JP4438983B2 - Fuel container for fuel cell - Google Patents

Fuel container for fuel cell Download PDF

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Publication number
JP4438983B2
JP4438983B2 JP2003297049A JP2003297049A JP4438983B2 JP 4438983 B2 JP4438983 B2 JP 4438983B2 JP 2003297049 A JP2003297049 A JP 2003297049A JP 2003297049 A JP2003297049 A JP 2003297049A JP 4438983 B2 JP4438983 B2 JP 4438983B2
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fuel
container
fuel cell
container body
inner container
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JP2005038803A (en
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保昭 中村
秀人 臼井
聡 小見山
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Tokai Corp
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Tokai Corp
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Priority to JP2003297049A priority Critical patent/JP4438983B2/en
Priority to PCT/JP2004/009048 priority patent/WO2005004268A1/en
Priority to US10/563,097 priority patent/US20060151494A1/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04201Reactant storage and supply, e.g. means for feeding, pipes
    • H01M8/04208Cartridges, cryogenic media or cryogenic reservoirs
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Description

本発明は、固体高分子型燃料電池(PEFC)などの燃料電池に供給するメタノール水溶液などの燃料を収容し、燃料電池に装着して該燃料電池に直接燃料を供給する燃料電池用燃料容器および燃料電池に装着して用いる燃料容器に燃料を再注入する燃料電池用燃料容器に関するものである。   The present invention relates to a fuel container for a fuel cell that contains a fuel such as an aqueous methanol solution supplied to a fuel cell such as a polymer electrolyte fuel cell (PEFC), is attached to the fuel cell, and supplies the fuel cell directly. The present invention relates to a fuel container for a fuel cell that reinjects fuel into a fuel container that is used by being attached to the fuel cell.

従来の溶液を収容する容器としては、例えば、エアゾール容器、化粧品容器などがあるが、その容器本体には、ガラス、金属、プラスチックが使用されている。これら容器内は加圧されることで、ノズルを開作動した際に、内部の溶液が噴霧状に流出して使用に供される。   Conventional containers for storing solutions include, for example, aerosol containers and cosmetic containers. Glass, metal, and plastic are used for the container body. By pressurizing the inside of these containers, when the nozzle is opened, the solution inside flows out in a spray state and is used.

上記のような容器においては、そのノズルを閉方向に付勢する付勢部材としてスプリングが使用されている。このスプリングとしては、コストや使い勝手から金属製コイルスプリングを用いるのが一般的であるが、リサイクル率を高めるために、付勢部材を樹脂製の筒状弾性材で構成した構造が提案されている(例えば、特許文献1参照)。
特開平11−90282号公報
In the container as described above, a spring is used as a biasing member that biases the nozzle in the closing direction. As this spring, a metal coil spring is generally used from the viewpoint of cost and convenience, but in order to increase the recycling rate, a structure in which the urging member is made of a resin cylindrical elastic material has been proposed. (For example, refer to Patent Document 1).
JP-A-11-90282

ところで、例えば携帯用パソコン(ノートパソコン、PDA等)その他の機器の小型電源として燃料電池の使用が検討されているが、この燃料電池に燃料を供給するための燃料容器が必要とされ、その燃料としては例えば固体高分子型燃料電池(PEFC)にはメタノールに純水またはエタノールに純水を加えたもの、または純メタノールまたは純エタノールが使用される。また、固体酸化物型燃料電池(SOFC)や固体高分子型燃料電池(PEFC)にはジメチルエーテルの使用が期待される。   By the way, for example, the use of a fuel cell as a small power source for a portable personal computer (notebook personal computer, PDA, etc.) and other devices is being studied. However, a fuel container for supplying fuel to the fuel cell is required. For example, for a polymer electrolyte fuel cell (PEFC), pure water or pure water added to methanol, or pure methanol or pure ethanol is used. Also, dimethyl ether is expected to be used in solid oxide fuel cells (SOFC) and solid polymer fuel cells (PEFC).

しかしながら、固体高分子型燃料電池(PEFC)や固体酸化物型燃料電池(SOFC)などの燃料電池では、金属イオンの混入を極度に嫌うため、燃料容器においては収容した燃料に金属イオンが混入しないように構成する必要があることが判明した。   However, in a fuel cell such as a polymer electrolyte fuel cell (PEFC) or a solid oxide fuel cell (SOFC), metal ions are extremely disliked, so that metal ions are not mixed in the fuel contained in the fuel container. It was found that it was necessary to configure as follows.

燃料と接触する部材に金属を用いることはイオンが発生することから不適切であり、この金属に樹脂をコーティングしても樹脂皮膜のピンホールによってイオンの発生は避けられない。また、燃料容器に内圧を加えて、この内圧によって燃料を噴出供給させる場合に、噴出材と燃料が混合供給されることも好ましくない。   It is inappropriate to use a metal for the member in contact with the fuel because ions are generated. Even if a resin is coated on the metal, the generation of ions is unavoidable due to the pinhole of the resin film. In addition, when the internal pressure is applied to the fuel container and the fuel is jetted and supplied by the internal pressure, it is not preferable that the jetted material and the fuel are mixedly supplied.

また、上記燃料容器の形状は、燃料電池本体もしくは燃料電池を搭載しているノートパソコン等の機器における燃料容器収容部の形状等に応じて設定されるもので、特定の機種に応じた特定の形状に設けられ、このような燃料容器を燃料消費に応じて使い捨てにするのはコスト的に不利であるとともに、入手困難となりやすく利便性に欠ける問題を有する。   In addition, the shape of the fuel container is set according to the shape of the fuel container housing portion in a device such as a fuel cell main body or a notebook personal computer equipped with the fuel cell, and a specific type according to a specific model. Disposing such a fuel container in a shape according to fuel consumption is disadvantageous in terms of cost, and is difficult to obtain and has a problem of lack of convenience.

本発明はこのような点に鑑みなされたもので、金属イオンおよび噴射材が混入しないとともに繰り返しての使用が可能な燃料電池に装着する燃料電池用燃料容器および燃料電池に装着する燃料容器に燃料を再注入する燃料電池用燃料容器を提供することを目的とするものである。   The present invention has been made in view of the above points. A fuel container for a fuel cell to be mounted on a fuel cell that can be used repeatedly without being mixed with metal ions and an injection material, and a fuel in a fuel container to be mounted on a fuel cell. An object of the present invention is to provide a fuel container for a fuel cell that re-injects fuel.

本発明の燃料電池用燃料容器は、燃料電池に供給する燃料を収容する燃料容器であって、密閉構造を有する容器本体と、該容器本体内に設置され内部に前記燃料を収容する可撓性袋で構成された内容器と、前記容器本体に設置され前記内容器の内部に連通し収容した燃料の供給を開閉するバルブ機構と、前記容器本体に設置され前記内容器の内部に連通し燃料を注入するための注入バルブと、前記容器本体と前記内容器との間に封入された燃料噴出用の圧縮ガスとを備え、前記燃料と接触する構成部材を全て非金属材料で構成してなり、燃料電池に装着して該燃料電池に直接燃料を供給することを特徴とするものである。   A fuel container for a fuel cell according to the present invention is a fuel container that contains fuel to be supplied to a fuel cell, and has a container body having a sealed structure, and a flexibility that is installed in the container body and contains the fuel therein. An inner container composed of a bag; a valve mechanism installed in the container body for opening and closing the supply of fuel contained in the inner container; and a fuel installed in the container body and communicated with the interior of the inner container An injection valve for injecting fuel, and a compressed gas for fuel injection sealed between the container main body and the inner container, and all the constituent members in contact with the fuel are made of a non-metallic material. The fuel cell is attached to the fuel cell and the fuel is directly supplied to the fuel cell.

