US20050241327A1 - Foul-resistant condenser using microchannel tubing - Google Patents
Foul-resistant condenser using microchannel tubing Download PDFInfo
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- US20050241327A1 US20050241327A1 US10/835,031 US83503104A US2005241327A1 US 20050241327 A1 US20050241327 A1 US 20050241327A1 US 83503104 A US83503104 A US 83503104A US 2005241327 A1 US2005241327 A1 US 2005241327A1
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B39/00—Evaporators; Condensers
- F25B39/04—Condensers
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47F—SPECIAL FURNITURE, FITTINGS, OR ACCESSORIES FOR SHOPS, STOREHOUSES, BARS, RESTAURANTS OR THE LIKE; PAYING COUNTERS
- A47F3/00—Show cases or show cabinets
- A47F3/04—Show cases or show cabinets air-conditioned, refrigerated
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47F—SPECIAL FURNITURE, FITTINGS, OR ACCESSORIES FOR SHOPS, STOREHOUSES, BARS, RESTAURANTS OR THE LIKE; PAYING COUNTERS
- A47F3/00—Show cases or show cabinets
- A47F3/04—Show cases or show cabinets air-conditioned, refrigerated
- A47F3/0404—Cases or cabinets of the closed type
- A47F3/0408—Cases or cabinets of the closed type with forced air circulation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D21/00—Defrosting; Preventing frosting; Removing condensed or defrost water
- F25D21/06—Removing frost
- F25D21/12—Removing frost by hot-fluid circulating system separate from the refrigerant system
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D1/00—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
- F28D1/02—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
- F28D1/04—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits
- F28D1/053—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being straight
- F28D1/0535—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with tubular conduits the conduits being straight the conduits having a non-circular cross-section
- F28D1/05366—Assemblies of conduits connected to common headers, e.g. core type radiators
- F28D1/05383—Assemblies of conduits connected to common headers, e.g. core type radiators with multiple rows of conduits or with multi-channel conduits
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F1/00—Tubular elements; Assemblies of tubular elements
- F28F1/10—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses
- F28F1/12—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element
- F28F1/24—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending transversely
- F28F1/32—Tubular elements and assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with projections, with recesses the means being only outside the tubular element and extending transversely the means having portions engaging further tubular elements
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2500/00—Problems to be solved
- F25B2500/01—Geometry problems, e.g. for reducing size
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D17/00—Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
- F25D17/04—Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection
- F25D17/06—Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection by forced circulation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D21/00—Defrosting; Preventing frosting; Removing condensed or defrost water
- F25D21/14—Collecting or removing condensed and defrost water; Drip trays
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D23/00—General constructional features
- F25D23/003—General constructional features for cooling refrigerating machinery
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2323/00—General constructional features not provided for in other groups of this subclass
- F25D2323/002—Details for cooling refrigerating machinery
- F25D2323/0026—Details for cooling refrigerating machinery characterised by the incoming air flow
- F25D2323/00264—Details for cooling refrigerating machinery characterised by the incoming air flow through the front bottom part
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2323/00—General constructional features not provided for in other groups of this subclass
- F25D2323/002—Details for cooling refrigerating machinery
- F25D2323/0027—Details for cooling refrigerating machinery characterised by the out-flowing air
- F25D2323/00271—Details for cooling refrigerating machinery characterised by the out-flowing air from the back bottom
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2331/00—Details or arrangements of other cooling or freezing apparatus not provided for in other groups of this subclass
- F25D2331/80—Type of cooled receptacles
- F25D2331/803—Bottles
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
- F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
- F28D2021/0068—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for refrigerant cycles
- F28D2021/007—Condensers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
- F28F21/06—Constructions of heat-exchange apparatus characterised by the selection of particular materials of plastics material
- F28F21/067—Details
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2215/00—Fins
- F28F2215/12—Fins with U-shaped slots for laterally inserting conduits
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2260/00—Heat exchangers or heat exchange elements having special size, e.g. microstructures
- F28F2260/02—Heat exchangers or heat exchange elements having special size, e.g. microstructures having microchannels
Definitions
- This invention relates generally to refrigerated beverage and food service merchandisers and, more particularly, to a foul resistant condenser coil therefor.
- refrigerated merchandisers In such stores, cold beverages, such as soft drinks, beer, wine coolers, etc. are commonly displayed in refrigerated merchandisers for self-service purchase by customers.
- Conventional merchandisers of this type usually comprise a refrigerated, insulated enclosure defining a refrigerated product display cabinet and having one or more glass doors.
- the beverage product typically in cans or bottles, single or in six-packs, is stored on shelves within the refrigerated display cabinet. To purchase a beverage, the customer opens one of the doors and reaches into the refrigerated cabinet to retrieve the desired product from the shelf.
- Beverage merchandisers of this type necessarily include a refrigeration system for providing the cooled environment within the refrigerated display cabinet.
- refrigeration systems include an evaporator coil housed within the insulated enclosure defining the refrigerated display cabinet and a condenser coil and compressor housed in a compartment separate from and exteriorly of the insulated enclosure.
- Cold liquid refrigerant is circulated through the evaporator coil to cool the air within the refrigerated display cabinet.
