US20040168429A1 - Process for decreasing content of particulate material contained in exhaust gas from lean burn engine or the like - Google Patents
Process for decreasing content of particulate material contained in exhaust gas from lean burn engine or the like Download PDFInfo
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- US20040168429A1 US20040168429A1 US10/717,898 US71789803A US2004168429A1 US 20040168429 A1 US20040168429 A1 US 20040168429A1 US 71789803 A US71789803 A US 71789803A US 2004168429 A1 US2004168429 A1 US 2004168429A1
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- burn engine
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Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0892—Electric or magnetic treatment, e.g. dissociation of noxious components
Definitions
- the present invention relates to a process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like.
- this type of the particulate material has a double-layer structure comprising a carbon solid fraction (soot) and a soluble organic fraction (SOF) covering the carbon solid fraction.
- the conventionally known process has the following problems: an exhausting resistance is increased by the ceramic filter, and hence an engine output cannot be sufficiently utilized; the engine control for raising the temperature of the exhaust gas is complicated; and the filter temperature may exceed 1,000° C. in some cases during burning of the particulate material, resulting in damage to the ceramic filter.
- a process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine comprising the steps of: generating plasma in the exhaust gas discharged from the lean burn engine and containing the particulate material, to thereby produce a plurality of O( 1 D) radicals and subsequently produce a plurality of per-hydroxide excited species; and oxidizing the particulate material by the per-hydroxide excited species.
- O( 1 D) radicals and ozone excited species are produced by the collision between electrons released from electrodes and oxygen molecules
- o hydroxide excited species are produced by the reaction of O( 1 D) radicals and ozone excited species with water ⁇ per-hydroxide excited species HOO* having a strong oxidizing force are produced by the reaction of the hydroxide excited species with oxygen.
- the production of the per-hydroxide excited species is carried out independent of the temperature of the exhaust gas.
- the particulate material is oxidized and converted by the per-hydroxide excited species. The conversion of the particulate material by the oxidization is conducted continuously and at a relatively low temperature.
- a plasma generating device has a good gas permeability, as compared with a filter, so that even if the plasma generating device is incorporated in an exhaust pipe, an increase in exhausting resistance is suppressed to a low level. Therefore, an influence cannot be exerted to an engine output.
- an intensity E of electric field is set at a value equal to or larger than 3.0 kV/mm and a power density Dw is set at a value equal to or larger than 1 W/cm 3 in the plasma generating conditions, the amount of released high-energy electrons existing in the plasma is increased, and hence the production of the per-hydroxide excited species is efficiently conducted, whereby the conversion of the particulate material by the oxidization can be enhanced.
- a power density Dw is set at a value equal to or larger than 1 W/cm 3 in the plasma generating conditions
- the entire surface of the dielectric is uniformly charged upon application of a voltage. Therefore, the entire space between the dielectric and the other electrode opposed to the dielectric constitutes a plasma space, so that the frequency of random contact between the particulate material and the per-hydroxide excited species can be increased to enhance the conversion of the particulate material by the oxidization.
- opposed surfaces of the opposed electrodes are covered with dielectrics, respectively, an increase in the applied voltage is provided by an increase in impedance, but it is possible to provide a converting performance equivalent to that in the case where the one surface is covered, by setting the plasma generating conditions as described above.
- a process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like and comprising a carbon solid fraction and a soluble organic fraction covering the carbon solid fraction comprising the steps of: subjecting the soluble organic fraction to the reaction with oxygen under the presence of a catalyst to oxidize the soluble organic fraction; generating plasma in the exhaust gas to produce plasma excited species; and oxidizing the carbon solid fraction by the plasma excited species.
- the soluble organic fraction usually comprises a polycyclic aromatic hydrocarbon and the like. A large amount of oxygen is contained in the exhaust gas from the lean burn engine. Therefore, if the catalyst is present, oxygen and the soluble organic fraction are brought into contact with each other on the catalyst, whereby the soluble organic fraction is oxidized and removed. This reaction occurs even at a low temperature.
- the plasma excited species are produced by the collision between electrons released from electrodes and gas molecules.
- the plasma excited species include large numbers of O( 1 D) radicals, hydroxide excited species OH*, per-hydroxide excited species HOO* and the like each having a strong oxidizing force, and hence the carbon solid fraction is oxidized by the plasma excited species.
- the carbon solid fraction is liable to be electrically charged in the plasma, so that there is generated a phenomenon that the carbon solid fraction is oxidized efficiently in a state in which they have been collected electrostatically on the electrodes.
- the significance of the preliminary removal of the soluble organic fraction from the surface of the particulate material resides in this point.
- the conversion of the carbon solid fraction by the oxidization as described above is conducted continuously and moreover at a relatively low temperature.
- a plasma generating device has a good gas permeability, as compared with a filter, so that even if the plasma generating device is incorporated in an exhaust pipe, an increase in exhausting resistance is suppressed to a low level. Therefore, an influence cannot be exerted to an engine output.
- At least one selected from the group consisting of Pt, Pd, Rh, Cu, Ag and Au is used as the catalyst.
- an intensity E of electric field is set at a value equal to or larger than 3.0 kV/mm and a power density Dw is set at a value equal to or larger than 1 W/cm 3 in the plasma generating conditions, the amount of released high-energy electrons existing in the plasma is increased, and hence the production of the plasma excited species is efficiently conducted, whereby the conversion of the carbon solid fraction by the oxidization can be enhanced.
- a power density Dw is set at a value equal to or larger than 1 W/cm 3 in the plasma generating conditions
- the entire surface of the dielectric is uniformly charged upon application of a voltage. Therefore, the entire space between the dielectric and the other electrode opposed to the dielectric constitutes a plasma space, so that the frequency of random contact between the carbon solid fraction and the plasma excited species can be increased to enhance the conversion of the carbon solid fraction by the oxidization. If opposed surfaces of the opposed electrodes are covered with dielectrics, respectively, an increase in the applied voltage is brought about with an increase in impedance, but it is possible to provide a converting performance equivalent to that in the case where the one surface is covered, by setting the plasma generating conditions as described above.
- a process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like comprising the steps of: generating plasma in the exhaust gas discharged from the lean burn engine and containing the particulate material to produce a plurality of nitrogen dioxide molecules and a plurality of ozone molecules; and oxidizing the particulate material by the nitrogen dioxide molecules and the ozone molecules.
- oxygen atom excited species are produced by the collision between released electrons and oxygen molecules
- ⁇ ozone is produced by the reaction of the oxygen atom excited species with oxygen molecules
- NO 2 nitrogen dioxide
- the productions of the nitrogen dioxide and ozone are-carried out independent of the temperature of the exhaust gas.
- the particulate material PM is oxidized and converted based on the reaction represented by PM+NO 2 +O 3 ⁇ CO 2 +H 2 O+N 2 .
- the conversion of the particulate material by the oxidization is conducted continuously and moreover at a relatively low temperature.
- a plasma generating device has a good gas permeability, as compared with a filter, so that even if the plasma generating device is incorporated in an exhaust pipe, an increase in exhausting resistance is suppressed to a low level. Therefore, an influence cannot be exerted to an engine output.
- a process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine comprising the steps of: generating plasma in the exhaust gas discharged from the lean burn engine and containing the particulate material to produce a plurality of nitrogen dioxide molecules and a plurality of ozone molecules; oxidizing the particulate material by the nitrogen dioxide molecules and the ozone molecules; and subjecting the particulate material to the reaction with the nitrogen dioxide molecules and the ozone molecules in the presence of a catalyst to oxidize the particulate material.
- the above-described reaction namely, the reaction represented by PM+NO 2 +O 3 ⁇ CO 2 +H 2 O+N 2 can be promoted to greatly increase the decrement rate of the particulate material.
- At least one selected from the group consisting of Pt, Pd, Rh, Cu, Ag and Au is used as the catalyst.
- an intensity E of electric field is set at a value equal to or larger than 3.0 kV/mm and a power density Dw is set at a value equal to or larger than 1 W/cm 3 in the plasma generating conditions, the amount of released high-energy electrons existing in the plasma is increased, and hence the productions of the nitrogen dioxide and ozone are efficiently conducted, whereby the conversion of the carbon solid fraction by the oxidization can be enhanced.
- a power density Dw is set at a value equal to or larger than 1 W/cm 3 in the plasma generating conditions
- the entire surface of the dielectric is uniformly charged upon application of a voltage. Therefore, the entire space between the dielectric and the other electrode opposed to the dielectric constitutes a plasma space, so that the frequency of random contact of the particulate material with the nitrogen dioxide and ozone can be increased to enhance the conversion of the carbon solid fraction by the oxidization.
- opposed surfaces of the opposed electrodes are covered with dielectrics, respectively, an increase in the, applied voltage is provided by an increase in impedance, but it is possible to provide a converting performance equivalent to that in the case where the one surface is covered, by setting the plasma generating conditions as described above.
- FIG. 1 is an illustration of a first embodiment of an equipment for a particulate material content decreasing test.
- FIG. 2 is a diagram of a plasma generating device.
- FIG. 3 is a graph showing amounts of a particulate material before and after a plasma treatment.
- FIG. 4 is an illustration of a second embodiment of an equipment for a particulate material content decreasing test.
- FIG. 5 is a graph showing amounts of a particulate material before and after a catalytic reaction and after a plasma treatment for Example 4.
- FIG. 6 is a graph showing amounts of a particulate material before and after a catalytic reaction and after a plasma treatment for Example 5.
- FIG. 7 is an illustration of a third embodiment of an equipment for a particulate material content decreasing test.
- FIG. 8 is a graph showing amounts of a particulate material before and after a plasma treatment and after a catalytic reaction for Example 6.
- FIG. 9 is a graph showing amounts of a particulate material before and after a plasma treatment and after a catalytic reaction for Example 7.
- a commercially available diesel generator 2 is selected as a source of generating an exhaust gas containing a particulate material.
- a first flow rate regulating valve 4 is mounted in an exhaust pipe 3 of the diesel generator 2 .
- a conduit 5 is connected at one end between the diesel generator 2 and the first flow rate regulating valve 4 1 .
- a second flow rate regulating valve 4 2 , a heater 6 , a plasma generating device PG and a flow-meter 8 are mounted in the exhaust pipe 3 sequentially in the named order from the side of the exhaust pipe 3 .
- the other end of the conduit 5 opens to the atmosphere.
- a first branch pipe 9 1 is connected at one end between the heater 6 and the plasma generating device PG, and at the other end to a first port p 1 of a three-way valve 10 .
- a second branch pipe 9 2 is also connected at one end between the plasma generating device PG and the flow-meter 8 , and at the other end to a second port p 2 of the three-way valve 10 .
- Another conduit 11 is connected at one end to a third port p 3 of the three-way valve 10 , and at the other end to a suction port of a suction pump 12 .
- a filter 13 is mounted in the conduit 11 .
- the diesel generator 2 is EXT12D made by Hyundai Motor Co., Ltd., and the specification thereof is as follows: the type of an engine: a water-cooled 3-cylinder and 4-cycle diesel engine; a total displacement: 1061 cc; a fuel used: diesel light oil; a rated output: 12 kVA.
- the filter 13 is a Teflon-coated filter made by German Laboratory, and has a mesh size of 0.3 ⁇ m mesh.
- the plasma generating device PG includes a plurality of first to sixth electrodes 14 , to 14 6 made of a metal, each of which is formed into a plate shape in the illustrated embodiment.
- the first to sixth electrodes 14 , to 14 6 are mounted in a housing 15 (see FIG. 1) so that they are parallel to a direction A of flowing of an exhaust gas, and the adjacent electrodes 14 1 and 14 2 ; 14 2 and 14 3 ; 14 3 and 14 4 ; 14 4 and 14 5 ; 14 5 and 14 6 are opposed to each other.
- the surface of the first electrode 14 1 located at one end, which is opposed to the second electrode 14 2 , is a non-coated metal surface, but the surface of the second electrode 14 2 , which is opposed to the first electrode 14 1 , is coated entirely with a dielectric 16 .
- the arrangement relationship between the opposed surfaces of the first and second electrodes 14 1 and 14 2 applies to those between the second and third electrodes 14 2 and 14 3 ; between the third and fourth electrodes 14 3 and 14 4 ; between the fourth and fifth electrodes 14 4 and 14 5 ; and between the fifth and sixth electrodes 14 5 and 14 6 .
- the first, third and fifth electrodes 14 1 , 14 3 and 14 5 are connected to a power source 18 through lead wires 17 , while the second, fourth and sixth electrodes 14 2 , 14 4 and 14 6 are earthed through lead wires 19 .
- the entire surface of each of the dielectrics 16 is uniformly charged upon application of a voltage, and hence the entire space between each of the dielectrics 16 and each of the electrodes 14 1 to 14 6 which is opposed thereto constitutes a plasma space Pp.
- the plasma spaces Pp are formed between the first and second electrodes 14 1 and 14 2 ; between the second and third electrodes 14 2 and 14 3 ; between the third and fourth electrodes 14 3 and 14 4 ; between the fourth and fifth electrodes 14 4 and 14 5 ; and between the fifth and sixth electrodes 14 5 and 14 6. That is, each of the plasma spaces Pp is defined by the opposed electrodes.
- Each of the first to sixth electrodes 14 1 to 14 6 is formed of a stainless steel (e.g., JIS SUS316), and has a size of 20 mm long, 50 mm wide and 1.0 mm thick, with a transverse side extending along the exhaust gas flowing direction A.
- Each of the dielectrics 16 comprises an alumina (Al 2 O 3 ) layer having a thickness of 0.5 mm, which is bonded to each of the second to sixth electrodes 14 2 to 14 6 by the mechanical pressing. The adhesion using an adhesive, the flame spraying or the like may be also utilized for such bonding.
- a gap g in each of the plasma spaces Pp namely, a distance between each of the adjacent electrodes 14 1 to 14 6 and each of the dielectrics 16 is 0.5 mm.
- a particulate material content reducing test was carried out using the above-described equipment 1 , according to the following procedure:
- the heater 6 was operated to heat the exhaust gas having a temperature of about 70° C. up to 150° C., and the exhaust gas was allowed to flow through the first and third ports p 1 and p 3 of the three-way valve 10 . Then, the testing exhaust gas flowing through the conduit 5 was diverted into the first branch pipe 9 1 by driving the suction pump 12 at a suction rate of 5.0 L/min, and caused to flow through the filter 13 over 10 minutes, whereby a particulate material in the testing exhaust gas was collected by the filter 13 . A weight of the particulate material collected was determined from the weights of the filter before and after the collection of the particulate material, and defined as an amount of the particulate material before a plasma treatment.
- Table 1 shows plasma generating conditions for Examples 1 to 3.
- TABLE 1 Plasma space Electricity input conditions Intensity E Gap Volume Alternate Frequency Voltage of electric field Power density Example (mm) (cm 3 ) current (Hz) (kVp-p) Power (W) (kV/mm) Dw (W/cm 3 ) 1 0.5 2.5 Sine wave 300 3.0 2.7 3.0 1.1 AC 2 1.5 7.5 Sine wave 700 8.2 9.1 2.7 1.2 AC 3 0.5 2.5 Sine wave 100 3.0 2.1 3.0 0.8 AC
- the intensity E of electric field is a value provided by dividing a voltage [(kV p-p )/2] applied between the opposed electrodes such as between the first and second electrodes 14 1 and 14 2 by the gap g (mm)
- Table 2 shows amounts of the particulate material before and after the plasma treatment, and decrement amounts and decrement rates of the particulate material decreased by the plasma treatment for Examples 1 to 3.
- Particulate material Amount (mg) Amount (mg) before plasma after plasma Decrement Decrement treatment treatment amount (mg) rate (%)
- Example 1 1.3 0.2 1.1 84.6
- Example 2 1.2 0.7 0.5 41.7
- Example 3 1.4 0.8 0.6 42.9
- FIG. 3 is a graph based on Table 2 and showing amounts of the particulate material before and after the plasma treatment for Examples 1 to 3.
- per-hydroxide excited species HOO* can be efficiently produced by setting the intensity E of electric field at a value equal to or larger than 3.0 kV/mm and the power density Dw at a value equal to or larger than 1 W/cm 3 , whereby the decrement rate of the particulate material can be increased to about 84.6%.
- the intensityE of electric field is preferably in a range of 3 kV/mm ⁇ E ⁇ 15 kV/mm
- the power density Dw is preferably in a range of 1 W/cm 3 ⁇ Dw ⁇ 10 W/cm 3 .
- the decrement rate of the particulate material is lower and approximately half of that in Example 1, because one of the intensity E of electric field and the power density Dw dose not satisfies the above-described requirement.
- Embodiment I is applicable for decreasing the content of a particulate material contained in an exhaust gas discharged from an automobile, a factory or the like.
- a commercially available diesel generator 2 is selected as a source of generating an exhaust gas containing a particulate material.
- a first flow rate regulating valve 4 1 is mounted in an exhaust pipe 3 of the diesel generator 2 .
- a conduit 5 is connected at one end between the diesel generator 2 and the first flow rate regulating valve 4 1 , and a second flow rate regulating valve 4 2 , a heater 6 , a catalytic reactor CR, a plasma generating device PG and a flow-meter 8 are mounted on the exhaust pipe 3 sequentially in the named order from the side of the exhaust pipe 3 .
- the other end of the conduit 5 opens to the atmosphere.
- a first branch pipe 9 1 is connected at one end between the heater 6 and the catalytic reactor CR, and at the other end to a suction port of a suction pump 12 .
- a first on-off valve 20 1 and a filter 13 are mounted in the first branch pipe 9 1 sequentially from the side of the conduit 5 .
- a second branch pipe 9 2 is also connected at one end between the catalytic reactor CR and the plasma generating device PG, and at the other end between the first on-off valve 20 1 and the filter 13 in the first branch pipe 9 1 .
- a second on-off valve 20 2 is mounted in the second branch pipe 9 2 .
- a third branch pipe 9 3 is connected at one end between the plasma generating device PG and the flow-meter 8 , and at the other end between a connection of the second branch pipe 9 2 and the filter 13 in the first branch pipe 9 1 .
- a third on-off valve 20 3 is mounted in the third branch pipe 9 3 .
- the diesel generator 2 is EXT12D made by Hyundai Motor Co. Ltd., and the specification thereof is as follows: the type of an engine: a water-cooled 3-cylinder and 4-cycle diesel engine; a total displacement: 1061 cc; a fuel used: diesel light oil; a rated output: 12 kVA.
- the filter 13 is a Teflon-coated filter made by German Laboratory, and has a mesh size of 0.3 ⁇ m mesh.
- the plasma generating device PG has the same structure as that in Embodiment I and includes a plurality of first to sixth electrodes 14 1 to 14 6 made of a metal, each of which is formed into a plate shape in the illustrated embodiment.
- the first to sixth electrodes 14 1 to 14 6 are mounted in a housing 15 (see FIG. 4) so that they are parallel to a direction A of flowing of an exhaust gas, and the adjacent electrodes 14 1 and 14 2 ; 14 2 and 14 3 ; 14 3 and 14 4 ; 14 4 and 14 5 ; 14 5 and 14 6 are opposed to each other.
- the surface of the first electrode 14 1 located at one end, which is opposed to the second electrode 14 2 , is a non-coated metal surface, but the surface of the second electrode 14 2 , which is opposed to the first electrode 14 1 , is coated entirely with a dielectric 16 .
- the arrangement relationship between the opposed surfaces of the first and second electrodes 14 1 and 14 2 applies to those between the second and third electrodes 14 2 and 14 3 ; between the third and fourth electrodes 14 3 and 14 4 ; between the fourth and fifth electrodes 14 4 and 14 5 ; and between the fifth and sixth electrodes 14 5 and 14 6 .
- the first, third and fifth electrodes 14 1 , 14 3 and 14 5 are connected to a power source 18 through lead wires 17 , while the second, fourth and sixth electrodes 14 2 , 14 4 and 14 6 are earthed through lead wires 19 .
- the entire surface of each of the dielectrics 16 is uniformly charged upon application of a voltage, and hence the entire space between each of the dielectrics 16 and each of the electrodes 14 1 to 14 6 which is opposed thereto constitutes a plasma space Pp.
- the plasma spaces Pp are formed between the first and second electrodes 14 1 and 14 2 ; between the second and third electrodes 14 2 and 14 3 ; between the third and fourth electrodes 14 3 and 14 4 ; between the fourth and fifth electrodes 14 4 and 14 5 ; and between the fifth and sixth electrodes 14 5 and 14 6 . That is, each of the plasma spaces Pp is defined by the opposed electrodes.
- Each of the first to sixth electrodes 14 1 to 14 6 is formed of a stainless steel (e.g., JIS SUS316), and has a size of 20 mm long, 50 mm wide and 1.0 mm thick, with a transverse side extending along the exhaust gas flowing direction A.
- Each of the dielectrics 16 comprises an alumina (Al 2 O 3 ) layer having a thickness of 0.5 mm, which is bonded to each of the second to sixth electrodes 14 2 to 14 6 by the mechanical pressing. The adhesion using an adhesive, the flame spraying or the like may be also utilized for such bonding.
- a gap g in each of the plasma spaces Pp namely, a distance between each of the adjacent electrodes 14 1 to 14 6 and each of the dielectric 16 is 0.5 mm.
- the catalytic reactor CR comprises a honeycomb carrier and platinum (Pt) carried as a catalyst on the honeycomb carrier, and is placed in a housing 21 .
- platinum platinum
- the following process was adopted: (i) 80 grams of a solution of platinum dinitrodiamine nitric acid [Pt(NH 3 ) 2 (NO 2 ) 2 .HNO 3 ] containing 5% by weight of platinum, 96 grams of commercially available ⁇ -Al 2 O 3 , and 1,000 grams of ion-exchange water were mixed together, and at the same time, an excessive amount of water was removed; (ii) a mixture was dried at 200° C.
- a powder of Al 2 O 3 carrying platinum was produced by calcining the mixture at 600° C. for 2 hours;
- a powder of Al 2 O 3 carrying platinum was produced by calcining the mixture at 600° C. for 2 hours;
- a slurry was prepared by wet-pulverizing the mixture over 12 hours using alumina balls;
- a honeycomb carrier carrying a platinum catalyst in an amount of 4 g/L at a wash coat amount of 100 g/L was prepared by repeating a process: immersing a honeycomb carrier made-of cordierite and having a volume of about 30 L (a diameter of 2.54 and a length of 60 mm) with 400 cells/in 2 and 6 mils into the slurry; removing an excessive amount of the slurry from the carrier by jet water injection after the removal of the carrier;
- This type of catalytic reactor CR has a structure substantially same as that of a catalytic converter, and hence the exhausting resistance cannot be greatly increased.
