US20030015267A1 - Delay compositions and detonation delay devices utilizing same - Google Patents

Delay compositions and detonation delay devices utilizing same Download PDF

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US20030015267A1
US20030015267A1 US09/895,334 US89533401A US2003015267A1 US 20030015267 A1 US20030015267 A1 US 20030015267A1 US 89533401 A US89533401 A US 89533401A US 2003015267 A1 US2003015267 A1 US 2003015267A1
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composition
delay
red lead
silicon
weight
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Rejean Aube
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Orica Explosives Technology Pty Ltd
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Publication of US20030015267A1 publication Critical patent/US20030015267A1/en
Priority to US11/977,921 priority Critical patent/US8066832B2/en
Priority to US13/302,186 priority patent/US20120060983A1/en
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    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
    • C06B33/12—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being two or more oxygen-yielding compounds
    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
    • C06C5/00—Fuses, e.g. fuse cords
    • C06C5/06—Fuse igniting means; Fuse connectors
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42—AMMUNITION; BLASTING
    • F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
    • F42B3/00—Blasting cartridges, i.e. case and explosive
    • F42B3/10—Initiators therefor
    • F42B3/16—Pyrotechnic delay initiators

Definitions

  • This invention relates to delay compositions used in detonators for explosives (sometimes referred to as blasting caps) and other devices (e.g. inline detonation delay devices), and to detonation delay elements and devices containing such compositions. More particularly, the invention relates to delay compositions having slow-burning (long delay) times for use with both non-electric and electric detonators, inline delay devices, and the like.
  • Delay compositions are materials that burn away rapidly, but not instantly, when ignited, thus create a timing delay, in the nature of a fuse, when shaped and compacted in the form of an elongated body or column and ignited at one end. Such compositions may therefore be used to create a delay between the instant at which a detonator or similar device receives a firing signal (which commences ignition of the column of delay composition), and the instant at which an associated explosive charge is set off (by heat when the combustion reaches the remote end of the burning column), or a further firing signal is generated.
  • Delay detonators and similar delay devices are widely employed in mining, quarrying and other blasting operations in order to permit sequential initiation of explosive charges distributed in a predetermined pattern of bore holes or shot holes.
  • the provision of a delay between sequential initiation of adjacent bore or shot holes is effective in controlling the fragmentation and throw of the rock being blasted and, in addition, provides a reduction in ground vibration and in air blast noise.
  • Modern commercial delay detonators whether non-electric or electric, normally comprise a metallic shell, closed at one end, which contains in sequence from the closed end: a base charge of a detonating high explosive, such as for example pentaerythritoltetranitrate (PETN), and an adjacent primer charge of a heat-sensitive detonable material, such as for example lead azide.
  • a detonating high explosive such as for example pentaerythritoltetranitrate (PETN)
  • PETN pentaerythritoltetranitrate
  • Adjacent to the heat-sensitive material is a consolidated, e.g. compressed, column of delay composition of sufficient length and quantity to provide a desired delay time as described above.
  • the column of the delay composition is normally confined within a hollow tubular confinement element made of metal.
  • an ignition (starter) charge adapted to be ignited by an electrically heated bridge wire or, alternatively, by the heat and flame of a low energy detonating cord or shock wave conductor retained in the open end of the metallic shell.
  • Such a delay detonator may serve as an in-line delay as when coupled at both ends to a detonating cord or shock wave conductor.
  • a delay device need not also be capable of serving as a detonator in order, for example, to initiate a shock wave conductor.
  • An ignition charge in close proximity to the end of the shock wave conductor, instead of a base charge of detonating high explosive, will suffice.
  • the containment of the delay composition within a confinement element facilitates the handling of the composition and its introduction into a detonator or the like.
  • the metal also protects other components (e.g. the outer shell of a detonator) from the heat and by-products of combustion as the delay composition is consumed and, for reasons of economy, minimizes the amount of the delay composition that is required.
  • lead has often been used as the metal for the confinement elements. Lead is soft and malleable and can be loaded with a burning core, drawn to a desired diameter and cut to required lengths (different lengths produce different delay times). Lead also has a low thermal conductivity and heat capacity, and therefore diverts only a minimum amount of heat from the composition as it burns, thus reducing the risk that the combustion may be quenched or extinguished prior to complete consumption of the delay composition.
  • rigid metal confinement elements can facilitate fabrication of delay units and their integration into detonators and delay devices, etc.
  • zinc and other suitable rigid metals have higher thermal conductivities and heat capacities than lead, and thus extract more heat from the delay composition as it burns. This can increase the failure rate of detonators and delay devices because there may be insufficient heat remaining in the delay composition to maintain the combustion temperature until complete consumption of the composition has taken place, especially when such devices are used in low temperature environments.
  • Particularly at risk of failure are delay units intended to provide long delays, e.g. more than one second, often used in underground applications.
  • delay compositions are known in the art. These generally comprise mixtures of fuels and oxidizers of various kinds. Many are substantially gasless compositions, which are generally preferred; that is, they burn without evolving large amounts of gaseous by-products which could interfere with the functioning of a delay detonator or other device. In addition to an essential gasless requirement, delay compositions are also required to be safe to handle, from both an explosive and health viewpoint, they must be resistant to moisture and not deteriorate over long periods of storage and hence change in burning characteristics, they must operate reliably over a wide range of temperatures, and they must be adaptable of use in a wide range of delay units within the limitations of space available inside a standard detonator shell or similar device. The numerous delay composition of the prior art have met with varying degrees of success in use and application.
  • the heat sink effect of the confinement metal element should not be such as to risk quenching of the exothermic reaction (i.e. burning) of the delay composition.
  • the delay compositions of the kind disclosed by Beck et al. do not work as well as might be desired, particularly when used for producing long delays.
  • the oxides used in these compositions as fluxes are expensive.
  • Beck et al. suggested that additions of red lead oxide or other reactive ingredients that cause a faster rate of burning may be incorporated into the composition, but noted that large loadings of such reactive ingredients may obviate the facilitating role of the flux. Beck et al. therefore recommended that the compositions omit such additional reactive ingredients.
  • An object of the present invention is to provide a delay composition that may be confined within a rigid delay element and yet still undergo reliable ignition and burning capable of producing long timing delays.
  • Another object of the invention is to provide a delay composition of the stated kind that can be produced easily and inexpensively.
  • Yet another object of the invention is to provide delay devices that are reliable in that they ignite and burn continuously with a high degree of reliability, even at low temperatures, and provide a reliable long delay period.
  • Another object of the invention is to provide delay elements and detonators or similar devices capable of providing long delay times while making use of rigid confinement elements for delay compositions.
  • a delay composition comprising mixed particles of silicon, barium sulfate and red lead, the red lead being present in an amount of about 3 to 15% by weight, preferably 6 to 12%, and more preferably 9 to 12% by weight, of the composition.
  • the barium sulfate and silicon components are preferably present in amounts of 40 to 65% by weight and 50 to 25% by weight, respectively, of the total weight of the composition.
  • the composition preferably also contains a binder causing collections of the particles to bind together in the form of free-flowing granules.
  • the binder is preferably present in amounts of 0.2 to 0.6% by weight of the composition.
  • Suitable binders include solvent-soluble polymers, silica and swelling clays, preferably water-soluble derivatives of cellulose, e.g. carboxymethyl cellulose.
  • a delay element for a detonator or delay device comprising an elongated hollow metal tube containing a delay composition comprising mixed particles of silicon, barium sulfate and red lead, the red lead being present in an amount of about 3 to 15% by weight of the composition.
  • the tube is preferably open at both ends, and is preferably made of a rigid metal, most preferably zinc.
  • the delay composition is preferably compressed to a density in the range of 1.8 to 2.2 g/cc, more preferably 1.95 to 2.15 g/cc.
  • the delay element preferably includes a sealer at one end thereof (the end subject to combustion first).
  • This is may be a type of pyrotechnic composition that forms a slag of material which seals the open end of the delay element. This is desirable as the burn rate of the delay composition may be pressure-dependent and uniform delay times can be achieved when the sealer regulates the pressure within the delay element.
  • the delay element may also have a starter composition at the same end.
  • the purpose of the starter composition is to generate enough heat to reliably initiate the slow burning delay composition having a high ignition temperature.
  • a single composition may server both the function of a starter composition and of a sealer composition.
  • a delay device such as a detonator or inline delay device, comprising a detonation signal input, a charge to be detonated by the detonation signal input, and delay element separating said detonation signal input and said charge, the delay element being an element of the type described above.
  • FIG. 1 is a vertical cross-section of an example of a non-electric detonator incorporating a delay element containing a delay composition of the present invention
  • FIG. 2 is a vertical cross-section of an example of an electric detonator incorporating a delay element containing a delay composition of the present invention.
  • FIGS. 3 to 20 are graphs showing results obtained in the ways described in the following Examples.
  • FIG. 1 of the accompanying drawings shows an example of a non-electric delay detonator 10 of a kind with a delay element and delay composition according to the present invention may be employed. As such, the detonator itself forms an example of one aspect of the present invention.
  • the detonator 10 has a metallic tubular detonator shell 11 closed at its bottom end and containing a base charge 12 of explosive (e.g. PETN) pressed or cast therein.
  • a confinement element 14 made of a rigid metal such as zinc, aluminum, steel or brass (preferably zinc).
  • the confinement element 14 contains an initiating charge 15 (e.g. of lead azide) at the lower end of the element, and a delay composition 16 within the delay element above the initiating charge 15 .
  • the confinement element and its contents, particularly the delay composition together form a delay element 14 a that is fabricated prior to the assembly of the detonator.
  • a starter element 17 which preferably also acts as a sealer, is located above the delay element.
  • a lower end of a bore in the starter element contains a starter charge 18 .
  • An anti-static cup 19 is positioned above the starter element and is designed to receive a lower end of a shock tube 20 , which carries the firing signal.
  • a bushing 21 surrounds the lower end of the shock tube 20 where it enters the detonator 10 , and the upper end of the detonator shell 11 is crimped to hold the bushing and shock tube in place.
  • FIG. 2 shows an example of an electric detonator 10 ′.
  • the detonator also has a metallic tubular detonator shell 11 ′ closed at its bottom end and containing a base charge 12 ′ of explosive (e.g. PETN) pressed or cast therein.
  • a base charge 12 ′ of explosive e.g. PETN
  • a delay element 14 ′ Located above the base charge 12 ′ is a delay element 14 ′ made of a rigid metal such as zinc, aluminum, steel or brass (preferably zinc).
  • the delay element 14 ′ contains an initiating charge 15 ′ (e.g. of lead azide) at the lower end of the element, and a delay composition 16 ′ within the delay element above the initiating charge 15 ′.
  • a starter element 17 ′ which may also act as a sealer, is located above the delay element, and a lower end of a bore in the starter element contains a starter charge 18 ′.
  • a hollow plastic tube 25 is positioned above the starter element 17 ′ and contains an electrically operated fuse head 26 attached to leg wires 27 that exit the detonator and that convey the electrical firing signal.
  • a bushing 21 ′ is positioned above the plastic tube 25 and has holes through with the leg wires may pass. The upper end of the detonator shell 11 ′ is crimped around the bushing 21 ′ to hold the leg wires and detonator contents securely in place.
  • the delay compositions of the invention are particularly suitable for creating long delay periods, e.g. more than one second, preferably 1 to 12 seconds, more preferably 1 to 9 seconds, and most preferably 2 to 9 seconds.
  • the compositions should preferably have a burn rate (burn duration) in the range of at least 1500 milliseconds per linear inch, more preferably 2,000 to 7000 milliseconds per linear inch, and most preferably about 4,000 to 6,000 milliseconds per linear inch, and ideally 5,000 to 6,000 milliseconds per linear inch.
  • the delay compositions of the present invention contain about 3 to 15% by weight of particulate red lead in addition to particles of silicon and barium sulfate. More preferably, the amount of red lead is 6 to 12% by weight, and most preferably it is 9 to 12% by weight. If the percentage of red lead is increased much beyond about 15% by weight, the burn rate becomes excessively fast for long delays, whereas if the percentage is less than 3%, there are no benefits in terms of robustness of combustion and reliability. Although the amount of red lead is much less than previously employed in compositions of this kind (e.g. as disclosed in U.S. Pat. No. 4,419,154), it has been surprisingly found that the amount is sufficient to impart suitable robustness and reliability of combustion to the composition when used in rigid metal confinement elements, without increasing the burn rate unacceptably for long delay uses.
  • the red lead used in the compositions of the present invention does not act as a flux. Without wishing to be bound by any particular theory of operation, the red lead appears to react with silicon at a low ignition temperature (about 500° C.) and generates heat which facilitates the barium sulfate/silicon combustion reaction whose ignition temperature is high (about 1200° C.).
  • the relative proportions of the silicon and barium sulfate are preferably 40 to 65% by weight barium sulfate and 25 to 50% by weight silicon (this corresponds to 45 to 70% by weight of barium sulfate to 30 to 55% by weight of silicon before the addition of the red lead).
  • a binder (described below)
  • no other materials are present in the composition. While the presence of fluxes can be tolerated, there is no particular advantage to their use in the present invention and their use merely adds cost.
  • compositions of the present invention may be prepared simply by dry mixing particles of the essential ingredients in the indicated proportions.
  • the particulate starting material preferably has a specific surface area of typically about 0.8 m 2 /g (e.g. about 0.75 to 0.85 m 2 /g).
  • the silicon powder preferably has a specific surface area of about 6 to 8 m 2 /g.
  • the red lead preferably has a particle size of about 1 to 3 microns.
  • binders include solvent-soluble polymers, fine silica and finely ground swelling clays. While polyvinylchloride may be used as a binder, it is more preferable to use a water-soluble form of cellulose, e.g. nitrocellulose or, most preferably, sodium carboxymethyl cellulose (e.g. as manufactured by a European subsidiary of Hoechst and sold under the trademarks TYLOSE and TYLOSE C-600).
  • This material is a sugar-like powder that is dissolved in water and then used for the wet mixing step. Standard methods of wet mixing, granulation and drying may be employed.
  • a binder makes it possible to produce the composition in the form of free-flowing granules made up of collections of particles of silicon, barium sulfate, red lead and binder. Free-flowing granules have the ability to flow freely (i.e. without clumping in the nature of dry sand) when poured from one container to another. This ability is highly preferred given that the composition must be introduced into the interior of a rigid confinement element of narrow interior diameter (e.g. typically about 3.35 mm) and then compacted.
  • the agglomerated granules each tend to contain particles (of all of the main constituents) with a range of particle sizes.
  • the homogeneity of the resulting composition is therefore very high and there tends to be little separation of large and small particles when the composition is subjected to storage or use over a long period of time.
  • the binder when present, is preferably contained in the resulting composition (when dry) in an amount in the range of 0.2 to 0.6% by weight, more preferably 0.3 to 0.5% by weight, of the total composition. With amounts more than 0.6% by weight, the granulation process becomes difficult. When the amount is less than about 0.2% by weight, the binding effect may become inadequate.
  • the composition After formation and drying, the composition is introduced into a rigid metal confinement element, as noted, and is compacted therein, usually by introducing a metal rod into one end of the confinement element and pressing while preventing the composition from escaping from the opposite end of the tubular confinement element. Pressing from both ends may, of course, also take place.
  • the resulting composition in the confinement element preferably has a density falling within the range of 1.90 to 2.20 g/cc, most preferably 1.95 to 2.15 g/cc. Compaction to a suitable density is important to ensure reliable propagation of combustion, although the desired density may vary somewhat from composition to composition.
  • red lead in the delay composition in the indicated amounts does not alter the essential character of the Si/BaSO 4 mixture as a slow delay composition (i.e. it does not substantially speed up or slow down the burning rate) but its presence does impart to the composition resistance to quenching caused by the heat-sink effect of the tubular metal confinement element, so that the composition is effective in rigid elements such as zinc elements.
  • Rigid elements containing the compositions of the invention have shown themselves in tests to be effective as reliable, reproducible delay elements within the confines of standard detonator shell dimensions used in the art while providing delays of more than one second, e.g. from about 2 seconds to optimally 9 seconds or even higher.
  • the rigid elements tested were in fact zinc elements, being the presently preferred metal for rigid confinement elements, but may of course have been made of another suitable material, e.g. aluminum, steel or brass.
  • the delay compositions of the invention consists only of silicon, barium sulfate, red lead and optionally a binder in the indicated amounts, i.e. there are no other materials such as oxidants and fluxes, except for incidental or adventitious minor impurities or ingredients.
  • Rigid zinc tubular confinement elements having bore diameters of 3.35 mm were loaded with each of the compositions, as well as a control containing no Pb 3 O 4 .
  • the loaded rigid confinement elements were assembled into detonators for testing. It was found necessary to use a Pb 3 O 4 /Si starter composition on top of the BaSO 4 /Silicon/Pb 3 O 4 mixture for reliable ignition. A pyrotechnic sealer element was placed on top of the starter element.
  • These detonators were assembled as shocktube (non-electric) detonators and tested for average delay timing and coefficient of variation (CV). The results of the tests are shown in Table 1 below.
  • a production mix sample of standard barium sulfate/silicon composition containing 45% by weight of silicon and 55% by weight of barium sulfate (referred to as Y composition) was first divided in 5 small mixes of 10 g each in a small VelostatTM (electrically conductive polymer) container. The first sample was left intact as a reference control sample while an addition of 3%, 5%, 7%, and 9% of red lead was made in the subsequent mixes. Conductive rubber balls were added to the mixes to help the ingredients to mix together during tumbling of the VelostatTM containers.
  • a 1 Kg batch of a modified standard barium sulfate/silicon composition (Y composition) having 6% red lead in it was prepared.
  • the respective mass ratios for the ingredients were 51.7% of BaSO 4 (0.8 m 2 /g surface area), 42.3% Silicon (milled for 12 hours) and 6% of Pb 3 O 4 .
  • the red lead was added to the medium from the start to ensure a good dispersion of particles, a regular wet mixing process for standard barium sulfate/silicon composition was followed.
  • compositions (both of the dry mix and the wet mix) were tested for ignition by friction. None of the compositions containing red lead showed signs of ignition when tested for friction sensitivity using a 1.33 kg steel torpedo sliding with 30° angle from 30 inch height.
  • a zinc confinement element was weighed, placed in a holder and a delay composition of the invention was poured into its cavity and pressed at the desired pressure in many small increments until full. The element was weighed again and the powder content recorded. The reliability (standard deviation SD) of powder content in elements was found good for both element lengths evaluated, as shown in Table 2 below. TABLE 2 Element Length Charge Weight Sample Size SD 12 mm 201 mg 30 2.1 30 mm 504 mg 30 6.0
  • the graph of FIG. 3 shows that the presence of red lead in a standard composition of barium sulfate/silicon (55%:45% by weight) has first, an effect of slowing down the burn rate with the 3% addition of red lead and slight speed increases with the higher red lead content.
  • the delay timings were determined in ORICA® 2.9 inch detonator shell having a 9.3 mm (0.362′′) zinc confinement element as main and a regular starter and sealer from drawn lead tube.
  • the graph of FIG. 4 illustrates the coefficient of variation of measured timing delays.
  • the maximum quantity of red lead that can be added to the barium sulfate/Si composition for a long delay period detonator is identified and the resistance to shock stop (failure of a detonator due to the shock from an adjacent explosion) of such systems is characterized for both, drawn lead and rigid confinement element technology.
  • All mixes used for the delay timing evaluation are from small dry mixes where red lead was added in various quantities in barium sulfate/Si. The ingredients were put together and tumbled in small Velostat pots with conductive rubber balls.
  • a steel torpedo of 1.33 Kg weight slides on a sample of powder from 30 inch height and 30° angle.
  • the lead azide charge 110 mg was pressed inside the zinc element cavity. The rest of the cavity was filled with the delay powder. A regular starter (red lead+silicon 75:25 by weight) and sealer (sealer with a small bore element filled with red lead+silicon 63:37 by weight) was pressed on top of the rigid element and a sealer crimp applied.
  • a low entropy plastic disc (LE disc) was put on top of the lead azide charge for those detonators made with the main delay elements from a drawn lead rod.
  • FIGS. 9 and 10 show the delay timing pattern for modified basic barium sulfate/silicon composition with 0% to 20% red lead content. A plateau of relatively stable delay times is observed for those mixes having between 0% and 12% of red lead added in the basic barium sulfate/silicon composition.
  • FIG. 9 is a graph showing the delay timing in zinc elements (9.30 mm L) on Y comp+Red Lead content (E starter & H sealer from drawn lead).
  • FIG. 10 is a graph showing the CV's from delay timing in zinc elements (9.30 mm) on Y comp.+Red Lead content (E starter & H sealer from drawn lead)
  • a drum test was performed on composition Y and modified comp. Y containing 6% and 12% of Red Lead.
  • the LP detonators from DNES (7000 ms) were also tested for shock resistance. Test method used: Cooking mode; meaning that both detonators were fired simultaneously. Delay timings: target: 5000 ms and 7000 ms donor: 2500 ms and 3500 ms
  • Test 1 Main delay composition in rigid zinc elements Control sample of Y comp.: 3/10 failures caused by shock stop. Y + 6% of Red Lead: 6/10 failures caused by shock stop. Y + 12% of Red Lead: 0/10 failure. DNES 7000 ms: 0/10 failure.
  • Test 2 Main delay composition in drawn lead elements Control sample of Y comp.: 5/10 failures caused by shock stop; Control sample of Y comp.: 5/10 failures caused by shock stop; 1 failed at the LE disc. Y + 6% of Red Lead: 8/10 failures caused by shock stop. Y + 12% of Red Lead: 6/10 failures caused by shock stop.
  • This Example relates to the use of a binder (carboxymethyl cellulose) in the preparation of the delay compositions of the invention.
  • the ratio of water to dry ingredients was 40%.
  • the batches contained 6%, 9% or 12% red lead and amounts of TYLOSE from 0.3 to 0.6% by weight.
  • the ratio of barium sulfate to silicon (discounting other ingredients) was about 55:45 by weight).
  • the mixtures were then dried for a few hours and manually granulated behind a shield through a 20 Tyler mesh sieve. The resulting granules were found to flow very well (i.e. freely), e.g. when poured from one container to another.
  • Test #2 Composition BaSO 4 /Si/Pb 3 O 4 /Tylose BaSO 4 /Si/Pb 3 O 4 /Tylose Incremental loading 5.0 mm pressed 3.0 mm pressed Loading force 150 pounds on punch 100 pounds on punch (12000 psi) (8000 psi) Pressed density 2.10 g/cc 2.10 g/cc Average delay of 7369 ms 7399 ms timing Coefficient of 2.2% 1.8% variation
  • Detonators were constructed with the rigid zinc confinement elements. These detonators contained a starter comprising a mixture of red lead and fine silicon (so-called E starter) and a sealer (so-called H sealer) prepared with a small bore element made from drawn lead rod containing a mixture of red lead and very fine silicon. All the results were obtained using ORICA® detonator shells.
  • the 6% red lead mix showed 20% detonator failures at room temperature.
  • the 9% red lead mix did not show detonator failure at room temperature, but 50% detonators failed when fired at low temperature ( ⁇ 40° C.).
  • the 12% red lead mix showed no failures at ⁇ 40° C. and was selected for the following extended characterization.
  • the burn rate of the composition in zinc elements was found to be very linear, even at low temperatures ( ⁇ 40° C.).
  • the graph of FIG. 11 shows the delay time pattern for the long period (LP) composition BaSO 4 /Si/Pb 3 O 4 /TYLOSE (48/39.5/12/0.5% by weight) versus the element length.
  • the graph of FIG. 12 shows the delay time pattern for BaSO 4 /Si/Pb 3 O 4 /TYLOSE
  • the graph of FIG. 13 shows that the addition of Tylose slows down the composition burn rate.
  • the loading pressure was kept constant at 12000 psi in 44 mm zinc elements.
  • FIG. 14 shows the “warming up” curve for a sample taken out of the freezer for five minutes.
  • the powder loading density is an important factor for the composition. This was found to be particularly true when detonators were fired at low temperature.
  • the graph of FIG. 15 shows the failure rate versus powder loading pressure (psi) for BaSO 4 /Si/Pb 3 O 4 /TYLOSE (48/39.5/12/0.5% by weight) loaded in 44 mm zinc elements fired at ⁇ 40° C.
  • the graph of FIG. 16 shows the number of detonator failures recorded when fired at ⁇ 40° C. TYLOSE contents of 0.3, 0.4 and 0.5% by weight did not cause failures.
  • the graph of FIG. 17 shows the timing shift between +20° C. and ⁇ 40° C. for long period composition BaSO 4 /Si/Pb 3 O 4 /TYLOSE in 44 mm zinc confinement elements and for regular ORICA® and DNES® long period detonators. long period detonators.
  • the graph of FIG. 18 shows the coefficient of variation on delay timing at ⁇ 40° C. for the BaSO 4 /Si/Pb 3 O 4 /TYLOSE composition pressed at 12,000 psi in 44 mm zinc element, and for regular ORICA® and DNES® long period detonators.
  • composition containing red lead +0.5% TYLOSE in 30 mm length zinc elements Composition containing red lead +0.5% TYLOSE in 30 mm length zinc elements.
  • the donor detonator was an ORICA® LP 10 (3500 ms delay) for all tests.

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CN103539595A (zh) * 2013-10-28 2014-01-29 安徽理工大学 用于雷管的纳米延期药的制备方法

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CL2007002677A1 (es) * 2006-09-20 2008-05-02 African Explosives Ltd Metodo para fabricar una composicion pirotecnica de retardo que comprende mezclar un oxidante solido, un combustible solido y agua para formar una suspension acuosa, transformar la suspension en goticulas y secar por gas dichas goticulas para formar
AU2011224469B2 (en) * 2010-03-09 2014-08-07 Dyno Nobel Inc. Sealer elements, detonators containing the same, and methods of making
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CN103539595A (zh) * 2013-10-28 2014-01-29 安徽理工大学 用于雷管的纳米延期药的制备方法

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WO2002072504A1 (en) 2002-09-19
CA2340523C (en) 2009-06-02
US20080223242A1 (en) 2008-09-18
AU2002240749B2 (en) 2005-02-24
CA2340523A1 (en) 2002-09-09
US20120060983A1 (en) 2012-03-15
SE0302370D0 (sv) 2003-09-04
US8066832B2 (en) 2011-11-29
SE0302370L (sv) 2003-11-10
ZA200306414B (en) 2004-08-18

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