|
US20070084772A1 true US20070084772A1 (en) | 2007-04-19 |
Family
ID=28454756
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/392,670 Expired - Fee Related US6913691B2 (en) | 2002-03-20 | 2003-03-18 | Controlled dosing of chlorine dioxide or other sanitizing agents into pressurized water systems |
US11/096,537 Expired - Fee Related US7112276B2 (en) | 2002-03-20 | 2005-04-01 | Controlled dosing of chlorine dioxide of other sanitizing agents into pressurized water systems |
US11/468,563 Abandoned US20070084772A1 (en) | 2002-03-20 | 2006-08-30 | Controlled dosing of chlorine dioxide or other sanitizing agents into pressurized water systems |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/392,670 Expired - Fee Related US6913691B2 (en) | 2002-03-20 | 2003-03-18 | Controlled dosing of chlorine dioxide or other sanitizing agents into pressurized water systems |
US11/096,537 Expired - Fee Related US7112276B2 (en) | 2002-03-20 | 2005-04-01 | Controlled dosing of chlorine dioxide of other sanitizing agents into pressurized water systems |
Country Status (8)
Country | Link |
---|---|
US (3) | US6913691B2 (en) |
EP (1) | EP1482991B1 (en) |
JP (1) | JP2006502836A (en) |
CN (1) | CN1642582A (en) |
AU (1) | AU2003225885A1 (en) |
BR (1) | BR0308272A (en) |
DE (1) | DE60331183D1 (en) |
WO (1) | WO2003080128A1 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20110121036A1 (en) * | 2008-07-21 | 2011-05-26 | Bassett Laurence W | Apparatus for dispersing additive into a fluid stream |
US9314716B2 (en) | 2012-11-12 | 2016-04-19 | Whirlpool Corporation | Customizable multi-stage water treatment assembly |
US9320993B2 (en) | 2012-11-12 | 2016-04-26 | Whirlpool Corporation | Filter housing for small media |
US9327216B2 (en) | 2012-11-12 | 2016-05-03 | Whirlpool Corporation | Customizable multi-stage water treatment system |
US9889478B2 (en) | 2012-11-12 | 2018-02-13 | Whirlpool Corporation | Consumable descaling cartridges for a refrigerator appliance |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5910329A (en) * | 1992-01-23 | 1999-06-08 | Rhodia Inc. | Process for producing frozen yogurt mix using S. thermophilus starter culture |
US6913691B2 (en) * | 2002-03-20 | 2005-07-05 | Cuno Incorporated | Controlled dosing of chlorine dioxide or other sanitizing agents into pressurized water systems |
FR2861604B1 (en) * | 2003-10-29 | 2007-02-16 | Millipore Corp | PURIFICATION MODULE OF A FLUID CONTAINING A CLEANING AGENT, AND METHODS OF MAKING AND USING SUCH A MODULE |
US7153422B2 (en) * | 2004-01-29 | 2006-12-26 | Fleetguard, Inc. | Liquid additive slow-release apparatus driven by a filter pressure gradient |
US7297256B2 (en) * | 2004-01-29 | 2007-11-20 | Fleet Guard, Inc. | Pressure gradient dosing system for fluid supply |
US7156991B2 (en) * | 2004-01-29 | 2007-01-02 | Fleetguard, Inc. | Liquid additive slow-release apparatus driven by a filter pressure gradient |
US7122116B2 (en) * | 2004-02-24 | 2006-10-17 | R-Kind Water Systems, Inc. | Water treatment system |
US20060120928A1 (en) * | 2004-11-12 | 2006-06-08 | William Annacone | Chlorine dioxide generator |
KR100762221B1 (en) | 2006-08-03 | 2007-10-04 | 대한민국(관리부서:농촌진흥청장) | Apparatus removing bad smell at compostizing facility of dung using chlorine dioxide |
MX2009010976A (en) * | 2007-04-18 | 2009-10-30 | Unilever Nv | Disinfectant device and process. |
