US20060151494A1 - Fuel container for fuel cell - Google Patents

Fuel container for fuel cell Download PDF

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Publication number
US20060151494A1
US20060151494A1 US10/563,097 US56309705A US2006151494A1 US 20060151494 A1 US20060151494 A1 US 20060151494A1 US 56309705 A US56309705 A US 56309705A US 2006151494 A1 US2006151494 A1 US 2006151494A1
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United States
Prior art keywords
fuel
container
main body
container main
housing
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Abandoned
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US10/563,097
Inventor
Yasuaki Nakamura
Hideto Usui
Satoshi Komiyama
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Tokai Corp
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Tokai Corp
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Assigned to TOKAI CORPORATION reassignment TOKAI CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KOMIYAMA, SATOSI, NAKAMURA, YASUAKI, USUI, HIDETO
Publication of US20060151494A1 publication Critical patent/US20060151494A1/en
Abandoned legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04201Reactant storage and supply, e.g. means for feeding, pipes
    • H01M8/04208Cartridges, cryogenic media or cryogenic reservoirs
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Definitions

  • the present invention relates to a fuel container for housing and directly supplying fuel, such as methanol solution, to a fuel cell, such as a polymer electrolyte fuel cell (PEFC)
  • a fuel container for reinjecting fuel into a fuel container, which is mounted on a fuel cell.
  • Conventional containers for housing solutions include aerosol containers, and cosmetic containers, for example.
  • glass, metal, or plastic is used as the material of the main bodies of the containers.
  • These containers are pressurized such that when nozzles thereof are opened, the solutions stored therein are sprayed out for use.
  • springs are utilized as urging members for urging the nozzles in the closing direction.
  • metallic coil springs are generally used.
  • cylindrical urging members constituted by elastic resin materials have been proposed (refer to Japanese Unexamined Patent Publication No. 11 (1999)-90282, for example)
  • fuel cells as miniature power sources for devices such as portable computers (laptop PC's, PDA's and the like) is being contemplated.
  • Fuel containers are necessary to supply fuel to these fuel cells.
  • the fuel cell is a polymer electrolyte fuel cell (hereinafter, referred to simply as PEFC)
  • PEFC polymer electrolyte fuel cell
  • methanol and distilled water ethanol and distilled water
  • pure methanol or pure ethanol
  • dimethyl ether is expected to be used as fuel for solid oxide fuel cells (hereinafter, referred to simply as SOFC) and PEFC's.
  • SOFC solid oxide fuel cells
  • the shape of the fuel container is set according to the shape of the fuel cell itself, or the shape of a fuel container housing portion of a device, such as a laptop PC. Therefore, it is disadvantageous from the viewpoint of cost to dispose of fuel containers, which have been provided in shapes according to specific devices, once the fuel therein is consumed. In addition, such fuel containers easily become difficult to obtain, which is inconvenient.
  • the present invention has been developed in view of the aforementioned points. It is an object of the present invention to provide a fuel container for fuel cells that prevents contamination of fuel by metallic ions and propellant, and which is reusable. It is another object of the present invention to provide a fuel container that reinjects fuel into fuel containers, which are mounted on fuel cells.
  • a first fuel container for housing fuel to be supplied to a fuel cell of the present invention comprises:
  • a second fuel container for housing fuel to be supplied to a fuel cell of the present invention comprises:
  • a third fuel container for housing fuel to be supplied to a fuel cell of the present invention comprises:
  • a fourth fuel container for housing fuel to be supplied to a fuel cell of the present invention comprises:
  • each of the above fuel containers prefferably be formed by a transparent material.
  • the fuel containers of the present invention are suited to house fuels for PEFC's, such as methanol and distilled water, ethanol and distilled water, pure methanol, and pure ethanol.
  • the fuel containers of the present invention may also be utilized to house fuel for SOFC's and PEFC's, such as dimethyl ether.
  • Each of the fuel containers of the present invention comprises: a container main body; an inner container for housing fuel; and a valve mechanism for enabling/disabling supply of fuel. All of the structural components that contact the fuel are formed by non-metallic materials, and compressed gas is sealed between the container main body and the inner container. Therefor, only the fuel can be ejected and supplied. Further, contamination by metallic ions can be prevented, because the housed fuel does not contact any metal. Particularly, in fuel cells such as PEFC's, contamination of fuel, such as methanol solution and ethanol solution by metallic ions is to be avoided. By forming the members that contact the fuel with non-metallic materials, the release of metallic ions can be avoided. Thereby, fuel containers to be mounted onto fuel cells to directly supply fuel thereto, and fuel containers to reinject fuel to fuel containers, which are mounted onto fuel cells, can be produced without decreasing the performance of the fuel cells.
  • the fuel container comprises an injection valve, through which fuel can be reinjected, or if the valve mechanism is configured to enable both supply and injection, users can easily refill the fuel container, by utilizing a fuel container configured to reinject fuel.
  • This is advantageous from the viewpoint of cost, and the degree of freedom regarding shapes corresponding to devices is improved.
  • additional fuel will become commonly available, by providing universal reinjecting fuel containers, which will improve convenience.
  • compressed gas for ejecting the fuel is sealed between the container main body and the inner container at a pressure higher than a fuel pressure of a fuel container, which is mounted on the fuel cell to directly supply fuel thereto.
  • the fourth fuel container of the present invention comprises: a cylindrical container main body for housing the fuel therein; and a piston shaped extruding member, which is manually operated.
  • the third and fourth fuel containers are capable of reinjecting fuel into fuel containers that directly supply fuel to fuel cells.
  • the shapes of the third and fourth fuel containers can be set as desired.
  • the third and fourth fuel containers can be constructed according to considerations regarding fuel capacity and portability, thereby improving convenience.
  • the container main body of each of the fuel containers of the present invention may be formed by a transparent material. In this case, the amount of remaining fuel and states of reinjection can be visually confirmed.
  • the fuel containers may be formed into various shapes, such as cylinders, polygons, ovals, and the like. Classification during disposal is facilitated, which is suitable for recycling. Thermal properties are favorable compared to metal, which is cold to the touch. Changes in the contents due to corrosion are not likely to occur.
  • FIG. 1 is a schematic sectional view illustrating a fuel container to be mounted on a fuel cell, according to a first embodiment of the present invention.
  • FIG. 2A is a sectional view of the main parts of a valve mechanism.
  • FIG. 2B is a sectional view of the main parts of an alternate valve mechanism.
  • FIG. 3 is a schematic sectional view illustrating a fuel container to be mounted on a fuel cell, according to a second embodiment of the present invention.
  • FIG. 4 is a schematic sectional view illustrating a fuel container for reinjecting fuel, according to a third embodiment of the present invention.
  • FIG. 5 is a schematic sectional view illustrating a fuel container for reinjecting fuel, according to a fourth embodiment of the present invention.
  • FIG. 1 is a schematic sectional view illustrating a fuel container 1 to be mounted on a fuel cell, according to a first embodiment of the present invention.
  • FIGS. 2A and 2B are sectional view of main parts of valve mechanisms.
  • the fuel container 1 of the first embodiment houses a methanol/distilled water solution at a predetermined concentration, a ethanol/distilled water solution at a predetermined concentration, pure methanol, or pure ethanol as fuel F.
  • the fuel container 1 supplies the fuel F to PEFC's and the like.
  • the fuel container 1 is mounted onto a fuel cell main body (not shown). It is possible to reinject fuel into the fuel container 1 by using reinjecting fuel containers 10 , 20 to be described later, and to use the fuel container 1 repeatedly.
  • the fuel container 1 comprises: an outer container main body 2 ; an inner container 3 for housing the fuel F therein, formed by a flexible bag provided within the container main body 2 ; a valve mechanism 4 for opening and closing an upper supply opening 2 a that communicates the interior of the inner container 3 with the exterior of the container main body 2 to supply fuel; an injection valve 5 for opening and closing a lower injection opening 2 b , provided opposite the supply opening 2 a , that communicates the interior of the inner container 3 with the exterior of the container main body 2 , through which fuel is injected; and a dip tube 6 , which is inserted into the interior of the inner container 3 from the valve mechanism 4 .
  • All of the parts, and particularly the parts that contact the fuel F, are formed by non-metallic materials, that is, resin.
  • the space between the container main body 2 and the inner container 3 is airtight, and compressed gas G for applying ejection pressure for the fuel F to the inner container 3 is sealed in this space.
  • the container main body 2 is formed as a sealed box.
  • the shape of the container main body 2 is set according to the shape of the fuel cell main body (not shown), or to the shape of a fuel container housing portion of a device, such as a laptop PC, in which the fuel cell is mounted. The shape can be varied as desired, in order to secure a predetermined inner capacity.
  • the structure and wall thickness of the container main body 2 are designed to have compressive strength capable of withstanding the pressure of the contents.
  • the outer container main body 2 is formed by a transparent material, such as transparent PC, PAN, PEN, PET, and the like, such that the amount of fuel F remaining within the inner container 3 can be visually confirmed.
  • the inner container 3 has resistance with respect to the fuel F.
  • a bag formed by sheets of rubber film, PAN, PEN or the like, which are coated with ceramic by vapor deposition and sealed together, or formed by sheets of PE, PP or the like, which are coated with metal foil (aluminum foil, for example) and sealed together, is fixed to the supply opening 2 a and the injection opening 2 b of the container main body 2 in a sealed state.
  • the inner container 3 is impermeable with respect to gases.
  • the volume of the inner container 3 is set such that a fuel housing ratio with respect to the entire volume of the container main body 2 is maximized.
  • Air, nitrogen, or carbon dioxide is employed as the compressed gas G, which is sealed between the container main body 2 and the inner container 3 .
  • a gas that does not contain oxygen, such as nitrogen is employed, oxidation of the fuel F (particularly methanol) by trace amounts of oxygen that permeates through the inner container 3 can be prevented.
  • compressed gas variations in pressure due to temperature change of the container main body are reduced, compared to cases in which liquefied gas is employed.
  • the valve mechanism 4 is provided within the supply opening 2 a , which is formed as a protrusive cylinder at a portion (the upper portion in FIG. 1 ) of the container main body 2 . Specific examples of the valve mechanism will be described with reference to FIG. 2A and FIG. 2B .
  • the valve mechanism 4 comprises a flow rate adjusting mechanism 7 and a resistance mechanism 8 .
  • the flow rate adjusting mechanism 7 (the detailed structure of which is not shown) is provided at the open portion of the supply opening 2 a of the container main body 2 (the portion that connects with the fuel cell), and the valve mechanism 4 is provided beneath the flow rate adjusting mechanism 7 .
  • FIG. 2A the flow rate adjusting mechanism 7 (the detailed structure of which is not shown) is provided at the open portion of the supply opening 2 a of the container main body 2 (the portion that connects with the fuel cell), and the valve mechanism 4 is provided beneath the flow rate adjusting mechanism 7 .
  • FIG. 2A the flow rate adjusting mechanism 7 (the detailed structure of which is not shown)
