US20040104211A1 - Heater and method of manufacturing same - Google Patents
Heater and method of manufacturing same Download PDFInfo
- Publication number
- US20040104211A1 US20040104211A1 US10/639,765 US63976503A US2004104211A1 US 20040104211 A1 US20040104211 A1 US 20040104211A1 US 63976503 A US63976503 A US 63976503A US 2004104211 A1 US2004104211 A1 US 2004104211A1
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- substrate
- central axis
- heater element
- heater
- resistant
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 22
- 239000000758 substrate Substances 0.000 claims abstract description 206
- 238000010438 heat treatment Methods 0.000 claims abstract description 97
- 238000012545 processing Methods 0.000 claims abstract description 26
- 238000000227 grinding Methods 0.000 claims abstract description 5
- 238000009826 distribution Methods 0.000 claims description 35
- 238000000034 method Methods 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 238000011077 uniformity evaluation Methods 0.000 claims description 13
- 238000005245 sintering Methods 0.000 claims description 11
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims description 10
- 239000000919 ceramic Substances 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 239000010937 tungsten Substances 0.000 claims description 5
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 4
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 4
- 238000007731 hot pressing Methods 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims 2
- 230000000052 comparative effect Effects 0.000 description 17
- 230000002093 peripheral effect Effects 0.000 description 17
- 238000003754 machining Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 238000005259 measurement Methods 0.000 description 7
- 239000000843 powder Substances 0.000 description 5
- 239000004065 semiconductor Substances 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 230000012447 hatching Effects 0.000 description 3
- 238000005304 joining Methods 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000005476 soldering Methods 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67098—Apparatus for thermal treatment
- H01L21/67103—Apparatus for thermal treatment mainly by conduction
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/12—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
- H05B3/14—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
- H05B3/141—Conductive ceramics, e.g. metal oxides, metal carbides, barium titanate, ferrites, zirconia, vitrous compounds
- H05B3/143—Conductive ceramics, e.g. metal oxides, metal carbides, barium titanate, ferrites, zirconia, vitrous compounds applied to semiconductors, e.g. wafers heating
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
- H05B3/22—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible
- H05B3/26—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor mounted on insulating base
- H05B3/265—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor mounted on insulating base the insulating base being an inorganic material, e.g. ceramic
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/20—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater
- H05B3/22—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible
- H05B3/28—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor embedded in insulating material
- H05B3/283—Heating elements having extended surface area substantially in a two-dimensional plane, e.g. plate-heater non-flexible heating conductor embedded in insulating material the insulating material being an inorganic material, e.g. ceramic
Definitions
- the present invention relates to a heater used for heating a substrate, such as a semiconductor wafer and a liquid crystal substrate and to a method of manufacturing the same.
- a heater which heats a semiconductor wafer and the like has at least a substrate including a heating surface on which an object to be heated such as a wafer is placed and a resistant heater element embedded in this substrate.
- This heater is manufactured by discriminating a peripheral shape of the resistant heater element, determining a central axis of the resistant heater element by use of the peripheral shape as a reference and allowing the central axis of the resistant heater element and a central axis of the substrate to be the same axis.
- a peripheral portion of the resistant heater element can be discriminated by use of X-ray photography or the like in a case where the resistant heater element is embedded within the substrate.
- the peripheral portion thereof can be discriminated by use of an image processing technology or the like in a case where the resistant heater element is on a surface portion of the substrate.
- heat uniformity of the heater is conventionally evaluated once the heater is a finished body capable of electrical connection.
- An object of the present invention is to provide a heater including a heating surface, which is capable of obtaining required thermal uniformity, and a method of manufacturing the same.
- the required thermal uniformity described above means an even temperature distribution across a heating surface of a substrate.
- To obtain the required uniformity means to obtain a temperature distribution with a small temperature difference, to correct and change the temperature distribution into appropriate one corresponding to an environment for use in which a predetermined film is formed on a wafer, or to minimize variations of the temperature distribution between individual products.
- a heater according to an aspect of the present invention includes a plate-shaped substrate including a heating surface for heating an object to be heated and a resistant heater element provided in the substrate or on a surface thereof.
- a central axis C 1 of a circumscribed circle of the resistant heater element and a central axis C 2 of the substrate are not concentric and there is a gap between the two axes.
- a method of manufacturing a heater according to another aspect of the present invention includes forming a plate-shaped preliminary substrate which has a resistant heater element in the substrate or on a surface thereof and has a heating surface for heating an object to be heated on one side of the substrate; specifying a position of the central axis C 1 of the resistant heater element provided in the preliminary substrate; evaluating thermal uniformity of the heating surface of the preliminary substrate; specifying a position on the central axis C 2 of the substrate to be located in a position where the thermal uniformity of the heating surface is superior compared to the case where the central axis C 2 of the substrate is positioned at the central axis C 1 , based on the thermal evaluation result; and forming a substrate which has the central axis C 2 by performing grinding processing for the preliminary substrate.
- the thermal uniformity on the heating surface of the heater can be improved.
- FIG. 1A is a plan view of a heater of an embodiment of the present invention and FIG. 1B is a side view of FIG. 1A.
- FIGS. 2A to 2 D show states of a substrate constituting the heater of the embodiment and a resistant heater element disposed in the substrate.
- the substrate is partially broken.
- FIGS. 2C and 2D are cross-sectional views of the substrate.
- FIGS. 3A to 3 C are cross-sectional views showing other disposition states of a resistant heater element embedded within the substrate of the heater of the embodiment.
- FIG. 4 is a flowchart showing a method of manufacturing the heater of the embodiment.
- FIG. 5A is a plan view of a preliminary substrate which is formed in a preliminary substrate formation step S 1 of the embodiment and has a circular resistant heater element disposed thereon.
- FIG. 5B is a plan view of a preliminary substrate having a polygonal resistant heater element disposed thereon.
- FIG. 6A is an isothermal map on a heating surface of a heater of comparative example 1 and FIG. 6B is a graph showing a temperature distribution on a circumference of a circle with radius 138 mm of the heater of comparative example 1.
- FIG. 6C is an isothermal map on a heating surface of a heater of example 1 and FIG. 6D is a graph showing a temperature distribution on a circumference of a circle with radius 138 mm of the heater of example 1.
- FIG. 7 shows a way of shifting a position of a substrate central axis C 2 with respect to a preliminary substrate central axis C 3 and a resistant heater element central axis C 1 in a substrate center position determination step S 4 in example 1.
- FIG. 8A is an isothermal map on a heating surface of a heater of comparative example 2 and FIG. 8B is a graph showing a temperature distribution on a line passing through a substrate center C 1 of the heater of comparative example 2.
- FIG. 8C is an isothermal map on a heating surface of a heater of example 2 and
- FIG. 8D is a graph showing a temperature distribution on a line passing through a substrate center C 1 of the heater of example 2.
- FIG. 9 shows a way of shifting a position of a substrate central axis C 2 with respect to a preliminary substrate central axis C 3 and a resistant heater element central axis C 1 in a substrate center position determination step S 4 in example 2.
- a temperature distribution of a heating surface does not always show a symmetric distribution around a center of the substrate while setting the center of the substrate as a reference and a series of heating conditions including calcining, firing and the like, which are applied to the substrate in a manufacturing process, greatly affect the temperature distribution of the heating surface of the heater.
- the inventor has found out that, by providing a gap between the central axis of the resistant heater element and the central axis of the substrate, the heat uniformity on the heating surface of the substrate can be improved and, alternatively, the temperature distribution can be changed into a desired distribution. Furthermore, the inventor has also found out that the thermal uniformity of the heating surface of the substrate can be improved by evaluating a thermal uniformity after heat treatment including calcining or firing which affects the temperature distribution of the heating surface of the substrate and by adding a step of processing a substrate shape so as to enable the central axis of the substrate to be set with a gap between the central axis of the resistant heater element based on the evaluation result. Thus, the inventor has completed the present invention.
- the central axis of the resistant heater element means an axis which passes through a center of a circumscribed circle of a peripheral shape of the resistant heater element and is perpendicular to the heating surface of the substrate.
- the central axis of the resistant heater element means an axis which passes through a center of a circumscribed circle of a peripheral shape of a projected image of all the heater element units on the heating surface of the substrate and is perpendicular to the heating surface.
- the central axis of the resistant heater element is merely called a center of the resistant heater element
- the center means a position of the central axis of the resistant heater element on the heating surface of the substrate.
- the central axis of the substrate means an axis which passes through a center of a circumscribed circle having a peripheral shape of the heating surface of the substrate and is perpendicular to the heating surface.
- the center means the center of the circumscribed circle having the peripheral shape of the heating surface of the substrate.
- FIGS. 1A and 1B show a heater 1 as an embodiment of the present invention.
- This heater 1 includes at least a disc-shaped substrate 3 having a heating surface 2 for heating an object to be heated; and a resistant heater element 4 provided on this substrate 3 .
- a central axis of a circumscribed circle C of the resistant heater element 4 that is, a central axis C 1 of the resistant heater element 4 and a central axis C 2 of the substrate 3 are not located at the same position and there is a gap D between the central axes C 1 and C 2 .
- the central axis C 1 and the central axis C 2 are not concentric.
- the heater 1 heats the substrate and is preferably used for heating a semiconductor wafer, a crystalline substrate or the like as an object to be heated.
- the object is placed on the heating surface 2 of the heater 1 .
- the substrate 3 is formed by use of aluminum nitride, silicon carbide, silicon nitride, aluminum oxide, aluminum, and alloys thereof or stainless-steel.
- a thickness T of the substrate 3 is, for example, 0.5 mm to 30 mm.
- a peripheral shape of the substrate 3 may be not only a circle, as shown in FIG. 1A, but also a substantially regular polygon. When the peripheral shape of the substrate 3 is a circle, an axis which passes through a center of the circle and is perpendicular to the heating surface 2 becomes a central axis C 2 of the substrate.
- peripheral shape of the substrate 3 is a substantially regular polygon
- an axis which passes through a center of a circumscribed circle of the substantially regular polygon and is perpendicular to the heating surface becomes the central axis C 2 of the substrate.
- both sides of the substrate of the heater shown in FIGS. 1A and 1B have the same size and the same shape.
- the peripheral shape of the substrate 3 coincides with a peripheral shape of the heating surface 2 .
- the central axis C 2 of the substrate is determined by use of the peripheral shape of the heating surface 2 as a reference.
- the heating surface 2 of the substrate 3 may be flat as shown in FIG. 1B and may also have a recess having trenches in a region where the object to be heated is placed.
- the surface on which the object is placed can be embossed or can be formed as an uneven surface by providing grooves therein.
- the resistant heater element 4 is made of molybdenum, tungsten, a compound of tungsten and molybdenum, platinum or the like.
- the resistant heater element may have a linear shape, a mesh shape or a film shape.
- a linear shaped resistant heater element one obtained by folding coiled or ribbon-shaped metal or the like can be used. Bulk metal or printed metal paste may be used therefor.
- the resistant heater element may be embedded within the substrate 3 or may be formed by printing a metal paste on an exposed surface of the substrate 3 .
- the resistant heater element 4 is embedded within the substrate 3 as shown, for example, in FIGS. 2A, 2C and 2 D.
- the resistant heater element 4 may be disposed approximately in parallel with the heating surface 2 as shown in FIG. 2A or may be disposed so as to have its outer portion shallow and its central portion deep within the substrate 3 as shown in FIG. 2C.
- the resistant heater element 4 may be disposed so as to have its outer portion deep and its central portion shallow within the substrate 3 .
- the resistant heater element may be formed by paste printing on the side opposite to the heating surface 2 .
- a peripheral shape of the resistant heater element 4 may be either circular or polygonal.
- an axis which passes through a center of a circumscribed circle tangent to the peripheral shape of the resistant heater element and is perpendicular to the heating surface of the substrate 3 is set as a central axis of the resistant heater element 4 .
- FIGS. 5A and 5B show a preliminary substrate 10 formed in a preliminary substrate formation step in a method of manufacturing the heater of the present invention, which will be described later.
- a circular resistant heater element 4 is disposed in the preliminary substrate 10 shown in FIG. 5A and a square (regular polygonal) resistant heater element 4 is disposed in the preliminary substrate 10 shown in FIG. 5B.
- the two resistant heater elements pass through a center of a circumscribed circle C (indicated by a dashed line) tangent to the resistant heater element 4 and take an axis perpendicular to the heating surface as the central axis C 1 of the resistant heater element 4 .
- the heating surface 2 of the heater 1 is heated.
- there is a gap between the position of the central axis C 1 of the resistant heater element 4 and the position of the central axis C 2 of the substrate 3 and thermal uniformity of the heating surface 2 of the substrate 3 can be improved by means of this gap.
- the position of the central axis C 2 of the substrate 3 relative to that of the central axis C 1 of the resistant heater element 4 that is, the size and direction of the gap D are preferably set in such a manner that the heat uniformity on the heating surface of the substrate is superior compared to a case where the central axes C 1 and C 2 are positioned on the same axis.
- the gap D is preferably set within a range of 0.005 to 10 mm.
- a lower limit of the gap D is set to 0.005 mm, required thermal uniformity attributable to the gap can be achieved.
- an upper limit thereof is set to 10 mm, required thermal uniformity can be achieved by positioning the resistant heater element 4 while avoiding interference with other parts (not shown) provided on the substrate 3 such as a lift pin hole and a shaft.
- the lift pin hole and the shaft are provided by using the substrate central axis C 2 as a reference.
- the resistant heater element 4 interferes with the lift pin hole and the shaft and thus the thermal uniformity is lowered.
- the gap D is set more preferably to 0.01 mm to 8 mm and further preferably to 0.02 mm to 5 mm.
- the resistant heater element 4 can include one or a plurality of heater element units 41 , 42 , . . . which are provided in the substrate 3 .
- an axis which passes through a center of a circumscribed circle relative to a projected shape E to the heating surface 2 of the heater element units 41 , 42 , . . . and is perpendicular to the heating surface is set as the central axis C 1 of the resistant heater element 4 .
- the resistant heater element 4 shown in FIG. 3A includes two heater element units 41 and 42 which are disposed approximately in parallel with the heating surface 2 and have the same size.
- the resistant heater element 4 shown in FIG. 3B includes one heater element unit 43 disposed approximately in parallel with the heating surface 2 and a cone-shaped heater element unit 44 deep in its center.
- the resistant heater element 4 shown in FIG. 3C includes two heater element units 45 and 46 which are disposed approximately in parallel with the heating surface 2 and have different sizes from each other (the lower one is formed to be wider than the upper one).
- the resistant heater element 4 includes a plurality of heater element units 41 , 42 , . . .
- the respective heater element units can be disposed not only by changing the depth from the heating surface 2 as shown in FIGS. 3A to 3 C but also by arranging the plurality of heater element units at the same depth from the heating surface 2 .
- FIG. 4 is a flowchart of the manufacturing method.
- the method of manufacturing the heater 1 according to the embodiment has: a preliminary substrate formation step S 1 of forming a plate-shaped preliminary substrate 10 having two sides with a larger area than the substrate 3 ; a heater element center measurement step S 2 of specifying a position of the central axis of the resistant heater element 4 provided in the preliminary substrate 10 ; a heat uniformity evaluation S 3 of the preliminary substrate 10 ; a substrate center position determination step S 4 of specifying a position of the central axis C 2 of the substrate 3 , based on the heat uniformity evaluation result, in a direction in which required thermal uniformity can be obtained by use of the center C 1 of the resistant heater element 4 as a reference; and an eccentric machining step S 5 of obtaining the substrate 3 having the central axis C 2 by subjecting the preliminary substrate 10 to grinding processing. Furthermore, thereafter, in order to obtain a finished body, a final processing series step S 6 is added.
- the preliminary substrate 10 which has two sides with a larger area than the substrate 3 as the finished body is formed.
- ceramic powder such as aluminum nitride, silicon carbide, silicon nitride and aluminum oxide, for example, is filled into a mold and subjected to preliminary molding until the powder has a certain degree of hardness so as to obtain a preformed body.
- a recess corresponding to the shape of the resistant heater element is provided on a surface of the preformed body.
- the resistant heater element 4 made of a linear or mesh shaped metal bulk body is housed in the recess and is covered with the same ceramic powder.
- This embedding of the resistant heater element 4 is performed only once in the case of the heater 1 shown in FIGS. 2A to 2 D. However, the embedding thereof is performed for every heater element unit in the case of the heater 1 shown in FIGS. 3A to 3 D.
- FIGS. 5A and 5B show the preliminary substrates 10 in which the circular resistant heater element 4 is embedded and FIG. 5B shows the preliminary substrate 10 in which the square (regular polygonal) resistant heater element 4 is embedded.
- heat treatment is performed for a substrate material under various conditions in a process of sintering of a molded body or sintering by hot-pressing which are executed as needed.
- a substrate material for example, as the substrate material
- sintering is performed by holding the substrate material for about 2 to 6 hours at a temperature of 1700 to 1900° C.
- the method of manufacturing the preliminary substrate 10 is not particularly limited to the above.
- Various molding methods and other sintering methods such as a normal pressure sintering method can be also used.
- a plate-shaped molded body is formed by use of a ceramic green sheet and, thereafter, a pattern having a linear shape, a mesh shape or a film shape is printed on one side of the molded body by use of a metal paste such as tungsten or molybdenum. Thereafter, another ceramic green sheet is laminated thereon and sintering is performed.
- a metal plate having a groove to mount the resistant heater element is prepared and, after mounting the resistant heater element in the groove, another metal plate is laminated thereon. Subsequently, the two metal plates are integrated with each other by screwing, soldering or the like. Note that the periphery of the resistant heater element is covered with a heat-resistant insulating material so as to electrically isolate the resistant heater element from the metal plates.
- This preliminary substrate 10 is formed to have two sides with a larger area than the substrate 3 as the finished body, because of a processing area H.
- a processing area H In FIGS. 5A and 5B, an outline of the substrate 3 is indicated by a double dashed line.
- the width of processing area H is set to 5 mm or less, and more preferably to about 1.5 mm.
- the central axis C 1 of the resistant heater element provided on the preliminary substrate 10 is specified. Note that, in practice, specifying only a passing point of the central axis C 1 of the resistant heater element in the heating surface 2 of the preliminary substrate 10 , that is, specifying the center C 1 of the resistant heater element is sufficient.
- central axis C 3 of the preliminary substrate 10 and the central axis C 1 of the resistant heater element 4 are set on approximately the same axis.
- the temperature distribution on the surface of the preliminary substrate 10 , to be the heating surface 2 is measured by use of, for example, an infrared thermometer. This measurement of the temperature distribution is performed after processing the preliminary substrate 10 to have a shape required for the measurement.
- the position of the central axis C 2 is set to be located in a position where heat uniformity is superior compared to a case where the central axis C 2 of the substrate and the central axis C 1 of the resistant heater element are located on the same axis in the finished substrate.
- a direction of a positional deviation of the central axis C 2 of the substrate 3 and the gap D thereof are set by use of the central axis C 1 of the resistant heater element 4 as a reference. Note that, in practice, specifying only a passing point of the central axis C 1 of the substrate 3 in the heating surface 2 of the preliminary substrate 10 , that is, specifying the center C 1 of the substrate 3 is sufficient.
- the direction of a positional deviation (a direction of an arrow K 1 of FIG. 7 or an arrow K 2 of FIG. 9) and the gap D, which are set in the previous step S 4 , are entered into, for example, an NC processing machine and its offset function processes the preliminary substrate 10 by using the specified position of the central axis C 2 as a processing centel
- a grinded area J 1 see FIG. 7
- a grinded area J 2 see FIG. 9
- the final processing step S 6 has: a primary substrate processing step S 61 of providing a lift pin hole in the substrate 3 and processing the substrate 3 into a shape required for shaft junction of the next step; a shaft junction step S 62 of joining a shaft with the substrate 3 ; a secondary substrate processing step S 63 of finishing the entire body into a final shape; a terminal junction step S 64 of joining terminals with both ends of the resistant heater element 4 and connecting power supply components to the terminals; and a finished body heat uniformity evaluation step S 65 of checking the quality of a finished body.
- a substrate which has passed in the finished body heat uniformity evaluation step S 65 becomes a finished body.
- this final processing step S 6 can leave out the shaft junction step S 62 and the secondary substrate processing step S 63 therefrom.
- the lift pin is a pin which pushes the substrate up in detaching the substrate mounted on the heating surface.
- the shaft junction step S 62 when the substrate is made of a ceramic material, the shaft is formed by using the same ceramic material and is joined with the substrate 3 by integral junction or by seal junction using an O-ring, metal packing or the like. In a case of subjecting the shaft and the substrate 3 to solid-phase bonding, those two are joined together by performing heat treatment under a high temperature condition close to a sintering temperature. Note that the thermal uniformity of the heating surface of the substrate 3 is most affected by a heat treatment condition in performing sintering of ceramics that is the substrate material in the preliminary substrate formation step S 1 and is less affected by heat treatment performed for joining the substrate with the shaft. Therefore, the heat uniformity evaluation of the heating surface of the substrate 3 , which is performed before specifying the position of the central axis C 2 of the substrate 3 , is preferably performed after the step of sintering the preliminary substrate 10 .
- the entire shape including the shaft undergoes finishing processing.
- metal is preferable, particularly nickel (Ni).
- Ni nickel
- the power supply component is applied in a shape of a rod or a wire.
- screwing, caulking, engaging, soldering, welding, eutectic bonding and the like are applicable.
- the temperature distribution in the heating surface of the substrate 3 can be adjusted to have a required temperature distribution and the thermal uniformity can be improved.
- Comparative example 1 is a conventional heater 100 in which the central axis C 2 of the substrate 3 and the central axis C 1 of the resistant heater element are on the same axis, that is, are concentric.
- the substrate 3 of the heater 100 is made of aluminum nitride and is a disc of ⁇ 335 mm ⁇ 15 mm of thickness T.
- the resistant heater element 4 is formed of a molybdenum coil and is embedded within the substrate 3 as shown in FIG. 2A.
- FIGS. 6A and 6B show temperature distributions in the heating surface 2 of the heater 100 .
- results obtained by measuring temperatures on the heating surface 2 by use of an infrared thermometer are indicated by isothermal curves F on the heating surface 2 .
- the temperature distribution shown in FIG. 6B indicates a distribution of temperatures at twelve measuring points on the heating surface 2 which are set at even intervals on the circumference of a circle with radius 138 mm which takes the substrate center C 2 as a reference. Note that a set temperature is 525° C.
- Example 1 is a heater 1 in which the central axis C 2 of the substrate 3 and the central axis C 1 of the resistant heater element are set by leaving a gap therebetween.
- the central axis C 1 of the resistant heater element 4 is set below the central axis C 2 of the substrate 3 at an angle to the left of C 2 on the drawing.
- the gap D between the central axes C 1 and C 2 is 1.5 mm.
- the substrate 3 of the heater 1 is made of aluminum nitride and is a disc of ⁇ 335 mm ⁇ 15 mm of thickness T.
- the materials, shapes and sizes of the substrate 3 and the resistant heater element are the same as those of comparative example 1.
- FIGS. 6C and 6D show temperature distributions in the heating surface 2 .
- the measurement conditions of the temperature distributions and the method of displaying the temperature distributions are the same as those of comparative example 1.
- FIG. 7 shows the preliminary substrate 10 , the position of the central axis C 1 of the resistant heater element, which is specified in the heater element center measurement step S 2 , the temperature distribution (isothermal curves) on the heating surface, which is obtained in the heat uniformity evaluation step S 3 , and the position of the central axis C 2 of the substrate 3 , which is specified in the substrate center position determination step. Furthermore, in FIG. 7, a grinded area in the eccentric machining step S 5 is denoted by J 1 .
- a hot portion A emerges in an area (indicated by hatching) which spreads upward at an angle to the right from a central portion of the preliminary substrate 10 and a cool portion B emerges in a lower left area (indicated by cross-hatching) of the preliminary substrate 10 .
- the position of the central axis C 2 of the substrate 3 as the finished body is set at a position shifted by 1.5 mm in a direction of the arrow K 1 passing the center C 1 of the heater element 4 and facing the hot portion A from the cool portion B.
- the substrate 3 having the central axis C 2 is obtained after the eccentric machining step S 5 .
- the heater 1 of example 1 has fewer isothermal curves F and has achieved evenness of heat across the entire heating surface 2 .
- the heater 100 has ⁇ 1.3% but the heater 1 is improved to have ⁇ 0.5%
- a heater 100 of comparative example 2 is a conventional heater 100 in which the central axis C 2 of the substrate 3 and the central axis C 1 of the resistant heater element are on the same axis, that is, are concentric.
- the substrate 3 of the heater 100 is made of aluminum nitride and is a disc of ⁇ 340 mm ⁇ 17 mm of thickness T.
- the resistant heater element 4 includes: a first heater element unit 5 disposed in a region which is 6.5 mm deep from the heating surface 2 ; and a second heater element unit 5 disposed in a region which is 12 mm deep from the heating surface 2 . Therefore, the circumscribed circle C of the resistant heater element 4 is a circumscribed circle abutting on the periphery of the projected shape of the first and second heater element units 41 and 42 .
- FIGS. 8A and 8B show temperature distributions in the heating surface 2 of the heater 100 of comparative example 2.