- the liquid refrigerant evaporates and leaves the evaporator coil as a vapor.
- the vapor phase refrigerant is then compressed in the compressor coil to a high pressure, as well as being heated to a higher temperature as a result of the compression process.
- the hot, high pressure vapor is then circulated through the condenser coil wherein it passes in heat exchange relationship with ambient air drawn or blown across through the condenser coil by a fan disposed in operative association with the condenser coil.
- the refrigerant is cooled and condensed back to the liquid phase and then passed through an expansion device which reduces both the pressure and the temperature of the liquid refrigerant before it is circulated back to the evaporator coil.
- the condenser coil comprises a plurality of tubes with fins extending across the flow path of the ambient air stream being drawn or blown through the condenser coil.
- a fan disposed in operative association with the condenser coil, passes ambient air from the local environment through the condenser coil.
- U.S. Pat. No. 3,462,966 discloses a refrigerated glass door merchandiser having a condenser coil with staggered rows of finned tubes and an associated fan disposed upstream of the condenser coil that blows air across the condenser tubes.
- U.S. Pat. No. 4,977,754 discloses a refrigerated glass door merchandiser having a condenser coil with in-line finned tube rows and an associated fan disposed downstream of the condenser that draws air across the condenser tubes.
- the usual structure for such a condenser coil is a tube and fin design wherein a plurality of serpentine tubes with refrigerant flowing therein are surrounded by orthogonally extending fins over which the cooling air is made to flow by way of a fan.
- a tube and fin design wherein a plurality of serpentine tubes with refrigerant flowing therein are surrounded by orthogonally extending fins over which the cooling air is made to flow by way of a fan.
- the greater the tube and fin densities the more efficient the performance of the coil in cooling the refrigerant.
- the greater the tube and fin densities the more susceptible it is to being fouled by the accumulation of dirt and fiber.
- the tube and fin condenser coil is replaced by a condenser coil having a greater number of microchannel tubes than the previous number of round tubes but, with the clearances from tube to tube being relatively large such that air side fouling is less likely to occur.
- such a microchannel refrigerant tube is able to operate with lower amounts of refrigerant when compared to traditional round tube condensers, such that the additional tube surface that is required to make up for using less fins does not significantly increase refrigerant charge requirements.
- the fin density of a microtubes condenser coil is reduced to a level which will substantially eliminate the bridging of fibers between fins such that the occurrence of fouling is substantially reduced or eliminated. If the fin density is reduced to the extent that there is little or no support between the microchannel tubes, then provision is made to include a support structure, in spaced relationship between the adjacent tubes to prevent movement and/or damage thereto.
- multiple rows of microchannel tubes may be provided with each row having its own header.
- the tubes rows are staggered such that the tubes from the downstream row are located so as to be substantially between the tubes of the upstream row.
- FIG. 1 is a perspective view of a refrigerated beverage merchandiser in accordance with the prior art.
- FIG. 2 is a sectional, side elevation view of the refrigerated beverage merchandiser showing the evaporator and condenser sections thereof.
- FIG. 3 is a perspective view of a condenser coil in accordance with one embodiment of the present invention.
- FIG. 4 is a graphic illustration of the relationship between tube/fin density and occurrence of fouling.
- FIG. 5 is a perspective view of an alternative embodiment of a condenser coil in accordance with the present invention.
- FIG. 6 is a side sectional view of a tube support arrangement in accordance with one embodiment of the invention.
- FIG. 7 is a front view thereof.
- FIG. 8 is an alternative embodiment of the invention showing staggered rows of microchannel tubes.
- the beverage merchandiser 10 includes an enclosure 20 defining a refrigerated display cabinet 25 and a separate utility compartment 30 disposed externally of and heat insulated from the refrigerated display cabinet 25 .
- the utility compartment may be disposed beneath the refrigerated display cabinet 25 as depicted or the utility compartment may be disposed above the display cabinet 25 .
- a compressor 40 , a condenser coil 50 , a condensate pan 53 and an associated condenser fan and motor 60 are housed within the compartment 30 .
- a mounting plate 44 may be disposed beneath the compressor 40 , the condenser coil 50 , and the condenser fan 60 .
- the mounting plate 44 may be slidably mounted within the compartment 30 for selective disposition into and out of the compartment 30 in order to facilitate servicing of the refrigeration equipment mounted thereon.
- the refrigerated display cabinet 25 is defined by an insulated rear wall 22 of the enclosure 20 , a pair of insulated side walls 24 of the enclosure 20 , an insulated top wall 26 of the enclosure 20 , an insulated bottom wall 28 of the enclosure 20 and an insulated front wall 34 of the enclosure 20 .
- Heat insulation 36 (shown by the looping line) is provided in the walls defining the refrigerated display cabinet 25 .
- Beverage product 100 such as for example individual cans or bottles or six packs thereof, are displayed on shelves 70 mounted in a conventional manner within the refrigerated display cabinet 25 , such as for example in accord with the next-to-purchase manner shown in U.S. Pat. No. 4,977,754, the entire disclosure of which is hereby incorporated by reference.
- the insulated enclosure 20 has an access opening 35 in the front wall 34 that opens to the refrigerated display cabinet 25 .
