US20020134957A1 - Electromagnetically actuated valve - Google Patents
Electromagnetically actuated valve Download PDFInfo
- Publication number
- US20020134957A1 US20020134957A1 US09/890,851 US89085101A US2002134957A1 US 20020134957 A1 US20020134957 A1 US 20020134957A1 US 89085101 A US89085101 A US 89085101A US 2002134957 A1 US2002134957 A1 US 2002134957A1
- Authority
- US
- United States
- Prior art keywords
- valve
- armature
- damping
- closing
- valve according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000013016 damping Methods 0.000 claims abstract description 23
- 230000004907 flux Effects 0.000 claims abstract description 16
- 238000007789 sealing Methods 0.000 claims description 6
- 238000002347 injection Methods 0.000 claims description 5
- 239000007924 injection Substances 0.000 claims description 5
- 229920002379 silicone rubber Polymers 0.000 claims description 4
- 239000004945 silicone rubber Substances 0.000 claims description 4
- 239000012528 membrane Substances 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16K—VALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
- F16K31/00—Actuating devices; Operating means; Releasing devices
- F16K31/02—Actuating devices; Operating means; Releasing devices electric; magnetic
- F16K31/06—Actuating devices; Operating means; Releasing devices electric; magnetic using a magnet, e.g. diaphragm valves, cutting off by means of a liquid
- F16K31/0682—Actuating devices; Operating means; Releasing devices electric; magnetic using a magnet, e.g. diaphragm valves, cutting off by means of a liquid with an articulated or pivot armature
Definitions
- the invention relates to an electromagnetically actuatable valve, in particular for use in motor vehicles according to the preamble of claim 1.
- Electromagnetic valves are made known in the related art, in which the opening and closing of the valve is achieved by means of a moveable solenoid plunger.
- the disadvantage of this is that, due to the structural arrangement of the components in such valves, an air gap results between coil and center pole, between solenoid plunger and coil, and between solenoid plunger and center pole, which leads to a marked loss of magnetic flux.
- a further disadvantage of the traditional electromagnetic valves is that, when the valve opens and closes, the solenoid plunger, which is made of iron, strikes the center pole of the magnetic coil and produces a clearly audible noise.
- Object of the present invention is to create an electromagnetically actuatable valve of the type described in the preamble of claim 1 that is low-noise or optimized in terms of noise during opening and closing that simultaneously ensures an improved magnetic flux and also saves space.
- the electromagnetically actuatable valve has a magnet part, a moveable armature element, a spring element, and a valve part.
- the magnet part includes at least one magnetic coil wound on a coil form, a flux concentrating element, and a center pole.
- the valve part has a closing element that cooperates with the armature element and controls the opening and closing of the valve on a valve seat.
- the armature element of the valve is designed as a clapper-type armature.
- the use of a clapper-type armature is advantageous, on the one hand, because the entire electromagnetically actuatable valve can then be designed to be smaller in size than when a traditional solenoid plunger is used. This space-saving design of the valve expands its potential uses.
- the use of a clapper-type armature involves a better efficiency of the magnetic circuit, which is caused, among other things, by the resultant improved possibility of arranging the clapper-type armature relative to the other components of the valve, whereby air gaps that inhibit magnetic flux are largely avoided and only occur between center pole and armature element.
- the clapper-type armature according to the invention cooperates with the center pole by way of a damping element so that unpleasant noises are prevented when the valve opens and closes. This is particularly important when the electromagnetically actuatable valve is situated in the passenger compartment of a motor vehicle, e.g., in the seats, to vary the seat surface.
- the armature element and the valve part are preferably located in a housing.
- the armature element, the flux concentrating element, the closing element, the spring element as well as the damping element are confined in the housing in pressure-sealed fashion. This can be achieved by pressure-sealed injection of the flux concentrating element. All sensitive components of the valve are therefore protected.
- the housing can also be designed to be two-piece or multi-piece and be permanently joined by gluing the housing parts together, for example.
- the electromagnetically actuatable valve has a damping element with a damping stop which absorbs sound, so noise is reduced when the valve opens and closes.
- the flux concentrating element is preferably designed as a bracket which is situated on the perimeter of the magnetic coil.
- the armature element actuates a closing element to open and close the valve, which closing element is designed as an umbrella sealing plug with an umbrella membrane.
- the umbrella sealing plug is flexible and preferably made out of silicone rubber.
- the damping element and the closing element can preferably be designed as an integral damping shoe, which also consists entirely of an elastic material such as silicone rubber.
- This damping shoe can be attached directly to the armature element or it can be injection moulded to it.
- This embodiment is particularly practical, because the absorption of the sound caused by the striking of the clapper-type armature when the valve opens as well as when it closes can be achieved using the same device, which can be easily and quickly attached to the clapper-type armature by sliding it into place, or it has already been injection moulded to it.
- FIG. 1 shows a schematic diagram of a cross-sectional view of the electromagnetically actuatable valve according to the invention
- FIG. 2 shows a schematic diagram of a cross-sectional view of a preferred embodiment of the electromagnetically actuatable valve according to the invention.
- FIG. 1 shows a schematic diagram of an electromagnetically actuatable valve 1 in cross section which has a magnet part 2 , which includes a coil form 3 on which a magnetic coil 4 is wound, as well as a perpendicular flux concentrating element 5 on the perimeter of the coil form 3 , and a center pole 6 situated inside the coil form 3 .
- the valve 1 has a valve part 9 having a closing element 11 .
- the closing element 11 for opening and closing the valve 1 cooperates with an armature element 7 on a valve seat 10 , whereby the armature element 7 is designed as a clapper-type armature.
- the armature element is thereby situated on a face of the magnet part perpendicular to the longitudinal axis of the center pole 6 and is connected with the flux concentrating element 5 .
- the closing element is an umbrella sealing plug with an umbrella membrane that makes it possible for a fluid to flow through the valve channel when the armature element 7 is picked up.
- the umbrella stopper consists of a flexible material such as silicone rubber.
- a head 18 designed on the center pole 6 is provided with a damping element 14 that has a damping stop 13 .
- the armature element 7 is held on a spring element 8 on the side opposite to the side actuating the closing element.
- the spring element 8 is a spiral-coiled spring that returns the armature element 7 to its position that closes the valve.
- the spring element 8 , a section of the flux concentrating element 5 , the armature element 7 , the head of the center pole 18 as well as the closing element 11 are contained in a housing.
- the housing comprises an upper housing section 16 that touches the coil form 3 , and a lower housing section 17 in which two openings 19 —one inlet opening and one outlet opening—and the valve seat 10 are located.
- the upper housing section 16 and the lower housing section 17 are permanently connected with each other and form a pressure-sealed compartment.
- the valve seat is generally a component of the lower housing 17 .
- FIG. 2 also shows a schematic diagram of an electromagnetically actuatable valve 1 in cross section, whereby the magnet part of the valve 1 has the same design as the one described in FIG. 1. It differs, however, in that the closing element 11 and the damping stop 13 are designed single-piece as a damping shoe 15 .
- the damping shoe 15 is attached directly to the armature element 7 or it is injection moulded to it.
- a leaf spring is used as the spring element 8 , which is attached to an end section of the flux concentrating element 5 extending into the housing and to a section of the armature element 7 .
- the layout of the housing as well as the arrangement of the components of the electromagnetically actuatable valve 1 included therein correspond to those in FIG. 1.
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Magnetically Actuated Valves (AREA)
Abstract
The invention relates to an electromagnetically actuatable valve that comprises a magnet part, a moveable armature element, a spring element, and a valve part. The magnet part has at least one coil form with a magnetic coil wound on it, a flux concentrating element and a center pole. The valve part comprises a closing element that cooperates with the armature element and controls the opening and closing of the valve on a valve seat. The armature element is designed as a clapper-type armature and cooperates with the center pole by way of a damping element.
Description
- The invention relates to an electromagnetically actuatable valve, in particular for use in motor vehicles according to the preamble of
claim 1. - Electromagnetic valves are made known in the related art, in which the opening and closing of the valve is achieved by means of a moveable solenoid plunger. The disadvantage of this is that, due to the structural arrangement of the components in such valves, an air gap results between coil and center pole, between solenoid plunger and coil, and between solenoid plunger and center pole, which leads to a marked loss of magnetic flux. A further disadvantage of the traditional electromagnetic valves is that, when the valve opens and closes, the solenoid plunger, which is made of iron, strikes the center pole of the magnetic coil and produces a clearly audible noise.
- Object of the present invention is to create an electromagnetically actuatable valve of the type described in the preamble of
claim 1 that is low-noise or optimized in terms of noise during opening and closing that simultaneously ensures an improved magnetic flux and also saves space. - This object is solved according to the invention using the subject matter of
claim 1. Advantageous embodiments of the subject matter according to the invention are listed insubclaims 2 through 10. - The electromagnetically actuatable valve according to the invention has a magnet part, a moveable armature element, a spring element, and a valve part. The magnet part includes at least one magnetic coil wound on a coil form, a flux concentrating element, and a center pole. The valve part has a closing element that cooperates with the armature element and controls the opening and closing of the valve on a valve seat.
- According to the present invention, the armature element of the valve is designed as a clapper-type armature. The use of a clapper-type armature is advantageous, on the one hand, because the entire electromagnetically actuatable valve can then be designed to be smaller in size than when a traditional solenoid plunger is used. This space-saving design of the valve expands its potential uses. On the other hand, the use of a clapper-type armature involves a better efficiency of the magnetic circuit, which is caused, among other things, by the resultant improved possibility of arranging the clapper-type armature relative to the other components of the valve, whereby air gaps that inhibit magnetic flux are largely avoided and only occur between center pole and armature element.
- Moreover, the clapper-type armature according to the invention cooperates with the center pole by way of a damping element so that unpleasant noises are prevented when the valve opens and closes. This is particularly important when the electromagnetically actuatable valve is situated in the passenger compartment of a motor vehicle, e.g., in the seats, to vary the seat surface.
- The armature element and the valve part are preferably located in a housing. The armature element, the flux concentrating element, the closing element, the spring element as well as the damping element are confined in the housing in pressure-sealed fashion. This can be achieved by pressure-sealed injection of the flux concentrating element. All sensitive components of the valve are therefore protected. The housing can also be designed to be two-piece or multi-piece and be permanently joined by gluing the housing parts together, for example.
- In a further preferred embodiment, the electromagnetically actuatable valve has a damping element with a damping stop which absorbs sound, so noise is reduced when the valve opens and closes.
- Moreover, the flux concentrating element is preferably designed as a bracket which is situated on the perimeter of the magnetic coil.
- In yet another preferred embodiment, the armature element actuates a closing element to open and close the valve, which closing element is designed as an umbrella sealing plug with an umbrella membrane. The umbrella sealing plug is flexible and preferably made out of silicone rubber. As a result, when the clapper-type armature, which is made of iron, strikes the umbrella sealing plug to open the valve, noise is reduced considerably.
- The damping element and the closing element can preferably be designed as an integral damping shoe, which also consists entirely of an elastic material such as silicone rubber. This damping shoe can be attached directly to the armature element or it can be injection moulded to it. This embodiment is particularly practical, because the absorption of the sound caused by the striking of the clapper-type armature when the valve opens as well as when it closes can be achieved using the same device, which can be easily and quickly attached to the clapper-type armature by sliding it into place, or it has already been injection moulded to it.
- Two preferred embodiments of the clapper-type armature are shown in the drawings, which are explained in greater detail using the description below.
- FIG. 1 shows a schematic diagram of a cross-sectional view of the electromagnetically actuatable valve according to the invention, and FIG. 2 shows a schematic diagram of a cross-sectional view of a preferred embodiment of the electromagnetically actuatable valve according to the invention.
- FIG. 1 shows a schematic diagram of an electromagnetically
actuatable valve 1 in cross section which has amagnet part 2, which includes acoil form 3 on which a magnetic coil 4 is wound, as well as a perpendicularflux concentrating element 5 on the perimeter of thecoil form 3, and acenter pole 6 situated inside thecoil form 3. Moreover, thevalve 1 has a valve part 9 having aclosing element 11. Theclosing element 11 for opening and closing thevalve 1 cooperates with anarmature element 7 on avalve seat 10, whereby thearmature element 7 is designed as a clapper-type armature. The armature element is thereby situated on a face of the magnet part perpendicular to the longitudinal axis of thecenter pole 6 and is connected with theflux concentrating element 5. To open the valve, thearmature element 7 is pulled through an induced magnetic field in the direction of the center pole. The closing element is an umbrella sealing plug with an umbrella membrane that makes it possible for a fluid to flow through the valve channel when thearmature element 7 is picked up. The umbrella stopper consists of a flexible material such as silicone rubber. Moreover, ahead 18 designed on thecenter pole 6 is provided with adamping element 14 that has adamping stop 13. Thearmature element 7 is held on aspring element 8 on the side opposite to the side actuating the closing element. Thespring element 8 is a spiral-coiled spring that returns thearmature element 7 to its position that closes the valve. - The
spring element 8, a section of theflux concentrating element 5, thearmature element 7, the head of thecenter pole 18 as well as theclosing element 11 are contained in a housing. The housing comprises anupper housing section 16 that touches thecoil form 3, and alower housing section 17 in which twoopenings 19—one inlet opening and one outlet opening—and thevalve seat 10 are located. Theupper housing section 16 and thelower housing section 17 are permanently connected with each other and form a pressure-sealed compartment. The valve seat is generally a component of thelower housing 17. - FIG. 2 also shows a schematic diagram of an electromagnetically
actuatable valve 1 in cross section, whereby the magnet part of thevalve 1 has the same design as the one described in FIG. 1. It differs, however, in that theclosing element 11 and thedamping stop 13 are designed single-piece as adamping shoe 15. Thedamping shoe 15 is attached directly to thearmature element 7 or it is injection moulded to it. Moreover, a leaf spring is used as thespring element 8, which is attached to an end section of theflux concentrating element 5 extending into the housing and to a section of thearmature element 7. The layout of the housing as well as the arrangement of the components of the electromagneticallyactuatable valve 1 included therein correspond to those in FIG. 1. -
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Claims (9)
1. Electromagnetically actuatable valve (1) comprising a magnet part (2), a moveable armature element (7), a spring element (8), and a valve part (9), whereby the magnet part has at least one magnetic coil (4) wound on a coil form (3), a flux concentrating element (5) and a center pole (6), and the valve part (9) has a closing element (11) that cooperates with the armature element (7) and controls the opening and closing of the valve on a valve seat (10), characterized in that the armature element (7) is designed as a clapper-type armature and cooperates with the center pole (6) by way of a damping element (14).
2. Valve according to claim 1 , characterized in that the armature element (7) and the valve part (9) are contained in a housing.
3. Valve according to claim 2 , characterized in that the armature element (7), the flux concentrating element (5), the closing element (11), the spring element (8), and the damping element (14) are arranged in the housing in a pressure-sealed compartment.
4. Valve according to one of the claims 1 through 3, characterized in that the damping element (14) has a damping stop (13).
5. Valve according to one of the claims I through 4, characterized in that the flux concentrating element (5) is designed as a bracket which is situated on the perimeter of the magnetic coil (4).
6. Valve according to one of the claims 1 through 5, characterized in that the closing element (11) actuated by the armature element (7) to open and close the valve (1) is an umbrella sealing plug with an umbrella membrane.
7. Valve according to claim 6 , characterized in that the umbrella sealing plug is flexible and, in particular, consists of silicone rubber.
8. Valve according to one of the claims 1 through 5, characterized in that the closing element (11) and the damping element (14) are designed as an integral damping shoe (15).
9. Valve according to claim 8 , characterized in that the damping shoe (15) is flexible and can be attached directly to the armature element (7) or it is injection moulded to it.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19958913A DE19958913A1 (en) | 1999-12-07 | 1999-12-07 | Electromagnetically actuated valve |
DE19958913.5 | 1999-12-07 | ||
PCT/DE2000/004296 WO2001042698A1 (en) | 1999-12-07 | 2000-12-02 | Electromagnetically actuated valve |
Publications (2)
Publication Number | Publication Date |
---|---|
US20020134957A1 true US20020134957A1 (en) | 2002-09-26 |
US6830231B2 US6830231B2 (en) | 2004-12-14 |
Family
ID=7931687
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/890,851 Expired - Fee Related US6830231B2 (en) | 1999-12-07 | 2000-12-02 | Electromagnetically actuated valve |
Country Status (7)
Country | Link |
---|---|
US (1) | US6830231B2 (en) |
EP (1) | EP1151217B1 (en) |
JP (1) | JP2003516509A (en) |
KR (1) | KR20010101789A (en) |
BR (1) | BR0008064A (en) |
DE (2) | DE19958913A1 (en) |
WO (1) | WO2001042698A1 (en) |
Cited By (9)
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US20060065872A1 (en) * | 2004-09-29 | 2006-03-30 | Mullally Michael J | Non-sliding valve |
US20160010760A1 (en) * | 2013-07-15 | 2016-01-14 | Parker - Hannifin Corporation | Miniature high performance solenoid valve |
US20170254435A1 (en) * | 2014-08-27 | 2017-09-07 | Koganei Corporation | Solenoid valve |
US10024452B2 (en) | 2014-08-20 | 2018-07-17 | Koganei Corporation | Solenoid valve |
US10024451B2 (en) | 2014-08-20 | 2018-07-17 | Koganei Corporation | Solenoid valve |
US10119625B2 (en) | 2014-08-20 | 2018-11-06 | Koganei Corporation | Solenoid valve |
WO2019005448A1 (en) * | 2017-06-30 | 2019-01-03 | Fisher Controls International Llc | Integrated transducer |
US10352474B2 (en) | 2014-03-18 | 2019-07-16 | Fisher Controls International Llc | Failsafe integrated transducer |
EP3964741A1 (en) * | 2020-09-07 | 2022-03-09 | KNORR-BREMSE Systeme für Nutzfahrzeuge GmbH | Plate anchor damping device for tilting anchor valve, plate anchor, and tilting anchor valve with a plate anchor damping device |
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ITTO20050348A1 (en) * | 2005-05-20 | 2006-11-21 | Matrix Spa | GROUP OF SOLENOID VALVES FOR A FUEL GAS SUPPLY DEVICE TO AN ENDOTHERMAL ENGINE |
TWI430844B (en) * | 2007-06-14 | 2014-03-21 | Graco Minnesota Inc | Longitudinal bulging seal |
CN101970920B (en) * | 2007-12-28 | 2013-03-20 | 星电株式会社 | Solenoid valve |
US8453992B2 (en) * | 2008-12-24 | 2013-06-04 | Robertshaw Controls Company | Pilot operated water valve |
US9368294B2 (en) * | 2010-12-21 | 2016-06-14 | Mitsubishi Electric Corporation | Solenoid operated device |
DE102011078426A1 (en) * | 2011-06-30 | 2013-01-03 | Robert Bosch Gmbh | Shared relay anchor |
DE102012001775B3 (en) * | 2012-01-31 | 2013-02-21 | Festo Ag & Co. Kg | Piezo valve i.e. 2/2-way piezo valve, has valve element arranged in valve chamber and linearly displaceable to perform working movement independent of bending transducer by linear guide unit relative to valve housing |
DE102012007766A1 (en) * | 2012-04-20 | 2013-10-24 | Bürkert Werke GmbH | Process and manufacture of valves, valves and valve series |
US9206921B1 (en) | 2013-01-02 | 2015-12-08 | Jansen's Aircraft Systems Controls, Inc. | Sealed solenoid and solenoid valve |
DE102014005498B4 (en) * | 2014-04-12 | 2023-03-16 | Festo Se & Co. Kg | valve device |
DE102015219176B3 (en) * | 2015-10-05 | 2017-03-30 | Conti Temic Microelectronic Gmbh | Pneumatic solenoid valve |
CA2945696A1 (en) | 2015-10-19 | 2017-04-19 | Backsaver International, Inc. | Tailgate lift handle, lift assembly, and related apparatus |
US11112025B2 (en) | 2017-03-30 | 2021-09-07 | Robertshaw Controls Company | Water valve guide tube with integrated weld ring and water valve incorporating same |
US11047501B2 (en) * | 2017-07-14 | 2021-06-29 | Robertshaw Controls Company | Normally open gas valve |
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- 2000-12-02 EP EP00989828A patent/EP1151217B1/en not_active Expired - Lifetime
- 2000-12-02 KR KR1020017009913A patent/KR20010101789A/en not_active Application Discontinuation
- 2000-12-02 BR BR0008064-0A patent/BR0008064A/en active Search and Examination
- 2000-12-02 JP JP2001543946A patent/JP2003516509A/en active Pending
- 2000-12-02 US US09/890,851 patent/US6830231B2/en not_active Expired - Fee Related
- 2000-12-02 DE DE50003440T patent/DE50003440D1/en not_active Expired - Lifetime
- 2000-12-02 WO PCT/DE2000/004296 patent/WO2001042698A1/en active IP Right Grant
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US7163187B2 (en) | 2004-09-29 | 2007-01-16 | Seal Tech, Inc. | Non-sliding valve |
US20060065872A1 (en) * | 2004-09-29 | 2006-03-30 | Mullally Michael J | Non-sliding valve |
US20160010760A1 (en) * | 2013-07-15 | 2016-01-14 | Parker - Hannifin Corporation | Miniature high performance solenoid valve |
US9482360B2 (en) * | 2013-07-15 | 2016-11-01 | Parker-Hannifin Corporation | Miniature high performance solenoid valve |
US10352474B2 (en) | 2014-03-18 | 2019-07-16 | Fisher Controls International Llc | Failsafe integrated transducer |
US10473230B2 (en) | 2014-03-18 | 2019-11-12 | Fisher Controls International Llc | Integrated transducer |
US10024452B2 (en) | 2014-08-20 | 2018-07-17 | Koganei Corporation | Solenoid valve |
US10024451B2 (en) | 2014-08-20 | 2018-07-17 | Koganei Corporation | Solenoid valve |
US10119625B2 (en) | 2014-08-20 | 2018-11-06 | Koganei Corporation | Solenoid valve |
US20170254435A1 (en) * | 2014-08-27 | 2017-09-07 | Koganei Corporation | Solenoid valve |
US10221957B2 (en) * | 2014-08-27 | 2019-03-05 | Koganei Corporation | Solenoid valve |
CN109210259A (en) * | 2017-06-30 | 2019-01-15 | 费希尔控制产品国际有限公司 | Integrated form energy converter |
WO2019005448A1 (en) * | 2017-06-30 | 2019-01-03 | Fisher Controls International Llc | Integrated transducer |
US10539251B2 (en) | 2017-06-30 | 2020-01-21 | Fisher Controls International Llc | Integrated transducer |
EP3964741A1 (en) * | 2020-09-07 | 2022-03-09 | KNORR-BREMSE Systeme für Nutzfahrzeuge GmbH | Plate anchor damping device for tilting anchor valve, plate anchor, and tilting anchor valve with a plate anchor damping device |
US11719356B2 (en) | 2020-09-07 | 2023-08-08 | Knorr-Bremse Systeme Fuer Nutzfahrzeuge Gmbh | Plate armature damping device for a tilting armature valve, plate armature, and tilting armature valve with a plate armature damping device |
Also Published As
Publication number | Publication date |
---|---|
KR20010101789A (en) | 2001-11-14 |
EP1151217B1 (en) | 2003-08-27 |
EP1151217A1 (en) | 2001-11-07 |
WO2001042698A1 (en) | 2001-06-14 |
BR0008064A (en) | 2001-11-06 |
DE50003440D1 (en) | 2003-10-02 |
US6830231B2 (en) | 2004-12-14 |
JP2003516509A (en) | 2003-05-13 |
DE19958913A1 (en) | 2001-06-28 |
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