US1947597A - Process for incorporation of metalcompounds into textiles - Google Patents
Process for incorporation of metalcompounds into textiles Download PDFInfo
- Publication number
- US1947597A US1947597A US581504A US58150431A US1947597A US 1947597 A US1947597 A US 1947597A US 581504 A US581504 A US 581504A US 58150431 A US58150431 A US 58150431A US 1947597 A US1947597 A US 1947597A
- Authority
- US
- United States
- Prior art keywords
- textiles
- textile
- treated
- ammonia
- drying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004753 textile Substances 0.000 title description 22
- 238000000034 method Methods 0.000 title description 12
- 150000002736 metal compounds Chemical class 0.000 title description 3
- 238000010348 incorporation Methods 0.000 title description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical class N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- 238000001035 drying Methods 0.000 description 8
- 229910044991 metal oxide Inorganic materials 0.000 description 8
- 229910021529 ammonia Inorganic materials 0.000 description 7
- 150000004706 metal oxides Chemical class 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 5
- 150000004645 aluminates Chemical class 0.000 description 4
- 239000004411 aluminium Substances 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- -1 fatty acid salts Chemical class 0.000 description 4
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 4
- 239000004312 hexamethylene tetramine Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000009738 saturating Methods 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 159000000013 aluminium salts Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- QKSIFUGZHOUETI-UHFFFAOYSA-N copper;azane Chemical compound N.N.N.N.[Cu+2] QKSIFUGZHOUETI-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 description 1
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010414 supernatant solution Substances 0.000 description 1
- AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
- 229940007718 zinc hydroxide Drugs 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/59—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
- D06M11/62—Complexes of metal oxides or complexes of metal salts with ammonia or with organic amines
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Definitions
- This invention relates to a process for incorporating metal compounds in textile materials, more particularly in those textile materials which are capable of swelling, either for the purpose of conferring covering capability to the filaments or for producing, a special effect such as for example, resistance to water or the like.
- the precipitate deposited is not particularly stable, particularly during washing operations, so that the effect produced subsides after a short time.
- the subject of the present invention is a novel process for incorporating metal oxides in textiles of the most varied kind, more particularly those of fibres or filaments which are capable of swelling.
- the material is treated with these baths, preferably while heating is uniformly pressed or squeezed out and then, again preferably under the action of heat, dried.
- a simultaneous or subsequent treatment with 40 fats, waxes or resins in dissolved, saponified, or I emulsified form enhances the desired effect and improves more particularly the feel of the treated wares.
- the precipitates deposited according to the invention separate out in extremely fine form and are extraordinarily stable to the influence of weathering and washing so that their action is long maintained.
- the process is explained below with reference to some specific examples, but it must be understood that the scope of the invention is in no way limited to the specific examples given.
- Nickel nitrate or sulphate is precipitated with caustic soda, and the hydroxide obtained repeatedly Washed until the drainings no longer contain alkali.
- the nickel hydroxide, filtered in the pump, is covered with concentrated ammonia and allowed to stand for a prolonged time.
- the supernatant solution, which contains nickel hexamine hydroxide, is then decanted off into a vessel containing aluminium borings, or aluminiumpowder.
- the aluminium reacts with the nickel complex base and forms nickel hexammine aluminate.
- the alu minate which is ready for weighting purposes is decanted off.
- the textiles are treated for a short time with this solution, then rung out or centrifuged, and dried at about IG-.
- Nickel hexammine hydroxide is prepared as described in Example 1 and zinc hydroxide is dissolved therein. The weighting is effected as described in Example 1.
- a concentrated solution of copper tetrammine hydroxide is prepared in the known manner from copper'sulphate, caustic soda and ammonia, and the solution is treated with aluminium powder; For weighting materials the aluminate solution is diluted preferably threefold in order to decrease its solvent capacity for cellulose. The impregnation is effected as described in Examples 1 and 2. 7
- a process for incorporating metal oxides in textiles comprising saturating the textile with a metallic oxide-ammonia 'compound in aqueous solution, drying the textile at temperatures of about '70 to 80 C. to volatilize the ammonia while retaining said metal oxide in said textile and simultaneously treating the impregnated textile with saponified substances of the group consisting of fats, waxes and resins.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
Patented Feb. 20, 1934 PATENT OFFICE PROCESS FOR INCORPORATION OF METAL- COMPOUNDS INTO TEXTILES Franz Hoelkeskamp, Vtuppertal-Wichlingl1ausen,
Germany, assignor to the firm American Bemberg Corporation, New York, N. Y., a corporation of Delaware No Drawing.