- results obtained by measuring temperatures on the heating surface 2 by use of an infrared thermometer are indicated by isothermal curves F on the heating surface 2 .
- the temperature distribution shown in FIG. 8B indicates a distribution of temperatures at five measuring points G 1 to G 5 on the heating surface 2 which are set at even intervals on a diameter passing through the substrate center C 2 . Note that a set temperature is 600° C.
- Example 2 is a heater 1 in which the central axis C 2 of the substrate 3 and the central axis C 1 of the resistant heater element are set by leaving a gap therebetween. As shown in FIG. 8C, in this heater 1 , the position of the central axis C 1 of the resistant heater element 4 is set to the left of the position of the central axis C 2 of the substrate in a horizontal direction on the drawing. The gap D between the central axes C 1 and C 2 is 1.0 mm.
- the substrate 3 of the heater 1 of example 2 is made of aluminum nitride and is a disc of ⁇ 335 mm ⁇ 15 mm of thickness T.
- the materials, shapes and sizes of the substrate 3 and the resistant heater element are the same as those of comparative example 2.
- FIG. 9 shows the position of the central axis C 1 of the resistant heater element, which is specified in the heater element center measurement step S 2 , the temperature distribution (isothermal curves) on the heating surface, which is obtained in the heat uniformity evaluation step S 3 , and the position of the central axis C 2 of the substrate 3 , which is specified in the substrate center position determination step, in the preliminary substrate 10 . Furthermore, in FIG. 9, a region to be deleted in the eccentric machining step S 5 is denoted by J 2 .
- a hot portion A emerges in an area (indicated by hatching) at a right end along a horizontal diameter of the preliminary substrate 10 and a cool portion B emerges in an area (indicated by cross-hatching) at a left end along the horizontal diameter of the preliminary substrate 10 .
- the position of the central axis C 2 of the substrate 3 as the finished body is set at a position shifted by 1.0 mm in a direction of the arrow K 2 passing the center C 1 of the heater element 4 and facing the hot portion A from the cool portion B.
- the substrate 3 having the central axis C 2 is obtained after the eccentric machining step S 5 .
- the central axis of the resistant heater element and the central axis of the substrate are not on the same axis and a predetermined gap is provided between the both central axes.
- the heating surface of the substrate can be set to have a temperature distribution achieving a desired heat uniformity.
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Abstract
A heater includes a plate-shaped substrate having a heating surface for heating an object to be heated and a heater element provided in the substrate or on a surface thereof. A central axis C2 of a circumscribed circle of the resistant heater element and a central axis C1 of the substrate are not on the same axis and there is a gap between these two axes. In a method of manufacturing the heater, a central axis C1 of a resistant heater is specified, thermal uniformity of the heating surface of a preliminary substrate is evaluated, and a central axis C2 of the substrate is specified. The central axis C2 is specified at a position where the thermal uniformity of the heating surface is superior to a case where the central axis C2 of the substrate is located on the central axis C1. Then a substrate having the central axis C2 is formed by subjecting the preliminary substrate to grinding processing.
Description
- This application is based upon and claims the benefit of priority from prior Japanese Patent Application No. 2002-241119, filed on Aug. 21, 2002; the entire contents of which are incorporated herein by reference.
- 1. Field of the Invention
- The present invention relates to a heater used for heating a substrate, such as a semiconductor wafer and a liquid crystal substrate and to a method of manufacturing the same.
- 2. Description of the Related Art
- In general, a heater which heats a semiconductor wafer and the like has at least a substrate including a heating surface on which an object to be heated such as a wafer is placed and a resistant heater element embedded in this substrate.
- This heater is manufactured by discriminating a peripheral shape of the resistant heater element, determining a central axis of the resistant heater element by use of the peripheral shape as a reference and allowing the central axis of the resistant heater element and a central axis of the substrate to be the same axis. A peripheral portion of the resistant heater element can be discriminated by use of X-ray photography or the like in a case where the resistant heater element is embedded within the substrate. Alternatively, the peripheral portion thereof can be discriminated by use of an image processing technology or the like in a case where the resistant heater element is on a surface portion of the substrate.
- Moreover, heat uniformity of the heater is conventionally evaluated once the heater is a finished body capable of electrical connection.
- In recent years, regarding a heater which heats a semiconductor wafer or the like, since thermal uniformity thereof directly affects a yield of an element, requirements for the thermal uniformity on a heating surface of the heater have become more and more strict. It is required to set the thermal uniformity to t ° C.±1.0% or less for a predetermined temperature (t ° C.) and to minimize the fluctuation range of temperature for a predetermined temperature distribution.
- However, conventionally, since the thermal uniformity has been evaluated for the finished body after the heater has been brought to completion, the heat uniformity has never been confirmed in the middle of the manufacturing process thereof. Moreover, the size of the finished body is already determined based on a relationship between the heater and a semiconductor manufacturing apparatus incorporating the heater built therein. Thus, it was not easily possible to change a shape of the heater in order to improve thermal uniformity and the like.
- An object of the present invention is to provide a heater including a heating surface, which is capable of obtaining required thermal uniformity, and a method of manufacturing the same.
- The required thermal uniformity described above means an even temperature distribution across a heating surface of a substrate. To obtain the required uniformity means to obtain a temperature distribution with a small temperature difference, to correct and change the temperature distribution into appropriate one corresponding to an environment for use in which a predetermined film is formed on a wafer, or to minimize variations of the temperature distribution between individual products.
- In order to accomplish the object of the present invention, a heater according to an aspect of the present invention includes a plate-shaped substrate including a heating surface for heating an object to be heated and a resistant heater element provided in the substrate or on a surface thereof. A central axis C1 of a circumscribed circle of the resistant heater element and a central axis C2 of the substrate are not concentric and there is a gap between the two axes.
- A method of manufacturing a heater according to another aspect of the present invention includes forming a plate-shaped preliminary substrate which has a resistant heater element in the substrate or on a surface thereof and has a heating surface for heating an object to be heated on one side of the substrate; specifying a position of the central axis C1 of the resistant heater element provided in the preliminary substrate; evaluating thermal uniformity of the heating surface of the preliminary substrate; specifying a position on the central axis C2 of the substrate to be located in a position where the thermal uniformity of the heating surface is superior compared to the case where the central axis C2 of the substrate is positioned at the central axis C1, based on the thermal evaluation result; and forming a substrate which has the central axis C2 by performing grinding processing for the preliminary substrate.
- According to the heater of the present invention and the manufacturing method thereof, by shifting the position of the central axis C2 of the substrate from that of the central axis C1 of the circumscribed circle of the resistant heater element, the thermal uniformity on the heating surface of the heater can be improved.
- FIG. 1A is a plan view of a heater of an embodiment of the present invention and FIG. 1B is a side view of FIG. 1A.
- FIGS. 2A to2D show states of a substrate constituting the heater of the embodiment and a resistant heater element disposed in the substrate. In FIGS. 2A and 2B, the substrate is partially broken. FIGS. 2C and 2D are cross-sectional views of the substrate.
- FIGS. 3A to3C are cross-sectional views showing other disposition states of a resistant heater element embedded within the substrate of the heater of the embodiment.
- FIG. 4 is a flowchart showing a method of manufacturing the heater of the embodiment.
- FIG. 5A is a plan view of a preliminary substrate which is formed in a preliminary substrate formation step S1 of the embodiment and has a circular resistant heater element disposed thereon. FIG. 5B is a plan view of a preliminary substrate having a polygonal resistant heater element disposed thereon.
- FIG. 6A is an isothermal map on a heating surface of a heater of comparative example 1 and FIG. 6B is a graph showing a temperature distribution on a circumference of a circle with radius 138 mm of the heater of comparative example 1.
- FIG. 6C is an isothermal map on a heating surface of a heater of example 1 and FIG. 6D is a graph showing a temperature distribution on a circumference of a circle with radius 138 mm of the heater of example 1.
- FIG. 7 shows a way of shifting a position of a substrate central axis C2 with respect to a preliminary substrate central axis C3 and a resistant heater element central axis C1 in a substrate center position determination step S4 in example 1.
- FIG. 8A is an isothermal map on a heating surface of a heater of comparative example 2 and FIG. 8B is a graph showing a temperature distribution on a line passing through a substrate center C1 of the heater of comparative example 2. FIG. 8C is an isothermal map on a heating surface of a heater of example 2 and FIG. 8D is a graph showing a temperature distribution on a line passing through a substrate center C1 of the heater of example 2.
- FIG. 9 shows a way of shifting a position of a substrate central axis C2 with respect to a preliminary substrate central axis C3 and a resistant heater element central axis C1 in a substrate center position determination step S4 in example 2.
- The inventor of this application has studied the properties of various heaters, each of which has a central axis of a substrate and a central axis of a resistant heater element on the same axis. Through this study, the inventor has found out the following. Specifically, a temperature distribution of a heating surface does not always show a symmetric distribution around a center of the substrate while setting the center of the substrate as a reference and a series of heating conditions including calcining, firing and the like, which are applied to the substrate in a manufacturing process, greatly affect the temperature distribution of the heating surface of the heater.
- Based on the above knowledge, the inventor has found out that, by providing a gap between the central axis of the resistant heater element and the central axis of the substrate, the heat uniformity on the heating surface of the substrate can be improved and, alternatively, the temperature distribution can be changed into a desired distribution. Furthermore, the inventor has also found out that the thermal uniformity of the heating surface of the substrate can be improved by evaluating a thermal uniformity after heat treatment including calcining or firing which affects the temperature distribution of the heating surface of the substrate and by adding a step of processing a substrate shape so as to enable the central axis of the substrate to be set with a gap between the central axis of the resistant heater element based on the evaluation result. Thus, the inventor has completed the present invention.
- Note that, in the present invention, the central axis of the resistant heater element means an axis which passes through a center of a circumscribed circle of a peripheral shape of the resistant heater element and is perpendicular to the heating surface of the substrate. Moreover, when the resistant heater element includes a plurality of heater element units, the central axis of the resistant heater element means an axis which passes through a center of a circumscribed circle of a peripheral shape of a projected image of all the heater element units on the heating surface of the substrate and is perpendicular to the heating surface. When the central axis of the resistant heater element is merely called a center of the resistant heater element, the center means a position of the central axis of the resistant heater element on the heating surface of the substrate.
- Moreover, in the present invention, the central axis of the substrate means an axis which passes through a center of a circumscribed circle having a peripheral shape of the heating surface of the substrate and is perpendicular to the heating surface. When the central axis of the substrate is merely called a center of the substrate, the center means the center of the circumscribed circle having the peripheral shape of the heating surface of the substrate.
- With reference to the drawings, embodiments of the present invention will be described below.
- FIGS. 1A and 1B show a
heater 1 as an embodiment of the present invention. Thisheater 1 includes at least a disc-shapedsubstrate 3 having aheating surface 2 for heating an object to be heated; and aresistant heater element 4 provided on thissubstrate 3. As shown in FIG. 1A, a central axis of a circumscribed circle C of theresistant heater element 4, that is, a central axis C1 of theresistant heater element 4 and a central axis C2 of thesubstrate 3 are not located at the same position and there is a gap D between the central axes C1 and C2. Namely the central axis C1 and the central axis C2 are not concentric. - The
heater 1 heats the substrate and is preferably used for heating a semiconductor wafer, a crystalline substrate or the like as an object to be heated. The object is placed on theheating surface 2 of theheater 1. - The
substrate 3 is formed by use of aluminum nitride, silicon carbide, silicon nitride, aluminum oxide, aluminum, and alloys thereof or stainless-steel. A thickness T of thesubstrate 3 is, for example, 0.5 mm to 30 mm. A peripheral shape of thesubstrate 3 may be not only a circle, as shown in FIG. 1A, but also a substantially regular polygon. When the peripheral shape of thesubstrate 3 is a circle, an axis which passes through a center of the circle and is perpendicular to theheating surface 2 becomes a central axis C2 of the substrate. On the other hand, when the peripheral shape of thesubstrate 3 is a substantially regular polygon, an axis which passes through a center of a circumscribed circle of the substantially regular polygon and is perpendicular to the heating surface becomes the central axis C2 of the substrate. - Note that both sides of the substrate of the heater shown in FIGS. 1A and 1B have the same size and the same shape. Thus, the peripheral shape of the
substrate 3 coincides with a peripheral shape of theheating surface 2. However, when theheating surface 2 and the side opposite thereto have different sizes and shapes from each other, the central axis C2 of the substrate is determined by use of the peripheral shape of theheating surface 2 as a reference. - Moreover, the
heating surface 2 of thesubstrate 3 may be flat as shown in FIG. 1B and may also have a recess having trenches in a region where the object to be heated is placed. Alternatively, the surface on which the object is placed can be embossed or can be formed as an uneven surface by providing grooves therein. - Further, the
resistant heater element 4 is made of molybdenum, tungsten, a compound of tungsten and molybdenum, platinum or the like. The resistant heater element may have a linear shape, a mesh shape or a film shape. As a linear shaped resistant heater element, one obtained by folding coiled or ribbon-shaped metal or the like can be used. Bulk metal or printed metal paste may be used therefor. The resistant heater element may be embedded within thesubstrate 3 or may be formed by printing a metal paste on an exposed surface of thesubstrate 3. - The
resistant heater element 4 is embedded within thesubstrate 3 as shown, for example, in FIGS. 2A, 2C and 2D. Theresistant heater element 4 may be disposed approximately in parallel with theheating surface 2 as shown in FIG. 2A or may be disposed so as to have its outer portion shallow and its central portion deep within thesubstrate 3 as shown in FIG. 2C. Alternatively, as shown in FIG. 2D, theresistant heater element 4 may be disposed so as to have its outer portion deep and its central portion shallow within thesubstrate 3. Moreover, as shown in FIG. 2B, the resistant heater element may be formed by paste printing on the side opposite to theheating surface 2. - Furthermore, a peripheral shape of the
resistant heater element 4 may be either circular or polygonal. When the peripheral shape of theresistant heater element 4 is polygonal, an axis which passes through a center of a circumscribed circle tangent to the peripheral shape of the resistant heater element and is perpendicular to the heating surface of thesubstrate 3 is set as a central axis of theresistant heater element 4. - FIGS. 5A and 5B show a
preliminary substrate 10 formed in a preliminary substrate formation step in a method of manufacturing the heater of the present invention, which will be described later. A circularresistant heater element 4 is disposed in thepreliminary substrate 10 shown in FIG. 5A and a square (regular polygonal)resistant heater element 4 is disposed in thepreliminary substrate 10 shown in FIG. 5B. The two resistant heater elements pass through a center of a circumscribed circle C (indicated by a dashed line) tangent to theresistant heater element 4 and take an axis perpendicular to the heating surface as the central axis C1 of theresistant heater element 4. - By sending electricity to the
resistant heater element 4, theheating surface 2 of theheater 1 is heated. In the heater according to this embodiment, there is a gap between the position of the central axis C1 of theresistant heater element 4 and the position of the central axis C2 of thesubstrate 3 and thermal uniformity of theheating surface 2 of thesubstrate 3 can be improved by means of this gap. The position of the central axis C2 of thesubstrate 3 relative to that of the central axis C1 of theresistant heater element 4, that is, the size and direction of the gap D are preferably set in such a manner that the heat uniformity on the heating surface of the substrate is superior compared to a case where the central axes C1 and C2 are positioned on the same axis. - The gap D is preferably set within a range of 0.005 to 10 mm. When a lower limit of the gap D is set to 0.005 mm, required thermal uniformity attributable to the gap can be achieved. At the same time, when an upper limit thereof is set to 10 mm, required thermal uniformity can be achieved by positioning the
resistant heater element 4 while avoiding interference with other parts (not shown) provided on thesubstrate 3 such as a lift pin hole and a shaft. - The lift pin hole and the shaft are provided by using the substrate central axis C2 as a reference. Thus, when the gap D exceeds 10 mm, the
resistant heater element 4 interferes with the lift pin hole and the shaft and thus the thermal uniformity is lowered. Besides, particularly in the case of a heater with a shaft attached thereto, it becomes difficult to take out rods (not shown) which are provided in the shaft in order to connect terminals connected to both ends of theresistant heater element 4 with external connectors. Consequently, the gap D is set more preferably to 0.01 mm to 8 mm and further preferably to 0.02 mm to 5 mm. - Moreover, as shown in FIGS. 3A to3C, in the
heater 1, theresistant heater element 4 can include one or a plurality ofheater element units substrate 3. In this case, an axis which passes through a center of a circumscribed circle relative to a projected shape E to theheating surface 2 of theheater element units resistant heater element 4. - The
resistant heater element 4 shown in FIG. 3A includes twoheater element units heating surface 2 and have the same size. Theresistant heater element 4 shown in FIG. 3B includes oneheater element unit 43 disposed approximately in parallel with theheating surface 2 and a cone-shapedheater element unit 44 deep in its center. Theresistant heater element 4 shown in FIG. 3C includes twoheater element units heating surface 2 and have different sizes from each other (the lower one is formed to be wider than the upper one). - Note that, when the
resistant heater element 4 includes a plurality ofheater element units heating surface 2 as shown in FIGS. 3A to 3C but also by arranging the plurality of heater element units at the same depth from theheating surface 2. - Next, the method of manufacturing the heater according to the embodiment will be described.
- FIG. 4 is a flowchart of the manufacturing method. The method of manufacturing the
heater 1 according to the embodiment has: a preliminary substrate formation step S1 of forming a plate-shapedpreliminary substrate 10 having two sides with a larger area than thesubstrate 3; a heater element center measurement step S2 of specifying a position of the central axis of theresistant heater element 4 provided in thepreliminary substrate 10; a heat uniformity evaluation S3 of thepreliminary substrate 10; a substrate center position determination step S4 of specifying a position of the central axis C2 of thesubstrate 3, based on the heat uniformity evaluation result, in a direction in which required thermal uniformity can be obtained by use of the center C1 of theresistant heater element 4 as a reference; and an eccentric machining step S5 of obtaining thesubstrate 3 having the central axis C2 by subjecting thepreliminary substrate 10 to grinding processing. Furthermore, thereafter, in order to obtain a finished body, a final processing series step S6 is added. - In the preliminary substrate formation step S1, the
preliminary substrate 10 which has two sides with a larger area than thesubstrate 3 as the finished body is formed. Specifically, in the preliminary substrate formation step S1, ceramic powder such as aluminum nitride, silicon carbide, silicon nitride and aluminum oxide, for example, is filled into a mold and subjected to preliminary molding until the powder has a certain degree of hardness so as to obtain a preformed body. In this process, on a surface of the preformed body, a recess corresponding to the shape of the resistant heater element is provided. Theresistant heater element 4 made of a linear or mesh shaped metal bulk body is housed in the recess and is covered with the same ceramic powder. With this process, an element for a high frequency electrode and an element for an electrostatic chuck can be simultaneously embedded. - This embedding of the
resistant heater element 4 is performed only once in the case of theheater 1 shown in FIGS. 2A to 2D. However, the embedding thereof is performed for every heater element unit in the case of theheater 1 shown in FIGS. 3A to 3D. - Thereafter, aluminum nitride powder is subjected to uniaxial pressure molding to provide a disc-shaped molded body, and then the molded body is sintered by hot-pressing. Thus, the
preliminary substrates 10 shown in FIGS. 5A and 5B can be formed. FIG. 5A shows thepreliminary substrate 10 in which the circularresistant heater element 4 is embedded and FIG. 5B shows thepreliminary substrate 10 in which the square (regular polygonal)resistant heater element 4 is embedded. - In the preliminary substrate formation step, heat treatment is performed for a substrate material under various conditions in a process of sintering of a molded body or sintering by hot-pressing which are executed as needed. When an aluminum nitride powder is used, for example, as the substrate material, sintering is performed by holding the substrate material for about 2 to 6 hours at a temperature of 1700 to 1900° C.
- Note that the method of manufacturing the
preliminary substrate 10 is not particularly limited to the above. Various molding methods and other sintering methods such as a normal pressure sintering method can be also used. - Moreover, when a printed electrode is formed as the resistant heater element, a plate-shaped molded body is formed by use of a ceramic green sheet and, thereafter, a pattern having a linear shape, a mesh shape or a film shape is printed on one side of the molded body by use of a metal paste such as tungsten or molybdenum. Thereafter, another ceramic green sheet is laminated thereon and sintering is performed.
- When metal such as aluminum or stainless steel is used as the substrate material, for example, a metal plate having a groove to mount the resistant heater element is prepared and, after mounting the resistant heater element in the groove, another metal plate is laminated thereon. Subsequently, the two metal plates are integrated with each other by screwing, soldering or the like. Note that the periphery of the resistant heater element is covered with a heat-resistant insulating material so as to electrically isolate the resistant heater element from the metal plates.
- This
preliminary substrate 10 is formed to have two sides with a larger area than thesubstrate 3 as the finished body, because of a processing area H. In FIGS. 5A and 5B, an outline of thesubstrate 3 is indicated by a double dashed line. When the processing area H is large, the burden on later grinding processing is large. Thus, in consideration of the above point, the width of processing area H is set to 5 mm or less, and more preferably to about 1.5 mm. - In the heater element center measurement step S2, by use of, for example, X-ray photography, image processing technologies or the like, the central axis C1 of the resistant heater element provided on the
preliminary substrate 10 is specified. Note that, in practice, specifying only a passing point of the central axis C1 of the resistant heater element in theheating surface 2 of thepreliminary substrate 10, that is, specifying the center C1 of the resistant heater element is sufficient. - Note that the central axis C3 of the
preliminary substrate 10 and the central axis C1 of theresistant heater element 4 are set on approximately the same axis. - In the heat uniformity evaluation step S3, the temperature distribution on the surface of the
preliminary substrate 10, to be theheating surface 2, is measured by use of, for example, an infrared thermometer. This measurement of the temperature distribution is performed after processing thepreliminary substrate 10 to have a shape required for the measurement. - In the substrate center position determination step S4, based on the heat uniformity evaluation result, the position of the central axis C2 is set to be located in a position where heat uniformity is superior compared to a case where the central axis C2 of the substrate and the central axis C1 of the resistant heater element are located on the same axis in the finished substrate. Preferably, so as to minimize an area to be grinded of a hot portion in the heating surface and to maximize an area to be grinded of a cool portion therein, a direction of a positional deviation of the central axis C2 of the
substrate 3 and the gap D thereof are set by use of the central axis C1 of theresistant heater element 4 as a reference. Note that, in practice, specifying only a passing point of the central axis C1 of thesubstrate 3 in theheating surface 2 of thepreliminary substrate 10, that is, specifying the center C1 of thesubstrate 3 is sufficient. - In the eccentric machining step S5, the direction of a positional deviation (a direction of an arrow K1 of FIG. 7 or an arrow K2 of FIG. 9) and the gap D, which are set in the previous step S4, are entered into, for example, an NC processing machine and its offset function processes the
preliminary substrate 10 by using the specified position of the central axis C2 as a processing centel For example, in examples 1 and 2 to be described later, by this processing of the substrate, a grinded area J1 (see FIG. 7) or a grinded area J2 (see FIG. 9), which are indicated by hatching between an outer rim of thesubstrate 3 and an outer rim of thepreliminary substrate 10, are removed. Thus, thesubstrate 3 having the processing center as the central axis C2 can be manufactured. In thesubstrate 3, theresistant heater element 4 having the central axis C1 whose position is shifted from the substrate central axis C2 is provided. - As shown in FIG. 4, the final processing step S6 has: a primary substrate processing step S61 of providing a lift pin hole in the
substrate 3 and processing thesubstrate 3 into a shape required for shaft junction of the next step; a shaft junction step S62 of joining a shaft with thesubstrate 3; a secondary substrate processing step S63 of finishing the entire body into a final shape; a terminal junction step S64 of joining terminals with both ends of theresistant heater element 4 and connecting power supply components to the terminals; and a finished body heat uniformity evaluation step S65 of checking the quality of a finished body. A substrate which has passed in the finished body heat uniformity evaluation step S65 becomes a finished body. - In the case of manufacturing a
heater 1 without a shaft, this final processing step S6 can leave out the shaft junction step S62 and the secondary substrate processing step S63 therefrom. - In the primary substrate processing step S61, drilling of the lift pin hole and other processings performed by using the center C2 of the
substrate 3 as a reference. Note that the lift pin is a pin which pushes the substrate up in detaching the substrate mounted on the heating surface. - In the shaft junction step S62, when the substrate is made of a ceramic material, the shaft is formed by using the same ceramic material and is joined with the
substrate 3 by integral junction or by seal junction using an O-ring, metal packing or the like. In a case of subjecting the shaft and thesubstrate 3 to solid-phase bonding, those two are joined together by performing heat treatment under a high temperature condition close to a sintering temperature. Note that the thermal uniformity of the heating surface of thesubstrate 3 is most affected by a heat treatment condition in performing sintering of ceramics that is the substrate material in the preliminary substrate formation step S1 and is less affected by heat treatment performed for joining the substrate with the shaft. Therefore, the heat uniformity evaluation of the heating surface of thesubstrate 3, which is performed before specifying the position of the central axis C2 of thesubstrate 3, is preferably performed after the step of sintering thepreliminary substrate 10. - In the secondary substrate processing step S63, the entire shape including the shaft undergoes finishing processing. For the power supply component used in the terminal junction step S64, metal is preferable, particularly nickel (Ni). The power supply component is applied in a shape of a rod or a wire. As means for electrically connecting the power supply component to the terminal, screwing, caulking, engaging, soldering, welding, eutectic bonding and the like are applicable.
- According to the manufacturing method of the embodiment, as to the temperature distribution produced by the heat treatment conditions and the like in the process of manufacturing the
preliminary substrate 10, by subjecting the preliminary substrate to the eccentric machining and by shifting the central axis C2 of thesubstrate 3 which is ultimately obtained from the central axis C1 of the resistant heater element, the temperature distribution in the heating surface of thesubstrate 3 can be adjusted to have a required temperature distribution and the thermal uniformity can be improved. - Comparative example 1 is a
conventional heater 100 in which the central axis C2 of thesubstrate 3 and the central axis C1 of the resistant heater element are on the same axis, that is, are concentric. Thesubstrate 3 of theheater 100 is made of aluminum nitride and is a disc of φ 335 mm×15 mm of thickness T. Theresistant heater element 4 is formed of a molybdenum coil and is embedded within thesubstrate 3 as shown in FIG. 2A. - FIGS. 6A and 6B show temperature distributions in the
heating surface 2 of theheater 100. In the temperature distribution shown in FIG. 6A, results obtained by measuring temperatures on theheating surface 2 by use of an infrared thermometer are indicated by isothermal curves F on theheating surface 2. The temperature distribution shown in FIG. 6B, indicates a distribution of temperatures at twelve measuring points on theheating surface 2 which are set at even intervals on the circumference of a circle with radius 138 mm which takes the substrate center C2 as a reference. Note that a set temperature is 525° C. - Example 1 is a
heater 1 in which the central axis C2 of thesubstrate 3 and the central axis C1 of the resistant heater element are set by leaving a gap therebetween. In thisheater 1, as shown in FIG. 6C, the central axis C1 of theresistant heater element 4 is set below the central axis C2 of thesubstrate 3 at an angle to the left of C2 on the drawing. The gap D between the central axes C1 and C2 is 1.5 mm. - The
substrate 3 of theheater 1 is made of aluminum nitride and is a disc of φ 335 mm×15 mm of thickness T. The materials, shapes and sizes of thesubstrate 3 and the resistant heater element are the same as those of comparative example 1. - FIGS. 6C and 6D show temperature distributions in the
heating surface 2. The measurement conditions of the temperature distributions and the method of displaying the temperature distributions are the same as those of comparative example 1. - The heater of example 1 is manufactured by use of the manufacturing method shown in FIG. 4. FIG. 7 shows the
preliminary substrate 10, the position of the central axis C1 of the resistant heater element, which is specified in the heater element center measurement step S2, the temperature distribution (isothermal curves) on the heating surface, which is obtained in the heat uniformity evaluation step S3, and the position of the central axis C2 of thesubstrate 3, which is specified in the substrate center position determination step. Furthermore, in FIG. 7, a grinded area in the eccentric machining step S5 is denoted by J1. - As shown in FIG. 7, in the heater of example 1, as a result of the heat uniformity evaluation, a hot portion A emerges in an area (indicated by hatching) which spreads upward at an angle to the right from a central portion of the
preliminary substrate 10 and a cool portion B emerges in a lower left area (indicated by cross-hatching) of thepreliminary substrate 10. Thus, the position of the central axis C2 of thesubstrate 3 as the finished body is set at a position shifted by 1.5 mm in a direction of the arrow K1 passing the center C1 of theheater element 4 and facing the hot portion A from the cool portion B. Thesubstrate 3 having the central axis C2 is obtained after the eccentric machining step S5. - ΔT (=[maximum temperature]−[minimum temperature]) at the twelve measuring points on the
heating surface 2 which are set at even intervals on the circumference of the circle with radius 138 mm which takes the center C2 of thesubstrate 3 as a reference is 5.8° C. in theheater 1 of example 1 but is 13.2° C. in theheater 100 of comparative example 1. Compared to theheater 100, in theheater 1, the heat uniformity at 525° C. is improved by 4.9° C. per gap of 1.0 mm. - Moreover, it is understood that, compared to the
heater 100 of comparative example 1, theheater 1 of example 1 has fewer isothermal curves F and has achieved evenness of heat across theentire heating surface 2. Specifically, regarding a heat uniformity requirement of t° C.±1.0% or less (525±5° C.), theheater 100 has ±1.3% but theheater 1 is improved to have ±0.5% - A
heater 100 of comparative example 2 is aconventional heater 100 in which the central axis C2 of thesubstrate 3 and the central axis C1 of the resistant heater element are on the same axis, that is, are concentric. Thesubstrate 3 of theheater 100 is made of aluminum nitride and is a disc of φ 340 mm×17 mm of thickness T. Moreover, as shown in FIG. 3A, theresistant heater element 4 includes: a firstheater element unit 5 disposed in a region which is 6.5 mm deep from theheating surface 2; and a secondheater element unit 5 disposed in a region which is 12 mm deep from theheating surface 2. Therefore, the circumscribed circle C of theresistant heater element 4 is a circumscribed circle abutting on the periphery of the projected shape of the first and secondheater element units - FIGS. 8A and 8B show temperature distributions in the
heating surface 2 of theheater 100 of comparative example 2. In the temperature distribution shown in FIG. 8A, results obtained by measuring temperatures on theheating surface 2 by use of an infrared thermometer are indicated by isothermal curves F on theheating surface 2. The temperature distribution shown in FIG. 8B, indicates a distribution of temperatures at five measuring points G1 to G5 on theheating surface 2 which are set at even intervals on a diameter passing through the substrate center C2. Note that a set temperature is 600° C. - Example 2 is a
heater 1 in which the central axis C2 of thesubstrate 3 and the central axis C1 of the resistant heater element are set by leaving a gap therebetween. As shown in FIG. 8C, in thisheater 1, the position of the central axis C1 of theresistant heater element 4 is set to the left of the position of the central axis C2 of the substrate in a horizontal direction on the drawing. The gap D between the central axes C1 and C2 is 1.0 mm. - The
substrate 3 of theheater 1 of example 2 is made of aluminum nitride and is a disc of φ335 mm×15 mm of thickness T. The materials, shapes and sizes of thesubstrate 3 and the resistant heater element are the same as those of comparative example 2. - The heater of example 2 is manufactured by use of the manufacturing method shown in FIG. 4. FIG. 9 shows the position of the central axis C1 of the resistant heater element, which is specified in the heater element center measurement step S2, the temperature distribution (isothermal curves) on the heating surface, which is obtained in the heat uniformity evaluation step S3, and the position of the central axis C2 of the
substrate 3, which is specified in the substrate center position determination step, in thepreliminary substrate 10. Furthermore, in FIG. 9, a region to be deleted in the eccentric machining step S5 is denoted by J2. - As shown in FIG. 9, in the heater of example 2, as a result of the heat uniformity evaluation, a hot portion A emerges in an area (indicated by hatching) at a right end along a horizontal diameter of the
preliminary substrate 10 and a cool portion B emerges in an area (indicated by cross-hatching) at a left end along the horizontal diameter of thepreliminary substrate 10. Thus, the position of the central axis C2 of thesubstrate 3 as the finished body is set at a position shifted by 1.0 mm in a direction of the arrow K2 passing the center C1 of theheater element 4 and facing the hot portion A from the cool portion B. Thesubstrate 3 having the central axis C2 is obtained after the eccentric machining step S5. - A temperature difference ΔT (=|TG1−TG5|) between the measuring points G1 and G5 on the
heating surface 2, which are set at even intervals on the diameter passing through the substrate center C2, is obtained. Consequently, the temperature difference ΔT is 0.3° C. in theheater 1 of example 2 but is 4.0° C. in theheater 100 of comparative example 2. Compared to theheater 100 of comparative example 2, in theheater 1 of example 2, the heat uniformity at 600 ° C. is improved by 3.7° C. per gap of 1.0 mm. - Moreover, in the
heater 1 of example 2, regarding the shape of the isothermal curves F taking the longitudinal diameter passing through the substrate center C2 as a reference, a degree of symmetry is increased compared to theheater 100 of comparative example 2. Thus, a symmetrical heat uniformity is achieved. - As described above, according to the heater of the present invention and the manufacturing method thereof, the central axis of the resistant heater element and the central axis of the substrate are not on the same axis and a predetermined gap is provided between the both central axes. Thus, by use of this gap, the heating surface of the substrate can be set to have a temperature distribution achieving a desired heat uniformity.
- Although the inventions have been described above by reference to certain embodiments of the inventions, the inventions are not limited to the embodiments described above. Modifications and variations of the embodiments described above will occur to those skilled in the art, in light of the above teachings.
Claims (16)
1. A heater comprising:
a plate-shaped substrate including a heating surface which heats an object to be heated; and
a resistant heater element provided in the substrate or on a surface thereof,
wherein a central axis C2 of a circumscribed circle of the resistant heater element and a central axis C1 of the substrate are not on the same axis and there is a gap between these two axes.
2. The heater according to claim 1 , wherein distance and direction of the gap are set so as to improve thermal uniformity on the heating surface compared to a case where the central axes C1 and C2 are on the same axis.
3. The heater according to claim 1 , wherein the gap is within a range of 0.05 mm to 10 mm.
4. The heater according to claim 1 , wherein the gap is within a range of 0.01 mm to 8 mm.
5. The heater according to claim 1 , wherein the resistant heater element includes one or a plurality of heater element units and the circumscribed circle is a circumscribed circle relative to a projected shape of all the heater element units onto the heating surface.
6. The heater according to claim 5 , wherein a planar shape of the substrate is any one of a substantial circle and a substantial regular polygon, and the projected shape thereof is any one of a substantial circle and a substantial regular polygon.
7. The heater according to claim 1 , wherein the substrate includes at least any one of ceramics selected from the group consisting of aluminum nitride, silicon carbide, silicon nitride and aluminum oxide as a main component, and the resistant heater element is made of at least one of metals selected from the group consisting of molybdenum, tungsten and platinum.
8. The heater according to claim 1 , wherein the resistant heater element has any one of shapes selected from the group consisting of a line shape, a band shape, a mesh shape and a film shape.
9. A method of manufacturing a heater, comprising:
forming a plate-shaped preliminary substrate which has a resistant heater element in the substrate or on a surface thereof and includes a heating surface on one side thereof for heating an object to be heated;
specifying a position of a central axis C1 of the resistant heater element provided in the preliminary substrate;
evaluating thermal uniformity of the heating surface of the preliminary substrate;
specifying a position of a central axis C2 of the substrate at a position where the heat uniformity of the heating surface is superior to the case where the central axis C2 of the substrate is on the central axis C1, based on results of the thermal uniformity evaluation; and
forming the substrate having the central axis C2 by subjecting the preliminary substrate to grinding processing.
10. The method according to claim 9 , wherein the position of the central axis C2 of the substrate is specified so as to set a gap between the central axis C2 and the central axis C1 of the resistant heater element to be within a range of 0.005 mm to 10 mm.
11. The method according to claim 9 , wherein the position of the central axis C2 of the substrate is specified so as to set a gap between the central axis C2 and the central axis C1 of the resistant heater element to be within a range of 0.01 mm to 8 mm.
12. The method according to claim 9 , wherein the central axis C1 of the resistant heater element is specified based on an X-ray photographed image of the resistant heater element.
13. The method according to claim 9 , wherein, in the thermal uniformity evaluation of the heating surface, a temperature distribution on the heating surface of the preliminary substrate is measured by use of an infrared thermometer.
14. The method according to claim 9 , wherein the preliminary substrate includes at least one of ceramics selected from the group consisting of aluminum nitride, silicon carbide, silicon nitride and aluminum oxide as a main component, and the resistant heater element is made of at least one of metals selected from the group consisting of molybdenum, tungsten and platinum.
15. The method according to claim 9 , wherein the preliminary substrate formation comprises:
molding a ceramic body having the resistant heater element embedded therein and
sintering the molded ceramic body.
16. The method according to claim 15 , wherein the step of sintering is performed by hot-pressing.
Priority Applications (1)
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US11/484,284 US7345260B2 (en) | 2002-08-21 | 2006-07-11 | Heater and method of manufacturing the same |
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JPP2002-241119 | 2002-08-21 | ||
JP2002241119A JP3833974B2 (en) | 2002-08-21 | 2002-08-21 | Manufacturing method of heating device |
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US11/484,284 Division US7345260B2 (en) | 2002-08-21 | 2006-07-11 | Heater and method of manufacturing the same |
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US20040104211A1 true US20040104211A1 (en) | 2004-06-03 |
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US10/639,765 Abandoned US20040104211A1 (en) | 2002-08-21 | 2003-08-12 | Heater and method of manufacturing same |
US11/484,284 Expired - Lifetime US7345260B2 (en) | 2002-08-21 | 2006-07-11 | Heater and method of manufacturing the same |
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US11/484,284 Expired - Lifetime US7345260B2 (en) | 2002-08-21 | 2006-07-11 | Heater and method of manufacturing the same |
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JP (1) | JP3833974B2 (en) |
Cited By (4)
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---|---|---|---|---|
US20020043530A1 (en) * | 1999-11-19 | 2002-04-18 | Yasutaka Ito | Ceramic heater |
US20060102613A1 (en) * | 2004-11-15 | 2006-05-18 | Sumitomo Electric Industries, Ltd. | Semiconductor fabrication device heater and heating device equipped with the same |
EP1703777A1 (en) * | 2005-03-17 | 2006-09-20 | Ngk Insulators, Ltd. | Position accuracy evaluation method and apparatus |
US20130161305A1 (en) * | 2011-08-30 | 2013-06-27 | Watlow Electric Manufacturing Company | High definition heater and method of operation |
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US8547005B1 (en) | 2010-05-18 | 2013-10-01 | Superior Technical Ceramics, Inc. | Multi-layer heater for an electron gun |
CN103255394A (en) * | 2012-02-17 | 2013-08-21 | 苏州艾默特材料技术有限公司 | Manufacturing method of heater for metal organic chemical vapor deposition |
JP6767833B2 (en) * | 2016-09-29 | 2020-10-14 | 日本特殊陶業株式会社 | Heating device |
JPWO2023026929A1 (en) * | 2021-08-27 | 2023-03-02 |
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US20040011780A1 (en) * | 2002-07-22 | 2004-01-22 | Applied Materials, Inc. | Method for achieving a desired process uniformity by modifying surface topography of substrate heater |
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US6133557A (en) * | 1995-01-31 | 2000-10-17 | Kyocera Corporation | Wafer holding member |
US6080970A (en) * | 1997-12-26 | 2000-06-27 | Kyocera Corporation | Wafer heating apparatus |
US5997998A (en) * | 1998-03-31 | 1999-12-07 | Tdk Corporation | Resistance element |
US6548787B2 (en) * | 2000-01-13 | 2003-04-15 | Sumitomo Electric Industries, Ltd. | Ceramic heater |
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Cited By (11)
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US20020043530A1 (en) * | 1999-11-19 | 2002-04-18 | Yasutaka Ito | Ceramic heater |
US20060102613A1 (en) * | 2004-11-15 | 2006-05-18 | Sumitomo Electric Industries, Ltd. | Semiconductor fabrication device heater and heating device equipped with the same |
EP1703777A1 (en) * | 2005-03-17 | 2006-09-20 | Ngk Insulators, Ltd. | Position accuracy evaluation method and apparatus |
KR100733444B1 (en) * | 2005-03-17 | 2007-06-29 | 니뽄 가이시 가부시키가이샤 | Position accuracy evaluation method and position accuracy evaluation apparatus |
US7948516B2 (en) | 2005-03-17 | 2011-05-24 | Ngk Insulators, Ltd. | Position accuracy evaluation method and position accuracy evaluation apparatus |
US20130161305A1 (en) * | 2011-08-30 | 2013-06-27 | Watlow Electric Manufacturing Company | High definition heater and method of operation |
US9263305B2 (en) * | 2011-08-30 | 2016-02-16 | Watlow Electric Manufacturing Company | High definition heater and method of operation |
US20160118276A1 (en) * | 2011-08-30 | 2016-04-28 | Watlow Electric Manufacturing Company | High definition heater and method of operation |
US20160118277A1 (en) * | 2011-08-30 | 2016-04-28 | Watlow Electric Manufacturing Company | High definition heater and method of operation |
US10043685B2 (en) * | 2011-08-30 | 2018-08-07 | Watlow Electric Manufacturing Company | High definition heater and method of operation |
US10734256B2 (en) * | 2011-08-30 | 2020-08-04 | Watlow Electric Manufacturing Company | High definition heater and method of operation |
Also Published As
Publication number | Publication date |
---|---|
JP3833974B2 (en) | 2006-10-18 |
US20060289449A1 (en) | 2006-12-28 |
US7345260B2 (en) | 2008-03-18 |
JP2004079440A (en) | 2004-03-11 |
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Owner name: NGK INSULATORS, LTD., JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:UNNO, YUTAKA;REEL/FRAME:014861/0431 Effective date: 20031118 |
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STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |