US3779799A - Coated woven textile product and process therefor - Google Patents

Coated woven textile product and process therefor Download PDF

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Publication number
US3779799A
US3779799A US3779799DA US3779799A US 3779799 A US3779799 A US 3779799A US 3779799D A US3779799D A US 3779799DA US 3779799 A US3779799 A US 3779799A
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United States
Prior art keywords
backing
fabric
coating
lubricant
tuft
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Inventor
H Dodds
Kennedy C Trowbridge
D Stout
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WT ACQUISITION Inc
ATK Launch Systems LLC
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Thiokol Corp
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Assigned to WT ACQUISITION, INC. reassignment WT ACQUISITION, INC. ASSIGNMENT OF ASSIGNORS INTEREST. Assignors: WAYN-TEX, INC.
Assigned to BANK OF AMERICA, N.A. reassignment BANK OF AMERICA, N.A. SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: WAYN-TEX INC.
Assigned to WAYN-TEX INC. reassignment WAYN-TEX INC. RELEASE OF SECURITY INTEREST Assignors: BANK AUSTRIA CREDITANSTALT CORPORATE FINANCE, INC.
Assigned to BANK OF AMERICA, N.A. reassignment BANK OF AMERICA, N.A. RELEASE OF SECURITY INTEREST Assignors: WAYN-TEX INC.
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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • DTEXTILES; PAPER
    • D05SEWING; EMBROIDERING; TUFTING
    • D05CEMBROIDERING; TUFTING
    • D05C17/00Embroidered or tufted products; Base fabrics specially adapted for embroidered work; Inserts for producing surface irregularities in embroidered products
    • D05C17/02Tufted products
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23907Pile or nap type surface or component
    • Y10T428/23979Particular backing structure or composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23907Pile or nap type surface or component
    • Y10T428/23986With coating, impregnation, or bond
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23907Pile or nap type surface or component
    • Y10T428/23993Composition of pile or adhesive
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/31931Polyene monomer-containing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/31935Ester, halide or nitrile of addition polymer

Definitions

  • the preferred coating material is a copolymer of ethylene vinyl acetate, and is applied to the backing by any known method including spraying, immersing, brushing or rolling.
  • the present invention relates to improvements in the preparation of tufted products, e.g., carpets or the like, which include a backing, partially or wholly comprised of a woven fabric.
  • the present invention relates to tufted products of the type referred to wherein the woven backing is coated by known methods which renders the finished, tufted product highly resistant to tuft raveling when such tufted product is applied to its end use as a carpet or floor covering.
  • woven backings comprising yarns of synthetic thermoplastic materials such as the polyolefins, polyethylene and polypropylene.
  • These backings of woven polyolefin yarns are, in most instances woven from yarns of substantially ribbon-like character, especially in the warp.
  • the backings, after weaving are fed into a multi-needle tufting machine which sews or otherwise inserts tufts of face yarn, into the backing.
  • the face yarns may be any of the materials above referred to or made from nylon, acrylic fibers or natural fibers.
  • Tufted pile fabrics produced from woven polyolefin backings have exhibited in the past, an undesirable tendency to ravel at a cut edge paralle to the tufting stitching line. This ravelling occurs when a force is applied perpendicular to the stitch line at the cut edge. Since in tufting the stitch line in carpets is most often parallel to the warp yarns of the primary backing fabric into which the face or pile yarn is tufted, the edge row of stitches along a cut tends to pull out sideways as the warp yarns of the backing fabric slide across the fill yarns of the backing.
  • Carpets provided to the trade usually have a rubber latex (adhesive) coating applied to the back of the tufted pile fabric as noted above. While this, by itself, tends to reduce tuft ravelling with woven backings of the type in which this invention is concerned, it, the latex lamination procedure, must be performed properly, or tuft ravelling resistance of the finished carpet will be unacceptable, even for commercial or contract ing into which the face yarn is tufted, since nonwoven backings inherently have excellent resistance to tuft ravelling. Woven backings would likewise be suitable for such end uses in commercial grade carpet if such tuft ravel resistance could be significantly improved.
  • Woven backings have certain advantages over nonwoven, as for example a tufted pile fabric with a nonwoven backing exhibits undesirable greater stretching when tensioned, because its modulus of elasticity is considerably lower than a woven backing carpet, which, as will be seen, is important in later steps of car pet manufacturing.
  • a backing woven from yarns of synthetic, thermoplastic materials wherein the tuft ravelling resistance is significantly improved over prior art backings.
  • Another object of this invention is to provide a woven backing for tufted pile fabrics wherein the backing receives a coating which effectively stabilizes the fabric (i.e., decreases its sleaziness) by bonding the yarns and reduces tuft ravelling of the finished carpet thereby providing an acceptable commercial product.
  • the coating applied is selected from a group of materials, the most preferred one being a co-polymer of ethylene and vinyl acetate.
  • a primary backing for a carpet product is woven from yarns of synthetic plastic.
  • the synthetic plastic is comprised of any of those plastic materials capable of formation into weavable yarns, including, but not limited to, polyethylene, polypropylene ethylene/propylene copolymers, copolymers of other alpha-olefins, polyesters, polyamides, cellulose acetate and polyvinyl chloride.
  • the backing is coated with a polymeric compound which is dried and cured, after which a lubricating material can, if desired, be applied, usually to one side.
  • a lubricating material can, if desired, be applied, usually to one side.
  • the lubricant can be applied before coating, or to the yarns, either the warp or the fill or both, prior to weaving.
  • a still additional alternative is to apply both the coating and the lubricant simultaneously, ei-
  • the amount of lubricant needed will vary according to the lubricant used, the primary backing to be treated and the type of tufting operation. In general it has been found that the specified fabric strength can be obtained by treating the synthetic plastic primary backing material (for example primary backing materials like those disclosed above) prior to tufting with at least so much lubricant that the tufting needles are enabled to pierce the individual yarns in the backing fabric without rupturing or shattering them. Generally from 0.2 to 12 percent, and preferably 0.6 to 8 percent by weight, of the lubricant will be used.
  • the lubricant used can be any lubricating substances that does not react with, have solvent action on, or otherwise materially affect the properties of the synthetic plastic yarns in the primary backing.
  • Suitable materials include, for example mineral oils; ethoxylated higher fatty acids (i.e., fatty acids having eight or more carbon atoms) more commonly known as polyethylene glycol esters, e.g.
  • the lubricant should be a relatively low viscosity liquid either as such or when in aqueous emulsion, so as to provide easy application and spreading.
  • the most especially preferred lubricants are mineral oil. ethoxylated castor oil, and the polyethylene glycol esters, especially polyethylene glycol oleate having an average of oxyethylene (CH CH O-) groups per molecule commercially sold under the tradename Nopcostat 2l52-P. Nopcostat" is a Registered Trade Mark.
  • Another material useful as a lubricant is a mixture of calcium stearate and silicone oil, the latter being present in minor amounts.
  • the thus treated backing now possessing ample strength retention after tufting, is coated before tufting with one of a number of materials, such as the dispersions in water, or other agents or polyethylenes, carboxylated styrene polybutadiene rubbers and acrylic latexes in addition to the ethylene vinyl acetate copolymer, which have been found to survive the impact imparted by the tufting needles.
  • Backing strength is needed also because subsequent operations on the fabric such as dyeing, drying and latexing above referred to tend to weaken the fabric resulting in an unsatisfactory carpet product.
  • a dispersion of polyethylene in water, with a small amount (0.05 percent) of a 2% gel agent, a styrene maleic anhydride polymer and a latex was found to provide a tufted pile fabric of good tuft ravel resistance with little or no loss in tufted fabric strength as compared to an uncoated, lubricated woven polyolefin backing.
  • latexes of carboxylated styrene butadiene rubber have also provided improved carpets when coated on a woven, lubricated or unlubricated backing used to receive tufts of face yarns.
  • Other acrylic latexes applied to the backing after weaving can also perform well in the finished carpeting from the standpoint of improving the characteristics of the backing to prevent or minimize tuft ravelling during the installation of the finished carpet product.
  • ethylene vinyl acetate copolymer one is selected having a softening temperature in the range of [F to 200F, so that when coated onto a lubricated or unlubricated backing, resealing of any ruptured yarn bonds caused by tufting occurs at 230F to 280F, which temperature range will be encountered by the backing in the drying of the carpet product after dyeing and/or latexing.
  • Another advantage obtained is that since there coatings are compatible with practically all presently used latex materials including the final, or finish underside materials, the invention is readily adapted over a broadrange of applications.
  • woven backings when coated according to the invention achieve a high degree of stabilization, by which is meant that objectionable sleaziness is eliminated thereby imparting to the backing better body so that, in tufting operations, its handling characteristics are much improved.
  • inventive backings herein set forth can be readily used in carpets having secondary backings, even when such secondary backings are made from jute, or other natural fibers with no harmful effects. In fact, such carpets will likewise enjoy all of the advantages hereinbefore set forth.
  • EXAMPLE l A woven polypropylene backing fabric having a weave configuration of 22 ends per inch of ribbon yarn in the warp and l 1 ends per inch of substantially round multifilament ends in the fill (Sample A, Table l) was coated on a textile padder and fused dried in a tentering frame at 310F. The coating used was applied by immersion in a bath and picked up through a wringer to squeeze out extra coating. The coating solution was: Microfene FE-530 ethylene vinyl acetate copolymer made by the US Industrial Chemical Co.
  • Tuft ravel resistance determined as follows: pins spaced over 2" inserted into back of tuft pile sample, 4" X 4"; force to pull out measured in lbs. on an Instron tester at 12''/ Min. rate of extension. Three different values are obtained by inserting pins into first tuft row (one row pull), second row (two row pull), and 0.7 inches from edge, which is seventh row for inch gage tufting.
  • Latex application oz. per sq. yd. standard latex coat on back of tufted backing.
  • Foamed back high density foam rubber adhesively attached to tufted, latexed backing.
  • sample D Three Samples D E and F (Table II) of laboratory pllot Scale equlpment After tuftmg compansons scale tufted pile fabrics were made, each with a differtween the control sample and the coated sample were em primary backing
  • the backing of sample D was made to determine the various characteristics in partic- 40 coated with ethylgne vinyl acetate copolymer; sample ul ar, fabric strength, and comparisons were also made
  • E was coated ith a olyethylene dispersion in water with a non-woven fabric (Sample C, Table I): T data with small amounts of a gel agent, latex and a styrene obtained are set forth in Table I herefollowmg. From maleic anhydride polymer.
  • Pi qulte favorably wlth the Ph hehessflry
  • Each fabric was clamped in a restraining frame and wlth hon-wove" fabncother features In which placed in at 320F. hot air oven for drying and fusion of Provemeht was noted are in the important features of the coating.
  • the fabrics were then tufted on a tufting tuft lock and fabric grab tensile Strength in the fill machine.
  • Half of each tufted pile fabric sample was yarn direction. Although lower warp direction grab tested for ravel resistance and the other half was strength is noted, it is of little or no concern since warp mock-dyed before testing.
  • Mock dyeing was accomgrab strength is not critical and is proportional to the plished in a laboratory dye beck, and included boiling reduction in the number of warp ribbons in coated fabfor 2 hours with the fabric sample in a roping condiric as compared to the uncoated fabric. Therefore betion in a typical nylon dispersed dye formulation with cause fewer warp ends per inch are present in the the dye stuffs omitted.
  • a dye beck is an open trough coated fabric than in the control fabric, it is expected containing the dye liquid and the carpet material is a lowering in grab strength would occur. However, it moved in and out of the liquid by a mechanism well should also be noted that the number of ends per inch known to the art.
  • Woven construction was the same for all: warp-30 ends/inch of .050" X 0.002 ribbon; filling- 13 ends/inch of 12 filament yarn 800 denier overall.
  • Mock dyed exposed to all conditions of a disperse dyeing procedure except no dyestuffs were used.
  • Tufting Natural nylon bulked continuous filament, 3600 denier. /16 loop pile, /32 gage, 8% stitches per inch.
  • Table 111 sets forth the results obtained from the data.
  • EXAMPLE IV Sample G of woven polypropylene fabric of a weave configuration of 30 ends per inch of 500 denier ribbon in the warp and 1 1 ends per inch of 1 100 denier ribbon in the fill was spray coated with a latex containing a solids to water ratio of 1 to 3 and air cured in an oven at A fabric prepared in a manner similar to any of those of Example IV was tested to determine tufted grab strength in the fill direction, the most critical strength requirement in the manufacture of carpets. This tudted fabric sample was coated with 0.44 oz./sq. yd. of coating and had a grab strength of 56 lbs. The tufted uncoated control fabric had 67 lbs.
  • the fabric of claim 1 wherein the coating material is carboxylated styrene polybutadiene rubber containing up to 3 percent carboxyl end groups.
  • Lubricant Coated fabric was sprayed with an ethoxylated castor dispersion, on one side, 1.2 percent by
  • a coating can be applied to the polyolefin backing composed of an acrylic latex supplied to the trade by the Union Carbide Corporation and sold under its trademark UCAR Latex No. 891.
  • This latex is a soft, flexible self-cross linking acrylic polymer and provides a coating for the backing which, when used in a tufted product of the character referred to hereinbefore, can enhance its tuft ravelling resistance in a significant way.
  • a woven plastic backing can be prepared which possesses superior tuft ravelling resistance and improved strength retention by applying to the backing a coating consisting of a mixture of any of the lubricating compounds set forth above and any of the coating materials also listed above, care being taken to insure adequate miscibility and compatibility of the mixed compounds with one another.
  • a tuft pile fabric comprised of a primary woven backing of thermo plastic warp and fill yarns, rows of tufts of pile yarn tufted into said backing and a lamination of cured latex for adhesively attaching said tufts to the bottom side thereof for locking said tufts into said cant applied is in the range of from 0.2 to 12 percent by weight based on the weight of said woven fabric.
  • the lubricant is a material selected from the group consisting of mineral oil, ethoxylated high fatty acids, and a mixture of calcium stearate and silicone.
  • a process for producing a tufted pile fabric of improved tuft ravelling resistance which comprises the steps of:
  • the lubricant is a material selected from the group consisting of mineral oil, ethoxylated high fatty acids and a mixture of calcium stearate and silicone.

Abstract

In a primary backing woven from synthetic yarns for tufted fabrics and other products, such as carpet and the like, an enhancement in the carpet and/or tufted fabrics tuft raveling resistance capabilities is obtained when the backing is coated with a polymeric substance which effectively reduces such tuft raveling to an acceptable degree. The preferred coating material is a copolymer of ethylene vinyl acetate, and is applied to the backing by any known method including spraying, immersing, brushing or rolling.

Description

United States Patent [1 Kennedy et al.
[111 3,779,799 1 Dec. 18, 1973 COATED WOVEN TEXTILE PRODUCT AND PROCESS THEREFOR [75] inventors: C. Trowbridge Kennedy; David J.
Stout; Harold E. Dodds, Jr., all of Waynesboro, Va.
[73] Assignee: Thiokol Chemical Corporation,
Bristol, Pa.
22 Filedz Sept.16, 1971 [21] Appl. No.: 181,226
Related US. Application Data -[63] Continuation of Ser. No. 45,938, June 12, 1970,
abandoned.
[52] US. C|...I 117/161 UZ, 117/76 T, 117/90, 11'7/l38.8 A,1l7/161Ul-l,156/72,161/67 [51] Int. Cl B32b 27/06 [58] Field of Search 161/67; 156/72; 117/76T,90, 138.8 A, 161 UH, 161 UZ [56] References Cited UNITED STATES PATENTS 3,293,105 12/1966 Koller 156/72 3,322,607 5/1967 Jung 161/67 3,414,458 12/1968 Lacy 161/67 3,496,055 I 2/1970 Hart, Jr 161/67 3,513,046 5/1970 Westfield.... 161/67 3,535,192 10/1970 Gamble 161/67 3,546,059 12/1970 lsgur et a1. 161/66 3,554,824 1/1971 Callahan 156/72 3,679,469 7/1972 'Moore 117/161 UZ 3,684,600 8/1972 Smedberg 156/72 Primary Examiner-William J. Van Balen Attorney-Thomas W. Brennan [5 7 ABSTRACT In a primary backing woven from synthetic yarns for tufted fabrics and other products, such as carpet and the like, an enhancement in the carpet and/or tufted fabrics tuft raveling resistance capabilities is obtained when the backing is coated with a polymeric substance which effectively reduces such tuft raveling to an acceptable degree. The preferred coating material is a copolymer of ethylene vinyl acetate, and is applied to the backing by any known method including spraying, immersing, brushing or rolling.
19 Claims, No Drawings COATED WOVEN TEXTILE PRODUCT AND PROCESS THEREFOR This is a continuation of application Ser. No. 45,938 filed June 12, 1970 now abandoned.
The present invention relates to improvements in the preparation of tufted products, e.g., carpets or the like, which include a backing, partially or wholly comprised of a woven fabric.
More particularly the present invention relates to tufted products of the type referred to wherein the woven backing is coated by known methods which renders the finished, tufted product highly resistant to tuft raveling when such tufted product is applied to its end use as a carpet or floor covering.
Carpeting or other forms of tufted products have ever increasingly been provided in the last few years with woven backings comprising yarns of synthetic thermoplastic materials such as the polyolefins, polyethylene and polypropylene. These backings of woven polyolefin yarns are, in most instances woven from yarns of substantially ribbon-like character, especially in the warp. The backings, after weaving are fed into a multi-needle tufting machine which sews or otherwise inserts tufts of face yarn, into the backing. The face yarns may be any of the materials above referred to or made from nylon, acrylic fibers or natural fibers. After tufting the tufted fabric thus produced has applied to it a lamination of latex on the bottom, or back side, thereof, to retain the tufts and lock" them in position. Applying the latex is a high temperature operation and on occasion has been found to adversely effect the material of the backing. Also when the finished fabric is used as a rug or carpet, and is cut, as is often necessary, the tuft lines along the cut edge may tend to ravel, especially when the cuts in the carpet are made parallel to the tufting stitch line. It is the usual practice in tufting to tuft the face yarns in such a way that the stitch line is most often parallel to the warp yarns of the primary backing fabric into which the pile yarn is tufted.
Tufted pile fabrics produced from woven polyolefin backings, as noted above, have exhibited in the past, an undesirable tendency to ravel at a cut edge paralle to the tufting stitching line. This ravelling occurs when a force is applied perpendicular to the stitch line at the cut edge. Since in tufting the stitch line in carpets is most often parallel to the warp yarns of the primary backing fabric into which the face or pile yarn is tufted, the edge row of stitches along a cut tends to pull out sideways as the warp yarns of the backing fabric slide across the fill yarns of the backing. Thus when cuts are made in installation of the rug, such as the so-called wall-to-wall application, and these cuts are made parallel to the rows of tufting stitches tuft ravelling is most likely to occur. Seams made after such cuts tend to show wear prematurely especially when the installation, and/or seam is made by workmen who have not yet acquired the greatest of skill. Thus what commonly results is a backing having unacceptable tuft ravel resistance.
Carpets provided to the trade usually have a rubber latex (adhesive) coating applied to the back of the tufted pile fabric as noted above. While this, by itself, tends to reduce tuft ravelling with woven backings of the type in which this invention is concerned, it, the latex lamination procedure, must be performed properly, or tuft ravelling resistance of the finished carpet will be unacceptable, even for commercial or contract ing into which the face yarn is tufted, since nonwoven backings inherently have excellent resistance to tuft ravelling. Woven backings would likewise be suitable for such end uses in commercial grade carpet if such tuft ravel resistance could be significantly improved. Woven backings have certain advantages over nonwoven, as for example a tufted pile fabric with a nonwoven backing exhibits undesirable greater stretching when tensioned, because its modulus of elasticity is considerably lower than a woven backing carpet, which, as will be seen, is important in later steps of car pet manufacturing.
Accordingly, it is an important object of the present invention is provide a backing woven from yarns of synthetic, thermoplastic materials wherein the tuft ravelling resistance is significantly improved over prior art backings. Another object of this invention is to provide a woven backing for tufted pile fabrics wherein the backing receives a coating which effectively stabilizes the fabric (i.e., decreases its sleaziness) by bonding the yarns and reduces tuft ravelling of the finished carpet thereby providing an acceptable commercial product. It is still another object of this invention to provide a woven backing of the character described wherein the coating applied is selected from a group of materials, the most preferred one being a co-polymer of ethylene and vinyl acetate.
