US20010031854A1 - Direct method for preparing doped polyaniline, product prepared thereby and resinous articles containing said product - Google Patents
Direct method for preparing doped polyaniline, product prepared thereby and resinous articles containing said product Download PDFInfo
- Publication number
- US20010031854A1 US20010031854A1 US09/822,941 US82294101A US2001031854A1 US 20010031854 A1 US20010031854 A1 US 20010031854A1 US 82294101 A US82294101 A US 82294101A US 2001031854 A1 US2001031854 A1 US 2001031854A1
- Authority
- US
- United States
- Prior art keywords
- acid
- polyaniline
- sulfonic acid
- doped polyaniline
- doped
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/026—Wholly aromatic polyamines
- C08G73/0266—Polyanilines or derivatives thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/124—Intrinsically conductive polymers
- H01B1/128—Intrinsically conductive polymers comprising six-membered aromatic rings in the main chain, e.g. polyanilines, polyphenylenes
Abstract
Doped polyanilines are prepared by contacting aniline with an oxidizing agent such as ammonium peroxydisulfate in aqueous solution at a temperature of at most about 10° C. in the presence of at least one organic sulfonic acid, preferably an alkylbenzenesulfonic acid such as dodecylbenzenesulfonic acid. The products may be blended with thermoplastic resins such as polystyrene to produce blends having excellent static discharge properties
Description
- This invention relates to conductive polymers, and more particularly to conductive doped polyanilines and compositions containing them The use of conductive materials as additives for plastics is of considerable interest since increased conductivity is desirable for many applications, including electrostatic painting and dissipation of static charges. For the latter purpose, especially, a very short static decay time, on the order of 0.02 second, is desirable.
- Among the conductive additives which have been employed are conductive carbon black and conductive carbon fiber. At high loadings, however, carbon black tends to accumulate at the surface of a plastic part and subsequently slough off the plastic part. Carbon fiber is expensive and can decrease impact resistance of the part.
- It is also possible to coat the surfaces of particulate non-conductive fillers such as mica, glass fibers or glass spheres with a conductive metal or compound thereof such as copper, silver or antimony-doped tin oxide. This, however, can cause problems including high cost, insufficient adhesion to the base resin and loss in conductivity as a result of oxidation of the metal coating.
- Many of these problems can be alleviated by employing a conductive polymer as the additive. A particularly advantageous conductive polymer is polyaniline, which may be prepared by electrochemical methods or chemically by the oxidation of aniline in the presence of a mineral acid under relatively mild conditions.
- These preparation methods typically afford the polyaniline as a partially oxidized and partially reduced material, with the reduced portion comprising —C6H4NH— structural units and the oxidized portion comprising alternating quinone and phenylene moieties separated by trivalent nitrogen atoms. This partially oxidized and partially reduced polyaniline is known as “emeraldine”. It can be readily converted to the fully oxidized state, known as “pernigraniline”, or to the fully reduced state, known as “leucoemeraldine”. It can also be handled in the protonated state, known as “protonated emeraldine”.
- Polyaniline prepared by known methods, including the above-described chemical method, has, however, various problems which detract from its utility as a conductive polymer. As a single example of such a problem, such polyaniline is often contaminated with by-products such as the virulently carcinogenic benzidine.
- PCT application 95/06,685 provides a summary of the state of the art of conductive polyaniline production and processing as of 1994, including the doping of polyaniline with such materials as alkylbenzenesulfonic acids. It also discloses a process in which doped polyaniline is combined with a polymer and a “solvent-plasticizer” to form a processable composition. Such a process requires a first step of preparing the polyaniline, a second step of doping it and a third step of combining the doped material with a polymer and a solvent-plasticizer.
- It remains of interest, therefore, to prepare a polyaniline which is not contaminated with harmful by-products and which can be prepared in a minimum of steps and then blended with plastic materials to produce a processable conductive material.
- The present invention provides a single-step direct method for preparing doped polyaniline and a method for separating the product from the reaction system I which it was prepared. The product of said method is benzidine-free and has a static decay time which is substantially shorter than that of doped polyaniline prepared by other methods. Said product can be combined in a single blending operation with thermoplastic polymers to afford processable conductive resinous compositions.