Application December 16, 1931,
Serial No. 581,504, and in Germany December 8 Claims.
This invention relates to a process for incorporating metal compounds in textile materials, more particularly in those textile materials which are capable of swelling, either for the purpose of conferring covering capability to the filaments or for producing, a special effect such as for example, resistance to water or the like.
It is known to treat textiles with aluminium salts, more particularly salts of organic acids, in order to render the same water-proof. This treatment is either carried out alone or in com bination with a soaping treatment, so that after the drying the material treated contains either finely divided alumina or a coating of fatty acid salts of aluminium.
This method of treatment possesses certain disadvantages since the precipitates'deposited on the material are not very uniform. These nonuniformities show themselves 'on a fabric, for
2O example, in the form of cloudiness and may render the fabric Worthless. Furthermore, the precipitate deposited is not particularly stable, particularly during washing operations, so that the effect produced subsides after a short time.
The subject of the present invention is a novel process for incorporating metal oxides in textiles of the most varied kind, more particularly those of fibres or filaments which are capable of swelling. According to the invention the treatment baths contain aqueous solutions of com=- pounds which contain complex metal oxide ammonia compounds and oxides of amphoteric metals, i. e. metal ammonia salts of acids which are derived from oxides of amphoteric metals. The material is treated with these baths, preferably while heating is uniformly pressed or squeezed out and then, again preferably under the action of heat, dried.
A simultaneous or subsequent treatment with 40 fats, waxes or resins in dissolved, saponified, or I emulsified form enhances the desired effect and improves more particularly the feel of the treated wares.
During the drying the ammonia volatilizes and a mixture of oxides remains behind in the fibre which in the first place-weights the fibre to a certain extent, and consequently imparts covering capability to it, and, in certain circumstances, makes the treated material water-proof chosen. I i J The process is of universal application since by choosing suitable metal oxides the most vaor fire-proof when the oxides have beensuitablyin a bath and the capability of the bath of completely penetrating the material being treated. A further advantage consists in the fact that the metal oxides are deposited in a form of maximum subdivision. However, the fact that no acid is liberated during the production of the metal precipitates and cannot form a salt,- which might be harmful to the material, by interaction, also appears to be of very considerable advantage. The precipitates deposited according to the invention separate out in extremely fine form and are extraordinarily stable to the influence of weathering and washing so that their action is long maintained. The process is explained below with reference to some specific examples, but it must be understood that the scope of the invention is in no way limited to the specific examples given.
(1.) Nickel nitrate or sulphate is precipitated with caustic soda, and the hydroxide obtained repeatedly Washed until the drainings no longer contain alkali. The nickel hydroxide, filtered in the pump, is covered with concentrated ammonia and allowed to stand for a prolonged time. The supernatant solution, which contains nickel hexamine hydroxide, is then decanted off into a vessel containing aluminium borings, or aluminiumpowder. The aluminium reacts with the nickel complex base and forms nickel hexammine aluminate. On completion of the reaction the alu minate, which is ready for weighting purposes is decanted off.
In order to effect the weighting, the textiles are treated for a short time with this solution, then rung out or centrifuged, and dried at about IG-.
, (2.) Nickel hexammine hydroxide is prepared as described in Example 1 and zinc hydroxide is dissolved therein. The weighting is effected as described in Example 1.
(3.) A concentrated solution of copper tetrammine hydroxide is prepared in the known manner from copper'sulphate, caustic soda and ammonia, and the solution is treated with aluminium powder; For weighting materials the aluminate solution is diluted preferably threefold in order to decrease its solvent capacity for cellulose. The impregnation is effected as described in Examples 1 and 2. 7
(4.) Zinc tetrammine aluminate is prepared,
and the textiles are treated with it as described in Examples 1 to 3.
What I claim is:
1. In a process for incorporating metal oxides in textiles, the steps of saturating thetextile to be treated with a metallic oxide-ammonia compound in aqueous solution and then drying the textile at temperatures of about to C. to volatilize the ammonia while simultaneously retaim'ng said metal oxide in said textile.
2; The process as set forth in claim 1, in which the material is saturated with an aqueous solution of a metallic amine-aluminate.
3. In a process for incorporating metal oxides in textiles, the steps comprising saturating the textile with a metallic oxide-ammonia 'compound in aqueous solution, drying the textile at temperatures of about '70 to 80 C. to volatilize the ammonia while retaining said metal oxide in said textile and simultaneously treating the impregnated textile with saponified substances of the group consisting of fats, waxes and resins.