  • valve mechanism 4 is provided at the open portion of the supply opening 2 a of the container main body 2 (the portion that connects with the fuel cell), and the rate adjusting mechanism 7 is provided beneath the valve mechanism 4 .
  • the basic structure of the valve mechanism 4 is the same between the examples of FIG. 2A and FIG. 2B , and will be described employing the same reference numerals.
  • the valve mechanism 4 comprises: a guiding screw 41 for fixing the valve mechanism to the container main body 2 ; a gasket 42 for enabling/disabling supply of the fuel F by functioning as a valve; a valve stem 43 , which is the operating member that opens and closes the valve; a resin spring 44 that functions as an urging member for urging the valve stem 43 in the closing direction; and a valve housing 45 for housing the resin spring 44 . All of the above components are formed by non-metallic materials.
  • the valve housing 45 is mounted onto the supply opening 2 a of the container main body 2 .
  • the flow rate adjusting mechanism 7 is built in to the bottom of the valve housing 45 in advance. Assembly of the valve mechanism 4 will be described.
  • the resin spring 44 is inserted into the valve housing 45 , the valve stem 43 is inserted atop the resin spring 44 , the gasket 42 is fitted about the outer periphery of the valve stem 43 , and the guide screw 41 is threadedly engaged with the container main body 2 to build the valve mechanism 4 into the container main body 2 .
  • the valve stem 43 is urged by the resin spring 44 toward the guide screw 41 , and the outer periphery of the gasket 42 is held and fixed to the container main body 2 by the guide screw 41 .
  • a peripheral groove is formed in the outer periphery of the valve stem 43 . Fine openings, which are open at the bottom of the peripheral groove, communicate with a central path, and the central path opens into an upper ejection opening.
  • the gasket 42 is fitted into the peripheral groove of the valve stem 43 . Elastic close contact of the inner peripheral surface of the gasket 42 seals the fine openings, to shut off supply of the fuel F.
  • the valve stem 43 is pressed inward against the resin spring 44 , via the flow rate adjusting mechanism 7 in the example of FIG. 2A , and directly in the example of FIG. 2B .
  • the inner peripheral portion of the gasket 42 deforms to open the fine openings.
  • the fuel F is supplied into the valve housing 45 by the dip tube 6 , via the flow rate adjusting mechanism 7 , in the example of FIG. 2B . Then, the fuel F, which has flowed into the valve housing 45 , is supplied to the fuel cell via the central path of the valve stem 43 , via the flow rate adjusting mechanism 7 in the example of FIG. 2A , and directly in the example of FIG. 2B .
  • the resin spring 44 that functions as the urging member comprises: a discoid base for holding the position of the lower end; an abutting portion for abutting the bottom of the valve stem 43 to transfer urging force thereto; and a folded deforming portion that links the base and the abutting portion.
  • the resin spring 44 is molded from polyacetal (POM), for example.
  • a compressive structure of a filter constitutes the flow rate adjusting mechanism 7 , for example.
  • a filter formed by urethane foam may be provided in a fuel flow path in a compressed state.
  • the flow rate of the fuel F may be adjusted by varying the compression of the filter. Thereby, abrupt ejection of the fuel F is suppressed, and the load on a flow rate adjusting mechanism of the fuel cell is reduced.
  • the resistance mechanism 8 is provided in the valve mechanism 4 , to prevent inadvertent opening operations thereof. In the examples illustrated in FIG. 2A and FIG. 2B , the periphery of the edge of the supply opening 2 a is formed toward the exterior of the tip of the valve stem 43 , to constitute the resistance mechanism 8 .
  • the resistance mechanism 8 prevents other members from contacting the tip of the valve stem 43 .
  • the injection valve 5 is of the same basic structure as the valve mechanism 4 . However, the flow rate adjusting mechanism 7 may be omitted from the injection valve 5 .
  • the fuel container 1 described above ejects the fuel F with a pressure within a predetermined range.
  • the fuel container 1 is of a double structure comprising the container main body 2 and the inner container 3 , so as to prevent contents other than the fuel F from being ejected. Therefore, fuel leaks due to shocks, imparted by the fuel container 1 being dropped or the like, can be prevented.
  • the fuel container 1 can adapt to the requirements for high space efficiency demanded in laptop PC's and PDA's. A compact fuel container having a large capacity can be realized.
  • the fuel container 1 comprises the injection valve 5 separate from the valve mechanism 4 . Therefore, fuel can be reinjected into the fuel container 1 , without removing it from the fuel cell.
  • the fuel container 1 of the first embodiment suited to house fuels such as methanol and distilled water, ethanol and distilled water, pure methanol, and pure ethanol.
  • the fuel container 1 of the first embodiment may also be utilized to house fuel for SOFC's and PEFC's, such as dimethyl ether.
  • Dimethyl ether is gaseous at room temperature, but may be compressed into liquefied gas and injected into the fuel container 1 .
  • the liquefied dimethyl ether itself possesses ejection pressure. Therefore, compressed gas need not be sealed between the container main body 2 and the inner container 3 .
  • Liquefied dimethyl ether exerts high pressure, which necessitates a pressure resistant construction.
  • the fuel container 1 is of a double structure. Accordingly, the inner container 3 maybe of a construction that is resistant against solubility by dimethyl ether, and also leak proof, while the container main body 2 may be of a construction which is resistant to cracking and deformation due to pressure.
  • FIG. 3 is a schematic sectional view illustrating a fuel container 1 ′ according to a second embodiment of the present invention.
  • the function of the injection valve 5 of the first embodiment is imparted to the valve mechanism 4 at the supply opening 2 a in the fuel container 1 ′, and a separate injection valve is omitted.
  • the other structures of the fuel container 1 ′ are the same as those of the fuel container 1 of the first embodiment. The following description will employ the same reference numerals as those of the first embodiment for common structures, and detailed descriptions thereof will be omitted.
  • supply of the fuel F to the fuel cell and reinjection of fuel into the fuel container 1 ′ are performed through opening and closing operations of the valve mechanism 4 illustrated in FIG. 2A and 2B .
  • the valve mechanism 4 illustrated in FIG. 2A and 2B When reinjecting fuel, it is necessary to remove the fuel container 1 ′ from the fuel cell.
  • the structure of the fuel container 1 ′ is simplified.
  • the parts that contact the fuel F are formed by resin.
  • metallic ions do not contaminate the fuel F for fuel cells, such as methanol solution and ethanol solution.
  • a favorable fuel container for PEFC's, for which the presence of metallic ions is to be avoided, can be realized.
  • the fuel containers 1 and 1 ′ do not decrease the performance of the fuel cell, and can be utilized repeatedly, by reinjecting fuel therein.
  • FIG. 4 and FIG. 5 are schematic sectional views of injecting fuel containers 10 and 20 according to a third and fourth embodiments of the present invention, respectively.
  • the injecting fuel containers 10 and 20 are utilized to reinject fuel into the inner containers 3 of the fuel containers 1 and 1 ′, when the amount of fuel therein decreases.
  • the injecting fuel container 10 illustrated in FIG. 4 comprises: a container main body 12 ; an inner container 13 formed by a flexible bag; a valve mechanism 14 (nozzle mechanism); a resistance mechanism 15 ; and a dip tube 16 .
  • the basic construction of the injecting fuel container 10 is the same as that of the fuel containers 1 and 1 ′.
  • Fuel F is housed in the interior of the inner container 13 , and compressed gas G for applying ejection pressure is sealed between the container main body 12 and the inner container 13 .
  • the valve mechanism 14 is configured to be connected to the injection valve 5 of the fuel container 1 or to the valve mechanism 4 of the fuel container 1 ′, to inject the fuel F into the fuel container 1 or 1 ′ by the pressure applied by the compressed gas G.
  • the pressure of the compressed gas G, which is sealed within the injecting fuel container 10 is set to be higher than the pressure of the compressed gas G, which is sealed within the fuel containers 1 and 1 ′. Thereby, the fuel F can be sufficiently injected into the fuel container 1 or 1 ′, even if the amount of fuel F remaining in the injecting fuel container 10 becomes low.
  • the valve mechanism 14 is basically of the same construction as the valve mechanisms 4 illustrated in FIG. 2 A and FIG. 2B . However, the tip of a valve stem of the valve mechanism 14 protrudes outward, and is configured to press the valve stem 43 of the valve mechanism 4 , thereby opening the fuel flow path thereof to inject the fuel F.
  • the resistance mechanism 15 prevents ejection of the fuel F due to inadvertent opening of the valve mechanism 14 .
  • the resistance mechanism 15 is constituted by a cylindrical wall formed about the periphery of the valve mechanism 14 , for example.
  • the resistance mechanism 15 is designed so as not to be impeded by the injection valve 5 or the valve mechanism 4 when reinjecting fuel into the fuel container 1 or the fuel container 1 ′.
  • the injecting fuel container 20 illustrated in FIG. 5 is manually operated, and no compressed gas is sealed therein.
  • the injecting fuel container 20 comprises: a cylindrical container main body 21 ; a piston shaped extruding member 22 , which is manually operated to slide within the container main body in an airtight manner; a valve mechanism 23 (nozzle mechanism), provided at the tip of the container main body 21 ; a lid member 24 , for sealing the end of the container main body 21 opposite that of the valve mechanism 23 ; and a resistance mechanism 25 .
  • Fuel F is suctioned into the container main body 21 by retracting the extruding member 22 .
  • the fuel F is pressurized by advancing an operating section 22 a of the extruding member 22 , and injected into the inner container 3 of the fuel container 1 or 1 ′, via the valve mechanism 23 .
  • Engaging protrusions 21 a are provided at portions of the container main body 21 that link with the lid member 24 .
  • the engaging protrusions 21 a function to prevent the lid member 22 from being disengaged from the container main body 21 , in case that fuel remaining in the fuel container 1 or 1 ′ flow into the container main body 21 when the injecting fuel container 20 is connected thereto.
  • the parts that contact the fuel F of the injecting fuel containers 10 and 20 are also formed by non-metallic materials, that is, resin. Thereby, contamination of the fuel F by metallic ions is prevented.
  • the container main bodies 12 and 21 are formed by transparent materials, to enable visual confirmation of the contents thereof. Further, the shapes of the container main bodies 12 and 21 can be designed as desired, taking fuel capacity, portability, and the like into consideration.
  • PE, PP, AS, ABS, PAN, PA, PET, PBT, PC, POM, PEN, and the like may be the resin to be employed as the material of the parts that contact the fuel F in the fuel containers 1 , 1 ′ and the injecting fuel containers 10 , 20 .
  • the material is selected on the basis of the intended contents, strength of the material, and the like. For example, if resistance against methanol is taken into consideration, polyethylene (PE), polypropylene (PP), polyethylene naphthalate (PEN), and poly acrylo nitrile (PAN) are superior and preferred.
  • ABS polypropylene
  • PEN polyethylene naphthalate
  • PAN poly acrylo nitrile
  • ABS Acrylonitrile butadiene styrene
  • PA polyamide
  • POM polyacetal
  • polyethylene polyethylene
  • PP polypropylene
  • PA polyamide
  • POM polyacetal
  • PEN polyethylene naphthalate
  • PET polyethylene terephthalate
  • PAN poly acrylo nitrile
  • ABS Acrylonitrile butadiene styrene
  • crystalline resins such as polyamide (PA), polyacetal (POM), poly butilene terephthalate (PBT), and polypropylene (PP) may be employed.
  • non-crystalline resins such as acetal, polycarbonate, and acrylo nitrile butadiene styrene, may be employed to form the parts, and the surfaces thereof may be coated with epoxy resin or polyamide resin.
  • a material having superior resistance is employed for the inner layer that contacts the contents, and a pressure and shock resistant material is employed as the outer layer.
  • Fuel containers employing the double layer structure may be formed by a double injection molding method, or by a coating method.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
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  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)