IT1394464B1 (en) * | 2009-07-03 | 2012-07-05 | Blupura Srl | SANITIZING FILTER FOR WATER DISPENSER |
US20120125845A1 (en) * | 2010-11-24 | 2012-05-24 | Mcdonald Neil K | Device and implementation for sanitizing a fluid-dispensing appliance |
DE102012207472C5 (en) * | 2012-05-04 | 2018-05-03 | Fritz Küke | Apparatus and process for the preparation of aqueous chlorine dioxide solutions and storage units and kits for the corresponding use |
US9309135B2 (en) * | 2012-05-16 | 2016-04-12 | Perfect Water Technologies, Inc. | Methods and apparatus for delivery system for water enhancements |
EP3407734B1 (en) | 2016-01-25 | 2023-03-08 | Signify North America Corporation | Biosecurity system for an agricultural dwelling |
US10780377B2 (en) * | 2016-11-30 | 2020-09-22 | Watts Regulator Co. | Sanitizing filter system and method for a residential water filtering system |
CN111565565A (en) * | 2017-12-22 | 2020-08-21 | 昕诺飞北美公司 | System and method for sanitizing eggs |
CN109455801B (en) * | 2018-12-24 | 2024-07-26 | 广州水如天环保科技有限公司 | Solid chlorine dioxide disinfection equipment |
US20200346957A1 (en) * | 2019-05-02 | 2020-11-05 | Dripping Wet Water, Inc. | Biofilm disruption leading to microbial destruction |
US12117110B2 (en) | 2021-11-11 | 2024-10-15 | Trevor Ned Trujillo | RV septic cleaner |
Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2546568A (en) * | 1945-01-11 | 1951-03-27 | Olin Mathieson | Process for the preservation of comestible materials |
US3183057A (en) * | 1958-11-03 | 1965-05-11 | Wallace & Tiernan Inc | Products and procedures for effecting treatiment with chlorinous gas |
US3754079A (en) * | 1972-05-19 | 1973-08-21 | Chemical Generators Inc | Process of preparing chlorine dioxide |
US4370305A (en) * | 1979-07-23 | 1983-01-25 | Hoelzle & Chelius Kg | Device for the sterilization of fluid substances |
US4547381A (en) * | 1983-11-10 | 1985-10-15 | Rio Linda Chemical Co., Inc. | Dry compositions for the production of chlorine dioxide |
US4689169A (en) * | 1983-11-10 | 1987-08-25 | Rio Linda Chemical Company, Inc. | Dry compositions for the production of chlorine dioxide |
US5019346A (en) * | 1988-09-21 | 1991-05-28 | Ecolab Inc. | Drain treatment product and method of use |
US5476579A (en) * | 1995-04-24 | 1995-12-19 | Choi; Hyeong S. | Process for generating chlorine dioxide and apparatus therefor |
US5772003A (en) * | 1995-11-22 | 1998-06-30 | Bio-Cide International, Inc. | Automatic lubrication injection sanitization system |
US5974810A (en) * | 1997-03-03 | 1999-11-02 | Engelhard Corporation | Method and composition for preventing odors in ice |
US6280617B1 (en) * | 1999-12-10 | 2001-08-28 | Brandreth, Iii John B. | Chemical dispenser |
US20010036421A1 (en) * | 1997-03-03 | 2001-11-01 | Engelhard Corporation | Method and system for the controlled release of chlorine dioxide gas |
US20040129627A1 (en) * | 2003-01-07 | 2004-07-08 | Mcgibbon Donald | Filter cartridge having bypass feature |
US6913691B2 (en) * | 2002-03-20 | 2005-07-05 | Cuno Incorporated | Controlled dosing of chlorine dioxide or other sanitizing agents into pressurized water systems |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5897770A (en) * | 1997-10-23 | 1999-04-27 | Plymouth Products, Inc. | Center core cartridge feeder insert |
MXPA02007993A (en) | 2000-02-18 | 2004-04-05 | Selective Micro Technologies L | Apparatus and method for controlled delivery of a gas. |
US6764661B1 (en) * | 2000-06-27 | 2004-07-20 | Avantec Technologies, Inc. | Device for producing an aqueous chlorine dioxide solution |
US7132865B1 (en) * | 2004-03-03 | 2006-11-07 | Atheros Communications, Inc. | Mitigating parasitic current that leaks to the control voltage node of a phase-locked loop |
-
2003
- 2003-03-18 US US10/392,670 patent/US6913691B2/en not_active Expired - Fee Related
- 2003-03-20 BR BR0308272A patent/BR0308272A/en not_active IP Right Cessation
- 2003-03-20 CN CNA038062739A patent/CN1642582A/en active Pending
- 2003-03-20 DE DE60331183T patent/DE60331183D1/en not_active Expired - Lifetime
- 2003-03-20 JP JP2003577953A patent/JP2006502836A/en not_active Abandoned
- 2003-03-20 AU AU2003225885A patent/AU2003225885A1/en not_active Abandoned
- 2003-03-20 WO PCT/US2003/008500 patent/WO2003080128A1/en active Application Filing
- 2003-03-20 EP EP20030745148 patent/EP1482991B1/en not_active Expired - Lifetime
-
2005
- 2005-04-01 US US11/096,537 patent/US7112276B2/en not_active Expired - Fee Related
-
2006
- 2006-08-30 US US11/468,563 patent/US20070084772A1/en not_active Abandoned
Patent Citations (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2546568A (en) * | 1945-01-11 | 1951-03-27 | Olin Mathieson | Process for the preservation of comestible materials |
US3183057A (en) * | 1958-11-03 | 1965-05-11 | Wallace & Tiernan Inc | Products and procedures for effecting treatiment with chlorinous gas |
US3754079A (en) * | 1972-05-19 | 1973-08-21 | Chemical Generators Inc | Process of preparing chlorine dioxide |
US4370305A (en) * | 1979-07-23 | 1983-01-25 | Hoelzle & Chelius Kg | Device for the sterilization of fluid substances |
US4547381A (en) * | 1983-11-10 | 1985-10-15 | Rio Linda Chemical Co., Inc. | Dry compositions for the production of chlorine dioxide |
US4689169A (en) * | 1983-11-10 | 1987-08-25 | Rio Linda Chemical Company, Inc. | Dry compositions for the production of chlorine dioxide |
US5019346A (en) * | 1988-09-21 | 1991-05-28 | Ecolab Inc. | Drain treatment product and method of use |
US5476579A (en) * | 1995-04-24 | 1995-12-19 | Choi; Hyeong S. | Process for generating chlorine dioxide and apparatus therefor |
US5772003A (en) * | 1995-11-22 | 1998-06-30 | Bio-Cide International, Inc. | Automatic lubrication injection sanitization system |
US5974810A (en) * | 1997-03-03 | 1999-11-02 | Engelhard Corporation | Method and composition for preventing odors in ice |
US20010036421A1 (en) * | 1997-03-03 | 2001-11-01 | Engelhard Corporation | Method and system for the controlled release of chlorine dioxide gas |
US6280617B1 (en) * | 1999-12-10 | 2001-08-28 | Brandreth, Iii John B. | Chemical dispenser |
US6913691B2 (en) * | 2002-03-20 | 2005-07-05 | Cuno Incorporated | Controlled dosing of chlorine dioxide or other sanitizing agents into pressurized water systems |
US7112276B2 (en) * | 2002-03-20 | 2006-09-26 | 3M Innovative Properties Company | Controlled dosing of chlorine dioxide of other sanitizing agents into pressurized water systems |
US20040129627A1 (en) * | 2003-01-07 | 2004-07-08 | Mcgibbon Donald | Filter cartridge having bypass feature |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20110121036A1 (en) * | 2008-07-21 | 2011-05-26 | Bassett Laurence W | Apparatus for dispersing additive into a fluid stream |
US8940163B2 (en) | 2008-07-21 | 2015-01-27 | 3M Innovative Properties Company | Apparatus for dispersing additive into a fluid stream |