4. In a process for treating textiles the step of immersing them in a bath containing nickel hexamine aluminate, then removing the textile from the bath and drying it at from about 70 to 80 n ckel hexamine aluminate, then removing the' textile from the bath and drying it at from about 70lto 80 C.
7. In a process for treating textiles, the steps of immersing them in a bath containing a metallic hexamine zincate, then removing the textile from the bath and drying it at from about 70 to 80 C.
' 8. In the treatment of textiles, the step of immersing the same in a bath containing copper tetramine hydroxide which has been treated with aluminum powder, then removing thetextile from the bath and drying it at from about 70 to 80 C.
FRANZ HOELKESKAMIP.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE542775T | 1931-01-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1947597A true US1947597A (en) | 1934-02-20 |
Family
ID=34258076
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US581504A Expired - Lifetime US1947597A (en) | 1931-01-01 | 1931-12-16 | Process for incorporation of metalcompounds into textiles |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US1947597A (en) |
| BE (1) | BE386187A (en) |
| DE (1) | DE542775C (en) |
| FR (1) | FR728376A (en) |
| GB (1) | GB378760A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2734834A (en) * | 1955-02-04 | 1956-02-14 | Coated pile fabric and method of making | |
| US3203752A (en) * | 1961-12-22 | 1965-08-31 | Ici Ltd | Aftertreatment of dyed polypropylene fibers containing a metal compound with metal complexes |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5427844A (en) * | 1991-06-12 | 1995-06-27 | New Japan Chemical Co., Ltd. | Articles of natural cellulose fibers with improved deodorant properties and process for producing same |
| JP3146262B2 (en) * | 1991-06-12 | 2001-03-12 | 敷島紡績株式会社 | Natural cellulose fiber holding inorganic metal compound and method for producing the same |
-
0
- BE BE386187D patent/BE386187A/xx unknown
-
1931
- 1931-01-01 DE DE1931542775D patent/DE542775C/en not_active Expired
- 1931-12-16 US US581504A patent/US1947597A/en not_active Expired - Lifetime
- 1931-12-17 FR FR728376D patent/FR728376A/en not_active Expired
- 1931-12-31 GB GB36113/31A patent/GB378760A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2734834A (en) * | 1955-02-04 | 1956-02-14 | Coated pile fabric and method of making | |
| US2734835A (en) * | 1955-02-04 | 1956-02-14 | Soil resistant fabric and method of | |
| US3203752A (en) * | 1961-12-22 | 1965-08-31 | Ici Ltd | Aftertreatment of dyed polypropylene fibers containing a metal compound with metal complexes |
Also Published As
| Publication number | Publication date |
|---|---|
| FR728376A (en) | 1932-07-05 |
| GB378760A (en) | 1932-08-18 |
| BE386187A (en) | |
| DE542775C (en) | 1932-01-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4201825A (en) | Metallized textile material | |
| US2260278A (en) | Process for the production of opaque protective coatings on aluminum and its alloys | |
| US1947597A (en) | Process for incorporation of metalcompounds into textiles | |
| US1536254A (en) | Water-repellent textile material and method of producing the same | |
| DE1958596A1 (en) | Process for the production of a carrier catalyst for the oxidation of ethylene to ethylene oxide | |
| US2724632A (en) | Cyanoethylated cellulose textiles modified with chromic and periodic acids and process of making same | |
| US2457853A (en) | Treatment of textiles and composition therefor | |
| US2528517A (en) | Impregnated protective charcoal and its manufacture | |
| US2140759A (en) | Method for dressing, treating, and finishing furs | |
| US1634791A (en) | Mothproofing composition | |
| US1648433A (en) | Textile material and method of dyeing the same | |
| US2565832A (en) | Process for treating cellulose fibers and composition therefor | |
| US1531143A (en) | Process for obtaining new effects on animal fibers | |
| US2234091A (en) | Treatment of textile materials | |
| US2127650A (en) | Coating, sizing, and finishing compositions | |
| US2831853A (en) | Manufacture of sizing | |
| US2252730A (en) | Method of treating and finishing cellulose and cellulosic fibers and products | |
| US1802935A (en) | Method of washing artificial silk | |
| US675413A (en) | Process of coating fibrous material with metal. | |
| US2295063A (en) | Protective coating | |
| US2429073A (en) | Dyed composite felt and method of making same | |
| US3024080A (en) | 2, 6-dioxaspiro (3, 3)heptane treated cellulose fabric and the production thereof | |
| US2737462A (en) | Process of stiffening felted bodies | |
| US2775506A (en) | Production of artificial filaments, threads, fibres, bands, and the like | |
| US3058848A (en) | Anti-crease finishings and their manufacture |