- the heater 6 was operated to heat the exhaust gas having a temperature of about 70° C. up to 150° C., and the first on-off valve 20 1 was opened, while the second and third on-off valves 20 2 and 20 3 were closed. Then, the testing exhaust gas flowing through the conduit 5 was diverted into the first branch pipe 9 1 by driving the suction pump 12 at a suction rate of 5.0 L/min, and caused to flow through the filter 13 over 20 minutes, whereby a particulate material in the testing exhaust gas was collected by the filter 13 .
- a weight of the particulate material collected was determined from the weights of the filter before and after the collection of the particulate material, and was defined as an amount of the particulate material before a catalytic reaction.
- the plasma generating device PG was operated, and the third on-off valve 20 3 was opened, while the first and second on-off valves 20 1 and 20 2 were closed. Then, the testing exhaust gas flowing through the conduit 5 via the catalytic reactor CR and the plasma generating device PG, was diverted into the third branch pipe 9 3 by driving the suction pump 12 at a suction rate of 5.0 L/min, and caused to flow through a new filter 13 over 20 minutes, whereby the particulate material in the testing exhaust gas was collected by the new filter 13 .
- a weight of the particulate material collected was determined from the weights of the filter before and after the collection of the particulate material, and defined as an amount of the particulate material after the plasma treatment.
- Example 4 The process using platinum as the catalyst as described above is defined as Example 4.
- Example 5 A particulate material content-decreasing test was carried out as Example 5 in a similar manner, except that a catalytic reactor CR having silver (Ag) as a catalyst was used, and the temperature of an exhaust gas flowing into the plasma generating device PG was set at 250° C.
- a catalytic reactor CR having silver (Ag) as a catalyst was used, and the temperature of an exhaust gas flowing into the plasma generating device PG was set at 250° C.
- this process was the same as Example 3, except that a mixture comprising 4.72 grams of silver nitrate (AgNO 3 ), 97 grams of commercially available ⁇ -Al 2 O 3 , and 1,000 grams of ion-exchange water were used as a silver-containing solution, and the amount of silver carried on the honeycomb carrier was set at 3 g/L.
- the plasma excited species include O( 1 D) radicals, hydroxide excited species OH*, per-hydroxide excited species HOO* and the like.
- Table 3 shows plasma generating conditions for Examples 4 and 5.
- TABLE 3 Plasma space Electricity input conditions Intensity E Gap Volume Alternate Frequency Voltage of electric field Power density Example (mm) (cm 3 ) current (Hz) (kVp-p) Power (W) (kV/mm) Dw (W/cm 3 ) 4 0.5 2.5 Sine wave 2,500 7.6 7.4 7.6 3.0 AC 5 0.5 2.5 Sine wave 1,600 7.2 9.5 7.2 3.8 AC
- Table 4 shows amounts of the particulate material before and after the catalytic reaction and after the plasma treatment, and decrement amounts and decrement rates of the particulate material decreased by the catalytic reaction and the plasma treatment for Examples 4 and 5.
- TABLE 4 Particulate material Amount before After catalytic reaction After plasma treatment catalytic Decrement Decrement reaction Amount amount Decrement amount Decrement Example (mg) (mg) (mg) rate(%) Amount (mg) (mg) rate (%) 4 2.6 1.9 0.7 26.9 0.2 2.4 92.3 5 2.4 1.7 0.7 29.2 0.2 2.2 91.7
- FIGS. 5 and 6 are graphs based on Table 4 and showing amounts of the particulate material before and after the catalytic reaction and after the plasma treatment for Examples 4 and 5.
- plasma excited species can be efficiently produced by setting the intensity E of electric field at a value equal to or larger than 3.0 kV/mm and setting the power density Dw at a value equal to or larger than 1 W/cm 3 , whereby the decrement rate of the particulate material can be increased up to about 92% or more.
- the intensity E of electric field is preferably in a range of 3 kV/mm ⁇ E ⁇ 15 kV/mm
- the power density Dw is preferably in a range of 1 W/cm 3 ⁇ Dw ⁇ 10 W/cm 3 .
- Embodiment II is applicable for decreasing the content of a particulate material contained in an exhaust gas discharged from an automobile, a factory or the like.
- a commercially available diesel generator 2 is selected as a source of generating an exhaust gas containing a particulate material.
- a first flow rate regulating valve 4 1 is mounted in an exhaust pipe 3 of the diesel generator 2 .
- a conduit 5 is connected at one end between the diesel generator 2 and the first flow rate regulating valve 4 1 , and a second flow rate regulating valve 4 2 , a heater 6 , a plasma generating device PG, a catalytic reactor CR and a flow-meter 8 are mounted on the exhaust pipe 3 sequentially in the named order from the side of the exhaust pipe 3 .
- the other end of the conduit 5 opens to the atmosphere.
- a first branch pipe 9 1 is connected at one end between the heater 6 and the plasma generating device PG, and at the other end to a suction port of a suction pump 12 .
- a first on-off valve 20 1 and a filter 13 are mounted in the first branch pipe 9 1 sequentially from the side of the conduit 5 .
- a second branch pipe 9 2 is also connected at one end between the plasma generating device PG and the catalytic reactor CR, and at the other end between the first on-off valve 20 1 and the filter 13 in the first branch pipe 9 1 .
- a second on-off valve 20 2 is mounted in the second branch pipe 9 2 .
- a third branch pipe 9 3 is connected at one end between the catalytic reactor CR and the flow-meter 8 , and at the other end between a connection of the second branch pipe 9 2 and the filter 13 in the first branch pipe 9 1 .
- a third on-off valve 20 3 is mounted in the third branch pipe 9 3 .
- the diesel generator 2 is EXT12D made by Hyundai Motor Co. Ltd., and the specification thereof is as follows: the type of an engine: a water-cooled 3-cylinder and 4-cycle diesel engine; a total displacement: 1061 cc; a fuel used: diesel light oil; a rated output: 12 kVA.
- the filter 13 is a Teflon-coated filter made by German Laboratory, and has a mesh size of 0.3 ⁇ m mesh.
- the plasma generating device PG has the same structure as that in Embodiments I and II, and includes a plurality of first to sixth electrodes 14 1 to 14 6 made of a metal, each of which is formed into a plate shape in the illustrated embodiment.
- the first to sixth electrodes 14 1 to 14 6 are mounted in a housing 15 (see FIG. 7) so that they are parallel to a direction A of flowing of an exhaust gas, and the adjacent electrodes 14 1 and 14 2 ; 14 2 and 14 3 ; 14 3 and 14 4 ; 14 4 and 14 5 ; 14 5 and 14 6 are opposed to each other.
- the surface of the first electrode 14 1 located at one end, which is opposed to the second electrode 14 2 , is a non-coated metal surface, but the surface of the second electrode 14 2 , which is opposed to the first electrode 14 1 , is coated entirely with a dielectric 16 .
- the arrangement relationship between the opposed surfaces of the first and second electrodes 14 1 and 14 2 applies to those between the second and third electrodes 14 2 and 14 3 ; between the third and fourth electrodes 14 3 and 14 4 ; between the fourth and fifth electrodes 14 4 and 14 5 ; and between the fifth and sixth electrodes 14 5 and 14 6 .
- the first, third and fifth electrodes 14 1 , 14 3 and 14 5 are connected to a power source 18 through lead wires 17 , while the second, fourth and sixth electrodes 14 2 , 14 4 and 14 6 are earthed through lead wires 19 .
- the entire surface of each of the dielectrics 16 is uniformly charged upon application of a voltage, and hence the entire space between each of the dielectrics 16 and each of the electrodes 14 1 to 14 6 which is opposed thereto constitutes a plasma space Pp.
- the plasma spaces Pp are formed between the first and second electrodes 14 1 and 14 2 ; between the second and third electrodes 14 2 and 14 3 ; between the third and fourth electrodes 14 3 and 14 4 ; between the fourth and fifth electrodes 14 4 and 14 5 ; and between the fifth and sixth electrodes 14 5 and 14 6 . That is, each of the plasma spaces Pp is defined by the opposed electrodes.
- Each of the first to sixth electrodes 14 1 to 14 6 is formed of a stainless steel (e.g., JIS SUS316), and has a size of 20 mm long, 50 mm wide and 1.0 mm thick, with a transverse side extending along the exhaust gas flowing direction A.
- Each of the dielectrics 16 comprises an alumina (Al 2 O 3 ) layer having a thickness of 0.5 mm, which is bonded to each of the second to sixth electrodes 14 2 to 14 6 by the mechanical pressing. The adhesion using an adhesive, the flame spraying or the like may be also utilized for such bonding.
- a gap g in each of the plasma spaces Pp namely, a distance between each of the adjacent electrodes 14 1 to 14 6 and each of the dielectric 16 is 0.5 mm.
- the catalytic reactor CR comprises a honeycomb carrier and platinum (Pt) carried as a catalyst on the honeycomb carrier, and is placed in a housing 21 .
- platinum platinum
- the following process was adopted: (i) 80 grams of a solution of platinum dinitrodiamine nitric acid (Pt(NH 3 ) 2 (NO 2 ) 2 .HNO 3 ] containing 5% by weight of platinum, 96 grams of commercially available ⁇ -Al 2 O 3 , and 1,000 grams of ion-exchange water were mixed together, and at the same time, an excessive amount of water was removed; (ii) a mixture was dried at 200° C.
- a powder of Al 2 O 3 carrying platinum was produced by calcining the mixture at 600° C. for 2 hours;
- a powder of Al 2 O 3 carrying platinum was produced by calcining the mixture at 600° C. for 2 hours;
- a slurry was prepared by wet-pulverizing the mixture over 12 hours using alumina balls;
- a honeycomb carrier carrying a platinum catalyst in an amount of 4 g/L at a wash coat amount of 100 g/L was prepared by repeating a process: immersing a honeycomb carrier made of cordierite and having a volume of about 30 L (a diameter of 2.54 and a length of 60 mm) with 400 cells/in 2 and 6 mils into the slurry; removing an excessive amount of the slurry from the carrier by jet water injection after the removal of the carrier; and drying the carrier at 150° C. for 1 hour;
- This type of catalytic reactor CR has a structure substantially same as that of a catalytic converter, and hence the exhausting resistance cannot be greatly increased.
- the heater 6 was operated to heat the exhaust gas having a temperature of about 70° C. up to 150° C., and the first on-off valve 20 1 was opened, while the second and third on-off valves 20 2 and 20 3 were closed. Then, the testing exhaust gas flowing through the conduit 5 was diverted into the first branch pipe 9 1 by driving the suction pump 12 at a suction rate of 5.0 L/min, and caused to flow through the filter 13 over 20 minutes, whereby a particulate material in the testing exhaust gas was collected by the filter 13 .
- a weight of the particulate material collected was determined from the weights of the filter before and after the collection of the particulate material, and was defined as an amount of the particulate material before a catalytic reaction.
- Example 7 A particulate material content-decreasing test was carried out as Example 7 in a similar manner, except that a catalytic reactor CR having silver (Ag) as a catalyst was used, and the temperature of an exhaust gas flowing into the plasma generating device PG was set at 250° C.
- a catalytic reactor CR having silver (Ag) as a catalyst was used, and the temperature of an exhaust gas flowing into the plasma generating device PG was set at 250° C.
- this process was the same as Example 6, except that a mixture comprising 4.72 grams of silver nitrate (AgNO 3 ), 97 grams of commercially available ⁇ -Al 2 O 3 , and 1,000 grams of ion-exchange water were used as a silver-containing solution, and the amount of silver carried on the honeycomb carrier was set at 3 g/L.
- Table 5 shows plasma generating conditions for Examples 6 and 7. TABLE 5 Plasma space Electricity input conditions Intensity E Gap Volume Alternate Frequency Voltage of electric field Power density Example (mm) (cm 3 ) current (Hz) (kVp-p) Power (W) (kV/mm) Dw (W/cm 3 ) 6 0.5 2.5 Sine wave 200 7.6 3.1 7.6 1.2 AC 7 0.5 2.5 Sine wave 500 6.6 8.5 6.6 3.4 AC
- Table 6 shows amounts of the particulate material before and after the plasma treatment and after the catalytic reaction, and decrement amounts and decrement rates of the particulate material decreased by the plasma treatment and the catalytic reaction for Examples 6 and 7.
- TABLE 6 Particulate material Amount before After plasma treatment After catalytic reaction plasma Decrement Decrement treatment Amount amount Decrement amount Decrement Example (mg) (mg) (mg) rate % Amount (mg) (mg) rate (%) 6 2.5 0.4 2.1 84.0 0.1 2.4 96.0 7 2.3 0.3 2.0 87.0 0.1 2.2 95.7
- FIGS. 8 and 9 are graphs based on Table 6 and showing amounts of the particulate material before and after the plasma treatment and after the catalytic reaction for Examples 6 and 7.
- nitrogen dioxide and ozone can be efficiently produced by setting the intensity E of electric field at a value equal to or larger than 3.0 kV/mm and setting the power density Dw at a value equal to or larger than 1 W/cm 3 , whereby the decrement rate of the particulate material can be increased up to about 84% or more.
- the intensity E of electric field is preferably in a range of 3 kV/mm ⁇ E ⁇ 15 kV/mm, and the power density Dw is preferably in a range of 1 W/cm 3 ⁇ Dw ⁇ 10 W/cm 3 . Further, the decrement rate of the particulate material can be further increased up to approximately 96% by carrying out the catalytic reaction.
- Embodiment III is applicable for decreasing the content of a particulate material contained in an exhaust gas discharged from an automobile, a factory or the like.
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Abstract
To decrease the content of a particulate material contained in an exhaust gas from a diesel engine or the like, the content of the particulate material is continuously decreased by generating plasma in the exhaust gas containing the particulate material to thereby produce a plurality of O(1D) radicals and subsequently produce a plurality of per-hydroxide excited species, and oxidizing the particulate material by the per-hydroxide excited species.
Description
- 1. Field of the Invention
- The present invention relates to a process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like.
- It is known that this type of the particulate material has a double-layer structure comprising a carbon solid fraction (soot) and a soluble organic fraction (SOF) covering the carbon solid fraction.
- 2. Description of the Related Art
- There is a conventionally known process for decreasing the content of a particulate material contained in an exhaust gas, for example, from a diesel engine or the like, in which a ceramic filter (diesel particulate filter) is placed into an exhaust pipe to collect the particulate material in the filter, and when an amount of the particulate material collected reaches a predetermined value, the temperature of the exhaust gas is raised by an engine control, thereby burning the particulate material.
- However, the conventionally known process has the following problems: an exhausting resistance is increased by the ceramic filter, and hence an engine output cannot be sufficiently utilized; the engine control for raising the temperature of the exhaust gas is complicated; and the filter temperature may exceed 1,000° C. in some cases during burning of the particulate material, resulting in damage to the ceramic filter.
- Accordingly, it is an object of the present invention to provide a process for decreasing the content of a particulate material, which is capable of continuously converting the particulate material by the oxidization thereof to remarkably decrease the content thereof, and of suppressing an increase in exhausting resistance to a low level.
- To achieve the above object, according to the present invention, there is provided a process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine, comprising the steps of: generating plasma in the exhaust gas discharged from the lean burn engine and containing the particulate material, to thereby produce a plurality of O(1D) radicals and subsequently produce a plurality of per-hydroxide excited species; and oxidizing the particulate material by the per-hydroxide excited species.
- When the plasma is generated in the exhaust gas, the following process is provided: O(1D) radicals and ozone excited species are produced by the collision between electrons released from electrodes and oxygen molecules o hydroxide excited species are produced by the reaction of O(1D) radicals and ozone excited species with water→per-hydroxide excited species HOO* having a strong oxidizing force are produced by the reaction of the hydroxide excited species with oxygen. The production of the per-hydroxide excited species is carried out independent of the temperature of the exhaust gas. The particulate material is oxidized and converted by the per-hydroxide excited species. The conversion of the particulate material by the oxidization is conducted continuously and at a relatively low temperature.
- A plasma generating device has a good gas permeability, as compared with a filter, so that even if the plasma generating device is incorporated in an exhaust pipe, an increase in exhausting resistance is suppressed to a low level. Therefore, an influence cannot be exerted to an engine output.
- If an intensity E of electric field is set at a value equal to or larger than 3.0 kV/mm and a power density Dw is set at a value equal to or larger than 1 W/cm3 in the plasma generating conditions, the amount of released high-energy electrons existing in the plasma is increased, and hence the production of the per-hydroxide excited species is efficiently conducted, whereby the conversion of the particulate material by the oxidization can be enhanced. However, if at least one of requirements of E≧3.0 kV/mm and Dw≧1 W/cm3 is lacked, the above-described effect cannot be obtained.
- Further, if the surface of at least one of opposed electrodes which is opposed to the other electrodes is covered with a dielectric, the entire surface of the dielectric is uniformly charged upon application of a voltage. Therefore, the entire space between the dielectric and the other electrode opposed to the dielectric constitutes a plasma space, so that the frequency of random contact between the particulate material and the per-hydroxide excited species can be increased to enhance the conversion of the particulate material by the oxidization. If opposed surfaces of the opposed electrodes are covered with dielectrics, respectively, an increase in the applied voltage is provided by an increase in impedance, but it is possible to provide a converting performance equivalent to that in the case where the one surface is covered, by setting the plasma generating conditions as described above.
- According to the present invention, there is also provided a process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like and comprising a carbon solid fraction and a soluble organic fraction covering the carbon solid fraction, the process comprising the steps of: subjecting the soluble organic fraction to the reaction with oxygen under the presence of a catalyst to oxidize the soluble organic fraction; generating plasma in the exhaust gas to produce plasma excited species; and oxidizing the carbon solid fraction by the plasma excited species.
- The soluble organic fraction usually comprises a polycyclic aromatic hydrocarbon and the like. A large amount of oxygen is contained in the exhaust gas from the lean burn engine. Therefore, if the catalyst is present, oxygen and the soluble organic fraction are brought into contact with each other on the catalyst, whereby the soluble organic fraction is oxidized and removed. This reaction occurs even at a low temperature.
- When the plasma is generated in the exhaust gas, the plasma excited species are produced by the collision between electrons released from electrodes and gas molecules. The plasma excited species include large numbers of O(1D) radicals, hydroxide excited species OH*, per-hydroxide excited species HOO* and the like each having a strong oxidizing force, and hence the carbon solid fraction is oxidized by the plasma excited species. The carbon solid fraction is liable to be electrically charged in the plasma, so that there is generated a phenomenon that the carbon solid fraction is oxidized efficiently in a state in which they have been collected electrostatically on the electrodes. The significance of the preliminary removal of the soluble organic fraction from the surface of the particulate material resides in this point. The conversion of the carbon solid fraction by the oxidization as described above is conducted continuously and moreover at a relatively low temperature.
- A plasma generating device has a good gas permeability, as compared with a filter, so that even if the plasma generating device is incorporated in an exhaust pipe, an increase in exhausting resistance is suppressed to a low level. Therefore, an influence cannot be exerted to an engine output.
- At least one selected from the group consisting of Pt, Pd, Rh, Cu, Ag and Au is used as the catalyst.
- If an intensity E of electric field is set at a value equal to or larger than 3.0 kV/mm and a power density Dw is set at a value equal to or larger than 1 W/cm3 in the plasma generating conditions, the amount of released high-energy electrons existing in the plasma is increased, and hence the production of the plasma excited species is efficiently conducted, whereby the conversion of the carbon solid fraction by the oxidization can be enhanced. However, if at least one of requirements of E≧3.0 kV/mm and Dw≧1 W/cm3 is lacked, the above-described effect cannot be obtained.
- Further, if the surface of at least one of opposed electrodes which is opposed to the other electrodes is covered with a dielectric, the entire surface of the dielectric is uniformly charged upon application of a voltage. Therefore, the entire space between the dielectric and the other electrode opposed to the dielectric constitutes a plasma space, so that the frequency of random contact between the carbon solid fraction and the plasma excited species can be increased to enhance the conversion of the carbon solid fraction by the oxidization. If opposed surfaces of the opposed electrodes are covered with dielectrics, respectively, an increase in the applied voltage is brought about with an increase in impedance, but it is possible to provide a converting performance equivalent to that in the case where the one surface is covered, by setting the plasma generating conditions as described above.
- Further, according to the present invention, there is provided a process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like, comprising the steps of: generating plasma in the exhaust gas discharged from the lean burn engine and containing the particulate material to produce a plurality of nitrogen dioxide molecules and a plurality of ozone molecules; and oxidizing the particulate material by the nitrogen dioxide molecules and the ozone molecules.
- When the plasma is generated in the exhaust gas, the following process is provided: oxygen atom excited species are produced by the collision between released electrons and oxygen molecules →ozone is produced by the reaction of the oxygen atom excited species with oxygen molecules→nitrogen dioxide (NO2) is produced by the reaction of ozone with nitrogen monoxide (NO). The productions of the nitrogen dioxide and ozone are-carried out independent of the temperature of the exhaust gas. The particulate material PM is oxidized and converted based on the reaction represented by PM+NO2+O3→CO2+H2O+N2. The conversion of the particulate material by the oxidization is conducted continuously and moreover at a relatively low temperature.
- A plasma generating device has a good gas permeability, as compared with a filter, so that even if the plasma generating device is incorporated in an exhaust pipe, an increase in exhausting resistance is suppressed to a low level. Therefore, an influence cannot be exerted to an engine output.
- Yet further, according to the present invention, there is provided a process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine, comprising the steps of: generating plasma in the exhaust gas discharged from the lean burn engine and containing the particulate material to produce a plurality of nitrogen dioxide molecules and a plurality of ozone molecules; oxidizing the particulate material by the nitrogen dioxide molecules and the ozone molecules; and subjecting the particulate material to the reaction with the nitrogen dioxide molecules and the ozone molecules in the presence of a catalyst to oxidize the particulate material.
- If the catalyst is used as described above, the above-described reaction, namely, the reaction represented by PM+NO2+O3→CO2+H2O+N2 can be promoted to greatly increase the decrement rate of the particulate material.
- At least one selected from the group consisting of Pt, Pd, Rh, Cu, Ag and Au is used as the catalyst.
- If an intensity E of electric field is set at a value equal to or larger than 3.0 kV/mm and a power density Dw is set at a value equal to or larger than 1 W/cm3 in the plasma generating conditions, the amount of released high-energy electrons existing in the plasma is increased, and hence the productions of the nitrogen dioxide and ozone are efficiently conducted, whereby the conversion of the carbon solid fraction by the oxidization can be enhanced. However, if at least one of requirements of E≧3.0 kV/mm and Dw≧1 W/cm3 is lacked, the above-described effect cannot be obtained.
- Further, if the surface of at least one of opposed electrodes which is opposed to the other electrodes is covered with a dielectric, the entire surface of the dielectric is uniformly charged upon application of a voltage. Therefore, the entire space between the dielectric and the other electrode opposed to the dielectric constitutes a plasma space, so that the frequency of random contact of the particulate material with the nitrogen dioxide and ozone can be increased to enhance the conversion of the carbon solid fraction by the oxidization. If opposed surfaces of the opposed electrodes are covered with dielectrics, respectively, an increase in the, applied voltage is provided by an increase in impedance, but it is possible to provide a converting performance equivalent to that in the case where the one surface is covered, by setting the plasma generating conditions as described above.
- FIG. 1 is an illustration of a first embodiment of an equipment for a particulate material content decreasing test.
- FIG. 2 is a diagram of a plasma generating device.
- FIG. 3 is a graph showing amounts of a particulate material before and after a plasma treatment.
- FIG. 4 is an illustration of a second embodiment of an equipment for a particulate material content decreasing test.
- FIG. 5 is a graph showing amounts of a particulate material before and after a catalytic reaction and after a plasma treatment for Example 4.
- FIG. 6 is a graph showing amounts of a particulate material before and after a catalytic reaction and after a plasma treatment for Example 5.
- FIG. 7 is an illustration of a third embodiment of an equipment for a particulate material content decreasing test.
- FIG. 8 is a graph showing amounts of a particulate material before and after a plasma treatment and after a catalytic reaction for Example 6.
- FIG. 9 is a graph showing amounts of a particulate material before and after a plasma treatment and after a catalytic reaction for Example 7.
- In an
equipment 1 for a particulate material content-decreasing test shown in FIG. 1, a commerciallyavailable diesel generator 2 is selected as a source of generating an exhaust gas containing a particulate material. A first flowrate regulating valve 4, is mounted in anexhaust pipe 3 of thediesel generator 2. In theexhaust pipe 3, aconduit 5 is connected at one end between thediesel generator 2 and the first flowrate regulating valve 4 1. A second flowrate regulating valve 4 2, aheater 6, a plasma generating device PG and a flow-meter 8 are mounted in theexhaust pipe 3 sequentially in the named order from the side of theexhaust pipe 3. The other end of theconduit 5 opens to the atmosphere. - In the
conduit 5, afirst branch pipe 9 1 is connected at one end between theheater 6 and the plasma generating device PG, and at the other end to a first port p1 of a three-way valve 10. In theconduit 5, asecond branch pipe 9 2 is also connected at one end between the plasma generating device PG and the flow-meter 8, and at the other end to a second port p2 of the three-way valve 10. Anotherconduit 11 is connected at one end to a third port p3 of the three-way valve 10, and at the other end to a suction port of asuction pump 12. Afilter 13 is mounted in theconduit 11. - The
diesel generator 2 is EXT12D made by Honda Motor Co., Ltd., and the specification thereof is as follows: the type of an engine: a water-cooled 3-cylinder and 4-cycle diesel engine; a total displacement: 1061 cc; a fuel used: diesel light oil; a rated output: 12 kVA. Thefilter 13 is a Teflon-coated filter made by German Laboratory, and has a mesh size of 0.3 μm mesh. - Referring to FIG. 2, the plasma generating device PG includes a plurality of first to sixth electrodes14, to 14 6 made of a metal, each of which is formed into a plate shape in the illustrated embodiment. The first to sixth electrodes 14, to 14 6 are mounted in a housing 15 (see FIG. 1) so that they are parallel to a direction A of flowing of an exhaust gas, and the adjacent electrodes 14 1 and 14 2; 14 2 and 14 3; 14 3 and 14 4; 14 4 and 14 5; 14 5 and 14 6 are opposed to each other. The surface of the first electrode 14 1 located at one end, which is opposed to the second electrode 14 2, is a non-coated metal surface, but the surface of the second electrode 14 2, which is opposed to the first electrode 14 1, is coated entirely with a dielectric 16. The arrangement relationship between the opposed surfaces of the first and second electrodes 14 1 and 14 2 applies to those between the second and third electrodes 14 2 and 14 3; between the third and fourth electrodes 14 3 and 14 4; between the fourth and fifth electrodes 14 4 and 14 5; and between the fifth and sixth electrodes 14 5 and 14 6. The first, third and fifth electrodes 14 1, 14 3 and 14 5 are connected to a
power source 18 throughlead wires 17, while the second, fourth and sixth electrodes 14 2, 14 4 and 14 6 are earthed throughlead wires 19. - If the plasma generating device PG is constructed as described above, the entire surface of each of the
dielectrics 16 is uniformly charged upon application of a voltage, and hence the entire space between each of thedielectrics 16 and each of the electrodes 14 1 to 14 6 which is opposed thereto constitutes a plasma space Pp. Namely, the plasma spaces Pp are formed between the first and second electrodes 14 1 and 14 2; between the second and third electrodes 14 2 and 14 3; between the third and fourth electrodes 14 3 and 14 4; between the fourth and fifth electrodes 14 4 and 14 5; and between the fifth and sixth electrodes 14 5 and 14 6. That is, each of the plasma spaces Pp is defined by the opposed electrodes. - Each of the first to sixth electrodes14 1 to 14 6 is formed of a stainless steel (e.g., JIS SUS316), and has a size of 20 mm long, 50 mm wide and 1.0 mm thick, with a transverse side extending along the exhaust gas flowing direction A. Each of the
dielectrics 16 comprises an alumina (Al2O3) layer having a thickness of 0.5 mm, which is bonded to each of the second to sixth electrodes 14 2 to 14 6 by the mechanical pressing. The adhesion using an adhesive, the flame spraying or the like may be also utilized for such bonding. A gap g in each of the plasma spaces Pp, namely, a distance between each of the adjacent electrodes 14 1 to 14 6 and each of thedielectrics 16 is 0.5 mm. - A particulate material content reducing test was carried out using the above-described
equipment 1, according to the following procedure: - (1) The
diesel generator 2 was operated, and an exhaust gas discharged from thediesel generator 2 was caused to flow through theexhaust gas 3 and theconduit 5. - (2) The flow rate of the testing exhaust gas flowing through the
conduit 5, and hence through the plasma generating device PG, was regulated to 7.0 L/min by the first and second flowrate regulating valves meter 8. - (3) The
heater 6 was operated to heat the exhaust gas having a temperature of about 70° C. up to 150° C., and the exhaust gas was allowed to flow through the first and third ports p1 and p3 of the three-way valve 10. Then, the testing exhaust gas flowing through theconduit 5 was diverted into thefirst branch pipe 9 1 by driving thesuction pump 12 at a suction rate of 5.0 L/min, and caused to flow through thefilter 13 over 10 minutes, whereby a particulate material in the testing exhaust gas was collected by thefilter 13. A weight of the particulate material collected was determined from the weights of the filter before and after the collection of the particulate material, and defined as an amount of the particulate material before a plasma treatment. - (4) The plasma generating device PG was operated, and the second and third ports P2 and P3 were put into communication with each other by switching-over of the three-
way valve 10. Then, the testing exhaust gas discharged from the plasma generating device PG and flowing through theconduit 5, was diverted into thesecond branch pipe 9 2 by driving thesuction pump 12 at a suction rate of 5.0 L/min, and caused to flow through anew filter 13 over 10 minutes, whereby the particulate material in the testing exhaust gas was collected by thenew filter 13. A weight of the particulate material collected was determined from the weights of the filter before and after the collection of the particulate material, and defined as an amount of the particulate material after the plasma treatment. - In the test, an excitation spectrum of the exhaust gas was analyzed as a plasma excited state of the exhaust gas within the plasma generating device PG by an emission spectrometricphotometer (IMUC-7000 made by Otsuka Electronics Co., Ltd.). As a result, the production of a plurality of excited-oxygen atoms by the generation of plasma was observed. Particularly, because an excitation spectrum of 6 eV or more was present, the existence of O(1D) radicals was considered to be present. Thus, it can be said that a plurality of hydroxide excited species and per-hydroxide excited species HOO* were produced.
- Table 1 shows plasma generating conditions for Examples 1 to 3.
TABLE 1 Plasma space Electricity input conditions Intensity E Gap Volume Alternate Frequency Voltage of electric field Power density Example (mm) (cm3) current (Hz) (kVp-p) Power (W) (kV/mm) Dw (W/cm3) 1 0.5 2.5 Sine wave 300 3.0 2.7 3.0 1.1 AC 2 1.5 7.5 Sine wave 700 8.2 9.1 2.7 1.2 AC 3 0.5 2.5 Sine wave 100 3.0 2.1 3.0 0.8 AC - In Table 1, the intensity E of electric field is a value provided by dividing a voltage [(kVp-p)/2] applied between the opposed electrodes such as between the first and second electrodes 14 1 and 14 2 by the gap g (mm), and the power density Dw is a value provided by dividing a power (0.54 W×5=2.7 W) in the plasma space Pp defined by the opposed electrodes by a volume [(2 cm×5 cm×0.05 cm)×5=2.5 cm3] of the plasma space Pp.
- Table 2 shows amounts of the particulate material before and after the plasma treatment, and decrement amounts and decrement rates of the particulate material decreased by the plasma treatment for Examples 1 to 3.
TABLE 2 Particulate material Amount (mg) Amount (mg) before plasma after plasma Decrement Decrement treatment treatment amount (mg) rate (%) Example 1 1.3 0.2 1.1 84.6 Example 2 1.2 0.7 0.5 41.7 Example 3 1.4 0.8 0.6 42.9 - FIG. 3 is a graph based on Table 2 and showing amounts of the particulate material before and after the plasma treatment for Examples 1 to 3. As apparent from Tables 1 and 2 and FIG. 3, according to Example 1, per-hydroxide excited species HOO* can be efficiently produced by setting the intensity E of electric field at a value equal to or larger than 3.0 kV/mm and the power density Dw at a value equal to or larger than 1 W/cm3, whereby the decrement rate of the particulate material can be increased to about 84.6%. The intensityE of electric field is preferably in a range of 3 kV/mm≦E≦15 kV/mm, and the power density Dw is preferably in a range of 1 W/cm3≦Dw≦10 W/cm3.
- In the cases of Examples 2 and 3, the decrement rate of the particulate material is lower and approximately half of that in Example 1, because one of the intensity E of electric field and the power density Dw dose not satisfies the above-described requirement.
- Embodiment I is applicable for decreasing the content of a particulate material contained in an exhaust gas discharged from an automobile, a factory or the like.
- According to the above-described process, it is possible to continuously convert the particulate material contained in the exhaust gas from the lean burn engine or the like by the oxidization, to thereby remarkably decrease the content thereof. In addition, this process cannot provide a disadvantage that the exhausting resistance is greatly increased to affect an engine output. Embodiment II
- In an
equipment 1 for a particulate material content decreasing test shown in FIG. 4, a commerciallyavailable diesel generator 2 is selected as a source of generating an exhaust gas containing a particulate material. A first flowrate regulating valve 4 1 is mounted in anexhaust pipe 3 of thediesel generator 2. In theexhaust pipe 3, aconduit 5 is connected at one end between thediesel generator 2 and the first flowrate regulating valve 4 1, and a second flowrate regulating valve 4 2, aheater 6, a catalytic reactor CR, a plasma generating device PG and a flow-meter 8 are mounted on theexhaust pipe 3 sequentially in the named order from the side of theexhaust pipe 3. The other end of theconduit 5 opens to the atmosphere. - In the
conduit 5, afirst branch pipe 9 1 is connected at one end between theheater 6 and the catalytic reactor CR, and at the other end to a suction port of asuction pump 12. A first on-off valve 20 1 and afilter 13 are mounted in thefirst branch pipe 9 1 sequentially from the side of theconduit 5. In theconduit 5, asecond branch pipe 9 2 is also connected at one end between the catalytic reactor CR and the plasma generating device PG, and at the other end between the first on-off valve 20 1 and thefilter 13 in thefirst branch pipe 9 1. A second on-off valve 20 2 is mounted in thesecond branch pipe 9 2. Further, in theconduit 5, athird branch pipe 9 3 is connected at one end between the plasma generating device PG and the flow-meter 8, and at the other end between a connection of thesecond branch pipe 9 2 and thefilter 13 in thefirst branch pipe 9 1. A third on-off valve 20 3 is mounted in thethird branch pipe 9 3. - As in Embodiment I, the
diesel generator 2 is EXT12D made by Honda Motor Co. Ltd., and the specification thereof is as follows: the type of an engine: a water-cooled 3-cylinder and 4-cycle diesel engine; a total displacement: 1061 cc; a fuel used: diesel light oil; a rated output: 12 kVA. Thefilter 13 is a Teflon-coated filter made by German Laboratory, and has a mesh size of 0.3 μm mesh. - As shown in FIG. 2, the plasma generating device PG has the same structure as that in Embodiment I and includes a plurality of first to sixth electrodes14 1 to 14 6 made of a metal, each of which is formed into a plate shape in the illustrated embodiment. The first to sixth electrodes 14 1 to 14 6 are mounted in a housing 15 (see FIG. 4) so that they are parallel to a direction A of flowing of an exhaust gas, and the adjacent electrodes 14 1 and 14 2; 14 2 and 14 3; 14 3 and 14 4; 14 4 and 14 5; 14 5 and 14 6 are opposed to each other. The surface of the first electrode 14 1 located at one end, which is opposed to the second electrode 14 2, is a non-coated metal surface, but the surface of the second electrode 14 2, which is opposed to the first electrode 14 1, is coated entirely with a dielectric 16. The arrangement relationship between the opposed surfaces of the first and second electrodes 14 1 and 14 2 applies to those between the second and third electrodes 14 2 and 14 3; between the third and fourth electrodes 14 3 and 14 4; between the fourth and fifth electrodes 14 4 and 14 5; and between the fifth and sixth electrodes 14 5 and 14 6. The first, third and fifth electrodes 14 1, 14 3 and 14 5 are connected to a
power source 18 throughlead wires 17, while the second, fourth and sixth electrodes 14 2, 14 4 and 14 6 are earthed throughlead wires 19. - If the plasma generating device PG is constructed as described above, the entire surface of each of the
dielectrics 16 is uniformly charged upon application of a voltage, and hence the entire space between each of thedielectrics 16 and each of the electrodes 14 1 to 14 6 which is opposed thereto constitutes a plasma space Pp. Namely, the plasma spaces Pp are formed between the first and second electrodes 14 1 and 14 2; between the second and third electrodes 14 2 and 14 3; between the third and fourth electrodes 14 3 and 14 4; between the fourth and fifth electrodes 14 4 and 14 5; and between the fifth and sixth electrodes 14 5 and 14 6. That is, each of the plasma spaces Pp is defined by the opposed electrodes. - Each of the first to sixth electrodes14 1 to 14 6 is formed of a stainless steel (e.g., JIS SUS316), and has a size of 20 mm long, 50 mm wide and 1.0 mm thick, with a transverse side extending along the exhaust gas flowing direction A. Each of the
dielectrics 16 comprises an alumina (Al2O3) layer having a thickness of 0.5 mm, which is bonded to each of the second to sixth electrodes 14 2 to 14 6 by the mechanical pressing. The adhesion using an adhesive, the flame spraying or the like may be also utilized for such bonding. A gap g in each of the plasma spaces Pp, namely, a distance between each of the adjacent electrodes 14 1 to 14 6 and each of the dielectric 16 is 0.5 mm. - The catalytic reactor CR comprises a honeycomb carrier and platinum (Pt) carried as a catalyst on the honeycomb carrier, and is placed in a
housing 21. To carry platinum on the honeycomb carrier, the following process was adopted: (i) 80 grams of a solution of platinum dinitrodiamine nitric acid [Pt(NH3)2(NO2)2.HNO3] containing 5% by weight of platinum, 96 grams of commercially available γ-Al2O3, and 1,000 grams of ion-exchange water were mixed together, and at the same time, an excessive amount of water was removed; (ii) a mixture was dried at 200° C. for 2 hours; (iii) a powder of Al2O3 carrying platinum was produced by calcining the mixture at 600° C. for 2 hours; (iv) 90 grams of the powder of Al2O3 carrying platinum, 50 grams of an SiO2 binder (containing 20% by weight of SiO2) and 150 grams of ion-exchange water were mixed together; (v) a slurry was prepared by wet-pulverizing the mixture over 12 hours using alumina balls; (vi) a honeycomb carrier carrying a platinum catalyst in an amount of 4 g/L at a wash coat amount of 100 g/L was prepared by repeating a process: immersing a honeycomb carrier made-of cordierite and having a volume of about 30 L (a diameter of 2.54 and a length of 60 mm) with 400 cells/in2 and 6 mils into the slurry; removing an excessive amount of the slurry from the carrier by jet water injection after the removal of the carrier; and drying the carrier at 150° C. for 1 hour; (vii) the honeycomb carrier was calcined at 500° C. for 2 hours; (viii) the honeycomb carrier carrying the catalyst was placed into the housing 21. - This type of catalytic reactor CR has a structure substantially same as that of a catalytic converter, and hence the exhausting resistance cannot be greatly increased.
- A particulate material content-decreasing test was carried out using the above-described equipment by the following procedure:
- (1) The
diesel generator 2 was operated, and an exhaust gas discharged from thediesel generator 2 was caused to flow through theexhaust gas 3 and theconduit 5. - (2) The flow rate of the testing exhaust gas flowing through the
conduit 5, and hence through the catalytic reactor CR and the plasma generating device PG, was regulated to 7.0 L/min by the first and second flowrate regulating valves meter 8. - (3) The
heater 6 was operated to heat the exhaust gas having a temperature of about 70° C. up to 150° C., and the first on-off valve 20 1 was opened, while the second and third on-off valves 20 2 and 20 3 were closed. Then, the testing exhaust gas flowing through theconduit 5 was diverted into thefirst branch pipe 9 1 by driving thesuction pump 12 at a suction rate of 5.0 L/min, and caused to flow through thefilter 13 over 20 minutes, whereby a particulate material in the testing exhaust gas was collected by thefilter 13. A weight of the particulate material collected was determined from the weights of the filter before and after the collection of the particulate material, and was defined as an amount of the particulate material before a catalytic reaction. - (4) The second on-off valve20 2 was opened, while the first and third on-off valves 20 1 and 20 3 were closed. Then, the testing exhaust gas flowing through the
conduit 5 via the catalytic reactor CR, was diverted into thesecond branch pipe 9 2 by driving thesuction pump 12 at a suction rate of 5.0 L/min, and caused to flow through anew filter 13 over 20 minutes, whereby the particulate material in the testing exhaust gas was collected by thenew filter 13. A weight of the particulate material collected was determined from the weights of the filter before and after the collection of the particulate material, and defined as an amount of the particulate material after the catalytic reaction. - (5) The plasma generating device PG was operated, and the third on-off valve20 3 was opened, while the first and second on-off valves 20 1 and 20 2 were closed. Then, the testing exhaust gas flowing through the
conduit 5 via the catalytic reactor CR and the plasma generating device PG, was diverted into thethird branch pipe 9 3 by driving thesuction pump 12 at a suction rate of 5.0 L/min, and caused to flow through anew filter 13 over 20 minutes, whereby the particulate material in the testing exhaust gas was collected by thenew filter 13. A weight of the particulate material collected was determined from the weights of the filter before and after the collection of the particulate material, and defined as an amount of the particulate material after the plasma treatment. - The process using platinum as the catalyst as described above is defined as Example 4.
- A particulate material content-decreasing test was carried out as Example 5 in a similar manner, except that a catalytic reactor CR having silver (Ag) as a catalyst was used, and the temperature of an exhaust gas flowing into the plasma generating device PG was set at 250° C. To carry silver (Ag) on Al2O3 in a catalyst-carried honeycomb carrier, this process was the same as Example 3, except that a mixture comprising 4.72 grams of silver nitrate (AgNO3), 97 grams of commercially available γ-Al2O3, and 1,000 grams of ion-exchange water were used as a silver-containing solution, and the amount of silver carried on the honeycomb carrier was set at 3 g/L.
- In each of Examples 4 and 5, an excitation spectrum of the exhaust gas was analyzed as a plasma excited state of the exhaust gas within the plasma generating device PG by an emission spectrometricphotometer (IMUC-7000 made by Otsuka Electronics Co., Ltd.). As a result, the production of a plurality of excited-oxygen atoms by the generation of plasma was observed. Particularly, because an excitation spectrum of 6 eV or more was present, O(1D) radicals was considered to be present. Thus, it can be said that if the plasma is generated in the exhaust gas, O(1D) radicals and ozone excited species are produced by the collision between electrons released from the electrodes and oxygen atoms→hydroxide excited species OH* are produced by the reaction of O(1D) radicals and ozone excited species with water→per-hydroxide excited species HOO* having a strong oxidizing force are produced by the reaction of the hydroxide excited species OH* with oxygen. Namely, the plasma excited species include O(1D) radicals, hydroxide excited species OH*, per-hydroxide excited species HOO* and the like.
- Table 3 shows plasma generating conditions for Examples 4 and 5.
TABLE 3 Plasma space Electricity input conditions Intensity E Gap Volume Alternate Frequency Voltage of electric field Power density Example (mm) (cm3) current (Hz) (kVp-p) Power (W) (kV/mm) Dw (W/cm3) 4 0.5 2.5 Sine wave 2,500 7.6 7.4 7.6 3.0 AC 5 0.5 2.5 Sine wave 1,600 7.2 9.5 7.2 3.8 AC - In Table 3, the intensity E of electric field is a value provided by dividing a voltage [(kVp-p)/2] applied between the opposed electrodes such as between the first and second electrodes 14 1 and 14 2 by the gap g (mm), and the power density Dw is a value provided by dividing a power (Example 4: 1.48 W x 5=7.4 W; and Example 5: 1.9 W×5=9.5 W) in the plasma space Pp defined by the opposed electrodes by a volume [(2 cm×5 cm×0.05 cm)×5=2.5 cm3] of the plasma space Pp.
- Table 4 shows amounts of the particulate material before and after the catalytic reaction and after the plasma treatment, and decrement amounts and decrement rates of the particulate material decreased by the catalytic reaction and the plasma treatment for Examples 4 and 5.
TABLE 4 Particulate material Amount before After catalytic reaction After plasma treatment catalytic Decrement Decrement reaction Amount amount Decrement amount Decrement Example (mg) (mg) (mg) rate(%) Amount (mg) (mg) rate (%) 4 2.6 1.9 0.7 26.9 0.2 2.4 92.3 5 2.4 1.7 0.7 29.2 0.2 2.2 91.7 - FIGS. 5 and 6 are graphs based on Table 4 and showing amounts of the particulate material before and after the catalytic reaction and after the plasma treatment for Examples 4 and 5. As apparent from Tables 3 and 4 and FIGS. 5 and 6, according to Examples 4 and 5, plasma excited species can be efficiently produced by setting the intensity E of electric field at a value equal to or larger than 3.0 kV/mm and setting the power density Dw at a value equal to or larger than 1 W/cm3, whereby the decrement rate of the particulate material can be increased up to about 92% or more. The intensity E of electric field is preferably in a range of 3 kV/mm≦E≦15 kV/mm, and the power density Dw is preferably in a range of 1 W/cm3≦Dw≦10 W/cm3.
- The particulate material before the catalytic reaction was subjected to an extraction using a Soxhlet extractor. As a result, an amount of a fraction soluble in an organic solvent was about 30% by weight, and an amount of carbon solid fraction was about 70% by weight. If Table 4 is reviewed with this fact in mind, it can be seen that substantially all the fraction soluble in the organic solvent was converted for purification of the exhaust gas by the catalytic reaction, and the conversion of the carbon solid fraction for purification of the exhaust gas was efficiently carried out by the subsequent plasma treatment.
- Embodiment II is applicable for decreasing the content of a particulate material contained in an exhaust gas discharged from an automobile, a factory or the like.
- According to the above-described process, it is possible to continuously convert a particulate material contained in an exhaust gas from a lean burn engine or the like by the oxidization, to thereby remarkably decrease the content of the particulate material. In addition, this process cannot provide a disadvantage that the exhausting resistance is greatly increased to affect an engine output.
- In an
equipment 1 for a particulate material content-decreasing test shown in FIG. 7, a commerciallyavailable diesel generator 2 is selected as a source of generating an exhaust gas containing a particulate material. A first flowrate regulating valve 4 1 is mounted in anexhaust pipe 3 of thediesel generator 2. In theexhaust pipe 3, aconduit 5 is connected at one end between thediesel generator 2 and the first flowrate regulating valve 4 1, and a second flowrate regulating valve 4 2, aheater 6, a plasma generating device PG, a catalytic reactor CR and a flow-meter 8 are mounted on theexhaust pipe 3 sequentially in the named order from the side of theexhaust pipe 3. The other end of theconduit 5 opens to the atmosphere. - In the
conduit 5, afirst branch pipe 9 1 is connected at one end between theheater 6 and the plasma generating device PG, and at the other end to a suction port of asuction pump 12. A first on-off valve 20 1 and afilter 13 are mounted in thefirst branch pipe 9 1 sequentially from the side of theconduit 5. In theconduit 5, asecond branch pipe 9 2 is also connected at one end between the plasma generating device PG and the catalytic reactor CR, and at the other end between the first on-off valve 20 1 and thefilter 13 in thefirst branch pipe 9 1. A second on-off valve 20 2 is mounted in thesecond branch pipe 9 2. Further, in theconduit 5, athird branch pipe 9 3 is connected at one end between the catalytic reactor CR and the flow-meter 8, and at the other end between a connection of thesecond branch pipe 9 2 and thefilter 13 in thefirst branch pipe 9 1. A third on-off valve 20 3 is mounted in thethird branch pipe 9 3. - As in Embodiments I and II, the
diesel generator 2 is EXT12D made by Honda Motor Co. Ltd., and the specification thereof is as follows: the type of an engine: a water-cooled 3-cylinder and 4-cycle diesel engine; a total displacement: 1061 cc; a fuel used: diesel light oil; a rated output: 12 kVA. Thefilter 13 is a Teflon-coated filter made by German Laboratory, and has a mesh size of 0.3 μm mesh. - As shown in FIG. 2, the plasma generating device PG has the same structure as that in Embodiments I and II, and includes a plurality of first to sixth electrodes14 1 to 14 6 made of a metal, each of which is formed into a plate shape in the illustrated embodiment. The first to sixth electrodes 14 1 to 14 6 are mounted in a housing 15 (see FIG. 7) so that they are parallel to a direction A of flowing of an exhaust gas, and the adjacent electrodes 14 1 and 14 2; 14 2 and 14 3; 14 3 and 14 4; 14 4 and 14 5; 14 5 and 14 6 are opposed to each other. The surface of the first electrode 14 1 located at one end, which is opposed to the second electrode 14 2, is a non-coated metal surface, but the surface of the second electrode 14 2, which is opposed to the first electrode 14 1, is coated entirely with a dielectric 16. The arrangement relationship between the opposed surfaces of the first and second electrodes 14 1 and 14 2 applies to those between the second and third electrodes 14 2 and 14 3; between the third and fourth electrodes 14 3 and 14 4; between the fourth and fifth electrodes 14 4 and 14 5; and between the fifth and sixth electrodes 14 5 and 14 6. The first, third and fifth electrodes 14 1, 14 3 and 14 5 are connected to a
power source 18 throughlead wires 17, while the second, fourth and sixth electrodes 14 2, 14 4 and 14 6 are earthed throughlead wires 19. - If the plasma generating device PG is constructed as described above, the entire surface of each of the
dielectrics 16 is uniformly charged upon application of a voltage, and hence the entire space between each of thedielectrics 16 and each of the electrodes 14 1 to 14 6 which is opposed thereto constitutes a plasma space Pp. Namely, the plasma spaces Pp are formed between the first and second electrodes 14 1 and 14 2; between the second and third electrodes 14 2 and 14 3; between the third and fourth electrodes 14 3 and 14 4; between the fourth and fifth electrodes 14 4 and 14 5; and between the fifth and sixth electrodes 14 5 and 14 6. That is, each of the plasma spaces Pp is defined by the opposed electrodes. - Each of the first to sixth electrodes14 1 to 14 6 is formed of a stainless steel (e.g., JIS SUS316), and has a size of 20 mm long, 50 mm wide and 1.0 mm thick, with a transverse side extending along the exhaust gas flowing direction A. Each of the
dielectrics 16 comprises an alumina (Al2O3) layer having a thickness of 0.5 mm, which is bonded to each of the second to sixth electrodes 14 2 to 14 6 by the mechanical pressing. The adhesion using an adhesive, the flame spraying or the like may be also utilized for such bonding. A gap g in each of the plasma spaces Pp, namely, a distance between each of the adjacent electrodes 14 1 to 14 6 and each of the dielectric 16 is 0.5 mm. - The catalytic reactor CR comprises a honeycomb carrier and platinum (Pt) carried as a catalyst on the honeycomb carrier, and is placed in a
housing 21. To carry platinum on the honeycomb carrier, the following process was adopted: (i) 80 grams of a solution of platinum dinitrodiamine nitric acid (Pt(NH3)2(NO2)2.HNO3] containing 5% by weight of platinum, 96 grams of commercially available γ-Al2O3, and 1,000 grams of ion-exchange water were mixed together, and at the same time, an excessive amount of water was removed; (ii) a mixture was dried at 200° C. for 2 hours; (iii) a powder of Al2O3 carrying platinum was produced by calcining the mixture at 600° C. for 2 hours; (iv) 90 grams of the powder of Al2O3 having platinum carried thereon, 50 grams of an SiO2 binder (containing 20% by weight of SiO2) and 150 grams of ion-exchange water were mixed together; (v) a slurry was prepared by wet-pulverizing the mixture over 12 hours using alumina balls; (vi) a honeycomb carrier carrying a platinum catalyst in an amount of 4 g/L at a wash coat amount of 100 g/L was prepared by repeating a process: immersing a honeycomb carrier made of cordierite and having a volume of about 30 L (a diameter of 2.54 and a length of 60 mm) with 400 cells/in2 and 6 mils into the slurry; removing an excessive amount of the slurry from the carrier by jet water injection after the removal of the carrier; and drying the carrier at 150° C. for 1 hour; (vii) the honeycomb carrier was calcined at 500° C. for 2 hours; (viii) the honeycomb carrier carrying the catalyst was placed into the housing 21. - This type of catalytic reactor CR has a structure substantially same as that of a catalytic converter, and hence the exhausting resistance cannot be greatly increased.
- A particulate material content-decreasing test was carried out using the above-described equipment by the following procedure:
- (1) The
diesel generator 2 was operated, and an exhaust gas discharged from thediesel generator 2 was caused to flow through theexhaust gas 3 and theconduit 5. - (2) The flow rate of the testing exhaust gas flowing through the
conduit 5, and hence through the plasma generating device PG and the catalytic reactor CR, was regulated to 7.0 L/min by the first and second flowrate regulating valves meter 8. - (3) The
heater 6 was operated to heat the exhaust gas having a temperature of about 70° C. up to 150° C., and the first on-off valve 20 1 was opened, while the second and third on-off valves 20 2 and 20 3 were closed. Then, the testing exhaust gas flowing through theconduit 5 was diverted into thefirst branch pipe 9 1 by driving thesuction pump 12 at a suction rate of 5.0 L/min, and caused to flow through thefilter 13 over 20 minutes, whereby a particulate material in the testing exhaust gas was collected by thefilter 13. A weight of the particulate material collected was determined from the weights of the filter before and after the collection of the particulate material, and was defined as an amount of the particulate material before a catalytic reaction. - (4) The plasma generating device PG was operated, and the second on-off valve20 2 was opened, while the first and third on-off valves 20, and 20 3 were closed. Then, the testing exhaust gas discharged from the plasma generating device PG and flowing through the
conduit 5 via the catalytic reactor CR, was diverted into thesecond branch pipe 9 2 by driving thesuction pump 12 at a suction rate of 5.0 L/min, and caused to flow through anew filter 13 over 20 minutes, whereby the particulate material in the testing exhaust gas was collected by thenew filter 13. A weight of the particulate material collected was determined from the weights of the filter before and after the collection of the particulate material, and defined as an amount of the particulate material after the plasma treatment. - (5) In a state in which the plasma generating device PG was operated, the third on-off valve20 3 was opened, while the first and second on-off valves 20, and 20 2 were closed. Then, the testing exhaust gas flowing through the
conduit 5 via the plasma generating device PG and the catalytic reactor CR, was diverted into thethird branch pipe 9 3 by driving thesuction pump 12 at a suction rate of 5.0 L/min, and caused to flow through anew filter 13 over 20 minutes, whereby the particulate material in the testing exhaust gas was collected by thenew filter 13. A weight of the particulate material collected was determined from the weights of the filter before and after the collection of the particulate material, and defined as an amount of the particulate material after the catalytic reaction. - The process using platinum as the catalyst as described above is defined as Example 6.
- A particulate material content-decreasing test was carried out as Example 7 in a similar manner, except that a catalytic reactor CR having silver (Ag) as a catalyst was used, and the temperature of an exhaust gas flowing into the plasma generating device PG was set at 250° C. To carry silver (Ag) on Al2O3 in a catalyst-carried honeycomb carrier, this process was the same as Example 6, except that a mixture comprising 4.72 grams of silver nitrate (AgNO3), 97 grams of commercially available γ-Al2O3, and 1,000 grams of ion-exchange water were used as a silver-containing solution, and the amount of silver carried on the honeycomb carrier was set at 3 g/L.
- In each of Examples 6 and 7, the exhaust gas upstream and the exhaust gas downstream of the plasma generating device PG was sampled, and the type of the gas was analyzed by FT-IR (a Fourier transform infrared spectroscopic device). As a result, the production of a plurality of nitrogen dioxide molecules and a plurality of ozone molecules by the generation of plasma was observed.
- Table 5 shows plasma generating conditions for Examples 6 and 7.
TABLE 5 Plasma space Electricity input conditions Intensity E Gap Volume Alternate Frequency Voltage of electric field Power density Example (mm) (cm3) current (Hz) (kVp-p) Power (W) (kV/mm) Dw (W/cm3) 6 0.5 2.5 Sine wave 200 7.6 3.1 7.6 1.2 AC 7 0.5 2.5 Sine wave 500 6.6 8.5 6.6 3.4 AC - In Table 5, the intensity E of electric field is a value provided by dividing a voltage [(kVp-p)/2] applied between the opposed electrodes such as between the first and second electrodes 14 1 and 14 2 by the gap g (mm), and the power density Dw is a value provided by dividing a power (Example 6: 0.62 W×5=3.1 W; and Example 7: 1.7 W×5=8.5 W) in the plasma space Pp defined by the opposed electrodes by a volume [(2 cm×5 cm×0.05 cm)×5=2.5 cm3] of the plasma space Pp.
- Table 6 shows amounts of the particulate material before and after the plasma treatment and after the catalytic reaction, and decrement amounts and decrement rates of the particulate material decreased by the plasma treatment and the catalytic reaction for Examples 6 and 7.
TABLE 6 Particulate material Amount before After plasma treatment After catalytic reaction plasma Decrement Decrement treatment Amount amount Decrement amount Decrement Example (mg) (mg) (mg) rate % Amount (mg) (mg) rate (%) 6 2.5 0.4 2.1 84.0 0.1 2.4 96.0 7 2.3 0.3 2.0 87.0 0.1 2.2 95.7 - FIGS. 8 and 9 are graphs based on Table 6 and showing amounts of the particulate material before and after the plasma treatment and after the catalytic reaction for Examples 6 and 7. As apparent from Tables 5 and 6 and FIGS. 8 and 9, according to Examples 6 and 7, nitrogen dioxide and ozone can be efficiently produced by setting the intensity E of electric field at a value equal to or larger than 3.0 kV/mm and setting the power density Dw at a value equal to or larger than 1 W/cm3, whereby the decrement rate of the particulate material can be increased up to about 84% or more. The intensity E of electric field is preferably in a range of 3 kV/mm≦E≦15 kV/mm, and the power density Dw is preferably in a range of 1 W/cm3≦Dw≦10 W/cm3. Further, the decrement rate of the particulate material can be further increased up to approximately 96% by carrying out the catalytic reaction.
- Embodiment III is applicable for decreasing the content of a particulate material contained in an exhaust gas discharged from an automobile, a factory or the like.
- According to the above-described process, it is possible to continuously convert a particulate material contained in an exhaust gas from a lean burn engine or the like by the oxidization, to thereby remarkably decrease the content of the particulate material. In addition, this process cannot provide a disadvantage that the exhausting resistance is greatly increased to affect an engine output.
Claims (12)
1. A process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine, comprising the steps of: generating plasma in the exhaust gas discharged from the lean burn engine and containing the particulate material, to thereby produce a plurality of O(1D) radicals and subsequently produce a plurality of per-hydroxide excited species; and oxidizing the particulate material by the per- hydroxide excited species.
2. A process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like according to claim 1 , wherein, in plasma generating conditions, an intensity E of an electric field is set at a value equal to or larger than 3.0 kV/mm, and a power density Dw is set at a value equal to or larger than 1 W/cm3.
3. A process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like according to claim 1 or 2, wherein the surface of at least one of opposed electrodes which is opposed to the other electrode is covered with a dielectric.
4. A process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like and comprising a carbon solid fraction and a soluble organic fraction covering the carbon solid fraction, the process comprising the steps of: subjecting the soluble organic fraction to the reaction with oxygen under the presence of a catalyst to oxidize the soluble organic fraction; generating plasma in the exhaust gas to produce plasma excited species; and oxidizing the carbon solid fraction by the plasma excited species.
5. A process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like according to claim 4 , wherein the catalyst is at least one selected from the group consisting of Pt, Pd, Rh, Cu Ag and Au.
6. A process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like according to claim 4 or 5, wherein, in plasma generating conditions, an intensity E of electric field is set at a value equal to or larger than 3.0 kV/mm, and a power density Dw is set at a value equal to or larger than 1 W/cm3.
7. A process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like according to claim 4 , 5 or 6, wherein the surface of at least one of opposed electrodes which is opposed to the other electrode is covered with a dielectric.
8. A process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like, comprising the steps of: generating plasma in the exhaust gas discharged from the lean burn engine and containing the particulate material to produce a plurality of nitrogen dioxide molecules and a plurality of ozone molecules; and oxidizing the particulate material by the nitrogen dioxide molecules and the ozone molecules.
9. A process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine, comprising the steps of: generating plasma in the exhaust gas discharged from the lean burn engine and containing the particulate material to produce a plurality of nitrogen dioxide molecules and a plurality of ozone molecules; oxidizing the particulate material by the nitrogen dioxide molecules and-the ozone molecules; and subjecting the particulate material to the reaction with the nitrogen dioxide molecules and the ozone molecules in the presence of a catalyst to oxidize the particulate material.
10. A process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like according to claim 9 , wherein the catalyst is at least one selected from the group consisting of Pt, Pd, Rh, Cu Ag and Au.
11. A process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like according to claim 8 , 9 or 10, wherein, in plasma generating conditions, an intensity E of electric field is set at a value equal to or larger than 3.0 kV/mm, and a power density Dw is set at a value equal to or larger than 1 W/cm3.
12. A process for decreasing the content of a particulate material contained in an exhaust gas from a lean burn engine or the like according to claim 8 , 9, 10 or 11, wherein the surface of at least one of opposed electrodes which is opposed to the other electrode is covered with a dielectric.
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002337834A JP2004169643A (en) | 2002-11-21 | 2002-11-21 | Method for reducing particulate substance that exhaust gas in lean burn engine contains |
JP2002-337832 | 2002-11-21 | ||
JP2002-337834 | 2002-11-21 | ||
JP2002337832A JP3803633B2 (en) | 2002-11-21 | 2002-11-21 | Method for reducing particulate matter contained in exhaust gas of diesel engine |
JP2002-337833 | 2002-11-21 | ||
JP2002337833A JP3819833B2 (en) | 2002-11-21 | 2002-11-21 | Method for reducing particulate matter contained in exhaust gas of diesel engine |
Publications (1)
Publication Number | Publication Date |
---|---|
US20040168429A1 true US20040168429A1 (en) | 2004-09-02 |
Family
ID=32314790
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/717,898 Abandoned US20040168429A1 (en) | 2002-11-21 | 2003-11-21 | Process for decreasing content of particulate material contained in exhaust gas from lean burn engine or the like |
Country Status (3)
Country | Link |
---|---|
US (1) | US20040168429A1 (en) |
EP (1) | EP1426102B1 (en) |
DE (1) | DE60314220T2 (en) |
Cited By (3)
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US20080124264A1 (en) * | 2006-11-29 | 2008-05-29 | Ict Co., Ltd. | Oxidation Catalyst and Exhaust-Gas Purification System Using the Same |
US20100218595A1 (en) * | 2004-02-16 | 2010-09-02 | Measurement Techonology Laboratories Corporation | Particulate filter and method of use |
WO2014160679A1 (en) * | 2013-03-27 | 2014-10-02 | Lockheed Martin Corporation | Reactants sprayed into plasma flow for rocket propulsion |
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Publication number | Priority date | Publication date | Assignee | Title |
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JP2005291071A (en) | 2004-03-31 | 2005-10-20 | Honda Motor Co Ltd | Exhaust emission control system and exhaust emission control method |
JP2006261040A (en) | 2005-03-18 | 2006-09-28 | Ngk Insulators Ltd | Plasma reactor |
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AT2330U1 (en) * | 1997-06-17 | 1998-08-25 | Fleck Carl M Dr | DEVICE FOR DISSOCIATING NITROGEN OXIDES CONTAINED IN THE EXHAUST GAS FROM COMBUSTION ENGINES |
GB9924999D0 (en) * | 1999-10-22 | 1999-12-22 | Aea Technology Plc | Reactor for the plasma treatment of gases |
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2003
- 2003-11-20 DE DE60314220T patent/DE60314220T2/en not_active Expired - Fee Related
- 2003-11-20 EP EP03026810A patent/EP1426102B1/en not_active Expired - Lifetime
- 2003-11-21 US US10/717,898 patent/US20040168429A1/en not_active Abandoned
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US6029442A (en) * | 1996-12-18 | 2000-02-29 | Litex, Inc. | Method and apparatus for using free radicals to reduce pollutants in the exhaust gases from the combustion of fuel |
US6321531B1 (en) * | 1996-12-18 | 2001-11-27 | Litex, Inc. | Method and apparatus for using free radicals to reduce pollutants in the exhaust gases from the combustion of a fuel |
US6330794B1 (en) * | 1996-12-18 | 2001-12-18 | Litex, Inc. | Method and apparatus for using free radicals to reduce pollutants in the exhaust gases from the combustion of a fuel |
US6479023B1 (en) * | 1999-08-14 | 2002-11-12 | Johnson Matthey Public Limited Company | System for converting particulate matter in gasoline engine exhaust gases |
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US20100218595A1 (en) * | 2004-02-16 | 2010-09-02 | Measurement Techonology Laboratories Corporation | Particulate filter and method of use |
US20130125623A1 (en) * | 2004-02-16 | 2013-05-23 | Measurement Technology Laboratories, Llc | Particulate filter and method of use |
US8555700B2 (en) * | 2004-02-16 | 2013-10-15 | Measurement Technology Laboratories, Llc | Particulate filter and method of use |
US20080124264A1 (en) * | 2006-11-29 | 2008-05-29 | Ict Co., Ltd. | Oxidation Catalyst and Exhaust-Gas Purification System Using the Same |
EP1941942A2 (en) | 2006-11-29 | 2008-07-09 | ICT Co., Ltd. | Oxidation Catalyst and Exhaust-Gas Purification System Using the Same |
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US8034311B2 (en) | 2006-11-29 | 2011-10-11 | Ict Co., Ltd. | Oxidation catalyst and exhaust-gas purification system using the same |
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WO2014160679A1 (en) * | 2013-03-27 | 2014-10-02 | Lockheed Martin Corporation | Reactants sprayed into plasma flow for rocket propulsion |
Also Published As
Publication number | Publication date |
---|---|
EP1426102B1 (en) | 2007-06-06 |
EP1426102A2 (en) | 2004-06-09 |
DE60314220D1 (en) | 2007-07-19 |
EP1426102A3 (en) | 2005-08-24 |
DE60314220T2 (en) | 2007-09-20 |
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