また、本発明の他の燃料電池用燃料容器は、燃料電池に供給する燃料を収容する燃料容器であって、密閉構造を有する容器本体と、該容器本体内に設置され内部に前記燃料を収容する可撓性袋で構成された内容器と、前記容器本体に設置され前記内容器の内部に連通し収容した燃料の供給を開閉するとともに内容器内に燃料を注入するためのバルブ機構と、前記容器本体と前記内容器との間に封入された燃料噴出用の圧縮ガスとを備え、前記燃料と接触する構成部材を全て非金属材料で構成してなり、燃料電池に装着して該燃料電池に直接燃料を供給することを特徴とするものである。   Further, another fuel container for a fuel cell according to the present invention is a fuel container for storing fuel to be supplied to the fuel cell, the container main body having a sealed structure, and the fuel stored in the container main body. An inner container composed of a flexible bag, a valve mechanism for opening and closing the supply of fuel that is installed in the container main body and communicated and accommodated inside the inner container, and for injecting fuel into the inner container, A fuel jet compressed gas sealed between the container main body and the inner container, and all the constituent members that come into contact with the fuel are made of a non-metallic material, and are mounted on a fuel cell. The fuel is directly supplied to the battery.

さらに、本発明の他の燃料電池用燃料容器は、燃料電池に供給する燃料を収容する燃料容器であって、密閉構造を有する容器本体と、該容器本体内に設置され内部に前記燃料を収容する可撓性袋で構成された内容器と、前記容器本体に設置され前記内容器の内部に連通し収容した燃料の供給を開閉するバルブ機構と、前記容器本体と前記内容器との間に、燃料電池に装着して該燃料電池に直接燃料を供給する燃料容器の燃料圧力より高く設定された圧力で封入された燃料噴出用の圧縮ガスとを備え、前記燃料と接触する構成部材を全て非金属材料で構成してなり、燃料電池に直接燃料を供給する前記燃料容器へ燃料を再注入することを特徴とするものである。   Furthermore, another fuel container for a fuel cell according to the present invention is a fuel container for storing fuel to be supplied to the fuel cell, the container main body having a sealed structure, and the fuel stored in the container main body. An inner container composed of a flexible bag, a valve mechanism that is installed in the container main body and opens and closes the supply of fuel that is communicated and accommodated inside the inner container, and between the container main body and the inner container A fuel injection compressed gas sealed at a pressure set higher than the fuel pressure of a fuel container that is attached to the fuel cell and supplies fuel directly to the fuel cell, and all the components that come into contact with the fuel It is composed of a non-metallic material and is characterized by reinjecting fuel into the fuel container that supplies fuel directly to the fuel cell.

さらにまた、本発明の他の燃料電池用燃料容器は、燃料電池に供給する燃料を収容する燃料容器であって、内部に前記燃料を収容するシリンダ状の容器本体と、この容器本体内を気密状態で摺動し前記燃料を加圧する手動操作されるピストン状の押出部材と、前記容器本体に設置され収容した燃料の供給を開閉するバルブ機構とを備え、前記燃料と接触する構成部材を全て非金属材料で構成してなり、燃料電池に装着して該燃料電池に直接燃料を供給する燃料容器へ燃料を再注入することを特徴とするものである。   Furthermore, another fuel container for a fuel cell according to the present invention is a fuel container for storing fuel to be supplied to the fuel cell, and a cylindrical container body for storing the fuel therein, and the inside of the container body is hermetically sealed. A piston-type push-out member that is manually operated to slide and pressurize the fuel, and a valve mechanism that opens and closes the supply of the fuel stored in the container body, and all the components that come into contact with the fuel It is made of a non-metallic material, and is characterized in that fuel is reinjected into a fuel container that is mounted on a fuel cell and directly supplies fuel to the fuel cell.

前記各燃料電池用燃料容器における容器本体を透明材料で構成するのが好適である。   The container body in each fuel cell fuel container is preferably made of a transparent material.

本発明燃料容器は、燃料がメタノールと純水またはエタノールと純水、もしくは純メタノールまたは純エタノールであり、固体高分子型燃料電池(PEFC)の燃料供給用であるものが好適である。また、固体酸化物型燃料電池(SOFC)や固体高分子型燃料電池(PEFC)の燃料としてはジメチルエーテルも使用可能である。   In the fuel container according to the present invention, it is preferable that the fuel is methanol and pure water, ethanol and pure water, or pure methanol or pure ethanol, and is used for fuel supply of a polymer electrolyte fuel cell (PEFC). Also, dimethyl ether can be used as a fuel for a solid oxide fuel cell (SOFC) or a polymer electrolyte fuel cell (PEFC).

上記のような本発明によれば、密閉構造を有する容器本体と、燃料を収容する内容器と、燃料の供給を開閉するバルブ機構とを備え、燃料と接触する構成部材を全て非金属材料で構成し、容器本体と内容器の間に圧縮ガスを封入したことにより、燃料のみを噴出供給することができ、さらに、収容した燃料が金属と接触せずに金属イオンの混入が防止でき、特に固体高分子型燃料電池(PEFC)などの燃料電池では供給するメタノール水溶液またはエタノール水溶液などの燃料に金属イオンが存在することが極端に嫌われるが、上記部材の非金属化によって金属イオンの溶出が防止でき、燃料電池の性能を損なうことがなく、燃料が再注入可能で燃料電池に装着して直接燃料を供給する燃料容器または燃料電池に装着して直接燃料を供給する燃料容器へ燃料を再注入する燃料容器が構成できる。   According to the present invention as described above, a container body having a sealed structure, an inner container for containing fuel, and a valve mechanism for opening and closing the supply of fuel are provided, and all the components that come into contact with the fuel are made of a non-metallic material. By configuring and sealing the compressed gas between the container body and the inner container, it is possible to supply only the fuel, and further, the contained fuel can be prevented from coming into contact with the metal and mixing of metal ions can be prevented. In a fuel cell such as a polymer electrolyte fuel cell (PEFC), it is extremely hated that metal ions are present in a fuel such as an aqueous methanol solution or an ethanol aqueous solution to be supplied. The fuel can be re-injected and can be re-injected, and the fuel can be re-injected and attached directly to the fuel container or the fuel cell. Fuel container to re-inject fuel into the fuel container can be constructed.

つまり、燃料を再注入する注入バルブをさらに備えた燃料容器、または、燃料の供給と注入が行えるバルブ機構を備えた燃料容器では、燃料再注入用に構成された燃料容器を使用することによって、ユーザーが簡単に燃料の再充填が可能で、繰り返しての使用ができ使い捨てでないことでコスト的に有利であるとともに、機種に対応した形状の自由度が高められ、注入用の燃料容器の汎用化を図ることで追加燃料が入手しやすく、利便性が向上できる。   In other words, in a fuel container further provided with an injection valve for reinjecting fuel, or a fuel container with a valve mechanism capable of supplying and injecting fuel, by using a fuel container configured for fuel reinjection, The user can easily refill the fuel, it can be used repeatedly and is not disposable, which is advantageous in terms of cost, and the flexibility of the shape corresponding to the model is increased, and the fuel container for injection is generalized. This makes it easier to obtain additional fuel and improves convenience.

特に、燃料電池に接続するバルブ機構とは別途に注入バルブを備えた燃料容器では、この燃料容器を燃料電池に装着した状態で注入バルブより燃料の再注入が可能である。一方、燃料の供給と再注入が行えるバルブ機構を備えた燃料容器では、この燃料容器を燃料電池より取り外して燃料の再注入を行うことになるが、別途の注入バルブを省略して構造の簡素化が図れる。   In particular, in a fuel container provided with an injection valve separately from the valve mechanism connected to the fuel cell, the fuel can be reinjected from the injection valve in a state where the fuel container is mounted on the fuel cell. On the other hand, in a fuel container equipped with a valve mechanism capable of supplying and reinjecting fuel, the fuel container is removed from the fuel cell and reinjecting fuel. However, a separate injection valve is omitted and the structure is simplified. Can be achieved.

一方、容器本体と内容器との間に封入した圧縮ガスの圧力を、燃料電池に装着して該燃料電池に直接燃料を供給する燃料容器の燃料圧力より高く設定した燃料容器、または、シリンダ状の容器本体と手動操作されるピストン状の押出部材とを備えた燃料容器では、燃料電池に直接燃料を供給する燃料容器への燃料の再注入が行え、その形状は任意であって、燃料収容量の自由度、携帯性等を考慮して各種形態に構成して利便性が向上できる。   On the other hand, the pressure of the compressed gas sealed between the container body and the inner container is set to be higher than the fuel pressure of the fuel container that is attached to the fuel cell and supplies fuel directly to the fuel cell, or the cylinder shape In the fuel container having the container main body and the manually operated piston-like pushing member, the fuel can be reinjected into the fuel container for supplying the fuel directly to the fuel cell. Convenience can be improved by configuring various forms in consideration of the degree of freedom, portability, and the like.

前記容器本体を透明材料で構成すると、燃料残量および再注入状態が監視できて好適である。   It is preferable that the container body is made of a transparent material because the remaining amount of fuel and the reinjection state can be monitored.

また、燃料容器の樹脂化に伴い次のような効果がある。容器形状が円筒形、多角形、楕円などの様々な形状に形成可能である。分別廃棄がしやすくリサイクルに適する。手に触れたとき、金属のような冷たさがなく温感がよい。腐食による内容物の変化が起きにくい。   In addition, the following effects can be obtained with the resinization of the fuel container. The container shape can be formed into various shapes such as a cylindrical shape, a polygonal shape, and an elliptical shape. Easy to separate and suitable for recycling. When touching the hand, there is no cold like metal, and a warm feeling is good. Changes in contents due to corrosion are unlikely to occur.

以下、本発明の実施の形態を詳細に説明する。図1は一つの実施の形態における燃料電池に装着して使用する燃料電池用燃料容器の概略断面図、図2はバルブ機構の設置例を示す要部断面図である。   Hereinafter, embodiments of the present invention will be described in detail. FIG. 1 is a schematic cross-sectional view of a fuel container for a fuel cell used by being mounted on a fuel cell according to one embodiment, and FIG. 2 is a cross-sectional view of a main part showing an installation example of a valve mechanism.

本実施形態の燃料電池用燃料容器1は、所定濃度のメタノールと純水またはエタノールと純水もしくは純メタノールまたは純エタノールを燃料電池用燃料Fとして収容し、固体高分子型燃料電池(PEFC)などに燃料を供給するためのものであり、不図示の燃料電池本体に装着され、後述の注入用燃料容器10,20などを用いて燃料Fの再注入が可能であり、繰り返して使用される。   A fuel container 1 for a fuel cell according to the present embodiment accommodates methanol and pure water or ethanol and pure water or pure methanol or pure ethanol having a predetermined concentration as a fuel F for a fuel cell, such as a polymer electrolyte fuel cell (PEFC). The fuel F is mounted on a fuel cell body (not shown), and fuel F can be reinjected using an injection fuel container 10 or 20 described later, and is used repeatedly.

前記燃料容器1は、図1に示すように、外形を構成する外側の容器本体2と、この容器本体2の内部空間に配設され内部に前記燃料Fを収容する可撓性袋による内容器3と、内容器3の内部から容器本体2の外部に連通する上部の供給口2aを開閉して収容した燃料を供給するバルブ機構4と、上記供給口2aと反対側の底部における内容器3の内部から容器本体2の外部に連通する注入口2bを開閉して燃料を注入するための注入バルブ5と、前記バルブ機構4から内容器3の内部空間に挿入されるディップチューブ6とで構成される。そして、これらを構成する全ての部品、特に燃料と接触する部品が非金属材料、すなわち樹脂にて構成されてなる。また、容器本体2と内容器3との間は気密に形成され、その空間に内容器3に対し燃料Fの噴出用圧力を加える圧縮ガスGを封入してなる。   As shown in FIG. 1, the fuel container 1 includes an outer container body 2 constituting an outer shape, and an inner container made of a flexible bag that is disposed in an inner space of the container body 2 and accommodates the fuel F therein. 3, a valve mechanism 4 for supplying fuel stored by opening and closing an upper supply port 2 a communicating from the inside of the inner container 3 to the outside of the container body 2, and the inner container 3 at the bottom opposite to the supply port 2 a An injection valve 5 for injecting fuel by opening and closing an injection port 2b communicating with the outside of the container body 2 from the inside of the container, and a dip tube 6 inserted into the internal space of the inner container 3 from the valve mechanism 4 Is done. And all the parts which comprise these, especially the parts which contact fuel, are comprised with a nonmetallic material, ie, resin. Further, the space between the container body 2 and the inner container 3 is formed in an airtight manner, and a compressed gas G that applies pressure for ejecting the fuel F to the inner container 3 is sealed in the space.

容器本体2は密閉ボックス状でその形状は、不図示の燃料電池本体もしくは燃料電池を搭載しているノートパソコン等の機器における燃料容器収容部の形状等に応じて設定される。また、その形状は所定の内容積を確保する上で任意に設定変更可能であり、収容圧力に対する耐圧強度を確保する構造および壁厚みに設けられている。この外側の容器本体2は、内容器3の形状に基づき燃料残量が確認できるよう、透明材料、例えば透明性を持ったPC,PAN,PEN,PET等の成形品で構成している。   The container body 2 is in the form of a sealed box, and the shape thereof is set according to the shape of the fuel container housing portion in a fuel cell body (not shown) or a device such as a notebook personal computer equipped with the fuel cell. Further, the shape can be arbitrarily changed in order to secure a predetermined internal volume, and is provided in a structure and a wall thickness that secures a pressure resistance against a housing pressure. The outer container body 2 is made of a transparent material, for example, a molded product such as transparent PC, PAN, PEN, or PET, so that the remaining amount of fuel can be confirmed based on the shape of the inner container 3.

一方、内容器3は、燃料に対する耐性を有し、ゴム膜か、PAN,PEN等のシートにセラミックを蒸着させたもの、PE,PP等のシートに金属箔(例えばアルミ箔)を貼り合わせたものを袋状とし、容器本体2の供給口2aおよび注入口2bにシール状態で固着されている。この内容器3はガス透過性を防ぐとともに容器本体2の全体容積に対する燃料容積率を高めるようにその内容積が設定されている。   On the other hand, the inner container 3 is resistant to fuel, and a rubber film or a sheet of PAN, PEN or the like deposited with ceramic, and a metal foil (for example, aluminum foil) bonded to a sheet of PE, PP or the like. A thing is made into a bag shape and it adheres to the supply port 2a and the injection port 2b of the container main body 2 in a sealed state. The inner volume of the inner container 3 is set so as to prevent gas permeability and increase the fuel volume ratio with respect to the entire volume of the container body 2.

外側容器本体2と内容器3との間に封入する圧縮ガスGとしては、空気もしくは窒素、二酸化炭素等を用いる。窒素等の酸素を含まないガスの場合、内容器3を透過した微量酸素による燃料(特にメタノール)の酸化を防ぐことができる。圧縮ガスを用いるため、液化ガスを用いるのに対し、容器本体2の温度上昇に対する圧力変化が小さくなる。   As the compressed gas G sealed between the outer container body 2 and the inner container 3, air, nitrogen, carbon dioxide, or the like is used. In the case of a gas that does not contain oxygen such as nitrogen, the oxidation of fuel (particularly methanol) by the trace amount of oxygen that has permeated through the inner container 3 can be prevented. Since the compressed gas is used, the change in pressure with respect to the temperature rise of the container main body 2 is reduced while the liquefied gas is used.

前記バルブ機構4は、容器本体2の一部(図で上部)に突起筒状に形成された供給口2aの内部に設置されており、その具体例を図2に基づいて説明する。このバルブ機構4には流量調整機構7およびレジスタンス機構8が付設されており、図2(a)の実施形態では、容器本体2の供給口2aの開口部分(燃料電池との接続部位)に、流量調整機構7(具体的構成は不図示)が設置され、その底部側にバルブ機構4が設置されている。一方、図2(b)の実施形態では、容器本体2の供給口2aの開口部分(燃料電池との接続部位)に、バルブ機構4が設置され、その底部側に流量調整機構7(具体的構成は不図示)が設置されている。バルブ機構4の基本構造は、図2(a)と図2(b)で同様に構成されており、同じ符号を付して説明する。   The said valve mechanism 4 is installed in the inside of the supply port 2a formed in the protruding cylinder shape in a part (upper part in the figure) of the container main body 2, The specific example is demonstrated based on FIG. The valve mechanism 4 is provided with a flow rate adjusting mechanism 7 and a resistance mechanism 8. In the embodiment of FIG. 2 (a), the opening portion of the supply port 2 a of the container body 2 (part connected to the fuel cell) A flow rate adjusting mechanism 7 (specific configuration is not shown) is installed, and a valve mechanism 4 is installed on the bottom side thereof. On the other hand, in the embodiment of FIG. 2 (b), the valve mechanism 4 is installed in the opening portion (connection portion with the fuel cell) of the supply port 2a of the container body 2, and the flow rate adjusting mechanism 7 (specifically, on the bottom side). The configuration is not shown). The basic structure of the valve mechanism 4 is configured similarly in FIGS. 2A and 2B, and will be described with the same reference numerals.

バルブ機構4は、容器本体2への固定部材としてのガイドネジ41、燃料の供給を開閉する弁体としてのガスケット42、開閉のための作動部材としてのバルブステム43、閉方向への付勢部材としての樹脂スプリング44、樹脂スプリング4を収容するバルブハウジング45で構成され、全て非金属材料で形成されてなる。   The valve mechanism 4 includes a guide screw 41 as a fixing member to the container body 2, a gasket 42 as a valve body that opens and closes fuel supply, a valve stem 43 as an operation member for opening and closing, and a biasing member in a closing direction The resin spring 44 and the valve housing 45 that accommodates the resin spring 4 are all formed of a non-metallic material.

そして、前記容器本体2の供給口2aに対し、バルブハウジング45が装着される。図2(b)ではバルブハウジング45の底部に予め流量調整機構7が組み付けられている。このバルブハウジング45に樹脂スプリング44が挿入され、その上にバルブステム43が挿入され、このバルブステム43の外周にガスケット42が嵌着され、バルブステム43の上方よりガイドネジ41が容器本体2に螺合されて組み付けられる。バルブステム43は樹脂スプリング44の付勢力によって上方のガイドネジ41へ付勢され、ガスケット42の外周部はガイドネジ41によって容器本体2に保持固定されている。   A valve housing 45 is attached to the supply port 2 a of the container body 2. In FIG. 2 (b), the flow rate adjusting mechanism 7 is assembled in advance at the bottom of the valve housing 45. A resin spring 44 is inserted into the valve housing 45, a valve stem 43 is inserted thereon, a gasket 42 is fitted on the outer periphery of the valve stem 43, and a guide screw 41 is attached to the container body 2 from above the valve stem 43. Screwed and assembled. The valve stem 43 is urged toward the upper guide screw 41 by the urging force of the resin spring 44, and the outer peripheral portion of the gasket 42 is held and fixed to the container body 2 by the guide screw 41.

上記バルブステム43は外周に周溝を有し、この周溝の底部に開口された連通細口が中心通路に連通し、中心通路は上端噴出口に開口している。そして、上記バルブステム43の周溝にガスケット42が嵌着され、ガスケット42の内周面の弾性密着によって連通細口が閉じられて、燃料の供給が遮断される。また、燃料電池との接続に応じて上部側より、図2(a)では流量調整機構7を通して、図2(b)では直接に、バルブステム43が樹脂スプリング44に抗して押し込まれると、その移動に伴ってガスケット42の内周部が変形して連通細口を開口し、ディップチューブ6からバルブハウジング45内に、図2(b)では流量調整機構7を通して、流入した燃料をバルブステム43の中心通路を経て上端開口から、図2(b)では直接燃料電池に、図2(a)では流量調整機構7を通して燃料電池に供給するようになっている。   The valve stem 43 has a circumferential groove on the outer periphery, and a communication narrow port opened at the bottom of the circumferential groove communicates with the central passage, and the central passage opens at the upper end outlet. The gasket 42 is fitted into the circumferential groove of the valve stem 43, and the communication narrow port is closed by the elastic contact of the inner peripheral surface of the gasket 42, thereby shutting off the fuel supply. Further, when the valve stem 43 is pushed against the resin spring 44 from the upper side according to the connection with the fuel cell, through the flow rate adjusting mechanism 7 in FIG. 2A and directly in FIG. Along with the movement, the inner peripheral portion of the gasket 42 is deformed to open the communication narrow port, and the fuel that has flowed into the valve housing 45 from the dip tube 6 and through the flow rate adjusting mechanism 7 in FIG. From the upper end opening through the central passage, the fuel cell is supplied directly to the fuel cell in FIG. 2B and to the fuel cell through the flow rate adjusting mechanism 7 in FIG.