Abstract

A fuel container (1) for supplying fuel (F) to a fuel cell is constituted by: a container main body (2) having a sealed structure; an inner container (3) for housing the fuel therein, formed by a flexible bag provided within the container main body; a valve mechanism (4) for enabling/disabling supply of fuel, provided in the container main body (2) and in communication with the interior of the inner container (3); and compressed gas (G) for ejecting the fuel, sealed between the container main body (2) and the inner container (3). All of the structural components that contact the fuel (F) are formed of non-metallic materials. The fuel container (1) may also include an injection valve (5). In this case, a fuel injecting container reinjects fuel (F) into the fuel container (1), such that the fuel container (1) can be used repeatedly.

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention
  • The present invention relates to a fuel container for housing and directly supplying fuel, such as methanol solution, to a fuel cell, such as a polymer electrolyte fuel cell (PEFC) The present invention also relates to a fuel container for reinjecting fuel into a fuel container, which is mounted on a fuel cell.
  • 2. Description of the Related Art
  • Conventional containers for housing solutions include aerosol containers, and cosmetic containers, for example. Generally, glass, metal, or plastic is used as the material of the main bodies of the containers. These containers are pressurized such that when nozzles thereof are opened, the solutions stored therein are sprayed out for use.
  • In the containers described above, springs are utilized as urging members for urging the nozzles in the closing direction. From the viewpoints of cost and ease of use, metallic coil springs are generally used. However, in order to improve recycling rates, cylindrical urging members constituted by elastic resin materials have been proposed (refer to Japanese Unexamined Patent Publication No. 11 (1999)-90282, for example)
  • The use of fuel cells as miniature power sources for devices such as portable computers (laptop PC's, PDA's and the like) is being contemplated. Fuel containers are necessary to supply fuel to these fuel cells. In the case that the fuel cell is a polymer electrolyte fuel cell (hereinafter, referred to simply as PEFC), methanol and distilled water, ethanol and distilled water, pure methanol, or pure ethanol is used as the fuel therefor. In addition, dimethyl ether is expected to be used as fuel for solid oxide fuel cells (hereinafter, referred to simply as SOFC) and PEFC's.
  • However, in fuel cells such as SOFC's and PEFC's, contamination by metallic ions is to be avoided. It has been found, therefore, that the fuel container must be constructed such that metallic ions do not contaminate fuel housed therein.
  • It is inappropriate to employ metallic materials for members that contact the fuel, because ions will be generated. Even if the metallic members are coated with resin, generation of ions cannot be avoided, due to pinholes in the resin film. In the case that interior pressure is applied to the fuel container such that the fuel is ejected and supplied, it is not preferable for the fuel to be supplied contaminated by the pressurizing agent (propellant).
  • The shape of the fuel container is set according to the shape of the fuel cell itself, or the shape of a fuel container housing portion of a device, such as a laptop PC. Therefore, it is disadvantageous from the viewpoint of cost to dispose of fuel containers, which have been provided in shapes according to specific devices, once the fuel therein is consumed. In addition, such fuel containers easily become difficult to obtain, which is inconvenient.
  • SUMMARY OF THE INVENTION
  • The present invention has been developed in view of the aforementioned points. It is an object of the present invention to provide a fuel container for fuel cells that prevents contamination of fuel by metallic ions and propellant, and which is reusable. It is another object of the present invention to provide a fuel container that reinjects fuel into fuel containers, which are mounted on fuel cells.
  • A first fuel container for housing fuel to be supplied to a fuel cell of the present invention comprises:
      • a container main body having a sealed structure;
      • an inner container for housing the fuel therein, formed by a flexible bag provided within the container main body;
      • a valve mechanism for enabling/disabling supply of fuel, provided in the container main body and in communication with the interior of the inner container;
      • an injection valve for injecting fuel, provided in the container main body and in communication with the interior of the inner container; and
      • compressed gas for ejecting the fuel, sealed between the container main body and the inner container;
      • all of the structural components that contact the fuel being formed of non-metallic materials; and
      • the fuel container being mountable on the fuel cell to directly supply fuel thereto.
  • A second fuel container for housing fuel to be supplied to a fuel cell of the present invention comprises:
      • a container main body having a sealed structure;
      • an inner container for housing the fuel therein, formed by a flexible bag provided within the container main body;
      • a valve mechanism for enabling/disabling supply of fuel and for injecting fuel, provided in the container main body and in communication with the interior of the inner container; and
      • compressed gas for ejecting the fuel, sealed between the container main body and the inner container;
      • all of the structural components that contact the fuel being formed of non-metallic materials; and
      • the fuel container being mountable on the fuel cell to directly supply fuel thereto.
  • A third fuel container for housing fuel to be supplied to a fuel cell of the present invention comprises:
      • a container main body having a sealed structure;
      • an inner container for housing the fuel therein, formed by a flexible bag provided within the container main body;
      • a valve mechanism for enabling/disabling supply of fuel, provided in the container main body and in communication with the interior of the inner container; and
      • compressed gas for ejecting the fuel, sealed between the container main body and the inner container at a pressure higher than a fuel pressure of a fuel container, which is mounted on the fuel cell to directly supply fuel thereto;
      • all of the structural components that contact the fuel being formed of non-metallic materials; and
      • the fuel container being mountable on the fuel container, which is mounted on the fuel cell, to reinject fuel therein.
  • A fourth fuel container for housing fuel to be supplied to a fuel cell of the present invention comprises:
      • a cylindrical container main body for housing the fuel therein;
      • a piston shaped extruding member, which is manually operated to slide within the container main body in an airtight manner so as to pressurize the fuel;
      • a valve mechanism for enabling/disabling supply of fuel, provided in the container main body;
      • all of the structural components that contact the fuel being formed of non-metallic materials; and
      • the fuel container being mountable on a fuel container, which is mounted on the fuel cell, to reinject fuel therein.
  • It is preferable for the container main body of each of the above fuel containers to be formed by a transparent material.
  • The fuel containers of the present invention are suited to house fuels for PEFC's, such as methanol and distilled water, ethanol and distilled water, pure methanol, and pure ethanol. The fuel containers of the present invention may also be utilized to house fuel for SOFC's and PEFC's, such as dimethyl ether.
  • Each of the fuel containers of the present invention comprises: a container main body; an inner container for housing fuel; and a valve mechanism for enabling/disabling supply of fuel. All of the structural components that contact the fuel are formed by non-metallic materials, and compressed gas is sealed between the container main body and the inner container. Therefor, only the fuel can be ejected and supplied. Further, contamination by metallic ions can be prevented, because the housed fuel does not contact any metal. Particularly, in fuel cells such as PEFC's, contamination of fuel, such as methanol solution and ethanol solution by metallic ions is to be avoided. By forming the members that contact the fuel with non-metallic materials, the release of metallic ions can be avoided. Thereby, fuel containers to be mounted onto fuel cells to directly supply fuel thereto, and fuel containers to reinject fuel to fuel containers, which are mounted onto fuel cells, can be produced without decreasing the performance of the fuel cells.
  • That is, in the case that the fuel container comprises an injection valve, through which fuel can be reinjected, or if the valve mechanism is configured to enable both supply and injection, users can easily refill the fuel container, by utilizing a fuel container configured to reinject fuel. This is advantageous from the viewpoint of cost, and the degree of freedom regarding shapes corresponding to devices is improved. In addition, additional fuel will become commonly available, by providing universal reinjecting fuel containers, which will improve convenience.
  • Particularly in fuel containers that comprise injection valves separate from the valve mechanism to be connected to fuel cells, it is possible to reinject fuel through the injection valves while the fuel containers are mounted on the fuel cells. On the other hand, in fuel containers that comprise valve mechanisms that enable both supply and injection of fuel, it is necessary to disconnect the fuel containers from fuel cells to reinject fuel therein. However, separate injection valves can be omitted, simplifying the structure of the fuel containers.
  • In the third fuel container of the present invention, compressed gas for ejecting the fuel is sealed between the container main body and the inner container at a pressure higher than a fuel pressure of a fuel container, which is mounted on the fuel cell to directly supply fuel thereto. The fourth fuel container of the present invention comprises: a cylindrical container main body for housing the fuel therein; and a piston shaped extruding member, which is manually operated. The third and fourth fuel containers are capable of reinjecting fuel into fuel containers that directly supply fuel to fuel cells. The shapes of the third and fourth fuel containers can be set as desired. The third and fourth fuel containers can be constructed according to considerations regarding fuel capacity and portability, thereby improving convenience.
  • The container main body of each of the fuel containers of the present invention may be formed by a transparent material. In this case, the amount of remaining fuel and states of reinjection can be visually confirmed.
  • In addition, forming the fuel containers from resin exhibits the following advantageous effects. The fuel containers may be formed into various shapes, such as cylinders, polygons, ovals, and the like. Classification during disposal is facilitated, which is suitable for recycling. Thermal properties are favorable compared to metal, which is cold to the touch. Changes in the contents due to corrosion are not likely to occur.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a schematic sectional view illustrating a fuel container to be mounted on a fuel cell, according to a first embodiment of the present invention.
  • FIG. 2A is a sectional view of the main parts of a valve mechanism.
  • FIG. 2B is a sectional view of the main parts of an alternate valve mechanism.
  • FIG. 3 is a schematic sectional view illustrating a fuel container to be mounted on a fuel cell, according to a second embodiment of the present invention.
  • FIG. 4 is a schematic sectional view illustrating a fuel container for reinjecting fuel, according to a third embodiment of the present invention.
  • FIG. 5 is a schematic sectional view illustrating a fuel container for reinjecting fuel, according to a fourth embodiment of the present invention.
  • DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • Hereinafter, embodiments of the present invention will be described in detail with reference to the attached drawings. FIG. 1 is a schematic sectional view illustrating a fuel container 1 to be mounted on a fuel cell, according to a first embodiment of the present invention. FIGS. 2A and 2B are sectional view of main parts of valve mechanisms.
  • The fuel container 1 of the first embodiment houses a methanol/distilled water solution at a predetermined concentration, a ethanol/distilled water solution at a predetermined concentration, pure methanol, or pure ethanol as fuel F. The fuel container 1 supplies the fuel F to PEFC's and the like. The fuel container 1 is mounted onto a fuel cell main body (not shown). It is possible to reinject fuel into the fuel container 1 by using reinjecting fuel containers 10, 20 to be described later, and to use the fuel container 1 repeatedly.
  • As illustrated in FIG. 1, the fuel container 1 comprises: an outer container main body 2; an inner container 3 for housing the fuel F therein, formed by a flexible bag provided within the container main body 2; a valve mechanism 4 for opening and closing an upper supply opening 2 a that communicates the interior of the inner container 3 with the exterior of the container main body 2 to supply fuel; an injection valve 5 for opening and closing a lower injection opening 2 b, provided opposite the supply opening 2 a, that communicates the interior of the inner container 3 with the exterior of the container main body 2, through which fuel is injected; and a dip tube 6, which is inserted into the interior of the inner container 3 from the valve mechanism 4. All of the parts, and particularly the parts that contact the fuel F, are formed by non-metallic materials, that is, resin. The space between the container main body 2 and the inner container 3 is airtight, and compressed gas G for applying ejection pressure for the fuel F to the inner container 3 is sealed in this space.
  • The container main body 2 is formed as a sealed box. The shape of the container main body 2 is set according to the shape of the fuel cell main body (not shown), or to the shape of a fuel container housing portion of a device, such as a laptop PC, in which the fuel cell is mounted. The shape can be varied as desired, in order to secure a predetermined inner capacity. The structure and wall thickness of the container main body 2 are designed to have compressive strength capable of withstanding the pressure of the contents. The outer container main body 2 is formed by a transparent material, such as transparent PC, PAN, PEN, PET, and the like, such that the amount of fuel F remaining within the inner container 3 can be visually confirmed.
  • Meanwhile, the inner container 3 has resistance with respect to the fuel F. A bag, formed by sheets of rubber film, PAN, PEN or the like, which are coated with ceramic by vapor deposition and sealed together, or formed by sheets of PE, PP or the like, which are coated with metal foil (aluminum foil, for example) and sealed together, is fixed to the supply opening 2 a and the injection opening 2 b of the container main body 2 in a sealed state. The inner container 3 is impermeable with respect to gases. The volume of the inner container 3 is set such that a fuel housing ratio with respect to the entire volume of the container main body 2 is maximized.
  • Air, nitrogen, or carbon dioxide is employed as the compressed gas G, which is sealed between the container main body 2 and the inner container 3. In the case that a gas that does not contain oxygen, such as nitrogen, is employed, oxidation of the fuel F (particularly methanol) by trace amounts of oxygen that permeates through the inner container 3 can be prevented. By employing compressed gas, variations in pressure due to temperature change of the container main body are reduced, compared to cases in which liquefied gas is employed.
  • The valve mechanism 4 is provided within the supply opening 2 a, which is formed as a protrusive cylinder at a portion (the upper portion in FIG. 1) of the container main body 2. Specific examples of the valve mechanism will be described with reference to FIG. 2A and FIG. 2B. The valve mechanism 4 comprises a flow rate adjusting mechanism 7 and a resistance mechanism 8. In the example illustrated in FIG. 2A, the flow rate adjusting mechanism 7 (the detailed structure of which is not shown) is provided at the open portion of the supply opening 2 a of the container main body 2 (the portion that connects with the fuel cell), and the valve mechanism 4 is provided beneath the flow rate adjusting mechanism 7. On the other hand, in the example illustrated in FIG. 2B, the valve mechanism 4 is provided at the open portion of the supply opening 2 a of the container main body 2 (the portion that connects with the fuel cell), and the rate adjusting mechanism 7 is provided beneath the valve mechanism 4. The basic structure of the valve mechanism 4 is the same between the examples of FIG. 2A and FIG. 2B, and will be described employing the same reference numerals.
  • The valve mechanism 4 comprises: a guiding screw 41 for fixing the valve mechanism to the container main body 2; a gasket 42 for enabling/disabling supply of the fuel F by functioning as a valve; a valve stem 43, which is the operating member that opens and closes the valve; a resin spring 44 that functions as an urging member for urging the valve stem 43 in the closing direction; and a valve housing 45 for housing the resin spring 44. All of the above components are formed by non-metallic materials.
  • The valve housing 45 is mounted onto the supply opening 2 a of the container main body 2. In the example of FIG. 2B, the flow rate adjusting mechanism 7 is built in to the bottom of the valve housing 45 in advance. Assembly of the valve mechanism 4 will be described. The resin spring 44 is inserted into the valve housing 45, the valve stem 43 is inserted atop the resin spring 44, the gasket 42 is fitted about the outer periphery of the valve stem 43, and the guide screw 41 is threadedly engaged with the container main body 2 to build the valve mechanism 4 into the container main body 2. The valve stem 43 is urged by the resin spring 44 toward the guide screw 41, and the outer periphery of the gasket 42 is held and fixed to the container main body 2 by the guide screw 41.
  • A peripheral groove is formed in the outer periphery of the valve stem 43. Fine openings, which are open at the bottom of the peripheral groove, communicate with a central path, and the central path opens into an upper ejection opening. The gasket 42 is fitted into the peripheral groove of the valve stem 43. Elastic close contact of the inner peripheral surface of the gasket 42 seals the fine openings, to shut off supply of the fuel F. When the fuel container 1 is connected to the fuel cell, the valve stem 43 is pressed inward against the resin spring 44, via the flow rate adjusting mechanism 7 in the example of FIG. 2A, and directly in the example of FIG. 2B. Accompanying the downward movement of the valve stem 43, the inner peripheral portion of the gasket 42 deforms to open the fine openings. Thereby, the fuel F is supplied into the valve housing 45 by the dip tube 6, via the flow rate adjusting mechanism 7, in the example of FIG. 2B. Then, the fuel F, which has flowed into the valve housing 45, is supplied to the fuel cell via the central path of the valve stem 43, via the flow rate adjusting mechanism 7 in the example of FIG. 2A, and directly in the example of FIG. 2B.
  • The resin spring 44 that functions as the urging member comprises: a discoid base for holding the position of the lower end; an abutting portion for abutting the bottom of the valve stem 43 to transfer urging force thereto; and a folded deforming portion that links the base and the abutting portion. The resin spring 44 is molded from polyacetal (POM), for example.
  • A compressive structure of a filter constitutes the flow rate adjusting mechanism 7, for example. A filter formed by urethane foam may be provided in a fuel flow path in a compressed state. The flow rate of the fuel F may be adjusted by varying the compression of the filter. Thereby, abrupt ejection of the fuel F is suppressed, and the load on a flow rate adjusting mechanism of the fuel cell is reduced. In addition, the resistance mechanism 8 is provided in the valve mechanism 4, to prevent inadvertent opening operations thereof. In the examples illustrated in FIG. 2A and FIG. 2B, the periphery of the edge of the supply opening 2 a is formed toward the exterior of the tip of the valve stem 43, to constitute the resistance mechanism 8. The resistance mechanism 8 prevents other members from contacting the tip of the valve stem 43.
  • The injection valve 5 is of the same basic structure as the valve mechanism 4. However, the flow rate adjusting mechanism 7 may be omitted from the injection valve 5.
  • The fuel container 1 described above ejects the fuel F with a pressure within a predetermined range. The fuel container 1 is of a double structure comprising the container main body 2 and the inner container 3, so as to prevent contents other than the fuel F from being ejected. Therefore, fuel leaks due to shocks, imparted by the fuel container 1 being dropped or the like, can be prevented. In addition, the fuel container 1 can adapt to the requirements for high space efficiency demanded in laptop PC's and PDA's. A compact fuel container having a large capacity can be realized. In addition, the fuel container 1 comprises the injection valve 5 separate from the valve mechanism 4. Therefore, fuel can be reinjected into the fuel container 1, without removing it from the fuel cell.
  • The fuel container 1 of the first embodiment suited to house fuels such as methanol and distilled water, ethanol and distilled water, pure methanol, and pure ethanol. The fuel container 1 of the first embodiment may also be utilized to house fuel for SOFC's and PEFC's, such as dimethyl ether. Dimethyl ether is gaseous at room temperature, but may be compressed into liquefied gas and injected into the fuel container 1. In this case, the liquefied dimethyl ether itself possesses ejection pressure. Therefore, compressed gas need not be sealed between the container main body 2 and the inner container 3. Liquefied dimethyl ether exerts high pressure, which necessitates a pressure resistant construction. In addition, a construction which is resistant to solubility due to the dimethyl ether is also necessary. The fuel container 1 is of a double structure. Accordingly, the inner container 3 maybe of a construction that is resistant against solubility by dimethyl ether, and also leak proof, while the container main body 2 may be of a construction which is resistant to cracking and deformation due to pressure.
  • FIG. 3 is a schematic sectional view illustrating a fuel container 1′ according to a second embodiment of the present invention. The function of the injection valve 5 of the first embodiment is imparted to the valve mechanism 4 at the supply opening 2 a in the fuel container 1′, and a separate injection valve is omitted. The other structures of the fuel container 1′ are the same as those of the fuel container 1 of the first embodiment. The following description will employ the same reference numerals as those of the first embodiment for common structures, and detailed descriptions thereof will be omitted.
  • In the second embodiment, supply of the fuel F to the fuel cell and reinjection of fuel into the fuel container 1′ are performed through opening and closing operations of the valve mechanism 4 illustrated in FIG. 2A and 2B. When reinjecting fuel, it is necessary to remove the fuel container 1′ from the fuel cell. However, the structure of the fuel container 1′ is simplified.
  • In the fuel containers 1 and 1′ of the first and second embodiments, to be mounted onto the fuel cell, the parts that contact the fuel F are formed by resin. Thereby, metallic ions do not contaminate the fuel F for fuel cells, such as methanol solution and ethanol solution. In addition, there is no contamination of the fuel F by propellant. Accordingly, a favorable fuel container for PEFC's, for which the presence of metallic ions is to be avoided, can be realized. The fuel containers 1 and 1′ do not decrease the performance of the fuel cell, and can be utilized repeatedly, by reinjecting fuel therein.
  • FIG. 4 and FIG. 5 are schematic sectional views of injecting fuel containers 10 and 20 according to a third and fourth embodiments of the present invention, respectively. The injecting fuel containers 10 and 20 are utilized to reinject fuel into the inner containers 3 of the fuel containers 1 and 1′, when the amount of fuel therein decreases.
  • The injecting fuel container 10 illustrated in FIG. 4 comprises: a container main body 12; an inner container 13 formed by a flexible bag; a valve mechanism 14 (nozzle mechanism); a resistance mechanism 15; and a dip tube 16. The basic construction of the injecting fuel container 10 is the same as that of the fuel containers 1 and 1′. Fuel F is housed in the interior of the inner container 13, and compressed gas G for applying ejection pressure is sealed between the container main body 12 and the inner container 13. The valve mechanism 14 is configured to be connected to the injection valve 5 of the fuel container 1 or to the valve mechanism 4 of the fuel container 1′, to inject the fuel F into the fuel container 1 or 1′ by the pressure applied by the compressed gas G.
  • The pressure of the compressed gas G, which is sealed within the injecting fuel container 10, is set to be higher than the pressure of the compressed gas G, which is sealed within the fuel containers 1 and 1′. Thereby, the fuel F can be sufficiently injected into the fuel container 1 or 1′, even if the amount of fuel F remaining in the injecting fuel container 10 becomes low.
  • The valve mechanism 14 is basically of the same construction as the valve mechanisms 4 illustrated in FIG. 2A and FIG. 2B. However, the tip of a valve stem of the valve mechanism 14 protrudes outward, and is configured to press the valve stem 43 of the valve mechanism 4, thereby opening the fuel flow path thereof to inject the fuel F.
  • The resistance mechanism 15 prevents ejection of the fuel F due to inadvertent opening of the valve mechanism 14. The resistance mechanism 15 is constituted by a cylindrical wall formed about the periphery of the valve mechanism 14, for example. The resistance mechanism 15 is designed so as not to be impeded by the injection valve 5 or the valve mechanism 4 when reinjecting fuel into the fuel container 1 or the fuel container 1′.
  • The injecting fuel container 20 illustrated in FIG. 5 according to the fourth embodiment of the present invention is manually operated, and no compressed gas is sealed therein. The injecting fuel container 20 comprises: a cylindrical container main body 21; a piston shaped extruding member 22, which is manually operated to slide within the container main body in an airtight manner; a valve mechanism 23 (nozzle mechanism), provided at the tip of the container main body 21; a lid member 24, for sealing the end of the container main body 21 opposite that of the valve mechanism 23; and a resistance mechanism 25. Fuel F is suctioned into the container main body 21 by retracting the extruding member 22. The fuel F is pressurized by advancing an operating section 22 a of the extruding member 22, and injected into the inner container 3 of the fuel container 1 or 1′, via the valve mechanism 23.
  • Engaging protrusions 21 a are provided at portions of the container main body 21 that link with the lid member 24. The engaging protrusions 21 a function to prevent the lid member 22 from being disengaged from the container main body 21, in case that fuel remaining in the fuel container 1 or 1′ flow into the container main body 21 when the injecting fuel container 20 is connected thereto.
  • The parts that contact the fuel F of the injecting fuel containers 10 and 20 are also formed by non-metallic materials, that is, resin. Thereby, contamination of the fuel F by metallic ions is prevented. In addition, the container main bodies 12 and 21 are formed by transparent materials, to enable visual confirmation of the contents thereof. Further, the shapes of the container main bodies 12 and 21 can be designed as desired, taking fuel capacity, portability, and the like into consideration.
  • PE, PP, AS, ABS, PAN, PA, PET, PBT, PC, POM, PEN, and the like may be the resin to be employed as the material of the parts that contact the fuel F in the fuel containers 1, 1′ and the injecting fuel containers 10, 20. The material is selected on the basis of the intended contents, strength of the material, and the like. For example, if resistance against methanol is taken into consideration, polyethylene (PE), polypropylene (PP), polyethylene naphthalate (PEN), and poly acrylo nitrile (PAN) are superior and preferred. Acrylonitrile butadiene styrene (ABS), polyamide (PA), or polyacetal (POM) may also be employed. If resistance against ethanol is taken into consideration, polyethylene (PE), polypropylene (PP), polyamide (PA), polyacetal (POM), polyethylene naphthalate (PEN), polyethylene terephthalate (PET), and poly acrylo nitrile (PAN) are superior and preferred. Acrylonitrile butadiene styrene (ABS) may also be employed.
  • If resistance against dimethyl ether is taken into consideration, crystalline resins, such as polyamide (PA), polyacetal (POM), poly butilene terephthalate (PBT), and polypropylene (PP) may be employed. Alternatively, non-crystalline resins, such as acetal, polycarbonate, and acrylo nitrile butadiene styrene, may be employed to form the parts, and the surfaces thereof may be coated with epoxy resin or polyamide resin.
  • A single layer structure, formed by a single material, or a double (multiple) layer structure, formed by a plurality of materials, maybe employed. In the case that the double layer structure is employed, a material having superior resistance is employed for the inner layer that contacts the contents, and a pressure and shock resistant material is employed as the outer layer. Fuel containers employing the double layer structure may be formed by a double injection molding method, or by a coating method.

Claims (5)

1. A fuel container for housing fuel to be supplied to a fuel cell, comprising:
a container main body having a sealed structure;
an inner container for housing the fuel therein, formed by a flexible bag provided within the container main body;
a valve mechanism for enabling/disabling supply of fuel, provided in the container main body and in communication with the interior of the inner container;
an injection valve for injecting fuel, provided in the container main body and in communication with the interior of the inner container; and
compressed gas for ejecting the fuel, sealed between the container main body and the inner container;
all of the structural components that contact the fuel being formed of non-metallic materials; and
the fuel container being mountable on the fuel cell to directly supply fuel thereto.
2. A fuel container for housing fuel to be supplied to a fuel cell, comprising:
a container main body having a sealed structure;
an inner container for housing the fuel therein, formed by a flexible bag provided within the container main body;
a valve mechanism for enabling/disabling supply of fuel and for injecting fuel, provided in the container main body and in communication with the interior of the inner container; and
compressed gas for ejecting the fuel, sealed between the container main body and the inner container;
all of the structural components that contact the fuel being formed of non-metallic materials; and
the fuel container being mountable on the fuel cell to directly supply fuel thereto.
3. A fuel container for housing fuel to be supplied to a fuel cell, comprising:
a container main body having a sealed structure;
an inner container for housing the fuel therein, formed by a flexible bag provided within the container main body;
a valve mechanism for enabling/disabling supply of fuel, provided in the container main body and in communication with the interior of the inner container; and
compressed gas for ejecting the fuel, sealed between the container main body and the inner container at a pressure higher than a fuel pressure of a fuel container, which is mounted on the fuel cell to directly supply fuel thereto;
all of the structural components-that contact the fuel being formed of non-metallic materials; and
the fuel container being mountable on the fuel container, which is mounted on the fuel cell, to reinject fuel therein.
4. A fuel container for housing fuel to be supplied to a fuel cell, comprising:
a cylindrical container main body for housing the fuel therein;
a piston shaped extruding member, which is manually operated to slide within the container main body in an airtight manner so as to pressurize the fuel;
a valve mechanism for enabling/disabling supply of fuel, provided in the container main body;
all of the structural components that contact the fuel being formed of non-metallic materials; and
the fuel container being mountable on a fuel container, which is mounted on the fuel cell, to reinject fuel therein.
5. A fuel container as defined in any one of claims 1 through 4, wherein:
the container main body is formed by a transparent material.
US10/563,097 2003-07-03 2004-06-21 Fuel container for fuel cell Abandoned US20060151494A1 (en)