US9314716B2 (en) | 2012-11-12 | 2016-04-19 | Whirlpool Corporation | Customizable multi-stage water treatment assembly |
US9320993B2 (en) | 2012-11-12 | 2016-04-26 | Whirlpool Corporation | Filter housing for small media |
US9327216B2 (en) | 2012-11-12 | 2016-05-03 | Whirlpool Corporation | Customizable multi-stage water treatment system |
US9889478B2 (en) | 2012-11-12 | 2018-02-13 | Whirlpool Corporation | Consumable descaling cartridges for a refrigerator appliance |
US10155669B2 (en) | 2012-11-12 | 2018-12-18 | Whirlpool Corporation | Customizable multi-stage water treatment system |
US10759675B2 (en) | 2012-11-12 | 2020-09-01 | Whirlpool Corporation | Customizable multi-stage water treatment system |
US11383990B2 (en) | 2012-11-12 | 2022-07-12 | Whirlpool Corporation | Customizable multi-stage water treatment system |
Also Published As
Publication number | Publication date |
---|---|
US20030209483A1 (en) | 2003-11-13 |
JP2006502836A (en) | 2006-01-26 |
WO2003080128A1 (en) | 2003-10-02 |
AU2003225885A1 (en) | 2003-10-08 |
EP1482991B1 (en) | 2010-02-03 |
US6913691B2 (en) | 2005-07-05 |
BR0308272A (en) | 2005-01-04 |
US20050167349A1 (en) | 2005-08-04 |
EP1482991A1 (en) | 2004-12-08 |
DE60331183D1 (en) | 2010-03-25 |
CN1642582A (en) | 2005-07-20 |
US7112276B2 (en) | 2006-09-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US7112276B2 (en) | Controlled dosing of chlorine dioxide of other sanitizing agents into pressurized water systems | |
CN100398459C (en) | Water treatment cartridge | |
US11891311B2 (en) | Process and system for back-and-forth washing of adsorptive media | |
US5556279A (en) | Water purification system for dental instrument | |
US4228000A (en) | Water treatment apparatus with means for automatic disinfection thereof | |
US5552057A (en) | Water-purifying device | |
US6274038B1 (en) | Water purifier with adjustable volume in dwell passage | |
JP2006502836A5 (en) | ||
CA2475443C (en) | Method for sterilisation and cleaning of water supply systems, in particular in swimming and bathing pool units and device for carrying out the same | |
US20150175461A1 (en) | Method and Apparatus for Sanitizing a Treated Water Supply of Unsatisfactory Quality to Produce a Potable Water Supply of Satisfactory Quality | |
JPH09182684A (en) | Water tank provided with chemical sustained release device | |
KR100552978B1 (en) | Manufacturing equipment for sterilized water with Uzone applied reactor in ozone-contact | |
WO1999062625A1 (en) | Liquid medicine preparing device | |
KR200344145Y1 (en) | Manufacturing equipment for sterilized water with Uzone applied reactor in ozone-contact | |
EP1901860B1 (en) | Device and method for cleaning and/or disinfecting filters | |
KR20230163154A (en) | Chlorine dioxide water manufacturing kit | |
JPH115084A (en) | Method of purifying water and water purifier | |
JPH02284610A (en) | Circulation device for bath | |
JPH06205947A (en) | Permeable membrane filtering device capable of sterilizing backwash water by ultraviolet rays | |
IE20130056U1 (en) | A method and apparatus for sanitising a treated water supply of unsatisfactory quality to produce a potable water supply of satisfactory quality | |
IES86231Y1 (en) | A method and apparatus for sanitising a treated water supply of unsatisfactory quality to produce a potable water supply of satisfactory quality |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |