US20030206571A1 - Plasma thermal processing system having carbon sensing and control - Google Patents
Plasma thermal processing system having carbon sensing and control Download PDFInfo
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- US20030206571A1 US20030206571A1 US10/138,758 US13875802A US2003206571A1 US 20030206571 A1 US20030206571 A1 US 20030206571A1 US 13875802 A US13875802 A US 13875802A US 2003206571 A1 US2003206571 A1 US 2003206571A1
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- flow path
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- elongated tube
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J15/00—Arrangements of devices for treating smoke or fumes
- F23J15/06—Arrangements of devices for treating smoke or fumes of coolers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D45/00—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces
- B01D45/04—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by utilising inertia
- B01D45/06—Separating dispersed particles from gases or vapours by gravity, inertia, or centrifugal forces by utilising inertia by reversal of direction of flow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
- B01D47/06—Spray cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D50/00—Combinations of methods or devices for separating particles from gases or vapours
- B01D50/40—Combinations of devices covered by groups B01D45/00 and B01D47/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
- B01J19/088—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D2203/00—Aspects of processes for making harmful chemical substances harmless, or less harmful, by effecting chemical change in the substances
- A62D2203/10—Apparatus specially adapted for treating harmful chemical agents; Details thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00121—Controlling the temperature by direct heating or cooling
- B01J2219/00123—Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00245—Avoiding undesirable reactions or side-effects
- B01J2219/00247—Fouling of the reactor or the process equipment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/0869—Feeding or evacuating the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/0873—Materials to be treated
- B01J2219/0875—Gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J2219/0894—Processes carried out in the presence of a plasma
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2217/00—Intercepting solids
- F23J2217/50—Intercepting solids by cleaning fluids (washers or scrubbers)
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2219/00—Treatment devices
- F23J2219/80—Quenching
Definitions
- the present invention relates to an apparatus for the disposal of hazardous wastes, by decomposition of the materials using an extremely high temperature plasma arc furnace, and subsequent treatment of the decomposed residue to control the carbon byproducts.
- a prior art patent which describes one form of an apparatus and process for disposing of waste material in this manner is U.S. Pat. No. 4,644,877, issued Feb. 24, 1987, which describes a system for feeding waste materials into a plasma arc burner furnace where the materials are atomized and ionized, and then discharging the residue into a reaction chamber to be cooled and recombined into a product gas and particulate matter which is nontoxic.
- the recombined products are quenched with an alkaline atomized spray to neutralize the products and to wet the particulate matter.
- the product gas is extracted from the recombined products, and the extracted product gas is burned.
- the patent describes a form of construction of the apparatus which is “compact” in size, permitting the device to made sufficiently small so as to be mobile and transportable to a hazardous waste site in a 45 -foot truck or trailer.
- the patent does not describe an apparatus or process for addressing the problem of carbon formation during the process, nor does it disclose any method or apparatus for sensing or controlling carbon formation.
- the furnace has a discharge and quench assembly which directs the furnace exhaust in a wrap-around path, and utilizes three water injection sprayers at various positions along the path for cooling, and utilizes a carbon sensor in the flow path which monitors flow path pressure to detect carbon buildup, and controls materials in the flow path as needed to maintain a low amount of carbon buildup.
- FIG. 1 shows and isometric view of the housing assembly for removal of hot gases and other materials from the plasma arc furnace
- FIG. 2 shows a side view in cross-section of the apparatus of FIG. 1;
- FIG. 3 shows an enlarged partial cross-section showing the carbon sensor.
- FIG. 1 shows an isometric view of the housing assembly 10 for removal of hot gases and particulates from a plasma arc furnace.
- a mounting flange 12 is secured to the outside wall of a furnace combustion chamber, which may be similar to the types described in the prior art patents identified herein.
- the temperature of the materials which flow into housing 10 through flange 12 is typically 800° C.-2000° C. As described in the Springer et al patent, it is desirable, to rapidly quench the temperature of the gases and particulates to a temperature in the range of 350° C. to about 800° C., to reduce the likelihood of reformation of organic compounds in the exhaust gases.
- the present invention accomplishes this quenching in a very small housing, as will be described herein.
- the exhaust gases leave housing 10 via an exit flange 22 , at the temperature range described herein.
- a pressure transducer 30 is positioned near the entrance point in housing 10 , to monitor the gas flow path and sense the carbon accumulation in the gas flow.
- a first quenching station 40 is positioned downstream of the transducer 30
- a second quenching station 50 is positioned downstream of the first station 40
- a final quenching station 60 is positioned proximate the exhaust flange 22 , downstream of station 50 .
- Each of these quenching stations is controllable to spray water into the flow path to assist in reducing the temperature of the gases, to incrementally reduce gas flow temperature.
- the parts of the housing 10 are formed in sections which are bolted together with a flange 13 a for ease of disassembly and repair.
- Housing 10 has an inner rigid tube 13 affixed at its lower end to flange 12 . Lining the inside of tube 13 is a refractory insulating tube 15 , and inside the lower portion of insulating tube 15 is positioned a further refractory insulating tube 16 . Together, the tubes 15 and 16 serve to insulate the outer tube 13 from the extreme temperatures of the gases flowing through the apparatus. As the gas flows in the direction of the arrows 21 past the first quenching station 40 it is partially cooled by a spray from sprayers 40 a , etc. which are positioned around the circumference of the tube 13 .
- the gas flow path reverses and continues downward along the outside of tube 13 .
- the gas flow path passes quenching station 60 and is further cooled by spray from sprayers 60 a , etc.
- the gas exhausts out through exhaust flange 22 at a significantly reduced temperature.
- FIG. 3 shows an expanded view, in partial cross-section, to illustrate the sensor 30 .
- the sensor 30 is comprised of a vacuum tube 31 having an inner bend facing toward the gas flow path within housing 10 .
- a porous, monolithic, ceramic head 32 At the inner end of tube 31 is mounted a porous, monolithic, ceramic head 32 , made from a material selected to be appropriate for micron to submicron particulate capture characteristic of carbon formation from the gas flow.
- the differential pressure across the ceramic material is monitored, and provides an indication of the amount of carbon accumulation that occurs on the ceramic head 32 , and therefore an indication of the amount of carbon in the gas flow. Based on the monitored differential pressure, remedial action can be taken within the furnace to reduce the carbon particulate loading, including action to add steam or oxygen into the furnace to change the heating and destruction characteristics.
- the individual quenching stations are controllable to regulate temperature at various points along the flow path, to control the output gas temperature to a desired level. Additionally, the differential pressure across ceramic head 32 is measured to permit control of the amount of oxygen or other material should be added to the destruction process, to thereby control the quantity of carbon particulate existing in the furnace exit flow.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Organic Chemistry (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
Abstract
Description
- The present invention relates to an apparatus for the disposal of hazardous wastes, by decomposition of the materials using an extremely high temperature plasma arc furnace, and subsequent treatment of the decomposed residue to control the carbon byproducts.
- A prior art patent which describes one form of an apparatus and process for disposing of waste material in this manner is U.S. Pat. No. 4,644,877, issued Feb. 24, 1987, which describes a system for feeding waste materials into a plasma arc burner furnace where the materials are atomized and ionized, and then discharging the residue into a reaction chamber to be cooled and recombined into a product gas and particulate matter which is nontoxic. The recombined products are quenched with an alkaline atomized spray to neutralize the products and to wet the particulate matter. The product gas is extracted from the recombined products, and the extracted product gas is burned. The patent describes a form of construction of the apparatus which is “compact” in size, permitting the device to made sufficiently small so as to be mobile and transportable to a hazardous waste site in a45-foot truck or trailer. The patent does not describe an apparatus or process for addressing the problem of carbon formation during the process, nor does it disclose any method or apparatus for sensing or controlling carbon formation.
- Another form of hazardous waste processing system is described in U.S. Pat. No. 5,319,176, issued Jun. 7, 1994. In this patent, a product of the process is carbon black, which is created and controlled by steam injection into the waste material stream during the burning process. The patent describes a dual plasma arc system, wherein one furnace is used for pyrolysis and a second chamber is used for secondary off-gas processing which produces a carbon black byproduct.
- Another prior art patent which discloses a typical construction for a plasma arc furnace of the type of interest herein is U.S. Pat. No. 5,534,659, issued Jul. 9, 1996, to Springer et al.
- In view of the foregoing patents, and other prior art in the field, it would provide a distinct advantage to have a hazardous material plasma arc furnace with as small a physical form as possible, and to provide such a processing system with sensors and control mechanisms for controlling the amount of carbon byproduct created by the processing system.
- An apparatus and method for destroying hazardous waste products in a plasma electric arc furnace of small physical size, using water quenching to cool the process gases and a carbon sensor in the process flow path to monitor carbon buildup, and a control mechanism to control carbon loading of the process materials. The furnace has a discharge and quench assembly which directs the furnace exhaust in a wrap-around path, and utilizes three water injection sprayers at various positions along the path for cooling, and utilizes a carbon sensor in the flow path which monitors flow path pressure to detect carbon buildup, and controls materials in the flow path as needed to maintain a low amount of carbon buildup.
- It is a principal object of the invention to provide a compact hazardous material disposal system which does not release hazardous materials into the atmosphere.
- It is a further object of the invention to provide a waste disposal system wherein the amount of carbon buildup can be controlled.
- It is another object of the invention to provide a plasma arc furnace for destroying hazardous materials where the destruction residue can be quickly and efficiently cooled after thermal processing.
- Other and further objects and advantages of the invention will become apparent from the following specification and claims and with reference to the appended drawings.
- FIG. 1 shows and isometric view of the housing assembly for removal of hot gases and other materials from the plasma arc furnace;
- FIG. 2 shows a side view in cross-section of the apparatus of FIG. 1; and
- FIG. 3 shows an enlarged partial cross-section showing the carbon sensor.
- Referring to the drawing figures, like reference characters refer to the same or functionally similar parts of the respective components illustrated in each of the figures.
- FIG. 1 shows an isometric view of the
housing assembly 10 for removal of hot gases and particulates from a plasma arc furnace. Amounting flange 12 is secured to the outside wall of a furnace combustion chamber, which may be similar to the types described in the prior art patents identified herein. The temperature of the materials which flow intohousing 10 throughflange 12 is typically 800° C.-2000° C. As described in the Springer et al patent, it is desirable, to rapidly quench the temperature of the gases and particulates to a temperature in the range of 350° C. to about 800° C., to reduce the likelihood of reformation of organic compounds in the exhaust gases. The present invention accomplishes this quenching in a very small housing, as will be described herein. The exhaust gases leavehousing 10 via anexit flange 22, at the temperature range described herein. - A
pressure transducer 30 is positioned near the entrance point inhousing 10, to monitor the gas flow path and sense the carbon accumulation in the gas flow. Afirst quenching station 40 is positioned downstream of thetransducer 30, asecond quenching station 50 is positioned downstream of thefirst station 40, and afinal quenching station 60 is positioned proximate theexhaust flange 22, downstream ofstation 50. Each of these quenching stations is controllable to spray water into the flow path to assist in reducing the temperature of the gases, to incrementally reduce gas flow temperature. The parts of thehousing 10 are formed in sections which are bolted together with aflange 13 a for ease of disassembly and repair. -
Housing 10 has an innerrigid tube 13 affixed at its lower end toflange 12. Lining the inside oftube 13 is arefractory insulating tube 15, and inside the lower portion ofinsulating tube 15 is positioned a furtherrefractory insulating tube 16. Together, thetubes outer tube 13 from the extreme temperatures of the gases flowing through the apparatus. As the gas flows in the direction of thearrows 21 past thefirst quenching station 40 it is partially cooled by a spray fromsprayers 40 a, etc. which are positioned around the circumference of thetube 13. - When the gas flow leaves the vicinity of the upper end of
tube 16, it has cooled somewhat, therefore slightly less insulating effect is provided by the remaining length oftube 15. As the gas flows out the top oftube 15 it passesquenching station 50, andsprayers - At the top of
tube 13, the gas flow path reverses and continues downward along the outside oftube 13. The gas flow path passesquenching station 60 and is further cooled by spray fromsprayers 60 a, etc. Finally, the gas exhausts out throughexhaust flange 22 at a significantly reduced temperature. - FIG. 3 shows an expanded view, in partial cross-section, to illustrate the
sensor 30. Thesensor 30 is comprised of avacuum tube 31 having an inner bend facing toward the gas flow path withinhousing 10. At the inner end oftube 31 is mounted a porous, monolithic,ceramic head 32, made from a material selected to be appropriate for micron to submicron particulate capture characteristic of carbon formation from the gas flow. The differential pressure across the ceramic material is monitored, and provides an indication of the amount of carbon accumulation that occurs on theceramic head 32, and therefore an indication of the amount of carbon in the gas flow. Based on the monitored differential pressure, remedial action can be taken within the furnace to reduce the carbon particulate loading, including action to add steam or oxygen into the furnace to change the heating and destruction characteristics. - In operation, the individual quenching stations are controllable to regulate temperature at various points along the flow path, to control the output gas temperature to a desired level. Additionally, the differential pressure across
ceramic head 32 is measured to permit control of the amount of oxygen or other material should be added to the destruction process, to thereby control the quantity of carbon particulate existing in the furnace exit flow. - The present invention may be embodied in other forms without departing from the spirit or essential attributes thereof; and it is, therefore, desired that the present embodiment be considered in all respects as illustrative and not restrictive, reference being made to the appended claims rather than to the foregoing description to indicate the scope of the invention.
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US10/138,758 US6642472B1 (en) | 2002-05-03 | 2002-05-03 | Plasma thermal processing system having carbon sensing and control |
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US10/138,758 US6642472B1 (en) | 2002-05-03 | 2002-05-03 | Plasma thermal processing system having carbon sensing and control |
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US6642472B1 US6642472B1 (en) | 2003-11-04 |
US20030206571A1 true US20030206571A1 (en) | 2003-11-06 |
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US10/138,758 Expired - Fee Related US6642472B1 (en) | 2002-05-03 | 2002-05-03 | Plasma thermal processing system having carbon sensing and control |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010017812A1 (en) * | 2008-08-14 | 2010-02-18 | Georgsmarienhütte Gmbh | Probe for continuously measuring exhaust gases |
CN103071875A (en) * | 2013-01-04 | 2013-05-01 | 中国原子能科学研究院 | Process for brazing dissimilar material part of high-frequency window of small medical rotary accelerator |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7115832B1 (en) * | 2005-07-26 | 2006-10-03 | United Technologies Corporation | Microplasma spray coating apparatus |
US7752983B2 (en) * | 2006-06-16 | 2010-07-13 | Plasma Waste Recycling, Inc. | Method and apparatus for plasma gasification of waste materials |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1225441A (en) | 1984-01-23 | 1987-08-11 | Edward S. Fox | Plasma pyrolysis waste destruction |
US5319176A (en) | 1991-01-24 | 1994-06-07 | Ritchie G. Studer | Plasma arc decomposition of hazardous wastes into vitrified solids and non-hazardous gasses |
US5207999A (en) * | 1991-08-13 | 1993-05-04 | Cameco Corporation | Generation of fluorine via thermal plasma decomposition of metal fluoride |
US5280757A (en) | 1992-04-13 | 1994-01-25 | Carter George W | Municipal solid waste disposal process |
US5376341A (en) * | 1992-07-24 | 1994-12-27 | Corning Incorporated | Catalytic converter for motorcycles |
US5548611A (en) * | 1993-05-19 | 1996-08-20 | Schuller International, Inc. | Method for the melting, combustion or incineration of materials and apparatus therefor |
US5534659A (en) | 1994-04-18 | 1996-07-09 | Plasma Energy Applied Technology Incorporated | Apparatus and method for treating hazardous waste |
US6224653B1 (en) * | 1998-12-29 | 2001-05-01 | Pulsatron Technology Corporation | Electrostatic method and means for removing contaminants from gases |
US6517791B1 (en) * | 2000-12-04 | 2003-02-11 | Praxair Technology, Inc. | System and process for gas recovery |
-
2002
- 2002-05-03 US US10/138,758 patent/US6642472B1/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010017812A1 (en) * | 2008-08-14 | 2010-02-18 | Georgsmarienhütte Gmbh | Probe for continuously measuring exhaust gases |
CN103071875A (en) * | 2013-01-04 | 2013-05-01 | 中国原子能科学研究院 | Process for brazing dissimilar material part of high-frequency window of small medical rotary accelerator |
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US6642472B1 (en) | 2003-11-04 |
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