It is a still further object of this invention to provide a woven backing for carpet products and the like wherein said backing has applied to at least one side thereof a lubricant to improve it strength retention characteristic after tufting.
According to the invention a primary backing for a carpet product is woven from yarns of synthetic plastic. The synthetic plastic is comprised of any of those plastic materials capable of formation into weavable yarns, including, but not limited to, polyethylene, polypropylene ethylene/propylene copolymers, copolymers of other alpha-olefins, polyesters, polyamides, cellulose acetate and polyvinyl chloride.
The backing is coated with a polymeric compound which is dried and cured, after which a lubricating material can, if desired, be applied, usually to one side. Alternatively the lubricant can be applied before coating, or to the yarns, either the warp or the fill or both, prior to weaving. A still additional alternative is to apply both the coating and the lubricant simultaneously, ei-
ther as a mixture of same, or separately onto the back- The amount of lubricant needed will vary according to the lubricant used, the primary backing to be treated and the type of tufting operation. In general it has been found that the specified fabric strength can be obtained by treating the synthetic plastic primary backing material (for example primary backing materials like those disclosed above) prior to tufting with at least so much lubricant that the tufting needles are enabled to pierce the individual yarns in the backing fabric without rupturing or shattering them. Generally from 0.2 to 12 percent, and preferably 0.6 to 8 percent by weight, of the lubricant will be used.
The lubricant used can be any lubricating substances that does not react with, have solvent action on, or otherwise materially affect the properties of the synthetic plastic yarns in the primary backing. Suitable materials include, for example mineral oils; ethoxylated higher fatty acids (i.e., fatty acids having eight or more carbon atoms) more commonly known as polyethylene glycol esters, e.g. polyethylene glycol linoleate, polyethylene glycol stearate, polyethylene glycol oleate polyethylene glycol laurate, ethoxylated mixtures of the fatty acids in naturally occurring higher fatty acids in various vegetable; e.g., castor oil and ethoxylated castor oil and marine oils; various low molecular weight waxes, both natural and synthetic; and a wide variety of well known, non-ionic surface active agents other than the ethoxylated higher fatty acids previously mentioned, e.g., those sold under the trade names Pluronic, and Carbowax". Pluronic and Carbowax" are Registered Trade Marks. Preferably the lubricant should be a relatively low viscosity liquid either as such or when in aqueous emulsion, so as to provide easy application and spreading. The most especially preferred lubricants (based on experimental results to date) are mineral oil. ethoxylated castor oil, and the polyethylene glycol esters, especially polyethylene glycol oleate having an average of oxyethylene (CH CH O-) groups per molecule commercially sold under the tradename Nopcostat 2l52-P. Nopcostat" is a Registered Trade Mark. Another material useful as a lubricant is a mixture of calcium stearate and silicone oil, the latter being present in minor amounts.
The thus treated backing, now possessing ample strength retention after tufting, is coated before tufting with one of a number of materials, such as the dispersions in water, or other agents or polyethylenes, carboxylated styrene polybutadiene rubbers and acrylic latexes in addition to the ethylene vinyl acetate copolymer, which have been found to survive the impact imparted by the tufting needles. Backing strength is needed also because subsequent operations on the fabric such as dyeing, drying and latexing above referred to tend to weaken the fabric resulting in an unsatisfactory carpet product. For example, a dispersion of polyethylene in water, with a small amount (0.05 percent) of a 2% gel agent, a styrene maleic anhydride polymer and a latex was found to provide a tufted pile fabric of good tuft ravel resistance with little or no loss in tufted fabric strength as compared to an uncoated, lubricated woven polyolefin backing.
Similarly latexes of carboxylated styrene butadiene rubber have also provided improved carpets when coated on a woven, lubricated or unlubricated backing used to receive tufts of face yarns. Other acrylic latexes applied to the backing after weaving can also perform well in the finished carpeting from the standpoint of improving the characteristics of the backing to prevent or minimize tuft ravelling during the installation of the finished carpet product.
However of all of the different materials, solutions, dispersions or emulsions tried it has been found that a dispersion or emulsion of ethylene vinyl acetate copolymer in water with small amounts of surfactant, a gel agent and a latex, gave best results and is the preferred embodiment.
In using the inventive coatings hereinafter to be described in more detail, and in particular the preferred ethylene vinyl acetate copolymer (EVA), one is selected having a softening temperature in the range of [F to 200F, so that when coated onto a lubricated or unlubricated backing, resealing of any ruptured yarn bonds caused by tufting occurs at 230F to 280F, which temperature range will be encountered by the backing in the drying of the carpet product after dyeing and/or latexing.
In addition to the improvement in tuft ravel resistance of the woven backings and carpet products made therewith which are treated with these inventive coatings, other advantages are also obtained. For example. it has been found that the coatings markedly improve carpet tuft lock, i.e., the ability of the face pile or yarn to resist pull out from the latex lamination, hence smaller amounts of latex can be used.
It has also been found that in the so-called patterned or sculptured tufted carpet, an improvement in pattern definition is achieved, thereby enhancing the appearance of the carpet and its commercial value.
Another advantage obtained is that since there coatings are compatible with practically all presently used latex materials including the final, or finish underside materials, the invention is readily adapted over a broadrange of applications.
In still another aspect of the invention, it has been found that woven backings when coated according to the invention, achieve a high degree of stabilization, by which is meant that objectionable sleaziness is eliminated thereby imparting to the backing better body so that, in tufting operations, its handling characteristics are much improved.
Yet another advantage, in particular when coating with EVA, is the increase found in dyeability of the carpet product since EVA takes on almost all commercial dye stuffs readily.
It should also be noted that the inventive backings herein set forth can be readily used in carpets having secondary backings, even when such secondary backings are made from jute, or other natural fibers with no harmful effects. In fact, such carpets will likewise enjoy all of the advantages hereinbefore set forth.
Accordingly the following examples are presented by way of illustration of the invention and its advantages as herein noted and presented. The examples are presented by way of illustrating the several embodiments including the preferred EVA embodiment above indicated, but it is understood that these examples are merely illustrative and not intended to limit the scope of the invention.
