US20060052501A1

US20060052501A1 - Process for producing glove having interpenetrating network structure

Info

Publication number: US20060052501A1
Application number: US11/265,469
Authority: US
Inventors: Rong-Shing Li
Original assignee: Individual
Current assignee: Individual
Priority date: 2003-04-25
Filing date: 2005-11-02
Publication date: 2006-03-09
Also published as: TW593511B; JP2004324034A; US7001941B2; TW200422340A; MY138110A; US20040214940A1

Abstract

A process for producing an elastomeric article having an interpenetrating network structure included the following steps. Firstly, a mold is contacted with an elastomeric composition. The elastomeric composition includes a base latex and a thermoplastic ethylene-vinylacetate (EVA) copolymer latex. The base latex includes a styrene-butadiene rubber (SBR) latex and a carboxylated styrene-butadiene rubber (C-SBR) latex, and the mixing ratio of the base latex to the EVA copolymer latex is from 95:5 to 40:60. Then, the elastomeric composition on the mold is allowed to perform a vulcanization reaction, thereby forming the elastomeric article having the interpenetrating network structure.

Description

CROSS REFERENCE TO RELATEDPATENT APPLICATION

This application is a divisional application of application Ser. No. 10/447,723, filed May 29, 2003, which application is incorporated herein by reference.

FIELD OF THE INVENTION

The present invention relates to a process for producing a glove, and more particularly to a process for producing a glove having an interpenetrating network structure.

BACKGROUND OF THE INVENTION

A conventional glove is produced by blending PVC materials with plasticizers. When such glove is combusted, for example in the case of fire or being incinerated, the PVCs will be oxidized to generate corrosive gases and toxic gases such as dioxin, and the plasticizers will be oxidized to generate various contaminating substances. The corrosive gases are considered responsible for pulmonary edema when being inhaled and for serious damages of instruments in contact therewith. Dioxin and some of the contaminating substances might also cause the problems of environmental hormone and the like. In views of environmental protection, these conventional gloves have been eliminated through competition. Therefore, there is always a need to develop an improved glove so as to meet the requirement of environmental protection.
Although a glove made of natural rubber is known to be environmentally-friendly, the mechanical properties such as Young's modulus of the natural rubber glove are unsatisfactory. In addition, the natural rubber is disadvantageous to be a source of irritation such as skin itch, asthma and shock, etc.
JP 9-505612 (1997) described a glove manufactured by nitrile-butadiene rubber (NBR) latex. Although the NBR glove contains no known sources of irritation and has good resistance to chemical solvents, the commercial applications thereof are limited due to high manufacturing costs.
JP 55-163202 (1980) described a process for manufacturing a glove by using styrene-butadiene rubber (SBR). The SBR material is cost-effective. However, such glove has poor tensile stress and low tear strength, and the immersion molding effects of such glove are unsatisfactory.
JP 7-506642 (1995) described a process for manufacturing a glove by using thermoplastic butadiene-styrene-butadiene block polymers. Their commercial applications are limited due to the poor flexibility of such materials and complex processes for producing the gloves therefrom.

SUMMARY OF THE INVENTION

It is an object of the present invention to provide a cost-effective process for producing a glove from an elastomeric composition, which has an interpenetrating network structure.
In accordance with a first aspect of the present invention, there is provided a process for producing a glove having an interpenetrating network structure. Firstly, a mold is contacted with an elastomeric composition comprising a base latex and a thermoplastic ethylene-vinylacetate (EVA) copolymer latex, wherein the base latex comprises a styrene-butadiene rubber (SBR) latex and a carboxylated styrene-butadiene rubber (C-SBR) latex, and the mixing ratio of the base latex to the EVA copolymer latex is from 95:5 to 40:60. Then, the elastomeric composition on the mold is allowed to perform a vulcanization reaction, thereby forming the elastomeric article having the interpenetrating network structure.
In an embodiment, the process further comprises a step of immersing the mold into a solution of a coagulant selected from a group consisting of calcium nitrate, calcium chloride, alky ammonium and a combination thereof, before the step of contacting the mold with the elastomeric composition.
In an embodiment, the process further comprises a step of surface-treating the mold after the step of contacting the mold with the elastomeric composition and before the vulcanization reaction is performed.
In an embodiment, the step of surface-treating the mold is performed by using a surface-treating agent comprising 10˜20% by weight of a synthesized resin, 10˜20% by weight of an acrylic-styrene resin, 1˜10% by weight of a silicon resin and the balance of water.
Preferably, the base latex comprises from 1% to 40% by mole of carboxylate group.
Preferably, the base latex comprises from 5% to 20 % by mole of carboxylate group.
In an embodiment, the elastomeric composition further comprises at least one additive selected from a group consisting of activators, vulcanization agents, vulcanization accelerators, anti-aging agents, enforcement agents, fillers and additional latices.
Preferably, the activator includes zinc oxides, in amount of from 1% to 10% by weight based on the total weight of the base latex and the EVA copolymer latex.
Preferably, the vulcanization agent includes sulfur, organic sulfide and a combination thereof, in amount of from 0.1% to 2% by weight based on the total weight of the base latex and the EVA copolymer latex.
Preferably, the vulcanization agent includes at least one selected from a group consisting of zinc N-ethyl-N-phenyldithiocarbamate, zinc dimethyldithiocarbamate, zinc diethyldithiocarbamate, zinc dibutyldithiocarbamate, zinc mercaptobenzothiazole, tetramethyl disulfide and a combination thereof, in amount of from 0.5% to 10% by weight based on the total weight of the base latex and the EVA copolymer latex.
Preferably, the anti-aging agent includes phenolic compounds or amine compounds, in amount of from 0.5% to 3% by weight based on the total weight of the base latex and the EVA copolymer latex.
Preferably, the enforcement agent includes at least one selected from a group consisting of nano-scale montmorillonite, mica, clay, bentonite, saponite, silica, titanium dioxide, potassium titanate whisker and a combination thereof, in amount of less than 20% by weight based on the total weight of the base latex and the EVA copolymer latex.
Preferably, the additive includes at least one selected from a group consisting of photocatalyst, talcum powder, calcium carbonate, titanium dioxide, antistatic agent, far infrared-ray emitting agent, pigment and a combination thereof, in amount of less than 20% by weight based on the total weight of the base latex and the EVA copolymer latex.
Preferably, the additional latices include aqueous polyurethane, aqueous nitrile rubber latex, acrylic resin latex and a combination thereof, in amount of less than 50% by weight based on the total weight of the base latex and the EVA copolymer latex.
In accordance with a second aspect of the present invention, there is provided a process for producing a glove having an interpenetrating network structure. Firstly, a mold is contacted with an elastomeric composition. The elastomeric composition includes a latex mixture comprising a base latex and a thermoplastic ethylene-vinylacetate (EVA) copolymer latex, wherein the base latex comprises a styrene-butadiene rubber (SBR) latex and a carboxylated styrene-butadiene rubber (C-SBR) latex, 1˜10 weight parts of an activator; 0.1˜2 weight parts of a vulcanization agent; and 0.5˜10 weight parts of a vulcanization accelerator. Then, the elastomeric composition on the mold is allowed to perform a vulcanization reaction, thereby forming the glove article having the interpenetrating network structure.
In an embodiment, the composition further comprises 0.5˜3 weight parts of an anti-aging agent, optionally an enforcement agent less than 20 weight parts, optionally a filler less than 20 weight parts and optionally additional latices less than 50 weight parts.
The above objects and advantages of the present invention will become more readily apparent to those ordinarily skilled in the art after reviewing the following detailed description.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

The objects of meeting the requirements of environmental protection and cost-effectiveness can be achieved by a method of the present invention for producing an elastomeric article having an interpenetrating network structure.
The elastomeric composition of the present invention comprises a base latex and a thermoplastic ethylene-vinylacetate (EVA) copolymer latex. The base latex comprises at least one of a styrene-butadiene rubber (SBR) latex and a carboxylated styrene-butadiene rubber (C-SBR) latex. Some suitable additives, for example activators, vulcanization agents, vulcanization accelerators, anti-aging agents, enforcement agents, fillers and additional latices, can be combined into the elastomeric composition so as to impart desirable properties of the produced elastomeric articles. During a vulcanization process, the base latex and the EVA copolymer latex of the elastomeric composition are cross-linked to form the interpenetrating network structure of the elastomeric article having the interpenetrating network structure so as to impart excellent elastomeric properties such as elasticity and extensibility, as will be described hereinafter. More specifically, due to the excellent elasticity and extensibility, the elastomeric article produced from the elastomeric composition will generate different contractible degrees for the moving and motionless portions of the wearer. Thus, the wearer can feel the elastomeric article next to the skin.
The carboxylated styrene-butadiene rubber (C-SBR) latex is obtained by introducing carboxylate groups into the molecule chains of SBR. The base latex comprises preferably from 1% to 40%, and more preferably from 5% to 20 % by mole of carboxylate groups. The presence of the C-SBR latex can provide good immersion molding effects of the produced elastomeric article and increase hydrogen-bond density of the SBR latex. The tensile stress and tear strength of the elastomeric article can be enhanced accordingly. The hydrogen bonding of C-SBR and/or SBR latex and EVA copolymer latex is increased during vulcanization so as to promote formation of the interpenetrating network structure. Furthermore, the EVA copolymer latex can also increase immersion molding effects of the produced elastomeric article, and thus provides good softness and touch feel.
The above-mentioned base latex can be used alone or in a mixture of at least two C-SBR lattices with different carboxylate groups. In addition, the combination of the SBR latex and the C-SBR latex can be used. The mixing ratio of the base latex to the EVA copolymer latex is preferably from 99:1 to 5:95, and more preferably from 95:5 to 40:60.
The activator used in the present invention may be zinc oxides, in amount of from 1% to 10% by weight based on the total weight of the base latex and the EVA copolymer latex.
The vulcanization agent includes for example sulfur, organic sulfide and a combination thereof, in amount of from 0.1% to 2% by weight based on the total weight of the base latex and the EVA copolymer latex.
The vulcanization agent is used to promote vulcanization reaction and can include for example zinc N-ethyl-N-phenyldithio-carbamate (PX), zinc dimethyldithiocarbamate (PZ), zinc diethyldithiocarbamate (EZ), zinc dibutyldithiocarbamate (BZ), zinc mercaptobenzothiazole (MZ), tetramethyl disulfide and a combination thereof, in amount of from 0.5% to 10% by weight based on the total weight of the base latex and the EVA copolymer latex.
The anti-aging agent may be phenolic compounds or amine compounds, in amount of from 0.5% to 3% by weight based on the total weight of the base latex and the EVA copolymer latex.
The enforcement agent used in the present invention includes for example nano-scale montmorillonite, mica, clay, bentonite, saponite, silica, titanium dioxide, potassium titanate whisker and a combination thereof, in amount of less than 20% by weight based on the total weight of the base latex and the EVA copolymer latex.
The additive used in the present invention includes for example photocatalyst, talcum powder, calcium carbonate, titanium dioxide, antistatic agent, far infrared-ray emitting agent, pigment and a combination thereof, in amount of less than 20% by weight based on the total weight of the base latex and the EVA copolymer latex.
The additional latices can include for example aqueous polyurethane, aqueous nitrile rubber (NBR) latex, acrylic resin latex and a combination thereof, in amount of less than 50% by weight based on the total weight of the base latex and the EVA copolymer latex.
The additives described hereinbefore can be incorporated into the elastomeric composition of the present invention in combination with a dispersing agent so as to increase dispersing effect thereof. Depending on the types of additives, such dispersing agents can be any suitable surfactant in amount of from 0.3% to 1% by weight based on the weight of the additive to be used.
A process for producing a glove will be described as follows. Firstly, a glove mold is immersed in a solution of a coagulant comprising calcium nitrate, calcium chloride, alky ammonium or a combination thereof. After the coagulant is precipitated from the solution, the glove mold is removed and dried. Then, the glove mold is immersed in an elastomeric composition of the present invention, removed and dried. Optionally, the glove mold is surface-treated by using a surface-treating agent comprising 10˜20% by weight of a synthesized resin, 10˜20% by weight of an acrylic-styrene resin, 1˜10% by weight of a silicon resin and the balance of water. Then, the elastomeric composition on the surface-treated glove mold is vulcanized at a temperature between 90 and 180° C. for several minutes to several hundred minutes. After the vulcanized elastomeric composition is cooled and demolded, a glove having an interpenetrating network structure is formed.
The present invention will be further understood in more details with reference to the following examples.

EXAMPLE

Examples 1˜4

Preparation of Elastomeric Composition

Four elastomeric compositions are prepared by the components indicated in Table 1 below, each component being represented by weight parts.

	TABLE 1


	Example#

	Component	1	2	3	4

SBR	100	0	40	50
C-SBR*	0	100	60	50
EVA	20	10	12	15
Sulfur	0.6	0.6	0.6	0.6
Zinc oxide	2	2	2	2
PX**	2	2	2	2
nano-scale clay	6	6	6	6
aqueous nitrile rubber	10	10	10	10
latex
water	20	20	20	20

*comprising 10% by mole of carboxylate group
**zinc N-ethyl-N-phenyldithiocarbamate

Preparation of Glove

Four sets of glove molds are immersed in an aqueous solution containing 0.5˜35% by weight of calcium nitrate. After calcium nitrate is precipitated from the solution, the glove mold is removed and dried. Then, the four sets of glove molds are immersed in the elastomeric compositions of the examples 1˜4, respectively. Then, these glove molds are removed and dried. Optionally, the glove mold is surface-treated by using a surface-treating agent comprising 15% by weight of a synthesized resin, 15% by weight of an acrylic-styrene resin, 4% by weight of a silicon resin and 66% by weight of water. Then, the elastomeric composition on the surface-treated glove mold is vulcanized at a temperature of 150° C. for 15 minutes. After the vulcanized elastomeric compositions are cooled and demolded, gloves having interpenetrating network structures are formed.

Testing of Physical Properties

Table 2 shows the test results of physical properties of the gloves produced in the examples 1˜4.

	TABLE 2


	Example#

Physical properties	1	2	3	4

Ultimate tensile stress (MPa)	20.3	23.3	21.9	20.5
Ultimate elongation (%)	560	740	680	620
Tensile stress @ 100% (MPa)	1.03	1.18	1.10	1.06
Tensile stress @ 200% (MPa)	1.90	2.27	2.11	2.03
Tensile stress @ 300% (MPa)	2.87	3.38	3.22	3.12
Tensile stress @ 400% (MPa)	4.67	5.13	5.01	4.88
Tensile stress @ 500% (MPa)	5.77	7.70	7.12	6.99

The results of Table 2 show that the gloves produced by using the elastomeric compositions of the present invention have excellent tensile stress and elongation. Thus, good softness and touch feel can be provided to the wearer.

Combustion Test of Glove

The combustion tests of the above gloves are performed to measure acidity of the combusted gases and contents of dioxin.
The results of the combustion tests show that the acidities of the combusted gases have pH values between 4.0 and 4.6, and the dioxin content is approximately 0 ng/g. In contrast, the acidities of the combusted gases for a commercial PVC glove is about pH 2.0, and the dioxin content is about 25 ng/g.
The above results show the gloves produced by using the elastomeric compositions of the present invention have superior environmental protection effects.
While the invention has been described in terms of what is presently considered to be the most practical and preferred embodiments, it is to be understood that the invention needs not be limited to the disclosed embodiment. On the contrary, it is intended to cover various modifications and similar arrangements included within the spirit and scope of the appended claims which are to be accorded with the broadest interpretation so as to encompass all such modifications and similar structures.

Claims

1. A process for producing a glove having an interpenetrating network structure, comprising steps of:

contacting a mold with an elastomeric composition comprising a base latex and a thermoplastic ethylene-vinylacetate (EVA) copolymer latex, said base latex comprising a styrene-butadiene rubber (SBR) latex and a carboxylated styrene-butadiene rubber (C-SBR) latex and the mixing ratio of said base latex to said EVA copolymer latex being from 95:5 to 40:60; and

allowing said elastomeric composition on said mold to perform a vulcanization reaction, thereby forming said elastomeric article having said interpenetrating network structure.

