US20050276941A1 - Polymer-based molded article with minimal flame spread and smoke properties - Google Patents

Polymer-based molded article with minimal flame spread and smoke properties Download PDF

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Publication number
US20050276941A1
US20050276941A1 US10/867,261 US86726104A US2005276941A1 US 20050276941 A1 US20050276941 A1 US 20050276941A1 US 86726104 A US86726104 A US 86726104A US 2005276941 A1 US2005276941 A1 US 2005276941A1
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US
United States
Prior art keywords
layer
molded article
recited
intermediate layer
molded
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/867,261
Inventor
Scott Kapelanski
Stanislav Zibrat
Alfredo Li Preti
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Masco Corp
Original Assignee
Masco Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Masco Corp filed Critical Masco Corp
Priority to US10/867,261 priority Critical patent/US20050276941A1/en
Assigned to MIROLIN INDUSTRIES CORPORATION reassignment MIROLIN INDUSTRIES CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KAPELANSKI, SCOTT, PRETI, ALFREDO LI, ZIBRAT, STANISLAV
Assigned to MASCO CORPORATION reassignment MASCO CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MIROLIN INDUSTRIES CORPORATION
Priority to CA002508155A priority patent/CA2508155A1/en
Publication of US20050276941A1 publication Critical patent/US20050276941A1/en
Abandoned legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47KSANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
    • A47K3/00Baths; Douches; Appurtenances therefor
    • A47K3/28Showers or bathing douches
    • A47K3/30Screens or collapsible cabinets for showers or baths
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]

Definitions

  • the present invention relates to molded components and more particularly to polymer-based bath fixtures which minimize flame spread and smoke when subjected to combustion.
  • Tub surrounds are positioned within a recess built around a bathtub or shower.
  • Conventional modular tub/shower units often include a tub portion at the bottom and two or more wall portions. The whole structure is inserted into the wall recess to form a waterproof surround.
  • the fully enclosed waterproof structure is highly advantageous in that it prevents the escape of water into the wall cavity despite the shower spraying water onto the surrounding walls.
  • Tub and shower surrounds and other such polymer-based bath fixtures are typically molded through an open mold fiberglass reinforced plastic molding system.
  • spray stations perform particular spraying operation to produce the molded component.
  • Such spray operations typically include an acrylic such as a gelcoat and resin/catalyst/chopped fiberglass fixture application.
  • the chopped fiberglass provides a support structure for the component which supports the gelcoat aesthetic surface.
  • polystyrene-based components may not meet certain requirements for flame spread and smoke according to particularly strict building codes.
  • the polymeric materials are based on benzene ring chemistry, which may generate smoke and support combustion. Because additives that reduce flame spread tend to increase smoke generation and vice-versa, the use of chemical additives to polymer-based components to control these two parameters has had limited success.
  • the molded article according to the present invention includes at least three layers: a cosmetic surface layer, an intermediate layer and a backing layer. Each layer is sprayed, in order, onto an open mold to build up the composite material molded article.
  • the intermediate layer is an energy absorbing layer between the surface layer and the backing layer. The construction at least partially confines burning to the surface layer where flame spread is controlled and smoke is minimized by the composition of the intermediate layer.
  • the present invention therefore provides a polymer-based component, which minimizes flame spread and smoke.
  • FIG. 1 is a general perspective view of a molded article according to the present invention.
  • FIG. 2 is a sectional view a portion of the molded article.
  • FIG. 1 illustrates a general perspective view of a polymer based molded article 20 .
  • the molded article 20 is preferably a tub and shower surround, which is formed of multiple portions.
  • a tub portion 22 receives wall portions 24 and 26 to form the molded article 20 .
  • any number of molded articles of any number of portions such as shower bases, sinks, or other plastic faced components, will benefit from the present invention.
  • such components are relatively large bathroom-related fixtures.
  • Each portion 22 , 24 , 26 preferably includes at least three layers: a cosmetic surface layer 28 , an intermediate layer 30 , and a backing layer 32 .
  • each layer 28 , 30 , 32 is sprayed, in order, onto an open mold to build up the composite material component as generally understood, however, other manufacturing techniques will also benefit from the present invention.
  • the cosmetic surface layer 28 is preferably a layer of resin referred herein as “gelcoat”.
  • the gelcoat is a hardenable polyester resin that becomes the visible surface of the finished product.
  • the backing layer 32 is preferably a sprayed layer of chopped fiberglass known as “chop.” Other chops such as a resin/catalyst/chopped fiberglass mixtures will also benefit from the present invention.
  • the intermediate layer 30 is an energy absorbing layer between the cosmetic surface layer 28 and the backing layer 32 .
  • the intermediate layer 30 absorbs energy in the form of heat from behind the exposed cosmetic surface layer 28 to delay ignition of the cosmetic surface layer 28 .
  • the composition of the intermediate layer 30 reduces the overall generation of smoke.
  • the intermediate layer 30 is preferably an aliphatic resin with flame inhibitors such as aluminum trihydrate and other inorganic, non-flammable materials.
  • the construction at least partially confines burning to the cosmetic surface layer 28 , where flame spread is controlled, and smoke is minimized by the composition of the intermediate layer 30 .
  • Involvement of the backing layer 32 is minimized as the fuel from the cosmetic surface layer 28 , which commonly provides ignition of the backing layer 32 , is segregated therefrom by the intermediate layer 30 .