- In one of its aspects, the invention is a method for preparing an electrically conductive polyaniline which comprises contacting aniline with an oxidizing agent in aqueous solution at a temperature of at most about 10° C. in the presence of at least one organic sulfonic acid. Another aspect of the invention is sulfonic acid-doped polyanilines prepared by this method.
- A further aspect is conductive resinous compositions comprising at least one thermoplastic resin and the sulfonic acid-doped polyaniline.
- A still further aspect is a method of isolating polyaniline doped with at least one organic sulfonic acid which comprises precipitating said doped polyaniline from aqueous solution by combination with a mixture of water and a C1-4 water-miscible alkanol and separating the precipitated polyaniline from said solution.
- In the method of the invention for polyaniline preparation, aniline is contacted with an oxidizing agent suitable for its conversion to polyaniline. Suitable oxidizing agents are, in general, mild ones and their identities are known in the art. The preferred oxidizing agent, for most purposes, is ammonium peroxydisulfate, (NH4)2S2OS.
- Also employed is at least one organic sulfonic acid. It may be an aliphatic, aromatic or heterocyclic sulfonic acid; illustrative acids are methanesulfonic acid, benzenesulfonic acid, p-toluenesulfonic acid, 3-carboxy-4-hydroxybenzenesulfonic acid and 8-hydroxyquinoline-5-sulfonic acid. The preferred acids are the alkylbenzenesulfonic acids, most preferably those in which the alkyl groups contain about 4-20 carbon atoms; examples are 2-n-octylbenzenesulfonic acid and 4-n-dodecylbenzenesulfonic acid, the latter often being especially preferred.
- Polyaniline preparation is effected by simply bringing the aniline into contact with the oxidizing agent and sulfonic acid at a temperature of at most about 10° C. at which the oxidation reaction takes place, the preferred temperature range being about 0-10° C. An aqueous medium is preferred. When the oxidizing agent is a peroxydisulfate such as ammonium peroxydisulfate, it is used in at least an equimolar amount with respect to the aniline, preferably in a molar ratio in the range of about 1.0-1.2:1. The sulfonic acid is preferably used in the amount of about 5-10 ml per gram of aniline. Most often, the oxidizing agent is added gradually or portionwise to a mixture of water, aniline and sulfonic acid, and the resulting mixture is agitated to facilitate polyaniline formation.
- The polyaniline obtained according to the invention is already doped with sulfonic acid and is generally in the form of a suspension in the aqueous medium, said suspension being difficult to filter since the polyaniline particles tend to clog filters of pore size less than about 200 microns or pass through filters with larger pore sizes. According to the polyaniline isolation method of the invention, the suspension is combined with a mixture of water and a C1-4 water-miscible alkanol such as methanol, ethanol, 1-propanol, 2-propanol or 2-methyl-2-propanol. The preferred alkanol in most instances is 2-propanol, by reason of its particular suitability, availability and low cost.
- Combination of the aqueous reaction mixture with the alkanol-water mixture is ordinarily effected under ambient conditions including temperatures in the range of about 20-30° C. Said.alkanol-water mixture typically contains an amount up * to about 95% by weight water with the balance being alkanol. Upon such combination, the doped polyaniline precipitates as a fine powder which may be easily removed by filtration. After drying, typically in vacuum, it is ready for use.
- The entire process of polyaniline preparation and isolation according to the invention is most often completed in a period of 6-8 hours. This is in contrast to the prior art method employing a mineral acid, which may require up to 10 hours for completion.
- Sulfonic acid-doped polyanilines prepared and, preferably, isolated by the method of this invention are conductive and may be used in the same way as other conductive polymers. In particular, it may be employed to form a conductive coating on fillers and reinforcing agents of high aspect ratio, such as glass fibers, which may then be incorporated in thermoplastic resins to increase their conductivity.
- The doped polyaniline may also be used directly as a conductive additive for thermoplastic resins. Illustrative resins include addition polymers, exemplified by olefin polymers such as polyethylene and polypropylene; diene polymers such as polybutadiene, polyisoprene, high impact styrene-diene copolymers and acrylonitrile-butadiene-styrene copolymers; alkenylaromatic polymers other than diene polymers, such as homo- and copolystyrenes; vinyl halide polymers; vinyl ester and alcohol polymers; acrylic polymers including polyacrylonitrile, polyacrylamide and poly(alkyl acrylates) and poly(alkyl methacrylates) such as poly(methyl methacrylate). Also included are condensation polymers, exemplified by polycarbonates such as bisphenol A polycarbonate, polyesters such as poly(ethylene terephthalate) and poly(1,4-butylene terephthalate); polyphenylene ethers such as poly(2,6-dimethyl-1,4-phenytene ether); polyarylene sulfides; polyetherimides such as the condensation product of 2,2-bis[4-(3,4-dicarboxyphenoxy)phenyl]propane dianhydride with at least one of p- and m-phenylenediamine; and polyethersulfones. For many purposes, polystyrene is a preferred thermoplastic resin. The resinous blends of the invention most often contain about 60-99% by weight of the thermoplastic resin and correspondingly about 1-40% of the doped polyaniline.
- The invention is illustrated by the following examples.
- A beaker was charged with 3,000 ml of water, 18.2 g of aniline and 90 ml of dodecylbenzenesulfonic acid. The mixture was cooled in an ice bath to 10° C. and a solution of 45.2 g of ammonium peroxydisulfate in 200 ml of water was added dropwise over 1.5 hours, with stirring. The reaction mixture was stirred for about 7 hours.
- The product was an aqueous suspension of dodecylbenzenesulfonic acid-doped polyaniline which was found by gas chromatography-mass spectroscopy to be free from benzidine. By contrast, a control polyaniline reaction mixture prepared similarly using hydrochloric acid in place of the sulfonic acid was found to contain a trace of benzidine.
- A 400-g portion of the aqueous polyaniline suspension prepared in Example 1 was mixed with 400 g of water and 400 g of 2-propanol. A precipitate formed which was easily removable from the aqueous medium by filtration through a filter with 1-micron pores. The filtration residue was the desired dodecylbenzenesulfonic acid-doped polyaniline (11.11 g).
- Blends of dodecylbenzenesulfonic acid-doped polyaniline, prepared and isolated by the method of Examples 1-2, and a commercially available polystyrene were prepared by mixing the resins in a Brabender mixer at 220° C. for 5 minutes. The static decay times of the resulting blend samples were determined by applying 5,000-volt positive charges thereto and measuring the time required for the charge to decrease to 500 volts. Three applications of positive charge were made to each sample at 5-second intervals, followed by three similar applications of negative charge.
- The average positive and negative charge dissipation times for each sample are reported in the following table. Comparison is made with two controls similarly prepared from the control polyaniline of Example 1; i.e., the polyaniline prepared using hydrochloric acid and subsequently doped with dodecylbenzenesulfonic acid.
Avg. positive Avg. negative dissipation dissipation Example Polystyrene, % Polyaniline, % time, V time, V 1 98 2 0.02 0.02 2 95 5 0.01 0.01 3 90 10 0.01 0.01 Control 1 98 2 6.56 2.37 Control 2 95 5 6.29 2.40 - The results in the table clearly demonstrate the superior conductivity of the doped polyaniline prepared by the method of the invention, as compared with polyaniline prepared conventionally and subsequently doped.
Claims (21)
1. A method for preparing an electrically conductive polyaniline which comprises contacting aniline with an oxidizing agent in aqueous solution at a temperature of at most about 10° C. in the presence of at least one organic sulfonic acid.
2. A method according to wherein the oxidizing agent is ammonium peroxydisulfate.
claim 1
3. A method according to wherein the sulfonic acid is an alkylbenzenesulfonic acid.
claim 2
4. A method according to wherein the alkylbenzenesulfonic acid is dodecylbenzenesulfonic acid.
claim 3
5. A method for preparing an electrically conductive polyaniline which comprises contacting aniline with ammonium peroxydisulfate in aqueous solution at a temperature in the range of about 0-10° C. in the presence of at least one alkylbenzenesulfonic acid, the molar ratio of said ammonium peroxydisulfate to said aniline being in the range of about 1.0-1.2:1 and the sulfonic acid being present in the amount of about 5-10 ml per gram of aniline.
6. A method according to wherein the alkylbenzenesulfonic acid is dodecylbenzenesulfonic acid.
claim 5
7. A sulfonic acid-doped polyaniline prepared by the method of .
claim 1
8. A sulfonic acid-doped polyaniline prepared by the method of .
claim 3
9. A sulfonic acid-doped polyaniline prepared by the method of .
claim 4
10. A sulfonic acid-doped polyaniline prepared by the method of .
claim 5
11. A sulfonic acid-doped polyaniline prepared by the method of .
claim 6
12. A method of isolating polyaniline doped with at least one organic sulfonic acid which comprises precipitating said doped polyaniline from aqueous solution by combination with a mixture of water and a C1-4 water-miscible alkanol and separating the precipitated polyaniline from said solution.
13. A method according to wherein the alkanol-water mixture contains an amount up to about 95% by weight water with the balance being alkanol.
claim 12
14. A method according to wherein the sulfonic acid is an alkylbenzenesulfonic acid.
claim 12
15. A method according to wherein the alkylbenzenesulfonic acid is dodecylbenzenesulfonic acid.
claim 14
16. A method according to wherein the alkanol is 2-propanol.
claim 12
17. A conductive resinous composition comprising at least one thermoplastic resin and a sulfonic acid-doped polyaniline according to .
claim 7
18. A composition according to wherein the thermoplastic resin is selected from the group consisting of olefin polymers, diene polymers, alkenylaromatic polymers other than diene polymers, vinyl halide polymers, vinyl ester and alcohol polymers, acrylic polymers, polycarbonates, polyesters, polyphenylene ethers, polyarylene sulfides, polyetherimides and polyethersulfones.
claim 17
19. A composition according to wherein the thermoplastic resin is polystyrene.
claim 18
20. A composition according to comprising about 60-99% by weight of said thermoplastic resin and correspondingly about 1-40% of said doped polyaniline.
claim 18
21. A conductive resinous composition comprising about 60-99% by weight of polystyrene and correspondingly about 1-40% of a dodecylbenzenesulfonic acid-doped polyaniline according to .
claim 11
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/822,941 US20010031854A1 (en) | 1999-11-15 | 2001-03-30 | Direct method for preparing doped polyaniline, product prepared thereby and resinous articles containing said product |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/440,186 US6277952B1 (en) | 1999-11-15 | 1999-11-15 | Direct method for preparing doped polyaniline, product prepared thereby and resinous articles containing said product |
US09/822,941 US20010031854A1 (en) | 1999-11-15 | 2001-03-30 | Direct method for preparing doped polyaniline, product prepared thereby and resinous articles containing said product |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/440,186 Division US6277952B1 (en) | 1999-11-15 | 1999-11-15 | Direct method for preparing doped polyaniline, product prepared thereby and resinous articles containing said product |
Publications (1)
Publication Number | Publication Date |
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US20010031854A1 true US20010031854A1 (en) | 2001-10-18 |
Family
ID=23747783
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
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US09/440,186 Expired - Fee Related US6277952B1 (en) | 1999-11-15 | 1999-11-15 | Direct method for preparing doped polyaniline, product prepared thereby and resinous articles containing said product |
US09/822,936 Abandoned US20010012884A1 (en) | 1999-11-15 | 2001-03-30 | Direct method for preparing doped polyaniline, product prepared thereby and resinous articles containing said product |
US09/822,941 Abandoned US20010031854A1 (en) | 1999-11-15 | 2001-03-30 | Direct method for preparing doped polyaniline, product prepared thereby and resinous articles containing said product |
US09/822,937 Abandoned US20010037013A1 (en) | 1999-11-15 | 2001-03-30 | Direct method for preparing doped polyaniline, product prepared thereby and resinous articles containing said product |
Family Applications Before (2)
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US09/440,186 Expired - Fee Related US6277952B1 (en) | 1999-11-15 | 1999-11-15 | Direct method for preparing doped polyaniline, product prepared thereby and resinous articles containing said product |
US09/822,936 Abandoned US20010012884A1 (en) | 1999-11-15 | 2001-03-30 | Direct method for preparing doped polyaniline, product prepared thereby and resinous articles containing said product |
Family Applications After (1)
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US09/822,937 Abandoned US20010037013A1 (en) | 1999-11-15 | 2001-03-30 | Direct method for preparing doped polyaniline, product prepared thereby and resinous articles containing said product |
Country Status (3)
Country | Link |
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US (4) | US6277952B1 (en) |
AU (1) | AU1210201A (en) |
WO (1) | WO2001035717A2 (en) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6900286B2 (en) * | 2003-03-31 | 2005-05-31 | Council Of Scientific And Industrial Research | Process for preparation of conducting polyaniline |
US7026432B2 (en) | 2003-08-12 | 2006-04-11 | General Electric Company | Electrically conductive compositions and method of manufacture thereof |
AU2003292511A1 (en) * | 2003-12-24 | 2005-07-14 | Council Of Scientific And Industrial Research | A process for the preparation of conducting polymer moulding compound with improved processability |
DE60321247D1 (en) * | 2003-12-31 | 2008-07-03 | Council Scient Ind Res | PROCESS FOR PREPARING CONDUCTIVE POLYANILINE |
US7462656B2 (en) | 2005-02-15 | 2008-12-09 | Sabic Innovative Plastics Ip B.V. | Electrically conductive compositions and method of manufacture thereof |
CN100480302C (en) * | 2005-03-23 | 2009-04-22 | 南京大学 | Controllable synthesis method for polyaniline nano structure and use thereof |
US20070194286A1 (en) | 2006-02-17 | 2007-08-23 | The Regents Of The University Of California | Fabrication of polyaniline nanofiber dispersions and films |
WO2008031992A2 (en) * | 2006-09-13 | 2008-03-20 | Arkema France | Composition of polymers exhibiting enhanced conductivity and enhanced antistatic properties |
FR2905699B1 (en) * | 2006-09-13 | 2008-11-14 | Arkema France | POLYMER COMPOSITION WITH IMPROVED ANTISTATIC CONDUCTIVITY AND PROPERTIES |
US8171483B2 (en) | 2007-10-20 | 2012-05-01 | Citrix Systems, Inc. | Method and system for communicating between isolation environments |
CN101798386A (en) * | 2010-03-17 | 2010-08-11 | 上海大学 | Method for preparing water-soluble conductive polyaniline |
WO2012145885A1 (en) * | 2011-04-25 | 2012-11-01 | Tongji University | Aniline copolymers and methods for their preparation and use |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5160457A (en) * | 1987-08-07 | 1992-11-03 | Allied-Signal Inc. | Thermally stable forms of electrically conductive polyaniline |
US4973391A (en) * | 1988-08-30 | 1990-11-27 | Osaka Gas Company, Ltd. | Composite polymers of polyaniline with metal phthalocyanine and polyaniline with organic sulfonic acid and nafion |
US5254633A (en) * | 1991-07-10 | 1993-10-19 | Allied Signal Inc. | Process for the preparation of conductive polymer blends |
JP3108894B2 (en) * | 1991-12-05 | 2000-11-13 | ネスト オイ | Electrically conductive and solid plastic material and its manufacturing method |
US5340499A (en) * | 1992-08-11 | 1994-08-23 | Neste Oy | Electrically conductive compositions and methods for their preparation |
WO1995006685A1 (en) * | 1993-09-03 | 1995-03-09 | Neste Oy | Electrically conducting compositions |
US5589108A (en) * | 1993-12-29 | 1996-12-31 | Nitto Chemical Industry Co., Ltd. | Soluble alkoxy-group substituted aminobenzenesulfonic acid aniline conducting polymers |
TW464661B (en) * | 1996-06-10 | 2001-11-21 | Nippon Catalytic Chem Ind | Water-soluble electrically-conductive polyaniline and method for production thereof and antistatic agent using water-soluble electrically-conductive polymer |
WO1999016084A1 (en) * | 1997-09-25 | 1999-04-01 | Zipperling Kessler & Co. (Gmbh & Co.) | Electrically conductive block copolymers containing an intrinsically conductive polymer |
-
1999
- 1999-11-15 US US09/440,186 patent/US6277952B1/en not_active Expired - Fee Related
-
2000
- 2000-10-17 AU AU12102/01A patent/AU1210201A/en not_active Abandoned
- 2000-10-17 WO PCT/US2000/028702 patent/WO2001035717A2/en active Application Filing
-
2001
- 2001-03-30 US US09/822,936 patent/US20010012884A1/en not_active Abandoned
- 2001-03-30 US US09/822,941 patent/US20010031854A1/en not_active Abandoned
- 2001-03-30 US US09/822,937 patent/US20010037013A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
US20010037013A1 (en) | 2001-11-01 |
US20010012884A1 (en) | 2001-08-09 |
WO2001035717A2 (en) | 2001-05-25 |
AU1210201A (en) | 2001-05-30 |
WO2001035717A3 (en) | 2001-11-29 |
US6277952B1 (en) | 2001-08-21 |
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