US20040244626A1 - Propellant charge batch in particular for bolt setting tools - Google Patents

Propellant charge batch in particular for bolt setting tools Download PDF

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Publication number
US20040244626A1
US20040244626A1 US10/851,370 US85137004A US2004244626A1 US 20040244626 A1 US20040244626 A1 US 20040244626A1 US 85137004 A US85137004 A US 85137004A US 2004244626 A1 US2004244626 A1 US 2004244626A1
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United States
Prior art keywords
propellant charge
chamber
propellant
batch
nitrocellulose
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Abandoned
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US10/851,370
Inventor
Gerhard Ehmig
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Hilti AG
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Hilti AG
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Assigned to HILTI AKTIENGESELLSCHAFT reassignment HILTI AKTIENGESELLSCHAFT ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: EHMIG, GERHARD
Publication of US20040244626A1 publication Critical patent/US20040244626A1/en
Abandoned legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42AMMUNITION; BLASTING
    • F42BEXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
    • F42B5/00Cartridge ammunition, e.g. separately-loaded propellant charges
    • F42B5/02Cartridges, i.e. cases with charge and missile
    • F42B5/16Cartridges, i.e. cases with charge and missile characterised by composition or physical dimensions or form of propellant charge, with or without projectile, or powder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B25HAND TOOLS; PORTABLE POWER-DRIVEN TOOLS; MANIPULATORS
    • B25CHAND-HELD NAILING OR STAPLING TOOLS; MANUALLY OPERATED PORTABLE STAPLING TOOLS
    • B25C1/00Hand-held nailing tools; Nail feeding devices
    • B25C1/08Hand-held nailing tools; Nail feeding devices operated by combustion pressure
    • B25C1/10Hand-held nailing tools; Nail feeding devices operated by combustion pressure generated by detonation of a cartridge
    • B25C1/16Cartridges specially adapted for impact tools; Cartridge and bolts units
    • B25C1/163Cartridges
    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B45/00Compositions or products which are defined by structure or arrangement of component of product
    • C06B45/12Compositions or products which are defined by structure or arrangement of component of product having contiguous layers or zones

Definitions

  • the present invention relates to a propellant charge batch for explosion-operated setting tool and including a socket member the inner space of which is filled with a propellant charge, and at least one ignition element.
  • the propellant charge batches of the type described above are formed, e.g., as cartridges or blisters filled with a powdered propellant charge.
  • the propellant charge batches of the above-described type are used in, e.g., bolt setting tools and serve as drive means for the tool drive piston.
  • a propellant charge batch of the above-described type is disclosed, e.g., in a German Publication DE-39 10 392 A1.
  • the propellant charge is located in a hollow space of a cartridge-shaped receptacle, with the ignition element being located in a sidewise recess formed in the receptacle.
  • the most favorable propellant charge component is ammoniumnitrate which, after being consumed in the setting tool, does not release any toxins and releases only gaseous reaction products.
  • the drawback of the ammoniumnitrate consists in that it is highly hygroscopic.
  • U.S. Pat. No. 3,753,810 discloses a shelled propellant powder on basis of nitrocellulose and ammoniumnitrate. With this propellant powder, the grains or granules are provided, for protection against moisture, with a nitrocellulose outer coating containing at least aluminum in a powder form. The method of manufacturing such a propellant charge is very expensive, which makes the powder very expensive.
  • an object of the present invention is to provide a propellant charge batch of the type discussed above, e.g., such as a cartridge in which the drawbacks of the prior art are eliminated.
  • a propellant charge batch having a socket member in an inner space of which there are provided a first chamber filled with a nitrocellulose propellant charge, and a second chamber filled with ammoniumnitrate powder, with at least the second chamber being closed medium tightly, and ignition means for igniting the propellant charge.
  • the nitrocellulose propellant can be in a pasty, granular, powder, fiber or the like form and can include or not include different additives such as, e.g., nitroglycerine.
  • the nitrocellulose propellant which is contained in the propellant charge batch or cartridge is easily ignited, and its amount is so adapted to the ammoniumnitrate powder that, advantageously, a neutral oxygen balance is achieved. This is energetically advantageous and prevents an eventual corrosion of the tool which could result from an excess of oxygen. Because the ammoniumnitrate powder is separated from the nitrocellulose propellant, the ignition of the nitrocellulose powder is not affected by an undefined distribution of the ammoniumnitrate powder in the nitrocellulose propellant. Further, the separation of the ammoniumnitrate powder from the nitrocellulose propellant insures a predetermined filling of the propellant charge batch or the cartridge during manufacturing.
  • the change of the volume of the ammoniumnitrate as a result of a phase change becomes irrelevant because the grains of the nitrocellulose are not affected due to the separation of the ammoniumnitrate and the nitrocellulose propellant.
  • the separation of the ammoniumnitrate and the nitrocellulose propellant provides for a complete water-tight packing of the ammoniumnitrate.
  • the harmful hygroscopicity of the ammoniumnitrate also becomes irrelevant.
  • both chambers are arranged one after another in the axial direction of the socket member.
  • the ignition means is arranged in the region of the bottom of the propellant charge batch, with the nitrocellulose propellant being located in the chamber which is adjacent to the ignition means, and ammoniumnitrate powder being located in the frontmost chamber remote from the ignition means.
  • the ignition means, the nitrocellulose propellant, and the ammoniumnitrate form an ignition chain.
  • the ignition condition for the ammoniumnitrate are particular good for ammoniumnitrate with the present invention. 200 J of an ignition energy provide for a temperature of about 2,500° C., a pressure of about 100 bar, and a high flow velocity.
  • the mixture of a combusting nitrocellulose propellant and ammoniumnitrate is intermixed during the combustion for a long time, e.g., in a swirl chamber.
  • An extended intermixing favorably influences the combustion process.
  • the combustion volume is maintained substantially constant. The combustion with a substantially constant volume and a high propellant density is very favorable for conversion of the entire propellant charge.
  • the two chambers are separated from each other by a separating element. This simplifies the manufacturing process and, thus, facilitate the production of the inventive propellant charge batch.
  • the separating element is formed as a disc-shaped element of a nitrocellulose board. Because the nitrocellulose board is combustible, no problem associate with a possible residue of the separation element exists.
  • the propellant charge batch is formed as a blister or a blister cartridge, i.e., the socket member is formed of a blister film or foil.
  • the formation of the batch of the blister film insures a cost-effective manufacturing of the batches.
  • Another advantage of using a blister film consists in that the film is easily opened by the propellant upon combustion.
  • the separation element is formed as a cup-shaped element of a film material, e.g., a blister film or foil.
  • This separation element is particularly suitable for use in a blister cartridge, as the socket member and the separating element can be welded or glued to each other in their end regions, which insures a proper sealing of the two chambers relative to each other.
  • FIG. 1 a longitudinal cross-sectional view of a first embodiment of a propellant charge batch according to the present invention.
  • FIG. 2 a longitudinal cross-sectional view of a second embodiment of a propellant charge batch according to the present invention.
  • a propellant charge batch according the present invention which is shown in FIG. 1, is formed as a socket member 10 the inner space of which is divided in two chambers 11 , 12 .
  • a propellant charge, which is contained in the propellant charge batch consists of nitrocellulose means 13 , e.g., a nitrocellulose powder, which is located in the chamber 11 , and an ammoniumnitrate powder 14 which is located in the chamber 12 .
  • the chambers 11 and 12 are arranged one after another in an axial direction 20 , with the chamber 11 being limited by the bottom 17 of the propellant charge batch.
  • the socket member 10 is closed, preferably, by a medium/liquid tight cover 18 .
  • both the socket 10 and the socket cover 18 are formed of a plastic material. However, they also can be formed of metal or any other suitable material. It should be understood that the graininess of the ammoniumnitrate can vary from fine-grained to coarse-grained.
  • the socket member 10 is provided with a salient edge region 19 with which the propellant charge batch can be supported on flanks of a cartridge support of a setting tool (not shown).
  • ignition means 15 is located in the empty space of the salient edge region.
  • the two chambers 11 , 12 are separated from each other, in the embodiment shown in the drawing, by a medium tight separating element 16 . 1 formed, in the embodiment shown in FIG. 1, as a plate cut out from a nitrocellulose board.
  • the nitrocellulose propellant means 13 is ignited. With the ignition of the nitrocellulose propellant means 13 , the separating plate 16 . 1 is teared open and is pressed back. The separating plate 16 . 1 takes part in the combustion and is completely consumed, so that no residue remains. As a result of the pressure of combustion, the propellant charge batch or cartridge opens in its front region, so that the ammoniumnitrate powder 14 becomes mixed with a remaining nitrocellulose propellant means 13 , which results in an optimal combustion of the propellant charge.
  • the intermixing of the ammoniumnitrate powder 14 with the remaining portion of the nitrocellulose propellant means 13 is enhanced by providing in the setting tool, downstream of the cartridge support, of a swirl chamber.
  • the combustion is effected without release of toxic substances and without formation of slag.
  • the ammoniumnitrate powder 14 is protected from penetration of moisture as a result of the chamber 12 being closed.
  • the propellant charge batch shown in FIG. 2 differs from that of FIG. 1, in that the socket member 10 is formed of a rigid plastic film (blister foil).
  • the socket cover 18 is formed of a thin foil that can be, optionally, metal-plated.
  • the separating element 16 . 2 which separates the chamber 11 with the nitrocellulose propellant means 13 and the chamber 12 with the ammoniumnitrate powder 14 , is formed of a cup-shaped blister foil having an edge region that overlaps the edge region 19 of the socket member 10 and is welded or glued thereto.
  • the ignition means 15 is located separately. Upon ignition of the propellant charge batch, the ignited nitrocellulose bursts the films, which form the separating element 16 .
  • the nitrocellulose propellant means 13 intermixes subsequently with the ammoniumnitrate powder 14 , with the mixture having been completely combusted, without leaving any toxic reaction products.
  • a cartridge according to the present invention can be also formed as a one-piece element, with the socket member having an integral bottom and with the front socket opening of the cartridge being closed and sealed.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • Air Bags (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)

Abstract

A propellant charge batch for an explosion-operated setting tool includes a socket member (10) in an inner space which there are provided a first chamber (11) filled with a nitrocellulose propellant charge (13), and a second chamber (12) filled with an ammoniumnitrate powder (14), with at least the second chamber (12) being closed medium tightly; and at least one ignition element (15) for igniting the propellant charge.

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention [0001]
  • The present invention relates to a propellant charge batch for explosion-operated setting tool and including a socket member the inner space of which is filled with a propellant charge, and at least one ignition element. [0002]
  • 2. Summary of the Invention [0003]
  • The propellant charge batches of the type described above are formed, e.g., as cartridges or blisters filled with a powdered propellant charge. [0004]
  • The propellant charge batches of the above-described type are used in, e.g., bolt setting tools and serve as drive means for the tool drive piston. [0005]
  • A propellant charge batch of the above-described type is disclosed, e.g., in a [0006] German Publication DE-39 10 392 A1. In the disclosed batch, the propellant charge is located in a hollow space of a cartridge-shaped receptacle, with the ignition element being located in a sidewise recess formed in the receptacle.
  • It is desirable to use in the propellant charge batches, a propellant charge powder which is free of harmful substances to a most possible extent. The powder, which is used presently, is, however, relatively expensive and produces slag which is highly undesirable in contemporary bolt setting tools and which cannot be removed. [0007]
  • From the environmental point of view, the most favorable propellant charge component is ammoniumnitrate which, after being consumed in the setting tool, does not release any toxins and releases only gaseous reaction products. The drawback of the ammoniumnitrate consists in that it is highly hygroscopic. [0008]
  • U.S. Pat. No. 3,753,810 discloses a shelled propellant powder on basis of nitrocellulose and ammoniumnitrate. With this propellant powder, the grains or granules are provided, for protection against moisture, with a nitrocellulose outer coating containing at least aluminum in a powder form. The method of manufacturing such a propellant charge is very expensive, which makes the powder very expensive. [0009]
  • Further, with strong temperature variations during charging, because of a phase change, the aluminum coat becomes lost. [0010]
  • Accordingly, an object of the present invention is to provide a propellant charge batch of the type discussed above, e.g., such as a cartridge in which the drawbacks of the prior art are eliminated. [0011]
  • SUMMARY OF THE INVENTION
  • This and other objects of the present invention, which will become apparent hereinafter, are achieved by providing a propellant charge batch having a socket member in an inner space of which there are provided a first chamber filled with a nitrocellulose propellant charge, and a second chamber filled with ammoniumnitrate powder, with at least the second chamber being closed medium tightly, and ignition means for igniting the propellant charge. [0012]
  • According to the invention, the nitrocellulose propellant can be in a pasty, granular, powder, fiber or the like form and can include or not include different additives such as, e.g., nitroglycerine. [0013]
  • The nitrocellulose propellant, which is contained in the propellant charge batch or cartridge is easily ignited, and its amount is so adapted to the ammoniumnitrate powder that, advantageously, a neutral oxygen balance is achieved. This is energetically advantageous and prevents an eventual corrosion of the tool which could result from an excess of oxygen. Because the ammoniumnitrate powder is separated from the nitrocellulose propellant, the ignition of the nitrocellulose powder is not affected by an undefined distribution of the ammoniumnitrate powder in the nitrocellulose propellant. Further, the separation of the ammoniumnitrate powder from the nitrocellulose propellant insures a predetermined filling of the propellant charge batch or the cartridge during manufacturing. Still further, the change of the volume of the ammoniumnitrate as a result of a phase change becomes irrelevant because the grains of the nitrocellulose are not affected due to the separation of the ammoniumnitrate and the nitrocellulose propellant. Further, the separation of the ammoniumnitrate and the nitrocellulose propellant provides for a complete water-tight packing of the ammoniumnitrate. As a result, the harmful hygroscopicity of the ammoniumnitrate also becomes irrelevant. Thus, there is provided a propellant charge batch which is environment-friendly and is characterized by a high propelling power. [0014]
  • According to an advantageous embodiment of the present invention, both chambers are arranged one after another in the axial direction of the socket member. Advantageously, the ignition means is arranged in the region of the bottom of the propellant charge batch, with the nitrocellulose propellant being located in the chamber which is adjacent to the ignition means, and ammoniumnitrate powder being located in the frontmost chamber remote from the ignition means. With such an arrangement, the ignition means, the nitrocellulose propellant, and the ammoniumnitrate form an ignition chain. The ignition condition for the ammoniumnitrate are particular good for ammoniumnitrate with the present invention. 200 J of an ignition energy provide for a temperature of about 2,500° C., a pressure of about 100 bar, and a high flow velocity. After ignition, e.g., in a setting tool, the mixture of a combusting nitrocellulose propellant and ammoniumnitrate is intermixed during the combustion for a long time, e.g., in a swirl chamber. An extended intermixing favorably influences the combustion process. Advantageously, during the combustion process, the combustion volume is maintained substantially constant. The combustion with a substantially constant volume and a high propellant density is very favorable for conversion of the entire propellant charge. [0015]
  • According to a further advantageous embodiment of the present invention, the two chambers are separated from each other by a separating element. This simplifies the manufacturing process and, thus, facilitate the production of the inventive propellant charge batch. [0016]
  • According to another advantageous embodiment of the present invention, the separating element is formed as a disc-shaped element of a nitrocellulose board. Because the nitrocellulose board is combustible, no problem associate with a possible residue of the separation element exists. [0017]
  • According to a still further advantageous embodiment of the present invention, the propellant charge batch is formed as a blister or a blister cartridge, i.e., the socket member is formed of a blister film or foil. The formation of the batch of the blister film insures a cost-effective manufacturing of the batches. Another advantage of using a blister film consists in that the film is easily opened by the propellant upon combustion. [0018]
  • According to yet another advantageous embodiment of the present invention, the separation element is formed as a cup-shaped element of a film material, e.g., a blister film or foil. This separation element is particularly suitable for use in a blister cartridge, as the socket member and the separating element can be welded or glued to each other in their end regions, which insures a proper sealing of the two chambers relative to each other. [0019]
  • The novel features of the present invention, which are considered as characteristic for the invention, are set forth in the appended claims. The invention itself, however, both as to its construction and its mode of operation, together with additional advantages and objects thereof, will be best understood from the following detailed description of preferred embodiments, when read with reference to the accompanying drawings.[0020]
  • BRIEF DESCRIPTION OF THE DRAWINGS:
  • The drawing show: [0021]
  • FIG. 1 a longitudinal cross-sectional view of a first embodiment of a propellant charge batch according to the present invention; and [0022]
  • FIG. 2 a longitudinal cross-sectional view of a second embodiment of a propellant charge batch according to the present invention.[0023]
  • DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • A propellant charge batch according the present invention, which is shown in FIG. 1, is formed as a [0024] socket member 10 the inner space of which is divided in two chambers 11, 12. A propellant charge, which is contained in the propellant charge batch, consists of nitrocellulose means 13, e.g., a nitrocellulose powder, which is located in the chamber 11, and an ammoniumnitrate powder 14 which is located in the chamber 12. The chambers 11 and 12 are arranged one after another in an axial direction 20, with the chamber 11 being limited by the bottom 17 of the propellant charge batch. At the bottom 17, the socket member 10 is closed, preferably, by a medium/liquid tight cover 18. In the embodiment shown in FIG. 1., both the socket 10 and the socket cover 18 are formed of a plastic material. However, they also can be formed of metal or any other suitable material. It should be understood that the graininess of the ammoniumnitrate can vary from fine-grained to coarse-grained.
  • In the region of the [0025] bottom 17, the socket member 10 is provided with a salient edge region 19 with which the propellant charge batch can be supported on flanks of a cartridge support of a setting tool (not shown). In the empty space of the salient edge region, ignition means 15 is located.
  • The two [0026] chambers 11, 12 are separated from each other, in the embodiment shown in the drawing, by a medium tight separating element 16.1 formed, in the embodiment shown in FIG. 1, as a plate cut out from a nitrocellulose board.
  • Upon ignition of the propellant charge batch with the ignition means [0027] 15 which is ignited by an ignition device of the setting tool, firstly, the nitrocellulose propellant means 13 is ignited. With the ignition of the nitrocellulose propellant means 13, the separating plate 16.1 is teared open and is pressed back. The separating plate 16.1 takes part in the combustion and is completely consumed, so that no residue remains. As a result of the pressure of combustion, the propellant charge batch or cartridge opens in its front region, so that the ammoniumnitrate powder 14 becomes mixed with a remaining nitrocellulose propellant means 13, which results in an optimal combustion of the propellant charge. The intermixing of the ammoniumnitrate powder 14 with the remaining portion of the nitrocellulose propellant means 13 is enhanced by providing in the setting tool, downstream of the cartridge support, of a swirl chamber. The combustion is effected without release of toxic substances and without formation of slag.
  • During filling of the [0028] chamber 12, the ammoniumnitrate powder 14 is protected from penetration of moisture as a result of the chamber 12 being closed.
  • The propellant charge batch shown in FIG. 2 differs from that of FIG. 1, in that the [0029] socket member 10 is formed of a rigid plastic film (blister foil). The socket cover 18 is formed of a thin foil that can be, optionally, metal-plated. The separating element 16.2, which separates the chamber 11 with the nitrocellulose propellant means 13 and the chamber 12 with the ammoniumnitrate powder 14, is formed of a cup-shaped blister foil having an edge region that overlaps the edge region 19 of the socket member 10 and is welded or glued thereto. The ignition means 15 is located separately. Upon ignition of the propellant charge batch, the ignited nitrocellulose bursts the films, which form the separating element 16.2 and the socket member 10, in the front region of the chamber 11. As it was described above, the nitrocellulose propellant means 13 intermixes subsequently with the ammoniumnitrate powder 14, with the mixture having been completely combusted, without leaving any toxic reaction products.
  • When the propellant charge batches are arranged in a magazine, the [0030] edge regions 19 of the adjacent propellant charge batches are connected with each other forming a magazine strip. A cartridge according to the present invention can be also formed as a one-piece element, with the socket member having an integral bottom and with the front socket opening of the cartridge being closed and sealed.
  • Though the present invention was shown and described with references to the preferred embodiments, such are merely illustrative of the present invention and are not to be construed as a limitation thereof and various modifications of the present invention will be apparent to those skilled in the art. It is, therefore, not intended that the present invention be limited to the disclosed embodiments or details thereof, and the present invention includes all variations and/or alternative embodiments within the spirit and scope of the present invention as defined by the appended claims. [0031]