EXAMPLE l A woven polypropylene backing fabric having a weave configuration of 22 ends per inch of ribbon yarn in the warp and l 1 ends per inch of substantially round multifilament ends in the fill (Sample A, Table l) was coated on a textile padder and fused dried in a tentering frame at 310F. The coating used was applied by immersion in a bath and picked up through a wringer to squeeze out extra coating. The coating solution was: Microfene FE-530 ethylene vinyl acetate copolymer made by the US Industrial Chemical Co. having a softening temperature of about lF., 58.00 percent; a surfactant sold under the trademark lGEPAL CO-430, 0.43percent; a carboxylated styrene polybutadiene 3,779,799 5 6 rubber latex supplied by the Dow Company as Dow The same three pile fabrics above and as noted in 636 LateX, P a 2 Percent g available to Table I herefollowing were subjected to the remainder th t as CARBOPOL Percent and the of the carpet making procedure; i.e., latexing and the rest water. -34.00 percent. The weight of coating after application of a high density foam backing to the bot- 'y was 09 Ounces P Square y 5 tom of the carpet. Note that on the right hand side of An uncoated control fabric of similar weave configu- Table I, tuft ravel resistance of the woven coated backration as above described except slightly denser Le, 30 ing carpet are shown to be equal, or nearly so, to the ends per inch in the warp and 13 ends per inch in the non-woven backing carpet.
TABLE l.-Coated woven backing versus uncoated versus non-woven backing TABLE l-a.-Tufted pile fabric (for tuft material see Note [3]) TABLE l-b. Finished capret with foamed back (Latexing: Note Tuft ravel resistance Fabric grab strength (4), foam back: Note (5)) (lbs.) (Note (2)) Tuft (lbs) lock m Tuft ruvel resistance tlbs.)
()ne row Two row .7 Inch (gms/ Warp Fill Smuplc ll'iuuu'y bucking pull pull pull lull) direction direction (we row pull l'wo row pull A (Note (ll). Weave: 22X ll; Coated 2.0 8.3 45.0 273 1.12 ll3 25.0 48.5
with 0.9 oz./sq. yd. of EVA. B (Note (l)). Weave: 30 X 13; Un- .9 4.8 173 l6l 78 9.1 18.5
292 2 L. PAW BAC backing.
C Non-woyenTypar.40Z./ 4.2 13.6 108 NA. I58 I32 29.4 41.0
sq. yd., polypropylene.
NOTES:
(1) A and B fabrics woven with polypropylene yarns: 0.050 X 0.002 ribbon warp and 12 filament filling, Le, a multifilament yarn of 800 denier overall. W... (2) Tuft ravel resistance determined as follows: pins spaced over 2" inserted into back of tuft pile sample, 4" X 4"; force to pull out measured in lbs. on an Instron tester at 12''/ Min. rate of extension. Three different values are obtained by inserting pins into first tuft row (one row pull), second row (two row pull), and 0.7 inches from edge, which is seventh row for inch gage tufting. (3) Iuft material z 23 oz. polypropylene bulked continuous filament, 3600 denienj; inch loop pile, {l iuchgagggstuches per inch. (4) Latex application: oz. per sq. yd. standard latex coat on back of tufted backing.
(5) Foamed back: high density foam rubber adhesively attached to tufted, latexed backing.
fill of the same type of yarn was also prepared (Sample I 7 EXAMPLE II B, Table I). Both fabrics, that is coated and uncoated,
were processed through identical carpet operations on Three Samples D E and F (Table II) of laboratory pllot Scale equlpment After tuftmg compansons scale tufted pile fabrics were made, each with a differtween the control sample and the coated sample were em primary backing The backing of sample D was made to determine the various characteristics in partic- 40 coated with ethylgne vinyl acetate copolymer; sample ul ar, fabric strength, and comparisons were also made E was coated ith a olyethylene dispersion in water with a non-woven fabric (Sample C, Table I): T data with small amounts of a gel agent, latex and a styrene obtained are set forth in Table I herefollowmg. From maleic anhydride polymer. and a sample F an the data presented in Table I, a manyfold improvement coated backing used as a control for comparison p in tuft rave] resistance is quite evident. For example, an OSes The backin s were a" woven 0| r l h P g P am py ene wit increase of from 0.9 lbs, to 8.3 lbs. in the force required the Same weave configuration Sample D was hand f P out two rows of tuftmg m the coated P F coated from the same ethylene vinyl acetate copolymer no as compared to the uncoated tufted fabric [5 most Solution of Example L Sample E was coated as noted notable, :slhd the 83 q to p two rows above from a polyethylene dispersion above described. Pi qulte favorably wlth the Ph hehessflry Each fabric was clamped in a restraining frame and wlth hon-wove" fabncother features In which placed in at 320F. hot air oven for drying and fusion of Provemeht was noted are in the important features of the coating. The fabrics were then tufted on a tufting tuft lock and fabric grab tensile Strength in the fill machine. Half of each tufted pile fabric sample was yarn direction. Although lower warp direction grab tested for ravel resistance and the other half was strength is noted, it is of little or no concern since warp mock-dyed before testing. Mock dyeing was accomgrab strength is not critical and is proportional to the plished in a laboratory dye beck, and included boiling reduction in the number of warp ribbons in coated fabfor 2 hours with the fabric sample in a roping condiric as compared to the uncoated fabric. Therefore betion in a typical nylon dispersed dye formulation with cause fewer warp ends per inch are present in the the dye stuffs omitted. A dye beck is an open trough coated fabric than in the control fabric, it is expected containing the dye liquid and the carpet material is a lowering in grab strength would occur. However, it moved in and out of the liquid by a mechanism well should also be noted that the number of ends per inch known to the art. However, in this test, the fabric is in the weave configuration was purposely decreased in subjected to a rather severe mechanical working due to order to compensate for the slight extra cost of coating. the factthat as it moves through the dye beck it is 7 E V A zm d polyethylene coated woven backing versus imcareufiroieiia Zrr'indi dyeing 240F. for 15 minutes. The latex used was a carboxylated styrene butadiene rubber containing up to 3 percent carboxyl end groups with no filler. This sample fabric was tufted twelve inches wide with loop pile consisting of 3700 denier bulked continuous filament nylon on a 5/32 inch gauge tufting machine at 8 stitches per inch.
Undyed Mock dyed (Note (3)) Bare Tuft ravel resist. (lbs) Bare Tuft ravel resist. (lbs.) .7 inch .7 inch pull One row .7 Inch pull One row .7 Inch Sample Primary backing (Note (2)) pull pull (Note (2)) pull pull D Weave: 30 X 13 Coated, with .8 oz./sq. 46 4.4 16.3 46 12.9 42.8
yd. EVA. E (Note (1)) Weavez30 13 Coated with 1.0oz./sq. 22 2.2 10.8 .8 1.0 6.0
yd. with polyethylene. F Weave: 30 X 13 uncoated .3 1.3 .7 .4 3.6
NOTES:
(1) Woven construction was the same for all: warp-30 ends/inch of .050" X 0.002 ribbon; filling- 13 ends/inch of 12 filament yarn 800 denier overall.
' (Ti Bare ravel resistance for .7 inch pull was performed same way as tuft ravel resistance (Table 1) except on bare. untufted backing.
(3) Mock dyed: exposed to all conditions of a disperse dyeing procedure except no dyestuffs were used. Formula included surfactants and dyeing aids; pH 9. Rope in 12" wide laboratory dye beck: 2 hours at boil (205-2 10 F.). (4) Tufting: Natural nylon bulked continuous filament, 3600 denier. /16 loop pile, /32 gage, 8% stitches per inch.
EXAMPLE III In an experiment to demonstrate that re-fusion of the coating on a backing in a tufted pile fabric can improve the tuft ravel resistance of the finished carpet, a portion of each of samples A and B tufted pile fabrics of Example I were mock-dyed in a pilot dye beck with the pile fabrics in a roped condition for one hour at the boiling point in a typical nylon dispersed dye formulation (dye A portion, Sample H, of Sample G was mock-dyed for two hours at the boiling point in a dye basket containing 2,000 ml. of water, 10 ml. of non-ionic polyethylene oxide surfactant and 5 ml. of glacial acetic acid.
The sample was rinsed in cold water and air dryed. The results of physical testing of the above samples along with uncoated fabric, Samples I and J, treated in a like manner are set forth on Table IV.
TABLE IV Tuft ravel resistance (lbs.)
One row Two row .7 Inch Tuft lock Description pull pull pull (grams/tuft) 0.89 oz/sq. yd. SBR* coating 4.0 17.0 36.0 155 This sample is mock-dyed sample G 9.4 22.0 45.0 400 No coating 0.7 1.8 8.0 138 .1 This sample is mock-dyed sample I .6 9.4 28.0 278 SBR -a 3 percent carboxylated styrene butadiene rubber.
stuffs omitted). At the end of 1 hour half of each sam- EXAMPLE V ple was dryed through a pilot hot air tenter at 260F.
air temperature. Tuft ravel resistance was then compared with samples air dryed at room temperature.
Table 111 sets forth the results obtained from the data.
TABLE III EVA COATED WOVEN BACKING Re-fusion aids in Tuft Ravel Resistance 260F. Air Tenter Dried Room Temp. Air Drying Tuft Ravel Resist. lb.
Primary Tuft Ravel Resist. lb.
Backing One Row Two Row One RowTwo Row Sample Pull Pull Pull Pull A 1.7 8.0 3.9 1 1.8 B 1 1.6 .l 1.8
EXAMPLE IV Sample G of woven polypropylene fabric of a weave configuration of 30 ends per inch of 500 denier ribbon in the warp and 1 1 ends per inch of 1 100 denier ribbon in the fill was spray coated with a latex containing a solids to water ratio of 1 to 3 and air cured in an oven at A fabric prepared in a manner similar to any of those of Example IV was tested to determine tufted grab strength in the fill direction, the most critical strength requirement in the manufacture of carpets. This tudted fabric sample was coated with 0.44 oz./sq. yd. of coating and had a grab strength of 56 lbs. The tufted uncoated control fabric had 67 lbs.
Since it is usually found that this test normally has a variation of plus or minus 6 lbs., it is therefore considered that the difierence between the coated and uncoated samples is not significant.
EXAMPLE VI In an experiment to determine the effects of lubrication on a coated backing two fabric Samples, K and L, were prepared each having a weave configuration of 30 ends per inch of 500 denier polypropylene ribbons in the warp and 11 ends per inch of 1100 denier ribbon in the fill. One, Sample K, was spray coated with an EVA co-polymer having a solids to water ratio of 1 to 4. The coated fabric was dried and cured in air at 270F in a tenter for 2 minutes. The coating weight was 0.5 oz. per sq. yd. Sample K was not lubricated after coating. After the coating was dried and cured the fabric was tufted with bulked continuous filament nylon, 2400 denier, 3/16 inch loop pile, 1/10 inch gauge at stitches per inch. The tufted fabric sample was tested in accordance with the procedure set forth in Note (2) of Table l. Sample L was coated the same as Sample K and then sprayed on one side with an ethoxylated castor oil supplied by the Sylvan Chemicals Company and marketed under the trade mark SYN-LUBE 107. After coating and lubricating, Sample L was tufted and tested in the same manner as Sample K. The significant data and the results obtained from the testing of these two sample fabrics is given in Table V herefollowing. The lower values for grab strength as compared with Sample A, Table I is accounted for because of the difference in coating weight, i.e., 0.9 oz. per sq. yd. (Sample A) vs. 0.5 oz. per sq. (Samples K and U 2. The fabric of claim 1 wherein the coating material is ethylene vinyl acetate copolymer.
3. The fabric of claim 1 wherein the coating material is carboxylated styrene polybutadiene rubber containing up to 3 percent carboxyl end groups.
4. The fabric of claim 1 wherein a lubricant is applied to at least one side of the backing.
5. The fabric gfclaim 4 wherein the amount of lubri- TABLE V.Coated woven backing versus lubricated coated woven backing Fabric grab Tuft ravel resistance strength (lbs.) (Note (2)) (lbs) Fill Two row .7 Inch Tuft lock Sample Primary backing direction pull pull (gmsltuft) K (Note (1)) Weave: X l l; coated with 0.5 02.] 39 4.8 21.8 106 sq. yd. of EVA; No lubricant. l.. (Note (1)) Weave: 30 X 11; coated with 0.5 oz./ 78 3.2 l8.l 130 sq. yd. of EVA; Lubricated (Note NOTES:
(1) Fabrics woven with polypropylene yarns, 500 denier ribbons in warp and 1100 denier ribbons in fill.
(2) See Table 1, Note 2 for test description.
(3) Lubricant: Coated fabric was sprayed with an ethoxylated castor dispersion, on one side, 1.2 percent by In another embodiment of the invention a coating can be applied to the polyolefin backing composed of an acrylic latex supplied to the trade by the Union Carbide Corporation and sold under its trademark UCAR Latex No. 891. This latex is a soft, flexible self-cross linking acrylic polymer and provides a coating for the backing which, when used in a tufted product of the character referred to hereinbefore, can enhance its tuft ravelling resistance in a significant way.
in still another embodiment of the invention, a woven plastic backing can be prepared which possesses superior tuft ravelling resistance and improved strength retention by applying to the backing a coating consisting of a mixture of any of the lubricating compounds set forth above and any of the coating materials also listed above, care being taken to insure adequate miscibility and compatibility of the mixed compounds with one another.
Thus by means of this invention is is possible to provide a woven polyolefin backing for tufted products wherein tuft ravelling resistance is substantially improved, and when out as by even unskilled carpet installers results in a highly competitive and commercially acceptable product from that standpoint.
Accordingly, what has been invented and described herein and for which Letters Patent is desired, is understood to be capable of modifications and variations without departing from the scope and spirit thereof except as defined in the hereinafter subtended claims.
What is claimed is:
1. in a tuft pile fabric comprised of a primary woven backing of thermo plastic warp and fill yarns, rows of tufts of pile yarn tufted into said backing and a lamination of cured latex for adhesively attaching said tufts to the bottom side thereof for locking said tufts into said cant applied is in the range of from 0.2 to 12 percent by weight based on the weight of said woven fabric.
6. The fabric of claim 4 wherein the lubricant is a material selected from the group consisting of mineral oil, ethoxylated high fatty acids, and a mixture of calcium stearate and silicone.
7. The fabric of claim 4 wherein the lubricant is an ethoxylated castor oil.
8. A process for producing a tufted pile fabric of improved tuft ravelling resistance which comprises the steps of:
1. selecting a primary backing woven of thermoplastic warp and fill yarns;
2. coating said backing in an amount of from about 0.5 ounces per square yard to about 0.9 ounces per square yard with a material selected from the group consisting of ethylene vinyl acetate co-polymer, polyethylene, carboxylated styrene abutadiene rubber and an acrylic latex;
3. tufting rows of pile yarn into said backing; and,
4. applying a lamination of latex rubber to the underside of said coated backing for locking said tufts thereinto.
12 percent by weight based on the weight of said woven fabric.
18. The process of claim 16 wherein the lubricant is a material selected from the group consisting of mineral oil, ethoxylated high fatty acids and a mixture of calcium stearate and silicone.
19. The process of claim 16 wherein the lubricant is an ethoxylated castor oil.

Claims (21)

  1. 2. coating said backing in an amount of from about 0.5 ounces per square yard to about 0.9 ounces per square yard with a material selected from the group consisting of ethylene vinyl acetate co-polymer, polyethylene, carboxylated styrene abutadiene rubber and an acrylic latex;
  2. 2. The fabric of claim 1 wherein the coating material is ethylene vinyl acetate copolymer.
  3. 3. The fabric of claim 1 wherein the coating material is carboxylated styrene polybutadiene rubber containing up to 3 percent carboxyl end groups.
  4. 3. tufting rows of pile yarn into said backing; and,
  5. 4. applying a lamination of latex rubber to the underside of said coated backing for locking said tufts thereinto.
  6. 4. The fabric of claim 1 wherein a lubricant is applied to at least one side of the backing.
  7. 5. The fabric of claim 4 wherein the amount of lubricant applied is in the range of from 0.2 to 12 percent by weight based on the weight of said woven fabric.
  8. 6. The fabric of claim 4 wherein the lubricant is a material selected from the group consisting of mineral oil, ethoxylated high fatty acids, and a mixture of calCium stearate and silicone.
  9. 7. The fabric of claim 4 wherein the lubricant is an ethoxylated castor oil.
  10. 8. A process for producing a tufted pile fabric of improved tuft ravelling resistance which comprises the steps of:
  11. 9. The process of claim 8 wherein the coating material is ethylene vinyl acetate copolymer.
  12. 10. The process of claim 8 wherein the coating material is carboxylated styrene butadiene rubber containing up to 3 percent carboxyl end groups.
  13. 11. The process of claim 8 wherein the coating material is applied to the backing prior to tufting of said pile thereinto.
  14. 12. The process of claim 8 wherein said coating is applied to said backing by spraying.
  15. 13. The process of claim 8 wherein said coating is applied to said backing by brushing.
  16. 14. The process of claim 8 wherein the coating is applied to the yarn prior to weaving by a roller.
  17. 15. The process of claim 8 wherein the coating is applied to said backing by immersing said backing in said coating material.
  18. 16. The process of claim 8 further including the step of applying to at least one side of the backing a lubricant.
  19. 17. The process of claim 16 wherein the amount of lubricant applied is in the range of from 0.2 percent to 12 percent by weight based on the weight of said woven fabric.
  20. 18. The process of claim 16 wherein the lubricant is a material selected from the group consisting of mineral oil, ethoxylated high fatty acids and a mixture of calcium stearate and silicone.
  21. 19. The process of claim 16 wherein the lubricant is an ethoxylated castor oil.
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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3887738A (en) * 1971-03-04 1975-06-03 Ashland Oil Inc Carpet backsized with hot melt adhesive and method
US4035533A (en) * 1976-06-01 1977-07-12 Champion International Corporation Tufted carpet with meltable-film primary-backing component
US4239563A (en) * 1971-11-02 1980-12-16 Air Products And Chemicals, Inc. Process for the use of vinyl acetate-ethylene copolymer emulsions to adhere fibers to carpet backing
US4246309A (en) * 1977-04-22 1981-01-20 Rhone-Poulenc Industries Tufted floor covering having binder with less than 0.5% water soluble compounds
US5026765A (en) * 1989-12-15 1991-06-25 National Starch And Chemical Investment Holding Corporation Emulsion binder for carpet and carpet tiles
US5925434A (en) * 1997-06-12 1999-07-20 Bp Amoco Corporation Tuftable backing and carpet construction
WO2000061853A1 (en) * 1999-04-12 2000-10-19 Tennessee Valley Patent Development Company Carpet and carpet making methods
US20040214940A1 (en) * 2003-04-25 2004-10-28 Rong-Shing Li Elastomeric composition and process for producing glove having interpenetrating network structure
EP1482009A1 (en) * 2003-05-30 2004-12-01 Posaidon Enterprise Co., Ltd. Elastromeric composition and process for producing glove having interpenetrating network structure
US20040258874A1 (en) * 2002-03-07 2004-12-23 Peter Desai Surface coverings containing styrene polymers
US20070270064A1 (en) * 2006-05-22 2007-11-22 Aseere Lester M Carpet primary backing having enhanced tufting and tuft securing characteristics
US7338698B1 (en) 1997-02-28 2008-03-04 Columbia Insurance Company Homogeneously branched ethylene polymer carpet, carpet backing and method for making same
US8283017B2 (en) 1997-02-28 2012-10-09 Columbia Insurance Company Carpet, carpet backings and methods
WO2015061399A1 (en) 2013-10-24 2015-04-30 Wacker Chemical Corporation Carpet product and process for the manufacturing of a carpet product
DE102014214472A1 (en) 2014-07-24 2016-01-28 Wacker Chemie Ag Aqueous, polyvinyl alcohol-stabilized vinyl acetate-ethylene copolymer dispersion with high filler compatibility for carpet coating compositions
WO2016092047A1 (en) 2014-12-12 2016-06-16 Wacker Chemie Ag Water-redispersible polymer powders for carpet coating compositions
US9382341B2 (en) 2012-09-27 2016-07-05 Wacker Chemical Corporation Carpet coating composition
DE102015206954A1 (en) 2015-04-17 2016-10-20 Wacker Chemie Ag Carpet coating compositions

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3293105A (en) * 1963-01-22 1966-12-20 Du Pont Pile article
US3322607A (en) * 1964-08-17 1967-05-30 Du Pont Lubricated polypropylene polyethylene self-bonded nonwoven carpet backing
US3414458A (en) * 1965-12-16 1968-12-03 Du Pont Non-cracking tufted carpet with nonwoven secondary backing and method of making same
US3496055A (en) * 1967-10-31 1970-02-17 Colonial Chem Corp Foam-backed carpet
US3513046A (en) * 1966-08-09 1970-05-19 Polymer Corp Manufacture of double-backed tufted carpets
US3535192A (en) * 1968-04-15 1970-10-20 Hale Mfg Co Carpet and method of making same
US3546059A (en) * 1964-05-04 1970-12-08 Grace W R & Co Composite fibrous article bonded with novel copolymer compositions and method of making same
US3554824A (en) * 1966-10-21 1971-01-12 Textile Rubber & Chem Co Method of making a tufted fabric
US3679469A (en) * 1970-02-24 1972-07-25 Dow Chemical Co Carpet backsizing with latexes of acidic olefin copolymers
US3684600A (en) * 1970-04-10 1972-08-15 Du Pont Hot melt carpet backsizing process

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3293105A (en) * 1963-01-22 1966-12-20 Du Pont Pile article
US3546059A (en) * 1964-05-04 1970-12-08 Grace W R & Co Composite fibrous article bonded with novel copolymer compositions and method of making same
US3322607A (en) * 1964-08-17 1967-05-30 Du Pont Lubricated polypropylene polyethylene self-bonded nonwoven carpet backing
US3414458A (en) * 1965-12-16 1968-12-03 Du Pont Non-cracking tufted carpet with nonwoven secondary backing and method of making same
US3513046A (en) * 1966-08-09 1970-05-19 Polymer Corp Manufacture of double-backed tufted carpets
US3554824A (en) * 1966-10-21 1971-01-12 Textile Rubber & Chem Co Method of making a tufted fabric
US3496055A (en) * 1967-10-31 1970-02-17 Colonial Chem Corp Foam-backed carpet
US3535192A (en) * 1968-04-15 1970-10-20 Hale Mfg Co Carpet and method of making same
US3679469A (en) * 1970-02-24 1972-07-25 Dow Chemical Co Carpet backsizing with latexes of acidic olefin copolymers
US3684600A (en) * 1970-04-10 1972-08-15 Du Pont Hot melt carpet backsizing process

Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3887738A (en) * 1971-03-04 1975-06-03 Ashland Oil Inc Carpet backsized with hot melt adhesive and method
US4239563A (en) * 1971-11-02 1980-12-16 Air Products And Chemicals, Inc. Process for the use of vinyl acetate-ethylene copolymer emulsions to adhere fibers to carpet backing
US4035533A (en) * 1976-06-01 1977-07-12 Champion International Corporation Tufted carpet with meltable-film primary-backing component
US4246309A (en) * 1977-04-22 1981-01-20 Rhone-Poulenc Industries Tufted floor covering having binder with less than 0.5% water soluble compounds
US4298637A (en) * 1977-04-22 1981-11-03 Rhone-Poulenc Industries Method of applying a binder having less than 0.5% water soluble compounds to tufted floor coverings
US5026765A (en) * 1989-12-15 1991-06-25 National Starch And Chemical Investment Holding Corporation Emulsion binder for carpet and carpet tiles
US8496769B2 (en) 1997-02-28 2013-07-30 Columbia Insurance Company Carpet, carpet backings and methods
US9376769B2 (en) 1997-02-28 2016-06-28 Columbia Insurance Company Homogeneously branched ethylene polymer carpet backsizing compositions
US7338698B1 (en) 1997-02-28 2008-03-04 Columbia Insurance Company Homogeneously branched ethylene polymer carpet, carpet backing and method for making same
US8283017B2 (en) 1997-02-28 2012-10-09 Columbia Insurance Company Carpet, carpet backings and methods
US7910194B2 (en) 1997-02-28 2011-03-22 Columbia Insurance Company Homogenously branched ethylene polymer carpet backsizing compositions
US7357971B2 (en) 1997-02-28 2008-04-15 Columbia Insurance Company Homogenously branched ethylene polymer carpet backsizing compositions
US5925434A (en) * 1997-06-12 1999-07-20 Bp Amoco Corporation Tuftable backing and carpet construction
WO2000061853A1 (en) * 1999-04-12 2000-10-19 Tennessee Valley Patent Development Company Carpet and carpet making methods
US20040258874A1 (en) * 2002-03-07 2004-12-23 Peter Desai Surface coverings containing styrene polymers
US20060052501A1 (en) * 2003-04-25 2006-03-09 Rong-Shing Li Process for producing glove having interpenetrating network structure
US7001941B2 (en) 2003-04-25 2006-02-21 Posaidon Enterprise Co., Ltd. Elastomeric composition and process for producing glove having interpenetrating network structure
US20040214940A1 (en) * 2003-04-25 2004-10-28 Rong-Shing Li Elastomeric composition and process for producing glove having interpenetrating network structure
EP1482009A1 (en) * 2003-05-30 2004-12-01 Posaidon Enterprise Co., Ltd. Elastromeric composition and process for producing glove having interpenetrating network structure
US20070270064A1 (en) * 2006-05-22 2007-11-22 Aseere Lester M Carpet primary backing having enhanced tufting and tuft securing characteristics
US9382341B2 (en) 2012-09-27 2016-07-05 Wacker Chemical Corporation Carpet coating composition
WO2015061399A1 (en) 2013-10-24 2015-04-30 Wacker Chemical Corporation Carpet product and process for the manufacturing of a carpet product
DE102014214472A1 (en) 2014-07-24 2016-01-28 Wacker Chemie Ag Aqueous, polyvinyl alcohol-stabilized vinyl acetate-ethylene copolymer dispersion with high filler compatibility for carpet coating compositions
WO2016012209A1 (en) 2014-07-24 2016-01-28 Wacker Chemie Ag Aqueous, polyvinyl alcohol stabilized vinyl acetate-ethylene-copolymer dispersion having high filler compatibility for carpet coating compositions
US10457827B2 (en) 2014-07-24 2019-10-29 Wacker Chemie Ag Aqueous, polyvinyl alcohol stabilized vinyl acetate-ethylene-copolymer dispersion having high filler compatibility for carpet coating compositions
WO2016092047A1 (en) 2014-12-12 2016-06-16 Wacker Chemie Ag Water-redispersible polymer powders for carpet coating compositions
US10227726B2 (en) 2014-12-12 2019-03-12 Wacker Chemie Ag Water-redispersible polymer powders for carpet coating compositions
DE102014225773A1 (en) 2014-12-12 2016-06-16 Wacker Chemie Ag Polymers for carpet coating compositions
DE102015206954A1 (en) 2015-04-17 2016-10-20 Wacker Chemie Ag Carpet coating compositions
WO2016166037A1 (en) 2015-04-17 2016-10-20 Wacker Chemie Ag Carpet coating compositions
US10480122B2 (en) 2015-04-17 2019-11-19 Wacker Chemie Ag Carpet coating compositions

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