US1982009A - Means for electroplating the interior surfaces of hollow articles - Google Patents
Means for electroplating the interior surfaces of hollow articles Download PDFInfo
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- US1982009A US1982009A US578172A US57817231A US1982009A US 1982009 A US1982009 A US 1982009A US 578172 A US578172 A US 578172A US 57817231 A US57817231 A US 57817231A US 1982009 A US1982009 A US 1982009A
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- electroplating
- tube
- plug
- barrel
- plated
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
- C25D7/04—Tubes; Rings; Hollow bodies
Definitions
- Our invention relates to apparatus for electroplating the interior surfaces. of hollow articles.
- the objects of this invention include the provision of means for making possible the use of high current densities, means for controlling closely the temperatures under which the operation is carried out, and a novel electrode capable of carrying a heavy current.
- Fig. 2 is a side elevation of the electrode;
- Fig. 3 is a longitudinal section of the electrode;
- Fig. 4 is a longitudinal section of a plugused in the breech chamber of a gun barrel when it is desired to plate the bore thereof;
- Fig. 5 is a plan view of the device shown in Fig. 1;
- Fig. 6 is a cross section on the line 66 of Fig. 1;
- Fig. I is a cross section on line 7-7 of Fig. 1;
- Fig. 8 is a cross section on line 8-8 of Fig. 1;
- Fig. 9 is a cross section on line 9-9 of Fig. 1.
- a ratio of anode surface to cathode surface of three to one but it is obviously impossible to adhere to these proportions when the surface to be plated is the interior of a hollow object, such as the inner surface of a hollow cylinder, as it is necessary to provide adequate space between the anode and the surface to be plated to contain the electrolyte.
- Chromium plating requires very high current densities and'control of the temperature within 7 of the optimum for securing best results.
- the temperature should not vary much from a range of 113 F. to 120 F.; at 225 amperes per square foot,
- the temperature should be from 135 F. to 140 F.;-
- the present invention provides an anode capable of carrying the heavycurrent requisite for successful plating with chromium without overheating, and
- Fig. 1 the numeral 11 indicates the wall of a pit of sufl'icient depth to accommodate apparatus suitable to articles of thelength it is desired to plate.
- a tank 12 is disposed in the pit to contain a temperature control bath 13.
- the ex- Fig. 1 is a longitudinal sectional view of a The article to be interiorly plated, here shown for purpose of illustration, as a gun barrel 25,.is positioned .in bath 13.
- the tapered breech chamber which is not to be plated, is closed by a tapered plug 20 that has a-gasket 21 secured.
- plug 20 has a gasket 27 set into it to form a seal against the end of barrel 25, and is provided with pairs of ears 28 between which eye-bolts 29 are pivoted, these bolts being disposed between ears 30 on split ring 31 that is clamped around barrel 25 and having nuts 32 thereon screwed against ears 30 to secure the plug 20 tightly in place.
- a drain valve in plug 20 comprises a disk 33 having apertures 34 therethrough, held against rotation by a key 35, and a rotatable disk 36 having apertures 37'that may be brought into registry with apertures 34 and a polygonal shank 38 to be engaged by a tool to rotate the disk 36, the two disks being held tightly together by a clamping ring 39 screwed into plug 20 against disk 36.
- Apertures 40 place the space within plug 20 in. communication with the interior of barrel 25, so that by turning disk 36 to align the openings '64 therein with the apertures 34 in disk 33, the electrolyte may be drained from the barrel after the as to fit snugly within tank 12 to position the upper end of the barrel.
- a gasket 45 isclamped between the end of barrel 25 and the base of a receptacle 46 for electrolyte, there being a suflicient quantity of the plating solution therein in excess of that required to fill the bore of the barrel 25 to replace any evaporation or other filosses and keep the bore full throughout the to hold receptacle 46 firmly in place.
- thermometer 49 perature of the electrolyte is shown by thermometer 49.
- Extending through tube 50 is a bar51 of copper that is se'aled into the tube at the lower end thereof and has a conical point to rest in the recess 24 in member 23 in the top of plug 20.
- the anode asse bly is laterally supported-by an insulating member .56 carried by member 46. Cables 57 conduct the current to the anode.
- An apparatus for electroplating the inner surfaces of hollow cylinders comprising atank to contain a temperature control bath in which the article to be plated may be immersed, means to vary the temperature 'of said bath, a hollow plug fitted into the lower end of such cylinders to form a closure therefor, an insulating block set into the closed upper end of said plug, apertures through said closed end, a disk non-rotatably positioned in said plug spaced from said end, a rotatable disk in contact with the first mentioned disk and having apertures therethrough that may be made to register with the apertures in the said first mentioned disk and means engageable by a tool to rotate said rotatable disk, means to retain said disks in contact, a frusto-conical face formed at the lower end of said plug, a frusto-conical boss on the bottom of said tank to interfit with said face; an anode disposable in said cylinders, comprising a copper tube exteriorly coated with lead and a solid copper b'ar extending through said tube and
- a temperature-control bath in which such cylinders may be immersed, a closure for the lower ends of said cylinders, said closure being adapted to cooperate 1 with a member in said bath to position said lower endand to support an electrode and drain valve mechanism incorporated therein, an-anode in said article comprising a tube of copper-c9125 teriorly plated with lead, a solid bar of copper ex-.
- said bar beingadapted to rest upon said closure, and means to circulate a cooling liquid in said tube, means to carry current away of such articles, said closure being hollow with one and closed, an insulating block setinto said closed end, apertures through said end ia" sealingannulus set into the periphery of said-closure, a
- a rotatable disk having perforations alignable with the perforations in said nonrotatable disk and means engageable by a tool solid bar of copper extending through said tube 130 and connected thereto at both ends, and means to circulate coolant in said tube.
- An anode for chromium plating the interior surfaces of hollow cylinders comprising a tube of copper exteriorly plated with lead, a solid bar of copper extending through said tube and sealed to said tube at one end, means connecting said bar metal that constitutes the anodic surface and a conducting member extending through said tube and connected thereto at both ends.
- An anode for electroplating the interior of hollow articles comprising a hollow member of substantially the same shape as the surface to be plated but of smaller size, conducting means within said member connected to opposite extremities of said member, and means to circulate a fluid in said member.
- An anode for electroplating the interior of hollow articles comprising a member of substantially the same shape as the surface to be plated but of smaller size, and means to supply current to said member at a point exteriorly of the article to be plated and at a point adjacent the other end of said member within said article.
Description
Nov. 27, 1934.
P. E. M KINNEY El AL .MEANS FOR ELECTROPLATING THE INTERIOR SURFACES OF HOLLOW ARTICLES Filed Nov. 30, 1931 4 Sheets-Sheet l- 20 NVENTO S -39 E. Mc mney 8 S ATTORNEY Nov. 27, 1934. E MCKINNEY ET AL 1,982,069
MEANS FOR ELECTROPLATING THE INTERIOR SURFACES OF HOLLOW ARTICLES Filed Nov. 50, 1951 4 Sheets-Sheet 2 I ii 0 5' 23 4 49 flay 74m 'a INVE TORS 28 25 g /zcklllhjd HZeLaur/h ATTORN EY Nov.27, 1934. E, MQKMNEY ET AL 1,982,609
Filed Nov. 30, 1951 4 Sheet-Sheet 5 Y 53 zgo INVENTORS flc/flhgay a LeLaur/n.
ATTORNEY Nov. 27, 1934. P, MCKINNEY ET AL 1,982,009
MEANS FOR ELECTROPLATING THE INTERIOR SURFACES OF HOLLOW ARTICLES Filed NOV. 30, 1931 4 Sheets-Sheet 4 mvENToRi/ MC/(mne S' [claw/l7.
ATTORNEY Patented Nov. 27, 1934 MEANS FOR. ELECTROPLATING THE m'rmuoa SURFACES F HOLLOW ARTICLES Paul E. McKinney, Bethlehem, Pa., and Harry Le Lanrin, Washington, D. 0.
Application November 30.1931, Serial No. 578,172
8 Claims.
Our invention relates to apparatus for electroplating the interior surfaces. of hollow articles.
The objects of this invention include the provision of means for making possible the use of high current densities, means for controlling closely the temperatures under which the operation is carried out, and a novel electrode capable of carrying a heavy current.
In the drawings: l0
plating installation according to our invention;
Fig. 2 is a side elevation of the electrode; Fig. 3 is a longitudinal section of the electrode; Fig. 4 is a longitudinal section of a plugused in the breech chamber of a gun barrel when it is desired to plate the bore thereof;
Fig. 5 is a plan view of the device shown in Fig. 1;
Fig. 6 is a cross section on the line 66 of Fig. 1;
Fig. I is a cross section on line 7-7 of Fig. 1; Fig. 8 is a cross section on line 8-8 of Fig. 1; and
Fig. 9 is a cross section on line 9-9 of Fig. 1. In ordinary electroplating work it is customary to provide a ratio of anode surface to cathode surface of three to one, but it is obviously impossible to adhere to these proportions when the surface to be plated is the interior of a hollow object, such as the inner surface of a hollow cylinder, as it is necessary to provide adequate space between the anode and the surface to be plated to contain the electrolyte.
Chromium plating requires very high current densities and'control of the temperature within 7 of the optimum for securing best results. For
example, where the current density is 150 amperes per square foot of surface to be plated the temperature should not vary much from a range of 113 F. to 120 F.; at 225 amperes per square foot,
the temperature should be from 135 F. to 140 F.;-
and at 325 amperes per square foot the temperature should be from 140 F. to 145 F. The present invention provides an anode capable of carrying the heavycurrent requisite for successful plating with chromium without overheating, and
means for controlling the temperature of the work within the specified narrow limits.
In Fig. 1 the numeral 11 indicates the wall of a pit of sufl'icient depth to accommodate apparatus suitable to articles of thelength it is desired to plate. A tank 12 is disposed in the pit to contain a temperature control bath 13. When the temperature becomes too high, water is admitted to bath 13 through pipe 14 to cool the bath, the ex- Fig. 1 is a longitudinal sectional view of a The article to be interiorly plated, here shown for purpose of illustration, as a gun barrel 25,.is positioned .in bath 13. The tapered breech chamber, which is not to be plated, is closed by a tapered plug 20 that has a-gasket 21 secured. thereon near its upper end by means of clamping ring 22, the gasket being somewhat larger than the plug at that place to make a fluid tight seal. An insulating block 23 is set into the top of plug 20; a depression 24 is formed in the block to receive a correspondingly shaped portion of the electrode, whereby the electrode is in part supported upon plug 20. Base 26of plug 20 has a gasket 27 set into it to form a seal against the end of barrel 25, and is provided with pairs of ears 28 between which eye-bolts 29 are pivoted, these bolts being disposed between ears 30 on split ring 31 that is clamped around barrel 25 and having nuts 32 thereon screwed against ears 30 to secure the plug 20 tightly in place.
A drain valve in plug 20 comprises a disk 33 having apertures 34 therethrough, held against rotation by a key 35, and a rotatable disk 36 having apertures 37'that may be brought into registry with apertures 34 and a polygonal shank 38 to be engaged by a tool to rotate the disk 36, the two disks being held tightly together by a clamping ring 39 screwed into plug 20 against disk 36. Apertures 40 place the space within plug 20 in. communication with the interior of barrel 25, so that by turning disk 36 to align the openings '64 therein with the apertures 34 in disk 33, the electrolyte may be drained from the barrel after the as to fit snugly within tank 12 to position the upper end of the barrel. A gasket 45 isclamped between the end of barrel 25 and the base of a receptacle 46 for electrolyte, there being a suflicient quantity of the plating solution therein in excess of that required to fill the bore of the barrel 25 to replace any evaporation or other filosses and keep the bore full throughout the to hold receptacle 46 firmly in place.
perature of the electrolyte is shown by thermometer 49.
plating operation. Stud bolts 47 screwed into the base of receptacle 46 and passed through arms 44 have nuts 48 that bear again'st arms 44 The tem- As the electrolyte used in chromium plating attacks copper quite vigorously, it is the usual practice to make the anodes of lead when chromium is to be electro-deposited upon an article. The resistance of lead is too high to be used successfully in plating the bores of guns,- as the high current. density necessary would develop in 'it temperatures .too great for satisfactory electrolysis.
The difliculty mentioned in the previous paragraph has been obviated by our novel anode which comprises a tube 50 made of copper because of the high conductivity of that inetal', electroplated on its exterior surface with lead or some. other metal 'resistant to the action of the electrolyte to be used. In the present instance, lead to the thickness of approximately 0.01 inch was applied, then cleaned and treated'by the sc-called scratch-' brush" method, to prevent the formation of large crystals which are not highly resistant to the action of the electrolyte, then another coating of lead that in turn was cleaned, and so on until a thiclmess of about 0.05 inch or more of lead had been deposited on the tube. With the last-mentioned thickness of lead on the tube there is no hazard of serious contamination of the electrolyte with the copper, and yet the conductivity of the tube is notmarkedly impaired.
Extending through tube 50 is a bar51 of copper that is se'aled into the tube at the lower end thereof and has a conical point to rest in the recess 24 in member 23 in the top of plug 20. An
distribution of the curren ""over the tube is secured. The anode asse bly is laterally supported-by an insulating member .56 carried by member 46. Cables 57 conduct the current to the anode.
The current ispcarried'away from the cathode (barrel 25) by heavy copper bands 58 clamped thereon that are connected to thereby to cables 60. Lifting links .61 secured to arms 44, and lugs 62 on band 63 that is clamped around barrel 25, provide means for hooking a crane to the barrel 25 to lower it into or lift it from the bath 13.
