US20020034985A1 - Golf club shaft with controllable feel and balance using combination of fiber-reinforced plastics and metal-coated fiber-reinforced plastics - Google Patents
Golf club shaft with controllable feel and balance using combination of fiber-reinforced plastics and metal-coated fiber-reinforced plastics Download PDFInfo
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- US20020034985A1 US20020034985A1 US09/994,553 US99455301A US2002034985A1 US 20020034985 A1 US20020034985 A1 US 20020034985A1 US 99455301 A US99455301 A US 99455301A US 2002034985 A1 US2002034985 A1 US 2002034985A1
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- metal
- golf club
- club shaft
- coated
- shaft
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- 239000002184 metal Substances 0.000 title claims abstract description 81
- 229920002430 Fibre-reinforced plastic Polymers 0.000 title abstract description 9
- 239000011151 fibre-reinforced plastic Substances 0.000 title abstract description 9
- 239000000835 fiber Substances 0.000 claims abstract description 75
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 26
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052802 copper Inorganic materials 0.000 claims abstract description 12
- 239000010949 copper Substances 0.000 claims abstract description 12
- 150000002739 metals Chemical class 0.000 claims abstract description 10
- 229910001369 Brass Inorganic materials 0.000 claims abstract description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000010951 brass Substances 0.000 claims abstract description 7
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 7
- 239000010941 cobalt Substances 0.000 claims abstract description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 7
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052737 gold Inorganic materials 0.000 claims abstract description 7
- 239000010931 gold Substances 0.000 claims abstract description 7
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- 239000004332 silver Substances 0.000 claims abstract description 7
- 239000010936 titanium Substances 0.000 claims abstract description 7
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 7
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 7
- 239000010937 tungsten Substances 0.000 claims abstract description 7
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 7
- 239000011701 zinc Substances 0.000 claims abstract description 7
- 239000002131 composite material Substances 0.000 claims description 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- 229910002804 graphite Inorganic materials 0.000 claims description 11
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- 229910052755 nonmetal Inorganic materials 0.000 claims description 4
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- 238000009730 filament winding Methods 0.000 description 13
- 238000005096 rolling process Methods 0.000 description 13
- 238000000034 method Methods 0.000 description 8
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- 238000005452 bending Methods 0.000 description 2
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Images
Classifications
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B60/00—Details or accessories of golf clubs, bats, rackets or the like
- A63B60/54—Details or accessories of golf clubs, bats, rackets or the like with means for damping vibrations
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B2209/00—Characteristics of used materials
- A63B2209/02—Characteristics of used materials with reinforcing fibres, e.g. carbon, polyamide fibres
- A63B2209/023—Long, oriented fibres, e.g. wound filaments, woven fabrics, mats
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B53/00—Golf clubs
- A63B53/10—Non-metallic shafts
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63B—APPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
- A63B60/00—Details or accessories of golf clubs, bats, rackets or the like
- A63B60/06—Handles
- A63B60/14—Coverings specially adapted for handles, e.g. sleeves or ribbons
Definitions
- the present invention relates generally to the field of golf club shafts.
- the present invention involves the use of metal coated fibers in forming composite golf club shafts to provide controllable feel and balance.
- a golfer's goal is to send the golf ball a greater distance, or, when fatigue or age are factors, to maintain a certain hitting distance.
- traditional golf club shafts are made from steel, there is a need for golf clubs which are lighter and specialized alternatives to steel in order to achieve these goals.
- Graphite shafts have reduced weight, greater flex and strength than steel, providing benefits such as vibration dampening on mis-hits, greater distance and reduced physical stress on the wrist, shoulder and elbow. Accordingly, graphite shafts are gaining in acceptance.
- graphite shafts have suffered from inconsistent manufacturing, higher costs, extra torque, a soft feel and higher breakage rates, particularly around the club head connection or hosel.
- Graphite golf clubs have been made from many different materials and recently have become available in different combinations of composites using fiber reinforced plastics and metals.
- Composite graphite shafts have normally been made by either a sheet-rolling method or a filament winding method.
- filament winding fibers are collected into groups called “tows” and each tow is impregnated with resin and wrapped around the mandrel to form the layers prior to curing. Filament winding generally results in an improved shaft with greater consistency in manufacture. The resulting shafts are substantially lighter than traditional metal shafts.
- a golf club including the shaft and head should be “tuned” or customized to a particular player in terms of weight, balance, torque, impact strength and flex.
- Composite shafts have been criticized, among other reasons, as difficult to tune for particular players. For example, sheet-wrapped shafts have been criticized as providing too much torque to the ball, while filament wound shafts have been criticized as having greater breakage rates.
- a shaft's weight, balance, impact strength and flex are interdependent so that attempting to adjust one characteristic frequently has undesired effects on other attributes. For example, including a sufficient number of carbon-fiber layers to achieve a desired weight can make the shaft too thick, effecting its stiffness and balance. It would be desirable to customize particular attributes of a shaft while maintaining the desirable characteristics of graphite composites and not negatively impacting other attributes of play.
- metals have been used in conjunction with composite shafts, but the combinations of materials and composites have not had the desired results.
- Use of metal reinforcement to date has consisted of using extruded tubing, amorphous metal tape wound as one or more layers of the shaft, or plating added to the outer layer of the shaft.
- These hybrid shafts, using combinations of fiber-reinforced plastics and metals, have yet to achieve widespread use due to higher material and production costs without significant performance improvement. While achieving one favorable effect, the weight, placement or design of the metals often effects other attributes undesirably.
- McIntosh suggests sheet-rolled hollow rods formed with non-coated sheet-rolled inner plies covered by one or two plies of sheet-rolled nickel-coated flags. McIntosh suggests that the fibers in the outer plies be oriented substantially parallel to the rod axis. McIntosh states that this will increase impact strength. McIntosh fails to address the concerns of weight, balance and torque. Although McIntosh mentions to golf clubs, McIntosh focuses on fishing rods and does not address many of the specific concerns encountered in manufacturing golf club shafts. Thus there remains a need for improved golf club shafts.
- a golf club shaft is formed with an elongated body using a combination of fiber-reinforced plastics and metal-coated fibers to assist in obtaining an optimally characterized golf club for a particular player.
- a sheet-rolled or filament wound core is covered by a filament wound outer layer having at least one ply including metal-coated fibers.
- the fibers can be coated with various metals such as nickel, titanium, platinum, zinc, copper, brass, tungsten, cobalt, gold or silver.
- metal-coated fibers allows the use of combinations of fiber reinforced plastic and metal-coated fibers in plies for producing golf shafts with optimum performance properties.
- the use of metal-coated fibers allows the addition of weight to the shaft without significantly influencing its longitudinal or torsional rigidity.
- Metal-coated fibers can be used to enhance the feel and sensitivity of the golf club shaft to suit the needs of a particular design or player.
- metal-coated carbon fibers are possible through filament winding to add weight to predetermined points in the shaft to shift the flex and balance points without varying the shaft's torsional properties and while still providing the optimum flex for a given golf club design.
- fibers coated with different metals can be used to form different portions of the shaft.
- FIG. 1 is an illustration of a golf club.
- FIGS. 2A and 2B are perspective views of steps in a sheet-rolling process.
- FIGS. 2C and 2D are view of sample flags used in the sheet-rolling process.
- FIG. 2E is a cross-sectional view of a shaft made with the sheet-rolling process.
- FIGS. 3A and 3B are perspective views of the process of filament winding used in one embodiment of the present invention.
- FIG. 4 is a perspective view of filament winding over sheet-rolling wrapping in one embodiment of the present invention.
- FIG. 5 is a longitudinal cut-away view of a shaft according to one embodiment of the present invention.
- FIG. 6 is a cross-sectional view of a shaft according to one embodiment of the present invention.
- FIG. 7 is an alternate preferred embodiment of a shaft according to the present invention.
- FIG. 8 is an alternate preferred embodiment of a shaft according to the present invention.
- FIG. 9 is an alternate preferred embodiment of a shaft according to the present invention.
- FIG. 10 is an alternate preferred embodiment of a shaft according to the present invention.
- FIGS. 11A, 11B, 11 C and 11 D are diagrammatic views of layers of a shaft made according to one embodiment of the present invention.
- the present invention provides an improved golf club shaft formed with an elongated body using a combination of fiber-reinforced plastics and metal-coated fibers to obtain an optimally characterized golf club for a particular player.
- a typical golf club made in accordance with the present invention is illustrated in FIG. 1, and includes shaft or body 10 with tip or hosel section 12 and butt or grip section 14 .
- FIGS. 2 A- 2 E A sheet-rolling process is illustrated in FIGS. 2 A- 2 E.
- flag or tapered sheet 22 having fibers at an angle, such as 45° is rolled around a mandrel 15 to form a first layer or ply.
- flag 22 ′ having fibers at the opposite angle to flag 22 is rolled around mandrel 15 and first sheet 22 , as shown in FIG. 2B.
- Additional plies such as 22 ′′ and 22 ′′′ in FIGS. 2C and 2D or more angled plies can then be rolled to form a sufficient number of layers to reach a desired thickness and weight.
- Short flags such as flag 22 ′′′
- a cross-section of a six ply shaft is illustrated in FIG. 2E included angled flags 22 and 22 ′, a longitudinal flag 22 ′′, a short flag 22 ′′′ and then a longitudinal flag 22 ′′ and a short flag 22 ′′′ again.
- the angle of the fibers in a ply can range from 0° to 90° from the longitudinal axis of the mandrel, although intermediate angles in sheet-rolled plies must be balanced with a ply having fibers angled in the opposite direction. Flags with longitudinal fibers (0°) have more effect on flex and bending strength, while fibers with higher angles have more effect on torque. Once a sufficient number of layers are applied, the shaft is cured and sanded for finishing. Shafts made with sheet-rolling alone are often criticized as mechanically inconsistent.
- Filament wrapping is a more exact process than sheet-rolling and involves precise equipment and control to create a desired shaft.
- one or more resin impregnated tows 24 are individually wound back and forth around the mandrel 15 at an angle to form a layer or ply.
- a tow consists of a number of individual fibers. Typical tows range from 2,000 to 80,000 fibers, such as 3K, 6K, 12K, 48K and 80K tows, with preferred tows having approximately 12,000 fibers.
- Filament winding is often computer controlled, allowing precise control of the winding process to change the winding angle between plies or during a ply, to adjust ply thickness and/or to select the placement of individual fibers. Filament winding also allows the introduction of different weave patterns, helping to control weight and flex. Filament winding results in a higher degree of mechanical consistency that sheet-rolling.
- One example of a hybrid composite illustrated in FIG. 4, has a core of several plies formed on mandrel 15 by sheet-rolling with flags such as flag 22 and an outer layer of several filament wound plies placed over the core using tows 24 .
- a hybrid composite having a core of sheet-wrapped layers and an outer layer of filament wound layers provides more combinations of attributes than sheet-rolling or filament winding alone.
- the present invention focuses on filament wound and hybrid composite shafts.
- golf shafts made in accordance with the present invention take advantage of the properties provided by metal-coated fibers.
- the fibers are typically made of carbon, glass or other known materials, and are made individually in filament form, or held in a parallel resin matrix to create a sheet or prepreg form, depending on the desired result.
- all or a portion of the fibers in the parallel matrix may be metal coated.
- coating metals which may be used on fibers include: nickel, titanium, platinum, zinc, copper, brass, tungsten, cobalt, gold and silver.
- various metals, such as copper and nickel have varying attributes and are used in different proportions to provide different degrees of weight, strength, and vibration absorption.
- the metal coating may be vapor deposited on the fibers; alternately the metal coating may be electroplated onto the fibers.
- the metal coating may bond to the fibers or form sheaths around them.
- the metallic coating may have a thickness between 400 Angstroms and 2.5 microns depending on the desired weight and appearance.
- Composite Materials L.L.C. of Mamaroneck, N.Y. sells certain of these coated fibers under the trade name Compmat.
- Certain other metal-coated fibers can be obtained from Inco Specialty Powder Products.
- the percentage of metal by weight may range from 0-99%, a preferred range for metal is 10-60% by weight, with a more preferred range being 40-45% by weight in flags for sheet-rolling and 20-26% by weight in tows for filament winding.
- a composite body 10 is made from a number of layers sheet-rolled or filament wound or a combination thereof to form core 20 , and a number of plies filament wound over core 20 to form outer layer 25 . Typically there are about 4-10 plies in a composite body 10 .
- the shaft includes metal coated fibers in core 20 and outer layer 25 .
- a limited number such as one to three of the plies in outer layer 25 may include tows with metal-coated fibers.
- additional weight is added uniformly, changing the feel, but not having a substantial effect on other properties such as flex, torque, bending or impact strength.
- FIGS. 11 A- 11 D show diagrammatic views of the plies used in one embodiment 100 of the present invention.
- Non-metal-coated tows are filament wound at 45° to form first ply 110 .
- First ply 110 is covered with second ply 112 of non-metal-coated tows filament wound at an angle of 10°.
- a longitudinal or 0° flag 114 is then sheet-rolled around second ply 112 .
- a top or outer ply 116 of metal-coated tows is filament wound over flag 114 at an angle between 5° and 25°.
- the shaft is then finished by curing, sanding and painting.
- metal-coated fibers can be filament wound non-uniformly to be added to specific, desired portions of the shaft.
- metal-coated fibers can be added to the lower portion of the shaft near hosel section 12 , up to approximately one-third of the shaft, lowering the balance and flex point of the shaft, and increasing the weight and strength at the hosel connection.
- metal-coated fibers can be added near grip section 14 of the shaft, up to approximately one-third of the shaft, to raise the balance, flex points and weight.
- the same or different metal coated fibers are added to only particular portions of the shaft.
- fibers coated with a first metal 26 are applied to grip section 14 while fibers coated with a second metal 24 are applied to hosel section 12 to adjust the weight, flex points, torque, and strength and to provide a unique look.
- copper coated fibers are added to hosel section 12 while nickel coated fibers are added to grip section 14 .
- the particular vibration, feel, torque, flex and overall weight of a club can be tuned by varying the percentage and thickness of the metal fibers in each layer. Additionally, the precise control in the filament winding process assists in customizing a shaft to an individual golfer's preference or needs by concentrating or reducing the metal-coated fiber percentage in specific areas to add weight to predetermined points on the shaft, tuning the balance point.
- shafts may be manufactured to form a shaft 10 ′ with two flex points 50 and 52 , illustrated in FIG. 10, such as in U.S. Pat. No. 5,496,028 issued Mar. 5, 1996 to Chien, hereby incorporated by reference.
- a diamond weave is used with the filament winding to add a diamond appearance to the shaft.
- a scrim layer may optionally be placed as an outer mask on a shaft and may be clear or include a design.
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Abstract
A golf club shaft is formed with an elongated body using a combination of fiber-reinforced plastics and metal-coated fibers to obtain the optimally characterized golf club for a particular player. In one embodiment, a sheet-rolled or filament wound core is covered by a filament wound outer layer having at least one ply including metal-coated fibers. The fibers can be metal-coated with metals such as: nickel, titanium, platinum, zinc, copper, brass, tungsten, cobalt, gold or silver. The use of metal-coated fibers allows the use of combinations of fiber reinforced plastic and metal-coated fibers in producing golf shafts with optimum performance properties. For example, the use of metal-coated fibers allows the addition of weight to the shaft without significantly influencing its longitudinal or torsional rigidity. In alternate embodiments, specific placement of the metal-coated fibers is possible to add weight to predetermined points in the shaft to shift the flex and balance points without varying the shaft's torsional properties and while providing the optimum flex for a given golf club design. In a still further example, two or more types of metal-coated fibers can be used at different portions on the shaft.
Description
- This application claims priority to provisional application serial No. 60/090,743 filed Jun. 24, 1998 and provisional application serial No. 60/118,886 filed Feb. 5, 1999.
- The present invention relates generally to the field of golf club shafts. In particular, the present invention involves the use of metal coated fibers in forming composite golf club shafts to provide controllable feel and balance.
- Frequently a golfer's goal is to send the golf ball a greater distance, or, when fatigue or age are factors, to maintain a certain hitting distance. Although traditional golf club shafts are made from steel, there is a need for golf clubs which are lighter and specialized alternatives to steel in order to achieve these goals. Graphite shafts have reduced weight, greater flex and strength than steel, providing benefits such as vibration dampening on mis-hits, greater distance and reduced physical stress on the wrist, shoulder and elbow. Accordingly, graphite shafts are gaining in acceptance. Traditionally however, graphite shafts have suffered from inconsistent manufacturing, higher costs, extra torque, a soft feel and higher breakage rates, particularly around the club head connection or hosel.
- Graphite golf clubs have been made from many different materials and recently have become available in different combinations of composites using fiber reinforced plastics and metals. Composite graphite shafts have normally been made by either a sheet-rolling method or a filament winding method.
- In the sheet-rolling or sheet-wrapping method, carbon, glass or other fibers are impregnated with a plastic resin and placed in a parallel matrix to form a broad sheet or prepreg. The prepreg is then cut into smaller sheets similar to a tapered flag shape with all of the fibers at a particular angle to the axis of the intended mandrel, the angle can be between 0° and 90°. These flags are then rolled around a mandrel to form various layers or plies. The layers are then cured to form a composite and the mandrel is removed.
- In the filament winding method, fibers are collected into groups called “tows” and each tow is impregnated with resin and wrapped around the mandrel to form the layers prior to curing. Filament winding generally results in an improved shaft with greater consistency in manufacture. The resulting shafts are substantially lighter than traditional metal shafts.
- Preferably a golf club including the shaft and head should be “tuned” or customized to a particular player in terms of weight, balance, torque, impact strength and flex. Composite shafts have been criticized, among other reasons, as difficult to tune for particular players. For example, sheet-wrapped shafts have been criticized as providing too much torque to the ball, while filament wound shafts have been criticized as having greater breakage rates.
- Moreover, a shaft's weight, balance, impact strength and flex are interdependent so that attempting to adjust one characteristic frequently has undesired effects on other attributes. For example, including a sufficient number of carbon-fiber layers to achieve a desired weight can make the shaft too thick, effecting its stiffness and balance. It would be desirable to customize particular attributes of a shaft while maintaining the desirable characteristics of graphite composites and not negatively impacting other attributes of play.
- As some attempts to solve these problems, metals have been used in conjunction with composite shafts, but the combinations of materials and composites have not had the desired results. Use of metal reinforcement to date has consisted of using extruded tubing, amorphous metal tape wound as one or more layers of the shaft, or plating added to the outer layer of the shaft. These hybrid shafts, using combinations of fiber-reinforced plastics and metals, have yet to achieve widespread use due to higher material and production costs without significant performance improvement. While achieving one favorable effect, the weight, placement or design of the metals often effects other attributes undesirably.
- One example of such an attempt is illustrated in U.S. Pat. No. 5,601,892 issued to McIntosh. McIntosh suggests sheet-rolled hollow rods formed with non-coated sheet-rolled inner plies covered by one or two plies of sheet-rolled nickel-coated flags. McIntosh suggests that the fibers in the outer plies be oriented substantially parallel to the rod axis. McIntosh states that this will increase impact strength. McIntosh fails to address the concerns of weight, balance and torque. Although McIntosh mentions to golf clubs, McIntosh focuses on fishing rods and does not address many of the specific concerns encountered in manufacturing golf club shafts. Thus there remains a need for improved golf club shafts.
- The prior art does not allow for the easy placement of weight or altered weight designs within the golf shaft without significantly affecting other shaft performance attributes. While sometimes desirable, this is most often not the case.
- A golf club shaft is formed with an elongated body using a combination of fiber-reinforced plastics and metal-coated fibers to assist in obtaining an optimally characterized golf club for a particular player. Preferably a sheet-rolled or filament wound core is covered by a filament wound outer layer having at least one ply including metal-coated fibers. The fibers can be coated with various metals such as nickel, titanium, platinum, zinc, copper, brass, tungsten, cobalt, gold or silver.
- The use of metal-coated fibers allows the use of combinations of fiber reinforced plastic and metal-coated fibers in plies for producing golf shafts with optimum performance properties. For example, the use of metal-coated fibers allows the addition of weight to the shaft without significantly influencing its longitudinal or torsional rigidity. There has been a widespread, unsolved demand for this type of product. Metal-coated fibers can be used to enhance the feel and sensitivity of the golf club shaft to suit the needs of a particular design or player.
- In alternate embodiments, specific placement of the metal-coated carbon fibers is possible through filament winding to add weight to predetermined points in the shaft to shift the flex and balance points without varying the shaft's torsional properties and while still providing the optimum flex for a given golf club design. In still further embodiments, fibers coated with different metals can be used to form different portions of the shaft.
- It is an object of the invention to provide an improved golf club shaft.
- It is another object of the invention to provide a golf club shaft which includes metal-coated fibers.
- It is a further object of a preferred embodiment of the present invention to provide a composite graphite golf shaft used in forming a golf club which may be tuned for a particular player.
- Further objects, features and advantages of the present invention shall become apparent from the detailed drawings and descriptions provided herein.
- FIG. 1 is an illustration of a golf club.
- FIGS. 2A and 2B are perspective views of steps in a sheet-rolling process.
- FIGS. 2C and 2D are view of sample flags used in the sheet-rolling process.
- FIG. 2E is a cross-sectional view of a shaft made with the sheet-rolling process.
- FIGS. 3A and 3B are perspective views of the process of filament winding used in one embodiment of the present invention.
- FIG. 4 is a perspective view of filament winding over sheet-rolling wrapping in one embodiment of the present invention.
- FIG. 5 is a longitudinal cut-away view of a shaft according to one embodiment of the present invention.
- FIG. 6 is a cross-sectional view of a shaft according to one embodiment of the present invention.
- FIG. 7 is an alternate preferred embodiment of a shaft according to the present invention.
- FIG. 8 is an alternate preferred embodiment of a shaft according to the present invention.
- FIG. 9 is an alternate preferred embodiment of a shaft according to the present invention.
- FIG. 10 is an alternate preferred embodiment of a shaft according to the present invention.
- FIGS. 11A, 11B,11C and 11D are diagrammatic views of layers of a shaft made according to one embodiment of the present invention.
- For the purposes of promoting an understanding of the principles of the invention, reference will now be made to the embodiments illustrated and specific language will be used to describe the same. It will nevertheless be understood that no limitation of the scope of the invention is thereby intended, such alterations, modifications, and further applications of the principles of the invention being contemplated as would normally occur to one skilled in the art to which the invention relates.
- The present invention provides an improved golf club shaft formed with an elongated body using a combination of fiber-reinforced plastics and metal-coated fibers to obtain an optimally characterized golf club for a particular player. A typical golf club made in accordance with the present invention is illustrated in FIG. 1, and includes shaft or
body 10 with tip orhosel section 12 and butt orgrip section 14. - A sheet-rolling process is illustrated in FIGS.2A-2E. In FIG. 2A flag or tapered
sheet 22 having fibers at an angle, such as 45°, is rolled around amandrel 15 to form a first layer or ply. Next,flag 22′ having fibers at the opposite angle toflag 22 is rolled aroundmandrel 15 andfirst sheet 22, as shown in FIG. 2B. Additional plies such as 22″ and 22′″ in FIGS. 2C and 2D or more angled plies can then be rolled to form a sufficient number of layers to reach a desired thickness and weight. Short flags, such asflag 22′″, are sometimes applied to the tip section for reinforcement and/or to provide an oversized finished section which may be sanded. A cross-section of a six ply shaft is illustrated in FIG. 2E includedangled flags longitudinal flag 22″, ashort flag 22′″ and then alongitudinal flag 22″ and ashort flag 22′″ again. - The angle of the fibers in a ply can range from 0° to 90° from the longitudinal axis of the mandrel, although intermediate angles in sheet-rolled plies must be balanced with a ply having fibers angled in the opposite direction. Flags with longitudinal fibers (0°) have more effect on flex and bending strength, while fibers with higher angles have more effect on torque. Once a sufficient number of layers are applied, the shaft is cured and sanded for finishing. Shafts made with sheet-rolling alone are often criticized as mechanically inconsistent.
- Filament wrapping, as illustrated in FIGS. 3A and 3B, is a more exact process than sheet-rolling and involves precise equipment and control to create a desired shaft. Instead of using a
sheet 22, one or more resin impregnatedtows 24 are individually wound back and forth around themandrel 15 at an angle to form a layer or ply. A tow consists of a number of individual fibers. Typical tows range from 2,000 to 80,000 fibers, such as 3K, 6K, 12K, 48K and 80K tows, with preferred tows having approximately 12,000 fibers. - After a tow is wound one direction on a shaft, the angle of winding is reversed so that a particular layer or ply may have windings at opposite angles. Normally a number of plies form a core with additional filament wound plies forming the outer layer. Filament winding is often computer controlled, allowing precise control of the winding process to change the winding angle between plies or during a ply, to adjust ply thickness and/or to select the placement of individual fibers. Filament winding also allows the introduction of different weave patterns, helping to control weight and flex. Filament winding results in a higher degree of mechanical consistency that sheet-rolling.
- One example of a hybrid composite, illustrated in FIG. 4, has a core of several plies formed on
mandrel 15 by sheet-rolling with flags such asflag 22 and an outer layer of several filament wound plies placed over thecore using tows 24. A hybrid composite having a core of sheet-wrapped layers and an outer layer of filament wound layers provides more combinations of attributes than sheet-rolling or filament winding alone. The present invention focuses on filament wound and hybrid composite shafts. - In addition to filament wound and hybrid composite construction, golf shafts made in accordance with the present invention take advantage of the properties provided by metal-coated fibers. The fibers are typically made of carbon, glass or other known materials, and are made individually in filament form, or held in a parallel resin matrix to create a sheet or prepreg form, depending on the desired result. In the prepreg form, all or a portion of the fibers in the parallel matrix may be metal coated. Examples of coating metals which may be used on fibers include: nickel, titanium, platinum, zinc, copper, brass, tungsten, cobalt, gold and silver. In addition to different visual effects, various metals, such as copper and nickel, have varying attributes and are used in different proportions to provide different degrees of weight, strength, and vibration absorption.
- The metal coating may be vapor deposited on the fibers; alternately the metal coating may be electroplated onto the fibers. The metal coating may bond to the fibers or form sheaths around them. By way of illustration, the metallic coating may have a thickness between 400 Angstroms and 2.5 microns depending on the desired weight and appearance. Composite Materials L.L.C. of Mamaroneck, N.Y. sells certain of these coated fibers under the trade name Compmat. Certain other metal-coated fibers can be obtained from Inco Specialty Powder Products. Although the percentage of metal by weight may range from 0-99%, a preferred range for metal is 10-60% by weight, with a more preferred range being 40-45% by weight in flags for sheet-rolling and 20-26% by weight in tows for filament winding.
- As illustrated in FIGS. 5 and 6, embodiments of the invention include
core 20 covered byouter layer 25. In one embodiment, acomposite body 10 is made from a number of layers sheet-rolled or filament wound or a combination thereof to formcore 20, and a number of plies filament wound overcore 20 to formouter layer 25. Typically there are about 4-10 plies in acomposite body 10. - In one embodiment, the shaft includes metal coated fibers in
core 20 andouter layer 25. As an alternate to having metal-coated fibers in the core and outer layer, a limited number such as one to three of the plies inouter layer 25 may include tows with metal-coated fibers. When each metal-coated tow is added uniformly to the final shaft, additional weight is added uniformly, changing the feel, but not having a substantial effect on other properties such as flex, torque, bending or impact strength. - By way of further illustration, FIGS.11A-11D show diagrammatic views of the plies used in one
embodiment 100 of the present invention. Non-metal-coated tows are filament wound at 45° to formfirst ply 110. First ply 110 is covered withsecond ply 112 of non-metal-coated tows filament wound at an angle of 10°. A longitudinal or 0°flag 114 is then sheet-rolled aroundsecond ply 112. A top orouter ply 116 of metal-coated tows is filament wound overflag 114 at an angle between 5° and 25°. The shaft is then finished by curing, sanding and painting. - In alternate embodiments, illustrated in FIGS. 7 and 8, metal-coated fibers can be filament wound non-uniformly to be added to specific, desired portions of the shaft. For example, metal-coated fibers can be added to the lower portion of the shaft near
hosel section 12, up to approximately one-third of the shaft, lowering the balance and flex point of the shaft, and increasing the weight and strength at the hosel connection. Conversely, metal-coated fibers can be added neargrip section 14 of the shaft, up to approximately one-third of the shaft, to raise the balance, flex points and weight. - In further embodiments, with one example illustrated in FIG. 9, the same or different metal coated fibers are added to only particular portions of the shaft. For example, fibers coated with a
first metal 26 are applied togrip section 14 while fibers coated with asecond metal 24 are applied tohosel section 12 to adjust the weight, flex points, torque, and strength and to provide a unique look. In one example, copper coated fibers are added tohosel section 12 while nickel coated fibers are added togrip section 14. - The particular vibration, feel, torque, flex and overall weight of a club can be tuned by varying the percentage and thickness of the metal fibers in each layer. Additionally, the precise control in the filament winding process assists in customizing a shaft to an individual golfer's preference or needs by concentrating or reducing the metal-coated fiber percentage in specific areas to add weight to predetermined points on the shaft, tuning the balance point.
- The metal also absorbs part of the impact force during use to reduce shock transmitted to the user and to minimize stress and cracking in the shaft. In another embodiment, shafts may be manufactured to form a
shaft 10′ with twoflex points - In some embodiments, a diamond weave is used with the filament winding to add a diamond appearance to the shaft. As a decorative and protective feature to assist with finishing, a scrim layer may optionally be placed as an outer mask on a shaft and may be clear or include a design.
- While the invention has been illustrated and described in detail in the drawings and foregoing description, the same is to be considered as illustrative and not restrictive in character, it being understood that only the preferred embodiment has been shown and described and that all changes and modifications that come within the spirit of the invention are desired to be protected.
Claims (27)
1. A composite golf club shaft formed from a body having multiple fiber reinforced graphite plies, comprising:
a) a core formed of one or more filament wound or sheet-rolled fiber reinforced graphite plies;
b) at least one sheet-rolled fiber reinforced ply rolled around said core;
c) an outer layer formed around said sheet-rolled ply around said core including at least one filament wound ply having metal-coated fibers.
2. The composite golf club shaft of claim 1 wherein said metal-coated fibers in said at least one filament wound ply in said outer layer are coated with a metal chosen from the group consisting of: nickel, titanium, platinum, zinc, copper, brass, tungsten, cobalt, gold and silver.
3. The composite golf club shaft of claim 2 wherein said metal-coated fibers in said at least one filament wound ply in said outer layer are coated with nickel.
4. The composite golf club shaft of claim 2 wherein said metal-coated fibers in said at least one filament wound ply in said outer layer are coated with copper.
5. The composite golf club shaft of claim 2 wherein said core is formed of non-metal-coated fiber plies.
6. The composite golf club shaft of claim 5 wherein said at least one sheet-rolled ply rolled around said core is formed of non-metal-coated fibers.
7. The composite golf club shaft of claim 6 wherein said at least one metal-coated filament wound ply in said outer layer has a metal content between about ten percent and about sixty percent by weight.
8. The composite golf club shaft of claim 7 wherein said at least one metal-coated filament wound ply in said outer layer has a metal content between about twenty percent and about twenty-six percent by weight.
9. The composite golf club shaft of claim 8 wherein said at least one metal-coated filament wound ply in said outer layer is wound at an angle between about five degrees and about twenty-five degrees from the longitudinal axis of the body.
10. A composite golf club shaft formed from a body having multiple fiber reinforced graphite plies, comprising:
a) a core formed of one or more filament wound or sheet-rolled fiber reinforced plies; and
b) an outer layer formed around said core including at least one filament wound ply having metal-coated fibers;
c) wherein said at least one filament wound ply with metal-coated fibers is wound to uniformly add a predetermined amount of weight to said shaft.
11. The golf club shaft of claim 10 wherein said metal is chosen from the group consisting of: nickel, titanium, platinum, zinc, copper, brass, tungsten, cobalt, gold and silver.
12. The golf club shaft of claim 11 wherein at least one ply in said core includes metal coated fibers.
13. The golf club shaft of claim 12 wherein said at least one metal-coated filament wound ply in said outer layer is wound in a diamond pattern.
14. The golf club shaft of claim 11 wherein said metal is vapor deposited on said fiber.
15. The golf club shaft of claim 11 wherein said metal is plated onto said fiber.
16. The golf club shaft of claim 11 wherein said metal is nickel.
17. The golf club shaft of claim 11 wherein said metal is copper.
18. A composite golf club shaft having a grip portion and a hosel portion and formed from multiple fiber reinforced graphite plies, comprising:
a) a core formed of one or more filament wound or sheet-wrapped fiber plies; and,
b) an outer layer formed around said core including at least one metal-coated filament wound ply;
c) wherein said at least one metal-coated filament wound ply in said outer layer is wound to non-uniformly concentrate a predetermined amount of weight in a predetermined location on said shaft.
19. The golf club shaft of claim 18 wherein said metal is chosen from the group consisting of: nickel, titanium, platinum, zinc, copper, brass, tungsten, cobalt, gold and silver.
20. The golf club shaft of claim 19 wherein said predetermined amount of weight is concentrated in the grip portion of said shaft.
21. The golf club shaft of claim 19 wherein said predetermined amount of weight is concentrated in the hosel portion of said shaft.
22. A composite golf club shaft having a grip portion and a hosel portion and formed from multiple fiber reinforced graphite plies, comprising:
a) a core formed of one or more filament wound or sheet-wrapped fiber plies; and,
b) an outer layer around said core, said outer layer including
i) a first filament wound portion including filaments coated with a first metal and wound to concentrate a first predetermined amount of weight in a first location on said shaft; and,
ii) a second filament wound portion including filaments coated with a second metal and wound to concentrate a second predetermined amount of weight in a second location on said shaft;
c) wherein said first metal is different from said second metal.
23. The golf club shaft of claim 22 wherein said first and second metals are chosen from the group consisting of: nickel, titanium, platinum, zinc, copper, brass, tungsten, cobalt, gold and silver.
24. The golf club shaft of claim 23 wherein said first metal is nickel.
25. The golf club shaft of claim 24 wherein said second metal is copper.
26. The golf club shaft of claim 25 wherein said first location is said grip portion.
27. The golf club shaft of claim 26 wherein said second location is said hosel portion.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/994,553 US20020034985A1 (en) | 1998-06-24 | 2001-11-27 | Golf club shaft with controllable feel and balance using combination of fiber-reinforced plastics and metal-coated fiber-reinforced plastics |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US9074398P | 1998-06-24 | 1998-06-24 | |
US11888699P | 1999-02-05 | 1999-02-05 | |
US09/337,356 US6354960B1 (en) | 1998-06-24 | 1999-06-21 | Golf club shaft with controllable feel and balance using combination of fiber reinforced plastics and metal-coated fiber-reinforced plastics |
US09/994,553 US20020034985A1 (en) | 1998-06-24 | 2001-11-27 | Golf club shaft with controllable feel and balance using combination of fiber-reinforced plastics and metal-coated fiber-reinforced plastics |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/337,356 Continuation US6354960B1 (en) | 1998-06-24 | 1999-06-21 | Golf club shaft with controllable feel and balance using combination of fiber reinforced plastics and metal-coated fiber-reinforced plastics |
Publications (1)
Publication Number | Publication Date |
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US20020034985A1 true US20020034985A1 (en) | 2002-03-21 |
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Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
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US09/337,356 Expired - Fee Related US6354960B1 (en) | 1998-06-24 | 1999-06-21 | Golf club shaft with controllable feel and balance using combination of fiber reinforced plastics and metal-coated fiber-reinforced plastics |
US09/994,553 Abandoned US20020034985A1 (en) | 1998-06-24 | 2001-11-27 | Golf club shaft with controllable feel and balance using combination of fiber-reinforced plastics and metal-coated fiber-reinforced plastics |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
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US09/337,356 Expired - Fee Related US6354960B1 (en) | 1998-06-24 | 1999-06-21 | Golf club shaft with controllable feel and balance using combination of fiber reinforced plastics and metal-coated fiber-reinforced plastics |
Country Status (3)
Country | Link |
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US (2) | US6354960B1 (en) |
AU (1) | AU4836699A (en) |
WO (1) | WO1999066991A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060135282A1 (en) * | 2004-12-17 | 2006-06-22 | Integran Technologies, Inc. | Article comprising a fine-grained metallic material and a polymeric material |
US7771289B2 (en) | 2004-12-17 | 2010-08-10 | Integran Technologies, Inc. | Sports articles formed using nanostructured materials |
CN113041583A (en) * | 2019-12-27 | 2021-06-29 | 古洛布莱株式会社 | Golf club shaft and golf club provided with same |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6860821B2 (en) * | 2000-12-25 | 2005-03-01 | Maimiya-Op Co., Ltd. | Golf shaft, forming method therefor and golf club |
US6955619B1 (en) * | 2004-03-29 | 2005-10-18 | Schutz Ronald W | Titanium hockey stick |
DE102004030158B4 (en) * | 2004-06-22 | 2017-04-06 | Andreas Stihl Ag & Co. Kg | Handle of a hand-held implement |
US20060005358A1 (en) * | 2004-06-22 | 2006-01-12 | Andreas Stihl Ag & Co. Kg | Handle for a Handheld Working Tool |
US7479069B2 (en) * | 2004-11-24 | 2009-01-20 | Michael H. L. Cheng | Insert for altering the stiffness of a golf club shaft |
US7815160B2 (en) * | 2006-04-04 | 2010-10-19 | A & P Technology | Composite mandrel |
US7500921B2 (en) | 2006-04-13 | 2009-03-10 | Cheng Michael H L | Golf club shaft insert assembly |
US7494423B2 (en) * | 2007-01-25 | 2009-02-24 | Cheng Michael H L | Golf club shaft insert assemblies, insert assembly systems and apparatus for use with same |
US7614963B2 (en) * | 2007-01-25 | 2009-11-10 | Cheng Michael H L | Golf club shaft insert assemblies, insert assembly systems and apparatus for use with same |
US20140094331A1 (en) * | 2012-09-24 | 2014-04-03 | George C. Hansen | Carbon fiber athletic equipment |
US9566486B2 (en) * | 2014-04-11 | 2017-02-14 | True Temper Sports, Inc. | Golf shaft and method of manufacturing same |
USD837320S1 (en) | 2016-12-07 | 2019-01-01 | True Temper Sports, Inc. | Golf club shaft |
JP7397088B2 (en) * | 2019-02-07 | 2023-12-12 | トゥルー テンパー スポーツ インコーポレイテッド | Sports equipment with cutouts in the outer layer of composite material |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030050210A1 (en) * | 2000-04-28 | 2003-03-13 | The Procter & Gamble Company | Pouched compositions |
US20030050209A1 (en) * | 2000-04-28 | 2003-03-13 | The Procter & Gamble Company | Pouched compositions |
US6878679B2 (en) * | 2000-04-28 | 2005-04-12 | The Procter & Gamble Company | Pouched compositions |
US6881713B2 (en) * | 2000-04-28 | 2005-04-19 | The Procter & Gamble Company | Pouched compositions |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52156173U (en) | 1976-05-19 | 1977-11-26 | ||
JPS52143125A (en) * | 1976-05-20 | 1977-11-29 | Avco Corp | Builttup composite shaft for golf club |
US4942090A (en) | 1982-03-16 | 1990-07-17 | American Cyanamid | Chaff comprising metal coated fibers |
US5026872A (en) | 1984-02-01 | 1991-06-25 | American Cyanamid | Aromatic ether-ketone polyamines, intermediates and products, and methods for preparing same |
US4889575A (en) * | 1986-06-06 | 1989-12-26 | Fiber-Speed International, Inc. | Method of manufacturing golf club shafts |
US5188152A (en) | 1987-02-05 | 1993-02-23 | Ryobi Ltd. | Tubular structures for fishing rods or the like |
US4836545A (en) * | 1988-11-07 | 1989-06-06 | Pompa J Benedict | Two piece metallic and composite golf shaft |
CA2026113C (en) | 1989-01-25 | 1998-12-01 | Tsunoe Igarashi | Prepreg, composite molded body, and method of manufacture of the composite molded body |
US5242720A (en) | 1990-04-11 | 1993-09-07 | Wasatch Fiber Group, Inc. | Cohesive finishes for composite materials |
JPH04224730A (en) | 1990-12-27 | 1992-08-14 | Kowa Co | Ophthalmological apparatus |
US5156396A (en) | 1991-08-26 | 1992-10-20 | Somar Corporation | Golf club shaft |
DE69219552T2 (en) | 1991-10-23 | 1997-12-18 | Inco Ltd | Nickel-coated carbon preform |
JP2545013B2 (en) * | 1992-06-10 | 1996-10-16 | 住友ゴム工業株式会社 | Golf club shaft |
US5496028A (en) | 1995-01-30 | 1996-03-05 | Rapport Composite Co. Ltd. | Golf club shaft with two flex points |
CA2224313A1 (en) * | 1995-06-14 | 1997-01-03 | Berkley Inc. | Golf shaft with bulge section |
US5601892A (en) * | 1995-07-19 | 1997-02-11 | Abu Ab | Hollow rods with nickel coated graphite fibers |
EP0816123B1 (en) * | 1996-06-27 | 2009-02-18 | Daiwa Seiko Inc. | Member for fishing or sport tool |
-
1999
- 1999-06-21 US US09/337,356 patent/US6354960B1/en not_active Expired - Fee Related
- 1999-06-24 WO PCT/US1999/014529 patent/WO1999066991A1/en active Application Filing
- 1999-06-24 AU AU48366/99A patent/AU4836699A/en not_active Abandoned
-
2001
- 2001-11-27 US US09/994,553 patent/US20020034985A1/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030050210A1 (en) * | 2000-04-28 | 2003-03-13 | The Procter & Gamble Company | Pouched compositions |
US20030050209A1 (en) * | 2000-04-28 | 2003-03-13 | The Procter & Gamble Company | Pouched compositions |
US6878679B2 (en) * | 2000-04-28 | 2005-04-12 | The Procter & Gamble Company | Pouched compositions |
US6881713B2 (en) * | 2000-04-28 | 2005-04-19 | The Procter & Gamble Company | Pouched compositions |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060135282A1 (en) * | 2004-12-17 | 2006-06-22 | Integran Technologies, Inc. | Article comprising a fine-grained metallic material and a polymeric material |
US7354354B2 (en) | 2004-12-17 | 2008-04-08 | Integran Technologies Inc. | Article comprising a fine-grained metallic material and a polymeric material |
US20080090066A1 (en) * | 2004-12-17 | 2008-04-17 | Integran Technologies, Inc. | Article comprising a fine-grained metallic material and a polymeric material |
US20080254310A1 (en) * | 2004-12-17 | 2008-10-16 | Integran Technologies, Inc. | Article comprising a fine-Grained metallic material and a polymeric material |
US7771289B2 (en) | 2004-12-17 | 2010-08-10 | Integran Technologies, Inc. | Sports articles formed using nanostructured materials |
CN113041583A (en) * | 2019-12-27 | 2021-06-29 | 古洛布莱株式会社 | Golf club shaft and golf club provided with same |
Also Published As
Publication number | Publication date |
---|---|
AU4836699A (en) | 2000-01-10 |
US6354960B1 (en) | 2002-03-12 |
WO1999066991A1 (en) | 1999-12-29 |
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