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  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Epidemiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Bathtubs, Showers, And Their Attachments (AREA)
  • Laminated Bodies (AREA)

Abstract

A molded article includes at least three layers: a cosmetic surface layer, an intermediate layer and a backing layer. The intermediate layer is an energy absorbing layer between the surface layer and the backing layer which at least partially confines burning to the surface layer, where flame spread is controlled, and smoke is minimized by the composition of the intermediate layer.

Description

    BACKGROUND OF THE INVENTION
  • The present invention relates to molded components and more particularly to polymer-based bath fixtures which minimize flame spread and smoke when subjected to combustion.
  • Tub surrounds are positioned within a recess built around a bathtub or shower. Conventional modular tub/shower units often include a tub portion at the bottom and two or more wall portions. The whole structure is inserted into the wall recess to form a waterproof surround. The fully enclosed waterproof structure is highly advantageous in that it prevents the escape of water into the wall cavity despite the shower spraying water onto the surrounding walls.
  • Tub and shower surrounds and other such polymer-based bath fixtures are typically molded through an open mold fiberglass reinforced plastic molding system. As the open molds transit the assembly line, spray stations perform particular spraying operation to produce the molded component. Such spray operations typically include an acrylic such as a gelcoat and resin/catalyst/chopped fiberglass fixture application. The chopped fiberglass provides a support structure for the component which supports the gelcoat aesthetic surface.
  • Although producing a high quality molded component, such polymer-based components may not meet certain requirements for flame spread and smoke according to particularly strict building codes. The polymeric materials are based on benzene ring chemistry, which may generate smoke and support combustion. Because additives that reduce flame spread tend to increase smoke generation and vice-versa, the use of chemical additives to polymer-based components to control these two parameters has had limited success.
  • Accordingly, it is desirable to provide a polymer-based component, which minimizes flame spread and smoke.
  • SUMMARY OF THE INVENTION
  • The molded article according to the present invention includes at least three layers: a cosmetic surface layer, an intermediate layer and a backing layer. Each layer is sprayed, in order, onto an open mold to build up the composite material molded article. The intermediate layer is an energy absorbing layer between the surface layer and the backing layer. The construction at least partially confines burning to the surface layer where flame spread is controlled and smoke is minimized by the composition of the intermediate layer.
  • The present invention therefore provides a polymer-based component, which minimizes flame spread and smoke.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The various features and advantages of this invention will become apparent to those skilled in the art from the following detailed description of the currently preferred embodiment. The drawings that accompany the detailed description can be briefly described as follows:
  • FIG. 1 is a general perspective view of a molded article according to the present invention; and
  • FIG. 2 is a sectional view a portion of the molded article.
  • DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
  • FIG. 1 illustrates a general perspective view of a polymer based molded article 20. The molded article 20 is preferably a tub and shower surround, which is formed of multiple portions. Generally, a tub portion 22 receives wall portions 24 and 26 to form the molded article 20. It should be understood that any number of molded articles of any number of portions, such as shower bases, sinks, or other plastic faced components, will benefit from the present invention. Preferably, such components are relatively large bathroom-related fixtures.
  • Referring to FIG. 2, a sectional view through one of the portions 22, 24, 26 is illustrated. It should be understood that the sectional view may be taken anywhere within the portions 22, 24, 26. Each portion 22, 24, 26 preferably includes at least three layers: a cosmetic surface layer 28, an intermediate layer 30, and a backing layer 32.
  • Typically, each layer 28, 30, 32 is sprayed, in order, onto an open mold to build up the composite material component as generally understood, however, other manufacturing techniques will also benefit from the present invention.
  • The cosmetic surface layer 28 is preferably a layer of resin referred herein as “gelcoat”. The gelcoat is a hardenable polyester resin that becomes the visible surface of the finished product.
  • The backing layer 32 is preferably a sprayed layer of chopped fiberglass known as “chop.” Other chops such as a resin/catalyst/chopped fiberglass mixtures will also benefit from the present invention.
  • The intermediate layer 30 is an energy absorbing layer between the cosmetic surface layer 28 and the backing layer 32. The intermediate layer 30 absorbs energy in the form of heat from behind the exposed cosmetic surface layer 28 to delay ignition of the cosmetic surface layer 28. Furthermore, the composition of the intermediate layer 30 reduces the overall generation of smoke. The intermediate layer 30 is preferably an aliphatic resin with flame inhibitors such as aluminum trihydrate and other inorganic, non-flammable materials. The construction at least partially confines burning to the cosmetic surface layer 28, where flame spread is controlled, and smoke is minimized by the composition of the intermediate layer 30. Involvement of the backing layer 32 is minimized as the fuel from the cosmetic surface layer 28, which commonly provides ignition of the backing layer 32, is segregated therefrom by the intermediate layer 30.
  • Although particular step sequences are shown, described, and claimed, it should be understood that steps may be performed in any order, separated or combined, unless otherwise indicated and will still benefit from the present invention.
  • The foregoing description is exemplary rather than defined by the limitations within. Many modifications and variations of the present invention are possible in light of the above teachings. The preferred embodiments of this invention have been disclosed, however, one of ordinary skill in the art would recognize that certain modifications would come within the scope of this invention. It is, therefore, to be understood that within the scope of the appended claims, the invention may be practiced otherwise than as specifically described. For that reason the following claims should be studied to determine the true scope and content of this invention.

Claims (12)

1. A molded article comprising:
a cosmetic surface layer;
a backing layer; and
an energy absorbing intermediate layer between said cosmetic surface layer and said backing layer.
2. The molded article as recited in claim 1, wherein said intermediate layer comprises an aliphatic resin.
3. The molded article as recited in claim 2, wherein said intermediate layer comprises a flame inhibitor.
4. The molded article as recited in claim 3, wherein said flame inhibitor comprises aluminum trihydrate.
5. The molded article as recited in claim 1, wherein said cosmetic surface layer comprises an acrylic.
6. The molded article as recited in claim 1, wherein said backing layer comprises a chopped fiberglass.
7. A molded bathroom fixture comprising:
a cosmetic surface layer;
a backing layer; and
an energy absorbing intermediate layer between said cosmetic surface layer and said backing layer.
8. The molded bathroom fixture as recited in claim 7, wherein said intermediate layer comprises an aliphatic resin.
9. The molded bathroom fixture as recited in claim 8, wherein said intermediate layer comprises a flame inhibitor.
10. The molded bathroom fixture as recited in claim 9, wherein said flame inhibitor comprises aluminum trihydrate.
11. The molded bathroom fixture as recited in claim 7, wherein said cosmetic surface layer, said backing layer, and said energy absorbing intermediate layer form a wall of a shower surround portion.
12. The molded bathroom fixture as recited in claim 7, wherein said cosmetic surface layer, said backing layer, and said energy absorbing intermediate layer form a wall of a tub surround portion.
US10/867,261 2004-06-14 2004-06-14 Polymer-based molded article with minimal flame spread and smoke properties Abandoned US20050276941A1 (en)

Priority Applications (2)

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US10/867,261 US20050276941A1 (en) 2004-06-14 2004-06-14 Polymer-based molded article with minimal flame spread and smoke properties
CA002508155A CA2508155A1 (en) 2004-06-14 2005-05-24 Polymer-based molded article with minimal flame spread and smoke properties