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JP2003-297049 2003-08-21
PCT/JP2004/009048 WO2005004268A1 (en) 2003-07-03 2004-06-21 Fuel container for fuel cell

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070148514A1 (en) * 2005-12-22 2007-06-28 Zhiping Jiang Fuel cells
US20070254198A1 (en) * 2004-06-25 2007-11-01 Mitsubishi Pencil Co., Ltd. Fuel cell
US20070259250A1 (en) * 2004-05-27 2007-11-08 Mitsubishi Pencil Co., Ltd. Fuel Reservoir for Fuel Cell
US20070298307A1 (en) * 2004-06-08 2007-12-27 Mitsubishi Pencil Co., Ltd. Fuel Reservoir for Fuel Cell
EP1959515A1 (en) * 2007-02-15 2008-08-20 Samsung SDI Co., Ltd. Fuel cartridge and fuel cell using the same
US20080292915A1 (en) * 2004-06-25 2008-11-27 Mitsubishi Pencil Co., Ltd. Fuel Reservoir for Fuel Cell
US20090004536A1 (en) * 2007-05-16 2009-01-01 Paul Knauer Direct methanol fuel cell process tower
US20090197150A1 (en) * 2006-06-02 2009-08-06 Toyo Seikan Kaisha, Ltd. Fuel cell cartridge
US20090305102A1 (en) * 2005-07-15 2009-12-10 Kenichi Takahashi Fuel battery
US20100062315A1 (en) * 2005-06-17 2010-03-11 Toyo Seikan Kaisha, Ltd. Methanol fuel cell cartridge
US8528774B2 (en) 2011-06-10 2013-09-10 Paccar Inc Fuel cooler assembly
US8579137B2 (en) 2008-08-01 2013-11-12 Boehringer Ingelheim International Gmbh Packaging unit with a plastic bottle and a foil bag arranged therein
AT515343A1 (en) * 2010-08-09 2015-08-15 Faber Ind Spa gas cylinders
US20180065778A1 (en) * 2016-09-02 2018-03-08 Kenneth Johnson Collapsible fuel container

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060204802A1 (en) 2005-03-10 2006-09-14 Specht Steven J Fuel cell systems and related methods
JP5100022B2 (en) * 2005-04-08 2012-12-19 三洋電機株式会社 Fuel cell system
WO2006121169A1 (en) 2005-05-09 2006-11-16 Kabushiki Kaisha Toshiba Liquid fuel, fuel cartridge and fuel cell
US20090117446A1 (en) * 2005-06-10 2009-05-07 Nix, Inc. Joint device for sending and receiving liquid and fuel cell system having the same
JP4947930B2 (en) * 2005-07-25 2012-06-06 株式会社東海 Fuel container for fuel cell
US8408246B2 (en) * 2005-10-05 2013-04-02 Societe Bic Fuel cartridge for fuel cells
KR100673755B1 (en) 2005-10-21 2007-01-24 삼성에스디아이 주식회사 Fuel cell system being capable of without fuel pump
JP5348852B2 (en) * 2006-06-20 2013-11-20 三菱鉛筆株式会社 Fuel cartridge
US8235077B2 (en) * 2006-09-14 2012-08-07 Societe Bic Device for refilling a fuel cartridge for a fuel cell
WO2010075163A2 (en) * 2008-12-22 2010-07-01 Eveready Battery Company, Inc. Device having fluid consuming battery and fluid manager
KR101356776B1 (en) * 2013-05-16 2014-01-27 주식회사 코베아 Portable burner
KR20200071545A (en) * 2018-12-11 2020-06-19 현대자동차주식회사 Device for adjusting pressure of exhaust gas of fuel cell system

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5123571A (en) * 1988-07-25 1992-06-23 Cebal Process for the production and packaging of a bag-type dispenser, sub-assemblies and corresponding dispensers
US5135137A (en) * 1991-01-17 1992-08-04 The Coca-Cola Company Simplified micro-gravity pre-mix package
US5137179A (en) * 1990-02-15 1992-08-11 Hans Stoffel Containers and methods for preparing and manufacturing the same
US5672439A (en) * 1995-12-18 1997-09-30 Ballard Power Systems, Inc. Method and apparatus for reducing reactant crossover in an electrochemical fuel cell
US5803311A (en) * 1994-05-19 1998-09-08 Ing. Erich Pfeiffer Gmbh & Co Kg Bottle closure for squeezing bottle
US20010025857A1 (en) * 2000-02-07 2001-10-04 Gilles Baudin Device for containing and dispensing a product
US6375046B1 (en) * 1998-10-28 2002-04-23 Rexam Sofab Pouch reservoir valve
US20030008193A1 (en) * 2001-06-28 2003-01-09 Foamex L.P. Liquid fuel delivery system for fuel cells
US20030082427A1 (en) * 2001-10-29 2003-05-01 Ravi Prasad Fuel supply for a fuel cell

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04223058A (en) * 1990-12-26 1992-08-12 Aisin Aw Co Ltd Fuel tank for liquid fuel cell
CA2155546A1 (en) * 1993-12-06 1995-06-15 Charles Kaeser Rechargeable aerosol can using air as the propellant
JP3148989B2 (en) * 1998-06-30 2001-03-26 株式会社ソフト九九コーポレーション Check valve
JP2000203605A (en) * 1998-11-16 2000-07-25 Waterfall Co Inc Cartridge for contamination-free dispensing and delivery
JP3668069B2 (en) * 1999-09-21 2005-07-06 株式会社東芝 Liquid fuel container for fuel cell and fuel cell
JP2001313047A (en) * 2000-04-28 2001-11-09 Yuasa Corp Direct methanol fuel cell
JP4259728B2 (en) * 2000-06-05 2009-04-30 横浜ゴム株式会社 A method for fixing a flexible bag-like tank used for a fuel tank of a flying object.
US6460733B2 (en) * 2001-02-20 2002-10-08 Mti Microfuel Cells, Inc. Multiple-walled fuel container and delivery system
JP2004193059A (en) * 2002-12-13 2004-07-08 Hitachi Maxell Ltd Fuel exchange device
JP2004206994A (en) * 2002-12-25 2004-07-22 Renesas Technology Corp Fuel supply of fuel cell

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5123571A (en) * 1988-07-25 1992-06-23 Cebal Process for the production and packaging of a bag-type dispenser, sub-assemblies and corresponding dispensers
US5137179A (en) * 1990-02-15 1992-08-11 Hans Stoffel Containers and methods for preparing and manufacturing the same
US5135137A (en) * 1991-01-17 1992-08-04 The Coca-Cola Company Simplified micro-gravity pre-mix package
US5803311A (en) * 1994-05-19 1998-09-08 Ing. Erich Pfeiffer Gmbh & Co Kg Bottle closure for squeezing bottle
US5672439A (en) * 1995-12-18 1997-09-30 Ballard Power Systems, Inc. Method and apparatus for reducing reactant crossover in an electrochemical fuel cell
US6375046B1 (en) * 1998-10-28 2002-04-23 Rexam Sofab Pouch reservoir valve
US20010025857A1 (en) * 2000-02-07 2001-10-04 Gilles Baudin Device for containing and dispensing a product
US20030008193A1 (en) * 2001-06-28 2003-01-09 Foamex L.P. Liquid fuel delivery system for fuel cells
US20030082427A1 (en) * 2001-10-29 2003-05-01 Ravi Prasad Fuel supply for a fuel cell

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070259250A1 (en) * 2004-05-27 2007-11-08 Mitsubishi Pencil Co., Ltd. Fuel Reservoir for Fuel Cell
US8173318B2 (en) 2004-05-27 2012-05-08 Mitsubishi Pencil Co., Ltd. Fuel reservoir for fuel cell
US7615305B2 (en) 2004-06-08 2009-11-10 Mitsubishi Pencil Co., Ltd. Fuel reservoir for fuel cell
US20070298307A1 (en) * 2004-06-08 2007-12-27 Mitsubishi Pencil Co., Ltd. Fuel Reservoir for Fuel Cell
US20070254198A1 (en) * 2004-06-25 2007-11-01 Mitsubishi Pencil Co., Ltd. Fuel cell
US20080292915A1 (en) * 2004-06-25 2008-11-27 Mitsubishi Pencil Co., Ltd. Fuel Reservoir for Fuel Cell
US7883815B2 (en) 2004-06-25 2011-02-08 Mitsubishi Pencil Co., Ltd. Fuel-storing tank for fuel cell
US7727657B2 (en) 2004-06-25 2010-06-01 Mitsubishi Pencil Co., Ltd. Fuel reservoir for fuel cell
US20100062315A1 (en) * 2005-06-17 2010-03-11 Toyo Seikan Kaisha, Ltd. Methanol fuel cell cartridge
EP1892786A4 (en) * 2005-06-17 2010-12-29 Toyo Seikan Kaisha Ltd Methanol fuel cell cartridge
US20090305102A1 (en) * 2005-07-15 2009-12-10 Kenichi Takahashi Fuel battery
US20070148514A1 (en) * 2005-12-22 2007-06-28 Zhiping Jiang Fuel cells
US20090197150A1 (en) * 2006-06-02 2009-08-06 Toyo Seikan Kaisha, Ltd. Fuel cell cartridge
EP1959515A1 (en) * 2007-02-15 2008-08-20 Samsung SDI Co., Ltd. Fuel cartridge and fuel cell using the same
US20090004536A1 (en) * 2007-05-16 2009-01-01 Paul Knauer Direct methanol fuel cell process tower
US8579137B2 (en) 2008-08-01 2013-11-12 Boehringer Ingelheim International Gmbh Packaging unit with a plastic bottle and a foil bag arranged therein
AT515343A1 (en) * 2010-08-09 2015-08-15 Faber Ind Spa gas cylinders
AT515343B1 (en) * 2010-08-09 2016-01-15 Faber Ind Spa gas cylinders
US8528774B2 (en) 2011-06-10 2013-09-10 Paccar Inc Fuel cooler assembly
US20180065778A1 (en) * 2016-09-02 2018-03-08 Kenneth Johnson Collapsible fuel container

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