US20030100117A1

US20030100117A1 - Standards, methods for making, and methods for using the standards in evaluation of oxide removal

Info

Publication number: US20030100117A1
Application number: US10/339,273
Authority: US
Inventors: Don Lipkin; Paul Dupree; Scott Weaver
Original assignee: Individual
Current assignee: Individual
Priority date: 1999-06-14
Filing date: 2003-01-09
Publication date: 2003-05-29
Also published as: US6537816B1

Abstract

An article of manufacture forms a tool for determining cleaning parameters of an oxide removal process. The article comprises a block of material upon which an oxide can be formed and a simulated defect structure disposed in the block of material. The article is capable of determining oxide removal parameters of an oxide removal process by disposing an oxidized standard in a reactor, conducting an oxide removal process to remove oxide from the standard, and evaluating the standard and simulated defect structure for remaining oxide and other oxide removal parameters.

Description

BACKGROUND OF THE INVENTION

The invention relates to standards for evaluating oxide removal, methods of making the standards, and their associated methods of use.

Aeronautical, marine, and land-based turbine components, such as, but not limited to, blades, shrouds, and vanes, are exposed to high-temperature oxidizing, and often corrosive, environments during service. Surfaces of turbine components, including cracks, may form complex, chemically stable thermal oxides during use. These oxides comprise, but are not limited to, oxides of aluminum, titanium, chromium, and combinations thereof.

Turbine components are periodically overhauled in order to prolong life or enhance performance. During these overhauls, the turbine components may be subjected to various repair operations, including welding, brazing, or coating. The presence of stable oxides impairs the reparability of a superalloy. Therefore, removal of these oxides prior to repair, for example by cleaning the turbine components, is important for successful turbine overhaul.

Grit-blasting or grinding operations can effectively remove surface oxides when only superficial repairs are required and the surfaces to be cleaned are readily accessible. These cleaning operations, however, are not only labor intensive but can result in inadvertent and undesirable loss of the base alloy material, thus compromising the turbine component's reliability and efficiency. Further, repair of hard-to-reach surfaces, including internal passages and highly concave sections, such as, but not limited to, cooling holes, cracks, and slots, generally requires a non-mechanical cleaning process that minimally degrades or consumes the base alloy. These cleaning processes have included batch thermo-chemical cleaning, such as processes that occur in a high-temperature reactive environment. These batch turbine-component cleaning processes can, in some cases, rely on fluoride ions, which are provided in a reactor to remove highly stable oxides from, cooling holes, cracks, slots, and other hard-to-reach surfaces. The fluoride-ion cleaning (FIC) processes are known to remove oxides while leaving the turbine component's base alloy essentially intact.

While processes such as FIC are useful for cleaning oxides on turbine components, the process effectiveness, especially with respect to oxide removal from, cooling holes, cracks, slots, and other hard-to-reach surfaces, is difficult to quantify. Known measures of oxide removal comprise sectioning of cleaned turbine components and measuring the extent of oxide cleaning. This measure does not provide a consistent indication of overall oxide removal, since both the damage and oxidation characteristics of each turbine component will vary. Therefore, a tool that can consistently gauge the effectiveness of an oxide removal process would be desirable.

SUMMARY OF THE INVENTION

The invention sets forth an article of manufacture comprising a block of material upon which an oxide can be formed and a defect structure disposed in the block of material. The article is capable of being used to assess the effectiveness of an oxide removal process by measuring oxide removal from the block and defect structure after subjecting it to an oxide removal process.

The invention further sets forth a tool for determining oxide removal parameters of an oxide removal process. The tool comprises a block of material upon which an oxide can be formed and a defect structure disposed in the block of material. The tool is capable of being used to assess the effectiveness of an oxide removal process by measuring oxide removal from the block and defect structure after subjecting it to an oxide removal process.

Another embodiment of the invention provides a process for determining an oxide removal effectiveness. The process comprises disposing an oxidized standard in a reactor that is capable of oxide removal. The standard comprises a block of material upon which an oxide can be formed and a defect structure disposed in the block of material. The method further includes conducting an oxide cleaning and evaluating the standard for remaining oxide.

A further embodiment of the invention comprises a process for forming an oxide removal evaluation standard. The standard comprises a block of material upon which an oxide can be formed and a defect structure disposed in the block of material. The process comprises machining the slot structure in the block of material, compressing the defect structure to form at least one crack-like defect, and exposing the block of material to a thermal treatment to form an oxide on the block surfaces and within the at least one crack-like defect.

These and other aspects, advantages and salient features of the invention will become apparent from the following detailed description, which, when taken in conjunction with the annexed drawings, where like parts are designated by like reference characters throughout the drawings, disclose embodiments of the invention.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic illustration of a standard for evaluating effectiveness of oxide removal processes; [0011]
FIG. 2 is a flow chart of a method for making and using standards, as embodied by the invention, and for evaluating effectiveness of oxide removal processes; and [0012]
FIG. 3 is a schematic illustration of a second standard for evaluating effectiveness of oxide removal processes.[0013]

DETAILED DESCRIPTION OF THE INVENTION

Oxide removal from engine-run turbine components is an important step in turbine component repair and overhaul processes. The invention provides a tool for evaluating performance of oxide removal processes. The tool is useful in quantifying oxide removal from cracks and other hard-to-reach surfaces, including cooling holes, slots, internal passages, and other highly concave sections (hereinafter referred to as “defects”). [0014]
The tool, as embodied by the invention, comprises a standard specimen that enables the extent and effectiveness of oxide removal to be evaluated. The standard comprises a solid article, for example an article having a generally rectangular-solid geometry. The standard typically comprises a material similar to that which is to be cleaned. For example, and in no way limiting of the invention, if an oxide removal process is used in repair of turbine components that are formed of superalloy materials, the standard is formed from a similar superalloy material, such as nickel-, cobalt-, or iron-based superalloys, or combinations thereof. [0015]
One embodiment of a standard [0016] 1 will be described, along with methods of its formation and use, with reference to FIGS. 1 and 2 and the flowchart of FIG. 3. The following structure is merely exemplary of standards within the scope of the invention, and is not meant to limit the invention in any way. The standard 1 comprises a solid block 2 (hereinafter “block”), for example a block formed of a superalloy material. The scope of the invention includes forming the block 2 in any appropriate shape, including but not limited to, a general rectangular solid. The block 2 may also comprise protrusions and depressions formed thereon. The following description of the invention will refer to a generally rectangular block, however this is merely exemplary and is not meant to limit the invention in any way.
The [0017] block 2 includes a defect structure. The defect structure comprises at least one slot 3 on surface 4 and the block 2 comprises a notch 5. As illustrated in FIG. 1, the notch 5 comprises a “V” (“Chevron”) notch 5 on an opposite surface 6, and having its apex 13 substantially co-linear with the slot 3. This configuration of a notch 5 is merely exemplary of notches within the scope of the invention. The scope of the invention comprises notches of varying sizes, shapes, and configurations, for example and in no way limiting of the invention, rectangular, curved, and combinations thereof.
The [0018] slot 3 comprises a thickness “t”, for example a constant thickness “t” in a range from about 10 micrometers (elm) to about 1 millimeter (mm), and a length in a range from about 1 mm to about 10 mm. The slot 3 and “V” notch 5 are formed in the block 2 by an appropriate process, such as, but not limited to, a wire electro-discharge machining (WEDM) process, in step S1 (FIG. 3).
The depth of the “V” notch [0019] 5 is generally similar to the depth of the slot 3. The “V” notch 5 and slot 3 define a bridge 7 of solid material in the block 2 that is disposed between the slot 3 and “V” notch 5. Typically, the height H, width W, thickness T of the standard are in a range from about 0.5 centimeter to about 10.0 centimeters. For example, the ratio H/T is in a range from about 0.5 to about 2.0, and the ratio of W/H is in a range from about 0.5 to about 1.0.
After the “V” notch [0020] 5 and the slot 3 are formed in the standard 1, the block 2 is cleaned in step S2 to remove any residue from the slot-structure formation processes. For example, if a machining process is used to form the slot structure, the block is cleaned to remove residue, such as but not limited to, oils, machining chips, recast and oxide deposits, and the like.
If the [0021] slot 3 is formed with a thickness t that simulates a relevant defect thickness, no compression is needed. If the thickness “t” of the slot 3 is greater than the thickness desired for use as a standard, the slot 3 can be compressed to a more desired final thickness. The block 2 is compressed (step S3) by applying a distributed force on surfaces 18 and 19 in a direction indicated by arrows 10 (FIG. 1). The formation of a slot structure, including any compression of the slot(s) creates a structure that simulates a defect, where defect includes cracks, holes, crevices, and other hard-to-reach surfaces (hereinafter “simulated defect”).
After the optional compression, the [0022] block 2 is exposed to a thermal treatment in step S4. An exemplary thermal treatment, which is within the scope of the invention, comprises, but is not limited to, a solution heat treatment followed by controlled exposure to a high-temperature, oxidizing environment for a time period sufficient to form oxides on both the block surface and the inside of the simulated defect.
The [0023] standard 1, with the oxide-filled simulated defect can be used for oxide-removal process evaluation. The evaluation comprises disposing the oxidized standard 1 in a cleaning reactor. The scope of the invention comprises any cleaning reactor and any oxide removal process that the reactor can employ. The exact type of cleaning reactor and process used does not affect the standard per se. The standard 1 is placed, by itself, and alternatively with other standards, in a reactor. Alternatively, the standard 1 is placed in the reactor with turbine components to be cleaned. The standard 1 is then subjected to an oxide removal process, in step S5. Once the oxide removal process is complete, the standard 1 is removed from the reactor for evaluation.
The evaluation of the [0024] standard 1 comprises exposing the simulated defect and its surfaces in step S6. The simulated defect is exposed by compressing the standard 1 at the “V” notch 5, in the direction of arrows 11 (FIG. 1), thus splitting the standard 1 to open the simulated defect.
Evaluation of the simulated defect, in step S[0025] 7, can also include metallographically sectioning the standard 1. The surfaces of the exposed slot 3 are evaluated for extent of oxide removal using various, known evaluation techniques. These evaluation techniques, include, but are not limited to, optical inspection, electrical resistivity measurement, weight loss measurement, and wetability evaluation.
A second embodiment of a standard [0026] 20, as embodied by the invention, is illustrated in FIGS. 4 and 5, and its formation and use are similar to that described above with respect to FIG. 3. The standard 20 comprises a block 2 of solid material. The simulated defect for the standard 20 comprises at least one slot 21, which is formed similar to slot 3 described above. For example, the slot structure comprises multiple slots 21, which are machined into the block 2, for example at least one slot in each of surfaces 24 and 26. The following description discusses multiple slots 21, however this is merely exemplary of the invention and is not meant to limit the invention in any way.
The standard [0027] 20 is cleaned (step S2) and, if desired, compressed (step S3) as described above to form simulated defects. The standard 20 is then subjected to a heat treatment to oxidize the surface and slot structure. The standard 20 is then oxidized (step S4), as discussed above. The standard 20 is then disposed in a cleaning reactor, and subjected to an oxide removal operation (step S5).
Once the oxide removal operation is complete, the standard, which comprises the simulated defect slot structure, is ready for evaluation. The evaluation comprises exposing the crack-like defect, such as by metallographic sectioning, in step S[0028] 6 and evaluating in step S7.
The [0029] standards 1 and 20 are evaluated for oxide removal, based on the known starting defect. The evaluation of oxide removal provides an indication of the effectiveness of the oxide removal capabilities of the oxide removal process. For example, and in no way limiting of the invention, performing an oxide removal process for a prescribed time on a standard having known oxide amount and in a reactor with known operational specifications provides oxide removal process benchmarks, which are indicative of the oxide removal process performance.
The standard can be used as an oxide-removal process guage to determine oxide removal process progress. The standard indicates the degree of oxide removal. For use as an oxide-removal process gauge, a standard is prepared with known oxide amounts. The standard is placed in a reactor and cleaned, as discussed above. The standard, which is disposed in the reactor, can be checked for the degree of oxide removal against the oxide removal process benchmarks. Therefore, it is possible to gauge whether a oxide removal process has removed sufficient oxide amounts for turbine components. [0030]
Either of the standard structures described above can be used to evaluate braze or welding repair effectiveness. In a braze-repair effectiveness evaluation process, a simulated defect structure is provided in a standard, the standard is oxidized, and then cleaned, as described above in steps S[0031] 1 through S5. A braze alloy is disposed on at least some portion of the standard and may be placed over at least one of the simulated defect structures. The standard then undergoes brazing and, if necessary, any subsequent thermal treatments, as known in the art, to form a brazed standard. The brazed standard is evaluated, as discussed above in step S7. For example, the brazed standard is metallographically sectioned, inspected, and evaluated for braze-repair parameters. Exemplary braze repair parameters comprise, but are not limited to, extent of oxide removal, depth of braze filling, and alloying element depletion. The evaluation of the brazed standard provides an indication of the effectiveness of the brazing preparation steps and the effectiveness of the braze repair process.
As discussed above, the standard's simulated defect structure configuration may vary. While the above description sets forth an elongated and planar slot, this slot configuration is merely exemplary of slot configurations within the scope of the invention. For example, the scope of the invention comprises a simulated defect that simulates cooling hole dimensions, which is used to determine oxide removal from cooling holes in a turbine component. [0032]
The standards, as embodied by the invention, are also useful as tools for determining desirable operational bounds for oxide-removal processes. As known in the art, oxide removal depends on various factors, including but not limited to, oxide-removal process temperature, process atmosphere, and process time. As an exemplary use as a process improvement tool, standards are formed of the same base material with similarly structured slots as a turbine component of interest. The nature and extent of oxidation is essentially identical between the standards. A standard is subjected to an oxide cleaning run under a first set of process conditions. A second run using a second standard is made varying at least one process condition. Subsequent runs using other standards vary other process conditions. Oxide removal amounts and other parameters for each of the runs are determined. An enhanced combination of oxide-removal process conditions, for example an enhanced oxide-removal amount. [0033]
An exemplary method of forming a standard will now be discussed. This method is merely exemplary and not meant to limit the invention in any way. A first step in the preparation of a standard involves using a wire electro-discharge machine (WEDM) to form slots in the standard. The structure and operation of standard WEDMs are known by those of ordinary skill in the art, and thus a detailed description is not provided. The standard is then etched and degreased to remove a recast layer therefrom. [0034]
The standard is then compressed, if needed. The compression occurs in a press that comprises tungsten carbide platens. The standard is oriented in the press to apply a force in the direction of arrows [0035] 10 (FIGS. 1 and 4). The standard is compressed with a suitable force to form crack-like defects. When the applied force is removed, and the slot reopens slightly due to elastic unloading of the material. The standard's slots are now reduced in thickness t to less that about 50% of the original thickness. For example, if 0.10 mm wire is used to make a simulated defect in the form of a slot having a thickness of about 0.12 mm, the simulated defect slot defect may be compressed to less than about 0.05 mm.
The solution heat treatment of the standard comprises placing the standards on an alumina tray, so the slot structures are out of contact with the tray and adjacent standards do not touch. The tray is then placed into an air furnace. The temperature in the furnace is increased to about 1250° C. at a rate of about 25° C./min and held for about 1 hour to solution the material. The standards are next oxidized at a temperature of about 1150° C. for about 300 hours. Thereafter, the furnace is cooled to a temperature below about 100° C. at a rate sufficient to form dense oxides in the simulated defects. [0036]
While various embodiments are described herein, it will be appreciated from the specification that various combinations of elements, variations or improvements therein may be made by those skilled in the art, and are within the scope of the invention. [0037]

Claims

We claim:

1. An article of manufacture comprising:

a block of material, the block being made of a material upon which an oxide can form; and

a defect structure disposed in the block of material, wherein an oxidized article is capable of being used to determine parameters of an oxide removal process by measuring oxide removal from the block and defect structure after the oxide removal process.

2. An article according to claim 1, wherein the block of material comprises a nickel-, cobalt-, or iron-nickel-based superalloys, or combinations thereof.

3. An article according to claim 1, wherein the block of material comprises a generally rectangular solid block of material.

4. An article according to claim 3, wherein the defect structure comprises at least one slot disposed in the block of material.

5. An article according to claim 1, wherein the defect structure comprises at least one slot that is disposed in faces of the block of material.

6. An article according to claim 5, wherein the at least one slot comprising a thickness in a range from about 10 micrometers (μm) to about 1 millimeter (mm ) and a depth in a range from about 10 micrometers to about 10 millimeters.

7. An article according to claim 6, wherein the at least one slot comprises slots on a plurality of faces of the block.

8. An article according to claim 1, wherein the standard further comprises a notch disposed in the block of material.

9. An article according to claim 8, wherein the notch comprises a “V” notch in the block of material.

10. An article according to claim 1, wherein the slot comprising a constant thickness in a range from about 10 μm to about 2 mm and a depth in a range from about 10 micrometers to about 10 millimeters, the “V” notch and the slot being separated by a bridge of material.

11. A tool for determining oxide removal parameters of an oxide removal process, the tool comprising:

a block of material, the block being formed of a material upon which an oxide can be formed; and

a defect structure disposed in the block of material, wherein an oxidized tool is capable of being used to determine parameters of an oxide removal process by measuring oxide removal from the block and defect structure after the oxide removal process.

12. A tool according to claim 11, wherein the block of material comprises a nickel-, cobalt-, or iron-nickel-based superalloys, or combinations thereof

13. A tool according to claim 11, wherein the block of material comprises a generally rectangular solid block of material.

14. A tool according to claim 11, wherein the defect structure comprises at least one defect disposed in the generally rectangular solid block.

15. A tool according to claim 11, wherein the defect structure comprises slots that are disposed in opposed faces of the generally defect solid block of material.

16. A tool according to claim 15, wherein the at least one slot comprising a constant thickness in a range from about 10 micrometers (μm) to about 1 millimeter (mm) and a depth in a range from about 10 micrometers to about 10 millimeters.

17. A tool according to claim 16, wherein the at least one slot comprises opposed slots, each opposed slots comprising a constant thickness in a range from about 10 micrometers (μm) to about 1 millimeter (mm).

18. A tool according to claim 11, wherein the standard further comprises a notch in the block of material.

19. An article according to claim 11, wherein the notch comprises a “V” notch in the block of material.

20. A tool according to claim 19, wherein the “V” notch and the at least one slot are separated by a bridge of material.

21. A tool according to claim 11, wherein defect structure comprises an oxide-filled, crack-like defect, and the oxide removal parameters comprise at least one of:

depth of oxide removal in the crack-like defect and the surfaces of the generally rectangular solid block of material, braze repair capability, depth of braze filing, and alloying element depletion at the crack-like defect and surfaces of the block of material.

22. A tool according to claim 21, wherein the oxide removal process parameters are determined by an evaluation comprising at least one of:

optical inspection, brazing evaluation, weight loss measurement, electrical resistivity measurement, and wetability evaluation.

23. A tool according to claim 11, wherein the tool determine benchmarks for the oxide removal process.

24. A tool according to claim 23, wherein the benchmarks comprise at least one of:

oxide removal amounts as a function of process time; oxide removal amounts as a function of reactor temperature; oxide removal as a function of reactor design and loading configuration; alloying element depletion of the block of material; alloying element depletion of the block of material as a function the oxide removal process; efficiency of the individual reactor; oxide removal as a function of the process run, and oxide removal as a function of previous oxide removal processes.

25. A process of determining oxide removal status, the process comprising:

disposing an oxidized standard in a reactor, the reactor capable of implementing an oxide removal process, the oxidized standard comprising a block of material, the block being formed of a material upon which the oxide is formed and a defect structure disposed in the block of material;

conducting an oxide removal process; and

evaluating the standard for at least one of oxide removal amounts as a function of process time; oxide removal amounts as a function of reactor temperature; oxide removal as a function of reactor design and loading configuration; alloying element depletion of the block of material; alloying element depletion of the block of material as a function the oxide removal process; efficiency of the individual reactor; oxide removal as a function of the process run, and oxide removal as a function of previous oxide removal processes.

26. A process according to claim 25, wherein the slot structure comprises a simulated crack-like defect and the step of evaluating comprises exposing the simulated crack-like defect.

27. A process according to claim 26, wherein the standard comprises the simulated crack-like defect and a notch opposed to the simulated crack-like defect, the step of exposing the simulated crack-like defect comprises:

compressing the standard at the notch to expose surfaces of the simulated crack-like defect.

28. A process according to claim 25, wherein the step of evaluating comprises:

exposing the simulated crack-like defect by metallographically sectioning the standard and splitting the standard at a simulated crack-like defect.

29. A process according to claim 25, wherein the step of evaluating comprises:

evaluating by optical inspecting, brazing capability determination, electrical resistivity measuring, weight loss measuring, and wetability evaluating.

30. A process according to claim 25, wherein the process of determining oxide removal status further comprises determining at least one of:

31. A process for forming an oxide removal process evaluation standard, the standard comprising a block of material, the block being formed of a material upon which an oxide can be formed; and a simulated defect structure disposed in the block of material, wherein the standard is capable of determining oxide removal process status, the process comprising:

machining the simulated defect structure in the block of material; and

exposing the block of material to a thermal treatment to form an oxide on the block of material and on surfaces of the simulated defect structure.

32. A process according to claim 31, wherein the step of exposing the block of material to a thermal treatment comprises controllably exposing the block of material to a high-temperature, oxidizing thermal environment for time period to form oxides on the block and filling the simulated defect structure.

33. A process according to claim 31, further comprising compressing the simulated defect structure to form a simulated crack-like defect after the step of machining the simulated defect structure.