US1970548A - Metal finish - Google Patents
Metal finish Download PDFInfo
- Publication number
- US1970548A US1970548A US569853A US56985331A US1970548A US 1970548 A US1970548 A US 1970548A US 569853 A US569853 A US 569853A US 56985331 A US56985331 A US 56985331A US 1970548 A US1970548 A US 1970548A
- Authority
- US
- United States
- Prior art keywords
- metal
- copper
- tin
- coating
- electroplated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title description 35
- 239000002184 metal Substances 0.000 title description 35
- 238000000576 coating method Methods 0.000 description 29
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 28
- 239000011248 coating agent Substances 0.000 description 28
- 229910052802 copper Inorganic materials 0.000 description 28
- 239000010949 copper Substances 0.000 description 28
- 239000011135 tin Substances 0.000 description 24
- 229910052718 tin Inorganic materials 0.000 description 23
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 22
- 239000010953 base metal Substances 0.000 description 17
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 16
- 239000000203 mixture Substances 0.000 description 13
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 10
- 229910052804 chromium Inorganic materials 0.000 description 10
- 239000011651 chromium Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- 229910052759 nickel Inorganic materials 0.000 description 8
- 239000000956 alloy Substances 0.000 description 7
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000002131 composite material Substances 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 6
- 229910000906 Bronze Inorganic materials 0.000 description 5
- 239000010974 bronze Substances 0.000 description 5
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 4
- 239000002659 electrodeposit Substances 0.000 description 4
- 238000003892 spreading Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 238000009713 electroplating Methods 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- DOBRDRYODQBAMW-UHFFFAOYSA-N copper(i) cyanide Chemical compound [Cu+].N#[C-] DOBRDRYODQBAMW-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229940079864 sodium stannate Drugs 0.000 description 1
- 229940071182 stannate Drugs 0.000 description 1
- 125000005402 stannate group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/58—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of copper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/934—Electrical process
- Y10S428/935—Electroplating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12472—Microscopic interfacial wave or roughness
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12708—Sn-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12708—Sn-base component
- Y10T428/12722—Next to Group VIII metal-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12806—Refractory [Group IVB, VB, or VIB] metal-base component
- Y10T428/12826—Group VIB metal-base component
- Y10T428/12847—Cr-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12806—Refractory [Group IVB, VB, or VIB] metal-base component
- Y10T428/12826—Group VIB metal-base component
- Y10T428/12847—Cr-base component
- Y10T428/12854—Next to Co-, Fe-, or Ni-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12903—Cu-base component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12993—Surface feature [e.g., rough, mirror]
Definitions
- An object of the invention is to produce an electrodeposit which can be built up to a con: siderable thickness without blistering or becoming roughened.
- Another object of the invention is to produce'a coating adapted to be easily buiied to a high 'polish.
- Another object is to obtain a metal or composition that may be electrodeposited over itself in successive layers.
- Another object is to obtain a coating that is not only highly resistant to corrosion in itself but has that property of being electrodeposited to or buiied to a dense surface that closes up porosity within the electrodeposited coating.
- a further object is to produce a coating adapted for use as an intermediate between a relatively rough polished or unpolished base metal and a r highly lustrous finish metal such as chromium.
- Our improved electrodeposited coating comprises a mixture or alloy of the two metals copper and tin.-
- the coating is obtained by a process which comprises the'electrolyzing of a cyanide solution containing both copper and tin using anodes containing both copper and tin.
- the composition of the bath may vary widely under different conditions depending-on the requirements of the particular work under treatment but in general it is desirable to maintain the proportions within the following limits:
- the main desirable ingredients are the copper cyanide, soluble stannate, soluble free cyanide, and a suitable alkali.
- Equivalent reagents for obtaining a solution containing such ingredients may also be used such for example as the potassium salts instead of the sodium salts and other equivalent substitutes.
- the recommended temperature of operation of the bath is between 50 and 60 C. but satisfactory electroplating can be obtained at room temperatures although with less current efliciency.
- the anodes used are preferably of pure copper and pure tin alternately arranged but anodes of a mixture or alloy of copper and tin may be used in lieu thereof.
- the anodes show good corrosion in the bath, thereby maintaining the preferred composition of the electrolyte. It is a noteworthy fact that the copper anode is maintained very bright in the bath in contradistinction to the dull appearance due to oxide formation in other electroplating processes involving the use of copper anodes.
- Our process may be used for electroplating directly on iron and its alloys including steel. It may also be used for plating onother metals whether they bethe base metal or onlya coating over another base metal. Examples of such metals are copper, nickel, tin, zinc, cobalt, silver, as well as combinations of these metals such as nickel and cobalt, copper and zinc, zinc and aluminum, cadmium and v silver and copper and nickel.
- the above metals can also be electrortCiiur new composition hasthe following prope es:
- Ihe electroplated coating may advantageously be used as an undercoat in the production of bright metal finishes.
- chromium plating an automobile radiator .shell in order to obtain both resistance to corrosion and high luster, it iscommon practice to take the steel shell as it comes from the dies and subject it to a series of polishingoperations to remove die marks, cuts, slight metal distortions, pits and othersurface defects in the metal as otherwise these blemishes would show in the final finish. With our process, we are enabled to eliminate the mechanical polishing of the base metal and electrodeposit our metal or alloy directly on the unpolished metal.
- Electrodeposited metal containing approximately.85% copper and 15% tin.
- a composite article comprising a base metal having surface irregularities therein, an electroplated coating composed of copper and tin bond.
- a composite article comprising a base metal having surface irregularities therein, an electroplated coating composed of Ill-25% tin and balance copper bonded to .said metal and having a smooth, bufled surface free from corresponding surface irregularities and an overcoating of an other metal.
- a composite article comprising a base metal having surface irregularities therein, an electroplated coating bonded to said metal and having a smooth, buffed surface free from corresponding surface irregularities, said coating comprising a preponderance of copper and a substantial amount of tin and characterized by a substan tially higher spreading power than electroplated copper,'and an outer coating of bright metal.
- a composite article comprising a base metal having surface irregularities therein, an electroplated coating composed of copper and tin bonded to said metal and having a'smooth, bufied surface free from corresponding surface irregularities and an outer coating of chromium.
- a composite article comprising a base metal having surface irregularities .therein, an electroplated coating composed of copper and-tin bonded to said metal and having a smooth, buffed surface free from corresponding surface irregularities, a superposed coating of nickel and an outer coating of chromium.
- a composite article comprising a base metal rough polished, with 80 to 120 emery, an electroplated coating composed of copper or tin bonded vto said base metal and having a smooth bufled surface.
- An article comprising a base metal, a superposed electroplated layer comprising copper and tin and an outer layer of a bright metal.
- An article comprising a base metal, a superposed electroplated layer comprising copper and tin and an outer coating of chromium.
- An article comprising a base metal, a superposed electroplated layer comprising copper and tinand a superposed layer of nickel.
- An article comprising a superposed electroplated layer comprising copper and tin and an outer layer of a bright metal.
- An article comprising a ferrous'metal, a contacting'electroplated layer comprising copper and tin and a contacting layer of bright metal.
- An article comprising a ferrous metal and successive contacting electroplated layers of bronze and chromium, said bronze comprising I copper and tin.
- An article comprising successive contacting layers of ferrous metal, electrodeposited bronze, nickel and chromium, said bronze comprising copper and tin.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR743797D FR743797A (enrdf_load_stackoverflow) | 1931-10-19 | ||
| US569853A US1970548A (en) | 1931-10-19 | 1931-10-19 | Metal finish |
| GB29160/32A GB409001A (en) | 1931-10-19 | 1932-10-18 | Metal finish and process of obtaining the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US569853A US1970548A (en) | 1931-10-19 | 1931-10-19 | Metal finish |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1970548A true US1970548A (en) | 1934-08-21 |
Family
ID=24277152
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US569853A Expired - Lifetime US1970548A (en) | 1931-10-19 | 1931-10-19 | Metal finish |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US1970548A (enrdf_load_stackoverflow) |
| FR (1) | FR743797A (enrdf_load_stackoverflow) |
| GB (1) | GB409001A (enrdf_load_stackoverflow) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2507400A (en) * | 1943-08-02 | 1950-05-09 | Sk Wellman Co | Method of electroplating with iron and cobalt |
| US2528601A (en) * | 1946-01-05 | 1950-11-07 | Metal & Thermit Corp | Copper-tin alloy plating |
| US2658032A (en) * | 1949-06-11 | 1953-11-03 | City Auto Stamping Co | Electrodeposition of bright copper-tin alloy |
| US2667429A (en) * | 1949-02-11 | 1954-01-26 | Rca Corp | Coating mixture with addition agent and method of coating therewith |
| US2918722A (en) * | 1955-11-02 | 1959-12-29 | Nat Standard Co | Electrical communication wire |
| US3051633A (en) * | 1959-03-16 | 1962-08-28 | Sealed Power Corp | Process of chromium plating vented piston rings |
| US3321328A (en) * | 1962-11-15 | 1967-05-23 | Ibm | Coating of aluminum substrates with a magnetic material |
| US3869261A (en) * | 1974-05-22 | 1975-03-04 | Usui Kokusai Sangyo Kk | Corrosion-resistant composite coating to be formed on steel materials and method of forming the same |
| ITVI20120300A1 (it) * | 2012-11-08 | 2014-05-09 | Italo Caoduro | Oggetto con strato superficiale di copertura ottenuto per deposizione elettrolitica, soluzione elettrolitica impiegata in tale deposizione e metodo di realizzazione di tale oggetto. |
| IT202100008084A1 (it) * | 2021-03-31 | 2022-10-01 | Bluclad S P A | Soluzione elettrolitica per l’elettrodeposizione su substrato metallico di uno strato preparatore a base di rame e stagno |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1219708A (en) * | 1984-05-01 | 1987-03-31 | Michael J.H. Ruscoe | Aureate coins, medallions and tokens |
| CA2013639C (en) * | 1990-04-02 | 1998-06-23 | Mitsuhiro Yasuda | Electroplated blank for coins, medallions and tokens |
-
0
- FR FR743797D patent/FR743797A/fr not_active Expired
-
1931
- 1931-10-19 US US569853A patent/US1970548A/en not_active Expired - Lifetime
-
1932
- 1932-10-18 GB GB29160/32A patent/GB409001A/en not_active Expired
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2507400A (en) * | 1943-08-02 | 1950-05-09 | Sk Wellman Co | Method of electroplating with iron and cobalt |
| US2528601A (en) * | 1946-01-05 | 1950-11-07 | Metal & Thermit Corp | Copper-tin alloy plating |
| US2667429A (en) * | 1949-02-11 | 1954-01-26 | Rca Corp | Coating mixture with addition agent and method of coating therewith |
| US2658032A (en) * | 1949-06-11 | 1953-11-03 | City Auto Stamping Co | Electrodeposition of bright copper-tin alloy |
| US2918722A (en) * | 1955-11-02 | 1959-12-29 | Nat Standard Co | Electrical communication wire |
| US3051633A (en) * | 1959-03-16 | 1962-08-28 | Sealed Power Corp | Process of chromium plating vented piston rings |
| US3321328A (en) * | 1962-11-15 | 1967-05-23 | Ibm | Coating of aluminum substrates with a magnetic material |
| US3869261A (en) * | 1974-05-22 | 1975-03-04 | Usui Kokusai Sangyo Kk | Corrosion-resistant composite coating to be formed on steel materials and method of forming the same |
| ITVI20120300A1 (it) * | 2012-11-08 | 2014-05-09 | Italo Caoduro | Oggetto con strato superficiale di copertura ottenuto per deposizione elettrolitica, soluzione elettrolitica impiegata in tale deposizione e metodo di realizzazione di tale oggetto. |
| EP2730683A1 (en) * | 2012-11-08 | 2014-05-14 | Italo Caoduro | Object with surface covering layer obtained through electrolytic deposition, electrolytic solution used for said deposition and method for making said object. |
| IT202100008084A1 (it) * | 2021-03-31 | 2022-10-01 | Bluclad S P A | Soluzione elettrolitica per l’elettrodeposizione su substrato metallico di uno strato preparatore a base di rame e stagno |
Also Published As
| Publication number | Publication date |
|---|---|
| GB409001A (en) | 1934-04-18 |
| FR743797A (enrdf_load_stackoverflow) | 1933-04-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2470775A (en) | Electroplating nickel and cobalt with periodic reverse current | |
| US2678909A (en) | Process of electrodeposition of metals by periodic reverse current | |
| US1970548A (en) | Metal finish | |
| GB2032961A (en) | Multi-layer corrosion resistant plating utilizing alloys hving micro-throwing powr | |
| US1931704A (en) | Process of protecting ferrous metals | |
| US2871550A (en) | Composite chromium electroplate and method of making same | |
| US2989446A (en) | Electroplating | |
| US3247082A (en) | Electrodeposition of a corrosion resistant coating | |
| US20060257683A1 (en) | Stainless steel electrolytic coating | |
| US1970549A (en) | Process of electroplating bronze | |
| US2658266A (en) | Laminated coating | |
| US3009238A (en) | Protective and decorative nickel coatings | |
| US2832729A (en) | Electrodeposition of iron-zinc alloys | |
| US2078868A (en) | Electroplating process | |
| US3064337A (en) | Composite metal article | |
| US3009236A (en) | Protective and decorative coatings containing nickel | |
| US2468825A (en) | Plating | |
| US1651278A (en) | Process of producing corrosion-resisting coating on iron and steel and products | |
| US2462870A (en) | Electrodeposition of copper | |
| US2856334A (en) | Chromium plating | |
| US1904732A (en) | Alloy plated iron and steel and process of making the same | |
| US2061056A (en) | Method of plating and article produced thereby | |
| US3202589A (en) | Electroplating | |
| US1614303A (en) | Process of producing corrosion-resisting coating on iron and steel and products thereof | |
| US2221562A (en) | Electroplating |