It,has been found that when the bore of a gun is plated with chromium the life thereof is very bus-bar '59 and -.much' prolonged. For the life of a large caliber gun'barrel is about one-hundred twenty rounds, when unplated. When plated with chromium, the plating lasts sixty rounds when it should be re-plated. As this process may be practiced repeatedly, the life of the barrel may be prolonged indefinitely. The chromium plating not only prevents pitting by the corrosive action perforated disk non-rotatably disposed in said.
of the gases from the propellant charge, but also seems to delay very much the crystallization of the metal of the barrel, the reason for which is not yet known.
It will be understood that the above description and accompanying drawings comprehend only the general and preferred embodiment of our invention, and that various changes in construction, proportion and arrangement ofparts may be made within the scope of the appended claims without sacrificing any of the advantages of our invention.
We claim:
1. An apparatus for electroplating the inner surfaces of hollow cylinders, comprising atank to contain a temperature control bath in which the article to be plated may be immersed, means to vary the temperature 'of said bath, a hollow plug fitted into the lower end of such cylinders to form a closure therefor, an insulating block set into the closed upper end of said plug, apertures through said closed end, a disk non-rotatably positioned in said plug spaced from said end, a rotatable disk in contact with the first mentioned disk and having apertures therethrough that may be made to register with the apertures in the said first mentioned disk and means engageable by a tool to rotate said rotatable disk, means to retain said disks in contact, a frusto-conical face formed at the lower end of said plug, a frusto-conical boss on the bottom of said tank to interfit with said face; an anode disposable in said cylinders, comprising a copper tube exteriorly coated with lead and a solid copper b'ar extending through said tube and sealed thereto at the lower end, the no lower end of said bar being disposed on the insulating block in said plug, means to circulate cooling liquids in said tube, and a heavy copper bar connecting the upper ,ends of said bar and said tube; and means connectible to said cylinders to conduct the current away therefrom.
2. In an apparatus for electroplating the interior surfaces of hollow cylinders, a temperature-control bath in which such cylinders may be immersed, a closure for the lower ends of said cylinders, said closure being adapted to cooperate 1 with a member in said bath to position said lower endand to support an electrode and drain valve mechanism incorporated therein, an-anode in said article comprising a tube of copper-c9125 teriorly plated with lead, a solid bar of copper ex-.
tendingtherethrough and connected thereto at i both-ends, said bar beingadapted to rest upon said closure, and means to circulate a cooling liquid in said tube, means to carry current away of such articles, said closure being hollow with one and closed, an insulating block setinto said closed end, apertures through said end ia" sealingannulus set into the periphery of said-closure, a
closure, a rotatable disk having perforations alignable with the perforations in said nonrotatable disk and means engageable by a tool solid bar of copper extending through said tube 130 and connected thereto at both ends, and means to circulate coolant in said tube.
4. An anode for chromium plating the interior surfaces of hollow cylinders, comprising a tube of copper exteriorly plated with lead, a solid bar of copper extending through said tube and sealed to said tube at one end, means connecting said bar metal that constitutes the anodic surface and a conducting member extending through said tube and connected thereto at both ends.
7. An anode for electroplating the interior of hollow articles, comprising a hollow member of substantially the same shape as the surface to be plated but of smaller size, conducting means within said member connected to opposite extremities of said member, and means to circulate a fluid in said member.
8. An anode for electroplating the interior of hollow articles, comprising a member of substantially the same shape as the surface to be plated but of smaller size, and means to supply current to said member at a point exteriorly of the article to be plated and at a point adjacent the other end of said member within said article.
, PAUL E. MCKINNEY.
HARRY LE LAURIN.
Priority Applications (1)
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US578172A US1982009A (en) | 1931-11-30 | 1931-11-30 | Means for electroplating the interior surfaces of hollow articles |
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US578172A US1982009A (en) | 1931-11-30 | 1931-11-30 | Means for electroplating the interior surfaces of hollow articles |
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Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2422242A (en) * | 1943-07-16 | 1947-06-17 | Wright Aeronautical Corp | Electroplating fixture |
US2431949A (en) * | 1943-11-24 | 1947-12-02 | Gen Motors Corp | Apparatus for electroplating the inside of bearing shells and the like |
US2544285A (en) * | 1944-03-15 | 1951-03-06 | Kenneth E Stuart | Electrolytic cell |
US2706175A (en) * | 1949-03-18 | 1955-04-12 | Electro Metal Hardening Co S A | Apparatus for electroplating the inner surface of a tubular article |
US3506557A (en) * | 1967-02-01 | 1970-04-14 | Allegheny Ludlum Steel | Electrochemical machining cell |
US3857772A (en) * | 1971-12-25 | 1974-12-31 | Toyo Kogyo Co | Electroplating apparatus for simultaneously and uniformly electroplating inside surfaces of annular bodies |
US3894925A (en) * | 1965-11-18 | 1975-07-15 | Inoue K | Electrode for electrical machining |
US3905885A (en) * | 1973-06-13 | 1975-09-16 | United States Steel Corp | Method for the electrolytic conditioning of metal tubes |
US4474613A (en) * | 1981-01-28 | 1984-10-02 | C. Conradty Nurnberg Gmbh & Co. Kg | Electrode for fusion electrolysis |
US4826582A (en) * | 1985-08-05 | 1989-05-02 | Framatome | Surface treatment process and device for heat exchangers |
US6547945B2 (en) * | 2000-07-31 | 2003-04-15 | United Technologies Corporation | Method and apparatuses for electrochemically treating an article |
US11286575B2 (en) * | 2017-04-21 | 2022-03-29 | Modumetal, Inc. | Tubular articles with electrodeposited coatings, and systems and methods for producing the same |
US11519093B2 (en) | 2018-04-27 | 2022-12-06 | Modumetal, Inc. | Apparatuses, systems, and methods for producing a plurality of articles with nanolaminated coatings using rotation |
US11560629B2 (en) | 2014-09-18 | 2023-01-24 | Modumetal, Inc. | Methods of preparing articles by electrodeposition and additive manufacturing processes |
US11692281B2 (en) | 2014-09-18 | 2023-07-04 | Modumetal, Inc. | Method and apparatus for continuously applying nanolaminate metal coatings |
US11851781B2 (en) | 2013-03-15 | 2023-12-26 | Modumetal, Inc. | Method and apparatus for continuously applying nanolaminate metal coatings |
-
1931
- 1931-11-30 US US578172A patent/US1982009A/en not_active Expired - Lifetime
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2422242A (en) * | 1943-07-16 | 1947-06-17 | Wright Aeronautical Corp | Electroplating fixture |
US2431949A (en) * | 1943-11-24 | 1947-12-02 | Gen Motors Corp | Apparatus for electroplating the inside of bearing shells and the like |
US2544285A (en) * | 1944-03-15 | 1951-03-06 | Kenneth E Stuart | Electrolytic cell |
US2706175A (en) * | 1949-03-18 | 1955-04-12 | Electro Metal Hardening Co S A | Apparatus for electroplating the inner surface of a tubular article |
US3894925A (en) * | 1965-11-18 | 1975-07-15 | Inoue K | Electrode for electrical machining |
US3506557A (en) * | 1967-02-01 | 1970-04-14 | Allegheny Ludlum Steel | Electrochemical machining cell |
US3857772A (en) * | 1971-12-25 | 1974-12-31 | Toyo Kogyo Co | Electroplating apparatus for simultaneously and uniformly electroplating inside surfaces of annular bodies |
US3905885A (en) * | 1973-06-13 | 1975-09-16 | United States Steel Corp | Method for the electrolytic conditioning of metal tubes |
US4474613A (en) * | 1981-01-28 | 1984-10-02 | C. Conradty Nurnberg Gmbh & Co. Kg | Electrode for fusion electrolysis |
US4826582A (en) * | 1985-08-05 | 1989-05-02 | Framatome | Surface treatment process and device for heat exchangers |
US6547945B2 (en) * | 2000-07-31 | 2003-04-15 | United Technologies Corporation | Method and apparatuses for electrochemically treating an article |
US11851781B2 (en) | 2013-03-15 | 2023-12-26 | Modumetal, Inc. | Method and apparatus for continuously applying nanolaminate metal coatings |
US11560629B2 (en) | 2014-09-18 | 2023-01-24 | Modumetal, Inc. | Methods of preparing articles by electrodeposition and additive manufacturing processes |
US11692281B2 (en) | 2014-09-18 | 2023-07-04 | Modumetal, Inc. | Method and apparatus for continuously applying nanolaminate metal coatings |
US11286575B2 (en) * | 2017-04-21 | 2022-03-29 | Modumetal, Inc. | Tubular articles with electrodeposited coatings, and systems and methods for producing the same |
US11519093B2 (en) | 2018-04-27 | 2022-12-06 | Modumetal, Inc. | Apparatuses, systems, and methods for producing a plurality of articles with nanolaminated coatings using rotation |
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