2. The process according to claim 1 wherein said base latex comprises from 1% to 40% by mole of carboxylate group.

3. The process according to claim 2 wherein said base latex comprises from 5% to 20 % by mole of carboxylate group.

4. The process according to claim 1 wherein said elastomeric composition comprises at least one additive selected from a group consisting of activators, vulcanization agents, vulcanization accelerators, anti-aging agents, enforcement agents, fillers and additional latices.

5. The process according to claim 4 wherein said activator includes zinc oxides, in amount of from 1% to 10% by weight based on the total weight of said base latex and said EVA copolymer latex.

6. The process according to claim 4 wherein said vulcanization agent includes sulfur, organic sulfide and a combination thereof, in amount of from 0.1% to 2% by weight based on the total weight of said base latex and said EVA copolymer latex.

7. The process according to claim 4 wherein said vulcanization agent includes at least one selected from a group consisting of zinc N-ethyl-N-phenyldithiocarbamate, zinc dimethyldithiocarbamate, zinc diethyldithiocarbamate, zinc dibutyldithiocarbamate, zinc mercaptobenzothiazole, tetramethyl disulfide and a combination thereof, in amount of from 0.5% to 10% by weight based on the total weight of said base latex and said EVA copolymer latex.

8. The process according to claim 4 wherein said anti-aging agent includes phenolic compounds or amine compounds, in amount of from 0.5% to 3% by weight based on the total weight of said base latex and said EVA copolymer latex.

9. The process according to claim 4 wherein said enforcement agent is a nano-scale enforcement agent including at least one selected from a group consisting of montmorillonite, mica, clay, bentonite, saponite, silica, titanium dioxide, potassium titanate whisker and a combination thereof, in amount of less than 20% by weight based on the total weight of said base latex and said EVA copolymer latex.

10. The process according to claim 4 wherein said additive includes at least one selected from a group consisting of photocatalyst, talcum powder, calcium carbonate, titanium dioxide, antistatic agent, far infrared-ray emitting agent, pigment and a combination thereof, in amount of less than 20% by weight based on the total weight of said base latex and said EVA copolymer latex.

11. The process according to claim 4 wherein said additional latices include aqueous polyurethane, aqueous nitrile rubber latex, acrylic resin latex and a combination thereof, in amount of less than 50% by weight based on the total weight of said base latex and said EVA copolymer latex.

12. The process according to claim 1 further comprising a step of immersing said mold into a solution of a coagulant selected from a group consisting of calcium nitrate, calcium chloride, alky ammonium and a combination thereof, before said step of contacting said mold with said elastomeric composition.

13. The process according to claim 1 further comprising a step of surface-treating said mold after said step of contacting said mold with said elastomeric composition and before said vulcanization reaction is performed.

14. The process according to claim 13 wherein said step of surface-treating said mold is performed by using a surface-treating agent comprising 10˜20% by weight of a synthesized resin, 10˜20% by weight of an acrylic-styrene resin, 1˜10% by weight of a silicon resin and the balance of water.

15. A process for producing a glove having an interpenetrating network structure, comprising steps of:

contacting a mold with an elastomeric composition, wherein said elastomeric composition comprises:

100 weight parts of a latex mixture comprising a base latex and a thermoplastic ethylene-vinylacetate (EVA) copolymer latex, said base latex comprising a styrene-butadiene rubber (SBR) latex and a carboxylated styrene-butadiene rubber (C-SBR) latex and the mixing ratio of said base latex to said EVA copolymer latex being from 99:1 to 5:95;

1˜10 weight parts of an activator, based on the total weight of said latex mixture;

0.1˜2 weight parts of a vulcanization agent, based on the total weight of said latex mixture; and

0.5˜10 weight parts of a vulcanization accelerator, based on the total weight of said latex mixture; and

allowing said elastomeric composition on said mold to perform a vulcanization reaction, thereby forming said glove having said interpenetrating network structure.

16. The process according to claim 15 wherein said elastomeric composition further comprises:

0.5˜3 weight parts of an anti-aging agent, based on the total weight of said latex mixture;

optionally an enforcement agent less than 20 weight parts based on the total weight of said latex mixture;

optionally a filler less than 20 weight parts based on the total weight of said latex mixture; and

optionally additional latices less than 50 weight parts based on the total weight of said latex mixture.