付勢部材としての前記樹脂スプリング44の形状は、下端の姿勢を保持する円板状等の支持基部と、上端のバルブステム43の底部に接触して付勢力を伝達する当接部と、両者を連結する折り返し形状の変形部とで構成されてなる。例えば、この樹脂スプリング44はポリアセタール(POM)で成形される。   The shape of the resin spring 44 as the urging member includes a disc-like support base that maintains the posture of the lower end, a contact portion that contacts the bottom of the valve stem 43 at the upper end and transmits the urging force, It is comprised with the deformation | transformation part of the return | turnback shape which connects. For example, the resin spring 44 is formed of polyacetal (POM).

上記流量調整機構7は、例えば、フィルターの圧縮構造が採用され、燃料流路部にウレタン発泡材等によるフィルターが圧縮状態で配置され、その圧縮率を変化させることにより燃料の流量を調整し、燃料の急激な噴出を抑え、本体機器側での流量調整機構の負荷を軽減させるように構成される。また、バルブ機構4には不用意な開作動を禁止するレジスタンス機構8が付設されてなる。図示の場合、容器本体2の供給口2aの開口端の周辺が、バルブステップS無43の先端より外側に形成されてレジスタンス機構8となり、他部材がバルブステム43の先端に接触するのを規制している。   The flow rate adjusting mechanism 7 employs, for example, a filter compression structure, a filter made of urethane foam or the like is disposed in a compressed state in the fuel flow path, and adjusts the flow rate of the fuel by changing its compression rate, It is configured to suppress a sudden jet of fuel and to reduce the load of the flow rate adjusting mechanism on the main device side. The valve mechanism 4 is provided with a resistance mechanism 8 that prohibits an inadvertent opening operation. In the case shown in the figure, the periphery of the opening end of the supply port 2 a of the container body 2 is formed outside the tip of the valve step S 43 to form the resistance mechanism 8, and other members are prevented from contacting the tip of the valve stem 43. is doing.

注入バルブ5は、基本的には上記バルブ機構4と同様の構成であるが、流量調整機構7は設置しなくてもよい。   The injection valve 5 has basically the same configuration as the valve mechanism 4 described above, but the flow rate adjusting mechanism 7 may not be installed.

上記のような燃料容器1では、所定範囲の圧力を持って燃料Fを噴出させ、かつ燃料以外は噴出させないよう容器本体2と内容器3の二重構造となっているため、落下等の衝撃に対する燃料漏れの防止機能がより高まる。また、ノートパソコン、PDAにおいては高いスペース効率の要求に対応でき、小型で収容量が多い燃料容器が構成できる。また、燃料電池と接続するバルブ機構4とは別途に注入バルブ5を備え、燃料容器1を取り外すことなく注入バルブ5に対し外部より燃料の再注入が行えるようになっている。   The fuel container 1 as described above has a double structure of the container body 2 and the inner container 3 so that the fuel F is ejected with a pressure within a predetermined range and other than the fuel is ejected. The function of preventing fuel leakage against the fuel is further enhanced. In addition, in a notebook personal computer and a PDA, it is possible to meet the demand for high space efficiency, and it is possible to configure a fuel container that is small and has a large capacity. Further, an injection valve 5 is provided separately from the valve mechanism 4 connected to the fuel cell so that fuel can be reinjected from the outside into the injection valve 5 without removing the fuel container 1.

本実施形態の燃料容器1では燃料としてメタノールまたはエタノール水溶液もしくは純メタノールまたは純エタノールを用いているが、固体酸化物型燃料電池(SOFC)や固体高分子型燃料電池(PEFC)の燃料としてはジメチルエーテルも使用可能である。このジメチルエーテルは常温でガス状であり、圧縮して液化ガスとして注入した際にはそれだけで噴出圧力を有するため、容器本体2と内容器3との間への圧縮ガスの封入が必要とされない場合がある。また、ジメチルエーテルは高圧となるため、耐圧構造とする必要があり、さらに溶解性に対する耐性構造とする必要がある。この場合に、燃料容器1が二重構造であるため、内容器3で溶解性の高いジメチルエーテルに対する耐性および漏れ防止機能を確保し、容器本体2で割れ、変形に対する耐圧構造を確保することができる。   In the fuel container 1 of the present embodiment, methanol, an aqueous ethanol solution, pure methanol, or pure ethanol is used as the fuel, but dimethyl ether is used as the fuel for the solid oxide fuel cell (SOFC) and the solid polymer fuel cell (PEFC). Can also be used. This dimethyl ether is gaseous at room temperature, and when compressed and injected as a liquefied gas, it has an ejection pressure by itself, so that it is not necessary to enclose the compressed gas between the container body 2 and the inner container 3 There is. Further, since dimethyl ether has a high pressure, it needs to have a pressure-resistant structure, and further needs to have a structure resistant to solubility. In this case, since the fuel container 1 has a double structure, the inner container 3 can secure resistance to highly soluble dimethyl ether and a leak prevention function, and the container body 2 can ensure a pressure resistant structure against cracking and deformation. .

図3は他の実施形態にかかる燃料電池用燃料容器1′の概略断面図であり、前記実施形態における注入バルブ5の機能を供給口2aのバルブ機構4に持たせ、注入バルブ5の設置を省略した構造である。その他は図1の前記実施形態と同様であり、同一部分には同一符号を付してその説明を省略する。   FIG. 3 is a schematic sectional view of a fuel cell fuel container 1 ′ according to another embodiment. The function of the injection valve 5 in the above embodiment is provided in the valve mechanism 4 of the supply port 2 a, and the injection valve 5 is installed. The structure is omitted. Others are the same as those of the above-described embodiment of FIG. 1, and the same portions are denoted by the same reference numerals and the description thereof is omitted.

本実施形態では、例えば前記図2のようなバルブ機構4の開閉作動によって燃料電池への燃料の供給と、燃料の再注入が行えるものであり、燃料の再注入時には燃料容器1′を燃料電池より取り外して行うことになるが、構造の簡素化を図っている。   In the present embodiment, for example, fuel can be supplied to the fuel cell and fuel can be reinjected by opening and closing the valve mechanism 4 as shown in FIG. 2, and the fuel container 1 'is placed in the fuel cell at the time of fuel reinjection. Although it will be performed by removing more, the structure is simplified.

上記のような燃料電池に装着する燃料容器1,1′の各実施形態によれば、燃料と接触する部品の樹脂化により、メタノール水溶液またはエタノール水溶液などの燃料電池用燃料に金属イオンが混入することなく、噴射材も含まれず、金属イオンの存在が極端に嫌われる固体高分子型燃料電池(PEFC)に対する良好な燃料容器が構成でき、燃料電池の性能を損なうことがないとともに、燃料の再注入により繰り返して使用ができる。   According to each embodiment of the fuel container 1, 1 ′ mounted on the fuel cell as described above, metal ions are mixed into the fuel for the fuel cell such as aqueous methanol solution or aqueous ethanol solution due to the resinization of the parts that come into contact with the fuel. In addition, a good fuel container for a polymer electrolyte fuel cell (PEFC) that does not contain propellants and is extremely disliked by the presence of metal ions can be constructed, and the performance of the fuel cell is not impaired. Can be used repeatedly by injection.

図4および図5は前述の燃料電池用燃料容器1,1′における内容器3内の燃料が減少した際に、燃料を再注入するのに使用する注入用燃料容器の2つの実施形態を示す概略断面図である。   4 and 5 show two embodiments of an injection fuel container used to reinject fuel when the fuel in the inner container 3 of the fuel cell fuel container 1, 1 ′ decreases. It is a schematic sectional drawing.

図4に示す注入用燃料容器10は、容器本体12、可撓性袋による内容器13、バルブ機構14(ノズル機構)、レジスタンス機構15、ディップチューブ16を備え、基本構造は前記燃料容器1,1′と同様であり、内容器13の内部に燃料Fを収容し、容器本体12と内容器13の間には噴出用の圧縮ガスGが封入され、バルブ機構14を燃料容器1の注入バルブ5または燃料容器1′のバルブ機構4に適用して接続し、収容した燃料Fを圧縮ガスGの圧力で注入するようになっている。   An injection fuel container 10 shown in FIG. 4 includes a container body 12, an inner container 13 made of a flexible bag, a valve mechanism 14 (nozzle mechanism), a resistance mechanism 15, and a dip tube 16, and the basic structure is the fuel container 1, 1 ', the fuel F is accommodated in the inner container 13, the compressed gas G for injection is enclosed between the container main body 12 and the inner container 13, and the valve mechanism 14 is connected to the injection valve of the fuel container 1. 5 or the valve mechanism 4 of the fuel container 1 ′ is connected to be connected, and the contained fuel F is injected under the pressure of the compressed gas G.

この注入用燃料容器10における封入された圧縮ガスGの圧力は、前記燃料容器1,1′における圧縮ガスGの圧力すなわち再注入される燃料容器での燃料圧力より高く設定され、注入用燃料容器10内の燃料残量が少なくなっても、十分に燃料容器1,1′内へ燃料の注入が行えるようになっている。   The pressure of the sealed compressed gas G in the fuel container 10 for injection is set higher than the pressure of the compressed gas G in the fuel containers 1 and 1 ', that is, the fuel pressure in the fuel container to be reinjected. Even when the remaining amount of fuel in the fuel tank 10 is reduced, fuel can be sufficiently injected into the fuel containers 1 and 1 '.

バルブ機構14は、前述の図2に示すバルブ機構4と基本的には同様であるが、そのバルブステムの先端が突出して、前記燃料容器1におけるバルブ機構4のバルブステム43を押圧して通路を開作動することで注入するようになっている。   The valve mechanism 14 is basically the same as the valve mechanism 4 shown in FIG. 2 described above, but the tip of the valve stem protrudes and presses the valve stem 43 of the valve mechanism 4 in the fuel container 1 to pass the valve mechanism 14. The injection is performed by opening the.

レジスタンス機構15は、例えば、バルブ機構14の外周に筒壁が形成されて不用意なバルブ機構14の開作動による燃料噴出を防止するもので、燃料容器1の注入バルブ5または燃料容器1′のバルブ機構4との組み合わせ構造によって、再注入時には障害とならないように設けられている。   The resistance mechanism 15 is, for example, a cylinder wall formed on the outer periphery of the valve mechanism 14 to prevent fuel injection due to an unintentional opening operation of the valve mechanism 14. The resistance mechanism 15 is provided with the injection valve 5 of the fuel container 1 or the fuel container 1 ′. Due to the combined structure with the valve mechanism 4, it is provided so as not to become an obstacle at the time of reinjection.

図5に示す他の形態の注入用燃料容器20は、手動注入式で噴出用の圧縮ガスが封入されていないものである。この注入用燃料容器20は、シリンダ状の容器本体21と、この容器本体21内を気密状態で摺動するピストン状の押出部材22と、容器本体21の先端部に設置されたバルブ機構23(ノズル機構)と、容器本体21のバルブ機構23と反対側を閉塞する蓋部材24と、レジスタンス機構25を備え、押出部材22の後退作動によって内部に収容した燃料Fを、押出部材22の操作部22aの前進移動によって容器本体21内の燃料を加圧し、バルブ機構23を介して燃料容器1,1′の内容器3に注入するようになっている。   An injection fuel container 20 of another form shown in FIG. 5 is a manual injection type and does not contain compressed gas for injection. The fuel container 20 for injection includes a cylindrical container main body 21, a piston-like push-out member 22 that slides in an airtight state in the container main body 21, and a valve mechanism 23 ( Nozzle mechanism), a lid member 24 that closes the container body 21 on the opposite side of the valve mechanism 23, and a resistance mechanism 25, and the fuel F contained therein by the retraction operation of the extrusion member 22 The fuel in the container main body 21 is pressurized by the forward movement of 22a and injected into the inner container 3 of the fuel container 1, 1 'through the valve mechanism 23.

また、上記容器本体21には、蓋部材24との接合部に嵌合突起21aを備え、燃料容器1,1′に接続した際に、その内部に残留している燃料が容器本体21内に逆流した際に、押出部材22が後退して蓋部材24が離脱するのを防止する機能を得ている。   Further, the container body 21 is provided with a fitting projection 21a at the joint portion with the lid member 24, and the fuel remaining inside the container body 21 when connected to the fuel container 1, 1 'is contained in the container body 21. The function of preventing the push-out member 22 from moving backward and the lid member 24 from being separated when backflowing is obtained.

上記注入用燃料容器10,20においても、燃料Fと接触する部品が非金属材料すなわち樹脂にて構成されてなり、燃料Fへの金属イオンの混入が防止される。また、その容器本体12,21は内容量が確認できるように透明材料で構成している。さらに、容器本体12,21の形状は任意であって、燃料収容量、携帯性等を考慮して各種形態に構成される。   Also in the fuel containers 10 and 20 for injection, components that come into contact with the fuel F are made of a non-metallic material, that is, a resin, and mixing of metal ions into the fuel F is prevented. The container bodies 12 and 21 are made of a transparent material so that the internal volume can be confirmed. Furthermore, the shape of the container bodies 12 and 21 is arbitrary, and is configured in various forms in consideration of the fuel capacity, portability, and the like.

前述の燃料容器1,1′および注入用燃料容器10,20における燃料と接触する部品の樹脂材質としては、PE,PP,AS,ABS,PAN,PA,PET,PBT,PC,POM,PEN等が使用できるが、内容物や形状および強度等により選択される。例えば、メタノールに対する耐性を考慮すると、ポリエチレン(PE),ポリプロピレン(PP),ポリエチレンナフタレート(PEN),ポリエチレンテレフタレート(PET),ポリアクリロニトリル(PAN)が優れて好ましく、アクリロニトリルブタジエンスチレン(ABS),ポリアミド(PA),ポリアセタール(POM)も使用可能である。また、エタノールに対する耐性を考慮すると、ポリエチレン(PE),ポリプロピレン(PP),ポリアミド(PA),ポリアセタール(POM),ポリエチレンナフタレート(PEN),ポリエチレンテレフタレート(PET),ポリアクリロニトリル(PAN)が優れて好ましく、アクリロニトリルブタジエンスチレン(ABS)も使用可能である。   The resin materials of the parts that come into contact with the fuel in the fuel containers 1 and 1 'and the fuel containers 10 and 20 are PE, PP, AS, ABS, PAN, PA, PET, PBT, PC, POM, PEN, and the like. Can be used, but is selected depending on the contents, shape, strength, and the like. For example, considering resistance to methanol, polyethylene (PE), polypropylene (PP), polyethylene naphthalate (PEN), polyethylene terephthalate (PET), and polyacrylonitrile (PAN) are preferable, and acrylonitrile butadiene styrene (ABS), polyamide (PA) and polyacetal (POM) can also be used. Considering the resistance to ethanol, polyethylene (PE), polypropylene (PP), polyamide (PA), polyacetal (POM), polyethylene naphthalate (PEN), polyethylene terephthalate (PET), and polyacrylonitrile (PAN) are excellent. Preferably, acrylonitrile butadiene styrene (ABS) can also be used.

また、ジメチルエーテルに対する耐性を考慮すると、結晶性樹脂であるポリアミド(PA)、ポリアセタール(POM)、ポリブチレンテレフタレート(PBT)、ポリプロピレン(PP)などで構成される。もしくは非結晶性樹脂であるアセタール、ポリカーボネイト、アクリロニトリルブタジエンスチレンで形成し、その表面にエポキシ樹脂またはポリアミド樹脂をコーティングして構成するのが好適である。   In consideration of resistance to dimethyl ether, it is composed of a crystalline resin such as polyamide (PA), polyacetal (POM), polybutylene terephthalate (PBT), polypropylene (PP), or the like. Alternatively, it is preferable to form an amorphous resin such as acetal, polycarbonate, or acrylonitrile butadiene styrene and coat the surface with an epoxy resin or a polyamide resin.

成形構造としては、単一材料で成形した単層構造、複数材料で成形した二層(多層)構造がある。二層構造の場合には、内容物が触れる内層部分に、耐性に優れた材料を用い、外層に耐圧性、耐衝撃性に優れた材料を使用し、二色成形、コーティング等によって構成する。   As the molding structure, there are a single-layer structure formed of a single material and a two-layer (multi-layer) structure formed of a plurality of materials. In the case of a two-layer structure, a material having excellent resistance is used for the inner layer portion touched by the contents, and a material having excellent pressure resistance and impact resistance is used for the outer layer, and the two-layer molding or coating is used.

本発明の一つの実施の形態における燃料電池に装着する燃料電池用燃料容器の概略断面図1 is a schematic cross-sectional view of a fuel container for a fuel cell attached to a fuel cell in one embodiment of the present invention. バルブ機構の2つの設置例を示す要部断面図Cross-sectional view of the main part showing two installation examples of the valve mechanism 他の実施形態にかかる燃料電池に装着する燃料電池用燃料容器の概略断面図Schematic sectional view of a fuel container for a fuel cell to be attached to a fuel cell according to another embodiment 一つの実施の形態における燃料再注入用の燃料電池用燃料容器の概略断面図1 is a schematic cross-sectional view of a fuel cell fuel container for fuel reinjection in one embodiment. 他の実施の形態にかかる燃料再注入用の燃料電池用燃料容器の概略断面図Schematic sectional view of a fuel container for a fuel cell for fuel reinjection according to another embodiment

符号の説明Explanation of symbols

1,1′ 燃料電池装着用の燃料電池用燃料容器
2 容器本体
2a 供給口
2b 注入口
3 内容器
4 バルブ機構
5 注入バルブ
10,20 注入用の燃料電池用燃料容器
12,21 容器本体
13 内容器
14,23 バルブ機構
22 押出部材
24 蓋部材
F 燃料
G 圧縮ガス
1,1 'Fuel cell fuel container for fuel cell installation 2 Container body
2a Supply port
2b Inlet 3 Inner container 4 Valve mechanism 5 Injection valve
10, 20 Fuel cell fuel container for injection
12, 21 Container body
13 Inner container
14, 23 Valve mechanism
22 Extruded member
24 Lid member F Fuel G Compressed gas

Claims (4)

燃料電池に供給するメタノールまたはエタノール水溶液もしくは純メタノールまたは純エタノールまたはジメチルエーテルからなる燃料を収容する燃料容器であって、
密閉構造を有する容器本体と、
該容器本体内に設置され内部に前記燃料を収容する可撓性袋で構成された内容器と、
前記容器本体に設置され前記内容器の内部に連通し収容した燃料の供給を開閉するバルブ機構と、
前記容器本体に設置され前記内容器の内部に連通し燃料を注入するための注入バルブと、
前記容器本体と前記内容器との間に封入された燃料噴出用圧力用の圧縮ガスとを備え、
前記燃料と接触する構成部材を全て非金属材料で構成してなり、燃料電池に装着して該燃料電池に直接燃料を供給することを特徴とする燃料電池用燃料容器。
A fuel container containing a fuel made of methanol or an aqueous ethanol solution or pure methanol or pure ethanol or dimethyl ether supplied to a fuel cell,
A container body having a sealed structure;
An inner container configured with a flexible bag installed in the container body and containing the fuel therein;
A valve mechanism that is installed in the container body and opens and closes the supply of fuel communicated and stored in the interior of the inner container;
An injection valve for injecting fuel in communication with the interior of the inner container installed in the container body;
A compressed gas for fuel ejection pressure enclosed between the container body and the inner container;
The fuel container for a fuel cell is characterized in that all of the constituent members that come into contact with the fuel are made of a non-metallic material, and are attached to the fuel cell to supply the fuel cell directly.
燃料電池に供給するメタノールまたはエタノール水溶液もしくは純メタノールまたは純エタノールまたはジメチルエーテルからなる燃料を収容する燃料容器であって、
密閉構造を有する容器本体と、
該容器本体内に設置され内部に前記燃料を収容する可撓性袋で構成された内容器と、
前記容器本体に設置され前記内容器の内部に連通し収容した燃料の供給を開閉するとともに内容器内に燃料を注入するためのバルブ機構と、
前記容器本体と前記内容器との間に封入された燃料噴出用圧力を加える圧縮ガスとを備え、
前記燃料と接触する構成部材を全て非金属材料で構成してなり、燃料電池に装着して該燃料電池に直接燃料を供給することを特徴とする燃料電池用燃料容器。
A fuel container containing a fuel made of methanol or an aqueous ethanol solution or pure methanol or pure ethanol or dimethyl ether supplied to a fuel cell,
A container body having a sealed structure;
An inner container configured with a flexible bag installed in the container body and containing the fuel therein;
A valve mechanism for opening and closing the supply of fuel that is installed in the container body and communicated and accommodated inside the inner container, and for injecting fuel into the inner container;
A compressed gas for applying a pressure for fuel injection sealed between the container body and the inner container;
The fuel container for a fuel cell is characterized in that all of the constituent members that come into contact with the fuel are made of a non-metallic material, and are attached to the fuel cell to supply the fuel cell directly.
燃料電池に供給するメタノールまたはエタノール水溶液もしくは純メタノールまたは純エタノールまたはジメチルエーテルからなる燃料を収容する燃料容器であって、
密閉構造を有する容器本体と、
該容器本体内に設置され内部に前記燃料を収容する可撓性袋で構成された内容器と、
前記容器本体に設置され前記内容器の内部に連通し収容した燃料の供給を開閉するバルブ機構と、
前記容器本体と前記内容器との間に、請求項1に記載の注入バルブから燃料が再注入される燃料電池用燃料容器の燃料圧力より高く設定された圧力で封入された噴出用圧力を加える圧縮ガスとを備え、
前記燃料と接触する構成部材を全て非金属材料で構成してなり、燃料電池に直接燃料を供給する前記燃料容器へ燃料を再注入することを特徴とする燃料電池用燃料容器。
A fuel container containing a fuel made of methanol or an aqueous ethanol solution or pure methanol or pure ethanol or dimethyl ether supplied to a fuel cell,
A container body having a sealed structure;
An inner container configured with a flexible bag installed in the container body and containing the fuel therein;
A valve mechanism that is installed in the container body and opens and closes the supply of fuel communicated and stored in the interior of the inner container;
The injection pressure enclosed by the pressure set higher than the fuel pressure of the fuel container for fuel cells into which fuel is reinjected from the injection valve of Claim 1 is added between the said container main body and the said inner container. With compressed gas ,
A fuel container for a fuel cell, wherein all of the constituent members that come into contact with the fuel are made of a non-metallic material, and the fuel is reinjected into the fuel container that supplies fuel directly to the fuel cell.
前記容器本体が透明材料で構成されてなることを特徴とする請求項1〜3のいずれか1項に記載の燃料電池用燃料容器。 The fuel container for a fuel cell according to any one of claims 1 to 3 , wherein the container body is made of a transparent material.
JP2003297049A 2003-07-03 2003-08-21 Fuel container for fuel cell Expired - Fee Related JP4438983B2 (en)

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Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1753060A4 (en) 2004-05-27 2009-01-14 Mitsubishi Pencil Co Fuel reservoir for fuel cell
JP4956184B2 (en) 2004-06-08 2012-06-20 三菱鉛筆株式会社 Fuel cell fuel reservoir
WO2006001419A1 (en) * 2004-06-25 2006-01-05 Mitsubishi Pencil Co., Ltd. Fuel cell
JP4956186B2 (en) * 2004-06-25 2012-06-20 三菱鉛筆株式会社 Fuel cell fuel reservoir
US20060204802A1 (en) 2005-03-10 2006-09-14 Specht Steven J Fuel cell systems and related methods
JP5100022B2 (en) * 2005-04-08 2012-12-19 三洋電機株式会社 Fuel cell system
WO2006121169A1 (en) 2005-05-09 2006-11-16 Kabushiki Kaisha Toshiba Liquid fuel, fuel cartridge and fuel cell
JPWO2006132017A1 (en) * 2005-06-10 2009-01-08 株式会社ニックス Liquid transmission / reception joint device and fuel cell system provided with the device
JP5042020B2 (en) * 2005-06-17 2012-10-03 東洋製罐株式会社 Methanol fuel cell cartridge
US20090305102A1 (en) * 2005-07-15 2009-12-10 Kenichi Takahashi Fuel battery
JP4947930B2 (en) * 2005-07-25 2012-06-06 株式会社東海 Fuel container for fuel cell
US8408246B2 (en) * 2005-10-05 2013-04-02 Societe Bic Fuel cartridge for fuel cells
KR100673755B1 (en) 2005-10-21 2007-01-24 삼성에스디아이 주식회사 Fuel cell system being capable of without fuel pump
US20070148514A1 (en) * 2005-12-22 2007-06-28 Zhiping Jiang Fuel cells
JP5063935B2 (en) * 2006-06-02 2012-10-31 東洋製罐株式会社 Polyester container for fuel cell cartridges
JP5348852B2 (en) * 2006-06-20 2013-11-20 三菱鉛筆株式会社 Fuel cartridge
US8235077B2 (en) * 2006-09-14 2012-08-07 Societe Bic Device for refilling a fuel cartridge for a fuel cell
KR100811984B1 (en) * 2007-02-15 2008-03-10 삼성에스디아이 주식회사 Fuel cartridge and fuel cell using the same
US20090004536A1 (en) * 2007-05-16 2009-01-01 Paul Knauer Direct methanol fuel cell process tower
CA2731928C (en) * 2008-08-01 2017-02-28 Boehringer Ingelheim International Gmbh Packaging unit with a plastic bottle and a foil bag arranged therein
JP5552492B2 (en) * 2008-12-22 2014-07-16 エバレデイ バツテリ カンパニー インコーポレーテツド Device with fluid consuming battery and fluid manager
AT515343B1 (en) * 2010-08-09 2016-01-15 Faber Ind Spa gas cylinders
US8528774B2 (en) 2011-06-10 2013-09-10 Paccar Inc Fuel cooler assembly
KR101356776B1 (en) * 2013-05-16 2014-01-27 주식회사 코베아 Portable burner
US20180065778A1 (en) * 2016-09-02 2018-03-08 Kenneth Johnson Collapsible fuel container
KR20200071545A (en) * 2018-12-11 2020-06-19 현대자동차주식회사 Device for adjusting pressure of exhaust gas of fuel cell system

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PT91260B (en) * 1988-07-25 1995-07-03 Cebal MANUFACTURING AND CONDITIONING PROCESS OF A BAG DISTRIBUTOR, SUBCONTRACTORS AND CORRESPONDING DISTRIBUTORS
US5137179A (en) * 1990-02-15 1992-08-11 Hans Stoffel Containers and methods for preparing and manufacturing the same
JPH04223058A (en) * 1990-12-26 1992-08-12 Aisin Aw Co Ltd Fuel tank for liquid fuel cell
US5135137A (en) * 1991-01-17 1992-08-04 The Coca-Cola Company Simplified micro-gravity pre-mix package
EP0681548B1 (en) * 1993-12-06 1998-09-23 Charles Kaeser Rechargeable aerosol can using air as the propellant
DE4417488A1 (en) * 1994-05-19 1995-11-23 Pfeiffer Erich Gmbh & Co Kg Discharge device for media
US5672439A (en) * 1995-12-18 1997-09-30 Ballard Power Systems, Inc. Method and apparatus for reducing reactant crossover in an electrochemical fuel cell
JP3148989B2 (en) * 1998-06-30 2001-03-26 株式会社ソフト九九コーポレーション Check valve
FR2785268B1 (en) * 1998-10-28 2001-01-19 Sofab VALVE FOR POCKET TANK
JP2000203605A (en) * 1998-11-16 2000-07-25 Waterfall Co Inc Cartridge for contamination-free dispensing and delivery
JP3668069B2 (en) * 1999-09-21 2005-07-06 株式会社東芝 Liquid fuel container for fuel cell and fuel cell
FR2804665B1 (en) * 2000-02-07 2002-06-14 Oreal POCKET AEROSOL WITH IMPROVED SEALING
JP2001313047A (en) * 2000-04-28 2001-11-09 Yuasa Corp Direct methanol fuel cell
JP4259728B2 (en) * 2000-06-05 2009-04-30 横浜ゴム株式会社 A method for fixing a flexible bag-like tank used for a fuel tank of a flying object.
US6460733B2 (en) * 2001-02-20 2002-10-08 Mti Microfuel Cells, Inc. Multiple-walled fuel container and delivery system
US20030008193A1 (en) * 2001-06-28 2003-01-09 Foamex L.P. Liquid fuel delivery system for fuel cells
US6924054B2 (en) * 2001-10-29 2005-08-02 Hewlett-Packard Development Company L.P. Fuel supply for a fuel cell
JP2004193059A (en) * 2002-12-13 2004-07-08 Hitachi Maxell Ltd Fuel exchange device
JP2004206994A (en) * 2002-12-25 2004-07-22 Renesas Technology Corp Fuel supply of fuel cell

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