- a door 32 as shown in the illustrated embodiment, or more than one door, may be provided to cover the access opening 35 . It is to be understood however that the present invention is also applicable to beverage merchandisers having an open access without a door. To access the beverage product for purchase, a customer need only open the door 32 and reach into the refrigerated display cabinet 25 to select the desired beverage.
- An evaporator coil 80 is provided within the refrigerated display cabinet 25 , for example near the top wall 26 .
- An evaporator fan and motor 82 may be provided to circulate air within the refrigerated display cabinet 25 through the evaporator 80 .
- the evaporator fan is not necessary as natural convection may be relied upon for air circulation through the evaporator.
- As the circulating air passes through the evaporator 80 it passes in a conventional manner in heat exchange relationship with refrigerant circulating through the tubes of the evaporator coil and is cooled as a result.
- the cooled air leaving the evaporator coil 80 is directed downwardly in a conventional manner into the cabinet interior to pass over the product 100 disposed on the shelves 70 before being drawn back upwardly to again pass through the evaporator.
- Refrigerant is circulated in a conventional manner between the evaporator 80 and the condenser 50 by means of the compressor 40 through refrigeration lines forming a refrigeration circuit (not shown) interconnecting the compressor 40 , the condenser coil 50 and the evaporator coil 80 in refrigerant flow communication.
- cold liquid refrigerant is circulated through the evaporator coil 80 to cool the air within the refrigerated display cabinet 25 .
- the liquid refrigerant evaporates and leaves the evaporator as a vapor.
- the vapor phase refrigerant is then compressed in the compressor 40 to a high pressure, as well as being heated to a higher temperature as a result of the compression process.
- the hot, high pressure vapor is then circulated through the condenser coil 50 wherein it passes in heat exchange relationship with ambient air drawn or blown across through the condenser coil 50 by the condenser fan 60 .
- the tube and fin condenser coil 50 of FIG. 2 is replaced by a microchannel condenser coil as shown generally at 110 .
- a plurality of microchannel tubes 111 having a plurality of parallel channels 112 extending the length thereof, are provided in parallel relationship in a row 115 and are connected at their respective ends by inlet and outlet headers 113 and 114 , respectively.
- An inlet line 116 is provided at the inlet header 113 and the outlet line 117 is provided at the outlet header 114 .
- the hot, high pressure refrigerant vapor is passed from the compressor into the inlet line 116 where it is distributed to flow, by way of the individual microchannels 112 , through each of the microchannel tubes 111 to be condensed to a liquid state.
- the liquid refrigerant then flows to the outlet header 114 and out the outlet line 117 to the expansion device.
- a plurality of fins 118 may be placed between adjacent microchannel tube pairs. These fins are preferable aligned orthogonally to the microchannel tube 111 and parallel with the direction of airflow through the microchannel condenser coil 110 .
- the lateral spacing between adjacent fins is the dimension “W”.
- microchannel tube 111 over the conventional round tubes in a condenser coil is that of obtaining more surface area per unit volume. That is, generally, a plurality of small tubes will provide more external surface area than a single large tube. This can be understood by comparison of a single 3 ⁇ 8 inch (8 millimeter) tube with a 5 millimeter tube. The external surface area-to-volume ratio of the 5 millimeter tube is 0.4, which is substantially greater than that for a 8 millimeter tube, which is 0.25.
- microchannel tubes are more streamlined so as to result in a lower pressure drop and lower noise level. That is, there is much less resistance to the air flowing over the relatively narrow microchannels than there is to the air flowing over relatively large round tubes.
- a field analysis was conducted to determine the types of material that were most likely to cause fouling in the condenser coil, and it was found that cotton fibers were the predominant cause of the foulings and that fouling is generally started by the bridging of an elongate fiber between adjacent fin or between adjacent tubes. Accordingly, experimental analysis was conducted to determine the fouling tendencies of a condenser coil in an environment of cotton fibers as the spacing of the fins is selectively varied.
- a number of heat exchangers, each being of a standard design with round tubes and plate fins of a specific spacing were exposed to an environment of natural cotton fibers and tested for their relative tendencies to foul.
- the associated increase in FGP is substantially linear to point B where the spacing is 0.40 inches and the FGP is 1.5.
- point C the relationship is still close to linear wherein the spacing is point 0.50 inches with an associated FGP of 2, which means that the heat exchanger is twice as “good” as compared to the heat exchanger at Point A in regards to fouling.
- the fin spacing should be maintained at 0.75 inches or greater if the maximum FGP is desired.
- the exposed surface area is reduced and therefore the heat exchange capability is also reduced. Accordingly, it may be desirable to maintain sufficient fin spacing so as to obtain a sufficiently high FGP while, at the same time, maintaining sufficient density to provide a desired amount of surface area. For example, at point E, a sufficiently high FGP of 6 is obtained with a fin spacing of 0.70 inches between adjacent fins.
- the fins have been eliminated and the microchannel tubes 111 are simply cantilevered between the inlet header 113 and outlet header 114 as shown.
- the construction is very much simplified, and the expense of the fins is eliminated.
- the benefit of having the surface area of the fin is also lost for heat transfer purposes.
- the considerations discussed hereinabove, with respect to the spacing of fins is also considered to be relevant with respect to the spacing of the microchannel tubes 111 . That is, with the spacing L of 0.75 inches, there will be little or no fouling that occurs, and as that fin density is increased, the fouling goodness parameter (FGP) will be decreased or, said in another way, the probability of fouling will be increased.
- FGP fouling goodness parameter
- FIG. 5 With the complete elimination of fins as shown in FIG. 5 , it may be necessary to provide some support between adjacent microchannel tubes 111 , so that both during the manufacture of the heat exchanger and in the finished product, the microchannel tubes 111 are restrained from sagging from their relative parallel positions.
- a support is shown at 118 in FIGS. 6 and 7 .
- the support member 118 with its plurality of teeth 119 is shown in the uninstalled position at the left and then in the installed position at the right.
- FIG. 7 there is shown in a side elevational view and a front view, three such support members 118 in their installed positions.
- Such a support member 118 may be fabricated of a heat conductive material so as to not only provide support but also act as a conductor in the same manner as a fin. However, with the significant spacing as shown, so as to not significantly add to the heat conduction surface area, the benefit of the fin effect is minimal. Accordingly, the support members may as well be made of other materials such as a plastic material which will provide the necessary support but not contribute to the function of heat transfer.
- the spacing of the support members 118 is clearly sufficient such that the lateral space between the support members will not contribute to the bridging of fibers that would cause fouling. Rather, it is only the distance L between adjacent microchannel tubes that will allow for the bridging of fibers therebetween. The considerations discussed with respect to the FIG. 5 embodiment is therefore relevant to the supported embodiment of FIGS. 6 and 7 .
- the airflow characteristics can be improved by staggering the two rows such that the tubes 122 of the second row are disposed substantially between, but downstream of, the tubes 111 of the first row 115 .
- the controlling parameter with respect to the fouling resistant parameter is still the distance L since this is the distance not only between the individual tubes 111 of the first row 115 but also between the tubes 122 of the second row 121 . That is, with such a staggered relationship, there is very little likelihood of a fiber tending to bridge the gap between a tube 111 in the first row 115 and a tube 122 in the second row 121 .
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Geometry (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Devices That Are Associated With Refrigeration Equipment (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Freezers Or Refrigerated Showcases (AREA)
Abstract
Description
- This invention relates generally to refrigerated beverage and food service merchandisers and, more particularly, to a foul resistant condenser coil therefor.
- It is long been the practice to sell soda and other soft drinks by way of vending machines or coin operated refrigerated containers for dispensing single bottles of beverages. These machines are generally stand alone machines that are plugged into standard outlets and include their own individual refrigeration circuit with both evaporator and condenser coils.
- This self serve approach has now been expanded to include other types of “plug in” beverage and food merchandisers that are located in convenience stores, delicatessens, supermarkets and other retail establishments.
- In such stores, cold beverages, such as soft drinks, beer, wine coolers, etc. are commonly displayed in refrigerated merchandisers for self-service purchase by customers. Conventional merchandisers of this type usually comprise a refrigerated, insulated enclosure defining a refrigerated product display cabinet and having one or more glass doors. The beverage product, typically in cans or bottles, single or in six-packs, is stored on shelves within the refrigerated display cabinet. To purchase a beverage, the customer opens one of the doors and reaches into the refrigerated cabinet to retrieve the desired product from the shelf.
- Beverage merchandisers of this type necessarily include a refrigeration system for providing the cooled environment within the refrigerated display cabinet. Such refrigeration systems include an evaporator coil housed within the insulated enclosure defining the refrigerated display cabinet and a condenser coil and compressor housed in a compartment separate from and exteriorly of the insulated enclosure. Cold liquid refrigerant is circulated through the evaporator coil to cool the air within the refrigerated display cabinet. As a result of heat transfer between the air and the refrigerant passing in heat exchange relationship in the evaporator coil, the liquid refrigerant evaporates and leaves the evaporator coil as a vapor. The vapor phase refrigerant is then compressed in the compressor coil to a high pressure, as well as being heated to a higher temperature as a result of the compression process. The hot, high pressure vapor is then circulated through the condenser coil wherein it passes in heat exchange relationship with ambient air drawn or blown across through the condenser coil by a fan disposed in operative association with the condenser coil. As a result, the refrigerant is cooled and condensed back to the liquid phase and then passed through an expansion device which reduces both the pressure and the temperature of the liquid refrigerant before it is circulated back to the evaporator coil.
- In conventional practice, the condenser coil comprises a plurality of tubes with fins extending across the flow path of the ambient air stream being drawn or blown through the condenser coil. A fan, disposed in operative association with the condenser coil, passes ambient air from the local environment through the condenser coil. U.S. Pat. No. 3,462,966 discloses a refrigerated glass door merchandiser having a condenser coil with staggered rows of finned tubes and an associated fan disposed upstream of the condenser coil that blows air across the condenser tubes. U.S. Pat. No. 4,977,754 discloses a refrigerated glass door merchandiser having a condenser coil with in-line finned tube rows and an associated fan disposed downstream of the condenser that draws air across the condenser tubes.
- One problem that occurs with such self-contained merchandisers is that they are often in area that is heavily trafficked by people that tend to track in debris and dirt from the outside. This, in turn, tends to expose the condenser coil, which is necessarily exposed to the flow of air in the immediate vicinity, to be susceptible to airside fouling. With such fouling, the accumulation of dust, dirt and oils impede refrigeration performance. As the condenser coil fouls, the compressor refrigerant pressure rises, which leads to system inefficiencies and possibly compressor failure. Further, such products are often used in locations where periodic cleaning is not likely to occur.
- The usual structure for such a condenser coil is a tube and fin design wherein a plurality of serpentine tubes with refrigerant flowing therein are surrounded by orthogonally extending fins over which the cooling air is made to flow by way of a fan. Generally, the greater the tube and fin densities, the more efficient the performance of the coil in cooling the refrigerant. However, the greater the tube and fin densities, the more susceptible it is to being fouled by the accumulation of dirt and fiber.
- This problem has been addressed in one form by the elimination of fins and relying on conventional tubes as set forth in U.S. patent application Ser. No. 10/421,575, assigned to the assignee of the present application and incorporated herein by reference. A further approach has been to selectively stagger the successive rows of tubes in relation to the direction of airflow as described in U.S. Patent Application No. (PCT/US03/12468), Continuation In Part Application of Provisional Application Ser. No. 60/376,486 filed on Apr. 30, 2002, assigned to the assignee of the present application and incorporated herein by reference.
- Briefly, in accordance with one aspect of the invention, the tube and fin condenser coil is replaced by a condenser coil having a greater number of microchannel tubes than the previous number of round tubes but, with the clearances from tube to tube being relatively large such that air side fouling is less likely to occur.
- In accordance with another aspect of the invention, such a microchannel refrigerant tube is able to operate with lower amounts of refrigerant when compared to traditional round tube condensers, such that the additional tube surface that is required to make up for using less fins does not significantly increase refrigerant charge requirements.
- By yet another aspect of the invention, the fin density of a microtubes condenser coil is reduced to a level which will substantially eliminate the bridging of fibers between fins such that the occurrence of fouling is substantially reduced or eliminated. If the fin density is reduced to the extent that there is little or no support between the microchannel tubes, then provision is made to include a support structure, in spaced relationship between the adjacent tubes to prevent movement and/or damage thereto.
- In accordance with another aspect of the invention, in order to provide sufficient heat exchange surface area with the reduced tube and fin densities, multiple rows of microchannel tubes may be provided with each row having its own header. In order to obtain better heat exchange efficiencies without an attendant increase in fouling, the tubes rows are staggered such that the tubes from the downstream row are located so as to be substantially between the tubes of the upstream row.
- In the drawings as hereinafter described, a preferred embodiment is depicted; however various other modifications and alternate constructions can be made thereto without departing from the true spirit and scope of the invention.
-
FIG. 1 is a perspective view of a refrigerated beverage merchandiser in accordance with the prior art. -
FIG. 2 is a sectional, side elevation view of the refrigerated beverage merchandiser showing the evaporator and condenser sections thereof. -
FIG. 3 is a perspective view of a condenser coil in accordance with one embodiment of the present invention. -
FIG. 4 is a graphic illustration of the relationship between tube/fin density and occurrence of fouling. -
FIG. 5 is a perspective view of an alternative embodiment of a condenser coil in accordance with the present invention. -
FIG. 6 is a side sectional view of a tube support arrangement in accordance with one embodiment of the invention. -
FIG. 7 is a front view thereof. -
FIG. 8 is an alternative embodiment of the invention showing staggered rows of microchannel tubes. - Referring now to
FIGS. 1 and 2 , there is depicted therein a refrigerated cold beverage merchandiser generally designated by thenumeral 10. Thebeverage merchandiser 10 includes anenclosure 20 defining a refrigerateddisplay cabinet 25 and aseparate utility compartment 30 disposed externally of and heat insulated from the refrigerateddisplay cabinet 25. The utility compartment may be disposed beneath the refrigerateddisplay cabinet 25 as depicted or the utility compartment may be disposed above thedisplay cabinet 25. Acompressor 40, acondenser coil 50, acondensate pan 53 and an associated condenser fan andmotor 60 are housed within thecompartment 30. A mounting plate 44 may be disposed beneath thecompressor 40, thecondenser coil 50, and thecondenser fan 60. Advantageously, the mounting plate 44 may be slidably mounted within thecompartment 30 for selective disposition into and out of thecompartment 30 in order to facilitate servicing of the refrigeration equipment mounted thereon. - The refrigerated
display cabinet 25 is defined by an insulatedrear wall 22 of theenclosure 20, a pair of insulatedside walls 24 of theenclosure 20, an insulatedtop wall 26 of theenclosure 20, aninsulated bottom wall 28 of theenclosure 20 and an insulatedfront wall 34 of theenclosure 20. Heat insulation 36 (shown by the looping line) is provided in the walls defining the refrigerateddisplay cabinet 25.Beverage product 100, such as for example individual cans or bottles or six packs thereof, are displayed onshelves 70 mounted in a conventional manner within the refrigerateddisplay cabinet 25, such as for example in accord with the next-to-purchase manner shown in U.S. Pat. No. 4,977,754, the entire disclosure of which is hereby incorporated by reference. The insulatedenclosure 20 has an access opening 35 in thefront wall 34 that opens to the refrigerateddisplay cabinet 25. If desired, adoor 32, as shown in the illustrated embodiment, or more than one door, may be provided to cover the access opening 35. It is to be understood however that the present invention is also applicable to beverage merchandisers having an open access without a door. To access the beverage product for purchase, a customer need only open thedoor 32 and reach into therefrigerated display cabinet 25 to select the desired beverage. - An
evaporator coil 80 is provided within therefrigerated display cabinet 25, for example near thetop wall 26. An evaporator fan andmotor 82, as illustrated inFIG. 2 , may be provided to circulate air within therefrigerated display cabinet 25 through theevaporator 80. However, the evaporator fan is not necessary as natural convection may be relied upon for air circulation through the evaporator. As the circulating air passes through theevaporator 80, it passes in a conventional manner in heat exchange relationship with refrigerant circulating through the tubes of the evaporator coil and is cooled as a result. The cooled air leaving theevaporator coil 80 is directed downwardly in a conventional manner into the cabinet interior to pass over theproduct 100 disposed on theshelves 70 before being drawn back upwardly to again pass through the evaporator. - Refrigerant is circulated in a conventional manner between the evaporator 80 and the
condenser 50 by means of thecompressor 40 through refrigeration lines forming a refrigeration circuit (not shown) interconnecting thecompressor 40, thecondenser coil 50 and theevaporator coil 80 in refrigerant flow communication. As noted before, cold liquid refrigerant is circulated through theevaporator coil 80 to cool the air within therefrigerated display cabinet 25. As a result of heat transfer between the air and the refrigerant passing in heat exchange relationship in theevaporator coil 80, the liquid refrigerant evaporates and leaves the evaporator as a vapor. The vapor phase refrigerant is then compressed in thecompressor 40 to a high pressure, as well as being heated to a higher temperature as a result of the compression process. The hot, high pressure vapor is then circulated through thecondenser coil 50 wherein it passes in heat exchange relationship with ambient air drawn or blown across through thecondenser coil 50 by thecondenser fan 60. - Referring now to
FIG. 3 , in accordance with the present invention, the tube andfin condenser coil 50 ofFIG. 2 is replaced by a microchannel condenser coil as shown generally at 110. Here, rather than round tubes, a plurality ofmicrochannel tubes 111, having a plurality ofparallel channels 112 extending the length thereof, are provided in parallel relationship in arow 115 and are connected at their respective ends by inlet andoutlet headers inlet line 116 is provided at theinlet header 113 and theoutlet line 117 is provided at theoutlet header 114. In operation, the hot, high pressure refrigerant vapor is passed from the compressor into theinlet line 116 where it is distributed to flow, by way of theindividual microchannels 112, through each of themicrochannel tubes 111 to be condensed to a liquid state. The liquid refrigerant then flows to theoutlet header 114 and out theoutlet line 117 to the expansion device. - In order to increase the heat exchange capacity of the
coil 110, a plurality offins 118 may be placed between adjacent microchannel tube pairs. These fins are preferable aligned orthogonally to themicrochannel tube 111 and parallel with the direction of airflow through themicrochannel condenser coil 110. The lateral spacing between adjacent fins is the dimension “W”. - One advantage offered by the
microchannel tube 111 over the conventional round tubes in a condenser coil is that of obtaining more surface area per unit volume. That is, generally, a plurality of small tubes will provide more external surface area than a single large tube. This can be understood by comparison of a single ⅜ inch (8 millimeter) tube with a 5 millimeter tube. The external surface area-to-volume ratio of the 5 millimeter tube is 0.4, which is substantially greater than that for a 8 millimeter tube, which is 0.25. - One disadvantage to the use of a greater number of smaller tubes rather than fewer larger tubes is that it is generally more expensive to implement. However, the techniques that have been developed for manufacturing microchannel tubes with a plurality of channels has evolved to the extent that they are now economical as compared with the manufacturer and implementation of round tubes in a heat exchanger coil.
- Another advantage of the microchannel tubes is that they are more streamlined so as to result in a lower pressure drop and lower noise level. That is, there is much less resistance to the air flowing over the relatively narrow microchannels than there is to the air flowing over relatively large round tubes.
- Considering now the problem of air side fouling which results from the accumulation of dust, dirt and oils between adjacent tubes and/or adjacent fins of a condenser coil, the applicants have recognized that such a fouling starts with the bridging of an elongate fiber between adjacent tubes or between adjacent fins. That is, most small particles will pass through the passages of a coil unless a passage is somewhat blocked by the lodging of a fiber therein. When a bridging fiber is lodged between adjacent fins or adjacent tubes, then small particles tend to collect on that fiber with the build up eventually resulting in a fouling of the passageway. In order to prevent or reduce the occurrence of fouling, it is therefore necessary to understand the manner in which the bridging effect is influenced by the structural configuration of the coil. With that in mind, the applicants have conducted experimental tests to determine how the variation in the spacing of the tubes and the spacing of the fins can affect the tendency of fouling to occur. The results are shown in
FIG. 4 . - A field analysis was conducted to determine the types of material that were most likely to cause fouling in the condenser coil, and it was found that cotton fibers were the predominant cause of the foulings and that fouling is generally started by the bridging of an elongate fiber between adjacent fin or between adjacent tubes. Accordingly, experimental analysis was conducted to determine the fouling tendencies of a condenser coil in an environment of cotton fibers as the spacing of the fins is selectively varied. A number of heat exchangers, each being of a standard design with round tubes and plate fins of a specific spacing were exposed to an environment of natural cotton fibers and tested for their relative tendencies to foul. A heat exchanger having seven fins per inch, or a fin spacing of 0.14 inches between adjacent fins, was arbitrarily assigned a fouling goodness parameter (FGP) of 1. This is shown at point A on the graph of
FIG. 4 . - As the fin spacing is increased, the associated increase in FGP is substantially linear to point B where the spacing is 0.40 inches and the FGP is 1.5. At point C, the relationship is still close to linear wherein the spacing is point 0.50 inches with an associated FGP of 2, which means that the heat exchanger is twice as “good” as compared to the heat exchanger at Point A in regards to fouling.
- As the front spacing is increased beyond the 0.50 spacing, it will be seen that the FGP begins to increase substantially beyond the linear relationship, and at a spacing of 0.75 inches as shown at point B, it approaches an asymptotic relationship. Thus, it can be concluded that ideally, the fin spacing should be maintained at 0.75 inches or greater if the maximum FGP is desired. At those higher spacing parameters, however, it will be recognized that the exposed surface area is reduced and therefore the heat exchange capability is also reduced. Accordingly, it may be desirable to maintain sufficient fin spacing so as to obtain a sufficiently high FGP while, at the same time, maintaining sufficient density to provide a desired amount of surface area. For example, at point E, a sufficiently high FGP of 6 is obtained with a fin spacing of 0.70 inches between adjacent fins.
- Although the experiential data as discussed hereinabove relates to fin spacing on round tube heat exchangers, the applicants believe that the same performance characteristics will be true of fin spacing with a microchannel tubing heat exchanger as shown in
FIG. 3 since the principals involving the attachment of elongate fibers will be substantially the same in each case. Further, recognizing that with a microchannel tubing arrangement as shown inFIG. 3 , it is possible to eliminate the fins entirely, or to reduce the number such that they are simply provided for support between the microchannel tubes, while at the same time increasing the density of the microchannel tubes to obtain the desired surface area for heat exchange purposes. Such a heat exchanger is shown inFIG. 5 . - In the
FIG. 5 embodiment, it will be seen that the fins have been eliminated and themicrochannel tubes 111 are simply cantilevered between theinlet header 113 andoutlet header 114 as shown. With this arrangement, the construction is very much simplified, and the expense of the fins is eliminated. However, the benefit of having the surface area of the fin is also lost for heat transfer purposes. Accordingly, it may be necessary to increase the density of themicrochannel tubing 111 such that the distance therebetween, shown as L inFIG. 5 is substantially reduced. In this regard, the considerations discussed hereinabove, with respect to the spacing of fins is also considered to be relevant with respect to the spacing of themicrochannel tubes 111. That is, with the spacing L of 0.75 inches, there will be little or no fouling that occurs, and as that fin density is increased, the fouling goodness parameter (FGP) will be decreased or, said in another way, the probability of fouling will be increased. - With the complete elimination of fins as shown in
FIG. 5 , it may be necessary to provide some support betweenadjacent microchannel tubes 111, so that both during the manufacture of the heat exchanger and in the finished product, themicrochannel tubes 111 are restrained from sagging from their relative parallel positions. Such a support is shown at 118 inFIGS. 6 and 7 . InFIG. 6 , thesupport member 118 with its plurality ofteeth 119 is shown in the uninstalled position at the left and then in the installed position at the right. InFIG. 7 , there is shown in a side elevational view and a front view, threesuch support members 118 in their installed positions. Such asupport member 118 may be fabricated of a heat conductive material so as to not only provide support but also act as a conductor in the same manner as a fin. However, with the significant spacing as shown, so as to not significantly add to the heat conduction surface area, the benefit of the fin effect is minimal. Accordingly, the support members may as well be made of other materials such as a plastic material which will provide the necessary support but not contribute to the function of heat transfer. Here, the spacing of thesupport members 118 is clearly sufficient such that the lateral space between the support members will not contribute to the bridging of fibers that would cause fouling. Rather, it is only the distance L between adjacent microchannel tubes that will allow for the bridging of fibers therebetween. The considerations discussed with respect to theFIG. 5 embodiment is therefore relevant to the supported embodiment ofFIGS. 6 and 7 . - With the elimination of the fins as discussed hereinabove, another effect that must be considered is that with the resulting reduced heat exchange surface area, and with an associated increase in the density of the microchannel tubes, will there be still sufficient heat exchange surface area to obtain the necessary performance? Presuming that, because of the performance characteristics discussed hereinabove, the spacing L between adjacent microchannels tubes is maintained at around 0.75 inches, the resulting number of microchannel tubes may not be sufficient to bring about the desired amount of heat exchange. One approach for overcoming this problem is shown in
FIG. 8 wherein asecond row 121 ofmicrochannel tubes 122 is shown with its associatedheader 123. This will, in effect, double the surface area of the heat exchanger without significantly adding to the problem of fouling between microchannel tubing. While the tworows tubes 122 of the second row are disposed substantially between, but downstream of, thetubes 111 of thefirst row 115. With such an arrangement, the controlling parameter with respect to the fouling resistant parameter is still the distance L since this is the distance not only between theindividual tubes 111 of thefirst row 115 but also between thetubes 122 of thesecond row 121. That is, with such a staggered relationship, there is very little likelihood of a fiber tending to bridge the gap between atube 111 in thefirst row 115 and atube 122 in thesecond row 121. - It will, of course, be understood that multiple rows of tubes can be placed in such a staggered relationship such that the third row would most likely be aligned with the first row and a fourth row would be most aligned with a second row and so forth. Again, the fouling goodness parameter would not significantly change since the controlling parameter would still be the distance L between tubes in any single row.
- While the present invention has been particular shown and described with reference to preferred and alternate embodiments as illustrated in the drawings, it will be understood by one skilled in the art that various changes in detail may be effective therein without departing from the true spirit and scope of the invention as defined by the claims.
Claims (23)
Priority Applications (10)
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US10/835,031 US7000415B2 (en) | 2004-04-29 | 2004-04-29 | Foul-resistant condenser using microchannel tubing |
EP05732381A EP1744651A4 (en) | 2004-04-29 | 2005-04-07 | Foul-resistant condenser using microchannel tubing |
PCT/US2005/011617 WO2005110164A1 (en) | 2004-04-29 | 2005-04-07 | Foul-resistant condenser using microchannel tubing |
AU2005244255A AU2005244255B8 (en) | 2004-04-29 | 2005-04-07 | Foul-resistant condenser using microchannel tubing |
BRPI0510276-6A BRPI0510276A (en) | 2004-04-29 | 2005-04-07 | refrigerated merchandise display |
NZ550273A NZ550273A (en) | 2004-04-29 | 2005-04-07 | A refrigerated merchandiser with a condenser coil using microchannel tubing |
KR1020067022452A KR101242317B1 (en) | 2004-04-29 | 2005-04-07 | Foul-resistant condenser using microchannel tubing |
CN200580012895XA CN1946318B (en) | 2004-04-29 | 2005-04-07 | Foul-resistant condenser using microchannel tubing |
US11/255,426 US7281387B2 (en) | 2004-04-29 | 2005-10-21 | Foul-resistant condenser using microchannel tubing |
HK07110628.2A HK1105340A1 (en) | 2004-04-29 | 2007-10-02 | Foul-resistant condenser using microchannel tubing |
Applications Claiming Priority (1)
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US10/835,031 US7000415B2 (en) | 2004-04-29 | 2004-04-29 | Foul-resistant condenser using microchannel tubing |
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US11/255,426 Continuation-In-Part US7281387B2 (en) | 2004-04-29 | 2005-10-21 | Foul-resistant condenser using microchannel tubing |
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- 2005-04-07 CN CN200580012895XA patent/CN1946318B/en not_active Expired - Fee Related
- 2005-04-07 EP EP05732381A patent/EP1744651A4/en not_active Withdrawn
- 2005-04-07 AU AU2005244255A patent/AU2005244255B8/en not_active Ceased
- 2005-04-07 BR BRPI0510276-6A patent/BRPI0510276A/en not_active IP Right Cessation
- 2005-04-07 WO PCT/US2005/011617 patent/WO2005110164A1/en active Application Filing
- 2005-04-07 NZ NZ550273A patent/NZ550273A/en unknown
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WO2008045113A1 (en) * | 2006-10-13 | 2008-04-17 | Carrier Corporation | Refrigeration unit with integrated structural condenser coil support |
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US11614286B2 (en) | 2016-09-09 | 2023-03-28 | Danfoss Micro Channel Heat Exchanger (Jiaxing) Co., Ltd. | Un-finned heat exchanger |
US10914524B2 (en) | 2016-09-09 | 2021-02-09 | Danfoss Micro Channel Heat Exchanger (Jianxing) Co., Ltd. | Un-finned heat exchanger |
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Also Published As
Publication number | Publication date |
---|---|
AU2005244255B8 (en) | 2010-04-08 |
US7000415B2 (en) | 2006-02-21 |
HK1105340A1 (en) | 2008-02-15 |
AU2005244255A1 (en) | 2005-11-24 |
EP1744651A1 (en) | 2007-01-24 |
CN1946318B (en) | 2010-12-08 |
KR101242317B1 (en) | 2013-03-12 |
AU2005244255B2 (en) | 2010-03-25 |
WO2005110164A1 (en) | 2005-11-24 |
NZ550273A (en) | 2009-05-31 |
EP1744651A4 (en) | 2007-12-12 |
CN1946318A (en) | 2007-04-11 |
KR20070006868A (en) | 2007-01-11 |
BRPI0510276A (en) | 2007-10-30 |
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