Applications Claiming Priority (1)

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US10/867,261 US20050276941A1 (en) 2004-06-14 2004-06-14 Polymer-based molded article with minimal flame spread and smoke properties

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012067695A1 (en) * 2010-11-15 2012-05-24 Masco Bath Corporation Method for bathing vessel having wood-containing base board
US20130256949A1 (en) * 2012-03-30 2013-10-03 Raymond Doss Mold for Creating Negative Draft Surfaces in Molded Items and Method of Molding

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3139627A (en) * 1962-08-08 1964-07-07 Rubber And Plastics Compound C Liner for a shower stall
US4801493A (en) * 1980-07-23 1989-01-31 Daniel Ferziger Coated fabric and mattress ticking
US4844944A (en) * 1987-12-18 1989-07-04 American Standard, Inc. Lightweight, durable plumbing fixture fabricated from a delamination-resistant multilayer polymeric composite
US4961995A (en) * 1987-08-10 1990-10-09 Ross Gilbert B Polishable, flame retarded, synthetic mineral product
US5494718A (en) * 1994-01-18 1996-02-27 The Geon Company Rigidizer for plastic vessels
US5643652A (en) * 1994-09-28 1997-07-01 Centura Solid Surfacing, Inc. Composite panel for toilet and shower partitions

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3139627A (en) * 1962-08-08 1964-07-07 Rubber And Plastics Compound C Liner for a shower stall
US4801493A (en) * 1980-07-23 1989-01-31 Daniel Ferziger Coated fabric and mattress ticking
US4961995A (en) * 1987-08-10 1990-10-09 Ross Gilbert B Polishable, flame retarded, synthetic mineral product
US4844944A (en) * 1987-12-18 1989-07-04 American Standard, Inc. Lightweight, durable plumbing fixture fabricated from a delamination-resistant multilayer polymeric composite
US5494718A (en) * 1994-01-18 1996-02-27 The Geon Company Rigidizer for plastic vessels
US5643652A (en) * 1994-09-28 1997-07-01 Centura Solid Surfacing, Inc. Composite panel for toilet and shower partitions

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012067695A1 (en) * 2010-11-15 2012-05-24 Masco Bath Corporation Method for bathing vessel having wood-containing base board
WO2012067696A1 (en) * 2010-11-15 2012-05-24 Masco Bath Corporation Method of forming a bathing vessel
WO2012067694A1 (en) * 2010-11-15 2012-05-24 Masco Bath Corporation Bathing vessel having wall reinforcement panel
US20140020172A1 (en) * 2010-11-15 2014-01-23 Masco Bath Corporation Structural Wall Design of a Composite Bathing Vessel
US9320393B2 (en) * 2010-11-15 2016-04-26 Delta Faucet Company Structural wall design of a composite bathing vessel
US9648988B2 (en) 2010-11-15 2017-05-16 Delta Faucet Company Method for bathing vessel having wood-containing base board
US9661956B2 (en) 2010-11-15 2017-05-30 Delta Faucet Company Method of forming a bathing vessel
US10213057B2 (en) 2010-11-15 2019-02-26 Delta Faucet Company Bathing vessel having wall reinforcement panel
US20130256949A1 (en) * 2012-03-30 2013-10-03 Raymond Doss Mold for Creating Negative Draft Surfaces in Molded Items and Method of Molding
US9321191B2 (en) * 2012-03-30 2016-04-26 Raymond Doss Mold for creating negative draft surfaces in molded items and method of molding
US10137604B2 (en) 2012-03-30 2018-11-27 Raymond Doss Mold for creating negative draft surfaces in molded items and method of molding

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Publication number Publication date
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Legal Events

Date Code Title Description
AS Assignment

Owner name: MIROLIN INDUSTRIES CORPORATION, CANADA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:KAPELANSKI, SCOTT;ZIBRAT, STANISLAV;PRETI, ALFREDO LI;REEL/FRAME:015482/0467;SIGNING DATES FROM 20040512 TO 20040607

AS Assignment

Owner name: MASCO CORPORATION, MICHIGAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:MIROLIN INDUSTRIES CORPORATION;REEL/FRAME:016207/0907

Effective date: 20050110

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION