US20020116945A1 - Process and apparatus for air separation - Google Patents

Process and apparatus for air separation Download PDF

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US20020116945A1
US20020116945A1 US09/975,306 US97530601A US2002116945A1 US 20020116945 A1 US20020116945 A1 US 20020116945A1 US 97530601 A US97530601 A US 97530601A US 2002116945 A1 US2002116945 A1 US 2002116945A1
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compressor
air separation
motor
air
electric motor
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Michael Buckland
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Linde GmbH
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Linde GmbH
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04109—Arrangements of compressors and /or their drivers
    • F25J3/04139—Combination of different types of drivers mechanically coupled to the same compressor, possibly split on multiple compressor casings
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
    • F25J3/04018—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of main feed air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
    • F25J3/04024—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of purified feed air, so-called boosted air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
    • F25J3/0403—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of nitrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
    • F25J3/04036—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of oxygen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04109—Arrangements of compressors and /or their drivers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04109—Arrangements of compressors and /or their drivers
    • F25J3/04115—Arrangements of compressors and /or their drivers characterised by the type of prime driver, e.g. hot gas expander
    • F25J3/04121—Steam turbine as the prime mechanical driver
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04109—Arrangements of compressors and /or their drivers
    • F25J3/04115—Arrangements of compressors and /or their drivers characterised by the type of prime driver, e.g. hot gas expander
    • F25J3/04133—Electrical motor as the prime mechanical driver
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04109—Arrangements of compressors and /or their drivers
    • F25J3/04145—Mechanically coupling of different compressors of the air fractionation process to the same driver(s)
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
    • F25J3/04527—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general
    • F25J3/04539—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the H2/CO synthesis by partial oxidation or oxygen consuming reforming processes of fuels
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
    • F25J3/04527—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general
    • F25J3/04539—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the H2/CO synthesis by partial oxidation or oxygen consuming reforming processes of fuels
    • F25J3/04545—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the H2/CO synthesis by partial oxidation or oxygen consuming reforming processes of fuels for the gasification of solid or heavy liquid fuels, e.g. integrated gasification combined cycle [IGCC]
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
    • F25J3/04527—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general
    • F25J3/04551—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the metal production
    • F25J3/04557—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the metal production for pig iron or steel making, e.g. blast furnace, Corex

Definitions

  • the invention concerns a process for air separation, wherein feed air is fed to an air separation unit, and a first process stream of the air separation is compressed in a first compressor.
  • Such first compressor is driven by the energy produced by work expansion of steam in a steam turbine, whereby such energy is transferred by mechanical coupling between such turbine and the main air compressor.
  • Air separation can be any type of physical separation process for producing at least one air gas, e.g., nitrogen and/or oxygen, from atmospheric air. Even though the invention is equally applicable to adsorption and membrane processes, it primarily refers to cryogenic processes separating air by distillative methods. Such cryogenic processes are known in general from the monograph “Tieftemperaturtechnik” of Hausen/Linde (2 nd ed., 1985) or from a paper of Latimer in Chemical Engineering Progress (vol. 63, no.2, 1967, p. 35), the disclosures of which are hereby incorporated by reference.
  • a “process stream of the air separation” can be formed by any of the following streams: feed air (total or portion) for the air separation, product of the air separation, recycle stream in the air separation. That means that the first compressor may be operated, e.g., as a main air compressor, booster air compressor, or product compressor. It comprises one or more stages with or without intercooling. If the first compressor is a multiple stage compressor, it may compress more than one process stream of the air separation.
  • Mechanical coupling can be realized as direct coupling by a common shaft or as indirect coupling by a gear box transmission.
  • the preferred field of application of the invention are air separators combined with Integrated Gasification Combined Cycle (IGCC) processes, Gas to Liquid (GTL), or other steam producing client processes, e.g. steel works.
  • IGCC Integrated Gasification Combined Cycle
  • GTL Gas to Liquid
  • client processes e.g. steel works.
  • Such processes require large amounts of oxygen for their operation, which are normally produced by cryogenic air separation.
  • One of the products of these processes is pressurized steam, which often is not or not completely used in the client process.
  • pressurized steam which often is not or not completely used in the client process.
  • the economics of these combined processes depends on the efficient use of the available steam.
  • the practice has been to use the steam for the air separation plant compressors.
  • the steam available from such processes often varies in its energy content, i.e. it is too low in pressure and/or temperature (low-grade steam) at least in some periods of operation.
  • the steam may not contain enough energy to drive the compressor at least in such
  • An object of the invention is, to provide a different concept, which reduces effort for apparatus and/or control, and/or is more flexible in adaptation to operating conditions.
  • an air separation process comprising feeding feed air into an air separation unit, and compressing a first process stream of the air separation unit in a first compressor ( 2 ) which is mechanically coupled ( 4 ) to a steam turbine ( 1 ) and to an electric motor ( 3 ).
  • the three machines, turbine driven by the external fluid, first compressor, frequently operated as main air compressor, and electric motor can be mounted on a common shaft or mechanically connected by other means, e.g., by one or more gear boxes. It is possible to couple just those three machines, or to include further machines into the mechanical coupling, e.g., a further compressor and/or a gas expander.
  • the mechanical energy provided by the externally driven turbine can be supplemented, at least in certain operating periods, by electric energy driving the electric motor.
  • the motor is then sized to match the power deficit appearing in some operation mode.
  • a single steam turbine drive and single condenser are used.
  • the size of the steam turbine may be up to the maximum available or up to the maximum the end user will accept from a technical risk.
  • a specific application of the invention are processes which produce relatively low steam pressures and temperatures (e.g. 15 bara-25 bara and 200° C.-350° C. in case of GTL). This would normally require the use of large mechanical drive turbines, which does. These turbines either do not exist or pose a technical risk. If a mechanical steam turbine drive large enough for the compressor does not exist (currently the largest referenced mechanical drive steam turbine is 57 MW the invention enables the difference in power required to be made up by the motor.
  • a further advantage of the invention can be used during start-up.
  • Starting compressors with a steam turbine requires rapid acceleration in order to pass quickly through resonant frequencies (critical speeds).
  • the electric motor drive is able to assist in starting and the acceleration is increased.
  • the machine train can be run up to speed with the motor power off. Once at full speed the motor is started. This gives the advantage of eliminating expensive starting equipment.
  • the motor is direct-on-line (DOL) started.
  • the air separation process comprises the compression of a second process stream of the air separation in a second compressor, frequently operated as booster compressor, in addition to the first compressor, frequently operated as main air compressor.
  • the second process stream can be constituted by a portion of the feed air downstream the main air compressor, which is further compressed in order to be used for evaporation of an internally compressed stream of a product.
  • it may be a product from the air separator (e.g., at least a part of the oxygen or nitrogen product produced in the air separation), which is to be compressed to a delivery pressure; in this case the booster compressor acts as a product compressor.
  • the second process stream may be constituted by a recycle stream of the air separation.
  • the second compressor can be driven as well by the turbine-motor combination.
  • the second compressor comprises one or more stages with or without intercooling. Normally, but not necessarily, the second compressor is smaller in capacity than the first compressor.
  • the steam turbine is directly coupled to one of the air separation plant compressors whilst the other air separation plant compressor is connected either directly to the other side of the steam turbine or via a step up/down gear or integrated compressor gear.
  • the additional power required by the train is supplied by the electric motor or, if surplus power is available, the motor/generator is operated as a generator.
  • the first and second compressors can be directly coupled. If the mechanical coupling between the second compressor and the first compressor is realized by a gear system, the gear is able to match for different speeds of the first compressor and the second compressor.
  • the invention also relates to an apparatus for air separation comprising a first compressor ( 2 ) and means for connecting the inlet or the outlet of the first compressor to an air separation unit, wherein the first compressor ( 2 ) is mechanically coupled to a steam turbine ( 1 ) and to an electric motor ( 3 ).
  • the invention also relates to an apparatus for compressing and expanding fluids comprising a first compressor ( 2 ), a steam turbine ( 1 ), a second compressor ( 5 ), and a electric motor ( 3 ), all being mechanically coupled ( 4 a, 4 b, 6 ).
  • This last apparatus can be used in any application, not only in connection with an air separation unit.
  • FIG. 1 shows a basic implementation of the invention
  • FIG. 2 is a more specific embodiment.
  • the external fluid to be work expanded is steam.
  • the machine train comprises a single steam turbine 1 , a single multiple stage main air compressor (“first compressor”) 2 and an electric motor 3 . All three machines are directly mechanically coupled by a common shaft 4 . In operation, they always run at the same speed. (Such direct coupling is always preferred, if the speeds of the machines match. Nevertheless, as an alternative, any of the couplings 4 can be realized by a gear box as well.)
  • the inlet of the main air compressor 2 is connected to a source for atmospheric air.
  • the air compressed in the main air compressor is purified, cooled and fed to a cryogenic air separation unit having at least one distillation column.
  • the air separation unit produces impure oxygen, which is delivered to an oxygen consuming process, which produces the steam to be expanded in turbine 1 .
  • a motor/generator is used as electric motor 3 . In this way, surplus steam power available during certain operation periods can be converted into electric energy.
  • FIG. 2 The embodiment of FIG. 2 is particularly suited for the case, where the air separation has more than one compression duty.
  • this machine train comprises a booster compressor (“second compressor”) 5 for compressing an oxygen or nitrogen stream produced in the air separation unit.
  • Two shafts 4 a, 4 b effect a direct mechanical coupling between main air compressor 2 and turbine 1 on the one hand, and booster compressor 5 and motor 3 on the other hand.
  • Those pairs of machines are connected by an indirect mechanical coupling effected by a gear-box 6 .
  • any of the couplings shown in the drawings may be direct (e.g. by a common shaft), or indirect (e.g. by a gear-box). Normally one tends to minimize or totally avoid gear-boxes in order to reduce investment costs.
  • the first compressor and/or the second compressor of the invention can be realized as one or two combined service machines, each performing more than one compression duty.
  • several stages of the first compressor may act as a main air compressor for feed air, whilst one or more other stages are operated as booster air compressor and/or product compressor.

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Manufacturing & Machinery (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Abstract

A first process stream of the air separation is compressed in a first compressor (2). The first compressor (2) is mechanically coupled (4) to a steam turbine (1) and to an electric motor (3).

Description

  • The invention concerns a process for air separation, wherein feed air is fed to an air separation unit, and a first process stream of the air separation is compressed in a first compressor. Such first compressor is driven by the energy produced by work expansion of steam in a steam turbine, whereby such energy is transferred by mechanical coupling between such turbine and the main air compressor. [0001]
  • “Air separation” can be any type of physical separation process for producing at least one air gas, e.g., nitrogen and/or oxygen, from atmospheric air. Even though the invention is equally applicable to adsorption and membrane processes, it primarily refers to cryogenic processes separating air by distillative methods. Such cryogenic processes are known in general from the monograph “Tieftemperaturtechnik” of Hausen/Linde (2[0002] nd ed., 1985) or from a paper of Latimer in Chemical Engineering Progress (vol. 63, no.2, 1967, p. 35), the disclosures of which are hereby incorporated by reference.
  • Simple air separation units are also described in [0003] Perry's Chemical Engineer's Handbook, 6th Edition (1984), at pages 12-53 and 12-54. For example, in the Linde Single-Column System for air separation, feed air is compressed in an air compressor and then cooled in a heat exchanger. In the heat exchanger, the compressed feed air is subjected to heat exchange with, for example, waste nitrogen and/or product oxygen gas. Thereafter, the compressed feed air is sent through a coil in the boiler of a rectification column wherein it is further cooled. The feed air is then expanded, whereby the air becomes mostly liquid, and introduced to the top of the rectification column. Nitrogen gas and gaseous or liquid oxygen product are removed from the rectification column. See FIG. 12-67 in Perry's. In the Linde Double-Column System for air separation (illustrated at FIG. 12-68 in Perry's), two rectification columns are placed on top of one another. The compressed feed air, after being subjected to heat exchange with nitrogen and oxygen gas streams, is sent through a coil in the boiler of the lower column ands then expanded and introduced at an intermediate location into the lower column. Nitrogen is removed from the top of the bottom column and delivered to the top of the upper column. In addition, oxygen rich-liquid from the bottom boiler of the lower column is introduced at an intermediate point into the upper column. Pure oxygen is then removed from the bottom of the upper column and pure nitrogen is removed from the top thereof.
  • A “process stream of the air separation” can be formed by any of the following streams: feed air (total or portion) for the air separation, product of the air separation, recycle stream in the air separation. That means that the first compressor may be operated, e.g., as a main air compressor, booster air compressor, or product compressor. It comprises one or more stages with or without intercooling. If the first compressor is a multiple stage compressor, it may compress more than one process stream of the air separation. [0004]
  • “Mechanical coupling” can be realized as direct coupling by a common shaft or as indirect coupling by a gear box transmission. [0005]
  • The preferred field of application of the invention are air separators combined with Integrated Gasification Combined Cycle (IGCC) processes, Gas to Liquid (GTL), or other steam producing client processes, e.g. steel works. Such processes require large amounts of oxygen for their operation, which are normally produced by cryogenic air separation. One of the products of these processes is pressurized steam, which often is not or not completely used in the client process. The economics of these combined processes depends on the efficient use of the available steam. The practice has been to use the steam for the air separation plant compressors. The steam available from such processes often varies in its energy content, i.e. it is too low in pressure and/or temperature (low-grade steam) at least in some periods of operation. The steam may not contain enough energy to drive the compressor at least in such periods. [0006]
  • A process of the kind described above is known from E. Schönpflug, Linde Reports on Science and Technology 23/1976, p. 55, the disclosure of which is hereby incorporated by reference. In this example, a steam turbine driven air compressor and an electrically driven air compressor are operated in parallel. This configuration overcomes the problem of missing steam power. It requires, however, huge apparatus and control effort. [0007]
    • SUMMARY OF THE INVENTION
  • An object of the invention is, to provide a different concept, which reduces effort for apparatus and/or control, and/or is more flexible in adaptation to operating conditions. [0008]
  • Upon further study of the specification and appended claims, further objects and advantages of this invention will become apparent to those skilled in the art. [0009]
  • These objects are achieved by an air separation process comprising feeding feed air into an air separation unit, and compressing a first process stream of the air separation unit in a first compressor ([0010] 2) which is mechanically coupled (4) to a steam turbine (1) and to an electric motor (3).
  • The three machines, turbine driven by the external fluid, first compressor, frequently operated as main air compressor, and electric motor can be mounted on a common shaft or mechanically connected by other means, e.g., by one or more gear boxes. It is possible to couple just those three machines, or to include further machines into the mechanical coupling, e.g., a further compressor and/or a gas expander. In the process of the invention, the mechanical energy provided by the externally driven turbine can be supplemented, at least in certain operating periods, by electric energy driving the electric motor. By this measure, a wide range of operating conditions, particularly concerning steam availability, can be covered, whereby in any case, the complete steam power available for compression requirements of the air separator can be used for such purpose. [0011]
  • If the amount of steam produced by the plants varies, the motor is then sized to match the power deficit appearing in some operation mode. [0012]
  • A single steam turbine drive and single condenser are used. The size of the steam turbine may be up to the maximum available or up to the maximum the end user will accept from a technical risk. A specific application of the invention are processes which produce relatively low steam pressures and temperatures (e.g. 15 bara-25 bara and 200° C.-350° C. in case of GTL). This would normally require the use of large mechanical drive turbines, which does. These turbines either do not exist or pose a technical risk. If a mechanical steam turbine drive large enough for the compressor does not exist (currently the largest referenced mechanical drive steam turbine is 57 MW the invention enables the difference in power required to be made up by the motor. [0013]
  • A further advantage of the invention can be used during start-up. Starting compressors with a steam turbine requires rapid acceleration in order to pass quickly through resonant frequencies (critical speeds). In the invention, the electric motor drive is able to assist in starting and the acceleration is increased. [0014]
  • Alternatively, if the electric motor is large compared with the electrical system network then the machine train can be run up to speed with the motor power off. Once at full speed the motor is started. This gives the advantage of eliminating expensive starting equipment. The motor is direct-on-line (DOL) started. [0015]
  • Even though the invention is quite advantageous for systems, where the steam power is too low for all operating conditions, so that always electric energy is supplied to the electric motor, additional flexibility can be gained by using a motor/generator as electric motor and operating it during some operating period as a generator. [0016]
  • In many cases, the air separation process comprises the compression of a second process stream of the air separation in a second compressor, frequently operated as booster compressor, in addition to the first compressor, frequently operated as main air compressor. The second process stream can be constituted by a portion of the feed air downstream the main air compressor, which is further compressed in order to be used for evaporation of an internally compressed stream of a product. Alternatively it may be a product from the air separator (e.g., at least a part of the oxygen or nitrogen product produced in the air separation), which is to be compressed to a delivery pressure; in this case the booster compressor acts as a product compressor. In another example, the second process stream may be constituted by a recycle stream of the air separation. According to a further aspect of the invention, the second compressor can be driven as well by the turbine-motor combination. [0017]
  • The second compressor comprises one or more stages with or without intercooling. Normally, but not necessarily, the second compressor is smaller in capacity than the first compressor. [0018]
  • The steam turbine is directly coupled to one of the air separation plant compressors whilst the other air separation plant compressor is connected either directly to the other side of the steam turbine or via a step up/down gear or integrated compressor gear. The additional power required by the train is supplied by the electric motor or, if surplus power is available, the motor/generator is operated as a generator. [0019]
  • In certain cases, the first and second compressors can be directly coupled. If the mechanical coupling between the second compressor and the first compressor is realized by a gear system, the gear is able to match for different speeds of the first compressor and the second compressor. [0020]
  • Furthermore, the invention also relates to an apparatus for air separation comprising a first compressor ([0021] 2) and means for connecting the inlet or the outlet of the first compressor to an air separation unit, wherein the first compressor (2) is mechanically coupled to a steam turbine (1) and to an electric motor (3).
  • The invention also relates to an apparatus for compressing and expanding fluids comprising a first compressor ([0022] 2), a steam turbine (1), a second compressor (5), and a electric motor (3), all being mechanically coupled (4 a, 4 b, 6). This last apparatus can be used in any application, not only in connection with an air separation unit.
    •  BRIEF DESCRIPTION OF THE DRAWINGS
  • Various other features and attendant advantages of the present invention will be more fully appreciated as the same becomes better understood when considered in conjunction with the accompanying drawings, in which like reference characters designate the same or similar parts throughout the several views, and wherein: [0023]
  • FIG. 1 shows a basic implementation of the invention; and [0024]
  • FIG. 2 is a more specific embodiment.[0025]
  • In the specific embodiment of FIG. 1, the external fluid to be work expanded is steam. The machine train comprises a [0026] single steam turbine 1, a single multiple stage main air compressor (“first compressor”) 2 and an electric motor 3. All three machines are directly mechanically coupled by a common shaft 4. In operation, they always run at the same speed. (Such direct coupling is always preferred, if the speeds of the machines match. Nevertheless, as an alternative, any of the couplings 4 can be realized by a gear box as well.)
  • In a particular example, the inlet of the [0027] main air compressor 2 is connected to a source for atmospheric air. The air compressed in the main air compressor is purified, cooled and fed to a cryogenic air separation unit having at least one distillation column. The air separation unit produces impure oxygen, which is delivered to an oxygen consuming process, which produces the steam to be expanded in turbine 1.
  • Alternatively, a motor/generator is used as [0028] electric motor 3. In this way, surplus steam power available during certain operation periods can be converted into electric energy.
  • The embodiment of FIG. 2 is particularly suited for the case, where the air separation has more than one compression duty. In addition to the [0029] steam turbine 1, the main air compressor 2 and a motor/generator 3, which are known from FIG. 1, this machine train comprises a booster compressor (“second compressor”) 5 for compressing an oxygen or nitrogen stream produced in the air separation unit. Two shafts 4 a, 4 b effect a direct mechanical coupling between main air compressor 2 and turbine 1 on the one hand, and booster compressor 5 and motor 3 on the other hand. Those pairs of machines are connected by an indirect mechanical coupling effected by a gear-box 6.
  • There are a lot of variations possible in the invention. For instance, depending on the particular circumstances of a specific plant, any of the couplings shown in the drawings may be direct (e.g. by a common shaft), or indirect (e.g. by a gear-box). Normally one tends to minimize or totally avoid gear-boxes in order to reduce investment costs. [0030]
  • In special cases, the first compressor and/or the second compressor of the invention can be realized as one or two combined service machines, each performing more than one compression duty. For example, several stages of the first compressor may act as a main air compressor for feed air, whilst one or more other stages are operated as booster air compressor and/or product compressor. [0031]
  • The entire disclosures of all applications, patents and publications, cited above and below, and of corresponding European Application No. 00122168.8, filed Oct. 12, 2000 are hereby incorporated by reference. [0032]
  • From the foregoing description, one skilled in the art can easily ascertain the essential characteristics of this invention and, without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions. [0033]

Claims (22)

1. In a process for air separation comprising feeding air in, wherein feed air is fed to an air separation unit, and compressing a first process stream of the air separation is compressed in a first compressor (2), the improvement wherein said first compressor isbeing mechanically coupled (4) to a steam turbine (1) driven by an external fluid and to an electric motor (3).
2. A process according to claim 1, wherein said first compressor is the main feed air compressor of said air separation unit.
3. A process according to claim 1, wherein said first compressor is a booster air compressor of said air separation unit.
4. A process according to claim 1, wherein said first compressor is a product gas compressor of said air separation unit.
5. A process according to claim 1, wherein said a first process stream is feed air for said air separation unit.
6. A process according to claim 1, wherein said a first process stream is a product gas of said air separation unit.
7. A process according to claim 1, wherein said a first process stream is a recycle gas of said air separation unit.
8. A process according to claim 1, wherein during at least a first operating period, electric energy is supplied to the motor.
9. A process according to claim 1, wherein the electric motor (3) is a motor/generator and wherein during at least a second operating period, electric energy is withdrawn from the motor/generator.
10. A process according to claim 2, wherein the electric motor (3) is a motor/generator and wherein during at least a second operating period, electric energy is withdrawn from the motor/generator.
11. A process according to claim 1, wherein a second process stream of the air separation is compressed in a second compressor (5) and the second compressor is mechanically coupled to the first compressor (2).
12. A process according to claim 11, wherein the mechanical coupling between the second compressor (5) and the first compressor (2) is realized by a gear system (6).
13. In an apparatus for air separation comprising a first compressor (2) and means for connecting the inlet or the outlet of the first compressor to an air separation unit, the improvement wherein the first compressor (2) is mechanically coupled to a steam turbine (1) for work expansion of a fluid and to an electric motor (3).
14. An apparatus according to claim 13, wherein the electric motor (3) is a motor/generator.
15. An apparatus according to claim 13, further comprising a second compressor (5) which is mechanically coupled to the first compressor (2).
16. An apparatus according to claim 14, further comprising a second compressor (5) which is mechanically coupled to the first compressor (2).
17. An apparatus according to claim 15, wherein the mechanical coupling between the second compressor (5) and the first compressor (2) is realized by a gear system (6).
18. An apparatus according to claim 16, wherein the mechanical coupling between the second compressor (5) and the first compressor (2) is realized by a gear system (6).
19. An apparatus for compressing and expanding fluids, comprising a first compressor (2), a steam turbine (1), a second compressor (5), and a electric motor (3), all being mechanically coupled (4 a, 4 b, 6).
20. An apparatus according to claim 19, wherein
the first compressor (2) and the turbine (1) are mechanically coupled by a common shaft (4 a),
the second compressor (5) and the electric motor (3) mechanically coupled by a common shaft (4 b), and
the compressor-turbine combination and the compressor-motor combination are mechanically coupled via a gear system (6).
21. Apparatus according to claim 19, whereby the electric motor (3) is a motor/generator.
22. Apparatus according to claim 20, whereby the electric motor (3) is a motor/generator.
US09/975,306 2000-10-12 2001-10-12 Process and apparatus for air separation Abandoned US20020116945A1 (en)

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US6581411B2 (en) * 2001-08-14 2003-06-24 L'air Liquide - Societe Anonyme A'directoire Et Conseil De Surveillance Pour L'etude Et L'explotation Des Procedes Georges Claude Plant for producing high pressure oxygen by air distillation
US20090100864A1 (en) * 2007-07-06 2009-04-23 Den Held Paul Anton Process to compress air and its use in an air separation process and systems using said processes
US20110005228A1 (en) * 2008-03-06 2011-01-13 Miura Co., Ltd Steam system
FR2949846A1 (en) * 2009-09-10 2011-03-11 Air Liquide PROCESS AND PLANT FOR PRODUCING OXYGEN BY AIR DISTILLATION
WO2011006862A3 (en) * 2009-07-13 2012-04-05 Alstom Technology Ltd System for gas processing
FR2967485A1 (en) * 2010-11-16 2012-05-18 Air Liquide Installation for purifying gaseous flow containing carbon dioxide, comprises a first unit to compress the gaseous flow, a heat exchanger to cool compressed gaseous flow, a distillation column to separate carbon dioxide, and separator pots
CN103306934A (en) * 2012-03-13 2013-09-18 固耐重工（苏州）有限公司 Carbon monoxide compressor
US9393515B2 (en) 2010-11-16 2016-07-19 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Method and appliance for purifying a flow rich in carbon dioxide

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FR2774159B1 (en) * 1998-01-23 2000-03-17 Air Liquide COMBINED INSTALLATION OF AN OVEN AND AN AIR DISTILLATION APPARATUS AND METHOD OF IMPLEMENTING IT
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US6581411B2 (en) * 2001-08-14 2003-06-24 L'air Liquide - Societe Anonyme A'directoire Et Conseil De Surveillance Pour L'etude Et L'explotation Des Procedes Georges Claude Plant for producing high pressure oxygen by air distillation
US20090100864A1 (en) * 2007-07-06 2009-04-23 Den Held Paul Anton Process to compress air and its use in an air separation process and systems using said processes
US20110005228A1 (en) * 2008-03-06 2011-01-13 Miura Co., Ltd Steam system
US8844290B2 (en) * 2008-03-06 2014-09-30 Miura Co., Ltd. Steam system
WO2011006862A3 (en) * 2009-07-13 2012-04-05 Alstom Technology Ltd System for gas processing
US20120167622A1 (en) * 2009-09-10 2012-07-05 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method and facility for producing oxygen through air distillation
CN102859303A (en) * 2009-09-10 2013-01-02 乔治洛德方法研究和开发液化空气有限公司 Method and facility for producing oxygen through air distillation
WO2011030050A3 (en) * 2009-09-10 2014-01-09 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Method and facility for producing oxygen through air distillation
FR2949846A1 (en) * 2009-09-10 2011-03-11 Air Liquide PROCESS AND PLANT FOR PRODUCING OXYGEN BY AIR DISTILLATION
AU2010294093B2 (en) * 2009-09-10 2015-01-15 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method and facility for producing oxygen through air distillation
FR2967485A1 (en) * 2010-11-16 2012-05-18 Air Liquide Installation for purifying gaseous flow containing carbon dioxide, comprises a first unit to compress the gaseous flow, a heat exchanger to cool compressed gaseous flow, a distillation column to separate carbon dioxide, and separator pots
US9393515B2 (en) 2010-11-16 2016-07-19 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Method and appliance for purifying a flow rich in carbon dioxide
CN103306934A (en) * 2012-03-13 2013-09-18 固耐重工（苏州）有限公司 Carbon monoxide compressor

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