Claims (9)

What is claimed is:
1. A propellant charge batch for an explosion-operated setting tool, composing:
a socket member (10) in an inner space of which there are provided a first chamber (11) filled with a nitrocellulose propellant charge (13), and a second chamber (12) filled with an ammoniumnitrate powder (14), with at least the second chamber (12) being closed medium tightly; and
ignition means (15) for igniting the propellant charge.
2. A propellant charge batch according to claim 1, wherein the first and second chambers (11, 12) are arranged one after another in an axial direction (20) for the socket member (10).
3. A propellant charge batch according to claim 1, wherein the ignition means (15) is provided in a region of a bottom (17) of the propellant charge batch, and wherein the first chamber (11) is arranged adjacent to the ignition means (15), and the second chamber (12) is arranged remotely from the ignition means (15).
4. A propellant charge batch according to claim 1, wherein the batch is formed as a cartridge.
5. A propellant charge batch according to claim 1 further comprising an element (16.1, 16.2) for separating the first (11) and second (12) chambers.
6. A propellant charge batch according to claim 5, wherein the separating element (16.1) is disc-shaped and is formed of a nitrocellulose board.
7. A propellant charge batch according to claim 1, wherein the batch is formed as a blister.
8. A propellant charge batch according to claim 5, wherein the separating element (16.2) is cup-shaped.
9. A propellant charge batch according to claim 8, wherein the separating element (16.2) is formed of a stiff film material.
US10/851,370 2003-05-24 2004-05-21 Propellant charge batch in particular for bolt setting tools Abandoned US20040244626A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10323531A DE10323531B3 (en) 2003-05-24 2003-05-24 Propellant charge set, especially for bolt guns
DE10323531.0 2003-05-24

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US20040244626A1 true US20040244626A1 (en) 2004-12-09

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CN (1) CN100448621C (en)
DE (1) DE10323531B3 (en)
FR (1) FR2855088A1 (en)
ZA (1) ZA200403924B (en)

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US20110146520A1 (en) * 2008-06-16 2011-06-23 Rheinmetall Waffe Munition Gmbh Flare with flare ignition and ejector mechanism for the same
US20110174182A1 (en) * 2008-06-16 2011-07-21 Rheinmetall Waffe Munition Gmbh Activation unit for munition-free decoys
US8689693B2 (en) 2009-06-26 2014-04-08 Rheinmetall Waffe Munition Gmbh Active body
US8714089B2 (en) 2009-05-08 2014-05-06 Rheinmetall Waffe Munition Gmbh Activation unit for explosive masses or explosive bodies
US8763533B2 (en) 2009-06-26 2014-07-01 Rheinmetall Waffe Munition Gmbh Active body
CN104690690A (en) * 2013-12-10 2015-06-10 崴钢工业有限公司 Gunpowder nail

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DE112013007387T5 (en) * 2013-08-27 2016-05-12 Halliburton Energy Services, Inc. Encapsulated explosives for drilling wells
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CN109945231A (en) * 2017-12-20 2019-06-28 中国石油天然气集团公司 A kind of spontaneous ignition device and the method using its progress spontaneous ignition

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US20110146520A1 (en) * 2008-06-16 2011-06-23 Rheinmetall Waffe Munition Gmbh Flare with flare ignition and ejector mechanism for the same
US20110174182A1 (en) * 2008-06-16 2011-07-21 Rheinmetall Waffe Munition Gmbh Activation unit for munition-free decoys
US8695504B2 (en) 2008-06-16 2014-04-15 Rheinmetall Waffe Munition Gmbh Activation unit for munition-free decoys
US8770109B2 (en) 2008-06-16 2014-07-08 Rheinmetall Waffe Munition Gmbh Flare with flare ignition and ejector mechanism for the same
US8714089B2 (en) 2009-05-08 2014-05-06 Rheinmetall Waffe Munition Gmbh Activation unit for explosive masses or explosive bodies
US8689693B2 (en) 2009-06-26 2014-04-08 Rheinmetall Waffe Munition Gmbh Active body
US8763533B2 (en) 2009-06-26 2014-07-01 Rheinmetall Waffe Munition Gmbh Active body
CN104690690A (en) * 2013-12-10 2015-06-10 崴钢工业有限公司 Gunpowder nail

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ZA200403924B (en) 2005-05-20
CN100448621C (en) 2009-01-07
FR2855088A1 (en) 2004-11-26
CN1572431A (en) 2005-02-02

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